WO2001046278A3 - Adhesive alpha-olefin inter-polymers - Google Patents

Adhesive alpha-olefin inter-polymers Download PDF

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Publication number
WO2001046278A3
WO2001046278A3 PCT/US2000/035016 US0035016W WO0146278A3 WO 2001046278 A3 WO2001046278 A3 WO 2001046278A3 US 0035016 W US0035016 W US 0035016W WO 0146278 A3 WO0146278 A3 WO 0146278A3
Authority
WO
WIPO (PCT)
Prior art keywords
alpha
polymers
olefin
polymer
adhesive
Prior art date
Application number
PCT/US2000/035016
Other languages
French (fr)
Other versions
WO2001046278A2 (en
Inventor
Anthony George Karandinos
David J Lohse
Olivier J F Georjon
Kenneth Lewtas
Jean M Tancrede
Bruce A Harrington
Keith A Nelson
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to CA002414498A priority Critical patent/CA2414498C/en
Priority to EP00986700A priority patent/EP1263815B1/en
Priority to DE60034151T priority patent/DE60034151T2/en
Priority to AU22891/01A priority patent/AU780051B2/en
Publication of WO2001046278A2 publication Critical patent/WO2001046278A2/en
Publication of WO2001046278A3 publication Critical patent/WO2001046278A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Abstract

The invention relates to novel adhesive alpha-olefin inter-polymers which are largely amorphous and have a rheological behavior that makes them suitable for adhesive use, both without and with minimized amounts of tackifying resins. Specifically, the invention poly-alpha olefin inter-polymer may be composed of A) from 60 to 94 % of units derived from one alpha mono-olefin having from 3 to 6 carbon atoms and B) from 6 to 40 mol % of units derived from one or more other mono-olefins having from 4 to 10 carbon atoms and at least one carbon atom more than A); and C) optionally from 0 to 10 mol % of units derived from another copolymerizable unsaturated hydrocarbon, different from A) and B); the diad distribution of component A in the polymer as determined by 13C NMR as described herein showing a ratio of experimentally determined diad distribution over the calculated Bernoullian diad distribution of less than 1.07; and the storage modulus G' of said polymer, determined upon cooling as described herein, intersecting a value of 3.105 Pa at a temperature of less than 85 °C. The invention also describes polymerization processes suitable for the manufacture of these adhesive alpha-olefin inter-polymers.
PCT/US2000/035016 1999-12-21 2000-12-21 Adhesive alpha-olefin inter-polymers WO2001046278A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002414498A CA2414498C (en) 1999-12-21 2000-12-21 Adhesive alpha-olefin inter-polymers
EP00986700A EP1263815B1 (en) 1999-12-22 2000-12-21 Adhesive alpha-olefin inter-polymers
DE60034151T DE60034151T2 (en) 1999-12-21 2000-12-21 ADHESIVES BASED ON ALPHA OLEFIN POLYMERS
AU22891/01A AU780051B2 (en) 1999-12-21 2000-12-21 Adhesive alpha-olefin inter-polymers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US60/171,715 1999-12-21
US17171599P 1999-12-22 1999-12-22
US19909300P 2000-04-21 2000-04-21
US60/199,093 2000-04-21

Publications (2)

Publication Number Publication Date
WO2001046278A2 WO2001046278A2 (en) 2001-06-28
WO2001046278A3 true WO2001046278A3 (en) 2002-08-15

Family

ID=26867350

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2000/035000 WO2001046277A2 (en) 1999-12-22 2000-12-21 Polypropylene-based adhesive compositions
PCT/US2000/035016 WO2001046278A2 (en) 1999-12-21 2000-12-21 Adhesive alpha-olefin inter-polymers

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2000/035000 WO2001046277A2 (en) 1999-12-22 2000-12-21 Polypropylene-based adhesive compositions

Country Status (13)

Country Link
US (4) US6627723B2 (en)
EP (3) EP1263909A2 (en)
JP (1) JP4966463B2 (en)
KR (1) KR100718424B1 (en)
CN (1) CN1333032C (en)
AT (1) ATE358144T1 (en)
AU (2) AU780051B2 (en)
BR (1) BR0016618B1 (en)
CA (2) CA2395532A1 (en)
DE (1) DE60034151T2 (en)
ES (1) ES2282158T3 (en)
MX (1) MXPA02006199A (en)
WO (2) WO2001046277A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
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US8957159B2 (en) 2002-10-15 2015-02-17 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US9593235B2 (en) 2013-02-15 2017-03-14 H.B. Fuller Company Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same

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