WO2006065369A3 - Photocurable michael addition polymers - Google Patents

Photocurable michael addition polymers Download PDF

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Publication number
WO2006065369A3
WO2006065369A3 PCT/US2005/039099 US2005039099W WO2006065369A3 WO 2006065369 A3 WO2006065369 A3 WO 2006065369A3 US 2005039099 W US2005039099 W US 2005039099W WO 2006065369 A3 WO2006065369 A3 WO 2006065369A3
Authority
WO
WIPO (PCT)
Prior art keywords
michael addition
photocurable
addition polymers
component
michael
Prior art date
Application number
PCT/US2005/039099
Other languages
French (fr)
Other versions
WO2006065369A2 (en
Inventor
Duane D Fansler
Kevin M Lewandowski
Babu N Gaddam
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to AT05820205T priority Critical patent/ATE503774T1/en
Priority to DE602005027241T priority patent/DE602005027241D1/en
Priority to EP05820205A priority patent/EP1819737B1/en
Priority to JP2007545465A priority patent/JP2008523205A/en
Priority to CN2005800425335A priority patent/CN101076545B/en
Publication of WO2006065369A2 publication Critical patent/WO2006065369A2/en
Publication of WO2006065369A3 publication Critical patent/WO2006065369A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/02—Addition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C08F220/303—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety and one or more carboxylic moieties in the chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/104—Esters of polyhydric alcohols or polyhydric phenols of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/135—Cross-linked structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/76—Post-treatment crosslinking
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group
    • Y10S522/905—Benzophenone group

Abstract

A curable composition is described comprising a Michael donor component, a polyacryl component, and a monoacryl component, where at least one of the Michael donor or monoacryl components comprises a pendent photoinitiator group. A Michael addition polymer that is the Michael addition reaction product of these components is also described.
PCT/US2005/039099 2004-12-10 2005-10-28 Photocurable michael addition polymers WO2006065369A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AT05820205T ATE503774T1 (en) 2004-12-10 2005-10-28 PHOTOCUREABLE MICHAEL ADDITION POLYMERS
DE602005027241T DE602005027241D1 (en) 2004-12-10 2005-10-28 Photohärtbare michaeladditionspolymere
EP05820205A EP1819737B1 (en) 2004-12-10 2005-10-28 Photocurable michael addition polymers
JP2007545465A JP2008523205A (en) 2004-12-10 2005-10-28 Photocurable Michael addition polymer
CN2005800425335A CN101076545B (en) 2004-12-10 2005-10-28 Photohardenable michael adduct polymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/009,588 2004-12-10
US11/009,588 US7307106B2 (en) 2004-12-10 2004-12-10 Photocurable Michael addition polymers

Publications (2)

Publication Number Publication Date
WO2006065369A2 WO2006065369A2 (en) 2006-06-22
WO2006065369A3 true WO2006065369A3 (en) 2006-08-03

Family

ID=36584900

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/039099 WO2006065369A2 (en) 2004-12-10 2005-10-28 Photocurable michael addition polymers

Country Status (8)

Country Link
US (1) US7307106B2 (en)
EP (1) EP1819737B1 (en)
JP (1) JP2008523205A (en)
KR (1) KR20070093097A (en)
CN (1) CN101076545B (en)
AT (1) ATE503774T1 (en)
DE (1) DE602005027241D1 (en)
WO (1) WO2006065369A2 (en)

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US6992217B2 (en) * 2002-12-11 2006-01-31 3M Innovative Properties Company Ring-opened azlactone initiators for atom transfer radical polymerization
CA2563358A1 (en) * 2004-04-21 2005-11-17 Ashland Licensing And Intellectual Property Llc Radiation-curable michael addition resins having built-in photoinitiators
EP1954748B1 (en) * 2005-11-30 2018-09-26 Ashland Licensing and Intellectual Property LLC Prepregs and cured in place solid surfaces prepared therefrom
EP2024427A4 (en) * 2006-06-05 2012-03-21 Henkel Corp Retortable radiation-cured coatings for plastic film and metallic foil substrates
US7411033B2 (en) * 2006-06-16 2008-08-12 Ppg Industries Ohio, Inc. Vinyl ethers and compositions containing them
US7745007B2 (en) * 2006-10-31 2010-06-29 S.D. Warren Company Release sheets and methods of making the same
US7705064B2 (en) * 2007-07-23 2010-04-27 Henkel Corporation Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same
TW201029966A (en) * 2008-11-17 2010-08-16 Bayer Materialscience Llc Biofilm-inhibitory coatings that release salicylic acid by hydrolisis
KR101355901B1 (en) 2009-06-29 2014-01-28 디아이씨 가부시끼가이샤 Michael addition reaction product and active energy ray-curable composition
MY168751A (en) 2012-03-09 2018-11-30 Polynt Composites Usa Inc Acetoacetyl thermosetting resin for zero voc gel coat
JP6183642B2 (en) 2012-08-10 2017-08-23 株式会社リコー Actinic ray curable composition, actinic ray curable ink composition for inkjet printing using the same, and actinic ray curable adhesive composition
CN105348466A (en) * 2015-10-29 2016-02-24 湖南汇田高分子科技有限公司 Preparation method of water-soluble ultraviolet light self-curing amino resin
CN110105799B (en) 2019-05-07 2021-10-01 广东华润涂料有限公司 Coating composition for woodware and woodware made of the same

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WO2005108452A2 (en) * 2004-04-21 2005-11-17 Ashland Licensing And Intellectual Property Llc Radiation-curable michael addition resins having built-in photoinitiators

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Also Published As

Publication number Publication date
JP2008523205A (en) 2008-07-03
US7307106B2 (en) 2007-12-11
US20060128825A1 (en) 2006-06-15
CN101076545A (en) 2007-11-21
EP1819737A2 (en) 2007-08-22
WO2006065369A2 (en) 2006-06-22
DE602005027241D1 (en) 2011-05-12
CN101076545B (en) 2011-03-02
ATE503774T1 (en) 2011-04-15
EP1819737B1 (en) 2011-03-30
KR20070093097A (en) 2007-09-17

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