WO2001002838A1 - Apparatus and method for gas sensing - Google Patents

Apparatus and method for gas sensing Download PDF

Info

Publication number
WO2001002838A1
WO2001002838A1 PCT/NZ2000/000118 NZ0000118W WO0102838A1 WO 2001002838 A1 WO2001002838 A1 WO 2001002838A1 NZ 0000118 W NZ0000118 W NZ 0000118W WO 0102838 A1 WO0102838 A1 WO 0102838A1
Authority
WO
WIPO (PCT)
Prior art keywords
hght
gas
photodetector
source
optical fibre
Prior art date
Application number
PCT/NZ2000/000118
Other languages
French (fr)
Inventor
Andrew Wilson
Original Assignee
University Of Otago
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University Of Otago filed Critical University Of Otago
Priority to NZ516974A priority Critical patent/NZ516974A/en
Priority to AU57194/00A priority patent/AU768639B2/en
Priority to EP00942591A priority patent/EP1198702A4/en
Publication of WO2001002838A1 publication Critical patent/WO2001002838A1/en

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
    • G—PHYSICS
    • G08—SIGNALLING
    • G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B17/00—Fire alarms; Alarms responsive to explosion
    • G08B17/10—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means
    • G08B17/103—Actuation by presence of smoke or gases, e.g. automatic alarm devices for analysing flowing fluid materials by the use of optical means using a light emitting and receiving device
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N2021/1793—Remote sensing
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • G01N2021/391—Intracavity sample
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/08—Optical fibres; light guides

Definitions

  • the invention relates to an optical fibre delivery system for apparatus and method for sensing properties of a gas such as concentration or temperature by reference to the attenuation of light passing through the gas (trace gas sensing) .
  • the invention comprises apparatus for remote gas sensing comprising a photodetector and a gas cell containing a gas or zone through which the gas passes and through which light from a light source passes and is reflected back to the photodetector, wherein the light source and photodetector, and the gas cell, are connected by a single polarisation preserving optical fibre through which light from the source passes to the gas cell, with Hght reflected back from the cell passing back through the optical fibre with a different polarisation to the transmitted light.
  • the apparatus of the invention more specifically comprises a light source, a gas cell or zone, a photodetector to receive light reflected back from the gas cell, a single polarisation preserving optical fibre connecting the light source and photodetector to the gas cell, means to polarise return light exiting the gas so that it re-enters the optical fibre polarised orthogonal to the transmitted light, and means at the other end of the optical fibre to split the return light from the transmitted light and direct the return hght to the photodetector.
  • the invention comprises a method for remote gas sensing utilising a photodetector and a gas cell or zone containing the gas or through which the gas passes and through which light from a source passes and is reflected back to the photodetector, including passing light from the source to the gas cell and back to the photodetector via a single polarisation preserving optical fibre such that the return light passes through the optical fibre with a different polarisation to that of the transmitted light.
  • the light source and photodetector are connected to the gas cell or zone via an arrangement including a polarisation preserving optical fibre which carries the transmitted and reflected light with different polarisations, which enables the photodetector and gas cell or zone to be remotely positioned from one another.
  • the photodetector and associated electronics do not need to be positioned close to the gas cell or zone.
  • the use of different polarisation for transmitted and reflected hght eliminates unwanted optical interference, and enables separation of reflected from transmitted light for optical detection.
  • a polarising beam splitter 1 which is oriented to linearly polarise the Hght parallel to one of the two polarisation maintaining axis of a polarisation preserving single-mode optical fibre 2.
  • the Hght is launched into the polarisation preserving fibre by a lens 3, and propagates through the optical fibre rnaintaining its polarisation state.
  • the Hght Upon exiting the fibre, the Hght is colHmated by a second lens 4, and propagates through a gas sample region or ceU 5, in a double pass configuration using a quarter- wave retarder 6 and retro-reflecting mirror 7. Some of the Hght is absorbed by the gas as it propagates through the gas ample, and this is used to determine properties of the sample, such as concentration and temperature.
  • Quarter-wave retarder 6 is oriented to change the polarisation state of the transmitted Hght from linear to pure circular. After retro-reflection by the mirror 7, the return Hght then passes back through the quarter- wave retarder 6, which changes the polarisation state of the Hght from circular back to linear, but with an orientation perpendicular to that of the forward propagating (transmitted) Hght.
  • the mirror 7 is aHgned so that the reflected Hght is launched back into the fibre, but because it is linearly polarised perpendicular to the forward propagating Hght, the reflecte ⁇ Hght is polarised paraUel to the other polarisation preserving axis of the optical fibre. This means that the forward and retro-reflected Hght propagates simultaneously through the optical fibre, but they have orthogonal linear polarisation states.
  • the retro-reflected Hght Upon exiting the fibre, the retro-reflected Hght is separated from the forward propagating Hght by the polarising beam spHtter 1 , and directed to the photodetector where its intensity is measured.
  • iHustrated is described by way of example.
  • Alternative arrangements utiHsed in the concept of the invention are possible.
  • Hght exiting the optical fibre may be aUowed to diverge by removing the collimating lens 4, and then retro-reflected using a spherical mirror placed a small distance equal to the radius of curvature of the mirror.
  • separate optical components may be replaced by thin film or optical fibre based elements.
  • the gas sample region or ceU 5 may be positioned in a hostile environment (for example hot or toxic), a cramped environment (for example within a compact machine), or a very distant location (for example on top of a smoke stack).
  • a hostile environment for example hot or toxic
  • a cramped environment for example within a compact machine
  • a very distant location for example on top of a smoke stack

Abstract

An apparatus for remote gas sensing comprises a light source, a polarising beam splitter (1), a photodetector, a single polarisation preserving optical fibre (2), a gas cell (5) or a zone through which the gas passes, a quarter-wave plate (6) and a mirror (7). A light beam from the light source passes through the beam splitter (1) and is focused by a lens (3) into the fibre (2) where it travels maintaining its polarisation state. Upon exiting the fibre (2), the light is collimated by a second lens (4) and propagates through the gas cell (5) and the quarter-wave plate (6) in a double pass configuration being retro-reflected by the mirror (7). The light beams is then focused back into the fibre (2) where it propagates with a polarisation state which is perpendicular to that of the forward propagating light. When light emerges from the fibre (2), it is reflected by the beam splitter (1) onto the photodetector.

Description

APPARATUS AND METHOD FOR GAS SENSING
FIELD OF INVENTION
The invention relates to an optical fibre delivery system for apparatus and method for sensing properties of a gas such as concentration or temperature by reference to the attenuation of light passing through the gas (trace gas sensing) .
SUMMARY OF INVENTION
In broad terms in one aspect the invention comprises apparatus for remote gas sensing comprising a photodetector and a gas cell containing a gas or zone through which the gas passes and through which light from a light source passes and is reflected back to the photodetector, wherein the light source and photodetector, and the gas cell, are connected by a single polarisation preserving optical fibre through which light from the source passes to the gas cell, with Hght reflected back from the cell passing back through the optical fibre with a different polarisation to the transmitted light.
In one form the apparatus of the invention more specifically comprises a light source, a gas cell or zone, a photodetector to receive light reflected back from the gas cell, a single polarisation preserving optical fibre connecting the light source and photodetector to the gas cell, means to polarise return light exiting the gas so that it re-enters the optical fibre polarised orthogonal to the transmitted light, and means at the other end of the optical fibre to split the return light from the transmitted light and direct the return hght to the photodetector.
In broad terms in another aspect the invention comprises a method for remote gas sensing utilising a photodetector and a gas cell or zone containing the gas or through which the gas passes and through which light from a source passes and is reflected back to the photodetector, including passing light from the source to the gas cell and back to the photodetector via a single polarisation preserving optical fibre such that the return light passes through the optical fibre with a different polarisation to that of the transmitted light. In the apparatus and method of the invention the light source and photodetector are connected to the gas cell or zone via an arrangement including a polarisation preserving optical fibre which carries the transmitted and reflected light with different polarisations, which enables the photodetector and gas cell or zone to be remotely positioned from one another. The photodetector and associated electronics do not need to be positioned close to the gas cell or zone. The use of different polarisation for transmitted and reflected hght eliminates unwanted optical interference, and enables separation of reflected from transmitted light for optical detection.
BRIEF DESCRIPTION OF THE DRAWING
The accompanying drawing schematically illustrates one preferred arrangement of gas sensing apparatus, by way of example.
DETAILED DESCRIPTION OF PREFERRED FORM
Light from a source such as a laser passes through a polarising beam splitter 1 which is oriented to linearly polarise the Hght parallel to one of the two polarisation maintaining axis of a polarisation preserving single-mode optical fibre 2. The Hght is launched into the polarisation preserving fibre by a lens 3, and propagates through the optical fibre rnaintaining its polarisation state.
Upon exiting the fibre, the Hght is colHmated by a second lens 4, and propagates through a gas sample region or ceU 5, in a double pass configuration using a quarter- wave retarder 6 and retro-reflecting mirror 7. Some of the Hght is absorbed by the gas as it propagates through the gas ample, and this is used to determine properties of the sample, such as concentration and temperature.
Quarter-wave retarder 6 is oriented to change the polarisation state of the transmitted Hght from linear to pure circular. After retro-reflection by the mirror 7, the return Hght then passes back through the quarter- wave retarder 6, which changes the polarisation state of the Hght from circular back to linear, but with an orientation perpendicular to that of the forward propagating (transmitted) Hght. The mirror 7 is aHgned so that the reflected Hght is launched back into the fibre, but because it is linearly polarised perpendicular to the forward propagating Hght, the reflecteα Hght is polarised paraUel to the other polarisation preserving axis of the optical fibre. This means that the forward and retro-reflected Hght propagates simultaneously through the optical fibre, but they have orthogonal linear polarisation states.
Upon exiting the fibre, the retro-reflected Hght is separated from the forward propagating Hght by the polarising beam spHtter 1 , and directed to the photodetector where its intensity is measured.
The preferred form iHustrated is described by way of example. Alternative arrangements utiHsed in the concept of the invention are possible. For example in an alternative arrangement Hght exiting the optical fibre may be aUowed to diverge by removing the collimating lens 4, and then retro-reflected using a spherical mirror placed a small distance equal to the radius of curvature of the mirror. In addition, separate optical components may be replaced by thin film or optical fibre based elements.
The gas sample region or ceU 5 may be positioned in a hostile environment (for example hot or toxic), a cramped environment (for example within a compact machine), or a very distant location (for example on top of a smoke stack).
The foregoing describes the invention including a preferred form thereof. Alterations and modifications as wul be obvious to those skilled in the art are intended to be incorporated within the scope hereof as defined in the accompanying claims.

Claims

1. An apparatus for remote gas sensing comprising a Hght source, a photodetector, a gas ceU containing gas or a zone through which the gas passes and through which Hght from the Hght source passes and is reflected back to the photodetector, wherein the Hght source, photodetector and gas ceU are connected by a single polarisation preserving optical fibre through which Hght from the Hght source passes to the gas cell, which Hght reflected back from the ceU passes back through the optical fibre with a different polarisation to that to the Hght transmitted by the Hght source.
2. An apparatus according to claim 1 further comprising means to polarise the returned Hght exiting the gas so that it re-enters the optical fibre polarised orthogonal to the transmitted Hght.
3. An apparatus according to either one of claims 1 and 2 further comprising means between the Hght source and the optical fibre arranged to spHt the returned Hght from the transmitted Hght and direct the returned Hght to the photodetector.
4. An apparatus according to any one of claims 1 to 3 wherein the Hght source and photodetector are positioned remotely to the gas ceU or zone.
5. A method for remote gas sensing utiHsing a Hght source, a photodetector and a gas ceU or zone containing gas or through which gas passes and through which Hght from the Hght source passes and is reflected back to the photodetector, including passing Hght from the source to the gas ceU and back to the photodetector via a single polarisation preserving optical fibre such that the return Hght passes through the optical fibre with a different polarisation to that of the transmitted Hght.
6. A method according to claim 5 further comprising polarising the returned
Hght exiting the gas so that it re-enters the optical fibre polarised orthogonal to the transmitted Hght.
7. A method according to either one of claims 5 and 6 further comprising spHtting, between the Hght source and the optical fibre, the returned Hght from the transmitted Hght and directing the returned Hght to the photodetector.
8. A method according to any one of claims 5 to 7 wherein the Hght source and photodetector are positioned remotely to the gas ceU or zone.
9. An apparatus for remote gas sensing, substantiaHy as herein described with reference to the accompanying drawing.
10. A method for remote gas sensing, substantiaHy as herein described with reference to the accompany drawing.
PCT/NZ2000/000118 1999-07-02 2000-07-03 Apparatus and method for gas sensing WO2001002838A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NZ516974A NZ516974A (en) 1999-07-02 2000-07-03 Apparatus and method for gas sensing
AU57194/00A AU768639B2 (en) 1999-07-02 2000-07-03 Apparatus and method for gas sensing
EP00942591A EP1198702A4 (en) 1999-07-02 2000-07-03 Apparatus and method for gas sensing

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NZ336552 1999-07-02
NZ33655299 1999-07-02

Publications (1)

Publication Number Publication Date
WO2001002838A1 true WO2001002838A1 (en) 2001-01-11

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ID=19927362

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NZ2000/000118 WO2001002838A1 (en) 1999-07-02 2000-07-03 Apparatus and method for gas sensing

Country Status (3)

Country Link
EP (1) EP1198702A4 (en)
AU (1) AU768639B2 (en)
WO (1) WO2001002838A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100403347C (en) * 2004-09-18 2008-07-16 清华大学深圳研究生院 Interference photoelectric smoke and fire detecting method and its device
CN100465505C (en) * 2006-03-07 2009-03-04 南开大学 Watt-grade broadband super-fluorescence light source with ytterbium doped photonic crystal fiber
EP2571117A1 (en) 2011-09-15 2013-03-20 Axetris AG Laser unit with reduced back reflection
EP2720326A1 (en) 2013-03-12 2014-04-16 Axetris AG Gas detection laser light source with reduced optical feedback
CN108074369A (en) * 2016-11-11 2018-05-25 基德科技公司 For smog of the aircraft based on optical fiber and/or overheating detection and monitoring

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111815924B (en) * 2020-08-21 2022-06-07 中国民用航空飞行学院 Thermal disaster early warning system and method for power lithium battery of all-electric drive fire truck in airport

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US4516432A (en) * 1983-10-13 1985-05-14 Nihon Kagaku Kogyo Co., Ltd. Apparatus for measuring two-phase flow
US4824251A (en) * 1987-09-25 1989-04-25 Digital Signal Corporation Optical position sensor using coherent detection and polarization preserving optical fiber
FR2666163A1 (en) * 1990-08-22 1992-02-28 Bertin & Cie Opto-electronic device for detecting smoke or gas in suspension in air
JPH09282577A (en) * 1996-04-11 1997-10-31 Tokyo Gas Co Ltd Gas detector
US6050656A (en) * 1997-10-23 2000-04-18 University Of North Carolina At Charlotte Optical based opacity and flow monitoring system and method of monitoring opacity and flow

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4516432A (en) * 1983-10-13 1985-05-14 Nihon Kagaku Kogyo Co., Ltd. Apparatus for measuring two-phase flow
US4824251A (en) * 1987-09-25 1989-04-25 Digital Signal Corporation Optical position sensor using coherent detection and polarization preserving optical fiber
FR2666163A1 (en) * 1990-08-22 1992-02-28 Bertin & Cie Opto-electronic device for detecting smoke or gas in suspension in air
JPH09282577A (en) * 1996-04-11 1997-10-31 Tokyo Gas Co Ltd Gas detector
US6050656A (en) * 1997-10-23 2000-04-18 University Of North Carolina At Charlotte Optical based opacity and flow monitoring system and method of monitoring opacity and flow

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Derwent World Patents Index; Class S03, AN 1992-134360/17 *
PATENT ABSTRACTS OF JAPAN *
See also references of EP1198702A4 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100403347C (en) * 2004-09-18 2008-07-16 清华大学深圳研究生院 Interference photoelectric smoke and fire detecting method and its device
CN100465505C (en) * 2006-03-07 2009-03-04 南开大学 Watt-grade broadband super-fluorescence light source with ytterbium doped photonic crystal fiber
EP2571117A1 (en) 2011-09-15 2013-03-20 Axetris AG Laser unit with reduced back reflection
CN102998281A (en) * 2011-09-15 2013-03-27 阿克塞特里斯股份公司 Laser unit with reduced back reflection
EP2720326A1 (en) 2013-03-12 2014-04-16 Axetris AG Gas detection laser light source with reduced optical feedback
CN108074369A (en) * 2016-11-11 2018-05-25 基德科技公司 For smog of the aircraft based on optical fiber and/or overheating detection and monitoring

Also Published As

Publication number Publication date
AU768639B2 (en) 2003-12-18
AU5719400A (en) 2001-01-22
EP1198702A1 (en) 2002-04-24
EP1198702A4 (en) 2005-02-02

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