WO2001027690A3 - Electrochromic device - Google Patents

Electrochromic device Download PDF

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Publication number
WO2001027690A3
WO2001027690A3 PCT/IE2000/000123 IE0000123W WO0127690A3 WO 2001027690 A3 WO2001027690 A3 WO 2001027690A3 IE 0000123 W IE0000123 W IE 0000123W WO 0127690 A3 WO0127690 A3 WO 0127690A3
Authority
WO
WIPO (PCT)
Prior art keywords
electrochromic device
metal oxide
nanostructured metal
concerns
chemisorption
Prior art date
Application number
PCT/IE2000/000123
Other languages
French (fr)
Other versions
WO2001027690A2 (en
Inventor
Donald Fitzmaurice
David Cummins
David Corr
Nagaraja S Rao
Gerrit Boschloo
Original Assignee
Univ Dublin
Donald Fitzmaurice
David Cummins
David Corr
Nagaraja S Rao
Gerrit Boschloo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU76816/00A priority Critical patent/AU770559B2/en
Priority to JP2001530641A priority patent/JP3934420B2/en
Priority to AT00966383T priority patent/ATE287096T1/en
Priority to DE60017440T priority patent/DE60017440T2/en
Priority to CA002385721A priority patent/CA2385721C/en
Priority to EP00966383A priority patent/EP1224505B1/en
Priority to US10/110,245 priority patent/US6870657B1/en
Application filed by Univ Dublin, Donald Fitzmaurice, David Cummins, David Corr, Nagaraja S Rao, Gerrit Boschloo filed Critical Univ Dublin
Publication of WO2001027690A2 publication Critical patent/WO2001027690A2/en
Publication of WO2001027690A3 publication Critical patent/WO2001027690A3/en
Priority to HK02108984.9A priority patent/HK1047623B/en
Priority to AU2004200554A priority patent/AU2004200554B2/en
Priority to US11/049,567 priority patent/US7253940B2/en
Priority to US11/049,520 priority patent/US7358358B2/en
Priority to US12/072,876 priority patent/US7576201B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02Boron compounds
    • C07F5/025Boronic and borinic acid compounds
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576Six-membered rings
    • C07F9/59Hydrogenated pyridine rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6509Six-membered rings
    • C07F9/650952Six-membered rings having the nitrogen atoms in the positions 1 and 4
    • C07F9/650994Six-membered rings having the nitrogen atoms in the positions 1 and 4 condensed with carbocyclic rings or carbocyclic ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6527Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07F9/6533Six-membered rings
    • C07F9/65335Six-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6536Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
    • C07F9/6544Six-membered rings
    • C07F9/6547Six-membered rings condensed with carbocyclic rings or carbocyclic ring systems
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02Organic tenebrescent materials
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1516Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y20/00Nanooptics, e.g. quantum optics or photonic crystals

Abstract

This invention concerns an electochromic device comprising an electrode including a nanostructured metal oxide film, doped to metallic levels of conductivity and optionally modified by chemisorption of an electroactive compound. Such an electrochromic device is suitable for applications where optical modulation is required, such as large area static displays and automatically dimmable rear-view mirrors. The invention also concerns conducting nanostructured metal oxide films and electrodes comprising same and which are suitable for use in the electrochromic device.
PCT/IE2000/000123 1999-10-11 2000-10-11 Electrochromic device WO2001027690A2 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
EP00966383A EP1224505B1 (en) 1999-10-11 2000-10-11 Electrochromic device
JP2001530641A JP3934420B2 (en) 1999-10-11 2000-10-11 Electrochromic element
AT00966383T ATE287096T1 (en) 1999-10-11 2000-10-11 ELECTROCHROMIC DEVICE
DE60017440T DE60017440T2 (en) 1999-10-11 2000-10-11 ELECTROCHROME DEVICE
CA002385721A CA2385721C (en) 1999-10-11 2000-10-11 Electrochromic device
AU76816/00A AU770559B2 (en) 1999-10-11 2000-10-11 Electrochromic device
US10/110,245 US6870657B1 (en) 1999-10-11 2000-10-11 Electrochromic device
HK02108984.9A HK1047623B (en) 1999-10-11 2002-12-11 Electrochromic device
AU2004200554A AU2004200554B2 (en) 1999-10-11 2004-02-12 Electroactive Compounds
US11/049,520 US7358358B2 (en) 1999-10-11 2005-02-01 Electrochromic compound
US11/049,567 US7253940B2 (en) 1999-10-11 2005-02-01 Nanoporous and nanocrystalline film and electrochromic device
US12/072,876 US7576201B2 (en) 1999-10-11 2008-02-28 Electrochromic compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IES990846 1999-10-11
IE990846 1999-10-11

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US10110245 A-371-Of-International 2000-10-11
US11/049,567 Division US7253940B2 (en) 1999-10-11 2005-02-01 Nanoporous and nanocrystalline film and electrochromic device
US11/049,520 Division US7358358B2 (en) 1999-10-11 2005-02-01 Electrochromic compound

Publications (2)

Publication Number Publication Date
WO2001027690A2 WO2001027690A2 (en) 2001-04-19
WO2001027690A3 true WO2001027690A3 (en) 2001-10-04

Family

ID=11042141

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IE2000/000123 WO2001027690A2 (en) 1999-10-11 2000-10-11 Electrochromic device

Country Status (10)

Country Link
US (4) US6870657B1 (en)
EP (2) EP1224505B1 (en)
JP (2) JP3934420B2 (en)
KR (1) KR100712006B1 (en)
AT (1) ATE287096T1 (en)
AU (1) AU770559B2 (en)
CA (1) CA2385721C (en)
DE (1) DE60017440T2 (en)
HK (1) HK1047623B (en)
WO (1) WO2001027690A2 (en)

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US9412314B2 (en) 2001-11-20 2016-08-09 E Ink Corporation Methods for driving electro-optic displays
US9470950B2 (en) 2002-06-10 2016-10-18 E Ink Corporation Electro-optic displays, and processes for the production thereof

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HAGFELD A ET AL: "NANOSTRUCTURED TIO2 SEMICONDUCTOR ELECTRODES MODIFIED WITH SURFACE ATTACHED VIOLOGENS: APPLICATIONS FOR DISPLAYS AND SMART WINDOWS", PROCEEDINGS OF THE SPIE, 12 July 1995 (1995-07-12), XP000671112 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9412314B2 (en) 2001-11-20 2016-08-09 E Ink Corporation Methods for driving electro-optic displays
US9470950B2 (en) 2002-06-10 2016-10-18 E Ink Corporation Electro-optic displays, and processes for the production thereof
US8928562B2 (en) 2003-11-25 2015-01-06 E Ink Corporation Electro-optic displays, and methods for driving same
US9542895B2 (en) 2003-11-25 2017-01-10 E Ink Corporation Electro-optic displays, and methods for driving same

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HK1047623B (en) 2005-05-06
EP1224505A1 (en) 2002-07-24
EP1500969A1 (en) 2005-01-26
US20050128561A1 (en) 2005-06-16
WO2001027690A2 (en) 2001-04-19
AU7681600A (en) 2001-04-23
AU770559B2 (en) 2004-02-26
ATE287096T1 (en) 2005-01-15
JP2003511837A (en) 2003-03-25
US20080167465A1 (en) 2008-07-10
DE60017440T2 (en) 2006-03-02
KR100712006B1 (en) 2007-04-27
CA2385721A1 (en) 2001-04-19
HK1047623A1 (en) 2003-02-28
CA2385721C (en) 2009-04-07
KR20020062286A (en) 2002-07-25
US7253940B2 (en) 2007-08-07
JP3934420B2 (en) 2007-06-20
US6870657B1 (en) 2005-03-22
DE60017440D1 (en) 2005-02-17
US7576201B2 (en) 2009-08-18
EP1224505B1 (en) 2005-01-12
JP2006309216A (en) 2006-11-09
US20050128562A1 (en) 2005-06-16
US7358358B2 (en) 2008-04-15

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