US3750962A - Disintegration process for fibrous sheet material - Google Patents

Disintegration process for fibrous sheet material Download PDF

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US3750962A
US3750962A US00182796A US3750962DA US3750962A US 3750962 A US3750962 A US 3750962A US 00182796 A US00182796 A US 00182796A US 3750962D A US3750962D A US 3750962DA US 3750962 A US3750962 A US 3750962A
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sheet
sheet material
fibrous sheet
drylap
tips
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US00182796A
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G Morgan
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Procter and Gamble Co
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Procter and Gamble Co
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/06Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
    • D21B1/066Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods the raw material being pulp sheets

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  • ABSTRACT A process for continuously converting dried cellulosic fibrous sheet material into a dispersion of individual fibers in air.
  • the fibrous sheet is advanced into a disintegrating device wherein the end of the sheet is repeatedly impacted at a predetermined velocity by one or more impacting elements at a critical distance from the support elements for the sheet.
  • the fibrous sheet is entirely disintegrated into individual fibers at relatively high rates.
  • the principal object of the present invention is to improve the operation of the prior art device of US. Pat. No. 3,519,2l1.
  • Another object of the present invention is the provision of a process for disintegrating dried cellulosic fibrous sheet material into individual cellulose fibers in such a way as to minimize the scorching and burning of the fibers.
  • Still another object of the present invention is the provision of a disintegration process for fibrous sheet material which increases the capacity and efficiency of the previously known processes and apparatus of this kind without need for artificial cooling.
  • the nature and substance of the invention can be briefly summarized as comprising a process for converting dried cellulosic fibrous sheet material into a dispersion of individual fibers in air.
  • the fibrous sheet material is fed inwardly to a disintegrating device having a plurality of impacting elements.
  • the fibrous sheet is advanced continuously between support elements for the sheet such that its end is disintegrated by the impact of the tips of the impacting elements on the free end of the sheet at a distance of from about 0.020 in. to about 0.050 in. from the end of the support elements.
  • the sheet is advanced at a relatively constant rate between successive impacts.
  • the fibers are freed from the cellulosic sheet whereupon they are dispersed in air and conducted away from the impact zone of disintegration by way of unobstructed passageways.
  • Such drylap sheets are typically between about 100 and about 200 pounds 1,000 ft. 2 basis weight, and generally have a caliper of at least about 0.04 inch or greater, e.g., from about 0.04 to about 0.06.
  • a drylap sheet of this type usually has a moisture content of less than about percent, e.g.,
  • dried cellulosic fibrous sheet describes any type of fibrous-sheet material capable of disintegration by the process of the invention.
  • a drylap sheet will be understood to mean a wood-fiber material of the above described characteristics to which the invention is preferably applied.
  • a roll 11 of drylap sheet material is unrolled into a web of sheet material 12 which is advanced to the disintegrator 13.
  • the sheet 12 is fed radially into the disintegrator 13.
  • a pair of metering infeed rolls l4 and 15 are mounted on one side of the disintegrator 13.
  • a motive power source which may typically be an electric motor is connected to the rolls in a conventional manner, to provide a driving force.
  • the disintegrator 13 comprises a casing 16 having a generally cylindrical bore".
  • the internal configuration of the casing 16 is not critical to the practice of the invention and it will be understood that a-cylindrical bore is shown in the preferred embodiment only as a matter of convenience.
  • a shaft 18 is joumaled in the casing such that one end extends outside the casing to permit coupling the shaft in some conventional manner to a motive source such as an electric motor. The motor continuously drives the shaft 18.
  • the casing 16 is provided with a slotted inlet opening 19 to receive the drylap sheet 12.
  • a relatively large discharge outlet 20 is provided in the bottom of the casing 16.
  • An air inlet opening 21 is provided near the discharge outlet 20 to permit air to be forced into the casing at a slight positive pressure from a suitable blower (not shown) or the like, for the purpose of preventing recycling of the fibers through the disintegrator. Additional air inlets 21a can be provided as necessary to carry out the function of adjusting the air flow.
  • Rotors 22 are keyed to the shaft 18 and are provided with a plurality of teeth 23 extending radially outwardly which serve as impacting elements 24. A critical small clearance is provided between the teeth 23 and the supports for the sheet 12 at the inner end 19a of the inlet opening 19. The inner end 19a forms a sheet support for the sheet 12.
  • successive teeth 23 impact the ends of the sheet 12 as the rotor 22 is turned.
  • the path of travel and the manner of supporting the teeth 23 is not critical to the practice of the invention. The only necessary requirement is that the teeth 23 are moved such that their tips 24 impact the sheet 12 with at least one force component normal or perpendicular to the free ends of the sheets as the tips move past the sheet support 19a.
  • the clearance between the tips 24 and the edge of the sheet support 19a should be maintained within a range of from about 0.023 in. to about 0.050 in.
  • this clearance is from about 0.027 in. to about 0.033 in. and most preferably about 0.028 in.
  • the gap range below about 0.035 is especially desirable with dry lap feed rates of from about 30 100 fpm where with this gap distance range there is essentially no scorching. With larger gap sizes there is scorching with these drylap feed rates unless auxilliary cooling means, e.g., a water spray, are provided; and with gaps smaller than about 0.023 in. the disintegration quality is much poorer. With higher feed rates gap sizes closer to 0.050 in.
  • the impact on the free end of the sheet material is preferably controlled by turning the rotor such that the impact velocity of the tips 24 is at least about 6,000 feet per minute, although an impact speed of at least about 12,000 feet per minute is preferred. About 15,500 feet per minute has been found to be a most desirable impact velocity. Velocities in excess of about 30,000 feet per minute are not practical with presently available materials.
  • the individual disintegrated fibers which have been disengaged from the sheet 12 are removed from the impact zone whereupon they are dispersed and discharged from the casing 16 by air flow and/or the velocity imparted to the fibers by the teeth 23.
  • the air flow is generated, at least in part, by rotation of the rotor, although it can be supplemented significantly by forced air flow into the casing from the inlet 21.
  • the individual fibers are removed at the discharge outlet 20 from where they can be conducted to a suitable collecting device.
  • a process for disintegrating dried cellulosic fibrous sheet material comprising the steps of feeding a fibrous sheet into a disintegrator comprising a casing, supporting said sheet in a slotted opening terminating in a sheet support in said casing, moving a plurality of impacting elements having tips so that the tips move at a velocity of at least about 6,000 feet per minute, and impacting said tips against the end of the fibrous sheet so that impact is substantially normal to the plane of the sheet whereby said fibrous sheet is disintegrated into individual fibers, the tips of said impacting elements moving past the sheet at a distance from the end of the sheet support of from about 0.023 in. to about 0.050 in., said distance being from about 0.023 in. to about 0.035 in.

Abstract

A process for continuously converting dried cellulosic fibrous sheet material into a dispersion of individual fibers in air. The fibrous sheet is advanced into a disintegrating device wherein the end of the sheet is repeatedly impacted at a predetermined velocity by one or more impacting elements at a critical distance from the support elements for the sheet. The fibrous sheet is entirely disintegrated into individual fibers at relatively high rates.

Description

United States Patent Morgamjr. 1 Aug. 7, 1973 [54] DISKNTEGRATION PROCESS FOR FIBROUS 1,417,961 5/1922 Williams 241/18 X SHEET MATERIAL 2,312,790 11/1957 Stuart 11.... 241/280 X 2,830,772 4/1958 Martin 241/280 [75] Inventor: George Morgan, Jr., Cincinnati,
Ohio
[73] Assignee: The Procter & Gamble Company, Cincinnati, Ohio [22] Filed: Sept. 22, 1971 [21] Appl. No.: 182,796
[52] US. Cl. 241/18 {51] Int. Cl. B02c 13/08 [58] Field of Search 241/18, 27, 28, 280
[56] References Cited UNITED STATES PATENTS 3,519,211 7/1970 Sakulich et a1. 241/18 Primary Examiner-Granville Y. Custer, Jr. Attorney-Richard C. Witte, Robert B. Aylor et a1.
[57] ABSTRACT A process for continuously converting dried cellulosic fibrous sheet material into a dispersion of individual fibers in air. The fibrous sheet is advanced into a disintegrating device wherein the end of the sheet is repeatedly impacted at a predetermined velocity by one or more impacting elements at a critical distance from the support elements for the sheet. The fibrous sheet is entirely disintegrated into individual fibers at relatively high rates.
9 Claims, 1 Drawing Figure PAIENIEDAUB 1m i/Z/fl INVENTOR. George Morgan J'r. BY W 8, 4 2m ATTORNEY DISINTEGRATION PROCESS FOR F IBROUS SHEET MATERIAL FIELD OF THE INVENTION This invention relates to the art of disintegrating fibrous sheet material. More particularly, it relates to a process whereby a dried cellulosic fibrous sheet is impacted under predetermined operating conditions to cause progressive disintegration of the sheet into individual fibers.
PRIOR ART A similar process is disclosed in U.S. Pat. No. 3,519,21 l where a different distance from the impacting element to the support elements is specified. Said patent is incorporated herein by reference.
OBJECTS OF THE INVENTION The principal object of the present invention is to improve the operation of the prior art device of US. Pat. No. 3,519,2l1.
Another object of the present invention is the provision of a process for disintegrating dried cellulosic fibrous sheet material into individual cellulose fibers in such a way as to minimize the scorching and burning of the fibers.
Still another object of the present invention is the provision of a disintegration process for fibrous sheet material which increases the capacity and efficiency of the previously known processes and apparatus of this kind without need for artificial cooling.
SUMMARYOF THE INVENTION The nature and substance of the invention can be briefly summarized as comprising a process for converting dried cellulosic fibrous sheet material into a dispersion of individual fibers in air. The fibrous sheet material is fed inwardly to a disintegrating device having a plurality of impacting elements. The fibrous sheet is advanced continuously between support elements for the sheet such that its end is disintegrated by the impact of the tips of the impacting elements on the free end of the sheet at a distance of from about 0.020 in. to about 0.050 in. from the end of the support elements. The sheet is advanced at a relatively constant rate between successive impacts. The fibers are freed from the cellulosic sheet whereupon they are dispersed in air and conducted away from the impact zone of disintegration by way of unobstructed passageways.
While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter regarded as forming the present invention, it is believed the invention will be better understood from the following description taken in connection with the accompanying drawing in which the Figure is a side elevation cross-section of the disintegration apparatus.
Referring now to the drawing, a preferred embodi ment of the process will be described with particular reference to the disintegration of a dried cellulosic fibrous sheet. The invention is particularly useful in disintegrating wood-fiber drylap material of the kind found in commerce. Such drylap" sheets are typically between about 100 and about 200 pounds 1,000 ft. 2 basis weight, and generally have a caliper of at least about 0.04 inch or greater, e.g., from about 0.04 to about 0.06. A drylap sheet of this type usually has a moisture content of less than about percent, e.g.,
about 7 percent, although lower and higher moisture contents can be used. It has been found that the method of the invention produces better results if the initial moisture content is as low as possible. In fact, a moisture content of about 1 percent was found to produce best results.
As .used herein, the term dried cellulosic fibrous sheet describes any type of fibrous-sheet material capable of disintegration by the process of the invention. On the other hand, a drylap sheet will be understood to mean a wood-fiber material of the above described characteristics to which the invention is preferably applied.
Referring now to the FIGURE, a roll 11 of drylap sheet material is unrolled into a web of sheet material 12 which is advanced to the disintegrator 13.
The sheet 12 is fed radially into the disintegrator 13. For this purpose, a pair of metering infeed rolls l4 and 15 are mounted on one side of the disintegrator 13. A motive power source which may typically be an electric motor is connected to the rolls in a conventional manner, to provide a driving force.
The disintegrator 13 comprises a casing 16 having a generally cylindrical bore". The internal configuration of the casing 16 is not critical to the practice of the invention and it will be understood that a-cylindrical bore is shown in the preferred embodiment only as a matter of convenience. A shaft 18 is joumaled in the casing such that one end extends outside the casing to permit coupling the shaft in some conventional manner to a motive source such as an electric motor. The motor continuously drives the shaft 18.
The casing 16 is provided with a slotted inlet opening 19 to receive the drylap sheet 12. A relatively large discharge outlet 20 is provided in the bottom of the casing 16. An air inlet opening 21 is provided near the discharge outlet 20 to permit air to be forced into the casing at a slight positive pressure from a suitable blower (not shown) or the like, for the purpose of preventing recycling of the fibers through the disintegrator. Additional air inlets 21a can be provided as necessary to carry out the function of adjusting the air flow.
One such system is disclosed in the copending application of Kenneth B. Buell entitled APPARATUS AND PROCESS FOR PREPARING AIRFELT, Ser. No. [82,795 filed concurrently herewith and incorporated herein by reference. 7
Rotors 22 are keyed to the shaft 18 and are provided with a plurality of teeth 23 extending radially outwardly which serve as impacting elements 24. A critical small clearance is provided between the teeth 23 and the supports for the sheet 12 at the inner end 19a of the inlet opening 19. The inner end 19a forms a sheet support for the sheet 12.
With the'above arrangement of the parts of the apparatus, successive teeth 23 impact the ends of the sheet 12 as the rotor 22 is turned. The path of travel and the manner of supporting the teeth 23 is not critical to the practice of the invention. The only necessary requirement is that the teeth 23 are moved such that their tips 24 impact the sheet 12 with at least one force component normal or perpendicular to the free ends of the sheets as the tips move past the sheet support 19a.
It has now been found that the clearance between the tips 24 and the edge of the sheet support 19a should be maintained withina range of from about 0.023 in. to about 0.050 in. Preferably, this clearance is from about 0.027 in. to about 0.033 in. and most preferably about 0.028 in. The gap range below about 0.035 is especially desirable with dry lap feed rates of from about 30 100 fpm where with this gap distance range there is essentially no scorching. With larger gap sizes there is scorching with these drylap feed rates unless auxilliary cooling means, e.g., a water spray, are provided; and with gaps smaller than about 0.023 in. the disintegration quality is much poorer. With higher feed rates gap sizes closer to 0.050 in. can be used since the short residence time in the heat generation zone will minimize scorching, but above 0.050, even with high feed rates, disintegration quality is significantly poorer. This gap size appears to be independent of the drylap, etc., which is used insofar as scorching is concerned, but good disintegration is dependent on the thickness of the drylap. The thicker the drylap, the larger the gap necessary for good disintegration.
The impact on the free end of the sheet material is preferably controlled by turning the rotor such that the impact velocity of the tips 24 is at least about 6,000 feet per minute, although an impact speed of at least about 12,000 feet per minute is preferred. About 15,500 feet per minute has been found to be a most desirable impact velocity. Velocities in excess of about 30,000 feet per minute are not practical with presently available materials.
The individual disintegrated fibers which have been disengaged from the sheet 12 are removed from the impact zone whereupon they are dispersed and discharged from the casing 16 by air flow and/or the velocity imparted to the fibers by the teeth 23. The air flow is generated, at least in part, by rotation of the rotor, although it can be supplemented significantly by forced air flow into the casing from the inlet 21. The individual fibers are removed at the discharge outlet 20 from where they can be conducted to a suitable collecting device.
The practice of the present process and apparatus results in the production of individual fibers in essentially the same size as they are derived originally from the pulping process prior to the manufacture of the fibrous sheet material being disintegrated. Such individual fibers may typically be somewhat contorted and fiattened cylinders of about -15 microns diameter and about 2,500 microns in length.
The preferred design of the tip 25 of the impacting elements 22 is set forth in the copending application of Kenneth B. Buell referred to hereinbefore.
While the present illustration of the invention describes the feeding of one sheet into the disintegrator, it will be understood, of course, that the invention can be practiced with the infeeding of two sheets or three or more sheets. The only structural changes that would be needed under such varying circumstances are in the number of pairs of infeed rolls and the provision of corresponding openings in the disintegrator casing for receiving the sheet material.
While particular embodiments of the invention have been illustrated and described, it will be obvious to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention and it is intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
What is claimed is:
1. A process for disintegrating dried cellulosic fibrous sheet material comprising the steps of feeding a fibrous sheet into a disintegrator comprising a casing, supporting said sheet in a slotted opening terminating in a sheet support in said casing, moving a plurality of impacting elements having tips so that the tips move at a velocity of at least about 6,000 feet per minute, and impacting said tips against the end of the fibrous sheet so that impact is substantially normal to the plane of the sheet whereby said fibrous sheet is disintegrated into individual fibers, the tips of said impacting elements moving past the sheet at a distance from the end of the sheet support of from about 0.023 in. to about 0.050 in., said distance being from about 0.023 in. to about 0.035 in. when said sheet material is advancing into said disintegrator at a speed of less than about fpm. and said distance being from about 0.023 in. to about 0.050 in. when said sheet material is advancing into said disintegrator at a speed of greater than about 100 fpm.
2. The process of claim 1 wherein the velocity of said tips is at least about 12,000 feet per minute.
3. The process of claim 1 wherein the distance from the sheet support to said tips is from about 0.027 in. to about 0.033 in.
4. The process of claim 3 wherein the cellulosic sheet material is fed into the disintegrator at a rate of from about 30 fpm to about 100 fpm.
5. The process of claim 4 wherein the dried cellulosic material is a drylap having a thickness of from about 0.04 in. to about 0.06 in.
6. The process of claim 3 wherein the dried cellulosic material is a drylap having a thickness of from about 0.04 in. to about 0.06 in.
7. The process of claim 6 wherein the moisture content of the drylap is less than about 7 percent.
8. The process of claim 3 wherein the velocity of said tips is less than about 30,000 feet per minute.
9. The process of claim 3 wherein the moisture content of the drylap is less than about 7 percent.

Claims (8)

  1. 2. The process of claim 1 wherein the velocity of said tips is at least about 12,000 feet per minute.
  2. 3. The process of claim 1 wherein the distance from the sheet support to said tips is from about 0.027 in. to about 0.033 in.
  3. 4. The process of claim 3 wherein the cellulosic sheet material is fed into the disintegrator at a rate of from about 30 fpm to about 100 fpm.
  4. 5. The process of claim 4 wherein the dried cellulosic material is a drylap having a thickness of from about 0.04 in. to about 0.06 in.
  5. 6. The process of claim 3 wherein the dried cellulosic material is a drylap having a thickness of from about 0.04 in. to about 0.06 in.
  6. 7. The process of claim 6 wherein the moisture content of the drylap is less than about 7 percent.
  7. 8. The process of claim 3 wherein the velocity of said tips is less than about 30,000 feet per minute.
  8. 9. The process of claim 3 wherein the moisture content of the drylap is less than about 7 percent.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388056A (en) * 1981-07-06 1983-06-14 The Procter & Gamble Company Apparatus for continuously making an air-laid fibrous web having patterned basis weight distribution
EP0169174A2 (en) * 1984-06-20 1986-01-22 FAMECCANICA S.p.A. Apparatus for the dry defibration of sheets of fibrous cellulose material and like materials, particularly for the preparation of absorbent masses for disposable nappies and the like
US4650127A (en) * 1985-01-31 1987-03-17 Kimberly-Clark Corporation Method and apparatus for fiberizing fibrous sheets
US5253815A (en) * 1990-10-31 1993-10-19 Weyerhaeuser Company Fiberizing apparatus
US5324391A (en) * 1990-10-31 1994-06-28 Weyerhaeuser Company Method for crosslinking cellulose fibers
US5437418A (en) * 1987-01-20 1995-08-01 Weyerhaeuser Company Apparatus for crosslinking individualized cellulose fibers
US5556976A (en) * 1987-01-20 1996-09-17 Jewell; Richard A. Reactive cyclic N-sulfatoimides and cellulose crosslinked with the imides
US6059924A (en) * 1998-01-02 2000-05-09 Georgia-Pacific Corporation Fluffed pulp and method of production
US6517017B1 (en) * 2001-08-07 2003-02-11 Masco Corporation End mill fiber chopper
US20120097351A1 (en) * 2010-01-06 2012-04-26 Sustainable Health Enterprises (She) Highly absorbent and retentive fiber material

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2708307C2 (en) * 1977-02-25 1983-04-28 Vsesojuznoe naučno-proizvodstvennoe ob"edinenie celljulozno-bumažnoj promyšlennosti, Leningrad Process for defibrating a web made of cellulose and apparatus for carrying out the process
US4241881A (en) * 1979-07-12 1980-12-30 Kimberly-Clark Corporation Fiber separation from pulp sheet stacks
JP4596520B2 (en) * 2004-08-25 2010-12-08 株式会社リブドゥコーポレーション Pulp crusher
CN111778588B (en) * 2020-06-03 2022-09-13 艾达索高新材料芜湖有限公司 Mechanical recovery method of unidirectional carbon fiber leftover material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1417961A (en) * 1920-10-07 1922-05-30 Williams Patent Crusher & Pulv Method of reducing fibrous sheet material
US2812790A (en) * 1954-10-04 1957-11-12 Hercules Powder Co Ltd Preparation of shredded wood pulp
US2830772A (en) * 1954-02-24 1958-04-15 Johns Manville Nodulator for mineral wool
US3519211A (en) * 1967-05-26 1970-07-07 Procter & Gamble Disintegration process for fibrous sheet material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1417961A (en) * 1920-10-07 1922-05-30 Williams Patent Crusher & Pulv Method of reducing fibrous sheet material
US2830772A (en) * 1954-02-24 1958-04-15 Johns Manville Nodulator for mineral wool
US2812790A (en) * 1954-10-04 1957-11-12 Hercules Powder Co Ltd Preparation of shredded wood pulp
US3519211A (en) * 1967-05-26 1970-07-07 Procter & Gamble Disintegration process for fibrous sheet material

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388056A (en) * 1981-07-06 1983-06-14 The Procter & Gamble Company Apparatus for continuously making an air-laid fibrous web having patterned basis weight distribution
EP0169174A2 (en) * 1984-06-20 1986-01-22 FAMECCANICA S.p.A. Apparatus for the dry defibration of sheets of fibrous cellulose material and like materials, particularly for the preparation of absorbent masses for disposable nappies and the like
EP0169174A3 (en) * 1984-06-20 1987-01-21 Fameccanica S.P.A. Apparatus for the dry defibration of sheets of fibrous cellulose material and like materials, particularly for the preparation of absorbent masses for disposable nappies and the like
US4650127A (en) * 1985-01-31 1987-03-17 Kimberly-Clark Corporation Method and apparatus for fiberizing fibrous sheets
US5437418A (en) * 1987-01-20 1995-08-01 Weyerhaeuser Company Apparatus for crosslinking individualized cellulose fibers
US5556976A (en) * 1987-01-20 1996-09-17 Jewell; Richard A. Reactive cyclic N-sulfatoimides and cellulose crosslinked with the imides
US6436231B1 (en) 1987-01-20 2002-08-20 Weyerhaeuser Method and apparatus for crosslinking individualized cellulose fibers
US5324391A (en) * 1990-10-31 1994-06-28 Weyerhaeuser Company Method for crosslinking cellulose fibers
US5253815A (en) * 1990-10-31 1993-10-19 Weyerhaeuser Company Fiberizing apparatus
US6059924A (en) * 1998-01-02 2000-05-09 Georgia-Pacific Corporation Fluffed pulp and method of production
US6517017B1 (en) * 2001-08-07 2003-02-11 Masco Corporation End mill fiber chopper
US20120097351A1 (en) * 2010-01-06 2012-04-26 Sustainable Health Enterprises (She) Highly absorbent and retentive fiber material
US8936697B2 (en) * 2010-01-06 2015-01-20 Sustainable Health Enterprises Highly absorbent and retentive fiber material
US20150152597A1 (en) * 2010-01-06 2015-06-04 Sustainable Health Enterprises (She) Highly absorbent and retentive fiber material
US9365972B2 (en) * 2010-01-06 2016-06-14 Sustainable Health Enterprises (She) Highly absorbent and retentive fiber material

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FI56565C (en) 1980-02-11
AT320417B (en) 1975-02-10
CH544582A (en) 1973-11-30
DE2245936C2 (en) 1983-02-24
ES406759A1 (en) 1975-10-01
IE36902L (en) 1973-03-22
DK133606C (en) 1976-11-01
DK133606B (en) 1976-06-14
IE36902B1 (en) 1977-03-16
BE789034A (en) 1973-03-20
CA976320A (en) 1975-10-21
AU4659772A (en) 1974-03-21
IT967713B (en) 1974-03-11
JPS4872401A (en) 1973-09-29
AU459658B2 (en) 1975-04-10
NO142450B (en) 1980-05-12
NL7212810A (en) 1973-03-26
JPS5225445B2 (en) 1977-07-07
GB1389606A (en) 1975-04-03
DE2245936A1 (en) 1973-03-29
FR2154195A5 (en) 1973-05-04
FI56565B (en) 1979-10-31
NO142450C (en) 1980-08-20

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