WO1993009281A1 - Shaped fabric products and methods of making same - Google Patents

Shaped fabric products and methods of making same Download PDF

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Publication number
WO1993009281A1
WO1993009281A1 PCT/GB1992/002003 GB9202003W WO9309281A1 WO 1993009281 A1 WO1993009281 A1 WO 1993009281A1 GB 9202003 W GB9202003 W GB 9202003W WO 9309281 A1 WO9309281 A1 WO 9309281A1
Authority
WO
WIPO (PCT)
Prior art keywords
product
tubular
filamentary
fill
resiliently
Prior art date
Application number
PCT/GB1992/002003
Other languages
French (fr)
Inventor
Michael A. Ford
Richard A. Barlow
Martin I. Jacobs
Original Assignee
T&N Plc
The Bentley Harris Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by T&N Plc, The Bentley Harris Manufacturing Company filed Critical T&N Plc
Priority to KR1019940701456A priority Critical patent/KR940702956A/en
Priority to EP92922758A priority patent/EP0611404B1/en
Priority to KR1019940701456A priority patent/KR100322737B1/en
Priority to DE69219785T priority patent/DE69219785T2/en
Publication of WO1993009281A1 publication Critical patent/WO1993009281A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/06Protection of pipes or objects of similar shape against external or internal damage or wear against wear
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • D03D1/0043Protective fabrics for elongated members, i.e. sleeves
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/002With diagonal warps or wefts
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D3/00Woven fabrics characterised by their shape
    • D03D3/02Tubular fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C5/00Shaping or stretching of tubular fabrics upon cores or internal frames
    • D06C5/005Shaping or stretching of tubular fabrics upon cores or internal frames of articles, e.g. stockings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/02Setting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/02Protection of pipes or objects of similar shape against external or internal damage or wear against cracking or buckling
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02GINSTALLATION OF ELECTRIC CABLES OR LINES, OR OF COMBINED OPTICAL AND ELECTRIC CABLES OR LINES
    • H02G3/00Installations of electric cables or lines or protective tubing therefor in or on buildings, equivalent structures or vehicles
    • H02G3/02Details
    • H02G3/04Protective tubing or conduits, e.g. cable ladders or cable troughs
    • H02G3/0462Tubings, i.e. having a closed section
    • H02G3/0481Tubings, i.e. having a closed section with a circular cross-section
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S139/00Textiles: weaving
    • Y10S139/01Bias fabric digest
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1328Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
    • Y10T428/1331Single layer [continuous layer]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]

Definitions

  • the present invention is directed to tubular
  • tubular fabrics which are particularly well adapted for bundling and protecting
  • elongated articles such as wires, cables, hoses and conduits.
  • the EXPANDO ® sleeving is lightweight and provides tough physical protection for cable assemblies, wire harnesses and the like.
  • the open construction of this type of product is of advantage over solid material in that it
  • Patent No. 4,228,824 - Evans et al. recognizes the difficulty of providing woven tubular products which resist kinking when curved or bent. Evans et al. teaches that this difficulty may be overcome by providing a hose having a reinforcement structure comprised of plied warp yarns formed of filaments of high modulus material which resists
  • Evans et al. are said to have a high degree of twist in the filaments in order to provide stability to the hose wall when compressed during curving of the hose. Furthermore, Evans et al. illustrates the warp elements as extending along the length of the hose in a direction substantially parallel to the axis of the hose.
  • U.S. Patent No. 4,652,263 - Herwick et al . is directed to woven fabric tubes especially adapted for use as prostheses in biomedical applications.
  • Herwick et al. note that such woven fabric tubes are preferably capable of
  • Herwick et al. also note that such tubular products should also be resistant to kinking or radial collapse. Elasticity is imparted to the tubes of Herwick et al. by providing the woven tubular products with axially- oriented warp threads forming loops extending radially outward between circumferential fill threads. The loops are set to return to the loop configuration upon release of tension applied axially to the tube.
  • U.S. Patent No. 4,015,641 - Goff et al. recognizes the difficulty associated with providing shape retaining woven tubular products.
  • Goff et al. notes that tubular fabrics have heretofore been filled with foam material so that the product will have a cushioned, shape retaining characteristic.
  • Goff et al. suggest that a similar effect can be obtained by forming a woven tubular product using
  • monofilament filling yarns in both layers of the fabric and alternately and intermittently weaving monofilament warp yarns between the layers to connect the two layers together.
  • Applicants have recognized a need for shaped-fabric products, and particularly for tubular fabrics, which are at once shape-retaining, kink-resistant and flexible.
  • the present invention provides flexible, kink-resistant shaped fabric products which are particularly well adapted for protecting and/or covering elongate substrates, such as cables, conduits, wiring and the like.
  • the shaped fabric products are preferably elongate tubular products having a longitudinal dimension which is substantially greater than the width, diameter or girth of the product.
  • the shaped fabric products include a wall portion comprising a filament resiliently set in a spiral configuration with respect to the longitudinal axis of the shaped product. Applicants have found that tubular products comprising fabrics, and preferably woven fabrics, having such spirally set filaments generally possess excellent flexibility and exceptional kink- and abrasion-resistance.
  • the wall portion of the tubular product also
  • the shaped product preferably comprises a filament in the form of circumferential hoops substantially conforming in shape and size to the cross- sectional configuration of the shaped product.
  • the filament in the form of circumferential hoops substantially conforming in shape and size to the cross- sectional configuration of the shaped product.
  • circumferential hoops are substantially circular hoops having a diameter equal to about the diameter of the cylinder.
  • the shaped fabric product comprises a woven tubular fabric having a fill end thereof in the form of hoops which lie in a plane substantially perpendicular to the axis of the tube and warp ends thereof resiliently set in a spiral
  • the present invention also provides methods of forming flexible, kink-resistant tubular fabrics.
  • the methods comprise: (1) providing a shaped fabric product comprising a wall portion comprising interlaced, resiliently settable filaments and (2) resiliently setting at least a portion of the resiliently settable filaments in a spiral configuration with respect to the longitudinal axis of the tubular product.
  • the providing step comprises providing a woven tubular fabric and the setting step comprises heat setting the resiliently settable
  • Fig. 1 is a perspective view of a woven tubular product according to a first embodiment of the present
  • Fig. 2 is a plan view of a woven tubular product according to a first embodiment of the present invention.
  • Fig. 3 is a perspective view of a woven tubular product which is radially discontinuous according to a second embodiment of the present invention.
  • Fig. 4 is a perspective view of a radially discontinuous woven tubular product of the present invention encasing an elongate substrate.
  • the present invention is directed to shaped products, and more particularly to shaped fabric products.
  • fabric refers to any material comprised of interlaced filamentary components.
  • many classes of fabric material exist, and it is contemplated that all such materials may be adaptable for use in connection with the present invention.
  • the shaped fabric products may comprise knitted products, braided products or woven products, with woven products being
  • the preferred woven products comprise fill and warp threads interlaced according to any one of the well-known weave patterns. In general, however, applicants have found that a twill pattern, and preferably a 2-2 twill pattern, produces acceptable results.
  • the shaped fabric products are preferably characterized by an open construction. That is, it is generally preferred that the filamentary materials comprising the wall portion of the shaped fabric are relatively loosely interlaced. In this way, the shaped fabric products of the present invention breath and prevent entrapment of moisture.
  • the present shaped fabric products are particularly well adapted for protecting and/or covering substrates, especially elongate substrates.
  • the particular shape of the present fabric will thus typically depend upon the shape of the substrate being covered or protected.
  • the shaped fabric product will provide a wall portion for covering the substrate and a chamber or open area internal to the wall portion for containing at least a portion of the substrate.
  • the shaped fabric products will preferably possess a hollow portion defined by a wall portion having a shape corresponding generally to the shape of the substrate to be protected, thereby providing a chamber or cavity for accepting the substrate. While all such shapes are within the scope of the present invention, it is contemplated that the shaped fabrics of the present invention will frequently and typically be in tubular form.
  • tubular refers to an elongate article having an internal chamber running substantially along the length thereof. While it is expected that the tubular products of the present invention will typically have a circular cross-sectional configuration, it is contemplated that other cross-sectional configurations, such as triangular, square and ellipsoidal, may also be used.
  • the shaped fabric products comprise filaments in the wall portion thereof resiliently set in a spiral
  • the fabric product includes filaments resiliently set in a spiral pattern with respect to the axis of the tube.
  • resilient set refers to the
  • the pitch of the resiliently set spiral filaments may vary widely within the scope hereof, depending upon such factors as the particular filamentary material being used, the cost of the product and the degree of flexibility and kink-resistance which is desired. In general, however, it is preferred that for tubular fabric products the resiliently set spiral filaments have a pitch of no greater than about 0.4 turns per longitudinal inch of tubular product, and even more preferably a pitch of from about 0.2 to about 0.3 turns per inch. Applicants have found that tubular fabric products, and especially woven tubular products having a circular cross-section and an inner diameter of from about 3/16 to about 4 inches, possess high levels of both flexibility and kink-resistance when the spiral filaments have a pitch within the range described herein. Furthermore,
  • tubular products possess an unexpectedly high degree of abrasion resistance.
  • the shaped fabric products include a wall portion comprising filaments resiliently set in a spiral configuration relative to the longitudinal axis of the shaped fabric such that the tubular product has an abrasion resistance of at least about 25,000 cycles and even more preferably of from about 30,000 to about 60,000 cycles of the ARP test.
  • the ARP test refers to the abrasion test outlined hereinafter in the Example section of the present specification.
  • the wall portion of the shaped fabric product also comprises resiliently set circumferential hoops substantially conforming in shape and size to the cross-sectional configuration of the shaped product.
  • cross-sectional configuration refers to the configuration of a shaped product in a plane which is
  • the wall portion of cylindrically shaped tubular fabrics preferably includes resiliently set circular filaments forming hoops having approximately the diameter of the cylinder.
  • the shaped product is a woven product in which a substantial portion of the fill threads, and even more
  • filamentary materials of construction are capable of being provided with a resilient set.
  • a large number of materials are adaptable for use in forming the resiliently settable filaments hereof.
  • many structural metals and engineering plastics will assume a permanent set when stressed above their elastic limit at room temperature.
  • the filamentary material of the present invention will be provided with a resilient set or bias by the application of heat, pressure, irradiation, chemical reagents and combinations of these.
  • thermoplastic resins are polymeric materials that soften or melt at elevated temperatures, thus allowing them to be processed into shapes and products that, when cooled, recover the physical and chemical properties of the original resin.
  • this class of materials generally has a good balance of high tensile properties, compressive and shear strength, as well as impact resistance.
  • Exemplary thermoplastic resins are polyamides, polyesters, and polyolefins, with polyamides and polyesters being preferred.
  • Filaments comprised of thermoplastic resins of the type described may be cause to take a resilient, permanent set by forming a product comprised of the plastic material to a specific geometry, for example, a circular or spiral shape, and then modifying the properties of the material.
  • a resilient set or bias (sometimes called an "elastic memory") in the shape in which it was formed, as is well recognized by those of ordinary skill in the art.
  • a resilient set or bias sometimes called an "elastic memory”
  • the application of heat is the usual and most widely employed method of producing the set or bias, it should also be recognized that other, eg., chemical or physical, methods may sometimes be employed.
  • such a set may be provided to filamentary material comprising polyethylene by irradiating the shaped product so as to cross-link the
  • cross-linking may be accelerated or enhanced by the inclusion of cross-linking promoters in the polymeric material.
  • the resiliently settable filaments used in the fabrics of the present invention may vary widely both as to type and dimension.
  • the resiliently settable filaments may include multi-filament yarns and threads, monofilament yarns and threads or mixtures of these types of filaments, with monofilaments being preferred.
  • filamentary material other than the resiliently settable material described above may be included with advantage in the shaped fabrics of the present invention.
  • filaments comprised of fluorocarbon polymer resin to impart low friction characteristics to the shaped products.
  • combinations of engineering plastic materials and yarns or strands or filaments comprised of metals or mineral materials may be used.
  • the present fabrics may comprise, in addition to the resiliently settable filaments hereof, other natural and synthetic
  • a woven tubular product having a circular cross-section.
  • the tubular product comprises a wall portion 11 forming a hollow chamber 12.
  • the hollow chamber 12 is filled by an elongate substrate which is to be protected by the shaped fabric 10.
  • Wall portion 11 of shaped product 10 comprises fill ends 13 interlaced with warp ends 14.
  • Fill ends 13 are in the shape of circular hoops or bands having a diameter equivalent to about the diameter of the wall portion 11 of tubular product 10. Warp ends 14 are
  • the tubular product is constructed by first providing a woven tubular product in which the fill ends lie in a plane which is substantially perpendicular to the axis of the tube and in which the warp ends lie in a plane which is substantially parallel to the axis of the tube.
  • a tubular product may be provided by first providing a rectangular sheet of woven fabric in which the fill ends are substantially parallel to the short edge of the sheet and the warp ends are
  • this woven rectangular sheet is then joined according to any one of several well-known techniques, such as sewing, to form a woven product which is continuous along its short edge. It will be appreciated that other methods and techniques are known and available for forming woven fabrics which are continuous along their short edge. For example, certain weaving equipment, such as narrow fabric needle looms, are readily adapted to produce such woven products.
  • the woven products can then be formed into a tubular configuration by, for example, placing the product over a cylindrical mandrel.
  • tubular products using narrow fabric needle looms as indicated herein produces woven tubular products in which a single fill end is knitted to itself to form interconnected resilient hoops disposed in a plane which is substantially perpendicular to the axis of the tube.
  • the fill ends 13 are also comprised of resiliently settable material, and the step of resiliently setting the warp ends in the spiral configuration will also provide the preferred step of resiliently setting the fill ends in the form of a circular hoop.
  • the present invention is not limited to continuous tubular products of the type illustrated in Fig. 1.
  • a second embodiment of the present invention provides tubular products which are discontinuous in the
  • tubular products of the present invention which are discontinuous in the circumferential direction have certain advantages,
  • tubular products which are discontinuous in the circumferential direction may be prepared according to various techniques, and all such techniques are within the scope of the present invention.
  • a cut or slit may be prepared by providing a longitudinal cut or slit in the wall portion 12 of the tubular product, thereby producing a tubular product having adjacent longitudinal edges. While such a cut or slit will provide the advantages described above, it may also have disadvantages in some applications. For example, the simple provision of a cut or a slit
  • This small gap or opening may be a
  • the longitudinal edges 15 and 16 of the discontinuous tubular product overlap one another in the radial direction, as illustrated in Fig. 3. This overlap may be provided using any one of several
  • tubular product will be radially
  • the discontinuous tubular product may be provided to a folder of well a known design and heated, preferably
  • the discontinuous tubular product may be wrapped around a mandrel having a diameter smaller than the inner diameter of the discontinuous tube such that overlap of the longitudinal edges occurs.
  • the overlapped configuration is then set into the tube, such as by the application of heat to the mandrel.
  • tubular products of the present invention may be provided in a wide variety of shapes and sizes, it is generally preferr8d that tubular products are substantially circular m cross-section and have an inner diameter of about 0.25 inch to about 4 inches.
  • the warp and fill threads of the present invention are monofilaments having a diameter of from about 5 to about 15 mil with about 8 to about 10 mil being preferred.
  • Shaped fabric products particularly tubular fabrics for use in casing and covering elongated substrates, according to the present invention exhibit exceptional and altogether unexpected results.
  • one important characteristic of the shaped articles of the present invention is the
  • each tubular fabric being tested was installed over a stainless steel mandrel, approximately 15 inches long.
  • the mandrel and tubular product were restrained by suitable clamps and
  • abrasive element comprising a 0.50 inch precision ground drill rod (QQ-T-580) with a specific heat treatment of 60-64 HRC hardness and a surface finish of R 16 ⁇ in (0.40 ⁇ m) was applied to the outer surface of the tubular fabric with a total force of about 5 pounds. The abrasive force was then reciprocated longitudinally across the tubular product at a rate of about 200 cycles per minute through a total stroke of about 3 inch.
  • failure of the protective cover is established as a wearing through of the cover by the abrasion element. Such a failure is determined by the abrasive element contacting the metal reinforcement of the hose assembly after wear through of the fabric product, thus closing an electrical circuit which stops the tester.
  • a braided tubular product having an inner diameter of about 0.5 inch comprising polyester monofilament having a diameter of about .010 inch and a braid pattern of one over, one under was subject to an abrasion test according to the procedure described above.
  • the tubular product was
  • a woven tubular product according to the present invention was subject to an abrasion test according to the procedure described above.
  • the woven product comprised polyester monofilament fill threads having a diameter of about 0.009 inch and polyester monofilament warp threads having a diameter of about .010 inch in a 2-2 twill pattern.
  • the tubular product was substantially circular in cross-section and had an inner diameter of about 0.5 inch.
  • the fill threads were all resiliently set by the application of heat in the form of a substantially circular hoop having a diameter of about 0.52 inch.
  • the warp threads were all resiliently set by the application of heat in a spiral configuration having a pitch of about 0.2 turns per inch.

Abstract

Disclosed are flexible, kink-resistant shaped fabric products which are particularly well adapted for protecting and/or covering elongate substrates, such as cables, conduits, wiring and the like. The shaped fabric products include a wall portion comprising a filament resiliently set in a spiral configuration with respect to the longitudinal axis of the shaped product. The wall portion may also preferably comprise a filament in the form of circumferential hoops substantially conforming in shape and size to the cross-sectional configuration of the shaped product. Also disclosed are methods for forming such shaped product.

Description

SHAPED FABRIC PRODUCTS AND METHODS OF MAKING SAME
The present invention is directed to tubular
products, and more particularly to tubular fabrics which are particularly well adapted for bundling and protecting
elongated articles, such as wires, cables, hoses and conduits.
The use of fabric sleeves for encasing cables, hoses and other elongated flexible articles is well-known in the art. Examples of such sleeving are available from the
Bentley-Harris Manufacturing Company under the registered trademark EXPANDO. The EXPANDO® sleeving is lightweight and provides tough physical protection for cable assemblies, wire harnesses and the like. The open construction of this type of product is of advantage over solid material in that it
breathes and prevents the entrapment of moisture. In
addition, this type of sleeving maintains the bundled,
elongated articles in clean, compact condition.
While sleeving of the type employed by the EXPANDO® product has achieved significant success and possesses certain advantageous characteristics, a need for flexible, kink-resistant woven tubular products continues to exist. U.S.
Patent No. 4,228,824 - Evans et al., for example, recognizes the difficulty of providing woven tubular products which resist kinking when curved or bent. Evans et al. teaches that this difficulty may be overcome by providing a hose having a reinforcement structure comprised of plied warp yarns formed of filaments of high modulus material which resists
longitudinal extension of the hose. The warp elements of Evans et al. are said to have a high degree of twist in the filaments in order to provide stability to the hose wall when compressed during curving of the hose. Furthermore, Evans et al. illustrates the warp elements as extending along the length of the hose in a direction substantially parallel to the axis of the hose.
U.S. Patent No. 4,652,263 - Herwick et al . is directed to woven fabric tubes especially adapted for use as prostheses in biomedical applications. Herwick et al. note that such woven fabric tubes are preferably capable of
returning to their original shape after being stretched, compressed or bent. Herwick et al. also note that such tubular products should also be resistant to kinking or radial collapse. Elasticity is imparted to the tubes of Herwick et al. by providing the woven tubular products with axially- oriented warp threads forming loops extending radially outward between circumferential fill threads. The loops are set to return to the loop configuration upon release of tension applied axially to the tube.
U.S. Patent No. 4,015,641 - Goff et al. recognizes the difficulty associated with providing shape retaining woven tubular products. In particular, Goff et al. notes that tubular fabrics have heretofore been filled with foam material so that the product will have a cushioned, shape retaining characteristic. Goff et al. suggest that a similar effect can be obtained by forming a woven tubular product using
monofilament filling yarns in both layers of the fabric and alternately and intermittently weaving monofilament warp yarns between the layers to connect the two layers together.
While the products mentioned above may have achieved some degree of success, they also possess certain drawbacks. For example, potentially costly and somewhat unusual
manufacturing techniques are required to produce the products of the type described above. Moreover, the products described in Goff et al. suffer from the disadvantage of requiring the presence of structural members spanning the hollow portion of the tubular product. The presence of such structural members limits the usefulness of the tubular product for encasing elongate substrates.
Thus, Applicants have recognized a need for shaped-fabric products, and particularly for tubular fabrics, which are at once shape-retaining, kink-resistant and flexible.
Furthermore, Applicants have recognized the failure of the prior art to provide methods for manufacturing woven tubular products which possess these characteristics.
Furthermore, while the abrasion-resistance of the heretofore used protective fabric coverings has been
acceptable in many applications, applicants have found that tremendous improvement in abrasion resistance is possible. Such improvement in abrasion resistance is highly desirable for obvious reasons, such as increasing the useful life of the protective fabric cover.
Accordingly, it is an object of the present invention to provide flexible, kink-resistant fabric covers.
It is a further object to the present invention to provide relatively low-cost protective fabric covers.
It is yet a further object of the present invention to provide flexible, kink-resistant fabric covers with
excellent abrasion resistance.
SUMMARY OF THE INVENTION
The present invention provides flexible, kink-resistant shaped fabric products which are particularly well adapted for protecting and/or covering elongate substrates, such as cables, conduits, wiring and the like. The shaped fabric products are preferably elongate tubular products having a longitudinal dimension which is substantially greater than the width, diameter or girth of the product. According to important aspects of the present invention, the shaped fabric products include a wall portion comprising a filament resiliently set in a spiral configuration with respect to the longitudinal axis of the shaped product. Applicants have found that tubular products comprising fabrics, and preferably woven fabrics, having such spirally set filaments generally possess excellent flexibility and exceptional kink- and abrasion-resistance. The wall portion of the tubular product also
preferably comprises a filament in the form of circumferential hoops substantially conforming in shape and size to the cross- sectional configuration of the shaped product. For the preferred cylindrically shaped tubular products, the
circumferential hoops are substantially circular hoops having a diameter equal to about the diameter of the cylinder.
According to preferred aspects of the present invention, the shaped fabric product comprises a woven tubular fabric having a fill end thereof in the form of hoops which lie in a plane substantially perpendicular to the axis of the tube and warp ends thereof resiliently set in a spiral
configuration with respect to the longitudinal axis of the tube.
The present invention also provides methods of forming flexible, kink-resistant tubular fabrics. The methods comprise: (1) providing a shaped fabric product comprising a wall portion comprising interlaced, resiliently settable filaments and (2) resiliently setting at least a portion of the resiliently settable filaments in a spiral configuration with respect to the longitudinal axis of the tubular product. According to certain preferred embodiments, the providing step comprises providing a woven tubular fabric and the setting step comprises heat setting the resiliently settable
filaments.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a perspective view of a woven tubular product according to a first embodiment of the present
invention.
Fig. 2 is a plan view of a woven tubular product according to a first embodiment of the present invention.
Fig. 3 is a perspective view of a woven tubular product which is radially discontinuous according to a second embodiment of the present invention.
Fig. 4 is a perspective view of a radially discontinuous woven tubular product of the present invention encasing an elongate substrate. DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The present invention is directed to shaped products, and more particularly to shaped fabric products. As the term is used herein, "fabric" refers to any material comprised of interlaced filamentary components. As will be appreciated by those skilled in the art, many classes of fabric material exist, and it is contemplated that all such materials may be adaptable for use in connection with the present invention. In particular, it is contemplated that the shaped fabric products may comprise knitted products, braided products or woven products, with woven products being
preferred. The preferred woven products comprise fill and warp threads interlaced according to any one of the well-known weave patterns. In general, however, applicants have found that a twill pattern, and preferably a 2-2 twill pattern, produces acceptable results.
Furthermore, it is generally preferred that the shaped fabric products are preferably characterized by an open construction. That is, it is generally preferred that the filamentary materials comprising the wall portion of the shaped fabric are relatively loosely interlaced. In this way, the shaped fabric products of the present invention breath and prevent entrapment of moisture.
The present shaped fabric products are particularly well adapted for protecting and/or covering substrates, especially elongate substrates. The particular shape of the present fabric will thus typically depend upon the shape of the substrate being covered or protected. In all cases, however, the shaped fabric product will provide a wall portion for covering the substrate and a chamber or open area internal to the wall portion for containing at least a portion of the substrate. Thus, the shaped fabric products will preferably possess a hollow portion defined by a wall portion having a shape corresponding generally to the shape of the substrate to be protected, thereby providing a chamber or cavity for accepting the substrate. While all such shapes are within the scope of the present invention, it is contemplated that the shaped fabrics of the present invention will frequently and typically be in tubular form. As used herein, the term
"tubular" refers to an elongate article having an internal chamber running substantially along the length thereof. While it is expected that the tubular products of the present invention will typically have a circular cross-sectional configuration, it is contemplated that other cross-sectional configurations, such as triangular, square and ellipsoidal, may also be used.
According to important aspects of the present invention, the shaped fabric products comprise filaments in the wall portion thereof resiliently set in a spiral
configuration relative to the longitudinal axis of the shaped fabric. For embodiments comprising tubular products, for example, the fabric product includes filaments resiliently set in a spiral pattern with respect to the axis of the tube. As the term is used herein, "resilient set" refers to the
incorporation of a permanent set or a bias in a resilient filamentary material. Thus, a filamentary material which has been resiliently set in a given configuration tends to remain in that configuration under ambient temperature conditions and in the absence of external stress. However, such material readily deforms upon the application of externally applied stress but returns to substantially its original "set"
position upon the release of the stress.
It is contemplated that the pitch of the resiliently set spiral filaments may vary widely within the scope hereof, depending upon such factors as the particular filamentary material being used, the cost of the product and the degree of flexibility and kink-resistance which is desired. In general, however, it is preferred that for tubular fabric products the resiliently set spiral filaments have a pitch of no greater than about 0.4 turns per longitudinal inch of tubular product, and even more preferably a pitch of from about 0.2 to about 0.3 turns per inch. Applicants have found that tubular fabric products, and especially woven tubular products having a circular cross-section and an inner diameter of from about 3/16 to about 4 inches, possess high levels of both flexibility and kink-resistance when the spiral filaments have a pitch within the range described herein. Furthermore,
Applicants have found that such tubular products possess an unexpectedly high degree of abrasion resistance.
According to preferred embodiments of the present invention, the shaped fabric products include a wall portion comprising filaments resiliently set in a spiral configuration relative to the longitudinal axis of the shaped fabric such that the tubular product has an abrasion resistance of at least about 25,000 cycles and even more preferably of from about 30,000 to about 60,000 cycles of the ARP test. As the term is used herein, the ARP test refers to the abrasion test outlined hereinafter in the Example section of the present specification.
According to certain preferred aspects of the present invention, the wall portion of the shaped fabric product also comprises resiliently set circumferential hoops substantially conforming in shape and size to the cross-sectional configuration of the shaped product. As used herein, the term "cross-sectional configuration" refers to the configuration of a shaped product in a plane which is
substantially normal with respect to the longitudinal axis of the product. For example, the wall portion of cylindrically shaped tubular fabrics preferably includes resiliently set circular filaments forming hoops having approximately the diameter of the cylinder. According to especially preferred embodiments, the shaped product is a woven product in which a substantial portion of the fill threads, and even more
preferably substantially all of the fill threads, are
resiliently set in the form of circumferential hoops and wherein a substantial portion of the warp ends, and even more preferably substantially all of the warp ends, are resiliently set in a spiral configuration with respect to the longitudinal axis of the shaped product.
As is known to those skilled in the art, many filamentary materials of construction are capable of being provided with a resilient set. Thus, it is contemplated that a large number of materials are adaptable for use in forming the resiliently settable filaments hereof. For example, many structural metals and engineering plastics will assume a permanent set when stressed above their elastic limit at room temperature. In general, however, it is expected that the filamentary material of the present invention will be provided with a resilient set or bias by the application of heat, pressure, irradiation, chemical reagents and combinations of these.
While it is contemplated that metals and natural fibers may be used for the resiliently settable filaments hereof, it is generally preferred that such filaments comprise synthetic fibers, and even more preferably synthetic fibers constructed from the class of materials known as thermoplastic resins. In general, thermoplastic resins are polymeric materials that soften or melt at elevated temperatures, thus allowing them to be processed into shapes and products that, when cooled, recover the physical and chemical properties of the original resin. In addition, this class of materials generally has a good balance of high tensile properties, compressive and shear strength, as well as impact resistance. Exemplary thermoplastic resins are polyamides, polyesters, and polyolefins, with polyamides and polyesters being preferred.
Filaments comprised of thermoplastic resins of the type described may be cause to take a resilient, permanent set by forming a product comprised of the plastic material to a specific geometry, for example, a circular or spiral shape, and then modifying the properties of the material. As
mentioned above, this is usually accomplished by the
application of heat to raise its temperature to a point either above the glass transition temperature or above the softening point. The shaped product is then cooled so as to
recrystallize or "set" the filamentary material. The product thereafter has a resilient set or bias (sometimes called an "elastic memory") in the shape in which it was formed, as is well recognized by those of ordinary skill in the art. Although the application of heat is the usual and most widely employed method of producing the set or bias, it should also be recognized that other, eg., chemical or physical, methods may sometimes be employed. For example, such a set may be provided to filamentary material comprising polyethylene by irradiating the shaped product so as to cross-link the
polyethylene chains. Such cross-linking may be accelerated or enhanced by the inclusion of cross-linking promoters in the polymeric material.
It is contemplated that the resiliently settable filaments used in the fabrics of the present invention may vary widely both as to type and dimension. In particular, it is contemplated that the resiliently settable filaments may include multi-filament yarns and threads, monofilament yarns and threads or mixtures of these types of filaments, with monofilaments being preferred.
It will be appreciated that filamentary material other than the resiliently settable material described above may be included with advantage in the shaped fabrics of the present invention. For example, it may be beneficial to include filaments comprised of fluorocarbon polymer resin to impart low friction characteristics to the shaped products. Moreover, combinations of engineering plastic materials and yarns or strands or filaments comprised of metals or mineral materials may be used. Thus, it is contemplated that the present fabrics may comprise, in addition to the resiliently settable filaments hereof, other natural and synthetic
filaments which contribute but do not detract from the
properties of the present shaped products.
A first embodiment of shaped-fabric product of the present invention will now be described in connection with Figs. 1 and 2. The shaped fabric product, designated
generally as 10, comprises a woven tubular product having a circular cross-section. The tubular product comprises a wall portion 11 forming a hollow chamber 12. In use, the hollow chamber 12 is filled by an elongate substrate which is to be protected by the shaped fabric 10. Wall portion 11 of shaped product 10 comprises fill ends 13 interlaced with warp ends 14. Fill ends 13 are in the shape of circular hoops or bands having a diameter equivalent to about the diameter of the wall portion 11 of tubular product 10. Warp ends 14 are
resiliently set in a spiral configuration with respect to the longitudinal axis z of tubular product 10.
It will be appreciated that numerous and varied methods may be employed to obtain a tubular product of the type disclosed in Figs. 1 and 2, and the use of all such methods is within the scope hereof. According to the method aspects of the present invention, however, the tubular product is constructed by first providing a woven tubular product in which the fill ends lie in a plane which is substantially perpendicular to the axis of the tube and in which the warp ends lie in a plane which is substantially parallel to the axis of the tube. Numerous techniques are available for providing such a product, and all such techniques are within the scope hereof. For example, such a tubular product may be provided by first providing a rectangular sheet of woven fabric in which the fill ends are substantially parallel to the short edge of the sheet and the warp ends are
substantially parallel to the long edge of the woven sheet. The long edges of this woven rectangular sheet are then joined according to any one of several well-known techniques, such as sewing, to form a woven product which is continuous along its short edge. It will be appreciated that other methods and techniques are known and available for forming woven fabrics which are continuous along their short edge. For example, certain weaving equipment, such as narrow fabric needle looms, are readily adapted to produce such woven products. The woven products can then be formed into a tubular configuration by, for example, placing the product over a cylindrical mandrel.
It will be appreciated that the formation of tubular products using narrow fabric needle looms as indicated herein produces woven tubular products in which a single fill end is knitted to itself to form interconnected resilient hoops disposed in a plane which is substantially perpendicular to the axis of the tube.
The methods of the present invention further
comprise resiliently setting the warp ends of the provided tubular product in a spiral configuration relative to the axis of the tube. This step preferably comprises rotating a first portion of the tubular product about its longitudinal axis while preventing a second portion of the tubular product from rotating. In this way, the warp ends of the woven product are twisted into a spiral configuration with respect to the axis of the tube. Once in the spiral configuration, the warp ends may be resiliently set according to techniques of the type described above to retain the spiral configuration. According to especially preferred embodiments, the fill ends 13 are also comprised of resiliently settable material, and the step of resiliently setting the warp ends in the spiral configuration will also provide the preferred step of resiliently setting the fill ends in the form of a circular hoop.
The present invention is not limited to continuous tubular products of the type illustrated in Fig. 1. For example, a second embodiment of the present invention provides tubular products which are discontinuous in the
circumferential direction as illustrated in Fig. 3. It will be appreciated by those skilled in the art that tubular products of the present invention which are discontinuous in the circumferential direction have certain advantages,
especially when the wall portion of the tubular product includes resiliently set fill ends in the form of hoops or bands. For example, the discontinuity imparted to products of the type illustrated in Fig. 3 permits the tubular product to be readily opened in the circumferential direction, thereby providing easy assembly of the protective cover around the substrate to be protected. Furthermore, because of the resiliently set circumferential hoops provided by fill ends 13, such a tubular product will return resiliently to its relatively closed configuration, thereby providing protection to the enclosed substrate, as illustrated in Fig. 4. It will be appreciated that tubular products which are discontinuous in the circumferential direction may be prepared according to various techniques, and all such techniques are within the scope of the present invention. For example, tubular products of the type disclosed in Fig. 3 may be prepared by providing a longitudinal cut or slit in the wall portion 12 of the tubular product, thereby producing a tubular product having adjacent longitudinal edges. While such a cut or slit will provide the advantages described above, it may also have disadvantages in some applications. For example, the simple provision of a cut or a slit
longitudinally of the tube may leave a small gap or opening in the tube wall. This small gap or opening may be a
disadvantage for applications which require that the enclosed substrate be completely mechanically isolated from the
environment. According to certain embodiments of the present invention, therefore, it is preferred that the longitudinal edges 15 and 16 of the discontinuous tubular product overlap one another in the radial direction, as illustrated in Fig. 3. This overlap may be provided using any one of several
processing techniques. In general, however, it is
contemplated that the tubular product will be radially
compressed so as to provide overlap between edges 15 and 16 and subsequently heat set in this compressed position. For example, the discontinuous tubular product may be provided to a folder of well a known design and heated, preferably
simultaneously heated, to provide edges 15 and 16 in a heat set, overlapped position. As an alternative example, the discontinuous tubular product may be wrapped around a mandrel having a diameter smaller than the inner diameter of the discontinuous tube such that overlap of the longitudinal edges occurs. The overlapped configuration is then set into the tube, such as by the application of heat to the mandrel.
While it is contemplated that the tubular products of the present invention may be provided in a wide variety of shapes and sizes, it is generally preferr8d that tubular products are substantially circular m cross-section and have an inner diameter of about 0.25 inch to about 4 inches.
Furthermore, it is generally preferred that the warp and fill threads of the present invention are monofilaments having a diameter of from about 5 to about 15 mil with about 8 to about 10 mil being preferred.
Shaped fabric products, particularly tubular fabrics for use in casing and covering elongated substrates, according to the present invention exhibit exceptional and altogether unexpected results. For example, one important characteristic of the shaped articles of the present invention is the
excellent abrasion resistance thereof. The following
examples, which are set forth by way of illustration but not by way of limitation, describe the improvements in abrasion resistance which are achieved according to the present
invention as compared to typical prior art products. In each of the examples which follows, abrasion tests were performed utilizing established standard test criteria for the
evaluation of chaff guards intended to provide from abrasion and chaffing of hose assemblies and adjacent components, as set forth by the Society of Automotive Engineers, Inc.
according to "Aerospace Recommended Practice" (ARP 15-36A), issued December 1978, revised February 1981, which are
incorporated herein by reference. In particular, each tubular fabric being tested was installed over a stainless steel mandrel, approximately 15 inches long. The mandrel and tubular product were restrained by suitable clamps and
fittings according to the specified criteria. The tests were operated under ambient temperature conditions. An abrasive element comprising a 0.50 inch precision ground drill rod (QQ-T-580) with a specific heat treatment of 60-64 HRC hardness and a surface finish of R 16 μ in (0.40 μm) was applied to the outer surface of the tubular fabric with a total force of about 5 pounds. The abrasive force was then reciprocated longitudinally across the tubular product at a rate of about 200 cycles per minute through a total stroke of about 3 inch. In the test results, failure of the protective cover is established as a wearing through of the cover by the abrasion element. Such a failure is determined by the abrasive element contacting the metal reinforcement of the hose assembly after wear through of the fabric product, thus closing an electrical circuit which stops the tester.
COMPARATIVE EXAMPLE 1
A braided tubular product having an inner diameter of about 0.5 inch comprising polyester monofilament having a diameter of about .010 inch and a braid pattern of one over, one under was subject to an abrasion test according to the procedure described above. The tubular product was
substantially circular in cross-section and had an inner diameter of about 0.5 inch. Such a product is generally available under the trade designation EXPANDO®. A series of three tests of the type described above were carried out. The results of this test are described in connection with Table 1 below.
Table 1
Run # Cycles to Failure
1 13,800
2 9,700
3 14,600
Avg. 12,700
EXAMPLE 1
A woven tubular product according to the present invention was subject to an abrasion test according to the procedure described above. The woven product comprised polyester monofilament fill threads having a diameter of about 0.009 inch and polyester monofilament warp threads having a diameter of about .010 inch in a 2-2 twill pattern. The tubular product was substantially circular in cross-section and had an inner diameter of about 0.5 inch. The fill threads were all resiliently set by the application of heat in the form of a substantially circular hoop having a diameter of about 0.52 inch. The warp threads were all resiliently set by the application of heat in a spiral configuration having a pitch of about 0.2 turns per inch. A series of three tests of the type described above were carried out. The results of this test are described in connection with Table 2 below.
Table 2
Run # Cycles to Failure
1 56,500
2 50,400
3 62,600
Avg. 56,500

Claims

1. A flexible, abrasion- and kink-resistant tubular product for protecting conduit, cable and like
elongated substrates comprising a woven tube having a
substantially circular cross-sectional configuration, an ARP abrasion resistance of at least about 25,000 cycles and a wall portion comprising:
(a) a filamentary fill end comprising
interconnected resiliently set hoops disposed in a plane substantially perpendicular to the axis of the tube; and
(b) a filamentary warp end interwoven with said fill end and heat set in a spiral configuration having a pitch of from about 0.2 to about 0.3 turns per longitudinal inch of tubular product.
2. The tubular product of claim 1 wherein said filamentary fill end and said filamentary warp end each comprise a synthetic monofilament.
3. The tubular product of claim 1 wherein said tubular product is discontinuous in the circumferential direction.
4. The tubular product of claim 1 wherein said fill ends and said warp ends each comprise filament formed of thermoplastic resin.
5. The tubular product of claim 1 wherein said filamentary fill end and said filamentary warp end each
comprise a monofilament of thermoplastic resin selected from the group consisting of polyamides, polyesters and
combinations of these.
6. The tubular product of claim 1 wherein said wall portion consists essentially of one or more of said
filamentary fill ends and one or more of said filamentary warp ends.
7. A tubular fabric product for protecting
conduit, cable and like elongate substrates, said product comprising a wall portion comprising first filamentary
material resiliently set in the form of a plurality of hoops disposed in a plane substantially perpendicular to the
longitudinal axis of the tube and second filamentary material interlaced with said first filamentary material and
resiliently set in a spiral configuration with respect to the axis of the tube.
8. The tubular fabric product of claim 7 comprising a woven tubular product.
9. The tubular fabric product of claim 7 comprising a tubular product having a substantially circular cross-section with an inner diameter of from about 0.25 inch to about 4 inches.
10. The tubular fabric of claim 7 wherein said second filamentary material has a pitch of no greater than 0.4 turns per inch of longitudinal length.
11. The tubular fabric product of claim 7 wherein first and second filamentary materials each comprise
thermoplastic filaments.
12. The tubular fabric product of claim 11 wherein said first and second filamentary material each comprise monofilament.
13. A flexible, abrasion- and kink-resistant shaped fabric product comprising a wall portion comprised of
filamentary material resiliently set in a spiral configuration with respect to the longitudinal axis of the shaped product.
14. The shaped fabric product of claim 13 comprising a woven product.
15. The shaped fabric product of claim 13 comprising a woven tube having a substantially circular cross- sectional configuration.
16. The shaped fabric product of claim 13 wherein said product has an ARP abrasion resistance of at least about 25,000 cycles.
17. The shaped fabric product of claim 13 wherein said product is a woven product and said spirally set
filamentary material comprises a filamentary warp end of said product.
18. The shaped fabric product of claim 17 wherein said woven product consists essentially of one or more warp ends and one or more fill ends and wherein substantially all of said warp ends are spirally set filamentary material.
19. The shaped fabric product of claim 18 wherein said one or more fill ends are resiliently set in the form of a plurality of hoops disposed in a plane substantially
perpendicular to the longitudinal axis of the shaped fabric.
20. The shaped fabric product of claim 19 wherein said one or more fill ends consist essentially of a single fill end in the form of interconnected resiliently set hoops, each hoop being substantially disposed in a plane
substantially perpendicular to the axis of the shaped product.
21. A method of making a tubular product
comprising:
(a) providing a fabric of interlaced filamentary material, at least a portion of said filamentary material being resiliently settable; and
(b) resiliently setting at least a portion of said settable filaments in the form of a spiral configuration with respect to the longitudinal axis of the tube.
22. The method of claim 21 wherein said providing step comprises providing a woven product.
23. The method of claim 21 wherein said providing step comprises providing a woven tubular product having a substantially circular cross-sectional configuration.
24. The method of claim 21 wherein said setting step comprises forming said filament in said spiral
configuration and then heat setting said filament in said configuration.
25. The method of claim 21 wherein:
(a) said providing step comprises providing a woven tubular product consisting essentially of substantially longitudinal warp filaments and one or more circumferential fill filaments; and
(b) said setting step comprises:
(i) twisting said tubular product to place said warp filaments in a spiral configuration relative to the axis of the tube; and
(ii) heat setting said warp filaments in said spiral configuration.
26. The method of claim 25 wherein said providing step comprises providing a circumferentially discontinuous tubular product having first and second longitudinal edges and said setting step comprises: (i) radially compressing said tubular product to provide radial overlap of said longitudinal edges; and (ii) heat setting said resiliently settable fill filaments in said overlapped configuration.
27. The method of claim 21 wherein said fill filaments comprise resiliently settable filaments and said setting step comprises heat setting said resiliently settable fill filaments in the form of a plurality of hoops disposed in a plane substantially perpendicular to the longitudinal axis of the shaped fabric.
PCT/GB1992/002003 1991-11-05 1992-11-02 Shaped fabric products and methods of making same WO1993009281A1 (en)

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KR1019940701456A KR940702956A (en) 1991-11-05 1992-11-02 Shaped textile products and manufacturing method thereof
EP92922758A EP0611404B1 (en) 1991-11-05 1992-11-02 Shaped fabric products and methods of making same
KR1019940701456A KR100322737B1 (en) 1991-11-05 1992-11-02 Fabric sleeves
DE69219785T DE69219785T2 (en) 1991-11-05 1992-11-02 PROFILED FABRIC AND METHOD FOR PRODUCING IT

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ES2101125T3 (en) 1997-07-01
US5413149A (en) 1995-05-09
CA2122733A1 (en) 1993-05-13
JPH07500882A (en) 1995-01-26
DE69219785T2 (en) 1997-12-18
JP2718571B2 (en) 1998-02-25
EP0611404A1 (en) 1994-08-24
EP0611404B1 (en) 1997-05-14
MX9206347A (en) 1993-10-01
US5556495A (en) 1996-09-17
KR940702956A (en) 1994-09-17

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