WO2000044555A1 - Electret film composition adapted for printing on computer printers and the like - Google Patents

Electret film composition adapted for printing on computer printers and the like Download PDF

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Publication number
WO2000044555A1
WO2000044555A1 PCT/US1999/001804 US9901804W WO0044555A1 WO 2000044555 A1 WO2000044555 A1 WO 2000044555A1 US 9901804 W US9901804 W US 9901804W WO 0044555 A1 WO0044555 A1 WO 0044555A1
Authority
WO
WIPO (PCT)
Prior art keywords
sheet
printing
electret
sheets
backing
Prior art date
Application number
PCT/US1999/001804
Other languages
French (fr)
Inventor
Calvin B. Ward
Robert G. Hockaday
Original Assignee
Permacharge Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Priority to US08/987,344 priority Critical patent/US5904985A/en
Application filed by Permacharge Corp filed Critical Permacharge Corp
Priority to PCT/US1999/001804 priority patent/WO2000044555A1/en
Priority to AU25657/99A priority patent/AU2565799A/en
Publication of WO2000044555A1 publication Critical patent/WO2000044555A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506Intermediate layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/90Magnetic feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/91Product with molecular orientation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24777Edge feature
    • Y10T428/24793Comprising discontinuous or differential impregnation or bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • Y10T428/31899Addition polymer of hydrocarbon[s] only
    • Y10T428/31902Monoethylenically unsaturated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31931Polyene monomer-containing

Definitions

  • the present invention relates to computer printers and printing materials for use therein, and more particularly, to a computer printing material that will adhere electrostatically to surfaces.
  • Modern desktop publishing has made possible the production of one of a kind posters and other displays.
  • a user of a conventional personal computer equipped with any one of a number of inexpensive printers can create professional quality artwork and displays. If the user also has access to a scanner, the user can input almost any type of artwork and modify the artwork for inclusion in the user's own creation.
  • Transparency materials for use with overhead projectors have been available for some time. Unfortunately, one needs a projector for each display. While such systems are practical for presentations to groups in business or educational settings, these systems are far from adequate in terms of serving the needs of an artist or teacher who wishes to hang a picture on a wall. Furthermore, the number of pictures that can be displayed at a time is limited to one per projector.
  • Printer compatible papers with glue backing are also known to those skilled in the publishing arts. These vary in sizes from small printer labels to full sized sheets. An art work printed on an adhesive backed sheet may be stuck to a surface without the need to frame the art work or damage the surface by the application of fasteners. Unfortunately, such adhesive backed sheets have a number of problems.
  • the artwork cannot, in general, be removed from one location and re-applied at another location more than a few times without the adhesive failing.
  • some of the adhesives used in these sheets leave a residue on the surface.
  • the adhesives used with some of these papers, such as those used for labels are sufficiently strong that the paper may not be removed from surfaces such as glass without destroying the artwork.
  • the art work must be scraped from the surface using a razor blade or the like.
  • an electret will be defined to be a plastic sheet which carries a permanent electrostatic charge. Such sheets can be generated by passing the plastic sheet through an electric field while the sheet is held at an elevated temperature. The sheet is then cooled before the induced electric diople moment generated by the field has time to dissipate. The resulting plastic sheet will stick to most clean surfaces. Furthermore, the sheet may be easily removed and re-applied to another surface.
  • Pads of sheets are commercially sold for use during presentations as a replacement for conventional "white boards". These sheets are typically made from polypropylene which is a few thousandths of an inch thick.
  • the sheets may be printed via conventional offset printing techniques provided they are re-charged after the printing process. Offset printing systems heat the sheets after the application of the ink to dry the ink. The increase in temperature results in a loss of some or all of the induced dipole moment in the sheet.
  • U.S. Patent 5,477,784 entitled “ Apparatus and Method for Printing on and Polarizing Polymer Electret Films” describes a printing arrangement in which the sheets are recharged during the drying process. While such recharging systems may be incorporated into large offset presses, they do not represent a viable solution at the desktop publishing level, since they would require modifications of the existing printers to include high voltage charging electrodes.
  • electrets should be capable of use with inkjet printers and some color printers which do not subject the electrets to excessive heat.
  • the electret sheets present a number of problems with respect to the sheet feeders used in these printers. To be cost effective, and to provide reliable adhesion, relatively thin sheets must be used. These sheets are too flexible to feed properly in many paper handling systems. Furthermore, individual sheets in a stack of electrostatically charged sheets in a sheet feeder tend to stick together because of the electrostatic charge. This further complicates the sheet feeding problem.
  • the present invention is a printing composition that is adapted for printing on computer printers and the like.
  • the printing composition includes a backing sheet and a printing sheet.
  • the printing sheet includes an electret which is reversibly bound to the backing sheet.
  • the printing sheet is coated with an ink absorbing coating.
  • the electret can be constructed from materials such as polypropylene or polyethylene that have been subjected to electrostatic fields.
  • Figure 1 is an exploded view of a printing composition according to present invention.
  • polyester films that have been coated to provide an ink absorbent surface for printing in inject printers are known to the printing arts. This material is used in conventional printing presses to generate posters and packaging materials.
  • polyester film with an acrylic coating suitable for printing may be obtained from Apollo Presentation Products, Ronkonkoma, NY 11779. Similar films are sold for generating transparencies using inkjet printers. However, these films tend to be two thick to provide optimal electrostatic adhesion, since the weight to surface area ratio of the films is too great. In addition, the cost of these films is relatively high.
  • Polypropylene films have been found to be suitable for printing in color printers that utilize wax transfer or dye sublimation processes.
  • the present invention is based on the observation that coated polyester sheets of this type may be charged by placing the sheets in an electric field which is typically 10,000 volts/cm. The sheets may be heated to increase the remnant electric field.
  • a polyester film having a thickness between O.OOlinches and 0.004 inches is passed between rollers and subjected to an electric field and corona discharge to charge the film.
  • This film is then backed with a paper sheet 14 as shown in Figure 1 which is an exploded view of a printing composition 10 according to the present invention.
  • Backing sheet 14 is preferably attached along one edge to electret sheet 12 by a layer of adhesive 15 which covers less than 10 percent of the area of the electret sheet.
  • a perforation 17 is included between the portion of the electret sheet attached via the adhesive and the remainder of the electret sheet.
  • This embodiment of the present invention is particularly well suited for "pull-outs" that are included in magazines and the like. After printing, the portion of the sheet that includes the glue is bound into the magazine. The reader can then remove the printed electret sheet by tearing the sheet along the perforations.
  • the electret sheets of the present invention are also well suited for printing in other types of presses that utilize rolls of material.
  • the backing sheet provides the dimensional stability needed during the printing process. Without the backing sheet, the thin electret sheet would be distorted by the printer rollers and other materials moving parts of the printer. In some environments, the electrostatic adhesion of the electret to the backing sheet is sufficient to prevent the two sheets from moving with respect to one another.
  • the combined backing sheet and electret are bound at periodic intervals in the roll by the adhesive bound sections. Accordingly, the two layers remain fixed with respect to one another as they pass through the press.
  • the top surface of the polyester film is coated to absorb ink as shown at 16. This coating is not needed for polypropylene films that are to be printed via wax transfer, dye sublimation or offset printing. This surface remains exposed for printing.
  • the backing sheet 14 separates the charged polyester sheet 12 from the any other sheets in the paper feeder.
  • the optimal thickness for the backing sheet is determined by the thickness of the electret sheet and the optimal thickness for the sheet feeder on the printer. Most printers are designed for a maximum sheet thickness. The combined thickness of the electret sheet and the backing sheet must be less than this maximum thickness. The minimum thickness for the backing sheet is determined by the degree of rigidity required by the paper feed of the printer. Thicker backing sheets provide higher degrees of rigidity; however, thicker backing sheets increase cost. In the preferred embodiment of the present invention, the thickness of the backing sheet is chosen such that the combined thickness of the backing sheet and the electret sheet is close to the optimal thickness for the printer feed mechanism. For example, in one preferred embodiment of the present invention the electret sheet consists of a 2.5 mil sheet of polypropylene backed with a 5 mil sheet of paper.
  • Such a composition has been shown to be suitable for printing in color printers such as the Tektronix 350 printer.
  • Polyester embodiments of the present invention in which a 0.3 mil polyester sheet is backed with a 5 mil sheet of paper have been found to be suitable for printing in inkjet printers, provided the sheet is coated with an ink absorbing material such as the coatings used on view graph sheets that are sold for use in such printers.
  • a suitable coating material for polypropylene sheets can be constructed as follows. Polyvinyl acetate (0.3 grams) is dissolved in 1.12 grams of methylene chloride. A second solution consisting of 0.57 grams of polyvinyl alcohol dissolved in the 20.6 grams of water is then mixed with this solution and 0.34 grams of dry psy Ilium husk fiber. The resulting solution is spread over the polypropylene sheets and vacuum dried.
  • plastic sheets that have been coated tend to curl when removed from the backing sheet if only one side of the sheet has been coated. Accordingly, in the preferred embodiment of the present invention, the plastic sheets are coated on both sides to prevent this curling.
  • backing sheet 14 permits the use of a significantly thinner electret sheet while allowing the sheets to pass through the printer without jamming.
  • the sheets are joined at one edge 17 by an adhesive that will allow the sheets to be separated after printing. While the sheets are only joined at one edge, the electrostatic attraction of the electret sheet and the backing sheet result in the sheets being stuck together over the entire length of the polyester sheet.
  • the backing sheet can support a thin electret sheet during the printing process in a manner that prevents the thin sheet from moving relative to the backing sheet. Prior to placing the printed sheet on a surface for displaying the printed sheet, the backing sheet is removed.
  • the cost of a "poster" according to the present invention is mainly the cost of the electret sheet which, in turn, is a function of the thickness of the sheet. Once the sheet is printed, the surface on which it is placed supports the sheet. Hence, there is no need for a thick sheet after the printing process is completed. Thus, for purposes of reducing cost, thin sheets are preferred.
  • the second benefit of thin sheets is their ability to cling to vertical surfaces. The electrostatic attraction of the sheets to the surface is predominantly a function of the surface charge on the sheet. The force tending to remove a sheet from the surface is the weight of the sheet. It has been found experimentally, that the surface charge is relatively independent of the thickness of the sheet. Hence, thin sheets cling better to vertical surfaces.
  • polyester or polypropylene sheets for the electret sheet
  • other plastics may be utilized for the electret.
  • Teflon, polycarbonate, and vinyl sheets may be used for the electret sheet.
  • the backing sheet is paper.
  • other backing sheet compositions may be used.
  • the surface of the backing sheet that is in contact with the electret sheet may be charged by embedding charges in the surface using a corona discharge.
  • the embedded charge has a polarity opposite to that of the adjacent surface of the electret sheet.
  • the charge cancels the charge on the adjacent surface while the sheets are in contact. This cancellation further decreases the inter- sheet attraction in the feeder tray of the printer.
  • the additional charge increases the electrostatic bonding of the electret and bonding sheets.
  • the surface of the backing sheet that is to be charged must comprise a material that will hold the charge.
  • the backing sheet may be constructed from a plastic coated paper.

Abstract

A printing composition [10] that is adapted for printing on computer printers and the like. The printing composition [10] includes a backing sheet [14] and a printing sheet [12]. The printing sheet [12] includes an electret which is reversibly bound to the backing sheet [14]. In one embodiment of the invention, the printing sheet [12] is coated with an ink absorbing coating [16]. The electret can be constructed from materials such as polypropylene or polyethylene that have been subjected to electrostatic fields.

Description

Electret Film Composition Adapted for Printing on Computer Printers and the Like
Field of the Invention
The present invention relates to computer printers and printing materials for use therein, and more particularly, to a computer printing material that will adhere electrostatically to surfaces.
Background of the Invention
Modern desktop publishing has made possible the production of one of a kind posters and other displays. A user of a conventional personal computer equipped with any one of a number of inexpensive printers can create professional quality artwork and displays. If the user also has access to a scanner, the user can input almost any type of artwork and modify the artwork for inclusion in the user's own creation.
While the ability to generate custom artwork has advanced rapidly, the ability to "hang" the art work has not progressed so rapidly. The options for displaying the artwork can be more or less summarized as "glue", "frame", or "project". Framing is not cost effective for many temporary displays. In addition, the frame must be mounted on the surface by a fastener or the like. Such fasteners can damage the surface. Such damage is particularly objectionable if the artist is renting the premises at which the damage occurs.
Transparency materials for use with overhead projectors have been available for some time. Unfortunately, one needs a projector for each display. While such systems are practical for presentations to groups in business or educational settings, these systems are far from adequate in terms of serving the needs of an artist or teacher who wishes to hang a picture on a wall. Furthermore, the number of pictures that can be displayed at a time is limited to one per projector. Printer compatible papers with glue backing are also known to those skilled in the publishing arts. These vary in sizes from small printer labels to full sized sheets. An art work printed on an adhesive backed sheet may be stuck to a surface without the need to frame the art work or damage the surface by the application of fasteners. Unfortunately, such adhesive backed sheets have a number of problems. First, the artwork cannot, in general, be removed from one location and re-applied at another location more than a few times without the adhesive failing. In addition, some of the adhesives used in these sheets leave a residue on the surface. Furthermore, the adhesives used with some of these papers, such as those used for labels, are sufficiently strong that the paper may not be removed from surfaces such as glass without destroying the artwork. In some cases, the art work must be scraped from the surface using a razor blade or the like.
One type of material that holds the promise of providing a display which sticks to a surface without the use of fasteners or adhesives is the electrets. For the purposes of the present discussion, an electret will be defined to be a plastic sheet which carries a permanent electrostatic charge. Such sheets can be generated by passing the plastic sheet through an electric field while the sheet is held at an elevated temperature. The sheet is then cooled before the induced electric diople moment generated by the field has time to dissipate. The resulting plastic sheet will stick to most clean surfaces. Furthermore, the sheet may be easily removed and re-applied to another surface.
Electret compositions for making posters have been described in the prior art. Pads of sheets are commercially sold for use during presentations as a replacement for conventional "white boards". These sheets are typically made from polypropylene which is a few thousandths of an inch thick.
The sheets may be printed via conventional offset printing techniques provided they are re-charged after the printing process. Offset printing systems heat the sheets after the application of the ink to dry the ink. The increase in temperature results in a loss of some or all of the induced dipole moment in the sheet. U.S. Patent 5,477,784 entitled " Apparatus and Method for Printing on and Polarizing Polymer Electret Films" describes a printing arrangement in which the sheets are recharged during the drying process. While such recharging systems may be incorporated into large offset presses, they do not represent a viable solution at the desktop publishing level, since they would require modifications of the existing printers to include high voltage charging electrodes.
In principle, electrets should be capable of use with inkjet printers and some color printers which do not subject the electrets to excessive heat. Unfortunately, the electret sheets present a number of problems with respect to the sheet feeders used in these printers. To be cost effective, and to provide reliable adhesion, relatively thin sheets must be used. These sheets are too flexible to feed properly in many paper handling systems. Furthermore, individual sheets in a stack of electrostatically charged sheets in a sheet feeder tend to stick together because of the electrostatic charge. This further complicates the sheet feeding problem.
Broadly, it is the object of the present invention to provide an improved printing material that incorporates the advantages of electrets.
It is another object of the present invention to provide a printing material that may be printed in conventional computer printers without suffering from the paper feed problems described above.
These and other objects of the present invention will become apparent to those skilled in the art from the following detailed description of the invention and the accompanying drawings.
Summary of the Invention
The present invention is a printing composition that is adapted for printing on computer printers and the like. The printing composition includes a backing sheet and a printing sheet. The printing sheet includes an electret which is reversibly bound to the backing sheet. In one embodiment of the invention, the printing sheet is coated with an ink absorbing coating. The electret can be constructed from materials such as polypropylene or polyethylene that have been subjected to electrostatic fields. Brief Description of the Drawings
Figure 1 is an exploded view of a printing composition according to present invention.
Detailed Description of the Invention
To simplify the following discussion, the manner in which the present invention achieves its advantages will be discussed with reference to polyester or polypropylene films. Polyester films that have been coated to provide an ink absorbent surface for printing in inject printers are known to the printing arts. This material is used in conventional printing presses to generate posters and packaging materials. For example, polyester film with an acrylic coating suitable for printing may be obtained from Apollo Presentation Products, Ronkonkoma, NY 11779. Similar films are sold for generating transparencies using inkjet printers. However, these films tend to be two thick to provide optimal electrostatic adhesion, since the weight to surface area ratio of the films is too great. In addition, the cost of these films is relatively high. Polypropylene films have been found to be suitable for printing in color printers that utilize wax transfer or dye sublimation processes.
The present invention is based on the observation that coated polyester sheets of this type may be charged by placing the sheets in an electric field which is typically 10,000 volts/cm. The sheets may be heated to increase the remnant electric field. In the preferred embodiment of the present invention, a polyester film having a thickness between O.OOlinches and 0.004 inches is passed between rollers and subjected to an electric field and corona discharge to charge the film. This film is then backed with a paper sheet 14 as shown in Figure 1 which is an exploded view of a printing composition 10 according to the present invention. Backing sheet 14 is preferably attached along one edge to electret sheet 12 by a layer of adhesive 15 which covers less than 10 percent of the area of the electret sheet.
In one embodiment of the present invention, a perforation 17 is included between the portion of the electret sheet attached via the adhesive and the remainder of the electret sheet. This embodiment of the present invention is particularly well suited for "pull-outs" that are included in magazines and the like. After printing, the portion of the sheet that includes the glue is bound into the magazine. The reader can then remove the printed electret sheet by tearing the sheet along the perforations.
The electret sheets of the present invention are also well suited for printing in other types of presses that utilize rolls of material. The backing sheet provides the dimensional stability needed during the printing process. Without the backing sheet, the thin electret sheet would be distorted by the printer rollers and other materials moving parts of the printer. In some environments, the electrostatic adhesion of the electret to the backing sheet is sufficient to prevent the two sheets from moving with respect to one another. In the embodiments that utilize the adhesive sections as shown in Figure 1 , the combined backing sheet and electret are bound at periodic intervals in the roll by the adhesive bound sections. Accordingly, the two layers remain fixed with respect to one another as they pass through the press.
The top surface of the polyester film is coated to absorb ink as shown at 16. This coating is not needed for polypropylene films that are to be printed via wax transfer, dye sublimation or offset printing. This surface remains exposed for printing. The backing sheet 14 separates the charged polyester sheet 12 from the any other sheets in the paper feeder.
The optimal thickness for the backing sheet is determined by the thickness of the electret sheet and the optimal thickness for the sheet feeder on the printer. Most printers are designed for a maximum sheet thickness. The combined thickness of the electret sheet and the backing sheet must be less than this maximum thickness. The minimum thickness for the backing sheet is determined by the degree of rigidity required by the paper feed of the printer. Thicker backing sheets provide higher degrees of rigidity; however, thicker backing sheets increase cost. In the preferred embodiment of the present invention, the thickness of the backing sheet is chosen such that the combined thickness of the backing sheet and the electret sheet is close to the optimal thickness for the printer feed mechanism. For example, in one preferred embodiment of the present invention the electret sheet consists of a 2.5 mil sheet of polypropylene backed with a 5 mil sheet of paper. Such a composition has been shown to be suitable for printing in color printers such as the Tektronix 350 printer. Polyester embodiments of the present invention in which a 0.3 mil polyester sheet is backed with a 5 mil sheet of paper have been found to be suitable for printing in inkjet printers, provided the sheet is coated with an ink absorbing material such as the coatings used on view graph sheets that are sold for use in such printers.
A suitable coating material for polypropylene sheets can be constructed as follows. Polyvinyl acetate (0.3 grams) is dissolved in 1.12 grams of methylene chloride. A second solution consisting of 0.57 grams of polyvinyl alcohol dissolved in the 20.6 grams of water is then mixed with this solution and 0.34 grams of dry psy Ilium husk fiber. The resulting solution is spread over the polypropylene sheets and vacuum dried.
It should be noted that thin plastic sheets that have been coated tend to curl when removed from the backing sheet if only one side of the sheet has been coated. Accordingly, in the preferred embodiment of the present invention, the plastic sheets are coated on both sides to prevent this curling.
In addition to reducing inter-sheet adhesion in the printer tray, backing sheet 14 permits the use of a significantly thinner electret sheet while allowing the sheets to pass through the printer without jamming. It should be noted that the sheets are joined at one edge 17 by an adhesive that will allow the sheets to be separated after printing. While the sheets are only joined at one edge, the electrostatic attraction of the electret sheet and the backing sheet result in the sheets being stuck together over the entire length of the polyester sheet. Hence, the backing sheet can support a thin electret sheet during the printing process in a manner that prevents the thin sheet from moving relative to the backing sheet. Prior to placing the printed sheet on a surface for displaying the printed sheet, the backing sheet is removed.
The ability to use thin electret sheets provides two advantages. First, the cost of a "poster" according to the present invention is mainly the cost of the electret sheet which, in turn, is a function of the thickness of the sheet. Once the sheet is printed, the surface on which it is placed supports the sheet. Hence, there is no need for a thick sheet after the printing process is completed. Thus, for purposes of reducing cost, thin sheets are preferred. The second benefit of thin sheets is their ability to cling to vertical surfaces. The electrostatic attraction of the sheets to the surface is predominantly a function of the surface charge on the sheet. The force tending to remove a sheet from the surface is the weight of the sheet. It has been found experimentally, that the surface charge is relatively independent of the thickness of the sheet. Hence, thin sheets cling better to vertical surfaces.
While the above described embodiments of the present invention utilize polyester or polypropylene sheets for the electret sheet, other plastics may be utilized for the electret. For example, Teflon, polycarbonate, and vinyl sheets may be used for the electret sheet.
In the preferred embodiment of the present invention, the backing sheet is paper. However, other backing sheet compositions may be used. For example, the surface of the backing sheet that is in contact with the electret sheet may be charged by embedding charges in the surface using a corona discharge. The embedded charge has a polarity opposite to that of the adjacent surface of the electret sheet. Hence, the charge cancels the charge on the adjacent surface while the sheets are in contact. This cancellation further decreases the inter- sheet attraction in the feeder tray of the printer. In addition, the additional charge increases the electrostatic bonding of the electret and bonding sheets. In this embodiment of the present invention, the surface of the backing sheet that is to be charged must comprise a material that will hold the charge. For example, the backing sheet may be constructed from a plastic coated paper.
Various modifications to the present invention will become apparent to those skilled in the art from the foregoing description and accompanying drawings. Accordingly, the present invention is to be limited solely by the scope of the following claims.

Claims

WHAT IS CLAIMED IS:
1. A printing composition[10] comprising: a backing sheet[14] and a printing sheet[12] comprising a sheet of electret having an ink absorbent coating[16] on said side of said printing sheet[12] that is to receive ink.
2. The printing composition[10] of Claim 1 wherein said backing sheet[14] is bonded on one side thereof, said remaining side being adapted for receiving ink, said bonded area[15] being less than 10 percent of the area of said sheet.
3. The printing composition[10] of Claim 1 wherein said printing sheet[12] further comprises a perforation displaced from one edge thereof by a distance sufficient to allow said edge to bound while allowing said sheet to be removed by tearing along said perforation.
4. The printing composition[10] of Claim 1 wherein said printing sheet[12] further comprises a layer of said ink absorbent coating[16] on the other side of said printing sheet[12].
5. The printing composition[10] of Claim 1 wherein said sheet of electret comprises polypropylene.
6. The printing composition[10] of Claim 1 wherein said sheet of electret comprises polyethylene.
7. The printing composition[10] of Claim 1 wherein said printing sheet[12] is less than 5 mils.
PCT/US1999/001804 1997-12-09 1999-01-27 Electret film composition adapted for printing on computer printers and the like WO2000044555A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US08/987,344 US5904985A (en) 1997-12-09 1997-12-09 Electret film composition adapted for printing on computer printers and the like
PCT/US1999/001804 WO2000044555A1 (en) 1997-12-09 1999-01-27 Electret film composition adapted for printing on computer printers and the like
AU25657/99A AU2565799A (en) 1997-12-09 1999-01-27 Electret film composition adapted for printing on computer printers and the like

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/987,344 US5904985A (en) 1997-12-09 1997-12-09 Electret film composition adapted for printing on computer printers and the like
PCT/US1999/001804 WO2000044555A1 (en) 1997-12-09 1999-01-27 Electret film composition adapted for printing on computer printers and the like

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WO2000044555A1 true WO2000044555A1 (en) 2000-08-03

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WO2004020211A2 (en) * 2002-08-30 2004-03-11 3M Innovative Properties Company Stencil and method of using the same

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US7785699B1 (en) * 2000-09-06 2010-08-31 Ward Calvin B Electrostatically charged porous water-impermeable absorbent laminate for protecting work surfaces from contamination
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US6660352B2 (en) 2001-01-09 2003-12-09 3M Innovative Properties Company Adhesive electrostatic sheets
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US20030049294A1 (en) * 2001-09-07 2003-03-13 Jose Porchia Film material
US20040018422A1 (en) * 2002-07-24 2004-01-29 Islam Quazi Towhidul Device including flexible battery and method of producing same
JP2005537358A (en) * 2002-08-30 2005-12-08 スリーエム イノベイティブ プロパティズ カンパニー Method for manufacturing erasable article and article
US20040043221A1 (en) * 2002-08-30 2004-03-04 3M Innovative Properties Company Method of adhering a film and articles therefrom
US20040202820A1 (en) * 2002-08-30 2004-10-14 3M Innovative Properties Company Perforated electret articles and method of making the same
EP1920021A1 (en) * 2005-08-11 2008-05-14 Stromberg Allen and Company Substrate having polarized adhesive
US20090029156A1 (en) * 2005-08-11 2009-01-29 Kruchko Steven N Substrate having polarized adhesive
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CN102066103A (en) * 2008-06-16 2011-05-18 优泊公司 Electrostatic attracting sheet
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WO2013191289A1 (en) * 2012-06-22 2013-12-27 株式会社ユポ・コーポレーション Electrostatically adsorptive sheet and display using same
JP6350078B2 (en) * 2014-07-31 2018-07-04 凸版印刷株式会社 Thermal transfer image receiving sheet
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WO2002032991A1 (en) * 2000-10-17 2002-04-25 Nordenia Office Promotion & Art Gmbh Use of a polyolefin film as a medium to be written or printed on
DE10051495C2 (en) * 2000-10-17 2003-09-25 Nordenia Office Promotion & Ar Use of a partially transparent polyolefin film
WO2004020211A2 (en) * 2002-08-30 2004-03-11 3M Innovative Properties Company Stencil and method of using the same
WO2004020211A3 (en) * 2002-08-30 2009-09-11 3M Innovative Properties Company Stencil and method of using the same

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AU2565799A (en) 2000-08-18

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