WO2007136495A3 - High efficiency solution polymerization process - Google Patents

High efficiency solution polymerization process Download PDF

Info

Publication number
WO2007136495A3
WO2007136495A3 PCT/US2007/009843 US2007009843W WO2007136495A3 WO 2007136495 A3 WO2007136495 A3 WO 2007136495A3 US 2007009843 W US2007009843 W US 2007009843W WO 2007136495 A3 WO2007136495 A3 WO 2007136495A3
Authority
WO
WIPO (PCT)
Prior art keywords
solution polymerization
high efficiency
polymerization process
efficiency solution
alumoxane
Prior art date
Application number
PCT/US2007/009843
Other languages
French (fr)
Other versions
WO2007136495A2 (en
Inventor
Wayde V Konze
James C Stevens
Daniel D Vanderlende
Original Assignee
Dow Global Technologies Inc
Wayde V Konze
James C Stevens
Daniel D Vanderlende
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38572813&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2007136495(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Global Technologies Inc, Wayde V Konze, James C Stevens, Daniel D Vanderlende filed Critical Dow Global Technologies Inc
Priority to EP07755919A priority Critical patent/EP2024400B1/en
Priority to ES07755919T priority patent/ES2394225T3/en
Priority to MX2008014671A priority patent/MX2008014671A/en
Priority to CA002652460A priority patent/CA2652460A1/en
Priority to JP2009510951A priority patent/JP5583402B2/en
Priority to US12/300,859 priority patent/US8202953B2/en
Priority to KR1020087030632A priority patent/KR101397337B1/en
Priority to BRPI0711029-4A priority patent/BRPI0711029A2/en
Publication of WO2007136495A2 publication Critical patent/WO2007136495A2/en
Publication of WO2007136495A3 publication Critical patent/WO2007136495A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Abstract

A catalyst composition comprising a zirconium complex of a polyvalent aryloxyether and an alumoxane, polymerization processes employing the same, especially the continuous, solution polymerization of ethylene and one or more C3-30 olefins or diolefins to prepare copolymers having reduced cocatalyst by-product content, are disclosed.
PCT/US2007/009843 2006-05-17 2007-04-24 High efficiency solution polymerization process WO2007136495A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP07755919A EP2024400B1 (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process
ES07755919T ES2394225T3 (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process
MX2008014671A MX2008014671A (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process.
CA002652460A CA2652460A1 (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process
JP2009510951A JP5583402B2 (en) 2006-05-17 2007-04-24 Highly efficient solution polymerization process
US12/300,859 US8202953B2 (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process
KR1020087030632A KR101397337B1 (en) 2006-05-17 2007-04-24 High Efficiency Solution Polymerization Process
BRPI0711029-4A BRPI0711029A2 (en) 2006-05-17 2007-04-24 process for polymerization of ethylene and one or more c3-30 α-olefins or diolefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80118206P 2006-05-17 2006-05-17
US60/801,182 2006-05-17

Publications (2)

Publication Number Publication Date
WO2007136495A2 WO2007136495A2 (en) 2007-11-29
WO2007136495A3 true WO2007136495A3 (en) 2008-01-17

Family

ID=38572813

Family Applications (6)

Application Number Title Priority Date Filing Date
PCT/US2007/009843 WO2007136495A2 (en) 2006-05-17 2007-04-24 High efficiency solution polymerization process
PCT/US2007/010070 WO2007136506A2 (en) 2006-05-17 2007-04-24 Polyolefin solution polymerization process and polymer
PCT/US2007/009845 WO2007136497A2 (en) 2006-05-17 2007-04-24 High temperature solution polymerization process
PCT/US2007/009841 WO2007136493A2 (en) 2006-05-17 2007-04-24 Polypropylene solution polymerization process
PCT/US2007/009844 WO2007136496A2 (en) 2006-05-17 2007-04-24 High temperature polyethylene solution polymerization process
PCT/US2007/009842 WO2007136494A2 (en) 2006-05-17 2007-04-24 Ethylene/ alpha-olefin/ diene solution polymerization process

Family Applications After (5)

Application Number Title Priority Date Filing Date
PCT/US2007/010070 WO2007136506A2 (en) 2006-05-17 2007-04-24 Polyolefin solution polymerization process and polymer
PCT/US2007/009845 WO2007136497A2 (en) 2006-05-17 2007-04-24 High temperature solution polymerization process
PCT/US2007/009841 WO2007136493A2 (en) 2006-05-17 2007-04-24 Polypropylene solution polymerization process
PCT/US2007/009844 WO2007136496A2 (en) 2006-05-17 2007-04-24 High temperature polyethylene solution polymerization process
PCT/US2007/009842 WO2007136494A2 (en) 2006-05-17 2007-04-24 Ethylene/ alpha-olefin/ diene solution polymerization process

Country Status (14)

Country Link
US (7) US8450438B2 (en)
EP (8) EP2787013A1 (en)
JP (6) JP5645400B2 (en)
KR (6) KR101397337B1 (en)
CN (8) CN102786619B (en)
AR (6) AR060642A1 (en)
AU (1) AU2007254428A1 (en)
BR (3) BRPI0711018A8 (en)
CA (5) CA2652456A1 (en)
ES (7) ES2534469T3 (en)
MX (4) MX2008014668A (en)
RU (4) RU2008149714A (en)
SG (1) SG158102A1 (en)
WO (6) WO2007136495A2 (en)

Families Citing this family (219)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101397337B1 (en) * 2006-05-17 2014-05-19 다우 글로벌 테크놀로지스 엘엘씨 High Efficiency Solution Polymerization Process
US8420760B2 (en) 2007-11-19 2013-04-16 Dow Global Technologies Llc Long chain branched propylene-alpha-olefin copolymers
KR101149755B1 (en) * 2009-01-06 2012-06-01 에스케이종합화학 주식회사 The Manufacture of Ethylene-Propylene-Diene Copolymer
US8722817B2 (en) 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
BRPI1007573A2 (en) * 2009-06-05 2019-09-24 Dow Global Technlogies Inc process
US9243087B2 (en) 2009-06-11 2016-01-26 Dow Global Technologies Llc LDPE enabling high output and good optics when blended with other polymers
SG10201403765WA (en) * 2009-07-01 2014-09-26 Dow Global Technologies Llc Ethylenic Polymer And Its Use
US8629214B2 (en) 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
US20110003940A1 (en) * 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
WO2011002998A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
CA2768705C (en) 2009-08-10 2017-06-20 Dow Global Technologies Llc Ldpe for use as a blend component in shrinkage film applications
US20110054122A1 (en) 2009-08-31 2011-03-03 Jerzy Klosin Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
JP5623043B2 (en) * 2009-09-04 2014-11-12 出光興産株式会社 Polyolefin production method, production apparatus thereof, and polymerization apparatus
WO2011032172A1 (en) 2009-09-14 2011-03-17 Dow Global Technologies Inc. Polymers comprising units derived from ethylene and siloxane
SG179052A1 (en) 2009-09-14 2012-04-27 Dow Global Technologies Llc Polymers comprising units derived from ethylene and poly(alkoxide)
US8987385B2 (en) 2009-09-14 2015-03-24 Dow Global Technologies Llc Interconnected copolymers of ethylene in combination with one other polyalkene
US8784996B2 (en) 2009-11-24 2014-07-22 Dow Global Technologies Llc Extrusion coating composition
US8679639B2 (en) 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition
BR112012014242A2 (en) 2009-12-24 2017-03-28 Dow Global Technologies Llc foam composition, article and cross-linked foam
CN105348417B (en) * 2010-01-14 2019-03-01 埃克森美孚化学专利公司 The method and apparatus of continuous solution polymerization
MY180069A (en) * 2010-03-02 2020-11-20 Dow Global Technologies Llc Ethylene-based polymer compositions
JP5767318B2 (en) * 2010-05-17 2015-08-19 ダウ グローバル テクノロジーズ エルエルシー Method for selectively polymerizing ethylene and catalyst therefor
EP2576685A1 (en) * 2010-05-26 2013-04-10 Dow Global Technologies LLC Electronic device module comprising polyolefin copolymer with low unsaturation and optional vinyl silane
JP2013528950A (en) 2010-06-04 2013-07-11 ダウ グローバル テクノロジーズ エルエルシー Electronic device module comprising homogeneous polyolefin copolymer and adhesion-enhanced graft polymer membrane
JP2013528951A (en) 2010-06-04 2013-07-11 ダウ グローバル テクノロジーズ エルエルシー Electronic device module comprising homogeneous polyolefin copolymer and adhesion-enhanced graft polymer membrane
EP3473673A1 (en) * 2010-06-14 2019-04-24 Dow Global Technologies, LLC Fiber comprising ethylene-based polymer compositions
WO2012006230A1 (en) * 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
WO2012061168A1 (en) 2010-11-02 2012-05-10 Dow Global Technologies Llc A sealant composition, method of producing the same
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
CN103339186B (en) * 2010-12-03 2016-03-30 陶氏环球技术有限责任公司 Prepare the method based on the polymer composition of ethene
EP2655439B1 (en) * 2010-12-21 2018-09-19 Dow Global Technologies LLC Polymerization process and raman analysis for olefin-based polymers
US9388254B2 (en) 2010-12-21 2016-07-12 Dow Global Technologies Llc Olefin-based polymers and dispersion polymerizations
KR101871533B1 (en) 2010-12-30 2018-06-26 다우 글로벌 테크놀로지스 엘엘씨 Compositions, methods of making the same, and articles prepared from the same
BR112014004794B1 (en) 2011-09-07 2020-11-10 Dow Global Technologies Llc composition, lattice composition and article
EP2751191B1 (en) * 2011-09-12 2020-07-22 Dow Global Technologies LLC Compositions and articles formed from the same
US20160272798A1 (en) 2011-09-23 2016-09-22 Exxonmobil Chemical Patents Inc. Modified Polyethylene Compositions with Enhanced Melt Strength
JP5960831B2 (en) 2011-09-23 2016-08-02 エクソンモービル ケミカル パテンツ インコーポレイテッド Modified polyethylene composition
US10131114B2 (en) * 2011-10-05 2018-11-20 Dow Global Technologies Llc Spunbond nonwoven fabrics
IN2014CN02606A (en) 2011-10-10 2015-08-07 Dow Global Technologies Llc
JP6170056B2 (en) 2011-10-20 2017-07-26 ダウ グローバル テクノロジーズ エルエルシー Ethylene-based polymer composition and articles made therefrom
EP2768667A4 (en) * 2011-10-21 2015-07-01 Dow Global Technologies Llc Multi-layered shrink films
BR112014009442A2 (en) * 2011-10-24 2017-04-11 Dow Global Technologies Llc synthetic grass and method for preparing synthetic grass
MX357976B (en) * 2011-12-13 2018-08-01 Dow Global Technologies Llc Ethylene-propylene-diene interpolymer composition.
KR20140107260A (en) 2011-12-19 2014-09-04 다우 글로벌 테크놀로지스 엘엘씨 Ethylene-based polymers prepared by dispersion polymerization
JP6189325B2 (en) * 2011-12-20 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー Ethylene / alphaolefin / nonconjugated polyene copolymer and method for forming the same
CA2861504C (en) * 2011-12-29 2019-11-05 Dow Global Technologies Llc Process for producing low molecular weight ethylene- and alpha-olefin-based materials
CA2861516C (en) * 2011-12-29 2021-01-05 Dow Global Technologies Llc Hyperbranched olefin oil based dielectric fluid
EP2617741B1 (en) * 2012-01-18 2016-01-13 Borealis AG Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process
WO2013116649A1 (en) 2012-02-03 2013-08-08 Dow Global Technologies Llc Silane-containing ethylene interpolymer formulation including films and electronic device module comprising same
EP2847243B1 (en) 2012-05-09 2018-09-05 Dow Global Technologies LLC Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer
EP2867296B1 (en) * 2012-06-29 2018-10-24 Dow Global Technologies LLC Ethylene/alpha-olefin/nonconjugated polyene based compositions for thermoplastic vulcanizates
WO2014012250A1 (en) * 2012-07-20 2014-01-23 Dow Global Technologies Llc A linear low density polyethylene composition suitable for cast film
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2880096B1 (en) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith
WO2014022011A1 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising salan ligands
US8957172B2 (en) 2012-08-03 2015-02-17 Exxonmobil Chemical Patents Inc. Nonsymmetric catalysts comprising salan ligands
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
CN104411777B (en) 2012-08-03 2017-10-24 埃克森美孚化学专利公司 Catalyst containing Salan ligand
US10822479B2 (en) 2012-09-20 2020-11-03 Exxonmobil Chemical Patents Inc. Foamed polyethylene compositions
US10836853B2 (en) 2012-09-20 2020-11-17 Exxonmobil Chemical Patents Inc. Crack-resistant polyethylene compositions
US9120879B2 (en) 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
JP6207336B2 (en) * 2012-11-12 2017-10-04 日本ポリプロ株式会社 Diol compound, catalyst for olefin polymerization, and method for producing olefin polymer
SG11201504003XA (en) 2012-11-30 2015-06-29 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
SG11201505060QA (en) 2012-12-27 2015-07-30 Dow Global Technologies Llc An ethylene based polymer
SG10201705090XA (en) * 2012-12-27 2017-07-28 Dow Global Technologies Llc An ethylene based polymer
SG11201505073SA (en) 2012-12-27 2015-07-30 Dow Global Technologies Llc A polymerization process for producing ethylene based polymers
SG11201505069VA (en) 2012-12-27 2015-07-30 Dow Global Technologies Llc A polymerization process for producing ethylene based polymers
KR20150100694A (en) * 2012-12-27 2015-09-02 다우 글로벌 테크놀로지스 엘엘씨 Catalyst systems for olefin polymerization
KR102038178B1 (en) * 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 Polymerization processes for high molecular weight polyolefins
CN107722148B (en) 2013-02-08 2021-06-08 三井化学株式会社 Solid polyaluminoxane composition, catalyst for olefin polymerization, and method for producing olefin polymer
US8937137B2 (en) 2013-03-13 2015-01-20 Exxonmobil Chemical Patents Inc. Diphenylamine salan catalyst
KR101657262B1 (en) * 2013-04-05 2016-09-13 한화케미칼 주식회사 Catalyst for olefin polymerization and method for preparing polyolefin using the same
US9200099B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Salenol catalyst
US9200100B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
CN105392776B (en) 2013-06-20 2019-02-12 埃克森美孚化学专利公司 Thio-Salalen catalyst
WO2014209084A1 (en) 2013-06-28 2014-12-31 주식회사 엘지화학 Trinary elastic copolymer comprising diene and method for preparing same
EP3925989A1 (en) 2013-06-28 2021-12-22 Dow Global Technologies LLC Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
WO2014209082A1 (en) 2013-06-28 2014-12-31 주식회사 엘지화학 Trinary elastic copolymer comprising diene and method for preparing same
IN2015DN02232A (en) 2013-06-28 2015-08-21 Lg Chemical Ltd
KR101585204B1 (en) * 2013-06-28 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
BR112015031326B1 (en) * 2013-06-28 2021-05-25 Dow Global Technologies Llc process for preparing a utility fluid composition
US10155831B2 (en) * 2013-09-05 2018-12-18 Univation Technologies, Llc Process control for long chain branching control in polyethylene production
CN104628920B (en) * 2013-11-08 2017-02-01 中国石油天然气股份有限公司 Preparation method of solution polymerized ethylene propylene (EP) rubber
EP3080073B1 (en) * 2013-12-13 2018-10-24 ExxonMobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
WO2015116381A1 (en) * 2014-01-30 2015-08-06 Exxonmobil Chemical Patents Inc. Crack-resistant polyethylene composiitions
WO2015116382A1 (en) * 2014-01-30 2015-08-06 Exxonmobil Chemical Patents Inc. Foamed polyethylene compositions
KR101791810B1 (en) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 Process to produce ethylene propylene copolymers
EP3126325B1 (en) 2014-03-31 2019-04-24 ExxonMobil Chemical Patents Inc. Phenylene-bridged salalen catalysts
US10167355B2 (en) * 2014-04-17 2019-01-01 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
EP3647314B1 (en) * 2014-06-30 2023-05-24 Dow Global Technologies LLC Catalyst systems for olefin polymerization
CN106459288B (en) 2014-06-30 2020-06-09 陶氏环球技术有限责任公司 Olefin polymerization process
EP3172250B1 (en) * 2014-07-24 2020-01-01 Dow Global Technologies LLC Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers
US10301412B2 (en) 2014-12-04 2019-05-28 Dow Global Technologies Llc Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers
CN107108804B (en) * 2014-12-31 2020-07-24 陶氏环球技术有限责任公司 Polyolefin composition and process for producing the same
ES2718058T3 (en) * 2015-03-31 2019-06-27 Dow Global Technologies Llc Procedures for the production of ethylene / alpha-olefin / non-conjugated interpolymers of high molecular weight with low levels of long chain branching
CN107709384B (en) 2015-05-28 2020-09-01 陶氏环球技术有限责任公司 Process for forming ethylene/alpha-olefin interpolymers
CN107771199B (en) * 2015-06-17 2021-05-25 陶氏环球技术有限责任公司 Process for making crosslinked cable insulation using high melt strength ethylene-based polymers made in a tubular reactor and optionally modified with a branching agent
US10647789B2 (en) 2015-06-22 2020-05-12 Dow Global Technologies Llc Process for making ethylene-based polymers using carbon-carbon free radical initiators
ES2785628T3 (en) 2015-06-30 2020-10-07 Dow Global Technologies Llc A polymerization process to produce ethylene-based polymers
BR112017027521B1 (en) 2015-06-30 2022-01-04 Dow Global Technologies Llc POLYMERIZATION PROCESS TO PRODUCE ETHYLENE-BASED POLYMERS
KR102587539B1 (en) 2015-09-02 2023-10-12 다우 글로벌 테크놀로지스 엘엘씨 Flexible crosslinked cable insulation and method of making flexible crosslinked cable insulation
WO2017040089A1 (en) 2015-09-02 2017-03-09 Dow Global Technologies Llc Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
US10800865B2 (en) 2015-09-14 2020-10-13 Exxonmobil Chemical Patents Inc. Process for making branched EPDM and the EPDM therefrom
US11732064B2 (en) 2015-09-30 2023-08-22 Dow Global Technologies Llc Process for preparing functional polymers through addition of amino and polymeryl groups to aldehyde moieties
CN108350121B (en) 2015-09-30 2021-10-01 陶氏环球技术有限责任公司 Procatalyst and polymerization process using the same
BR112018005199B1 (en) 2015-09-30 2020-12-15 Dow Global Technologies Llc PROCESS FOR THE PREPARATION OF A COMPOSITION, COMPOSITION AND PROCESS FOR POLYMERIZATION OF AT LEAST ONE POLYMERIZABLE MONOMER BY ADDITION TO FORM A POLYMER COMPOSITION
EP3356430B1 (en) 2015-09-30 2022-06-22 Dow Global Technologies LLC A polymerization process for producing ethylene based polymers
EP3368602B1 (en) 2015-10-29 2020-07-08 Dow Global Technologies, LLC Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
EP3397665B2 (en) 2015-12-29 2023-11-08 Dow Global Technologies LLC Highly grafted ethylene-based polymers, highly grafted ethylene-based polymer compositions, and processes for forming the same
EP3214115B1 (en) 2016-03-03 2018-10-03 Dow Global Technologies LLC Polyethylene composition, method of making the same, and films made therefrom
WO2017206009A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymers compositions
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
WO2018005852A1 (en) 2016-06-30 2018-01-04 Dow Global Technologies Llc Ethylene/alpha-olefin/polyene based compositions
KR102450870B1 (en) 2016-06-30 2022-10-05 다우 글로벌 테크놀로지스 엘엘씨 Ethylene/alpha-olefin/polyene interpolymers and compositions containing them
WO2018005789A1 (en) 2016-06-30 2018-01-04 Dow Global Technologies Llc Procatalyst compositions useful for low comonomer incorporation and process for preparing the same
US10808049B2 (en) 2016-07-13 2020-10-20 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
WO2018013283A2 (en) 2016-07-13 2018-01-18 Exxonmobil Chemical Patents Inc. Dual metallocene catalyst copolymer compositions
US10822440B2 (en) 2016-07-14 2020-11-03 Exxonmobil Chemical Patents Inc. Dual metallocene-catalyzed bimodal copolymer compositions
MX2019000698A (en) 2016-07-21 2019-07-04 Dow Global Technologies Llc Composite cushioning structures, and methods of manufacturing thereof.
WO2018022975A1 (en) 2016-07-29 2018-02-01 Dow Global Technologies Llc Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
US11155658B2 (en) 2016-07-29 2021-10-26 Dow Global Technologies Llc Mixed catalyst systems for producing multimodal elastomers
CN109715677B (en) 2016-09-29 2022-03-22 陶氏环球技术有限责任公司 Modified ziegler-natta (pro) catalysts and systems
BR112019006072B1 (en) 2016-09-29 2023-02-14 Dow Global Technologies Llc METHOD OF POLYMERIZATION OF AN OLEFIN USING A ZIEGLER-NATTA CATALYST AND AN UNSUPPORTED MOLECULAR CATALYST IN THE SAME REACTOR AT THE SAME TIME AND POLYMERIZATION METHOD
KR102449474B1 (en) 2016-09-29 2022-10-11 다우 글로벌 테크놀로지스 엘엘씨 Magnesium halide-supported titanium (pre)catalyst
TW201840572A (en) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
JP7029448B2 (en) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー A sealed multi- or dual-head composition useful for chain shuttling, and the process of preparing it.
CN109963888A (en) 2016-09-30 2019-07-02 陶氏环球技术有限责任公司 It is used to prepare the method for being suitable for bull or double end composition that chain shuttle moves
EP3532511B1 (en) 2016-10-27 2020-11-25 Univation Technologies, LLC Method of preparing a molecular catalyst
WO2018089165A1 (en) * 2016-11-11 2018-05-17 Exxonmobil Chemical Patents Inc. Catalyst compositions and use thereof
US10280234B2 (en) 2016-11-11 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and use thereof
TW201829574A (en) 2016-11-16 2018-08-16 美商陶氏全球科技有限責任公司 Tie layer compositions and multilayer films incorporating same
JP7221206B2 (en) 2017-02-28 2023-02-13 ダウ グローバル テクノロジーズ エルエルシー Phosphoramidate catalysts for ethylene-based interpolymers
BR112019019129A2 (en) 2017-03-15 2020-04-14 Dow Global Technologies Llc catalyst system for multi-block copolymer formation
JP7179750B2 (en) 2017-03-15 2022-11-29 ダウ グローバル テクノロジーズ エルエルシー Catalyst system for forming multi-block copolymers
JP7101185B2 (en) 2017-03-15 2022-07-14 ダウ グローバル テクノロジーズ エルエルシー Catalyst system for forming multi-block copolymers
SG11201908414YA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
JP7028885B2 (en) 2017-03-15 2022-03-02 ダウ グローバル テクノロジーズ エルエルシー Catalyst system for forming multi-block copolymers
JP2018162231A (en) * 2017-03-27 2018-10-18 三井化学株式会社 Transition metal compound, catalyst for olefin polymerization and method for producing olefin polymer
EP3409697A1 (en) 2017-05-28 2018-12-05 SABIC Global Technologies B.V. Preparation of polymer dispersions
EP3638730A1 (en) 2017-06-14 2020-04-22 ExxonMobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications
KR20200044032A (en) 2017-08-24 2020-04-28 다우 글로벌 테크놀로지스 엘엘씨 Ethylene / C5-C10 alpha-olefin / polyene interpolymer
EP3688045B1 (en) 2017-09-29 2022-03-02 Dow Global Technologies LLC Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility
EP3688043B1 (en) 2017-09-29 2023-06-14 Dow Global Technologies LLC Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility
WO2019067274A1 (en) 2017-09-29 2019-04-04 Dow Global Technologies Llc Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
EP3732216B1 (en) 2017-12-26 2023-04-19 Dow Global Technologies LLC Process for the production of multimodal ethylene-based polymers
ES2908893T3 (en) 2017-12-26 2022-05-04 Dow Global Technologies Llc Multimodal ethylene-based polymeric compositions with improved toughness
US20200332036A1 (en) 2017-12-26 2020-10-22 Dow Global Technologies Llc Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures
US11680120B2 (en) 2017-12-26 2023-06-20 Dow Global Technologies Llc Dual reactor solution process for the production of multimodal ethylene-based polymer
KR20200103723A (en) 2017-12-26 2020-09-02 다우 글로벌 테크놀로지스 엘엘씨 Multimode ethylene-based polymer treatment system and method
EP3732217B1 (en) 2017-12-26 2023-06-21 Dow Global Technologies, LLC Compositions comprising multimodal ethylene based polymers and low density polyethylene (ldpe)
KR102644634B1 (en) 2017-12-29 2024-03-07 다우 글로벌 테크놀로지스 엘엘씨 Capped double head organic aluminum composition
EP3732181A1 (en) 2017-12-29 2020-11-04 Dow Global Technologies LLC Dual-headed organoaluminum compositions
US20190248934A1 (en) 2018-02-09 2019-08-15 Exxonmobil Chemical Patents Inc. Ethylene-a-olefin-diene Elastomers and Methods of Making Them
JP2021517916A (en) 2018-02-14 2021-07-29 ダウ グローバル テクノロジーズ エルエルシー Ethylene / alpha-olefin interpolymer composition with improved long-term heat aging performance
EP3768687A1 (en) 2018-03-19 2021-01-27 Dow Global Technologies LLC Silicon-terminated organo-metal compounds and processes for preparing the same
KR20200133348A (en) 2018-03-19 2020-11-27 다우 글로벌 테크놀로지스 엘엘씨 Polyolefin-polydiorganosiloxane block copolymer and method for its synthesis
JP2021518330A (en) 2018-03-19 2021-08-02 ダウ グローバル テクノロジーズ エルエルシー Silicon-terminated telechelic polyolefin composition and the process for preparing it
CA3093558A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof
WO2019182718A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Hot melt adhesive composition containing a polyolefin - polydiorganosiloxane copolymer and methods for the preparation and use thereof
SG11202008429TA (en) 2018-03-19 2020-10-29 Dow Global Technologies Llc Process for functionalization of organo-zinc compounds with halosilanes using basic nitrogen containing heterocycles and silyl-functionalized compounds prepared thereby
CN112074547A (en) 2018-03-19 2020-12-11 陶氏环球技术有限责任公司 Method for functionalizing organometallic compounds with silane-based functionalizing agents and silane-functionalized compounds prepared thereby
SG11202009138QA (en) 2018-03-19 2020-10-29 Dow Global Technologies Llc Silicon-terminated organo-metal compounds and processes for preparing the same
WO2019182721A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof
JP2021523956A (en) 2018-03-29 2021-09-09 ダウ グローバル テクノロジーズ エルエルシー Resins for use as bond layers in multi-layer structures, and multi-layer structures containing them
EP3774937A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
JP2021519362A (en) * 2018-03-30 2021-08-10 ダウ グローバル テクノロジーズ エルエルシー Olefin polymerization activator
CN111918717B (en) 2018-03-30 2024-04-09 陶氏环球技术有限责任公司 Olefin polymerization activator
JP7304880B2 (en) 2018-03-30 2023-07-07 ダウ グローバル テクノロジーズ エルエルシー Dinuclear olefin polymerization activator
JP2021528510A (en) 2018-05-31 2021-10-21 パフォーマンス マテリアルズ エヌエー インコーポレイテッド Molded article and its method
US11873393B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
JP7419269B2 (en) 2018-06-15 2024-01-22 ダウ グローバル テクノロジーズ エルエルシー Blown films containing bimodal ethylene-based polymers with high molecular weight high-density fractions
CA3103015A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
JP7406513B2 (en) 2018-06-15 2023-12-27 ダウ グローバル テクノロジーズ エルエルシー Production process of bimodal ethylene-based polymers with high molecular weight and high density fractions
CN112334515B (en) 2018-07-17 2022-08-09 美国陶氏有机硅公司 Polysiloxane resin-polyolefin copolymers and methods of making and using the same
WO2020046597A1 (en) 2018-08-29 2020-03-05 Exxonmobil Chemical Patents Inc. Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes
JP2022509781A (en) 2018-11-30 2022-01-24 ダウ グローバル テクノロジーズ エルエルシー Polymer-based film with balanced properties
EP3902809A1 (en) 2018-12-28 2021-11-03 Dow Global Technologies LLC Curable compositions comprising unsaturated polyolefins
KR20210121027A (en) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 Curable composition comprising unsaturated polyolefin
BR112021012777A2 (en) 2018-12-28 2021-09-08 Dow Global Technologies Llc ORGANOMETALLIC COMPOSITION
KR20210121026A (en) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 Telechelic polyolefin and method for preparing same
JP2022516119A (en) 2018-12-28 2022-02-24 ダウ グローバル テクノロジーズ エルエルシー Curable composition containing telechelic polyolefin
US11028805B2 (en) 2019-01-09 2021-06-08 Saudi Arabian Oil Company System and method for on-board catalytic upgrading of hydrocarbon fuels
KR101995951B1 (en) * 2019-03-12 2019-07-03 주식회사 라이온켐텍 A continuous method for manufacturing polyolefin copolymer
US20220162352A1 (en) 2019-03-28 2022-05-26 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators
BR112021021366A2 (en) 2019-04-30 2022-03-15 Dow Global Technologies Llc polymerization process
EP3963005A4 (en) 2019-04-30 2022-11-23 Dow Global Technologies LLC Ethylene/propylene/nonconjugated diene interpolymer composition
US11945888B2 (en) 2019-05-15 2024-04-02 Exxonmobil Chemical Patents Inc. Solution polymerization process and product control using effluent density
WO2020263681A1 (en) 2019-06-26 2020-12-30 Dow Global Technologies Llc Controlled long chain branching in epdm by post-reactor modification
BR112021025999A2 (en) 2019-06-26 2022-02-08 Dow Global Technologies Llc Composition, b terpolymer, nr terpolymer, and nr epdm
EP3763745A1 (en) 2019-07-10 2021-01-13 Borealis AG High temperature solution process for the copolymerization of alpha-olefins
CN114206952A (en) * 2019-07-31 2022-03-18 陶氏环球技术有限责任公司 In-solution polymerization of ethylene using ziegler-natta catalyst and hydrogenation procatalyst
WO2021035709A1 (en) 2019-08-30 2021-03-04 Dow Global Technologies Llc Polyolefin compositions having improved electrical properties
US20220289960A1 (en) 2019-09-24 2022-09-15 Dow Global Technologies Llc Polymer compositions for extruded profiles
BR112022005433A2 (en) 2019-09-24 2022-06-21 Dow Global Technologies Llc Composition, lattice composition and article
US20220402855A1 (en) 2019-12-30 2022-12-22 Dow Global Technologies Llc Process for preparing an alpha-substituted acrylate
JP2023508106A (en) 2019-12-30 2023-02-28 ダウ グローバル テクノロジーズ エルエルシー Process for preparing alpha-substituted acrylates
JP2023520328A (en) 2020-03-27 2023-05-17 ダウ グローバル テクノロジーズ エルエルシー Long-chain branched ethylene-based polymer
CN115298236A (en) 2020-03-27 2022-11-04 陶氏环球技术有限责任公司 Long chain branched ethylene-based polymers
WO2021195505A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
CN115397875A (en) 2020-03-27 2022-11-25 陶氏环球技术有限责任公司 Process for producing long chain branched ethylene-based polymers
EP4127061A1 (en) 2020-03-30 2023-02-08 ExxonMobil Chemical Patents Inc. Comb-block copolymers and methods thereof
KR20230003156A (en) 2020-04-29 2023-01-05 다우 글로벌 테크놀로지스 엘엘씨 High-flow propylene-based interpolymer composition
CN111662403B (en) * 2020-07-14 2022-08-05 万华化学集团股份有限公司 Cascade catalytic system and method for preparing LLDPE (Linear Low Density polyethylene) by using same
WO2022015369A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
US20240010771A1 (en) * 2020-07-17 2024-01-11 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalyst for bis-phenylphenoxy metal-ligand complexes
WO2022015368A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
CN111909196B (en) * 2020-08-10 2023-05-26 万华化学集团股份有限公司 IVB-group-containing bimetallic complex catalyst, and preparation method and application thereof
WO2022073805A1 (en) 2020-10-05 2022-04-14 Borealis Ag High temperature solution process for the copolymerization of ethylene with one ore more α-Olefin comonomer(s)
JP2023552277A (en) 2020-11-10 2023-12-15 ダウ グローバル テクノロジーズ エルエルシー Preparation of polyolefin-polyacrylate block copolymer additives to increase surface energy of polyethylene
WO2022103803A1 (en) 2020-11-10 2022-05-19 Dow Global Technologies Llc Preparation of non-polar–polar block copolymers via vinyl-terminated polyolefins
WO2022115410A2 (en) 2020-11-24 2022-06-02 Dow Global Technologies Llc Process to produce long chain branching in epdm and product
JP2024509386A (en) * 2021-02-26 2024-03-01 ダウ グローバル テクノロジーズ エルエルシー Bis-phenoxy-ether ligands for Group IV polyolefin catalysts
TW202323424A (en) 2021-08-04 2023-06-16 大陸商中國石油化工科技開發有限公司 Flexible polypropylene modified insulation material, preparation method therefor, and application thereof
WO2023039515A2 (en) 2021-09-10 2023-03-16 Dow Global Technologies Llc Borate cocatalysts for polyolefin production
WO2023039514A1 (en) 2021-09-10 2023-03-16 Dow Global Technologies Llc Hydrocarbon soluble borate cocatalysts for olefin polymerization
CN114957530B (en) * 2022-06-28 2023-09-29 杭州双安科技有限公司 Solution polymerization method of ethylene and alpha-olefin
CN115160472B (en) * 2022-08-09 2023-07-11 万华化学集团股份有限公司 High insertion rate ethylene copolymer solution polymerization method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
US20050164872A1 (en) * 2002-04-24 2005-07-28 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2006020624A1 (en) * 2004-08-09 2006-02-23 Dow Global Technologies Inc. Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers

Family Cites Families (152)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3914342A (en) * 1971-07-13 1975-10-21 Dow Chemical Co Ethylene polymer blend and polymerization process for preparation thereof
US3953413A (en) 1974-06-13 1976-04-27 Chemplex Company Supported chromium-containing catalyst and process of polymerizing 1-olefins
US4173548A (en) * 1977-02-02 1979-11-06 Chemplex Company Ethylene polymerization catalyst and method
US4330646A (en) 1979-08-13 1982-05-18 Asahi Kasei Kogyo Kabushiki Kaisha Polymerization of an α-olefin
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
DZ520A1 (en) 1982-03-24 2004-09-13 Union Carbide Corp Improved process for increasing the space-time yield of an exothermic polymerization reaction in a fluidized bed.
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) * 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4430563A (en) 1982-04-30 1984-02-07 Minnesota Mining And Manufacturing Company Data processing form
US4564660A (en) 1983-06-30 1986-01-14 Union Carbide Corporation Use of alkylaluminum compounds and hydroxyl-containing compounds to initiate polymerization of ethylene with chromium oxide catalysts
US4612300A (en) * 1985-06-06 1986-09-16 The Dow Chemical Company Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
EP0594218B1 (en) 1986-09-24 1999-03-17 Mitsui Chemicals, Inc. Process for polymerizing olefins
JPH0780933B2 (en) 1986-11-20 1995-08-30 三井石油化学工業株式会社 Olefin Polymerization Method
JPS63154753A (en) 1986-12-18 1988-06-28 Nippon Oil Co Ltd Polyethylene composition
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH0742301B2 (en) 1987-02-14 1995-05-10 三井石油化学工業株式会社 Particulate aluminoxane, its manufacturing method and its use
JP2538588B2 (en) 1987-04-03 1996-09-25 三井石油化学工業株式会社 Method for producing solid catalyst for olefin polymerization
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US4981927A (en) 1987-05-20 1991-01-01 National Distillers And Chemical Corporation Chromium catalyst compositions and polymerization utilizing same
FR2634212B1 (en) 1988-07-15 1991-04-19 Bp Chimie Sa APPARATUS AND METHOD FOR POLYMERIZATION OF GASEOUS OLEFINS IN A FLUIDIZED BED REACTOR
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
ES2071086T5 (en) 1989-10-30 2002-01-16 Fina Technology PREPARATION OF METALOCENICAL CATALYSTS FOR OLEFINE POLYMERIZATION.
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
FR2656314B1 (en) 1989-12-22 1992-04-17 Bp Chemicals Snc ZIRCONIUM CATALYST SUPPORTED ON MAGNESIUM CHLORIDE, PROCESS FOR THE PREPARATION AND USE OF THE CATALYST IN OLEFIN POLYMERIZATION.
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP2545006B2 (en) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー Addition polymerization catalyst
KR940009020B1 (en) 1990-07-24 1994-09-29 미쓰이 도오아쓰 가가쿠 가부시키가이샤 CATALYST FOR Ñß-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY Ñß-OLEFIN THEREWITH
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5296443A (en) * 1991-03-01 1994-03-22 Dai Nippon Printing Co., Ltd. Thermal transfer image receiving sheet
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5308815A (en) 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US6448355B1 (en) 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5674342A (en) * 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
US5525695A (en) 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
DE69232297T2 (en) 1992-01-06 2002-08-14 Dow Chemical Co catalyst composition
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5288933A (en) * 1992-04-16 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polyethylene
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
BE1005957A5 (en) * 1992-06-05 1994-04-05 Solvay Preparation method of catalyst system, process (co) polymerization of olefins and (co) polymer at least one olefine.
ES2190567T3 (en) 1992-07-01 2003-08-01 Exxonmobil Chem Patents Inc PRECURSORS OF TRANSITION METAL CATALYSTS OF GROUPS 5 AND 6.
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
CA2145635A1 (en) 1992-09-29 1994-04-14 Patrick Brant Long chain branched polymers and a process to make long chain branched polymers
DE69312306T2 (en) 1992-10-02 1997-11-13 Dow Chemical Co APPLICATION OF HOMOGENIC COMPLEX CATALYST FOR OLEFIN POLYMERIZATION
DE4322884A1 (en) 1992-10-09 1994-04-14 Bayer Ag Biologically active polymers
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5391793A (en) 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
US5608019A (en) 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5391529A (en) 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
TW298593B (en) * 1993-02-12 1997-02-21 Hoechst Ag
KR100311244B1 (en) * 1993-02-22 2001-12-15 가지와라 야스시 Process for producing ethylene / α-olefin copolymer
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
RU2120947C1 (en) 1993-04-26 1998-10-27 Эксон Кемикэл Пейтентс Инк. Method of gas-phase polymerization in fluidized layer
CA2160705C (en) * 1993-04-28 2006-08-22 Pak Wing Steve Chum Fabricated articles made from ethylene polymer blends
BE1007148A3 (en) * 1993-05-17 1995-04-11 Solvay Support for catalyst, method for producing gel precursor media for catalyst, method for preparing a catalyst support, catalyst for olefin polymerization and method for olefin polymerization using the catalyst .
FR2705252B1 (en) * 1993-05-19 1995-07-21 Bp Chemicals Snc Process for introducing a solid into a reactor and apparatus.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
EP0705269B1 (en) 1993-06-24 1997-01-15 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
JPH09505340A (en) 1993-11-19 1997-05-27 エクソン・ケミカル・パテンツ・インク Polymerization catalyst system, production method and use thereof
JPH07144455A (en) 1993-11-25 1995-06-06 Canon Inc Ink jet recording apparatus
US5648310A (en) * 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5674795A (en) 1993-12-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
DE4436392C2 (en) 1994-10-12 2002-10-31 Fraunhofer Ges Forschung Metal niobates and / or tantalates, processes for their preparation and their further processing into perovskites
US5616661A (en) * 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
UA47394C2 (en) 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Ethylene polymer with improved processability and an article containing the ethylene polymer
JP3281389B2 (en) * 1995-06-08 2002-05-13 昭和電工株式会社 Ionic compounds and catalysts for olefin polymerization using the compounds
US5731253A (en) 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
US5693838A (en) 1995-11-13 1997-12-02 Albemarle Corporation Aluminoxane process and product
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
EP0786466B1 (en) 1996-01-25 2003-04-16 Tosoh Corporation Olefin polymerisation process which comprises a transition metal catalyst.
WO1997032922A2 (en) * 1996-03-05 1997-09-12 The Dow Chemical Company Rheology-modified polyolefins
KR100437238B1 (en) * 1996-03-27 2004-08-16 다우 글로벌 테크놀로지스 인크. Highly soluble olefin polymerization catalyst activator
JP2000517349A (en) * 1996-03-27 2000-12-26 ザ ダウ ケミカル カンパニー Solution polymerization with dispersed catalytic activators.
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US5731451A (en) 1996-07-12 1998-03-24 Akzo Nobel Nv Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
WO1998009996A1 (en) 1996-09-06 1998-03-12 Hyundai Petrochemical Co., Ltd. Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system
US5744656A (en) 1996-10-25 1998-04-28 Boulder Scientific Company Conversion of hexafluorobenzene to bromopentafluorobenzene
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
FI970349A (en) 1997-01-28 1998-07-29 Borealis As New activator systems for metallocene compounds
IL132189A (en) 1997-04-03 2003-10-31 Univ Colorado State Res Found Polyhalogenated monoheteroborane anion compositions
US6420507B1 (en) * 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6319989B1 (en) * 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
WO1999015534A1 (en) 1997-09-19 1999-04-01 The Dow Chemical Company Modified alumoxane catalyst activator
ZA988572B (en) 1997-09-19 2000-03-22 Dow Chemical Co Narrow MWD, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom.
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
DE19744102A1 (en) 1997-10-06 1999-04-15 Targor Gmbh Metallocene catalyst system useful in (co)polyolefin production
ES2196835T3 (en) 1998-02-20 2003-12-16 Dow Global Technologies Inc CATALYTIC ACTIVATORS THAT INCLUDE EXPANDED ANIONS.
WO1999045042A1 (en) * 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Noncoordinating anions for olefin polymerization
US6827976B2 (en) 1998-04-29 2004-12-07 Unaxis Trading Ag Method to increase wear resistance of a tool or other machine component
DE69901451T2 (en) * 1998-08-11 2002-12-12 Dow Chemical Co ANSA TO (.MU.-ALUMINUM) -SUBSTITUED GROUP-4-METAL COMPLEXES
EP1104426B1 (en) * 1998-08-11 2002-08-14 The Dow Chemical Company Catalyst activator composition
MXPA01003978A (en) 1998-10-23 2003-06-06 Exxonmobil Chem Patents Inc Bridged metallocenes for olefin copolymerization.
JP2000129045A (en) * 1998-10-27 2000-05-09 Asahi Chem Ind Co Ltd Clean vessel made of polyethylene
ATE495205T1 (en) * 1998-11-02 2011-01-15 Dow Global Technologies Inc SHEER-FLUFFILIZABLE ETHYLENE/ALPHA-OLEFIN/DIENE POLYMERS AND THEIR PRODUCTION
AU2716700A (en) * 1998-12-31 2000-07-31 Homedics, Inc. Percussive massager
AU1919900A (en) * 1999-02-19 2000-09-04 Dow Chemical Company, The Process for preparing trifluoroarylaluminum etherates
US6420298B1 (en) * 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby
JP2001098028A (en) * 1999-09-29 2001-04-10 Japan Polychem Corp Polyethylene resin for medical and medical container
US6750302B1 (en) * 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
WO2002046249A2 (en) 2000-11-07 2002-06-13 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
ATE376005T1 (en) * 2000-12-04 2007-11-15 Univaton Technologies Llc POLYMERIZATION PROCESS
JP3549868B2 (en) * 2001-02-08 2004-08-04 三井化学株式会社 Ethylene polymer, method for producing the same, and molded article using the same
MY137183A (en) 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
AU2002310315A1 (en) 2001-07-23 2003-02-17 Dow Global Technologies, Inc. Salt of lewis acid/acid adducts and catalyst activators therefrom
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US6756455B2 (en) 2002-05-31 2004-06-29 Equistar Chemicals, Lp High-temperature solution process for polyolefin manufacture
US6794908B2 (en) * 2002-05-31 2004-09-21 Honeywell International Inc. Radiation-hard circuit
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
WO2005090426A1 (en) * 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US8263722B2 (en) * 2004-03-24 2012-09-11 Exxonmobil Chemical Patents Inc. Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
US20050288461A1 (en) 2004-06-25 2005-12-29 Jensen Michael D Polymerization catalysts for producing polymers with low levels of long chain branching
CA2479704C (en) * 2004-08-31 2013-08-13 Nova Chemicals Corporation High density homopolymer blends
WO2006052427A1 (en) * 2004-11-05 2006-05-18 Dow Global Technologies Inc. Highly soluble ferrocenyl compounds
KR100639696B1 (en) * 2005-07-01 2006-10-30 에스케이 주식회사 ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMERS OR ETHYLENE COPOLYMERS WITH alpha;-OLEFINS
KR101397337B1 (en) * 2006-05-17 2014-05-19 다우 글로벌 테크놀로지스 엘엘씨 High Efficiency Solution Polymerization Process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
US20050164872A1 (en) * 2002-04-24 2005-07-28 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2006020624A1 (en) * 2004-08-09 2006-02-23 Dow Global Technologies Inc. Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers

Also Published As

Publication number Publication date
KR101401785B1 (en) 2014-05-30
CN101490094A (en) 2009-07-22
AU2007254428A1 (en) 2007-11-29
KR101397337B1 (en) 2014-05-19
EP2024402A2 (en) 2009-02-18
CA2652551A1 (en) 2007-11-29
EP2024400B1 (en) 2012-09-12
US20120101241A1 (en) 2012-04-26
AR060640A1 (en) 2008-07-02
ES2475159T3 (en) 2014-07-10
KR20090026150A (en) 2009-03-11
KR101396058B1 (en) 2014-05-15
CN101484475A (en) 2009-07-15
KR101352674B1 (en) 2014-01-16
JP5623738B2 (en) 2014-11-12
JP2009537653A (en) 2009-10-29
US8058373B2 (en) 2011-11-15
MX2008014668A (en) 2009-01-26
KR20090024159A (en) 2009-03-06
EP2024399B1 (en) 2014-04-09
ES2534469T3 (en) 2015-04-23
RU2008149714A (en) 2010-06-27
CN102786619B (en) 2015-01-07
US20120108770A1 (en) 2012-05-03
KR101395970B1 (en) 2014-05-21
EP2787013A1 (en) 2014-10-08
WO2007136496A3 (en) 2008-01-31
JP5666129B2 (en) 2015-02-12
US8202953B2 (en) 2012-06-19
CN101472952B (en) 2012-10-03
WO2007136493A3 (en) 2008-01-10
EP2024402B1 (en) 2017-10-25
JP5583402B2 (en) 2014-09-03
MX2008014669A (en) 2009-01-26
US20110313119A1 (en) 2011-12-22
EP2492287A3 (en) 2012-11-07
CN104725535A (en) 2015-06-24
AR060639A1 (en) 2008-07-02
AR060638A1 (en) 2008-07-02
WO2007136494A2 (en) 2007-11-29
CA2652456A1 (en) 2007-11-29
WO2007136496A2 (en) 2007-11-29
WO2007136495A2 (en) 2007-11-29
JP2009537654A (en) 2009-10-29
ES2567140T3 (en) 2016-04-20
US20090312509A1 (en) 2009-12-17
AR060643A1 (en) 2008-07-02
AR060642A1 (en) 2008-07-02
EP2024400A2 (en) 2009-02-18
CN101484475B (en) 2013-04-03
BRPI0711029A2 (en) 2011-05-31
JP2009537656A (en) 2009-10-29
EP2021378B1 (en) 2016-03-09
US8349984B2 (en) 2013-01-08
EP2024403B1 (en) 2014-09-17
AR060641A1 (en) 2008-07-02
CA2652460A1 (en) 2007-11-29
KR101384380B1 (en) 2014-04-10
KR20090026149A (en) 2009-03-11
RU2450026C2 (en) 2012-05-10
CA2653534A1 (en) 2007-11-29
RU2008149709A (en) 2010-06-27
MX2008014671A (en) 2009-01-26
EP2024403A2 (en) 2009-02-18
ES2651590T5 (en) 2023-05-05
WO2007136506A2 (en) 2007-11-29
CA2652465A1 (en) 2007-11-29
KR20090027212A (en) 2009-03-16
EP2024399A2 (en) 2009-02-18
US20090299116A1 (en) 2009-12-03
EP2021378A2 (en) 2009-02-11
WO2007136497A3 (en) 2008-01-31
EP2492287B1 (en) 2017-05-31
ES2524779T3 (en) 2014-12-12
CN101490094B (en) 2013-06-26
CN101490096B (en) 2012-06-13
CN102786619A (en) 2012-11-21
ES2651590T3 (en) 2018-01-29
US8101696B2 (en) 2012-01-24
JP6001042B2 (en) 2016-10-05
EP2024401A2 (en) 2009-02-18
JP2009537657A (en) 2009-10-29
CN101472951A (en) 2009-07-01
ES2634440T3 (en) 2017-09-27
BRPI0711819A2 (en) 2011-12-13
KR20090026151A (en) 2009-03-11
RU2008149712A (en) 2010-06-27
US8354484B2 (en) 2013-01-15
WO2007136506A3 (en) 2008-01-24
CN101472952A (en) 2009-07-01
JP5645400B2 (en) 2014-12-24
JP5603595B2 (en) 2014-10-08
US20120088894A1 (en) 2012-04-12
US8299189B2 (en) 2012-10-30
MX2008014667A (en) 2009-01-26
CN101490095A (en) 2009-07-22
WO2007136493A2 (en) 2007-11-29
JP2015071786A (en) 2015-04-16
US20100036069A1 (en) 2010-02-11
WO2007136497A2 (en) 2007-11-29
ES2394225T3 (en) 2013-01-23
RU2008149711A (en) 2010-06-27
EP2492287A2 (en) 2012-08-29
US8450438B2 (en) 2013-05-28
EP2024402B2 (en) 2023-01-25
WO2007136494A3 (en) 2008-01-10
KR20090026147A (en) 2009-03-11
CN101472951B (en) 2014-07-02
CN101490096A (en) 2009-07-22
EP2024401B1 (en) 2015-02-25
BRPI0711018A8 (en) 2017-09-19
RU2463311C2 (en) 2012-10-10
JP2009537655A (en) 2009-10-29
SG158102A1 (en) 2010-01-29
BRPI0711018A2 (en) 2011-08-23

Similar Documents

Publication Publication Date Title
WO2007136495A3 (en) High efficiency solution polymerization process
WO2007092753A3 (en) Polymerization catalysts for producing polymers with low levels of long chain branching
WO2009045301A3 (en) Polymerization catalysts for producing polymers with low melt elasticity
WO2007115093A3 (en) Polymerization catalysts for producing polymers with low levels of long chain branching
EP1728553A3 (en) A catalytic composition comprising a neutral metal-pair complex and its preparation and use for preparing polymers from ethylenically unsaturated monomers
DE602005006949D1 (en) Double catalyst on a common carrier
ATE350173T1 (en) EXTRUSION COATING
WO2009064452A3 (en) Ethylene polymers
TW200704651A (en) Process for production of propylene copolymers
WO2007080365A3 (en) Supported catalyst system
WO2006004789A3 (en) Polymerization catalysts for producing polymers with low levels of long chain branching
WO2006004709A3 (en) Polymerization catalysts for producing polymers with low levels of long chain branching
MY152947A (en) Dual metallocene catalysts for polymerization of bimodal polymers
HK1113583A1 (en) Catalysts for olefin polymerization
ES2250736T3 (en) THERMOPLASTIC ELASTOMEROS AND PROCEDURE TO MANUFACTURE THEM.
BR0317830A (en) Processes for transitioning between metallocene polymerization catalysts and ziegler-natta
WO2012092491A3 (en) Compositions, methods of making the same, and articles prepared from the same
EP2392611A3 (en) Functionalized ethylene/alpha-olefin interpolymer compositions
WO2004060921A3 (en) Processes for transitioning between various polymerization catalysts
EP1471085A4 (en) Non-rigid propylene resin composition
WO2008036591A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2003087177A3 (en) Ethylene-styrene copolymers, complexes and catalysts with phenol-triazole ligands and processes for polymerizing therewith
WO2008011269A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
DK1994006T3 (en) Polymerization of ethylene and alpha-olefins with imino-quinolinol complexes
TW200615288A (en) ANSA-metallocene compound, process of preparing the same, and process of preparing polyolefin using the same

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780025953.1

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07755919

Country of ref document: EP

Kind code of ref document: A2

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: MX/A/2008/014671

Country of ref document: MX

Ref document number: 2007755919

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2009510951

Country of ref document: JP

Ref document number: 2652460

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 1020087030632

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2008149712

Country of ref document: RU

WWE Wipo information: entry into national phase

Ref document number: 12300859

Country of ref document: US

ENP Entry into the national phase

Ref document number: PI0711029

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20081117