WO2001031115A2 - Colored bleach-resistant pile fabrics and floor mat articles comprising said pile fabrics - Google Patents
Colored bleach-resistant pile fabrics and floor mat articles comprising said pile fabrics Download PDFInfo
- Publication number
- WO2001031115A2 WO2001031115A2 PCT/JP2000/007630 JP0007630W WO0131115A2 WO 2001031115 A2 WO2001031115 A2 WO 2001031115A2 JP 0007630 W JP0007630 W JP 0007630W WO 0131115 A2 WO0131115 A2 WO 0131115A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pile
- fibers
- dyestuff
- colored
- pile fabrics
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L23/00—Cleaning footwear
- A47L23/22—Devices or implements resting on the floor for removing mud, dirt, or dust from footwear
- A47L23/26—Mats or gratings combined with brushes ; Mats
- A47L23/266—Mats
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
- D06N7/0065—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by the pile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/241—Polyamides; Polyurethanes using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/245—Polyamides; Polyurethanes using metallisable or mordant dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0807—Coloured
- D06N2209/0823—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1692—Weather resistance
Definitions
- This invention i elates to new dveing systems toi nvlon pile fabrics which are free fiom chrome-metallized d ⁇ estuffs and which comprise at least one cobalt- metallized dvestuff and at least one milling acid dvestutf
- Such systems pi ovide highly desirable and effective coloi ations within tai get pile fab ⁇ cs and also provide dramatic impi ovements m bleach resistance to the nvlon fabric surface
- the inventive colored pile fab ⁇ cs aie utilized genei allv as components within launderable flooi mat articles which l equire pe ⁇ odic cleaning with bleach- containing foi mulations
- the inventive coloied fab ⁇ cs do not exhibit any appreciable reduction in color aftei such continuous, penodic ngoi ous cleaning procedures
- Flooi mats comp ⁇ sed of such inventive coloied pile fab ⁇ cs as well as the particular dyestuff compositions themselves are also encompass
- pile fab ⁇ cs may be colored and/oi patterned w ith dyestuffs to piovide aesthetically pleasing products for placement in certain locations around entryways, around produce ref ⁇ geiators and freezeis in giocerv stores, and the like Since such colored pile fab ⁇ cs must be subjected to harsh cleaning proceedingsuies, both physically and chemically, the dyestuffs utilized to provide such desired coloiations must be able to withstand bleach exposuie as well as vigorous lotary washings and diyings on an industrial level
- Another object of this invention is to provide a highly bleach-resistant, colored pile fabric.
- Another object of this invention is to provide a floor mat product including a colored pile fabric which exhibits excellent coloring without the need for chrome-metallized dyestuffs.
- a further object of this invention is to provide a floor mat product including a colored pile fabric which can be laundered periodically with bleach compositions and which do not lose an appreciable amount of color due to such exposui e to bleach-contaming cleaning foimulations
- this invention encompasses a pile fabnc compnsing synthetic fibeis (piefei ably nylon and moie prefei ably solution-dyed nylon) wheiein at least a portion of said s ⁇ nthet ⁇ c fibers is coloied with at least two
- the invention also encompasses a floor mat product comprising such a pile fabnc
- a specific combination of dyestuffs provides excellent durable coloiations, washfastness, weatherfastness, and bleach-iesistance to the target pile fabric
- the synthetic fibers of the inventive pile fabric thus may be any fiber of manmade origin
- fibeis may be thus be selected from, without limitation, polyester, polyamide (nvlon such as nylon-6, or nylon-6,6, which is preferred), polypropylene, fibei glass and the like, as well as blends of such fibers
- the fibers may be coarse or fine in structure as well
- the delois of such individual fibers may lange fiom about 10 to about 200, preferably, such fibers possess deniers ranging from about 20 about 100, moie prefeiably from about 20 to about 25, and most preferably at about 23
- a plurality of such fibeis may preferably be twisted together to form vai ns (pi efei ably between about 40 and 80 aie twisted in such a manner, most preferably about 60) and then multiple plies of such yarns (3, as one prefened example) may also be twisted togethei to form the final yarn stmctuies to be mcoipo
- Cobalt-metallized dyestuffs have been utilized extensively foi coloring different fibeis, most notably polyamides, in the past
- LJ S Patents 3,658,460 to Mikula, 3,221 ,004 to Neiei, and 2,374, 106 to Kvalnes et al all discuss such coloi ing pioceduies
- the teim "cobalt-metallized ' is intended to encompass any class of dyestuffs comprising water-solubi zing gioups (such as carboxyhc acid, sulfonic acid sulfonoamido, etc , gioups) and which also comprise cobalt metal ions complexed with standaid dye components (such as azos, disazos, methines bisazos and the like)
- compositions compiis g both of these types of dyestuffs may be applied in any mannei to the taiget pile fibeis
- available coloiing procedures includes jet dye g spiaying immersing brushing and the like
- Spray techniques aie most piefeired including piocesses that utilize a plurality of individual jet nozzles foi patterning capability as well as thoiough coloiing of each individual target fibei
- Such spraying techniques include the utilization of Milhtron® and Chiomojet® dyeing machines
- topical overspiay should comprise a polymei IC finishing agent to coat the pile fabnc (01, actually, the individual pile fibeis) in oidei to protect the same fiom environmental and atmospheric exposure and potential damage
- One specific topical ovei spray includes Sunlife® EPS-2 manufactui ed by Emo ⁇ Shoji which comprises an anionic polymei finish
- the aqueous form of such a topical oveispiay possesses a pH of roughh 2
- inventive pile fabrics have thus been colored with a specific combination of dyestuffs and, optionally, tieated with a heated topical overspray It has now been detei mined that pleasing textuies and shades aie possible thiough the utilization of cobalt-metallized dyestuffs while such pleasant colorations are not compromised thiough the introduction of at least one additional milling acid dyestuff which piovides the beneficial bleach-iesistance properties to the finished product Such a finding lequned extensive ieview of many diffeient types of metallized dy estuffs (othei than chromium-based compounds of course) Even with propei colorations, the selected dyestuffs had to provide bleach-resistance in older to be utilized as possible ieplacements for the afoiementioned chromium- metallized dyestuffs It was detei mined that bleach-i esistance was not completely
- inventive flooi mat article geneiallv compi ises any amount of the inventive coloi ed pile fabric Othei types of fibei s, such as cotton, wool, and the like, may be piesent within the inventive floor mat, as well as non-colored synthetic fibei s
- the key component of this inventive floor mat is the presence of
- inventive and standard types within the inventive floor mat ai e generally tufted
- any type of standaid pile substrate may be utilized including woven non-woven
- the pile substiate may comprise withei synthetic or natui al fibers
- polyester including, as mei ely examples polyester, polyamide cotton sisal wool, and the
- such flooi mat articles also include rubbei backing sheets
- carpet fibers tufted thi ough the pile substrate are placed on top of such a backing
- this invention concerns, in its broadest sense, pile fab ⁇ cs colored with compositions of cobalt-metallized and milling acid dyestuffs, these pile fabrics may therefoie be incorporated within or utilized as carpets, rugs, mats, wall-covei ings automobile mtei iors, and the like
- a thickening agent (Kelzan S) was added to modify the viscosity of the composition to about 450 cps
- the colored pile fabnc exhibited an excellent thorough red color throughout
- the colored fabric was then laundered utilizing standard industrial-style l otary washing and diying machines, including cleaning compositions comp ⁇ sing chlo ⁇ ne bleach constituents
- the pile fabric did not exhibit any appreciable loss of coloi upon 10 such repeated laundering piocedures
- the pile fabric was then placed on top of a aibber sheet and subsequently subjected to a vulcanization piocedure for about 15 minutes The color was not appreciably affected by such high temperatuies and pressures Lastly, the pile fabric-containing (inventive) flooi mat article was placed outside an entryway for 4 weeks to test foi peifoimance as a floor mat article Attei another laundering as noted above the floor mat article did not exhibit anv appi eciable diffeience in coloi shade oi coloi sitesngth empi ⁇ cally This floor mat article pile fabric was also compared with a standaid chi ome-metallized red-colored pile fabnc incorpoiated within a similai flooi mat article Thiough the utilization of a gray scale (empu ical test) aftei bleaching and after exposui e to a xenon-aic Weatherometei appaiatus all of the bleachfastness and
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00970208A EP1248879A2 (en) | 1999-10-29 | 2000-10-30 | Colored bleach-resistant pile fabrics and floor mat articles comprising said pile fabrics |
AU79634/00A AU7963400A (en) | 1999-10-29 | 2000-10-30 | Colored bleach-resistant pile fabrics and floor mat articles comprising said pile fabrics |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11/309443 | 1999-10-29 | ||
JP30944399A JP2001131883A (en) | 1999-10-29 | 1999-10-29 | Colored pile fabric having durability to bleaching agent and floor mat article provided with the pile fabric |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2001031115A2 true WO2001031115A2 (en) | 2001-05-03 |
WO2001031115A3 WO2001031115A3 (en) | 2002-08-01 |
Family
ID=17993070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/007630 WO2001031115A2 (en) | 1999-10-29 | 2000-10-30 | Colored bleach-resistant pile fabrics and floor mat articles comprising said pile fabrics |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1248879A2 (en) |
JP (1) | JP2001131883A (en) |
CN (1) | CN1198013C (en) |
AU (1) | AU7963400A (en) |
WO (1) | WO2001031115A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7692281B2 (en) * | 2007-02-16 | 2010-04-06 | Tyco Electronics Corporation | Land grid array module with contact locating features |
CN105520491A (en) * | 2014-09-29 | 2016-04-27 | 陈方林 | Novel chlorine-bleaching-resistant carpet |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4383835A (en) * | 1980-10-31 | 1983-05-17 | Bayer Aktiengesellschaft | Process for improving the light fastness of polyamide dyeings with copper complexes of schiff bases or ortho-hydroxy benzophenone |
EP0612880A1 (en) * | 1993-02-24 | 1994-08-31 | Milliken Research Corporation | Method for improving the bleach resistance of dyed textile fiber and product made thereby |
US5573553A (en) * | 1992-04-24 | 1996-11-12 | Milliken Research Corporation | Method for improving the bleach resistance of dyed textile fiber and product made thereby |
-
1999
- 1999-10-29 JP JP30944399A patent/JP2001131883A/en active Pending
-
2000
- 2000-10-30 AU AU79634/00A patent/AU7963400A/en not_active Abandoned
- 2000-10-30 CN CN 00815034 patent/CN1198013C/en not_active Expired - Fee Related
- 2000-10-30 EP EP00970208A patent/EP1248879A2/en not_active Withdrawn
- 2000-10-30 WO PCT/JP2000/007630 patent/WO2001031115A2/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4383835A (en) * | 1980-10-31 | 1983-05-17 | Bayer Aktiengesellschaft | Process for improving the light fastness of polyamide dyeings with copper complexes of schiff bases or ortho-hydroxy benzophenone |
US5573553A (en) * | 1992-04-24 | 1996-11-12 | Milliken Research Corporation | Method for improving the bleach resistance of dyed textile fiber and product made thereby |
EP0612880A1 (en) * | 1993-02-24 | 1994-08-31 | Milliken Research Corporation | Method for improving the bleach resistance of dyed textile fiber and product made thereby |
Also Published As
Publication number | Publication date |
---|---|
JP2001131883A (en) | 2001-05-15 |
CN1451062A (en) | 2003-10-22 |
CN1198013C (en) | 2005-04-20 |
AU7963400A (en) | 2001-05-08 |
EP1248879A2 (en) | 2002-10-16 |
WO2001031115A3 (en) | 2002-08-01 |
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