WO2009036458A1

WO2009036458A1 - Integration of an integrated gasification combined cycle power plant and coal to liquid facility

Info

Publication number: WO2009036458A1
Application number: PCT/US2008/076452
Authority: WO
Inventors: Joseph A. Regnery; Richard O. Sheppard
Original assignee: Rentech, Inc.
Priority date: 2007-09-14
Filing date: 2008-09-15
Publication date: 2009-03-19
Also published as: CA2699510A1; US8105403B2; ZA201002125B; EP2197984A4; EP2197984A1; US20090090057A1; AU2008298514A1; CN101842466A

Abstract

A novel method of combing the CTL fuel plant and IGCC electrical plant by sharing the systems of coal intake, coal preparation, gas separation, and water units is described herein. This configuration allows for the combined facility to offer advantages in efficiencies of production, operational flexibility, scalability, and reliability by a multi-path integration of the processing units.

Description

INTEGRATION OF AN INTEGRATED GASIFICATION COMBINED CYCLE POWER PLANT AND COAL TO LIQUID FACILITY

[0001] This application claims the benefit under 35 U.S. C. § 119(e) of U.S. Provisional Patent Application No. 60/972,450, filed September 14, 2007, and Application No. 60/972,522, filed September 14, 2007, the disclosures of which are incorporated herein by reference in their entirety for all purposes.

BACKGROUND Field of the Invention

[0002] This invention relates generally to the field of clean coal energy production. More specifically, the invention relates to a method of combining two clean coal processes into a single facility.

Backfiround of the Invention

[0003] Natural gas, coal deposits, and biomass are abundant energy sources that often serve as fuel for power generation. The United States has significant known reserves of coal, and coal currently burned for power generation represents only a fraction of the total deposits that are available. This coal used for power satisfies approximately one-half of the electrical energy demand of the United States. Current and tightening emissions regulations limit the amount of sulfur, oxides of nitrogen, and greenhouse gas emissions, making coals high in these materials less favorable for electricity generation. Failure to comply with these regulations results in hefty penalties in the form of fines, shutdowns, and limited operations. Further, upgrading of current coal burning electric generation plants requires substantial investment. With increased awareness of environmental issues such as global warming, and greenhouse gases, this trend is predicted to continue, potentially making coal-burning plants unfavorable and expensive to operate. [0004] Rising worldwide oil demand has increased the cost of oil distillates and encouraged development of alternative clean power facilities. One such power production facility is the Integrated Gasification Combined Cycle (IGCC) plant. Electricity is produced from the combustion of a synthesis gas (syngas) produced by the gasification of coal. Gasification is a method of reacting coal with limited oxygen at high temperatures for the production of synthesis gas. The process of gasification removes potential pollutants such as mercury, arsenic, nitrogen oxides, and sulfur oxides. Further benefits are realized when syngas is combusted, as the burning of syngas releases lower amounts of carbon dioxide. The lowered carbon dioxide emissions and technological advances make these facilities "capture ready," since stored carbon dioxide from the coal is removed in the gasifier.

[0005] Conventional steam turbines require pressure, temperature, and corrosion resistant components to generate electricity. The limitations of these components dictate the upper range of the steam temperatures, and therefore limit efficiency of electric power production. In the case of an IGCC gas turbine, the same limitations do not apply. The gas turbine has a higher gas cycle firing temperature that feeds the compressor, burner, and turbine systems as a means of electricity production. The high-temperature exhaust-gas output of the turbine can be used to heat steam for a supplemental steam turbine, thereby increasing the overall efficiency of an electrical power plant. [0006] Coal may also be converted to a synthetic liquid fuel by the conversion of syngas. Liquid fuels have an advantage over coal in that they are easily transported long distances without expensive processes or packaging. The process of converting coal to a liquid fuel typically involves a catalytic reaction of syngas to form liquid hydrocarbons. Fischer-Tropsch (FT) reactor facilities execute the vital step of catalyzed synthesis of petroleum substitute liquid fuels. The process occurs via a catalyzed chemical reaction in which the carbon monoxide and hydrogen in syngas are converted into liquid hydrocarbons. The production of liquid hydrocarbon fuels from solid material reduces dependence on oil distillates for fuels. The hydrocarbon production reaction is highly exothermic, and requires a cooled reactor to maintain conditions favorable for continued synthesis.

[0007] The IGCC and FT process represent two potential clean coal processes to reduce dependence on oil distillates. The former provides clean electrical power and the latter provides liquid hydrocarbons for further processing into products. Additionally, both processes require coal processing, air separation, and syngas production for operation. The current costs of material, process, capital, and infrastructure make individual investments in these processes expensive rendering them unfavorable for development. Previous discussions on the combination of facilities for these processes have centered on their shared starting material and parallel infrastructure requirements for the production of syngas. However, it is recognized that provided a singular source of syngas to operate a plurality of clean coal plants is disadvantageous for operational flexibility, the capacity to scale output to demand, and maintain production during maintenance, or in the case of a device failure.

[0008] Accordingly, there is a need in industry for a method of integrating IGCC and CTL facilities with operational flexibility, scalable output, and online maintenance.

BRIEF SUMMARY

[0009] These and other needs in the art are addressed in an embodiment of an integrated Coal to Liquid and Integrated Gasification Combined Cycle facility described herein. A novel method of combining a CTL fuel plant and an IGCC electrical plant by sharing the systems of coal intake, coal preparation, gas separation, and water units is described herein. This configuration allows the combined facility to offer advantages in efficiency of production, operational flexibility, scalability, and reliability by a multi-path integration of the processing units. [0010] In embodiments, coal is received by the plant, and prepared for gasification in handling and preparation units. Additionally, air is separated into oxygen for gasification, and nitrogen for the IGCC gas turbine unit in a shared unit. The prepared coal and gas are routed to the CTL section or the IGCC section of the integrated facility. The direction of the processed materials transportation depends on factors involving the profitability of a given product, the quantity of processed material necessary to produce the product, and the maintenance status of the equipment. The production and purification of synthesis gas, or syngas occurs in the gasification and purification units, which both sections retain. An aspect of the disclosed process is that the produced syngas in one section may be provided to the adjacent section depending upon the profitability of a given product, the quantity of processed material necessary to produce the product, and the maintenance status of the equipment.

[0011] Byproduct, waste, or tail gases from the CTL section of the facility may be utilized in the IGCC section as a fuel for the gas turbines. In some cases the syngas feed stream to the CTL is not processed, thereby exiting the reactor for gaseous transportation to the IGCC section. These gases may also be recycled to increase the liquid product from the CTL Fischer-Tropsch reactor unit. Water and wastewater units may be shared between the sections of the facility. [0012] The foregoing has outlined rather broadly the features and technical advantages of the invention in order that the detailed description of the invention that follows may be better understood. Additional features and advantages of the invention will be described hereinafter that form the subject of the claims of the invention. It should be appreciated by those skilled in the art that the conception and the specific embodiments disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

[0013] For a detailed description of the preferred embodiments of the , reference will now be made to the accompanying drawings in which:

[0014] FIGURE 1 illustrates a schematic of non integrated operations of IGCC and CTL plants; [0015] FIGURE 2 illustrates a process flow diagram according to one embodiment of the method of integrating operations of IGCC and CTL plants;

[0016] FIGURE 3 illustrates a detailed process flow diagram according to one embodiment of the method of integrating operations of IGCC and CTL plant;

[0017] FIGURE 4 illustrates detailed process flow diagram according to one embodiment of the method of integrating operations of IGCC and CTL plant.

NOTATION AND NOMENCLATURE

[0018] Certain terms are used throughout the following descriptions and claims to refer to particular system components. This document does not intend to distinguish between components that differ in name but not function.

[0019] In the following discussion and in the claims the term "IGCC" is used to refer to an Integrated Gasification Combined Cycle electricity generation plant or facility. Similarly, the term "CTL" or "coal to liquid" is used to refer to a Fischer-Tropsch reactor based plant for the synthesis of liquid hydrocarbons from coal, or coal products without limitation by the individual processes involved. Additionally, the term syngas refers to a gaseous mixture comprised of varying amounts of the main components carbon monoxide and hydrogen with potentially other gaseous molecules. [0020] In further discussion the term "facility", "section" and "unit" are used in open ended fashion and thus should be interpreted to mean a premises for a system of components for the execution of a step, or series of steps and associated devices, or apparatuses within the described process.

[0021] In the following discussion and in the claims, the terms "including" and "comprising" are used in an open-ended fashion, and thus should be interpreted to mean "including, but not limited to..."

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS [0022] Referring now to Figure 1, that illustrates the components of non-integrated facilities for coal to liquid (CTL) fuel production 10 and an integrated gasification combined cycle (IGCC) power plant 20 in a side-by-side manner. CTL facility 10 comprises a Fischer-Tropsch Reactor 47 for the production of liquid hydrocarbons. IGCC facility comprises IGCC gas turbine 53 for the combustion of syngas to produce electricity. Further, Figure 1 illustrates the parallel or similar coal processing steps used in both the facilities. For example without limitation, these may include coal handling, 31, 32 coal preparation 33, 34 and gasifier (gasification unit) 35, 37, and syngas purifier 43, 45. Additionally, both facilities may comprise a process for gas treatment, water treatment, wastewater treatment, waste removal and/or similar processes understood by one skilled in the art.

[0023] In an embodiment, the disclosed process comprises a multi-path means to integrate the CTL 10 and IGCC 20 facilities. Figure 2 illustrates a novel integrated facility 30 incorporating an integrated IGCC electrical plant section 20 and a CTL Fischer Tropsch liquid hydrocarbon production section 10. In an embodiment, the coal handling 31, and coal preparation 33 units from the CTL facility 10 are shared between both sections. Alternatively, it can be envisioned that the coal handling 31 and coal preparation 33 units are derived from the IGCC facility 20 coal handling 32 and coal preparation 34 units. Coal delivered to the facility arrives at the coal-handling unit 31, before being moved to the coal preparation unit 33. The coal is moved between units by conveyors, trucks, slides or other means as known to one skilled in the art.

[0024] Determination of which section requires coal for operations is made and the coal is distributed to the CTL gasification unit 35, the IGCC gasification unit 37, or both. The facility receiving the coal may be considered the receiving facility. Alternatively, the facility without active coal reception may be considered the opposite facility. Coal delivered to the CTL facility 10 is processed through gasification 35, and syngas purification 45 to feed syngas stream 3. Coal delivered to IGCC facility 20 is processed through gasification 37 and syngas purification 43 to feed syngas stream 3.

[0025] The section of the integrated facility 30 receiving and processing coal from the coal preparation unit 33 determines the scale and operations of the opposing side. For instance, the IGCC facility 20 has a contract to produce a certain amount of electrical power from IGCC gas turbine 53. In order to satisfy that contract, IGCC facility 20 uses at least a portion of the output from coal preparation unit 33 through IGCC gasifier 37 and syngas preparation 43. CTL facility 10 and associated CTL gasifier 35 and syngas purification 45 only utilize remaining portion of coal. In further embodiments, the receiving facility uses all coal; alternatively a portion there of. Further, the opposing facility may supplement syngas stream 3, which is routed to receiving facility in order to boost production.

[0026] In preferred embodiments, syngas stream 3 is a shared between the CTL facility 10 and the IGCC facility 20. Syngas stream 3 is routed from either section of the integrated facility 30 to the other. For instance, syngas stream 3 is routed from the CTL facility 10 to the IGCC facility 20, and vice versa, without limitation. In an exemplary situation, where maintenance requires the temporary shut down of the IGCC gasifier 37, syngas stream 3 may be routed from the CTL syngas purifier 45 to the IGCC plant 20. In certain embodiments, gasification units 35, 37 and syngas purification 43, 45 may contribute to syngas stream 3 between the facilities. [0027] Referring now to Figure 3, gases required for the gasification of coal are processed and separated in the Air Separation Unit (hereinafter ASU) 39 of the integrated facility 30. The CTL gasification 35 and IGCC gasification 37 units include their own air separation units. Preferably, the CTL gasification 35 and IGCC gasification 37 units share a single ASU 39. The primary gas required is oxygen, which is distributed to the CTL gasifier 35, the IGCC gasifier 37, or both for the oxidation of coal and production of syngas. As previously discussed in regards to coal, the rate of delivery, and the facility, receiving the oxygen gas determines the scale and operational direction of the integrated facility 30. The oxygen depleted air, is further separated so as to supply nitrogen to the IGCC gas turbine 53. The ASU 39 produced gases, such as without limitation, oxygen and nitrogen, are transported inter-facility by enclosed conduits such as without limitation, pipes, tubes, pressurized lines, or tanks. The ASU 39 may utilize any suitable technologies to separate oxygen and nitrogen from air as understood by one skilled in the art. Examples include without limitation, compressors, columns, exchangers, pumps, or combinations thereof. [0028] Figure 4 illustrates further potential syngas 3 and off-gas sharing between the CTL section 10 and the IGCC section 20 of the integrated facility 30. In embodiments, the off gases, produced by Fischer Tropsch reactors 47 and the off gases from the refining unit 51 , can be used to as a co- feed stream 5 with syngas to the IGCC gas turbine 53. As necessary, the Fischer-Tropsch reactors 47 in the CTL section 10 may have the reaction temperature reversibly lowered. By lowering the temperature outside of the favorable reaction range, the result is the complete expulsion of syngas input as tail gas into co-feed stream 5 for feeding to the IGCC turbine 53. Without lowering temperature, reactor 47 creates product stream 6 for product refining facility 51. In certain embodiments, product refining comprises production of diesel, naptha, or other liquid hydrocarbons, without limitation. In further embodiments, the off or tail gases introduced to co- feed stream 5 may be used as a fuel feed to elevate steam temperature at an associated steam turbine generator 49. In alternative embodiments, the off gases from co-feed stream 5 maybe returned to the reactor 47 through a tail gas recycling facility 59.

[0029] Further, the IGCC section 20 of the integrated facility 30 may include Fischer Tropsch reactors 47 inline with the syngas supply stream from the purification unit 43 to the IGCC turbine 53. In this manner, the IGCC section 20 may produce additional liquid fuels as market demands dictate. The tail gases produced in the reactors may be used to power the IGCC turbine 53. In cases where electrical power is immediately required the temperature of the reactor is sufficiently lowered so that the syngas feed stream exits the reactor as unchanged tail gas. The salient details of this embodiment of the IGCC section 20 are disclosed in U.S. Patent No: 6,976,362, incorporated herein by reference in its entirety for all purposes. In certain instances, this arrangement may comprise a bolt-on CTL facility 10 incorporated into IGCC facility to form an integrated facility 30.

[0030] Water may be transported through a system of vessels, pipes, valves, and/or pumps, from the water unit to the entirety of the integrated facility 30. The water may be supplied to the units of the CTL facility 10 including the reactor 47, the product refining 51, the syngas purification 43 and gasification 35 units. In further embodiments, water may be provided to a steam turbine 49 that utilizes heat and steam from the other units to produce quantities of electricity. The other units may comprise any portion of the integrated facility 30, that generates suitable thermal waste, or heat for producing steam. Additionally, water may be routed from the gasification unit 35 to coal preparation unit 33. The coal preparation facility 33 is shared by both CTL 10 and IGCC 20 plants. Water supplied to each unit of the CTL section 10 may be routed through other units in the integrated facility 30, disconnected, or removed completely for treatment off premises, without limitations.

[0031] Water may also be transported to the IGCC syngas purification unit 43, the gas turbine 53 and the heat recovery steam generator (hereinafter HRSG) 55. Steam from HRSG is cycled to steam turbine 58. Steam turbine 58 may produce additional electrical power. In further embodiments, water is provided to the IGCC gasification unit 37. The IGCC gasification unit 37 may further provide water to the coal preparation unit 33 shared by the CTL 10 and IGCC 20 sections. Water supplied to each unit of the IGCC section 20 may be routed through other units, disconnected or removed completely, as known to one skilled in the art.

[0032] A wastewater treatment unit 57 may be included in the integrated facility 30. The wastewater treatment unit 57 drains the syngas purification units 43, 45, the gasification units 35, 37, the CTL reactor 47, the CTL product refining facilities 51, the coal preparation unit 33, and the IGCC gas turbine 53 of used water. Wastewater removal from individual units of the integrated facility 30 may be alternatively coupled, routed through other units, or omitted from the system. The wastewater may be recycled, reused, or treated and expelled from the integrated facility. [0033] While embodiments of the invention have been shown and described, modifications thereof can be made by one skilled in the art without departing from the spirit and teachings of the invention. The embodiments described and the examples provided herein are exemplary only, and are not intended to be limiting. Many variations and modifications of the invention disclosed herein are possible and are within the scope of the invention. Accordingly, the scope of protection is not limited by the description set out above, but is only limited by the claims which follow, that scope including all equivalents of the subject matter of the claims.

Claims

CLAIMS What is claimed is:

1. A method for operating integrated liquid hydrocarbon and electrical power production facilities comprising: a) providing an amount of coal to a coal separating unit; b) dividing the coal into a feed stream, wherein a feedstream, comprises a syngas production stream; c) providing a gas to the feedstream from an air separations unit (ASU) wherein gas is reacted with the feedstream, to produce a syngas stream; d) directing a portion of the syngas stream to a liquid hydrocarbon production reactor to produce liquid hydrocarbons, wherein byproducts from the liquid hydrocarbon reactor are directed to an electrical power turbine; and e) directing a portion of the syngas stream to turbine to produce electricity.

2. The method of claim 1 further comprising combining a coal to liquid (CTL) facility and an Integrated Gasification Combined Cycle (IGCC) facility.

3. The method of claim 1 wherein the liquid hydrocarbon reactor comprises a Fischer- Tropsch Reactor.

4. The method of claim 1 wherein b) further comprises dividing the coal into at least two syngas production streams.

5. The method of claim 4 wherein a syngas production stream is part of a liquid hydrocarbon production process.

6. The method of claim 4 wherein a syngas production stream is part of an electrical power production process.

7. The method of claim 1 wherein c) comprises dividing oxygen produced by the ASU.

8. The method of claim 7 wherein a portion of the oxygen is delivered to the syngas production stream that is part of a liquid hydrocarbon production process.

9. The method of claim 7 wherein a portion of the oxygen is delivered to the syngas production stream that is part of an electrical power production process.

10. The method of claim 1 wherein d) further comprise conveying a syngas stream to one or more reactors configured to produce liquid hydrocarbons.

11. The method of claim 1 wherein e) further comprises conveying a syngas stream to a steam turbine to produce electricity.

12. The method of claim 1 wherein a syngas stream is in fluid connection with one or more reactors configured to produce liquid hydrocarbons and to a steam turbine to produce electricity.

13. The method of claim 12, wherein the syngas stream is in fluid connection between one or more reactors configured to produce liquid hydrocarbons and to a steam turbine to produce electricity.

14. The method of claim 1 further comprising conveying wastewater from liquid hydrocarbon and electrical power production facilities a shared wastewater treatment unit.

15. The method of claim 1 further comprising supplying water from a shared water liquid hydrocarbon and electrical power production facilities.

16. The method of claim 1 further comprising selecting between d) and e) comprises evaluating the profitability of the product.

17. A method of integrating a coal-to-liquid (CTL) process and an integrated gasification combined cycle (IGCC) facility comprising: a) providing a coal handling unit and a coal preparation unit such that the coal-to- liquid (CTL) process and the integrated gasification combined cycle (IGCC) facility share the coal handling unit and the coal preparation unit, wherein the coal handling unit provides a coal feed stream for both the coal-to-liquid process and the integrated gasification combined cycle facility; and b) providing an air separation unit such that such that the coal-to-liquid process and the integrated gasification combined cycle facility share the air separation unit, wherein the single air separation unit provides an oxygen feed stream for both the coal-to-liquid process and the integrated gasification combined cycle facility.

18. The method of claim 17 wherein the CTL process further comprises a CTL gasification unit which produces a CTL syngas stream.

19 The method of claim 17 wherein the IGCC facility further comprises an IGCC gasification unit which produces an IGCC syngas stream.

20. The method of claim 17 further comprising supplying syngas to the IGCC facility via the CTL syngas stream.

21. The method of claim 17 further comprising supplying syngas to the CTL process via the IGCC syngas stream.

22. The method of claim 17 further comprises transferring at least one chosen from the group consisting of byproducts, electricity, liquid hydrocarbons, tail gases, exhaust gases, and syngas from the CTL process to the IGCC facility.

23. The method of claim 17 further comprises transferring at least one chosen from the group consisting of byproducts, electricity, liquid hydrocarbons, tail gases, exhaust gases, and syngas from the IGCC facility to the CTL process.

24. The method of claim 17 wherein the CTL syngas feedstream is run through the CTL facility unreacted, and delivered to the IGCC facility by a tail-gas conduit.