US2916630A - Electroluminescent device - Google Patents
Electroluminescent device Download PDFInfo
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- US2916630A US2916630A US776817A US77681758A US2916630A US 2916630 A US2916630 A US 2916630A US 776817 A US776817 A US 776817A US 77681758 A US77681758 A US 77681758A US 2916630 A US2916630 A US 2916630A
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- electrode
- energy
- photoconductor
- stratum
- electroluminescent
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- 239000000463 material Substances 0.000 description 77
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 59
- 230000005855 radiation Effects 0.000 description 41
- 239000000126 substance Substances 0.000 description 19
- 239000002131 composite material Substances 0.000 description 12
- 230000000644 propagated effect Effects 0.000 description 12
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 9
- 229910001887 tin oxide Inorganic materials 0.000 description 9
- 230000000717 retained effect Effects 0.000 description 8
- 230000035945 sensitivity Effects 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000235646 Cyberlindnera jadinii Species 0.000 description 1
- 241001424392 Lucia limbaria Species 0.000 description 1
- 101100427344 Mus musculus Usp10 gene Proteins 0.000 description 1
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229910052981 lead sulfide Inorganic materials 0.000 description 1
- 229940056932 lead sulfide Drugs 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- SLIUAWYAILUBJU-UHFFFAOYSA-N pentacene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC=CC=C5C=C4C=C3C=C21 SLIUAWYAILUBJU-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- UQMZPFKLYHOJDL-UHFFFAOYSA-N zinc;cadmium(2+);disulfide Chemical compound [S-2].[S-2].[Zn+2].[Cd+2] UQMZPFKLYHOJDL-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/12—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof structurally associated with, e.g. formed in or on a common substrate with, one or more electric light sources, e.g. electroluminescent light sources, and electrically or optically coupled thereto
- H01L31/14—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof structurally associated with, e.g. formed in or on a common substrate with, one or more electric light sources, e.g. electroluminescent light sources, and electrically or optically coupled thereto the light source or sources being controlled by the semiconductor device sensitive to radiation, e.g. image converters, image amplifiers or image storage devices
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
Definitions
- This invention relates to electroluminescent devices and, more particularly, to energyand image-amplifying devices having fast response and a high degree of sensitivity.
- the photoconductor layer can be represented as a parallel-connected resistance and capacitance.
- the electroluminescent layer can also be represented as a parallel-connected resistance and capacitance. Both of these parallel-connected R.C. circuits are connected in series across the source of energizing A.C. potential. When the photoconductor is not irradiated or otherwise energized, the resistances of both the photoconductor and the electroluminescent layer. are quite high.
- the capacitance of the photoconductor In order that most of the energizing potential is applied across the photoconductor under so-called dark conditions, the capacitance of the photoconductor must be small as compared to the capacitance of the electroluminescent portion of the device. This in turn requires that thickness of the photoconductor be made great as compared to the thickness of the electroluminescent phosphor layer. A thick photoconductor layer, however, impairs resolution and sensitivity and in addition, the most sensitive photoconductor materials are quite slow in response.
- the outermost electrodes bounding the separate strata which electrodes are not directly electrically. connected I to one another, are adapted to be connected across a source of D.C. potential.
- the remaining electrodeorj' electrodes are adapted to be commutated' in an alternating and rapid fashion in order alternately and rapidly to place such electrode or electrodes at a potential level which at least approaches'the potential level of the outermost uncommutated electrode which is adjacent to the electroluminescent phosphor. This allows the device to operate from D.C'.
- the device can be made extremely sensitive with respectto amplifying energy and energy-images and fast-response photoconductor materials can be used in very thin layers if desired.
- Fig. 1 is a sectional elevation of an energy-amplifying device with the commutator means therefor shown in per: spective view;
- Fig. 2 is a diagrammatic representationof the embodi ment as shown in Fig. 1; p v
- Fig. 3 is analternative'embodimentfof the device as shown in Fig. 1 Wherein 'the' phosphor and photoconductor strata are formed with an appreciable spacing therebetween;
- Fig. 4 isa diagrammatic representation of a multielement device which can operatev as an image amplifier
- Fig. 5 is a fragmentary, enlarged perspective view," partly in section, of one embodiment ofan image-a rfv plifying device; 7
- Fig.- 6 is' a fragmentary sectionalyenlargement, ofja portion of the device as shown, in Fig. 5, further illustratingconstrnctional details therefor;
- I Fig. 7 s a fragmentary, enlargedperspective view, shown partly in section, illustrating an .alternative embodiment of the device as, shown in Figs. Sand 6;,
- Fig. 8 is an alternative embodiment of an image-a'm-l plifying device wherein the photoconductor'andelectroluminescent phosphor strata. are considerably spacedfrom one another, with a commutating mechanism interposed therebetween;
- Fig. 6 is a fragmentary front elevation of the contact plate used to commutate the individual amplifying elementscomprising the device as shown in-Fig. 8.
- the numeral 10 in Fig. 1 illustrates anenergy-amplifying device which can also be” used as one element of an image-amplifying device.
- the device 10 generally comprises a first electrode 12 which is transmissive to the energy-amplified radiation to be presented by the device, a second electrode 14 and the "electrode 14 which also acts 'to energize the stratum 16 comprising electroluminescent phosphor.
- An additiqual electrode 12! is placed on the other side of the stratum 1 read this slashed; 2. is t ans s to the energy which is to be received by the device 10.
- the area of each of the electrodes can vary considerably.
- p t n which a utn at tl 9 the e se rede 15 s r pidly di a slh D-C- squ j .22. ca deliver a pot ntial of '100 yolts for example.
- the d v e 1 s s o n F 1 can b sou ri st d to amplify any energy which can be propagated through vacuum such as X-rays, ultraviolet radiations, visible, light, infrared radiations or cathode rays. This energy is" converted intoenergy-amplified radiations, which will normally take the form of visible light.
- a diagrammatic representation of the device illustrated in Fig, 'l is shown in Fig.
- the photoconductor stratum 18 is represented as s i ns ich is uit h wh n he ho o onductor stratum is not energized and which varies inversely with the intensity of the energy to be received by the device 10.' In other words, the stronger the exciting energy signal, he lower the resistance or" the photoconductor stratum 18 A lowered resistance of the photo- Conductor stratum 18 allows one side of the capacitor formed bythe electroluminescent stratum 16 and the bounding electrodes 12 and 14 to charge, with the rate of charging being determined by the intensity of the re; ceived energy.
- the commutator 2,8 After a predetermined period, which can be second for example, the commutator 2,8 has rotated sufficiently to place the electrode 14 at substantially the same potential level as the electrode 12.
- This sudden dissipation of charge causes the electroluminescent cell which is formed by the electrodes 12 and 14- and theiph'osphor stratum 16 to emit a sudden flash of light, the intensity of which varies with the amount of charge dissipated.
- the device thus operates on the Priuciple that a D.C charge is accumulated and then is"suddenly, discharged and the resulting change in electric field across the electroluminescent phosphor.
- the photoconductor. stratum 18 can be made as thin as desired and in addition, extremely fast photoconductor materials can be used, since even relatively insensitive photoconductor materials when used in thin layers, have a high efiective sensitivity with respect to exciting energy.
- the electrode 12 can'be formed of light transmitting"tin oxide deposited onto a, glass supporting plate 36.
- the electroluminescent stratum 16 can comprisean electroluminescent phosphor such as zinc sulfide activated by copper and coactivated by chlorine and such phosphors are well known.
- the phosphor is embedded throughout a dielectric material ,"such as by embedding the finely-divided phosphor in equal; amount by weight of dielectric. material. withfsuch a construction thedielectric material should be light transmitting and polyvinyl-chloride acetate or h xs t al P a ti r. ssrami d sls r ma r al v well known.
- the electrode 14 can be formed of vacuum-metallized aluminum or it can be formed of copper iodide for example. If the energy which is to be amplified comprises visible light or energy which is capable of exciting the electroluminescent phosphor to visible luminescence, the electrode 14 can be formed of a material which is not transmissive to visible light or to the energy which is to be amplified.
- the electrode 14 can be formed of vacuum-metallized aluminum deposited as an opaque layer and if cathode rays are to be amplified, an additional layer of glass can also be included adjacent the electrode 14.
- the thickness oi the phosphor dielectric layer 16 is in no way critical and as an example is one mil.
- the electroluminescent phosphor can also be included between hi slss wtlss .12 and 15 th no admix or separate dielectric or the phosphor can be utilized in the form of a thin him, such thin films of phosphor being generally described in Feldman and OHara article appearing in Journal of the Optical Society of America, vol. 47, No. 4, pages 300-305 (April 1957).
- the photoconductor stratum 18 can beformed of variu m teri ls dep din p e ne y hi h i to e amplified.
- the photoconductor stratum 18 can be formed of powdered cadmium sulfide, which if desired can have admixed therewith a small amount of dielectric material such as 5% by weight.
- the admixed dielectric, if used, can be similar to the dielectric used with the phosphor, but the amount should be limited so that the stratum 18 can when excited conduct D.C. Powdered cadmium sulfide varies in resistance under irradiation by longer Wavelength visible radiations or X-rays.
- Cadmium selenide and cadmium telluride can be substituted for'the cadmium sulfide and are also similar in response.
- Powdered zinc-cadmium sulfide is not as sensitive a photoconductor as cadmium sulfide per so, but can be made broadly responsive to ditferent wavelengths by varying the zinc to cadmium ratio, as is Well known, and such a photoconductor can respond to a broad range extending from 3650 AU. to 7000 A.U., as well as to X-rays.
- Lead sulfide is sensitive to infra red radiations.
- inorganic photoconductor substances can also be evaporated as thin continuous films by means of the technique as specified hereinbefore for. preparing thin films of zinc sulfide electroluminescent phosphor. These thin films of inorganic photoconductor substances are quite sensitive and are somewhat faster in decay time than the powdered inorganic photoconductor materials. It is also possible to use organic photoconductor substances. Organic photoconductor substances are normally quite fast in response and decay, but are somewhat less sensitive than the powdered inorganic photoconductor. substances, although in the. present device this. is' not particularly"detrimental since the photoconductor stratum 18 can be made extremely thin in order to enhance the etiective sensitivity of the photoconductor material.
- anthracene photoconductor material is responsive to ultraviolet radiations to decrease in resistance and under relativelylow intensity irradiation has a decay time in the order of 0.01 second; Naphthacene is responsive toultraviolet and to visible radiations up to the yellow portion of the spectrum, which radiations cause this photoconductor to decrease in resistance. Pentacene is responsive to all visible radiations to vary in resistance and is relatively fast in decay time. In th case organic photoconductor substances are utilized, it is necessary that the positive pole of the applied D,C. po-
- the electrode '20 can be formed of copper iodide or of tin oxide formed on an additional glass support (not shown).
- a device embodiment 38 which generally corresponds to the device embodiment 10 as shown in Fig. 1 except that the electode members which bound the separate strata comprising photoconductor material 18 and electroluminescent phosphor 16 are physically separated from one another with one of the electrodes 40 bounding the photoconductor material maintained in electrical continuity with one of the electrodes 42 bounding the electroluminescent phosphor.
- An additional supporting plate glass 44 is provided adjacent the electrode 40, which can be formed of tin oxide for example.
- the electrode 42 which is electrically connected to the electrode 40 can be formed of vacuum-metallized aluminum for example.
- the device 38 can be identical to the device 10 as shown in Fig. 1. With a device of this general description, brightness amplifications of 242 and energy amplifications of 150,000 have been achieved.
- the device embodiments 10 and 38 as shown in Figs. 1 and 3 represent either an energy-amplifying device or one element of an image-amplifying device wherein a plurality of such elements are arranged in adjacentrelationship in order to present a composite image.
- An image-amplifying device 46 is represented diagrammatically in Fig. 4, wherein three individual energy-amplifying elements are positioned in adjacent relationship to act as an image amplifier.
- Each of the individual elements as shown in Fig. 4 can be constructed in accordance with either of the embodiments 10 or 38 as shown in Figs. 1 and 3.
- the electrodes which are used with each of the elements comprising the image amplifier are electrically insulated from one another and each has an area corresponding to the degree of resolution which is desired for the image-amplifying device, such as four square mils for example.
- the outermost bounding electrodes can be made continuous in nature, as will be described hereinafter, and in such construction only a small portion of each of the outermost continuous electrodes will cooperate with the very small electrode member oppositely disposed thereto, which small electrode member has an area preselected in accordance with the degree of reso-- lution desired for the device.
- FIG. is shown in perspective view a portion of an image-amplifying device 48 which comprises a plurality.
- the device 48 comprises a foundation layer 52 which can be-formed of an opaque, electrically-insulating material such asglass-bonded mica or urea formaldehyde for example, having a plurality of aligned apertures 54 laterally drilled
- the photoconductor canbe madeas thin as desired and as an example, can have therethrough.
- the thickness of the fouiidation' layer 52' is the thickness of the fouiidation' layer 52'.
- Photoconductor material 56 is retained in alternate lines of the apertures and electroluminescent phosphor 58 is retained in the remainder to said apertures.
- Each aperture containing photoconductor material 56 and an adjacent aperture containing electroluminescentv phosphor 58 forms one element 50 of the image-amplifying device 48 and the area of each of these elements 50 is preselected in accordance with the degree of resolution desired for the image-amplifying device 48.
- Each line of photoconductor-filled apertures is electrically connected at one side 6001': the foundation layer 52 by means of first conducting strips ;62 of tin oxide for example.
- Each alternate line of apertures containing eIectrolumineScentphOsphor 58 is also electrically connected by second conductingstrips -64 of tin oxide for example.
- Each of these conducting strips 62 and 64 can be formed on a. glass plate 66 and are adapted to have a DC. potential;
- the other side 68 of the foundation 52 has included thereon a plurality of small conducting segments 70 which serve to connect electrically one side of the photoconductor material 56 with one side of the electroluminescent phosphor 58 of each element 50.
- These small conducting segments 70 can be formed by vacuum-metallizing aluminum over selected portions of side 68 of the foundation layer 52.
- Each element 50 comprising the image-amplifying device 48 can be generally similar to the device embodiment 38 shown in Fig. 3.
- a contact plate 72 which is adapted to reciprocate in a rapid fashion, alternately contacts the conducting segments 70.
- contact plate 72 can be formed of metal-backed plastic such as polyethylene terephthalate having a layer 73 of conducting material such as copper affixed to the side thereof which is adapted to contact the segments 70.
- This conducting layer 7 3 is electrically connected'to the second tin oxide electrode strips 64.
- the conducting segments 70 at the same potential as the second tin oxide conducting strips 64. If the photo conductor material 56 of an element 50 has not been excited with light or other energy to be amplified, no D.C. charge will have accumulated on the conducting member 70 associated with the element. conductor portion 56 of an element 50 has been irradiated with energy to which it is sensitive, a DC. charge will have accumulated on the appropriate conducting member 70 in proportion to the amount of light or other energy which excited the photoconductor material. The resulting rapid discharge of all of the accumulated charges will cause the electroluminescent portions of the device to emit flashes of light. With a sufiiciently rapid cycling period, such as 60 cycles per second, the eye will blend the resultant flashes together to what appears to be continuous light.
- Fig. 6 an enlarged fragmentary view of one of the energy-amplifying elements '50 of the device 48 as shown inFig. 5. As shown more. clearly in this view, when the radiation which is to be amplified, such as visible light, irradiates the photoconductor substance,
- Thevibrator for the contact plate 72 can comprise any conventional electrical vibrator which actuates the plate 72 through a conventional connecting shaft 74 aflixed to the metal backing of the contact plate 72.
- the photoradiationsenergy-image. is viewed from the same face of the device.
- Such an embodiment. 76 is shown in. Fig. 7. Thisembodiment generally. corresponds to the. device. embodiment 48as showninFig. 6except that the reciprocable contact plate. 78 is. provided with a plurality of apertures 80 which are. alignedwith the electroluminescent portions 82' of each of. the energy amplifyingelements 84 which comprise. the device 76. modified. in.
- eachraised contacting mem ber 86 is..electrically connected to a transparent conducting segment 88, one eachofwhich. coversaone. side of each of the. amplifying elements 84.comp.rising .the device 76.
- the:conducting strips 90 whichare adjacent the electroluminescent portion'82 of each element 84 and through which D.C. energizingpotential is applied, not be made radiation or energy-transmitting and can be fabricated of copper strips for example.
- the device 76 .as shown in Pig. 7 corresponds to the device 48 as shown. in Figs. and 6.
- a device embodiment 92 As a further alternative device embodiment,-.the photoconductor and electroluminescent portions ofeach element comprising an imaging device can be physically separated fromone another by any desired. distance and such a device embodiment 92 is shown in Fig, 8'.
- This device embodiment comprises a first electrode 9.4 which is transmissive to the energy-amplified radiationswhich are to be presented and this. electrode can be. fabricated of tin oxide on a glasssupporting plate 96.. Over the first electrode 94 is placed a stratum 98 comprising electroluminescent phosphor, such as described hereinbefore. Over the stratum comprising electroluminescentphosphor is placed a composite electrode 100.
- the photoconductor: portions of theimaging device 92 are similar in construction to the. electroluminescent phosphor portion. of the device in that the photoconductor material stratum102 isbounded. by a continuous electrode 104 and composite electrode 106.
- the stratum 102 can be similar to those described. hereinbefore.
- the composite electrode 106 is formed as a plurality of small conducting segments eachhaving an area corresponding to the degree of resolutiondesired for the device.
- the electrode 104 can be formed of tin oxide on a glass supporting layer 108.
- Each of the small segmentscomprising the composite electrodes100 and 106 can be formed of small copper segments for example, with each small segment electrically insulated from. the segment adjacent thereto.
- The. outermost bounding electrodes 94 and 104 are adapted to. be connected across. a source of DC. potential.
- Each individual segment comprising the composite electrode. 100 is maintained in electrical continuity with an individual segment comprising the composite electrode. 106.
- a commutating means 109 which can comprise a vibrating contact plate 110, is providedintermediate the electroluminescent and photoconductor portions. of the device .92, in-order alternately and rapidly to place each segment comprisingthe composite electrode 100 at a potential level which.
- Thecontact plate110- is shown inFig. 9 andcomprises aconductingplate member-such as copper having a plurality of apertures 112 provided therethrough.
- Each of the apertures 112' contains an insulating bushing..114' and a center conducting member This embodiment. is. further 116v within the bushing 11T4.
- Spring loaded electrical contacts 118 are laterally reciprocable within electrically insulating retaining members 120positioned on either side of contact plate 110.
- Vibration of the contact plate can be accomplished'by any conventional electrical vibrating. or equivalent device.
- Theelectromechanical commutation means 109 can be replaced by an electronic commutating means if ergy-amplified radiations are viewed from the glasssup porting plate 96.
- any of the foregoing devices'as illustrated and described hereinbefore can be used to amplify. extremely weak energy or energy-images and to present suchlenergy or energy-images as amplified radiations.
- the devices can be operated so-as to accumulate energy over a relatively long period of time andito dis sipate such accumulated energy in a rapid fashionto cause the electroluminescent portions of the. devicesto produce light varyingin intensity inproportion to the magnitudeof the accumulated charges.
- the commutating mechanisms asdisclosed hereinbefore can be slowed down or dispensed :with if desired. In the case the commutating mechanismsare. dispensed with, amanual switching.
- the arrangement can be used to dissipate ina rapid'fashionany accumulated" charges on the innermostelectrode bounding the electroluminescent stratum.
- the foregoingdevices can thus be made to operate on a one-shot principle andthe resulting'energy-amplified radiations can be photographed if desired.
- the electrodes or electrode segments associatedwiththe photoconductor material need not have the same dimensions as the electrodesor electrode segments associated with the. electroluminescent phosphor.
- the presented radiation energy or energy-image can thus beexpanded or decreased considerably with respect to the-area-of the energy or energy-image to be amplified
- the electrodes or electrode segments associated with the photoconductor material can have an area which is one-tenth the area of the electrodes'or'electrode segments associated Wl'th'thB electroluminescent phosphor.
- a device for receiving energy which can be prop: agated through vacuum and presenting such received energy as energy-amplified radiation, said device comprising, a first electrode transmissive to energy-amplified radiation to bepresented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a, stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of electrode members provided on either side of said stratum comprising photoconductor material, one electrode of said pair of electrode members transmissive to energy tobe received by said device, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said first electrode and said one of said pair of electrode members adapted to be connected across a source of D.C. potential, and means for rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
- a device for receiving energy which can be propagted through vacuum and presenting such received energy as energy-amplified radiation comprising, a first electrode transmissive to energy-amplified radiation to be presented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of electrode members provided on either side of said stratum comprising photoconductor material, one electrode of said pair of electrode members transmissive to energy to be received by said device, said second electrode forming the other electrode of said pair a potential level at least approaching the potential level 't of said first electrode.
- a device for receiving energy which can be propagated through vacuum and presenting such received energy as energy-amplified radiation comprising, a first electrode transmissive to energy-amplified radiation to be presented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of additional electrode members physically separated from said first and second electrodes and provided on either side of said stratum comprising photoconductor material, one electrode of said pair of additional electrode members transmissive to energy to be received by said device, the other electrode of said pair of additional electrodemembers maintained in electrical continuity with said second electrode, said first electrode potential, and means for alternately and rapidly placing said second electrode at apotential level .at least approaching the potential level of said first electrode.
- An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum and presenting such received energy-image elemental portion as energy-amplified radiation said device elemental portion comprising, a first electrode transmissive to the energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of electrode members provided on opposite sides of said stratum comprising photoconductor material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said one electrode of said pair of electrode members and said first electrode adapted to be connected across a source of D.C. potential, and means for
- An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum and presenting such received energy-image elemental portion as energy-amplified radiation said device elemental portion comprising, a first electrodetransmissive to the energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elementalportion, a pair of electrode members provided on opposite sides of said stratum comprising photoconductor material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, said second electrode forming the other electrode of said pair of electrode members, said one electrode of said pair of electrode members and said'first electrode adapted to be connected across a source of D.C. potential, and means for alternately
- a first electrode transmissive to energy-amplified radiation to be presented a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of additional electrode members physically separated from said first and second electrodes and provided on opposite sides of said stratum comprising-photoconductor material,one electrode of said pair of additional electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, the other electrode of said pair of additional electrode members maintained in electrical continuity with said second elec- 11 trode, said one electrode of said pair of additional electrode members and said first electrode adapted to be connected across a source of DC. potential, and means l'or alternatelyand' rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
- An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum andpresenting such received energy-image elemental portion as energy-amplified radiation said device elemental portion comprising, a first electrode transmissive to energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, astratum comprisingphotoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of electrode members provided on opposite sides of said stratum comprising material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received 'by said device elemental portion, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said one electrode of said pair of electrode members and said first electrode adapted to be connected across a source of DC. potential, and electrically-actuated make-and
- An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and. presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formedof a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, material comprising electroluminescent phosphor sandwiched between said first and second elec* trodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varyinginversely with the intensity of the energy comprising energy-images to be received by said device, a pair of electrode members provided on or posite sides of said stratum comprising photoconductor material, one of said pair of electrode members transmissive to energy-images to be received by said device, the other of said pair of electrode members comprising a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to
- An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formed of a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, material comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said startum comprising photoconductor material varying inversely with the intensity of the energy comprising energy-images to be received by said device, a pair of electrode members provided-on opposite sides of said stratum comprising photoconductor material, one of said pair of electrode members transmissive to energy-images to be received by said device, said second electrode forming the other electrode of said pair of electrode members, said first electrode and said one of said pair of electrode members adapted to be connected across a source of DC.
- An image-amplifying device for receiving images comprised of energy whichcan be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formed of a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree .of resolution desired for said device, material comprising electroluminesceut phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy comprising energy-images to be received by said device, a pair of additional electrode members physically separated from said first and second electrodes and provided on opposite sides of said stratum comprising photoconductor material, one of said pair of additional electrode members transmissive to energyimages to be received by said device, the other of said pair of.
- additional electrode members comprising a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, each individual small conducting segment comprising said other of said pair of additional electrode members electrically connecting to an individual member comprising said second electrode, said first electrode and said one of said pair of additional electrode members adapted to be connected across a source of DC. potential. and means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
- An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprlsing photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying inversely with the intensity of energy comprising the energy images to be received by said device, additional sub stance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adajcent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connected-to one another on one side of said foundation layer, the photoconductor material and
- An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprising photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying inversely with the intensity of energy comprising the energy-images to be received by said device, additional substance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adjacent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energyamplifying element electrically connected to one another on one side of said foundation layer, the photoconductor material and electroluminescent phosphor comprising each said energy
- a conducting vibrator adapted to contact in a rapid and alternating fashion the one side of said foundation layer on which said photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connect to one another, and said conducting vibrator adapted to have electrical continuity with the pole of the DC. potential adapted to be applied to said electroluminescent phosphor comprising each said energy-amplifying element.
- An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprising photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying in- Wersely with the intensity of energy comprising the energyimages to be received by said device, additional substance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adjacent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connected to one another on one side of said foundation layer, the photoconductor material and electroluminescent phosphor comprising
- a conducting vibrator adapted to contact in a rapid and alternating fashion the one side of said foundation layer on which said photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connect to one another, said conducting vibrator adapted to have electrical continuity with the pole of the DC. potential adapted to be applied to said electroluminescent phosphor comprising each said energy-amplifying element, and said conducting vibrator being radiation transmitting in locations disposed adjacent to said electroluminescent phosphor of each said energy-amplitying element.
Description
Dec. 8, 1959 B. ROSENBERG I 2,916,630
ELECTROLUMINESCENT DEVICE Filed Nov. 28, 1958 2 Sheets-Sheet 1 INCIDENT ENERGY FIG.
l I V V V AMPLIFIED RADIATIONS GAP 6s 72 6 T 7O G 56 sffl2 48 ww'%\ 52 MENTOR 6 2 4M: 58 BHENET agsaggy a 6 BY 50 AA.A A W 54 f i f 4, f flW/EMEY.
Dec. 8, 1959 B. ROSENBERG ELECTROLUMINESCENT DEVICE 2 Sheets-Sheet 2 Filed NOV. 28, 1958 \O C 6 D O 6 5 2 5 R m 4 M l 7 m 5 m u I, w V 0 T 2 6 I A v 4 Q H 7 5 4 6 7 7 J m w 6 0 2 5 M 5 6 6 4 m 6 F e H OUT OUT
OUT
FIG. 8.
IN VEN TOR.
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I00 I20 "4 H0 I20 106 [O8 5/) ENETT FflJE/VBRG.
United States Patent ELECTROLUMINESCENT DEVICE Barnett Rosenberg, New Yorlr, N.Y., assign'or to Westinghouse Electric Corporation, East Pittsburgh, Pa., a corporation of Pennsylvania Application November 28, 1958, Serial'No. 776,817
' 13 Claims. (Cl. 250-213 This invention relates to electroluminescent devices and, more particularly, to energyand image-amplifying devices having fast response and a high degree of sensitivity.
Energyphotoconductor material and electroluminescent phosphor combinations are well known and are generally described in US. Patent No. 2,650,310, dated August 25, 1953. Such devices as described in the above-mentioned patent comprise a layer or stratum of photoconductor material and a separate layer or stratum of electroluminescent phosphor material, which separate layers are sandwiched together between two electrodes. When an A.C. potential is applied across the electrodes and the photoconductor material, or a portion thereof, is irradiated with some sort of external energy, such as X-rays or light for example, the electrical impedance of the photoconductor stratum decreases at that portion which is irradiated. This in turn places the alternating electric field across the electroluminescent phosphor layer per se rather than the combined phosphor-photoconductor layer, thereby causing the phosphor to emit light because of the i creased field. With such a device, the photoconductor layer can be represented as a parallel-connected resistance and capacitance. The electroluminescent layer can also be represented as a parallel-connected resistance and capacitance. Both of these parallel-connected R.C. circuits are connected in series across the source of energizing A.C. potential. When the photoconductor is not irradiated or otherwise energized, the resistances of both the photoconductor and the electroluminescent layer. are quite high. In order that most of the energizing potential is applied across the photoconductor under so-called dark conditions, the capacitance of the photoconductor must be small as compared to the capacitance of the electroluminescent portion of the device. This in turn requires that thickness of the photoconductor be made great as compared to the thickness of the electroluminescent phosphor layer. A thick photoconductor layer, however, impairs resolution and sensitivity and in addition, the most sensitive photoconductor materials are quite slow in response.
It is the general object of this invention to avoid and overcome the foregoing and other difliculties of and objections to prior-art practices by the provision of an photoconductor layers which are fast in response and are very sensitive to excitation. It is an additional object to provide'various embodiments and constructional details for and image-amplifying devices.
The aforesaid objects of the invention, and other and image-amplifying devices comprising energy-amplifying "Fee.-
' objects which will become apparent as the descriptio the electrodes bounding the separate strata can be made common if desired or four separate electrodes can be used with a direct electrical connection between two of them.. The outermost electrodes bounding the separate strata," which electrodes are not directly electrically. connected I to one another, are adapted to be connected across a source of D.C. potential. The remaining electrodeorj' electrodes are adapted to be commutated' in an alternating and rapid fashion in order alternately and rapidly to place such electrode or electrodes at a potential level which at least approaches'the potential level of the outermost uncommutated electrode which is adjacent to the electroluminescent phosphor. This allows the device to operate from D.C'. potential excitation with a storagetype' operation and capacitive elfectsfof the photoconductor stratumand electrodes associated with same are minimized. The result is that the device can be made extremely sensitive with respectto amplifying energy and energy-images and fast-response photoconductor materials can be used in very thin layers if desired.
For a better understanding of the invention reference should be hadto the accompanying drawings wherein;
Fig. 1 is a sectional elevation of an energy-amplifying device with the commutator means therefor shown in per: spective view;
Fig. 2 is a diagrammatic representationof the embodi ment as shown in Fig. 1; p v
Fig. 3 is analternative'embodimentfof the device as shown in Fig. 1 Wherein 'the' phosphor and photoconductor strata are formed with an appreciable spacing therebetween;
Fig. 4 isa diagrammatic representation of a multielement device which can operatev as an image amplifier;
Fig. 5 is a fragmentary, enlarged perspective view," partly in section, of one embodiment ofan image-a rfv plifying device; 7
Fig.- 6 is' a fragmentary sectionalyenlargement, ofja portion of the device as shown, in Fig. 5, further illustratingconstrnctional details therefor; I Fig. 7 "s a fragmentary, enlargedperspective view, shown partly in section, illustrating an .alternative embodiment of the device as, shown in Figs. Sand 6;,
Fig. 8 is an alternative embodiment of an image-a'm-l plifying device wherein the photoconductor'andelectroluminescent phosphor strata. are considerably spacedfrom one another, with a commutating mechanism interposed therebetween;
Fig. 6 is a fragmentary front elevation of the contact plate used to commutate the individual amplifying elementscomprising the device as shown in-Fig. 8.
With specific reference to the form of the invention shown in the drawings, the numeral 10 in Fig. 1 illustrates anenergy-amplifying device which can also be" used as one element of an image-amplifying device. The device 10 generally comprises a first electrode 12 which is transmissive to the energy-amplified radiation to be presented by the device, a second electrode 14 and the "electrode 14 which also acts 'to energize the stratum 16 comprising electroluminescent phosphor. An additiqual electrode 12!) is placed on the other side of the stratum 1 read this slashed; 2. is t ans s to the energy which is to be received by the device 10. The area of each of the electrodes can vary considerably. In h s 9 2 SiRlPrPQi ener -a p tude deviee. sh slashed? an ha ne o om o e sg are inch t bnesqasrs t f r example 5 th sas of a ima e.- am plify'ii g device, the effective area of the electrodes will usually be made considerably smaller. A 13.0. liQ sflt t l ur e 2 is connected o the ele t ode 1. nd by means of lead conductors 24 and 26 respectively. A W i e m t o 8 el ctr c l y con e between the electrodes 12 and 14 in order alternately an ra d t Pl e electr de 4 a a Poten ia e e w it r least ap ss s th p stlt l e el or he qls t sd 2- T ommuta 2!? ssrn riss a me estab e. dru 0. ca ryin the e n 2 3 i ul tin see titan 3'2- s he b ush 41s n ire ee ta t ith t e nduc in t i drum .9 an 1. p t n which a utn at tl 9 the e se rede 15 s r pidly di a slh D-C- squ j .22. ca deliver a pot ntial of '100 yolts for example.
. The d v e 1 s s o n F 1 can b sou ri st d to amplify any energy which can be propagated through vacuum such as X-rays, ultraviolet radiations, visible, light, infrared radiations or cathode rays. This energy is" converted intoenergy-amplified radiations, which will normally take the form of visible light. A diagrammatic representation of the device illustrated in Fig, 'l is shown in Fig. 2 The photoconductor stratum 18 is represented as s i ns ich is uit h wh n he ho o onductor stratum is not energized and which varies inversely with the intensity of the energy to be received by the device 10.' In other words, the stronger the exciting energy signal, he lower the resistance or" the photoconductor stratum 18 A lowered resistance of the photo- Conductor stratum 18 allows one side of the capacitor formed bythe electroluminescent stratum 16 and the bounding electrodes 12 and 14 to charge, with the rate of charging being determined by the intensity of the re; ceived energy. After a predetermined period, which can be second for example, the commutator 2,8 has rotated sufficiently to place the electrode 14 at substantially the same potential level as the electrode 12. This sudden dissipation of charge causes the electroluminescent cell which is formed by the electrodes 12 and 14- and theiph'osphor stratum 16 to emit a sudden flash of light, the intensity of which varies with the amount of charge dissipated. The device thus operates on the Priuciple that a D.C charge is accumulated and then is"suddenly, discharged and the resulting change in electric field across the electroluminescent phosphor. causes sameto"er'nit'light.' Since the capacitive eitects of the Dh P' QttClQJCtQIT'. and its bounding electrodes are minimizedfbythis arrangement, the photoconductor. stratum 18 can be made as thin as desired and in addition, extremely fast photoconductor materials can be used, since even relatively insensitive photoconductor materials when used in thin layers, have a high efiective sensitivity with respect to exciting energy.
As a specific example, the electrode 12 can'be formed of light transmitting"tin oxide deposited onto a, glass supporting plate 36. The electroluminescent stratum 16 can comprisean electroluminescent phosphor such as zinc sulfide activated by copper and coactivated by chlorine and such phosphors are well known. Desirably the phosphor is embedded throughout a dielectric material ,"such as by embedding the finely-divided phosphor in equal; amount by weight of dielectric. material. withfsuch a construction thedielectric material should be light transmitting and polyvinyl-chloride acetate or h xs t al P a ti r. ssrami d sls r ma r al v well known. If desired anadditional qf'di. t ip. anbe. nc d sf s i. hefe e ga d ft'q s a a e. vers. of mount in dielectric material can be included between the electrodes 12 and 14. Such constructions are conventional in the electroluminescent art. The electrode 14 can be formed of vacuum-metallized aluminum or it can be formed of copper iodide for example. If the energy which is to be amplified comprises visible light or energy which is capable of exciting the electroluminescent phosphor to visible luminescence, the electrode 14 can be formed of a material which is not transmissive to visible light or to the energy which is to be amplified. As an example, ii ultraviolet .or visible radiations are to be amplified, the electrode 14 can be formed of vacuum-metallized aluminum deposited as an opaque layer and if cathode rays are to be amplified, an additional layer of glass can also be included adjacent the electrode 14. The thickness oi the phosphor dielectric layer 16 is in no way critical and as an example is one mil. The electroluminescent phosphor can also be included between hi slss wtlss .12 and 15 th no admix or separate dielectric or the phosphor can be utilized in the form of a thin him, such thin films of phosphor being generally described in Feldman and OHara article appearing in Journal of the Optical Society of America, vol. 47, No. 4, pages 300-305 (April 1957).
The photoconductor stratum 18 can beformed of variu m teri ls dep din p e ne y hi h i to e amplified. As an example, the photoconductor stratum 18 can be formed of powdered cadmium sulfide, which if desired can have admixed therewith a small amount of dielectric material such as 5% by weight. The admixed dielectric, if used, can be similar to the dielectric used with the phosphor, but the amount should be limited so that the stratum 18 can when excited conduct D.C. Powdered cadmium sulfide varies in resistance under irradiation by longer Wavelength visible radiations or X-rays. Cadmium selenide and cadmium telluride can be substituted for'the cadmium sulfide and are also similar in response. Powdered zinc-cadmium sulfide is not as sensitive a photoconductor as cadmium sulfide per so, but can be made broadly responsive to ditferent wavelengths by varying the zinc to cadmium ratio, as is Well known, and such a photoconductor can respond to a broad range extending from 3650 AU. to 7000 A.U., as well as to X-rays. Lead sulfide is sensitive to infra red radiations. The foregoing inorganic photoconductor substances can also be evaporated as thin continuous films by means of the technique as specified hereinbefore for. preparing thin films of zinc sulfide electroluminescent phosphor. These thin films of inorganic photoconductor substances are quite sensitive and are somewhat faster in decay time than the powdered inorganic photoconductor materials. It is also possible to use organic photoconductor substances. Organic photoconductor substances are normally quite fast in response and decay, but are somewhat less sensitive than the powdered inorganic photoconductor. substances, although in the. present device this. is' not particularly"detrimental since the photoconductor stratum 18 can be made extremely thin in order to enhance the etiective sensitivity of the photoconductor material. As an example, anthracene photoconductor material is responsive to ultraviolet radiations to decrease in resistance and under relativelylow intensity irradiation has a decay time in the order of 0.01 second; Naphthacene is responsive toultraviolet and to visible radiations up to the yellow portion of the spectrum, which radiations cause this photoconductor to decrease in resistance. Pentacene is responsive to all visible radiations to vary in resistance and is relatively fast in decay time. In th case organic photoconductor substances are utilized, it is necessary that the positive pole of the applied D,C. po-
tential is connected to the electrode which isadjacent the surface oi the photoconductor material which is adaptcase of inorganic photoconductoh substances, it does not usually matter which pole of the applied DC potential is connected to the electrode layer adjacent to the photostance need not have a great thickness as compared to the electroluminescent phosphor stratum, as in prior art energyand image-amplifying devices. This is because the photoconductor substance acts primarily as a valve in order to accummulate a DC. potential on an electrode which is adjacent to the stratum comprising ele ctroluminescent phosphor.
a thickness of ten microns. This thickness can be varied considerably. The electrode '20 can be formed of copper iodide or of tin oxide formed on an additional glass support (not shown). Q
In Fig. 3 is shown a device embodiment 38 which generally corresponds to the device embodiment 10 as shown in Fig. 1 except that the electode members which bound the separate strata comprising photoconductor material 18 and electroluminescent phosphor 16 are physically separated from one another with one of the electrodes 40 bounding the photoconductor material maintained in electrical continuity with one of the electrodes 42 bounding the electroluminescent phosphor. An additional supporting plate glass 44 is provided adjacent the electrode 40, which can be formed of tin oxide for example. The electrode 42 which is electrically connected to the electrode 40 can be formed of vacuum-metallized aluminum for example. Other than these indicated differences, the device 38 can be identical to the device 10 as shown in Fig. 1. With a device of this general description, brightness amplifications of 242 and energy amplifications of 150,000 have been achieved.
The device embodiments 10 and 38 as shown in Figs. 1 and 3 represent either an energy-amplifying device or one element of an image-amplifying device wherein a plurality of such elements are arranged in adjacentrelationship in order to present a composite image. An image-amplifying device 46 is represented diagrammatically in Fig. 4, wherein three individual energy-amplifying elements are positioned in adjacent relationship to act as an image amplifier. Each of the individual elements as shown in Fig. 4 can be constructed in accordance with either of the embodiments 10 or 38 as shown in Figs. 1 and 3. In the device embodiment 46, the electrodes which are used with each of the elements comprising the image amplifier are electrically insulated from one another and each has an area corresponding to the degree of resolution which is desired for the image-amplifying device, such as four square mils for example. In some cases, the outermost bounding electrodes can be made continuous in nature, as will be described hereinafter, and in such construction only a small portion of each of the outermost continuous electrodes will cooperate with the very small electrode member oppositely disposed thereto, which small electrode member has an area preselected in accordance with the degree of reso-- lution desired for the device.
In Fig. is shown in perspective view a portion of an image-amplifying device 48 which comprises a plurality.
of individual energy-amplifying elements 50. The device 48 comprises a foundation layer 52 which can be-formed of an opaque, electrically-insulating material such asglass-bonded mica or urea formaldehyde for example, having a plurality of aligned apertures 54 laterally drilled Thus the photoconductor canbe madeas thin as desired and as an example, can have therethrough. The thickness of the fouiidation' layer 52'.
can vary considerably and as an example is 1-2 mils. Photoconductor material 56 is retained in alternate lines of the apertures and electroluminescent phosphor 58 is retained in the remainder to said apertures. Each aperture containing photoconductor material 56 and an adjacent aperture containing electroluminescentv phosphor 58 forms one element 50 of the image-amplifying device 48 and the area of each of these elements 50 is preselected in accordance with the degree of resolution desired for the image-amplifying device 48. Each line of photoconductor-filled apertures is electrically connected at one side 6001': the foundation layer 52 by means of first conducting strips ;62 of tin oxide for example. Each alternate line of apertures containing eIectrolumineScentphOsphor 58 is also electrically connected by second conductingstrips -64 of tin oxide for example. Each of these conducting strips 62 and 64 can be formed on a. glass plate 66 and are adapted to have a DC. potential;
applied thereacross. The other side 68 of the foundation 52.has included thereon a plurality of small conducting segments 70which serve to connect electrically one side of the photoconductor material 56 with one side of the electroluminescent phosphor 58 of each element 50. These small conducting segments 70 can be formed by vacuum-metallizing aluminum over selected portions of side 68 of the foundation layer 52. Each element 50 comprising the image-amplifying device 48 can be generally similar to the device embodiment 38 shown in Fig. 3. For purposes of commutation, a contact plate 72, which is adapted to reciprocate in a rapid fashion, alternately contacts the conducting segments 70. contact plate 72 can be formed of metal-backed plastic such as polyethylene terephthalate having a layer 73 of conducting material such as copper affixed to the side thereof which is adapted to contact the segments 70. This conducting layer 7 3 is electrically connected'to the second tin oxide electrode strips 64. When the contact plate 72 is vibrated in a rapid manner to contact the conductingv segments 70, this has the effect of placing.
the conducting segments 70 at the same potential as the second tin oxide conducting strips 64. If the photo conductor material 56 of an element 50 has not been excited with light or other energy to be amplified, no D.C. charge will have accumulated on the conducting member 70 associated with the element. conductor portion 56 of an element 50 has been irradiated with energy to which it is sensitive, a DC. charge will have accumulated on the appropriate conducting member 70 in proportion to the amount of light or other energy which excited the photoconductor material. The resulting rapid discharge of all of the accumulated charges will cause the electroluminescent portions of the device to emit flashes of light. With a sufiiciently rapid cycling period, such as 60 cycles per second, the eye will blend the resultant flashes together to what appears to be continuous light.
In Fig. 6 is shown an enlarged fragmentary view of one of the energy-amplifying elements '50 of the device 48 as shown inFig. 5. As shown more. clearly in this view, when the radiation which is to be amplified, such as visible light, irradiates the photoconductor substance,
such flash varying in intensity with the magnitude of the accumulated charge which is dissipated, Thevibrator for the contact plate 72 can comprise any conventional electrical vibrator which actuates the plate 72 through a conventional connecting shaft 74 aflixed to the metal backing of the contact plate 72.
In the embodiment as shown in Figs. 5 and 6, the
The
If the photoradiationsenergy-image. is viewed from the same face of the device. For some purposes, it is desirable to present thev amplified radiationrenergy-image on the face of the device whichis opposite. to theface of. the device which is adapted to receive the energy which is to be amplified! Such an embodiment. 76 is shown in. Fig. 7. Thisembodiment generally. corresponds to the. device. embodiment 48as showninFig. 6except that the reciprocable contact plate. 78 is. provided with a plurality of apertures 80 which are. alignedwith the electroluminescent portions 82' of each of. the energy amplifyingelements 84 which comprise. the device 76. modified. in. that .a raised contactingmember 86 isprovided tocontact electrically the.contact plate 78" at the lower extreme of. its throw. Eachraised contacting mem ber 86 is..electrically connected to a transparent conducting segment 88, one eachofwhich. coversaone. side of each of the. amplifying elements 84.comp.rising .the device 76. In addition, the:conducting strips 90, whichare adjacent the electroluminescent portion'82 of each element 84 and through which D.C. energizingpotential is applied, not be made radiation or energy-transmitting and can be fabricated of copper strips for example. Other than these indicated differences, the device 76 .as shown in Pig. 7 corresponds to the device 48 as shown. in Figs. and 6.
As a further alternative device embodiment,-.the photoconductor and electroluminescent portions ofeach element comprising an imaging device can be physically separated fromone another by any desired. distance and such a device embodiment 92 is shown in Fig, 8'. This device embodiment comprises a first electrode 9.4 which is transmissive to the energy-amplified radiationswhich are to be presented and this. electrode can be. fabricated of tin oxide on a glasssupporting plate 96.. Over the first electrode 94 is placed a stratum 98 comprising electroluminescent phosphor, such as described hereinbefore. Over the stratum comprising electroluminescentphosphor is placed a composite electrode 100. comprising-a plurality of small electrode segments, each of-which has an area corresponding to the degree of resolutiondesired for they imaging device. The photoconductor: portions of theimaging device 92 are similar in construction to the. electroluminescent phosphor portion. of the device in that the photoconductor material stratum102 isbounded. by a continuous electrode 104 and composite electrode 106. The stratum 102 can be similar to those described. hereinbefore. As in the case of the composite electrode. 100, the composite electrode 106 is formed as a plurality of small conducting segments eachhaving an area corresponding to the degree of resolutiondesired for the device. The electrode 104 can be formed of tin oxide on a glass supporting layer 108. Each of the small segmentscomprising the composite electrodes100 and 106 can be formed of small copper segments for example, with each small segment electrically insulated from. the segment adjacent thereto. The. outermost bounding electrodes 94 and 104 are adapted to. be connected across. a source of DC. potential. Each individual segment comprising the composite electrode. 100 is maintained in electrical continuity with an individual segment comprising the composite electrode. 106. In addition a commutating means 109, which can comprise a vibrating contact plate 110, is providedintermediate the electroluminescent and photoconductor portions. of the device .92, in-order alternately and rapidly to place each segment comprisingthe composite electrode 100 at a potential level which. at least approaches the potential leveloftheelectrode v94 Thecontact plate110-is shown inFig. 9 andcomprises aconductingplate member-such as copper having a plurality of apertures 112 provided therethrough. Each of the apertures 112' contains an insulating bushing..114' and a center conducting member This embodiment. is. further 116v within the bushing 11T4. Spring loaded electrical contacts 118are laterally reciprocable within electrically insulating retaining members 120positioned on either side of contact plate 110. In the operation of the commutating means 109, whenthe plate 110 is not actuated, one of each of the segments comprising the composite electrode106.will'bemaintained in electrical continuity with-one ofeach of the segments comprising the composite electrode through the center conducting members 116"in" contactplate 110. When the contact plate 'is vibrated from the position as illustrated in Fig. 8, the spring-loaded electrical contacts 118' will be placed in direct electrical contact with the body of the contact plate 110,- which in turn is electrically connected to theelectrode 94. This will place each of the small segments comprising the composite electrodes 100 and 106 at a potential level which is substantially the-same as the potential level of "the first electrode 94. Vibration of the contact plate can be accomplished'by any conventional electrical vibrating. or equivalent device. Theelectromechanical commutation means 109 can be replaced by an electronic commutating means if ergy-amplified radiations are viewed from the glasssup porting plate 96.
In any of. the image-amplifying device embodiments as illustrated and described hereinbefore, excellent resolution can .be obtained. by virtue of thevery thin photoconductor. layers which can be'utilized: In" addition, extremely fast photoconductor substances ican'be utilized while stillobtaining ahigh degree of effective sensitivity, since even relatively-insensitive photoconductor materials display, ahigh effective sensitivity when used1in= very-thin layers.
Any of the foregoing devices'as illustrated and described hereinbefore can be used to amplify. extremely weak energy or energy-images and to present suchlenergy or energy-images as amplified radiations. For such a use, the devices can be operated so-as to accumulate energy over a relatively long period of time andito dis sipate such accumulated energy in a rapid fashionto cause the electroluminescent portions of the. devicesto produce light varyingin intensity inproportion to the magnitudeof the accumulated charges. For suchoperation, the commutating mechanisms asdisclosed hereinbefore can be slowed down or dispensed :with if desired. In the case the commutating mechanismsare. dispensed with, amanual switching. arrangement can be used to dissipate ina rapid'fashionany accumulated" charges on the innermostelectrode bounding the electroluminescent stratum. The foregoingdevices can thus be made to operate on a one-shot principle andthe resulting'energy-amplified radiations can be photographed if desired. In addition, in any of the foregoing device embodiments, the electrodes or electrode segments associatedwiththe photoconductor material need not have the same dimensions as the electrodesor electrode segments associated with the. electroluminescent phosphor. The presented radiation energy or energy-image can thus beexpanded or decreased considerably with respect to the-area-of the energy or energy-image to be amplified As -an.ex ample, the electrodes or electrode segments associated with the photoconductor material can have an area which is one-tenth the area of the electrodes'or'electrode segments associated Wl'th'thB electroluminescent phosphor.
It will'be recognized that the objects of the invention have been achieved by providing energy-amplifying andimage-amplifying devices which are extremely sensitive and which can be made to operate with good resolution. In addition, there have been provided energyand image-amplifying devices which can utilize comparatively thin photoconductor materials which are very fast in response and are very sensitive to excitation. There have also been provided various embodiments and constructional details for energy-amplifying and imageamplifying devices.
While various embodiments have been illustrated and described hereinbefore, it is to be particularly understood that the invention is not limited thereto or thereby.
I claim:
1. A device for receiving energy which can be prop: agated through vacuum and presenting such received energy as energy-amplified radiation, said device comprising, a first electrode transmissive to energy-amplified radiation to bepresented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a, stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of electrode members provided on either side of said stratum comprising photoconductor material, one electrode of said pair of electrode members transmissive to energy tobe received by said device, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said first electrode and said one of said pair of electrode members adapted to be connected across a source of D.C. potential, and means for rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
2. A device for receiving energy which can be propagted through vacuum and presenting such received energy as energy-amplified radiation, said device comprising, a first electrode transmissive to energy-amplified radiation to be presented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of electrode members provided on either side of said stratum comprising photoconductor material, one electrode of said pair of electrode members transmissive to energy to be received by said device, said second electrode forming the other electrode of said pair a potential level at least approaching the potential level 't of said first electrode.
3. A device for receiving energy which can be propagated through vacuum and presenting such received energy as energy-amplified radiation, said device comprising, a first electrode transmissive to energy-amplified radiation to be presented by said device, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of energy to be received by said device, a pair of additional electrode members physically separated from said first and second electrodes and provided on either side of said stratum comprising photoconductor material, one electrode of said pair of additional electrode members transmissive to energy to be received by said device, the other electrode of said pair of additional electrodemembers maintained in electrical continuity with said second electrode, said first electrode potential, and means for alternately and rapidly placing said second electrode at apotential level .at least approaching the potential level of said first electrode.
4. An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum and presenting such received energy-image elemental portion as energy-amplified radiation, said device elemental portion comprising, a first electrode transmissive to the energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of electrode members provided on opposite sides of said stratum comprising photoconductor material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said one electrode of said pair of electrode members and said first electrode adapted to be connected across a source of D.C. potential, and means for. rapidly placing said second electrode at a potential level at least approaching the potential level of said first'electrode.
5. An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum and presenting such received energy-image elemental portion as energy-amplified radiation, said device elemental portion comprising, a first electrodetransmissive to the energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elementalportion, a pair of electrode members provided on opposite sides of said stratum comprising photoconductor material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, said second electrode forming the other electrode of said pair of electrode members, said one electrode of said pair of electrode members and said'first electrode adapted to be connected across a source of D.C. potential, and means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
6. An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be'propagated'through vacuum and presenting such received energy-image elemental portion as energy-amplified radiation, said device elemental portion comprisand said one of said pair of additional electrode mem- 'bers adapted to be connected across a source of D.C.
ing, a first electrode transmissive to energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of additional electrode members physically separated from said first and second electrodes and provided on opposite sides of said stratum comprising-photoconductor material,one electrode of said pair of additional electrode members adapted to receive incident thereon and transmissive to the energy to be received by said device elemental portion, the other electrode of said pair of additional electrode members maintained in electrical continuity with said second elec- 11 trode, said one electrode of said pair of additional electrode members and said first electrode adapted to be connected across a source of DC. potential, and means l'or alternatelyand' rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
7. An elemental portion of a device for receiving an elemental portion of an image comprised of energy which can be propagated through vacuum andpresenting such received energy-image elemental portion as energy-amplified radiation, said device elemental portion comprising, a first electrode transmissive to energy-amplified radiation to be presented, a second electrode, a stratum comprising electroluminescent phosphor sandwiched between said first and second electrodes, astratum comprisingphotoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy to be received by said device elemental portion, a pair of electrode members provided on opposite sides of said stratum comprising material, one electrode of said pair of electrode members adapted to receive incident thereon and transmissive to the energy to be received 'by said device elemental portion, the other electrode of said pair of electrode members maintained in electrical continuity with said second electrode, said one electrode of said pair of electrode members and said first electrode adapted to be connected across a source of DC. potential, and electrically-actuated make-and-brea'k means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
8. An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and. presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formedof a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, material comprising electroluminescent phosphor sandwiched between said first and second elec* trodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varyinginversely with the intensity of the energy comprising energy-images to be received by said device, a pair of electrode members provided on or posite sides of said stratum comprising photoconductor material, one of said pair of electrode members transmissive to energy-images to be received by said device, the other of said pair of electrode members comprising a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, each individual small conducting segment comprising said other of said pair of electrode members electrically connecting to an individual segment comprising said second electrode, said first electrode and said one of said pair of electrode members adapted to be connected across a source of DC. potential, and means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
9. An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formed of a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, material comprising electroluminescent phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said startum comprising photoconductor material varying inversely with the intensity of the energy comprising energy-images to be received by said device, a pair of electrode members provided-on opposite sides of said stratum comprising photoconductor material, one of said pair of electrode members transmissive to energy-images to be received by said device, said second electrode forming the other electrode of said pair of electrode members, said first electrode and said one of said pair of electrode members adapted to be connected across a source of DC. potential, and means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
10. An image-amplifying device for receiving images comprised of energy whichcan be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a first electrode transmissive to amplified radiation images to be presented, a second electrode formed of a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree .of resolution desired for said device, material comprising electroluminesceut phosphor sandwiched between said first and second electrodes, a stratum comprising photoconductor material, the electrical resistance of said stratum comprising photoconductor material varying inversely with the intensity of the energy comprising energy-images to be received by said device, a pair of additional electrode members physically separated from said first and second electrodes and provided on opposite sides of said stratum comprising photoconductor material, one of said pair of additional electrode members transmissive to energyimages to be received by said device, the other of said pair of. additional electrode members comprising a plurality of individual small conducting segments electrically insulated from one another and each having an area corresponding to the degree of resolution desired for said device, each individual small conducting segment comprising said other of said pair of additional electrode members electrically connecting to an individual member comprising said second electrode, said first electrode and said one of said pair of additional electrode members adapted to be connected across a source of DC. potential. and means for alternately and rapidly placing said second electrode at a potential level at least approaching the potential level of said first electrode.
1.1. An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprlsing photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying inversely with the intensity of energy comprising the energy images to be received by said device, additional sub stance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adajcent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connected-to one another on one side of said foundation layer, the photoconductor material and electroluminescent phosphor comprising each said energyamplifying element adapted to have a DC. potential 13 applied thereacross at the other side of said foundation layer, and means -for efiecting in a rapid manner a substantially equipotential condition across said electroluminescent phosphor of each said energy-amplifying element.
12. An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprising photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying inversely with the intensity of energy comprising the energy-images to be received by said device, additional substance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adjacent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energyamplifying element electrically connected to one another on one side of said foundation layer, the photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element adapted to have a DC. potential applied thereacross at the other side of said foundation, a conducting vibrator adapted to contact in a rapid and alternating fashion the one side of said foundation layer on which said photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connect to one another, and said conducting vibrator adapted to have electrical continuity with the pole of the DC. potential adapted to be applied to said electroluminescent phosphor comprising each said energy-amplifying element.
13. An image-amplifying device for receiving images comprised of energy which can be propagated through vacuum and presenting amplified radiation images which correspond to such received energy-images, which device comprises, a foundation layer comprising opaque electrical-insulating material, a plurality of apertures laterally disposed through said foundation layer, substance comprising photoconductor material retained in the portion of said apertures which are alternately disposed with respect to one another, the electrical resistance of said substance comprising photoconductor material varying in- Wersely with the intensity of energy comprising the energyimages to be received by said device, additional substance comprising electroluminescent phosphor retained in the remainder of said apertures, an energy-amplifying element formed by each said aperture containing photoconductor material and one of said apertures positioned adjacent thereto and containing electroluminescent phosphor, the photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connected to one another on one side of said foundation layer, the photoconductor material and electroluminescent phosphor comprising each said energy-ampli- 'fying element adapted to have a DC. potential applied thereacross at the other side of said foundation, a conducting vibrator adapted to contact in a rapid and alternating fashion the one side of said foundation layer on which said photoconductor material and electroluminescent phosphor comprising each said energy-amplifying element electrically connect to one another, said conducting vibrator adapted to have electrical continuity with the pole of the DC. potential adapted to be applied to said electroluminescent phosphor comprising each said energy-amplifying element, and said conducting vibrator being radiation transmitting in locations disposed adjacent to said electroluminescent phosphor of each said energy-amplitying element.
References Cited in the file of this patent UNITED STATES PATENTS 2,566,349 Mager Sept. 4, 1951 2,650,310 White Aug. 25, 1953 2,839,690 Kazan June 17, 1958 2,873,380 Kazan Feb. 10, 1959
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Application Number | Priority Date | Filing Date | Title |
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US776817A US2916630A (en) | 1958-11-28 | 1958-11-28 | Electroluminescent device |
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Application Number | Priority Date | Filing Date | Title |
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US776817A US2916630A (en) | 1958-11-28 | 1958-11-28 | Electroluminescent device |
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US2916630A true US2916630A (en) | 1959-12-08 |
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US776817A Expired - Lifetime US2916630A (en) | 1958-11-28 | 1958-11-28 | Electroluminescent device |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3019345A (en) * | 1959-12-03 | 1962-01-30 | Lockheed Aircraft Corp | Radiation amplifier |
US3064133A (en) * | 1959-12-01 | 1962-11-13 | Rca Corp | Layer type storage light amplifier |
US3135866A (en) * | 1961-08-29 | 1964-06-02 | Joseph T Mcnaney | Photoelectric storage devices using jacketed light fibers |
US3217168A (en) * | 1960-12-29 | 1965-11-09 | Philips Corp | Photosensitive solid-state image intensifier |
US3312825A (en) * | 1962-12-26 | 1967-04-04 | Cornell Aeronautical Labor Inc | Panel using intrinsic or carrier-injection electroluminescence usable in an image converter |
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US2566349A (en) * | 1950-01-28 | 1951-09-04 | Sylvania Electric Prod | Electroluminescent lamp |
US2650310A (en) * | 1952-10-10 | 1953-08-25 | Gen Electric | X-ray image intensification and method |
US2839690A (en) * | 1955-11-17 | 1958-06-17 | Rca Corp | Circuit for energizing light amplifier devices |
US2873380A (en) * | 1952-10-20 | 1959-02-10 | Rca Corp | Electroluminescent device |
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Patent Citations (4)
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US2566349A (en) * | 1950-01-28 | 1951-09-04 | Sylvania Electric Prod | Electroluminescent lamp |
US2650310A (en) * | 1952-10-10 | 1953-08-25 | Gen Electric | X-ray image intensification and method |
US2873380A (en) * | 1952-10-20 | 1959-02-10 | Rca Corp | Electroluminescent device |
US2839690A (en) * | 1955-11-17 | 1958-06-17 | Rca Corp | Circuit for energizing light amplifier devices |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3064133A (en) * | 1959-12-01 | 1962-11-13 | Rca Corp | Layer type storage light amplifier |
US3019345A (en) * | 1959-12-03 | 1962-01-30 | Lockheed Aircraft Corp | Radiation amplifier |
US3217168A (en) * | 1960-12-29 | 1965-11-09 | Philips Corp | Photosensitive solid-state image intensifier |
US3135866A (en) * | 1961-08-29 | 1964-06-02 | Joseph T Mcnaney | Photoelectric storage devices using jacketed light fibers |
US3312825A (en) * | 1962-12-26 | 1967-04-04 | Cornell Aeronautical Labor Inc | Panel using intrinsic or carrier-injection electroluminescence usable in an image converter |
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