US4438253A - Poly(glycolic acid)/poly(alkylene glycol) block copolymers and method of manufacturing the same - Google Patents
Poly(glycolic acid)/poly(alkylene glycol) block copolymers and method of manufacturing the same Download PDFInfo
- Publication number
- US4438253A US4438253A US06/441,306 US44130682A US4438253A US 4438253 A US4438253 A US 4438253A US 44130682 A US44130682 A US 44130682A US 4438253 A US4438253 A US 4438253A
- Authority
- US
- United States
- Prior art keywords
- poly
- copolymer
- surgical
- suture
- glycolic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L17/00—Materials for surgical sutures or for ligaturing blood vessels ; Materials for prostheses or catheters
- A61L17/06—At least partially resorbable materials
- A61L17/10—At least partially resorbable materials containing macromolecular materials
- A61L17/12—Homopolymers or copolymers of glycolic acid or lactic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/04—Macromolecular materials
- A61L31/06—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
Description
TABLE I ______________________________________ Properties of PGA/POE Block Copolymers* Ex- Wt. % Wt. % am- Mol. Wt. POE POE η inh ple of POE Charged by NMR (HFAS) Tg Tm ______________________________________ 1 4000 15 12 0.47 29° 217-220° 2 4000 20 -- 0.46 -- -- 3 1000 7.5 6.3 0.43 -- -- 4 4000 15 -- 0.64 -- -- 5 4000 20 16 0.54 24° 219° PGA -- 0 -- 1.07 43° 218-220° PGA -- 0 -- 0.60 38° 221° ______________________________________ *All Data on reprecipitated samples.
Claims (12)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/441,306 US4438253A (en) | 1982-11-12 | 1982-11-12 | Poly(glycolic acid)/poly(alkylene glycol) block copolymers and method of manufacturing the same |
EP83109964A EP0108912B1 (en) | 1982-11-12 | 1983-10-05 | Poly(glycolic acid)/poly(alkylene glycol)block copolymers and method of manufacturing the same |
DE8383109964T DE3378371D1 (en) | 1982-11-12 | 1983-10-05 | Poly(glycolic acid)/poly(alkylene glycol)block copolymers and method of manufacturing the same |
JP58210042A JPS59100131A (en) | 1982-11-12 | 1983-11-10 | Poly(glycolic acid)/poly(alkylene glycol) block copolymer and manufacture |
CA000440921A CA1205235A (en) | 1982-11-12 | 1983-11-10 | Poly(glycolic acid)/poly(alkylene glycol)block copolymers and method of manufacturing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/441,306 US4438253A (en) | 1982-11-12 | 1982-11-12 | Poly(glycolic acid)/poly(alkylene glycol) block copolymers and method of manufacturing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
US4438253A true US4438253A (en) | 1984-03-20 |
Family
ID=23752379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/441,306 Expired - Lifetime US4438253A (en) | 1982-11-12 | 1982-11-12 | Poly(glycolic acid)/poly(alkylene glycol) block copolymers and method of manufacturing the same |
Country Status (5)
Country | Link |
---|---|
US (1) | US4438253A (en) |
EP (1) | EP0108912B1 (en) |
JP (1) | JPS59100131A (en) |
CA (1) | CA1205235A (en) |
DE (1) | DE3378371D1 (en) |
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CA1205235A (en) | 1986-05-27 |
JPS59100131A (en) | 1984-06-09 |
DE3378371D1 (en) | 1988-12-08 |
JPH0463893B2 (en) | 1992-10-13 |
EP0108912B1 (en) | 1988-11-02 |
EP0108912A2 (en) | 1984-05-23 |
EP0108912A3 (en) | 1985-10-23 |
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