WO2003106758A3 - Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non - Google Patents

Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non Download PDF

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Publication number
WO2003106758A3
WO2003106758A3 PCT/FR2003/001835 FR0301835W WO03106758A3 WO 2003106758 A3 WO2003106758 A3 WO 2003106758A3 FR 0301835 W FR0301835 W FR 0301835W WO 03106758 A3 WO03106758 A3 WO 03106758A3
Authority
WO
WIPO (PCT)
Prior art keywords
optionally
pos
emulsion
adherence promoter
units
Prior art date
Application number
PCT/FR2003/001835
Other languages
English (en)
Other versions
WO2003106758A2 (fr
Inventor
Laurent Dumont
Michel Feder
Francis Lafaysse
Sylvie Robelin
Original Assignee
Rhodia Chimie Sa
Laurent Dumont
Michel Feder
Francis Lafaysse
Sylvie Robelin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa, Laurent Dumont, Michel Feder, Francis Lafaysse, Sylvie Robelin filed Critical Rhodia Chimie Sa
Priority to AU2003258809A priority Critical patent/AU2003258809A1/en
Priority to JP2004513557A priority patent/JP4563173B2/ja
Priority to AT03760053T priority patent/ATE536438T1/de
Priority to US10/518,401 priority patent/US20060122323A1/en
Priority to EP03760053A priority patent/EP1513979B1/fr
Publication of WO2003106758A2 publication Critical patent/WO2003106758A2/fr
Publication of WO2003106758A3 publication Critical patent/WO2003106758A3/fr
Priority to US12/068,128 priority patent/US7935386B2/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/40—Organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

Abstract

La présente invention concerne une émulsion aqueuse de polyorganosiloxane (POS), pour le revêtement de supports tissés (textiles) ou non tissés, destinée à produire un élastomère après réticulation en couche mince, ainsi qu'à un procédé de revêtement correspondant et aux supports ainsi revêtus. Le but visé est de fournir une émulsion dotée de propriétés rhéologiques telles qu'elle puisse être aisément déposée/appliquée sur le support fibreux, à grande vitesse, et selon des taux de dépôt limités, par exemple inférieurs à 40 g/m². Pour atteindre ce but, l'émulsion revendiquée comprend A) un POS à motifs =SiVinyle, (B) un POS à motifs =SiH, (C) un promoteur d'adhérence spécial, (D) un catalyseur, (E) au moins un tensioactif, (F) éventuellement une résine POS à motifs =SiVinyle, (G) éventuellement un inhibiteur de réticulation, (H) éventuellement un agent de fixation du pH,(I) éventuellement un additif de formulation, (J) éventuellement une charge, (K) et de l'eau, le promoteur d'adhérence (C) étant choisi dans le groupe de composés comprenant les hydrocolloïdes protecteurs, les silanes et/ou les POS hydroxylés porteurs par molécule d'au moins un groupement hydroxyle et d'au moins une fonction aminée et salifiée, et leurs mélanges, avec la condition selon laquelle le pourcentage en poids du promoteur d'adhérence (C) par rapport à la phase silicone est strictement situé dans l'intervalle allant de 0,005 à 10 %, de préférence de 0,03 à 5 % et plus préférentiellement encore de 0,05 à 4 %.
PCT/FR2003/001835 2002-06-18 2003-06-17 Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non WO2003106758A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2003258809A AU2003258809A1 (en) 2002-06-18 2003-06-17 Aqueous silicone emulsion for coating woven or nonwoven textile substrates
JP2004513557A JP4563173B2 (ja) 2002-06-18 2003-06-17 製織又は不織繊維質基材を被覆するための水性シリコーンエマルジョン
AT03760053T ATE536438T1 (de) 2002-06-18 2003-06-17 Wässrige silikonemulsion zur beschichtung von gewebten oder nichtgewebten faserigen substraten
US10/518,401 US20060122323A1 (en) 2002-06-18 2003-06-17 Aqueous silicone emulsion for coating woven or non-woven fibrous substrates
EP03760053A EP1513979B1 (fr) 2002-06-18 2003-06-17 Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non
US12/068,128 US7935386B2 (en) 2002-06-18 2008-02-01 Aqueous silicone emulsion for coating woven or non-woven fibrous substrates

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR02/07498 2002-06-18
FR0207498A FR2840912B1 (fr) 2002-06-18 2002-06-18 Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US10518401 A-371-Of-International 2003-06-17
US12/068,128 Continuation US7935386B2 (en) 2002-06-18 2008-02-01 Aqueous silicone emulsion for coating woven or non-woven fibrous substrates

Publications (2)

Publication Number Publication Date
WO2003106758A2 WO2003106758A2 (fr) 2003-12-24
WO2003106758A3 true WO2003106758A3 (fr) 2004-04-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2003/001835 WO2003106758A2 (fr) 2002-06-18 2003-06-17 Emulsion silicone aqueuse pour le revetement de supports fibreux tisses ou non

Country Status (8)

Country Link
US (2) US20060122323A1 (fr)
EP (1) EP1513979B1 (fr)
JP (2) JP4563173B2 (fr)
CN (1) CN100335712C (fr)
AT (1) ATE536438T1 (fr)
AU (1) AU2003258809A1 (fr)
FR (1) FR2840912B1 (fr)
WO (1) WO2003106758A2 (fr)

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EP1078823A2 (fr) * 1999-08-24 2001-02-28 Shin-Etsu Chemical Co., Ltd. Composition de revêtement de caoutchouc de polysiloxane liquide et tissu pour sac gonflable

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US20080207827A1 (en) 2008-08-28
CN100335712C (zh) 2007-09-05
ATE536438T1 (de) 2011-12-15
FR2840912A1 (fr) 2003-12-19
EP1513979B1 (fr) 2011-12-07
AU2003258809A8 (en) 2003-12-31
FR2840912B1 (fr) 2005-10-21
JP4563173B2 (ja) 2010-10-13
EP1513979A2 (fr) 2005-03-16
US7935386B2 (en) 2011-05-03
JP2009215697A (ja) 2009-09-24
WO2003106758A2 (fr) 2003-12-24
US20060122323A1 (en) 2006-06-08
CN1671916A (zh) 2005-09-21
AU2003258809A1 (en) 2003-12-31
JP2005530052A (ja) 2005-10-06

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