WO2004039870A3 - Size for glass fibers and use thereof in cation exchange membranes - Google Patents

Size for glass fibers and use thereof in cation exchange membranes Download PDF

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Publication number
WO2004039870A3
WO2004039870A3 PCT/DE2003/003429 DE0303429W WO2004039870A3 WO 2004039870 A3 WO2004039870 A3 WO 2004039870A3 DE 0303429 W DE0303429 W DE 0303429W WO 2004039870 A3 WO2004039870 A3 WO 2004039870A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
layer
size
cation exchange
glass fibers
Prior art date
Application number
PCT/DE2003/003429
Other languages
German (de)
French (fr)
Other versions
WO2004039870A2 (en
Inventor
Verena Graf
Stefan Lotz
Thomas Soczka-Guth
Original Assignee
Daimler Chrysler Ag
Verena Graf
Stefan Lotz
Thomas Soczka-Guth
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10250314A external-priority patent/DE10250314A1/en
Application filed by Daimler Chrysler Ag, Verena Graf, Stefan Lotz, Thomas Soczka-Guth filed Critical Daimler Chrysler Ag
Priority to AU2003277822A priority Critical patent/AU2003277822A1/en
Publication of WO2004039870A2 publication Critical patent/WO2004039870A2/en
Publication of WO2004039870A3 publication Critical patent/WO2004039870A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/40—Organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

The invention relates to a reinforced polymer membrane comprising at least one polymer layer that is based on at least one polymer having acid properties and at least one layer of reinforcement material having alkaline properties. At least one outer surface of the polymer layer is in contact with an outer surface of the layer of reinforcement material so as to adhere thereto, the adhesion being based on a mutual electrostatic effect. The invention further relates to a method for reinforcing a polymer membrane, the use of reinforced polymer membranes, and fuel cells, especially polymer electrolyte membrane fuel cells, comprising at least one inventive reinforced polymer membrane.
PCT/DE2003/003429 2002-10-29 2003-10-16 Size for glass fibers and use thereof in cation exchange membranes WO2004039870A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003277822A AU2003277822A1 (en) 2002-10-29 2003-10-16 Size for glass fibers and use thereof in cation exchange membranes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10250314.1 2002-10-29
DE10250314A DE10250314A1 (en) 2002-10-29 2002-10-29 Reinforced polymer membrane, used as electrolyte membrane in fuel cell or as dialysis or separation membrane, has acid polymer and basic reinforcement layers adhering by electrostatic interaction

Publications (2)

Publication Number Publication Date
WO2004039870A2 WO2004039870A2 (en) 2004-05-13
WO2004039870A3 true WO2004039870A3 (en) 2004-07-01

Family

ID=32114909

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2003/003429 WO2004039870A2 (en) 2002-10-29 2003-10-16 Size for glass fibers and use thereof in cation exchange membranes

Country Status (3)

Country Link
AU (1) AU2003277822A1 (en)
DE (1) DE10262007A1 (en)
WO (1) WO2004039870A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1756887A2 (en) * 2004-06-16 2007-02-28 Itm Fuel Cells Limited Membrane electrode assembly with controlled water management/ion flow
DE102004063030A1 (en) * 2004-12-28 2006-08-17 Johannes-Gutenberg-Universität Mainz Multilayer system, process for its production and its use in electro-optical components
CN102605552B (en) * 2012-02-17 2014-04-02 山东大学 Method for preparing nitrogen-doped nanometer TiO2 fiber cloth

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3193429A (en) * 1952-05-12 1965-07-06 Bjorksten Res Lab Inc Method of making a laminate of silane treated glass fibers
US4500600A (en) * 1977-04-25 1985-02-19 Owens-Corning Fiberglas Corporation Size composition for glass fibers
RO93609A2 (en) * 1985-11-18 1988-02-29 Combinatul Chimic"Victoria",Ro PROCEDURE FOR TREATMENT OF GLASS FIRE FABRICS
US5066361A (en) * 1990-05-15 1991-11-19 Jonathan Scharf Method and product for improved glass fiber reinforced and filled thermoplastic and thermosetting resin systems
WO2000023510A1 (en) * 1998-10-16 2000-04-27 Johnson Matthey Public Limited Company Substrate
WO2000073235A1 (en) * 1999-05-28 2000-12-07 Bayer Aktiengesellschaft Sizing composition, sized glass fibers and their use
US20020064700A1 (en) * 1999-07-21 2002-05-30 Asahi Glass Company Limited Solid polymer electrolyte fuel cell and method of its production
US20030087972A1 (en) * 2000-02-23 2003-05-08 Takumi Taniguchi Polymer electrolyte membrane and method of production thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3193429A (en) * 1952-05-12 1965-07-06 Bjorksten Res Lab Inc Method of making a laminate of silane treated glass fibers
US4500600A (en) * 1977-04-25 1985-02-19 Owens-Corning Fiberglas Corporation Size composition for glass fibers
RO93609A2 (en) * 1985-11-18 1988-02-29 Combinatul Chimic"Victoria",Ro PROCEDURE FOR TREATMENT OF GLASS FIRE FABRICS
US5066361A (en) * 1990-05-15 1991-11-19 Jonathan Scharf Method and product for improved glass fiber reinforced and filled thermoplastic and thermosetting resin systems
WO2000023510A1 (en) * 1998-10-16 2000-04-27 Johnson Matthey Public Limited Company Substrate
WO2000073235A1 (en) * 1999-05-28 2000-12-07 Bayer Aktiengesellschaft Sizing composition, sized glass fibers and their use
US20020064700A1 (en) * 1999-07-21 2002-05-30 Asahi Glass Company Limited Solid polymer electrolyte fuel cell and method of its production
US20030087972A1 (en) * 2000-02-23 2003-05-08 Takumi Taniguchi Polymer electrolyte membrane and method of production thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198830, Derwent World Patents Index; AN 1988-210947, XP002277310 *

Also Published As

Publication number Publication date
AU2003277822A8 (en) 2004-05-25
DE10262007A1 (en) 2004-05-19
AU2003277822A1 (en) 2004-05-25
WO2004039870A2 (en) 2004-05-13

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