WO2005055248A3 - Organic semiconducting layer formulations comprising polyacenes and organic binder polymers - Google Patents

Organic semiconducting layer formulations comprising polyacenes and organic binder polymers Download PDF

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Publication number
WO2005055248A3
WO2005055248A3 PCT/GB2004/004973 GB2004004973W WO2005055248A3 WO 2005055248 A3 WO2005055248 A3 WO 2005055248A3 GB 2004004973 W GB2004004973 W GB 2004004973W WO 2005055248 A3 WO2005055248 A3 WO 2005055248A3
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WO
WIPO (PCT)
Prior art keywords
group
optionally substituted
optionally
organic
polyacene
Prior art date
Application number
PCT/GB2004/004973
Other languages
French (fr)
Other versions
WO2005055248A2 (en
Inventor
Beverley Anne Brown
Janos Veres
Remi Manouk Anemian
Richard Thomas Williams
Simon Dominic Ogier
Stephen William Leeming
Original Assignee
Avecia Ltd
Beverley Anne Brown
Janos Veres
Remi Manouk Anemian
Richard Thomas Williams
Simon Dominic Ogier
Stephen William Leeming
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0327654A external-priority patent/GB0327654D0/en
Priority claimed from GB0407852A external-priority patent/GB0407852D0/en
Priority claimed from GB0414347A external-priority patent/GB0414347D0/en
Priority to US10/580,552 priority Critical patent/US7842942B2/en
Priority to JP2006540612A priority patent/JP5089986B2/en
Priority to AT04819715T priority patent/ATE475971T1/en
Priority to DE602004028399T priority patent/DE602004028399D1/en
Priority to EP04819715A priority patent/EP1687830B1/en
Application filed by Avecia Ltd, Beverley Anne Brown, Janos Veres, Remi Manouk Anemian, Richard Thomas Williams, Simon Dominic Ogier, Stephen William Leeming filed Critical Avecia Ltd
Publication of WO2005055248A2 publication Critical patent/WO2005055248A2/en
Publication of WO2005055248A3 publication Critical patent/WO2005055248A3/en
Priority to KR1020067010374A priority patent/KR101217963B1/en
Priority to US11/671,877 priority patent/US7807993B2/en
Priority to US11/822,594 priority patent/US7576208B2/en
Priority to US12/719,545 priority patent/US8119804B2/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/0805Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/081Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06Copolymers with vinyl aromatic monomers
    • HELECTRICITY
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/40Organosilicon compounds, e.g. TIPS pentacene
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/615Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
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    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/615Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
    • H10K85/623Polycyclic condensed aromatic hydrocarbons, e.g. anthracene containing five rings, e.g. pentacene
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/615Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
    • H10K85/624Polycyclic condensed aromatic hydrocarbons, e.g. anthracene containing six or more rings
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
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    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6574Polycyclic condensed heteroaromatic hydrocarbons comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes
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    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6576Polycyclic condensed heteroaromatic hydrocarbons comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having a potential-jump barrier or a surface barrier
    • H10K10/40Organic transistors
    • H10K10/46Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462Insulated gate field-effect transistors [IGFETs]
    • H10K10/484Insulated gate field-effect transistors [IGFETs] characterised by the channel regions
    • H10K10/488Insulated gate field-effect transistors [IGFETs] characterised by the channel regions the channel region comprising a layer of composite material having interpenetrating or embedded materials, e.g. a mixture of donor and acceptor moieties, that form a bulk heterojunction
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    • H10K50/00Organic light-emitting devices
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    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
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    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/115Polyfluorene; Derivatives thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/631Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60Organic compounds having low molecular weight
    • H10K85/649Aromatic compounds comprising a hetero atom
    • H10K85/657Polycyclic condensed heteroaromatic hydrocarbons
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

An organic semiconducting layer formulation, which comprises: an organic binder which has a permittivity, ϵ, at 1,000 Hz of 3.3 or less; and a polyacene compound of Formula: (A) wherein: each of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12, which may be the same or different, independently represents hydrogen; an optionally substituted C1-C40 carbyl or hydrocarbyl group; an optionally substituted C1-C40 alkoxy group; an optionally substituted C6-C40 aryloxy group; an optionally substituted C7-C40 alkylaryloxy group; an optionally substituted C2-C40 alkoxycarbonyl group; an optionally substituted C7-C40 aryloxycarbonyl group; a cyano group (-CN); a carbamoyl group (-C(=O)NH2); a haloformyl group (-C(=O)-X, wherein X represents a halogen atom); a formyl group (-C(=O)-H); an isocyano group; an isocyanate group; a thiocyanate group or a thioisocyanate group; an optionally substituted amino group; a hydroxy group; a nitro group; a CF3 group; a halo group (CI, Br, F); or an optionally substituted silyl group; and wherein independently each pair of R2 and R3 and/or R8 and R9, may be cross-bridged to form a C4-C40 saturated or unsaturated ring, which saturated or unsaturated ring may be intervened by an oxygen atom, a sulphur atom or a group shown by formula -N(Ra)- (wherein Ra is a hydrogen atom or an optionally substituted hydrocarbon group), or may optionally be substituted; and wherein one or more of the carbon atoms of the polyacene skeleton may optionally be substituted by a heteroatom selected from N, P, As, O, S, Se and Te; and wherein independently any two or more of the substituents R1-R12 which are located on adjacent ring positions of the polyacene may, together, optionally constitute a further C4-C40 saturated or unsaturated ring optionally interrupted by O, S or -N(Ra) where Ra is as defined above) or an aromatic ring system, fused to the polyacene; and wherein n is 0, 1, 2, 3 or 4, also claimed is an electronic device, particularly an organic field effect transistor comprising the organic semiconductor layer formulation.
PCT/GB2004/004973 2003-11-28 2004-11-25 Organic semiconducting layer formulations comprising polyacenes and organic binder polymers WO2005055248A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US10/580,552 US7842942B2 (en) 2003-11-28 2004-11-25 Organic semiconducting layers
JP2006540612A JP5089986B2 (en) 2003-11-28 2004-11-25 Organic semiconductor layer and its improvement
AT04819715T ATE475971T1 (en) 2003-11-28 2004-11-25 ORGANIC SEMICONDUCTOR LAYER FORMULATIONS WITH POLYACENES AND ORGANIC BINDER POLYMERS
DE602004028399T DE602004028399D1 (en) 2003-11-28 2004-11-25 ORGANIC SEMICONDUCTOR LAYER FORMULATIONS WITH POLYACENES AND ORGANIC BINDER POLYMERS
EP04819715A EP1687830B1 (en) 2003-11-28 2004-11-25 Organic semiconducting layer formulations comprising polyacenes and organic binder polymers
KR1020067010374A KR101217963B1 (en) 2003-11-28 2006-05-26 Improvements in and relating to organic semiconducting layers
US11/671,877 US7807993B2 (en) 2003-11-28 2007-02-06 Organic pentacene semiconducting layers
US11/822,594 US7576208B2 (en) 2003-11-28 2007-07-09 Organic semiconductor layers
US12/719,545 US8119804B2 (en) 2003-11-28 2010-03-08 Organic semiconducting layers

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB0327654A GB0327654D0 (en) 2003-11-28 2003-11-28 Improvements in and relating to organic semiconducting layers
GB0327654.0 2003-11-28
GB0407852A GB0407852D0 (en) 2004-04-07 2004-04-07 Improvements in and relating to organic semi-conducting layers
GB0407852.3 2004-04-07
GB0414347.5 2004-06-26
GB0414347A GB0414347D0 (en) 2004-06-26 2004-06-26 Improvements in and relating to organic semiconducting layers

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US10/580,552 A-371-Of-International US7842942B2 (en) 2003-11-28 2004-11-25 Organic semiconducting layers
US11/671,877 Division US7807993B2 (en) 2003-11-28 2007-02-06 Organic pentacene semiconducting layers
US11/822,594 Division US7576208B2 (en) 2003-11-28 2007-07-09 Organic semiconductor layers

Publications (2)

Publication Number Publication Date
WO2005055248A2 WO2005055248A2 (en) 2005-06-16
WO2005055248A3 true WO2005055248A3 (en) 2005-07-28

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PCT/GB2004/004973 WO2005055248A2 (en) 2003-11-28 2004-11-25 Organic semiconducting layer formulations comprising polyacenes and organic binder polymers

Country Status (8)

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US (4) US7842942B2 (en)
EP (3) EP1808866A1 (en)
JP (2) JP5089986B2 (en)
KR (1) KR101217963B1 (en)
AT (1) ATE475971T1 (en)
DE (1) DE602004028399D1 (en)
TW (1) TWI358144B (en)
WO (1) WO2005055248A2 (en)

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