WO1998020073A3 - Biodegradable polymeric compositions comprising starch and a thermoplastic polymer - Google Patents

Biodegradable polymeric compositions comprising starch and a thermoplastic polymer Download PDF

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Publication number
WO1998020073A3
WO1998020073A3 PCT/EP1997/006103 EP9706103W WO9820073A3 WO 1998020073 A3 WO1998020073 A3 WO 1998020073A3 EP 9706103 W EP9706103 W EP 9706103W WO 9820073 A3 WO9820073 A3 WO 9820073A3
Authority
WO
WIPO (PCT)
Prior art keywords
compositions
polyester
thermoplastic polymer
starch
aliphatic
Prior art date
Application number
PCT/EP1997/006103
Other languages
French (fr)
Other versions
WO1998020073A2 (en
Inventor
Catia Bastioli
Vittorio Bellotti
Gian Domenico Cella
Giudice Luciano Del
Sandro Montino
Gabriele Perego
Original Assignee
Novamont Spa
Catia Bastioli
Vittorio Bellotti
Gian Domenico Cella
Giudice Luciano Del
Sandro Montino
Gabriele Perego
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26332335&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1998020073(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from IT96TO000890 external-priority patent/IT1288817B1/en
Priority claimed from IT96TO000996 external-priority patent/IT1289723B1/en
Priority to US09/297,733 priority Critical patent/US7176251B1/en
Priority to AU53174/98A priority patent/AU724397B2/en
Priority to AT97950097T priority patent/ATE277124T1/en
Priority to CA2270362A priority patent/CA2270362C/en
Priority to BR9712882-1A priority patent/BR9712882A/en
Priority to IL12974597A priority patent/IL129745A0/en
Priority to HU0000335A priority patent/HU229197B1/en
Application filed by Novamont Spa, Catia Bastioli, Vittorio Bellotti, Gian Domenico Cella, Giudice Luciano Del, Sandro Montino, Gabriele Perego filed Critical Novamont Spa
Priority to JP52105598A priority patent/JP4034357B2/en
Priority to EP97950097A priority patent/EP0937120B1/en
Priority to DE69730852T priority patent/DE69730852T2/en
Publication of WO1998020073A2 publication Critical patent/WO1998020073A2/en
Publication of WO1998020073A3 publication Critical patent/WO1998020073A3/en
Priority to IL129745A priority patent/IL129745A/en
Priority to NO19992159A priority patent/NO335963B1/en
Priority to US11/657,857 priority patent/US8410199B2/en
Priority to US11/657,799 priority patent/US7956107B2/en
Priority to IL188860A priority patent/IL188860A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0895—Manufacture of polymers by continuous processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones
    • C08G18/4277—Caprolactone and/or substituted caprolactone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/12—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00—Compositions for preparing biodegradable polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/06—Biodegradable

Abstract

Polymeric compositions comprising thermoplastic starch and a thermoplastic polymer incompatible with starch, in which the starch constitutes the dispersed phase and the thermoplastic polymer constitutes the continuous phase, selected: A) from compositions comprising an agent with an interfacial effect selected from esters of polyols with mono- or polycarboxylic acids with dissociation constants within certain limits, the esters having specific values of the hydrophilic/lipophilic balance index HLB or being amongst the non-ionic surfactants which are soluble in water but cannot significantly be extracted by water from the compositions which contain them; B) from compositions wherein the thermoplastic polymer is an aliphatic or aliphatic-aromatic copolyester wherein the ratio (R) between the average viscometric molecular weight and the melt index is greater than 25,000 and C) from compositions wherein the thermoplastic polymer is selected from aliphatic-aromatic copolyesters, polyester-amides, polyester-ethers, polyester-ether-amides, polyester-urethanes and polyester-ureas and wherein the compositions are obtained by extrusion of the component maintaining a water content during the mixing stage from 1 to 5 % by weight.
PCT/EP1997/006103 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer WO1998020073A2 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
JP52105598A JP4034357B2 (en) 1996-11-05 1997-11-05 Biodegradable polymer composition comprising starch and thermoplastic polymer
EP97950097A EP0937120B1 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
DE69730852T DE69730852T2 (en) 1996-11-05 1997-11-05 BIODEGRADABLE POLYMER COMPOSITIONS CONTAINING STARCH AND A THERMOPLASTIC POLYMER
AU53174/98A AU724397B2 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and thermoplastic polymer
AT97950097T ATE277124T1 (en) 1996-11-05 1997-11-05 BIODEGRADABLE POLYMER COMPOSITIONS CONTAINING STARCH AND A THERMOPLASTIC POLYMER
CA2270362A CA2270362C (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
BR9712882-1A BR9712882A (en) 1996-11-05 1997-11-05 Biodegradable heterophasic polymeric compositions
IL12974597A IL129745A0 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
HU0000335A HU229197B1 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
US09/297,733 US7176251B1 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
IL129745A IL129745A (en) 1996-11-05 1999-05-03 Biodegradable heterophase polymeric compositions comprising a thermoplastic starch, a thermoplastic polymer incompatible with starch and an interfacial agent, process for their preparation and their use in organic and inorganic products
NO19992159A NO335963B1 (en) 1996-11-05 1999-05-04 Biodegradable polymeric materials comprising starch and a thermoplastic polymer, and process for the preparation of the materials and use
US11/657,799 US7956107B2 (en) 1996-11-05 2007-01-25 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
US11/657,857 US8410199B2 (en) 1996-11-05 2007-01-25 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
IL188860A IL188860A (en) 1996-11-05 2008-01-17 Biodegradable heterophase polymeric compositions comprising a thermoplastic starch, a thermoplastic polymer incompatible with starch and an interfacial agent, process for their preparation and their use in organic and inorganic products

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IT96TO000890 IT1288817B1 (en) 1996-11-05 1996-11-05 Biodegradable thermoplastic polymer compositions - contain dispersed starch and interfacial agent if thermoplastic polymer is not polyester
ITTO96A000890 1996-11-05
ITTO96A000996 1996-12-09
IT96TO000996 IT1289723B1 (en) 1996-12-09 1996-12-09 Biodegradable thermoplastic polymer compositions - contain dispersed starch and interfacial agent if thermoplastic polymer is not polyester

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US09297733 A-371-Of-International 1997-11-05
US11/657,857 Division US8410199B2 (en) 1996-11-05 2007-01-25 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer
US11/657,799 Division US7956107B2 (en) 1996-11-05 2007-01-25 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer

Publications (2)

Publication Number Publication Date
WO1998020073A2 WO1998020073A2 (en) 1998-05-14
WO1998020073A3 true WO1998020073A3 (en) 1998-08-06

Family

ID=26332335

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1997/006103 WO1998020073A2 (en) 1996-11-05 1997-11-05 Biodegradable polymeric compositions comprising starch and a thermoplastic polymer

Country Status (16)

Country Link
US (3) US7176251B1 (en)
EP (6) EP0947559B1 (en)
JP (3) JP4034357B2 (en)
KR (1) KR100329588B1 (en)
CN (1) CN1104467C (en)
AT (4) ATE278737T1 (en)
AU (1) AU724397B2 (en)
BR (1) BR9712882A (en)
CA (1) CA2270362C (en)
DE (4) DE69730852T2 (en)
DK (2) DK0947559T3 (en)
ES (1) ES2229591T3 (en)
HU (1) HU229197B1 (en)
IL (3) IL129745A0 (en)
NO (1) NO335963B1 (en)
WO (1) WO1998020073A2 (en)

Cited By (2)

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US8834925B2 (en) 2006-08-25 2014-09-16 Purdue Pharma L.P. Tamper resistant dosage forms
US9161917B2 (en) 2008-05-09 2015-10-20 Grünenthal GmbH Process for the preparation of a solid dosage form, in particular a tablet, for pharmaceutical use and process for the preparation of a precursor for a solid dosage form, in particular a tablet

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