US4888120A - Water-based drilling and well-servicing fluids with swellable, synthetic layer silicates - Google Patents
Water-based drilling and well-servicing fluids with swellable, synthetic layer silicates Download PDFInfo
- Publication number
- US4888120A US4888120A US07/094,635 US9463587A US4888120A US 4888120 A US4888120 A US 4888120A US 9463587 A US9463587 A US 9463587A US 4888120 A US4888120 A US 4888120A
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- US
- United States
- Prior art keywords
- fluid
- well
- weight
- hectorite
- sub
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000012530 fluid Substances 0.000 title claims abstract description 113
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000005553 drilling Methods 0.000 title claims description 30
- 150000004760 silicates Chemical class 0.000 title abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 12
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 25
- 229910000271 hectorite Inorganic materials 0.000 claims description 25
- 229920001059 synthetic polymer Polymers 0.000 claims description 21
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 9
- 230000008719 thickening Effects 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 150000004676 glycans Chemical class 0.000 claims description 6
- 229920001282 polysaccharide Polymers 0.000 claims description 6
- 239000005017 polysaccharide Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 6
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 15
- 239000004927 clay Substances 0.000 claims 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- 206010037660 Pyrexia Diseases 0.000 claims 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 abstract description 5
- 235000012216 bentonite Nutrition 0.000 description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 13
- 239000000440 bentonite Substances 0.000 description 13
- 229910000278 bentonite Inorganic materials 0.000 description 13
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000008399 tap water Substances 0.000 description 9
- 235000020679 tap water Nutrition 0.000 description 9
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 7
- 239000010428 baryte Substances 0.000 description 7
- 229910052601 baryte Inorganic materials 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- 230000009974 thixotropic effect Effects 0.000 description 7
- 239000008186 active pharmaceutical agent Substances 0.000 description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000010335 hydrothermal treatment Methods 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- 229910004742 Na2 O Inorganic materials 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- -1 hectorites Chemical class 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229920005613 synthetic organic polymer Polymers 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- ANCPBLUIOKGULL-UHFFFAOYSA-N 2-methylidene-3-oxopent-4-enamide Chemical group NC(=O)C(=C)C(=O)C=C ANCPBLUIOKGULL-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910011763 Li2 O Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 229940021013 electrolyte solution Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical class C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 229910000269 smectite group Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/145—Clay-containing compositions characterised by the composition of the clay
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/901—Organically modified inorganic solid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/922—Fracture fluid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/927—Well cleaning fluid
- Y10S507/928—Spacing slug or preflush fluid
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Lubricants (AREA)
Abstract
MgO.aMA.bAl.sub.2 O.sub.3.cSiO.sub.2.nH.sub.2 O (I)
Description
MgO.aMA.bAl.sub.2 O.sub.3.cSiO.sub.2.nH.sub.2 O (I)
TABLE I ______________________________________ Viscosities (mPa.s) at Viscosities (mPa.s) at hectorite concentrations bentonite concentrations 1.0% 2.0% 2.5% 2.5% ______________________________________ Tapwater 30 2550 2750 152 2.5% NaCl 400 50 2.5% CaCl.sub.2 350 43 swelling time for all solutions: 8 hours ______________________________________
TABLE II ______________________________________ Temperature Viscosity (mPa.s) ______________________________________ Before temperature stressing 4950 (25° C. starting value) 200° C. 5100 250° C. 5350 300° C. 5500 350° C. 5450 ______________________________________
TABLE III ______________________________________ Drilling fluid API fluid loss (ml) ______________________________________ a 3.0 b 3.0 c >100 ______________________________________
TABLE IV ______________________________________ Drilling Fluid A B C ______________________________________ Apparent viscosity (mPa.s) 9 9.5 12.5 Plastic viscosity (mPa.s) 7.5 6 9 Yield value (lbs/100 ft.sup.2) 2.5 7 7 Gel strength (lbs/100 ft.sup.2) 10" 2 3 5 Gel strength (lbs/100 ft.sup.2) 10' 10 14 8 HTHP fluid loss after 30 mins. (ml) 3.6 3.5 4 ______________________________________
TABLE V ______________________________________ Comparison between natural and synthetic hectorite Brookfield viscosity, Product spindle 2 (20 r.p.m.) ______________________________________ 2.5% by weight natural hectorite 10 mPa.s in distilled water 2.5% by weight natural hectorite 160 mPa.s in tapwater 2.5% by weight synthetic hectorite >600 mPa.s in distilled water 2.5% by weight synthetic hectorite 15,000 mPa.s in tapwater ______________________________________
TABLE VI ______________________________________ Comparison of drilling fluids a b c d ______________________________________ Apparent viscosity 52 24 15 14 (mPa.s) Plastic viscosity 41 28 15.5 15 (mPa.s) Yield value 31 -- -- -- (lbs/100 ft.sup.2) API fluid loss 1.5 15 3 80 (30 mins) (ml) API fluid loss 3 25 8 12 (30 mins) after aging for 16 hours at 177° C. (ml) Evaluation no barite complete complete complete sedimen- barite barite barite tation sedimen- sedimen- sedimen- tation tation tation ______________________________________
TABLE VIII ______________________________________ Rheological data of synthetic hectorite solution at 30 to 200° C. pH 11 (adjusted with NaOH) pH 11 (adjusted with LiOH) plastic Bingham plastic Bingham Measurement viscosity yield value viscosity yield value temperature (mPa.s) (dPa) (mPa.s) (dPa) ______________________________________ 30 5 12 6 11 50 4 11 5 17 80 4 15 4 19 100 4 15 3 16 150 2 12 2 15 200 2 10 2 11 ______________________________________
Claims (37)
MgO.aMA.bAl.sub.2 O.sub.3.cSiO.sub.2.nH.sub.2 O (I)
MgO.aMA.bAl.sub.2 O.sub.3.cSiO.sub.2.nH.sub.2 O (I)
MgO.aMA.bAl.sub.2 O.sub.3.cSiO.sub.2.nH.sub.2 O (I)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3631764 | 1986-09-18 | ||
DE19863631764 DE3631764A1 (en) | 1986-09-18 | 1986-09-18 | USE OF SWELLABLE, SYNTHETIC LAYERED SILICATES IN AQUEOUS DRILL RING AND HOLE TREATMENT AGENTS |
Publications (1)
Publication Number | Publication Date |
---|---|
US4888120A true US4888120A (en) | 1989-12-19 |
Family
ID=6309853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/094,635 Expired - Fee Related US4888120A (en) | 1986-09-18 | 1987-09-09 | Water-based drilling and well-servicing fluids with swellable, synthetic layer silicates |
Country Status (9)
Country | Link |
---|---|
US (1) | US4888120A (en) |
EP (1) | EP0260538B2 (en) |
AT (1) | ATE63132T1 (en) |
BR (1) | BR8704798A (en) |
CA (1) | CA1296513C (en) |
DE (2) | DE3631764A1 (en) |
ES (1) | ES2022239B3 (en) |
GR (1) | GR3001896T3 (en) |
MX (1) | MX169678B (en) |
Cited By (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4968728A (en) * | 1986-06-17 | 1990-11-06 | J.M. Huber Corporation | Synthetic alkali metal alumino-silicates, methods and uses, compositions and their methods of preparation |
US4990270A (en) * | 1988-12-19 | 1991-02-05 | Meister John J | Water soluble graft copolymers of lignin methods of making the same and uses therefore |
US5028342A (en) * | 1988-09-29 | 1991-07-02 | Henkel Kommanditgesellschaft Auf Aktien | Drilling mud additives based on a polymer mixture, their use, and a process for their production |
US5397560A (en) * | 1993-04-06 | 1995-03-14 | The Dow Chemical Company | Microporous crystalline aluminosilicate designated DCM-2 |
US5663122A (en) * | 1992-07-27 | 1997-09-02 | Henkel Kommanditgesellschaft Auf Aktien | Mineral additives for setting and/or controlling the rheological properties and gel structure of aqueous liquid phases and the use of such additives |
EP0813105A1 (en) * | 1996-06-13 | 1997-12-17 | Agfa-Gevaert N.V. | Recording materials and method for manufacturing said materials coated from hydrophilic layers having no gelatin or low amounts of gelatin |
US5711383A (en) * | 1996-04-19 | 1998-01-27 | Halliburton Company | Cementitious well drilling fluids and methods |
US5789352A (en) * | 1996-06-19 | 1998-08-04 | Halliburton Company | Well completion spacer fluids and methods |
US5866517A (en) * | 1996-06-19 | 1999-02-02 | Atlantic Richfield Company | Method and spacer fluid composition for displacing drilling fluid from a wellbore |
US5874387A (en) * | 1996-06-19 | 1999-02-23 | Atlantic Richfield Company | Method and cement-drilling fluid cement composition for cementing a wellbore |
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EP3601474A4 (en) * | 2017-03-20 | 2020-04-08 | Baker Hughes, a GE company, LLC | Viscosity modifiers and methods of use thereof |
CN109749721A (en) * | 2017-11-01 | 2019-05-14 | 中国石油化工股份有限公司 | A kind of container horizon protective agent and preparation method suitable for low permeability gas reservoirs |
CN109749721B (en) * | 2017-11-01 | 2021-01-08 | 中国石油化工股份有限公司 | Reservoir protection agent suitable for low-permeability gas reservoir and preparation method |
CN112639048A (en) * | 2018-09-04 | 2021-04-09 | 沙特阿拉伯石油公司 | Synthetic functionalized additives, methods of synthesis, and methods of use |
Also Published As
Publication number | Publication date |
---|---|
DE3769735D1 (en) | 1991-06-06 |
EP0260538B2 (en) | 1994-01-19 |
MX169678B (en) | 1993-07-19 |
EP0260538A2 (en) | 1988-03-23 |
ES2022239B3 (en) | 1991-12-01 |
ATE63132T1 (en) | 1991-05-15 |
EP0260538B1 (en) | 1991-05-02 |
DE3631764C2 (en) | 1990-08-09 |
CA1296513C (en) | 1992-03-03 |
DE3631764A1 (en) | 1988-03-24 |
GR3001896T3 (en) | 1992-11-23 |
BR8704798A (en) | 1988-05-17 |
EP0260538A3 (en) | 1989-11-15 |
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