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United States Patent [19] [ii] Patent Number: 5,076,673

Lynam et al. [45] Date of Patent: Dec. 31, 1991

[54] PROLONGED COLORATION

ELECTROCHROM1C ASSEMBLY

[75] Inventors: Nial) R. Lynam, Holland; Kenneth L.

Schierbeek, Zeeland, both of Mich.

[73] Assignee: Donnelly Corporation, Holland, Mich.

[21] Appl. No.: 565,660

[22] Filed: Aug. 10, 1990

[51] Int. CI.' G02F 1/01

[52] U.S. CI 359/271; 359/275;

359/265

[58] Field of Search 350/357, 355

[56] References Cited

U.S. PATENT DOCUMENTS

2,632,045 4/1953 Sziklai 178/5.4

3,280,701 10/1966 Donnelly et al 88/77

3,453,038 7/1969 Kissa et al 358/160

4,135,790 1/1979 Takahashi et al 350/357

4,294,518 10/1981 O'Connor et al 350/357

4,436,378 3/1984 Kirkman 350/357

4,573,768 3/1986 Polak et al 350/357

4,618,218 10/1986 Shaw et al 350/355

4,787,717 11/1988 Heinz geb Belgardt et al. ... 350/357

4,958,917 9/1990 Hashimoto et al 350/357

4,960,323 10/1990 Demiryont 350/357

4,983,957 1/1991 Ishikawa et al 350/357

FOREIGN PATENT DOCUMENTS

240226 3/1987 European Pal. Off. .
285724 12/1987 European Pat. Off. .

OTHER PUBLICATIONS

"Electrochromism of Organic Compounds II. Spectral and Electrochemical Examination of a System based on Methyl viologen and 5,10-Dihydro-5,10-Dimethyl

[blocks in formation]

An electrochromic assembly useful for rearview mirrors, windows, vehicle sunroofs, information displays, office partitions and other structures which allows prolonged coloration substantially indefinitely without voltage or concentration gradient induced color segregation. The assembly includes a pair of optically aligned, electrochromic devices defined by at least one transparent sheet, first and second layers of electrochromic material adjacent opposing surfaces of the sheet, the transmittance of said layers being variable when an electrical field is applied, and electrical conductors for applying such an electrical field. Electrical energy is switched alternately from one device to the other for short periods of time while the remaining device is alternately bleached. The switching can continue cyclically for any desired period. A reflective coating may be included to allow operation as a dimming mirror. Anti-reflection and index of refraction matching coatings may be included to enhance transmission. Electrical energy may also be applied to both devices simultaneously to provide a deeper level of coloration than is possible from either device alone.

51 Claims, 7 Drawing Sheets

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