WO2001035915A1 - Cosmetic hair composition providing good resistance properties and comprising polyurethanes - Google Patents
Cosmetic hair composition providing good resistance properties and comprising polyurethanes Download PDFInfo
- Publication number
- WO2001035915A1 WO2001035915A1 PCT/FR2000/003149 FR0003149W WO0135915A1 WO 2001035915 A1 WO2001035915 A1 WO 2001035915A1 FR 0003149 W FR0003149 W FR 0003149W WO 0135915 A1 WO0135915 A1 WO 0135915A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- film
- composition
- polyurethanes
- cosmetic
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the subject of the invention is a cosmetic composition
- a cosmetic composition comprising, in a cosmetically acceptable medium, at least one polyurethane (A) with particular characteristics. It also relates to a process for shaping or maintaining hair using this composition, as well as its use for the formulation of hair cosmetic products, such as styling products such as hairsprays, sprays or mousses, in order to obtain the maintenance or shaping of the hairstyle.
- hair cosmetic products such as styling products such as hairsprays, sprays or mousses
- compositions for spraying in an aerosol or in a pump bottle such as lacquers, sprays or foams, essentially consisting of a more often alcoholic or hydroalcoholic and of a film-forming polymer soluble in water or in alcohol, mixed with various cosmetic adjuvants.
- these hair formulations such as mousses, gels and especially sprays and aerosol lacquers intended to maintain the shape of the hairstyle do not yet allow the hairstyle to resist satisfactorily the various natural movements of life such as walking, head movements or gusts of wind.
- the polymers used for the formulation of these hair products are anionic, amphoteric or nonionic film-forming polymers, which lead to the formation of films having a more or less hard and brittle nature.
- the percentage of elongation at break measured on the film is low, that is to say generally less than 2% and the holding of the hairstyle is not ensured over time.
- these polymers have already been mixed with plasticizers and obtained more flexible and non-friable coatings.
- these films are deformable and plastic, that is to say that after deformation, they recover very little of their initial shape. If the holding of the hairstyle is improved, it is not yet satisfactory since the shape of the hairstyle changes over time.
- compositions comprising a combination of film-forming polymers, such as for example a polyvinylcaprolactam polymer and an acrylic polymer.
- film-forming polymers such as for example a polyvinylcaprolactam polymer and an acrylic polymer.
- these compositions are not yet entirely satisfactory, insofar as the hair loses some of its natural cosmetic properties.
- Cosmetic compositions are therefore sought, in particular for maintaining and / or fixing the hairstyle which provides the hair, in addition to lasting fixation, with good cosmetic properties, in particular good disentangling, softness and a pleasant appearance.
- the subject of the invention is a cosmetic composition
- a cosmetic composition comprising, in a cosmetically acceptable medium, at least one film-forming polyurethane (A) chosen such that the material obtained by drying this polymer in an aqueous or alcoholic medium, at ambient temperature and at a relative humidity of 50%, has a mechanical profile defined by at least:
- Another object of the present invention relates to a method of shaping or maintaining the hairstyle comprising the use of this composition.
- Yet another object of the present invention relates to the use of this composition for the manufacture of hair cosmetic compositions, with a view to obtaining maintenance or shaping of the hairstyle.
- the polyurethanes (N) particularly targeted by the present invention are those distributed by Sanyo under the name PA Marin UA310 and PA Marin UA200, as well as the polyurethane marketed by Zeneca under the name ⁇ eorez R987.
- the PN Marin UA200 and ⁇ eroez R987 polyurethanes are polyether polyurethanes, and the PA Marin UA310 polyurethane is a carbonate polyurethane.
- the term film obtained by drying at room temperature (22 ⁇ 2 ° C) and at a relative humidity level of 50% ⁇ 5% means the film obtained under these conditions from a mixture with 6% of active material (ma) of polymer N with ethanol or water, the quantity of mixture being adapted to obtain, in a Teflon matrix, a film with a thickness of 500 ⁇ 50 ⁇ . Drying is continued until the weight of the film no longer changes, which represents approximately 12 days.
- the polymers N which are soluble or partially soluble in ethanol are tested in ethanol.
- the other polymers are tested in water in soluble or dispersed form.
- the film is cut into test pieces of rectangular shape, length 80 mm and width 15 mm:
- the tests are carried out on a device marketed under the name Lloyd or marketed under the name Zwick under the same temperature conditions and humidity only for drying, i.e. a temperature of 22 ⁇ 2 ° C and a relative humidity of 50 ⁇ 5%.
- test pieces are drawn at a speed of 20mm / min and the distance between the jaws is 50 ⁇ 1 mm.
- the specimen is stretched by 150% ( ⁇ max ), that is to say 1.5 times its initial length (I 0 ) - the stress is relaxed by imposing a return speed equal to the traction speed, ie 20mm / min and the elongation of the test piece is measured as a percentage, after return to zero load ( ⁇ ;).
- R; (( ⁇ m ax - ⁇ ; ) / ⁇ max ) x 100
- the specimen having undergone the preceding operations is maintained at zero stress for an additional 300 seconds, and its percentage elongation rate is measured ( ⁇ 30 o).
- R 3 00 (( ⁇ m ax - ⁇ 3 where) / ⁇ max) X 100
- the glass transition temperature is evaluated using the MDSC 299 device sold by TA Instrument, in standard mode. Preferably, the glass transition temperature is less than 10 ° C.
- the film-forming polyurethane (s) (A) are preferably present at concentrations of between 0.05 and 20% by weight, more preferably between 0.1 and 15% by weight, and more preferably between 0.25 and 10% by weight relative to the total weight of the composition.
- the film-forming polyurethane (A) is chosen from the group comprising polyurethanes, polyether polyurethanes, polyurethane carbonates.
- the cosmetically acceptable medium is preferably constituted by water or one or more cosmetically acceptable solvents such as alcohols or water-solvent mixtures (s), these solvents being preferably CC 4 alcohols.
- composition of the invention can also contain at least one additive chosen from silicones, thickeners, anionic, nonionic, cationic or amphoteric surfactants, perfumes, preservatives, sun filters, proteins, vitamins, provitamins , anionic, nonionic, cationic or amphoteric non-fixing polymers, mineral, vegetable or synthetic oils, ceramides, pseudoceramides, volatile or non-volatile, linear or cyclic silicones, modified or not, and any other additive conventionally used in the compositions cosmetics intended to be applied to the hair.
- additives chosen from silicones, thickeners, anionic, nonionic, cationic or amphoteric surfactants, perfumes, preservatives, sun filters, proteins, vitamins, provitamins , anionic, nonionic, cationic or amphoteric non-fixing polymers, mineral, vegetable or synthetic oils, ceramides, pseudoceramides, volatile or non-volatile, linear or cyclic silicones, modified or not, and any
- compositions can be packaged in various forms, in particular in pump dispensers or in aerosol devices, in order to ensure application of the composition in vaporized form or in the form of foam. Such forms of packaging are indicated, for example, when it is desired to obtain a spray, a hairspray or mousse for fixing or treating hair.
- the compositions according to the invention can also be in the form of creams, gels, emulsions, lotions or waxes.
- composition according to the invention when packaged in the form of an aerosol in order to obtain a lacquer or a foam, it comprises at least one propellant which can be chosen from volatile hydrocarbons such as n-butane, propane, isobutane, pentane, a chlorinated and / or fluorinated hydrocarbon and their mixtures.
- propellants such as n-butane, propane, isobutane, pentane, a chlorinated and / or fluorinated hydrocarbon and their mixtures.
- Carbon dioxide, nitrous oxide, dimethyl ether (DME), nitrogen, compressed air can also be used as a propellant.
- Mixtures of propellants can also be used.
- dimethyl ether is used.
- the propellant is present at a concentration between 5 and 90% by weight relative to the total weight of the composition in the aerosol device and, more particularly, at a concentration between 10 and 60%.
- compositions according to the invention can be applied to dry or damp hair.
- compositions are produced in accordance with the invention.
- Composition 1 is a composition of Composition 1:
- PA Marin UA 310 marketed by Sanyo 6% m.a
- PA Marin UA 200 marketed by Sanyo 6%
- Composition 3 is a composition of Composition 3:
- Neorez R987 marketed by Zeneca 6%
- compositions 1 ′ to 3 ′ are used in accordance with the invention and identical to compositions 1 to 3, except that they contain 1.5% of m.a. instead of 6%.
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU17113/01A AU1711301A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
MXPA02004996A MXPA02004996A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes. |
EP00979714A EP1233741A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
CA002391640A CA2391640A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
JP2001537708A JP2003527339A (en) | 1999-11-19 | 2000-11-10 | Hair cosmetic composition providing excellent retention properties and comprising polyurethane |
BR0015762-7A BR0015762A (en) | 1999-11-19 | 2000-11-10 | Cosmetic composition comprising polyurethanes, aerosol device, styling or styling process and use of a composition |
KR1020027006283A KR20020050285A (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9914590A FR2801203B1 (en) | 1999-11-19 | 1999-11-19 | HAIR COSMETIC COMPOSITION PROVIDING GOOD HOLD PROPERTIES AND COMPRISING POLYURETHANES |
FR99/14590 | 1999-11-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001035915A1 true WO2001035915A1 (en) | 2001-05-25 |
Family
ID=9552320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2000/003149 WO2001035915A1 (en) | 1999-11-19 | 2000-11-10 | Cosmetic hair composition providing good resistance properties and comprising polyurethanes |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1233741A1 (en) |
JP (1) | JP2003527339A (en) |
KR (1) | KR20020050285A (en) |
CN (1) | CN1167404C (en) |
AU (1) | AU1711301A (en) |
BR (1) | BR0015762A (en) |
CA (1) | CA2391640A1 (en) |
FR (1) | FR2801203B1 (en) |
MX (1) | MXPA02004996A (en) |
PL (1) | PL356209A1 (en) |
RU (1) | RU2002116369A (en) |
WO (1) | WO2001035915A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2831437B1 (en) * | 2001-10-26 | 2004-02-06 | Oreal | COSMETIC HAIR TREATMENT COMPOSITION COMPRISING A NON-ASSOCIATIVE FIXING POLYURETHANE AND ANIONIC OR NON-IONIC ASSOCIATIVE POLYURETHANE, AND COSMETIC TREATMENT METHOD |
US20050209428A1 (en) * | 2002-06-19 | 2005-09-22 | Krishnan Tamareselvy | Breathable polyurethanes, blends, and articles |
FR2872410B1 (en) * | 2004-07-01 | 2006-12-15 | Oreal | COSMETIC COMPOSITION COMPRISING A TENSOR AND ELASTOMERIC FILMOGENIC POLYMER |
FR2872424B1 (en) * | 2004-07-01 | 2006-12-29 | Oreal | NON-RINSE COSMETIC COMPOSITION COMPRISING ELASTOMERIC FILMOGENIC POLYMERS, ITS USE FOR PACKAGING KERATINIC MATERIALS |
FR2872428B1 (en) * | 2004-07-01 | 2006-09-15 | Oreal | PRESSURIZED CAPILLARY COMPOSITION COMPRISING AT LEAST ONE ELASTOMERIC FILMOGENIC POLYMER |
WO2006003027A1 (en) * | 2004-07-01 | 2006-01-12 | L'oreal | Cosmetic composition comprising a tensioning agent and an elastomeric film-forming polymer |
FR2872425B1 (en) * | 2004-07-01 | 2006-12-22 | Oreal | RINSE COSMETIC COMPOSITION COMPRISING ELASTOMERIC FILMOGENIC POLYMERS, USE THEREOF FOR CONDITIONING KERATINIC MATERIALS |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3822238A (en) * | 1972-08-02 | 1974-07-02 | Princeton Polymer Lab | Hydrophilic polyurethane polymers |
US3975350A (en) * | 1972-08-02 | 1976-08-17 | Princeton Polymer Laboratories, Incorporated | Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles |
US4789720A (en) * | 1988-03-09 | 1988-12-06 | Tyndale Plains-Hunter, Ltd. | Hydrophilic polyurethanes prepared from mixed oxyalkylene glycols |
WO1994013724A1 (en) * | 1992-12-07 | 1994-06-23 | Basf Aktiengesellschaft | Use of cationic polyurethanes and polycarbamides as auxiliary substances in cosmetic and pharmaceutical compositions |
EP0779310A2 (en) * | 1992-07-29 | 1997-06-18 | Basf Aktiengesellschaft | Use of water-soluble or water-dispersible polyurethanes as auxiliary agents in cosmetic and pharmaceutical preparations and polyurethanes containing polylactic acid polyols incorporated by polymerization |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0441416A (en) * | 1990-06-07 | 1992-02-12 | Noevir Co Ltd | Cosmetic for hair |
JPH0627053B2 (en) * | 1990-09-28 | 1994-04-13 | 第一工業製薬株式会社 | Hair fixative |
DE69401230T3 (en) * | 1993-04-06 | 2006-02-16 | National Starch And Chemical Investment Holding Corp., Wilmington | Use of polyurethanes containing carboxyl functional group for hair fixation |
FR2740330B1 (en) * | 1995-10-27 | 1997-12-05 | Oreal | COMPOSITION CONSISTING OF A POLYMERIC SYSTEM AND USE OF THE SAID SYSTEM |
FR2751543B1 (en) * | 1996-07-24 | 1998-09-11 | Oreal | COMPOSITION COMPRISING A POLYMERIC SYSTEM AND USE OF SAID SYSTEM IN PARTICULAR IN COSMETICS |
FR2758084B1 (en) * | 1997-01-03 | 1999-02-05 | Oreal | COSMETIC AND / OR DERMATOLOGICAL COMPOSITION CONTAINING A DISPERSION OF A POLYMERIC SYSTEM AND USE OF THE SYSTEM AS A TENSIONER |
JP3667518B2 (en) * | 1997-01-14 | 2005-07-06 | 三洋化成工業株式会社 | Hair treatment agent |
JP3667480B2 (en) * | 1997-01-23 | 2005-07-06 | 三洋化成工業株式会社 | Hair treatment |
FR2771927B1 (en) * | 1997-12-05 | 2001-12-07 | Oreal | COSMETIC OR DERMATOLOGICAL COMPOSITION COMPRISING A FILM-FORMING POLYMER AND AN AQUEOUS SILICONE EMULSION |
FR2775593B1 (en) * | 1998-03-09 | 2002-06-14 | Oreal | FILM-FORMING COMPOSITION COMPRISING AN AQUEOUSLY DISPERSION POLYURETHANE AND A PLASTICIZING AGENT |
FR2788972B1 (en) * | 1999-02-03 | 2001-04-13 | Oreal | HAIR COMPOSITION COMPRISING A WASHING BASE, A CATIONIC POLYMER AND AN ANIONIC POLYURETHANE AND USE THEREOF |
JP4104791B2 (en) * | 1999-08-10 | 2008-06-18 | 日本エヌエスシー株式会社 | Cosmetics |
WO2001013884A2 (en) * | 1999-08-26 | 2001-03-01 | Basf Aktiengesellschaft | Cosmetic and/or pharmaceutical preparations with polymers containing polysiloxanes and the uses thereof |
DE19941365A1 (en) * | 1999-08-31 | 2001-03-01 | Basf Ag | Cosmetic agent based on urethane and / or urea group-containing oligomers |
-
1999
- 1999-11-19 FR FR9914590A patent/FR2801203B1/en not_active Expired - Fee Related
-
2000
- 2000-11-10 MX MXPA02004996A patent/MXPA02004996A/en unknown
- 2000-11-10 EP EP00979714A patent/EP1233741A1/en not_active Withdrawn
- 2000-11-10 BR BR0015762-7A patent/BR0015762A/en not_active IP Right Cessation
- 2000-11-10 CN CNB008159343A patent/CN1167404C/en not_active Expired - Fee Related
- 2000-11-10 RU RU2002116369/15A patent/RU2002116369A/en unknown
- 2000-11-10 AU AU17113/01A patent/AU1711301A/en not_active Abandoned
- 2000-11-10 JP JP2001537708A patent/JP2003527339A/en active Pending
- 2000-11-10 PL PL00356209A patent/PL356209A1/en unknown
- 2000-11-10 CA CA002391640A patent/CA2391640A1/en not_active Abandoned
- 2000-11-10 KR KR1020027006283A patent/KR20020050285A/en not_active Application Discontinuation
- 2000-11-10 WO PCT/FR2000/003149 patent/WO2001035915A1/en not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3822238A (en) * | 1972-08-02 | 1974-07-02 | Princeton Polymer Lab | Hydrophilic polyurethane polymers |
US3975350A (en) * | 1972-08-02 | 1976-08-17 | Princeton Polymer Laboratories, Incorporated | Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles |
US4789720A (en) * | 1988-03-09 | 1988-12-06 | Tyndale Plains-Hunter, Ltd. | Hydrophilic polyurethanes prepared from mixed oxyalkylene glycols |
EP0779310A2 (en) * | 1992-07-29 | 1997-06-18 | Basf Aktiengesellschaft | Use of water-soluble or water-dispersible polyurethanes as auxiliary agents in cosmetic and pharmaceutical preparations and polyurethanes containing polylactic acid polyols incorporated by polymerization |
WO1994013724A1 (en) * | 1992-12-07 | 1994-06-23 | Basf Aktiengesellschaft | Use of cationic polyurethanes and polycarbamides as auxiliary substances in cosmetic and pharmaceutical compositions |
Non-Patent Citations (1)
Title |
---|
See also references of EP1233741A1 * |
Also Published As
Publication number | Publication date |
---|---|
MXPA02004996A (en) | 2002-09-18 |
RU2002116369A (en) | 2004-01-20 |
FR2801203B1 (en) | 2002-12-27 |
PL356209A1 (en) | 2004-06-14 |
CN1391462A (en) | 2003-01-15 |
JP2003527339A (en) | 2003-09-16 |
FR2801203A1 (en) | 2001-05-25 |
KR20020050285A (en) | 2002-06-26 |
BR0015762A (en) | 2002-08-06 |
AU1711301A (en) | 2001-05-30 |
EP1233741A1 (en) | 2002-08-28 |
CA2391640A1 (en) | 2001-05-25 |
CN1167404C (en) | 2004-09-22 |
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