|Publication number||US3924929 A|
|Publication date||9 Dec 1975|
|Filing date||6 Mar 1972|
|Priority date||14 Nov 1966|
|Publication number||US 3924929 A, US 3924929A, US-A-3924929, US3924929 A, US3924929A|
|Inventors||Holmen Reynold E, Nellessen Alfred H|
|Original Assignee||Minnesota Mining & Mfg|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (4), Referenced by (173), Classifications (14), Legal Events (1)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent 1191 Holmen et al.
[ Dec. 9, 1975 RETRO-REFLECTIVE SHEET MATERIAL  Inventors: Reynold E. Holmen, White Bear Lake; Alfred H. Nellessen, Roseville, both of Minn.
[ 73] Assignee: Minnesota Mining & Manufacturing Company, St. Paul, Minn.
 Filed: Mar. 6, 1972  Appl. No.: 232,023
Related U.S. Application Data  Continuation of Ser. No. 594,137, Nov. 14, 1966,
 U.S. Cl. 350/103; 350/67; 94/15  Int. Cl. G02B 5/12  Field of Search 40/135; 350/67, 97-109; 94/ 1.5
 References Cited UNITED STATES PATENTS 322,151 5/1943 Swarovsko 350/103 2,037,773 4/1936 Egnon 40/208 3,140,340 7/1964 Weber 350/103 3,359,671 12/1967 Nier et al. 350/103 FOREIGN PATENTS OR APPLICATIONS 987,243 3/1965 United Kingdom 350/67 547,786 9/1956 Italy 350/101 Primary ExaminerRonald L. Wibert Assistant ExaminerMichael J. Tokar Attorney, Agent, or Firm-Alexander, Sell, Steldt & DeLal-lunt [5 7] ABSTRACT A retro-reflective article having a retro-reflectivity of at least 400 candle power per foot candle per square foot when measured by a detector at an angle of 0.2 degrees divergence from an incident light beam and having a plurality of cube'corner retro-reflecting units and septa embossed on one surface, the septa being disposed to divide said surface into a multiplicity of separate sealable cells with a plurality of units in each cell.
9 Claims, 5 Drawing Figures U.S. Patent Dec. 9, 1975 3,924,929
RETRO-REFLECTIVE SHEET MATERIAL CROSS-REFERENCES TO RELATED APPLICATIONS This application is a continuation of application U.S. Ser. No. 594,137, filed Nov. 14, 1966, now abandoned.
BACKGROUND OF THE INVENTION This invention relates to a retro-reflecting sheet material, and in one aspect, to a cellular cube-corner retro-reflecting sheet material affording increased performance over prior known material.
The fundamental characteristic of reflex-reflecting or retro-reflecting material is its ability of returning back a brilliant cone of light toward the source of an angularly incident ray. This is to be distinguished from mirrors which cause specular reflection and from diffuse reflecting surfaces which scatter the incident light in all directions without selective return in the direction of incidence.
It has been conventional practice to form letters on highway signs by applying retro-reflective articles in the form of a multiplicity of unitary circular buttons upon a sign board. The buttons are arranged to block in or outline a letter, or other indicia. These buttons comprise a lens of transparent material, the rear surface of which is embossed with cube-corner retro-reflective units. A metal plate is usually sealed to the edges of the circular lens. These buttons commonly vary in diameter from one-half inch to seven inches (l3mm-l8cm). In arranging circular buttons however, to block in indicia, a large amount of the area to be covered is lost between the buttons with a resulting measurable decrease in brilliance over what might exist if the area were completely covered by such material. Further, when one of these buttons becomes damaged, allowing dirt or moisture to contaminate the cube-corner retroreflective units embossed on the rear surface thereof, the reflective properties of the entire button are soon lost. This further decreases the brilliance and legibility of the sign at night and eventually the sign requires maintenance.
Another commonly employed material is cube-corner sheeting which has a reflective metal coating on the side embossed with cube-corner retro-reflecting units. This coating materially decreases the brilliance of the sheeting and causes the same to appear undesirably dark during daylight hours.
The sheet material of the present invention would materially increase the brilliance of the indicia on a sign by increasing the unit area covered by a cube-corner retro-reflective material. At the same time, the sheet material of this invention is constructed so that far less maintenance on the signs is required. Further, the sheet material of the present invention may be cut to form letter copy, and time and material need not be utilized in edge sealing to protect the cube-corners from contamination by dust or moisture.
The material of this invention has an advantage over the cube-corner material which has the cube-corner rear surface vapor-coated and painted in that the material of this invention offers greater retro-reflective brilliance and does not appear to be dark in color during the daylight hours.
The material of the present invention affords these advantages because the cube-corner prism retroreflecting units in the material have a substantially continuous prism-air interface and the material has a novel multieellular structure. The cells afforded by the present invention are of a size such that the loss of the retro-reflectivity over the area of an occasional entire cell does not cause any significant decrease in total brilliance of a legend formed from our material. The built in cellular structure also permits cutting of the material to form the desired indicia or legends without the added operation of edge sealing.
The brilliant cellular retro-reflective sheet material of the present invention will have a great advantage in the making of signs for streets and highways. The present invention provides a material which will exhibit the high brilliance needed for long-range advance warning to motorists travelling at high speeds along the super highways. Also, this cellular structure provides a longlasting sign in that damage to a sign by vandals striking the same with pop bottles or rifle bullets will be limited to only those cells actually struck and broken by the force and will not involve a significant area of the entire indicia or legend as is the case with prior art unitary cube-corner sheeting or button-like structures.
Each sheet or plate of material constructed in accordance with the present invention includes at least three cells and each cell is polygonal and contains at least three cube-corner retro-reflecting units, whether said units are formed to represent. a cube section formed by a near diagonal cut of a cube or whether they contain three full square side walls of a cube and the included trihedral angle. The cell structure provides an improved material and the area thereof occupied by septa defining said cell should be kept to a minimum since the area so occupied is lost for retro-reflective purposes.
The present invention further provides a retro-reflective sheet material of any desired size from which indicia for signs may be cut. In a preferred embodiment the sheet material of this invention may be rolled or folded even though the cube-corners are embossed on a rigid transparent material. This is accomplished by adhering a multiplicity of mating small separate strips or platelike cube-corner articles in a predetermined close pattern on a flexible backing. The cube-corner articles are preferably aligned to place edges of the same in an axial alignment with respect to the direction the material will be rolled, or they may be aligned such that the same may be folded once along a joint.
These and other novel features and advantages will become more apparent after reading the following detailed description which relates to the accompanying drawing wherein:
FIG. 1 is a rear view of one cube-corner cellular retro-reflecting article formed in accordance with the present invention;
FIG. 2 is a rear view of another article formed in accordance with the present invention;
FIG. 3 is a fragmentary vertical sectional view of a retro-reflecting sheet material formed in accordance with the present invention;
FIG. 4 is an enlarged fragmentary rear view of an article formed in accordance with the present invention having cube-corner retro-reflecting units illustrating a second embodiment; and
FIG. 5 is a perspective view of a small sheet of material formed according to the present invention and partially rolled.
Referring now to the drawing, FIGS. 1 through 3 illustrate two articles generally designated 10 and 10a having different geometric shapes and formed with cells of different shapes in accordance with the present invention. Each article is monolithic and is made from a transparent polymeric solid material, for example polymethylmethacrylate, polystyrene, or celluloseacetate, by the use of suitable pressing or molding techniques known in the art. The articles and 10a have a smooth light receiving front face and the back face (shown in FIGS. 1 and 2) has embossed thereon a multiplicity of trihedral prismatic retro-reflecting units 11 and 11a separated into cells by interconnecting septa. In the preferred embodiment the front face and the free edges of the septa are disposed in parallel planes and the articles have a uniform thickness, although the articles could have curved faces or flat nonparallel faces to make the material less directional. The articles thus each have throughout an area within its perimeter a substantially smooth uninterrupted front face and the back face opposite said area is formed with units 11 and 11a and with intervening septa to form a plurality of cells.
The plate-like article 10 shown in FIG. 1 is trapezoidal in shape and is embossed with contiguous prismatic cube-corner retro-reflecting units 11, each being formed by three smooth planar surfaces meeting in a point and disposed at right angles to each other. Wall members or septa l2 border the plate 10 and are continuous with septa 13 which divide the article 10 into three similar cells, each cell of which includes three cube-corner retro-reflecting units 11. As illustrated, each of these retro-reflecting units is defined by planar surfaces amounting to substantially three complete sides of a cube.
FIG. 2 illustrates another embodiment of an article formed in accordance with the present invention wherein the article 10a is rectangular having septa 12a bordering the article and septa 13a dividing the article into separate rectangular cells also having a rectangular configuration and enclosing within each cell three or more contiguous cube-corner retro-reflecting units 11a. The lead lines on the numerals are directed to the points of the units.
It is desired that the cells be as small in size as possible but yet the reflectivity of an article must, as a practical matter, be sufficient such that the non-retroreflective areas caused by the septa forming a grid and the pattern of polygonal cells on the rear surface of the article do not constitute a greater area-than that defined by retro-reflecting units. Preferably the area of an article occupied by the septa is such that their area compared to the area occupied by retro-reflecting units results in a measure of the retro-reflectivity of at least 400 candle power per square foot (930 square centimeters) of area per foot candle of transmittible incident light measured at 0.2 degrees divergence from a light beam at 4 degrees incidence. The cells should therefore preferably have a retro-reflective area not less than 0.006 square inch (4 square millimeters) or greater than one square inch (6 square centimeters) and should include not less than 3 retro-reflecting units. The units may have a width, measured between centers of opposed edges of facets defining a cube corner retro-reflecting unit, of between about l/25 and inch (1mm and 10mm). The septa should have a free bondable edge surface of at least l/l00 inch (0.2mm) in width and preferably not over /a inch (3mm) and indeed never over A inch (6mm) wide, giving an area on the free edge of the septa sufficient to provide a bonding surface for the article to a backing sheet.
FIG. 3 illustrates a vertical section through an article such as 10a with a backing 16 bonded uninterruptedly to the free edges of the septa 12a and 13a. This backing 16 is preferably a material which is essentially vapor impermeable and durable when exposed to the weather. Examples of such materials for the backing are aluminum sheeting, galvanized steel, various laminates and/or durable polymeric film-like sheet materials suitably formed, for example, of polymethyl methacrylate, polyesters, polyamides, polyvinyl fluoride, polyvinyl chloride, or polychlorotrifluoroethylene. This backing may be flexible or rigid, but it must be hermetically bonded uninterruptedly to all the free edges of the septa providing a multiplicity of hermetically sealed cells which are each free from contamination by dust particles or moisture to maintain a substantially complete prism-air interface on the smooth facets of the retro-reflecting units 1111. There is no silvering or other reflective coating on the units. In fact, such coatings 1 only degrade or diminish the retro-reflectivity of the article.
The free edges of the septa form a grid and may be bonded to the backing by various means such as heat sealing (using a grid next to the backing corresponding to the pattern of the septa); adhesives, either pressure sensitive or heat or solvent activatable adhesives; or by using a solvent which attacks the septa to make the free edge tacky and, preferably, the backing material to thus form a bond. The adhesive may be applied to the face of the backing, to the face edges of the septa or to both. Further, a polymerizable syrup, e.g. methylmethacrylate syrup, could be applied to the backing or septa to bond the articles. It is important, however, to avoid exposure of the facets forming the retro-reflecting units to the solvents, adhesives or excessive heat.
It will be noted in FIG. 3 that the free edge surfaces of septa 12a and 13a are spaced rearwardly from the smooth front surface of the article a distance greater than peaks of the cube-corner reflecting units 11a. such that an air space is formed between the entire retroreflecting unit and the backing. As the size of the retroreflecting units increases beyond the H25 inch (lmm) size it becomes increasingly feasible to limit the rearward extentof the septa such that they terminate in edge surfaces. spaced from the front surface of the article only as far rearward as the rearmost points of the retro-reflecting units. The septa must bespaced at least as far as the rearmost points or the prism-air interface is disturbed by contact of the facets with the backing and when the backing is coated with an adhesive layer some degradation of the retro-reflective effect of the units occurs.
As shown in FIG. 3, for one cell, the voids formed between the article 10a and the backing 16 may, for example, be filled with a particulate material 17 affording a back filling to strengthen the construction of the sheeting without degradation of the retro-reflectivity of the material. The particulate material 17 maintains a substantially continuous prism-air interface with the facets of the cube-corner units because the particles afford substantially only point contact with said facets. Examples of such particulate material are glass bubbles, granules of calcium sulfate and pigments, preferably between 2 to I00 microns in size. The more nearly spherical the particulate, the larger the size of the particulate may be, within this range, without excessive surface contact. The particulate could be fused together, if desired, provided the point contact aforenoted is maintained.
FIG. 4 shows a fragmentary rear view of an article 1017 divided by septa 13b to place sixteen retro-reflecting units 115 within a cell. The units 11b are defined by 3 planar facets forming a point and intersecting each other at right angles. The facets are each less than a complete wall of a' cube but afford good retro-reflection and the groups of four cubec orners afford easy division of the article into cells each having cube-corners in some multiple of four, but the area of the cell should not be greater than 1 square inch (6 square centimeters).
A multiplicity of the articles, such as either 10, 10a or 10b, may be bonded to a flexible backing, such as a polyester or polyvinyl chloride web, affording a large sheet of cellular cube-corner retro-reflecting material from which indicia may be cut for forming a sign. A fragment of such a sheet 22 is illustrated in FIG. 5 with a plurality of articles 10a bonded to a flexible backing web 21. Such sheeting may be rolled with the adhered plate-like articles 10a aligned to permit folds to be formed therein which extend axially of the roll of material. The articles la are placed on the backing in such a manner that when placed on a flat article the edges of each adjacent plate-like article are contiguous to afford substantially complete coverage of the sign board upon which such sheeting may be attached. FIG. illustrates a plurality of rectangular articles such as are illustrated in FIG. 2 or in FIG. 3 positioned in aligned relationship along two adjacent edges of each article, allowing the same to be rolled or folded in either direction. Thus articles such as may be adhered to'a large flexible sheet or the article 10a may be suitably bonded to a rigid backing 16 which in turn may be adhered to a flexible web 21.
Sheeting, a portion of such as is illustrated in FIGS. 2, 3, 4 and 5, may be cut to form letters. This will obviously cause some to be cut and the respective hermetic seals to be broken. The cell size is such however that, even though the retro-reflecting units in a cut cell become contaminated and lose their retro-reflecting property, only small insignificant segments of a sign or legend are lost since the retro-reflective area of a cell preferably is not greater than one square inch (6 square centimeters).
Providing a substantially complete prism-air interface to the retro-reflective unit rather than coating the same with a reflective metal finish increases the efficiency of cube-corner units since all of the reflection of the light is carried on within the transparent material forming the cube-corner prism. Further, sheet material according to the present invention affords an advantage over reflective-coated cube-corner material in that the sheet of this invention does not have a darkened appearance in the daylight. Of course, colored transparent material of either a silver white, red or yellow will maintain its colored appearance satisfactorily in the daylight as well as under the artificial light at night.
Having thus disclosed the present invention by reference to the accompanying drawing, it is to be understood that modifications may be made herein without departing from the spirit or scope of the present invention.
What is claimed is:
l. A cellular reflector structure having a plurality of individual adjacent cells for providing improved vandal-resistant reflectors, signs and legends having high retroreflectivity and good'daytime color appearance, said reflector structure comprising a monolithic body of transparent material having a light receiving from face having a smooth uninterrupted surface area extending over adjacent cells and i a rear face having a rear surface area immediately opposite and coextensive with said uninterrupted front surface area, said rear surface area having a plurality of intersecting septa visible from said front face defining and isolating a plurality of polygonal cells each from the other and having a plurality of cube-corner retroreflecting units each having a set of three mutually perpendicular facets, each said cell having an area not greater than about one square inch and containing at least three of said cube-corner retroreflecting units and the combined area within said cells being not less than the combined area of said septa, said septa having 1 continuous free edges positioned rearward of the front face at least as far as said cube-corner retroreflecting units, which free edges permit the structure to be affixed to a backing to hermetically seal the cells individually,
said cube-corner retroreflecting units being oriented in said cells to reflect light falling upon them through said front face back toward the source thereof to render said reflector structure highly visible at night and said septa improving the day time appearance of the structure.
2. A reflector structure according to claim 1 wherein a backing is hermetically bonded uninterruptedly to all the free edges of said septa to form a plurality of hermetically sealed cellsenclosing said cube-corner retroreflecting units.
3. A reflector structure according to claim 1 wherein the hermetically sealed cells contain a particulate material of a size to afford substantially only point contact with the facets defining said cube-corner retro-reflecting units.
4. A cellular reflector structure having a plurality of individual adjacent cells for providing improved vandal-resistant reflectors, signs and legends having high retro-reflectivity and good daytime color appearance, said reflector structure comprising a monolithic body of transparent material having a light receiving front face having a smooth uninter rupted surface area extending over adjacent cells and a rear face having a rear surface area immediately opposite and coextensive with said uninterrupted front surface area, said rear surface area having a plurality of intersecting septa visible from said front face defining and isolating a plurality of polygonal cells each from the other and having a plurality of cube-corner retroreflecting units each having a set of three mutually perpendicular facets, each said cell having an area not greater than about one square inch and containing at least three of said cube-corner retroreflecting units and the combined area within said cells being not less than the combined area of said septa such that the retroreflectivity of said body is at least 400 candle power per square foot of area per foot candle of transmittable incident light, said septa having continuous free edges positioned rear-ward of the front face at least as far as said cube-corner retroreflecting units, which free edges permit the structure to be affixed to a backing to hermetically seal the cells individually,
said cube-corner retroreflecting units being oriented in said cells to reflect light falling upon them through said front face back toward the source thereof to render said reflector structure highly visible at night and said septa improving the day time appearance of the structure.
5. A retro-reflective article according to claim 4 wherein said article is of uniform thickness with said front surface smooth and planar, and with said free edges of said septa disposed in a plane parallel to said front face.
6. A retroreflective sheet material having a plurality of individual adjacent cells for providing improved vandal-resistant reflectors, signs and legends having high retroreflectivity and good daytime color appearance, said sheet material comprising a monolithic article of transparent material having a light receiving front face having a smooth uninterrupted surface area extending over adjacent cells and a rear face having a rear surface area immediately opposite and coextensive with said uninterrupted front surface area, said rear surface area having a plurality of intersecting septa visible from said front face defining and isolating a plurality of polygonal cells each from the other and having a plurality of cube-corner,retroreflecting units each having a set of three mutually perpendicular facets, each said cell having an area not greater than about one square inch and containing at least three of said cube-corner retroreflecting units and the combined area within said cells being not less than the combined area of said septa, said septa having continuous free edges positioned rearward of the front face at least as far as said cube-corner retroflecting units, which free edges permit the structure to be affixed to a backing to hermetically seal the cells individually, said cube-corner retroflecting units being oriented in said cells to reflect light falling upon them through said front face back toward the source thereof to render said reflector structure highly visible at night and said septa improving the daytime appearance of the structure, and
a backing hermetically bonded uninterruptedly to all the free edges of said septa of said monolithic article to form hermetically sealed cells enclosing said cube-corner units.
7. A retro-reflective sheet material according to claim 6 wherein said article is plate-like having a uniform thickness with said front surface being planar and with said cells having a uniform .size.
8. A retro-reflective sheet material according to claim 6 wherein said sheet material comprises a plurality of said retro-reflective articles positioned in contiguous relationship, and wherein said articles are joined by a flexible material permitting the sheet material to be rolled or folded.
9. A retro-reflective sheet material according to claim 6 wherein the hermetically sealed cells contain a particulate material of a size to afford substantially only point contact with the facets defining said cube-corner retro-reflecting units.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US322151 *||17 Feb 1885||14 Jul 1885||beaumont|
|US2037773 *||18 Nov 1932||21 Apr 1936||Eynon Benjamin G||Motor vehicle registration marker|
|US3140340 *||1 Mar 1961||7 Jul 1964||Minnesota Mining & Mfg||Reflex reflector article|
|US3359671 *||25 Apr 1963||26 Dec 1967||Nier Erich-Arthur||Signboard, more particularly traffic sign|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US4025159 *||17 Feb 1976||24 May 1977||Minnesota Mining And Manufacturing Company||Cellular retroreflective sheeting|
|US4070095 *||2 Feb 1976||24 Jan 1978||Itl Industries, Inc.||Pavement marker and reflector assembly|
|US4208090 *||22 Dec 1976||17 Jun 1980||Amerace Corporation||Reflector structure|
|US4224002 *||4 Aug 1978||23 Sep 1980||Amerace Corporation||Highway delineator|
|US4243618 *||23 Oct 1978||6 Jan 1981||Avery International Corporation||Method for forming retroreflective sheeting|
|US4498733 *||2 Jul 1982||12 Feb 1985||Amerace Corporation||Reflector structure|
|US4555161 *||16 Feb 1984||26 Nov 1985||Reflexite Corporation||Encapsulated retroreflective material and method of making same|
|US4618518 *||20 Jun 1985||21 Oct 1986||Amerace Corporation||Retroreflective sheeting and methods for making same|
|US4681402 *||2 Oct 1985||21 Jul 1987||Tiffany Carlton R||Rainbow projector|
|US4703999 *||16 Jun 1986||3 Nov 1987||Minnesota Mining And Manufacturing Company||Wide-angle-reflective cube-corner retroreflective sheeting|
|US4875798 *||30 Jun 1988||24 Oct 1989||Minnesota Mining And Manufacturing Company||Retroreflective pavement marker|
|US4921319 *||23 Jan 1989||1 May 1990||American Bank Note Holographics, Inc.||Surface relief hologram structure with reflection from an air interface|
|US4952023 *||18 Mar 1988||28 Aug 1990||Minnesota Mining And Manufacturing Company||Internally illuminated retroreflective sign|
|US5069964 *||22 Feb 1991||3 Dec 1991||Minnesota Mining And Manufacturing Company||Flexible, substrate-insular retroreflective sheeting|
|US5122902 *||31 Mar 1989||16 Jun 1992||Minnesota Mining And Manufacturing Company||Retroreflective articles having light-transmissive surfaces|
|US5138488 *||10 Sep 1990||11 Aug 1992||Minnesota Mining And Manufacturing Company||Retroreflective material with improved angularity|
|US5189553 *||8 Jun 1992||23 Feb 1993||Minnesota Mining And Manufacturing Company||Optimized construction of retroreflective articles for curved applications|
|US5229882 *||16 May 1990||20 Jul 1993||Reflexite Corporation||Colored retroreflective sheeting and method of making same|
|US5264063 *||16 May 1990||23 Nov 1993||Reflexite Corporation||Method for making flexible retroreflective sheet material|
|US5450235 *||20 Oct 1993||12 Sep 1995||Minnesota Mining And Manufacturing Company||Flexible cube-corner retroreflective sheeting|
|US5557836 *||20 Oct 1994||24 Sep 1996||Minnesota Mining And Manufacturing Company||Method of manufacturing a cube corner article|
|US5564870 *||20 Oct 1994||15 Oct 1996||Minnesota Mining And Manufacturing Company||Method of manufacturing an asymmetric cube corner article|
|US5585164 *||20 Oct 1993||17 Dec 1996||Minnesota Mining And Manufacturing Company||Dual groove set retroreflective cube corner article and method of manufacture|
|US5600484 *||20 Oct 1993||4 Feb 1997||Minnesota Mining And Manufacturing Company||Machining techniques for retroreflective cube corner article and method of manufacture|
|US5614286 *||20 Oct 1993||25 Mar 1997||Minnesota Mining And Manufacturing Company||Conformable cube corner retroreflective sheeting|
|US5632946 *||7 Jun 1995||27 May 1997||Minnesota Mining And Manufacturing Company||Methods of making a conformable cube corner retroreflective sheeting|
|US5657162 *||26 Jul 1995||12 Aug 1997||Reflexite Corporation||Retroreflective articles with multiple size prisms in multiple locations|
|US5667335 *||19 May 1995||16 Sep 1997||Minnesota Mining And Manufacturing Commpany||Fiber reinforced raised pavement marker and method of making|
|US5677050 *||19 May 1995||14 Oct 1997||Minnesota Mining And Manufacturing Company||Retroreflective sheeting having an abrasion resistant ceramer coating|
|US5691846 *||7 Jun 1995||25 Nov 1997||Minnesota Mining And Manufacturing Company||Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture|
|US5696627 *||20 Oct 1994||9 Dec 1997||Minnesota Mining And Manufacturing Company||Directly machined raised structure retroreflective cube corner article and method of manufacture|
|US5706132 *||19 Jan 1996||6 Jan 1998||Minnesota Mining And Manufacturing Company||Dual orientation retroreflective sheeting|
|US5721640 *||19 Apr 1996||24 Feb 1998||Minnesota Mining And Manufacturing Company||Multiple structure cube corner article and method of manufacture|
|US5734501 *||1 Nov 1996||31 Mar 1998||Minnesota Mining And Manufacturing Company||Highly canted retroreflective cube corner article|
|US5754338 *||8 Nov 1996||19 May 1998||Minnesota Mining And Manufacturing Company||Structured retroreflective sheeting having a rivet-like connection|
|US5759468 *||3 Oct 1996||2 Jun 1998||Minnesota Mining And Manufacturing Company||Raised zone retroreflective cube corner article and method of manufacture|
|US5763049 *||30 Apr 1996||9 Jun 1998||Minnesota Mining And Manufacturing Company||Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same|
|US5764413 *||6 Jun 1996||9 Jun 1998||Minnesota Mining And Manufacturing Company||Tiled retroreflective sheeting|
|US5770124 *||30 Apr 1996||23 Jun 1998||Minnesota Mining And Manufacturing Company||Method of making glittering cube-corner retroreflective sheeting|
|US5784197 *||1 Apr 1996||21 Jul 1998||Minnesota Mining And Manufacturing Company||Ultra-flexible retroreflective sheeting with coated back surface|
|US5812315 *||6 Jun 1996||22 Sep 1998||Minnesota Mining And Manufacturing Company||Cube corner articles exhibiting improved entrance angularity in one or more planes|
|US5814355 *||30 Apr 1996||29 Sep 1998||Minnesota Mining And Manufacturing Company||Mold for producing glittering cube-corner retroreflective sheeting|
|US5822121 *||6 Jun 1996||13 Oct 1998||Minnesota Mining And Manufacturing Company||Retroreflective cube corner article having scalene base triangles|
|US5831767 *||6 Jun 1996||3 Nov 1998||Minnesota Mining And Manufacturing Company||Asymmetric cube corner article|
|US5840405 *||30 Apr 1996||24 Nov 1998||Minnesota Mining And Manufacturing Company||Glittering cube-corner retroreflective sheeting|
|US5910858 *||1 Apr 1996||8 Jun 1999||Minnesota Mining And Manufacturing Company||Retroreflective sheeting with coated back surface|
|US5914812 *||8 Aug 1997||22 Jun 1999||Minnesota Mining And Manufacturing Company||Directly machined raised structure retroreflective cube corner article and method of manufacture|
|US5914813 *||13 Nov 1997||22 Jun 1999||3M Innovative Properties Company||Multiple structure cube corner article|
|US5926314 *||17 Jul 1998||20 Jul 1999||Minnesota Mining And Manufacturing Company||Retroreflective cube corner article having scalene base triangles|
|US5930041 *||24 Jul 1998||27 Jul 1999||Stimsonite Corporation||Method of producing cellular retroreflective sheeting|
|US5936770 *||2 Jul 1997||10 Aug 1999||3M Innovative Properties Company||Dual orientation retroreflective sheeting|
|US5946134 *||22 Sep 1997||31 Aug 1999||Minnesota Mining & Manufacturing Company||Raised structure retroreflective article|
|US5959774 *||19 Jan 1999||28 Sep 1999||3M Innovative Properties Company||Raised structure retroreflective article|
|US5962108 *||2 May 1995||5 Oct 1999||Minnesota Mining And Manufacturing Company||Retroreflective polymer coated flexible fabric material and method of manufacture|
|US5988820 *||14 Mar 1997||23 Nov 1999||3M Innovative Properties Company||Flexible cube-corner retroreflective sheeting|
|US6021559 *||1 Nov 1996||8 Feb 2000||3M Innovative Properties Company||Methods of making a cube corner article master mold|
|US6080340 *||24 Sep 1996||27 Jun 2000||3M Innovative Properties Company||Machining techniques for retroreflective cube corner article and method of manufacture|
|US6126360 *||26 Nov 1996||3 Oct 2000||3M Innovative Properties Company||Raised retroreflective pavement marker|
|US6132861 *||4 May 1998||17 Oct 2000||3M Innovatives Properties Company||Retroreflective articles including a cured ceramer composite coating having a combination of excellent abrasion, dew and stain resistant characteristics|
|US6136416 *||11 May 1998||24 Oct 2000||3M Innovative Properties Company||Raised zone retroreflective cube corner article|
|US6139158 *||12 Aug 1997||31 Oct 2000||Reflexite Corporation||Retroreflective articles with multiple size prisms in multiple locations|
|US6166856 *||15 Jun 1998||26 Dec 2000||3M Innovative Properties Company||Self light-emitting retroreflective sheet and method for producing the same|
|US6168275||21 Oct 1999||2 Jan 2001||3M Innovative Properties Company||Retroreflective cube corner article|
|US6224792||13 Apr 1999||1 May 2001||3M Innovative Properties Company||Cutting and edge sealing cellular retroreflective sheeting|
|US6245833||3 Sep 1999||12 Jun 2001||3M Innovative Properties||Ceramer composition incorporating fluoro/silane component and having abrasion and stain resistant characteristics|
|US6253477 *||23 Sep 1998||3 Jul 2001||Hallmark Technologies, Inc.||Retro-reflective sign|
|US6265061||3 Sep 1999||24 Jul 2001||3M Innovative Properties Company||Retroflective articles including a cured ceramer composite coating having abrasion and stain resistant characteristics|
|US6277470||28 Dec 1999||21 Aug 2001||3M Innovative Properties Company||Method of forming cube corner geometric structures in a substrate using both replicating and machining processes|
|US6318867||24 May 2000||20 Nov 2001||3M Innovative Properties Company||Conformable cube corner retroreflective sheeting|
|US6350035||16 Aug 1995||26 Feb 2002||3M Innovative Properties Company||Flexible cube-corner retroreflective sheeting|
|US6352758||4 May 1998||5 Mar 2002||3M Innovative Properties Company||Patterned article having alternating hydrophilic and hydrophobic surface regions|
|US6376576||8 Dec 2000||23 Apr 2002||3M Innovative Properties Company||Ceramer composition incorporating fluoro/silane component and having abrasion and stain resistant characteristics|
|US6413615||15 Jun 2001||2 Jul 2002||3M Innovative Properties Company||Cube corner geometric structures in a substrate formed by both replicating and machining processes|
|US6470610||29 May 1998||29 Oct 2002||3M Innovative Properties Company||Prefabricated retroreflective sign|
|US6508559||30 Jul 2001||21 Jan 2003||3M Innovative Properties Company||Conformable cube corner retroreflective sheeting|
|US6645331||11 Sep 2002||11 Nov 2003||3M Innovative Properties Company||Prefabricated retroreflective sign|
|US6656307||24 Nov 1999||2 Dec 2003||3M Innovative Properties Company||Method of making signs having metalized cube corner sheeting|
|US6877866||19 Aug 2002||12 Apr 2005||Reflexite Corporation||Multi-orientation retroreflective structure|
|US6958179||18 Dec 2000||25 Oct 2005||3M Innovative Properties Company||Segmented sheeting and methods of making and using same|
|US7025847||26 Jun 2003||11 Apr 2006||3M Innovative Properties Company||Segmented sheeting and methods of making and using same|
|US7185993||4 Jan 2002||6 Mar 2007||3M Innovative Properties Company||Flexible cube-corner retroflective sheeting|
|US7251079||4 Jan 2006||31 Jul 2007||General Electric Company||Brightness enhancement film, and methods of making and using the same|
|US7341784||10 Sep 2004||11 Mar 2008||General Electric Company||Light management film and its preparation and use|
|US7384161||26 Mar 2007||10 Jun 2008||3M Innovative Properties Company||Structured surface articles containing geometric structures with compound faces and methods for making same|
|US7561323||14 Jul 2009||Idc, Llc||Optical films for directing light towards active areas of displays|
|US7562991||31 Oct 2007||21 Jul 2009||3M Innovative Properties Company||Structured surface articles containing geometric structures with compound faces and methods for making same|
|US7568807||20 Sep 2006||4 Aug 2009||3M Innovative Properties Company||Flexible cube-corner retroreflective sheeting|
|US7603001||13 Oct 2009||Qualcomm Mems Technologies, Inc.||Method and apparatus for providing back-lighting in an interferometric modulator display device|
|US7706050||5 Mar 2004||27 Apr 2010||Qualcomm Mems Technologies, Inc.||Integrated modulator illumination|
|US7712904||22 Jul 2008||11 May 2010||3M Innovative Properties Company||Structured surface articles containing geometric structures with compound faces and methods for making same|
|US7719747||25 Feb 2008||18 May 2010||Qualcomm Mems Technologies, Inc.||Method and post structures for interferometric modulation|
|US7733439||30 Apr 2007||8 Jun 2010||Qualcomm Mems Technologies, Inc.||Dual film light guide for illuminating displays|
|US7750886||6 Jul 2010||Qualcomm Mems Technologies, Inc.||Methods and devices for lighting displays|
|US7766498||21 Jun 2006||3 Aug 2010||Qualcomm Mems Technologies, Inc.||Linear solid state illuminator|
|US7777954||30 Jan 2007||17 Aug 2010||Qualcomm Mems Technologies, Inc.||Systems and methods of providing a light guiding layer|
|US7845841||7 Dec 2010||Qualcomm Mems Technologies, Inc.||Angle sweeping holographic illuminator|
|US7855827||6 Oct 2006||21 Dec 2010||Qualcomm Mems Technologies, Inc.||Internal optical isolation structure for integrated front or back lighting|
|US7864395||27 Oct 2006||4 Jan 2011||Qualcomm Mems Technologies, Inc.||Light guide including optical scattering elements and a method of manufacture|
|US7880954||3 May 2006||1 Feb 2011||Qualcomm Mems Technologies, Inc.||Integrated modulator illumination|
|US7907319||15 Mar 2011||Qualcomm Mems Technologies, Inc.||Method and device for modulating light with optical compensation|
|US7949213||7 Dec 2007||24 May 2011||Qualcomm Mems Technologies, Inc.||Light illumination of displays with front light guide and coupling elements|
|US8015620||13 Sep 2011||3M Innovative Properties Company||Vapor permeable retroreflective garment|
|US8040588||18 Oct 2011||Qualcomm Mems Technologies, Inc.||System and method of illuminating interferometric modulators using backlighting|
|US8040589||18 Oct 2011||Qualcomm Mems Technologies, Inc.||Devices and methods for enhancing brightness of displays using angle conversion layers|
|US8049951||1 Nov 2011||Qualcomm Mems Technologies, Inc.||Light with bi-directional propagation|
|US8061882||1 Apr 2009||22 Nov 2011||Qualcomm Mems Technologies, Inc.||Illumination device with built-in light coupler|
|US8107155||6 Oct 2006||31 Jan 2012||Qualcomm Mems Technologies, Inc.||System and method for reducing visual artifacts in displays|
|US8172417||8 May 2012||Qualcomm Mems Technologies, Inc.||Shaped frontlight reflector for use with display|
|US8224189||2 Feb 2007||17 Jul 2012||Sunlight Photonics Inc.||Retro-directive target for free-space optical communication and method of producing the same|
|US8256025||15 Aug 2011||4 Sep 2012||3M Innovative Properties Company||Vapor permeable retroreflective garment|
|US8375933 *||19 Feb 2013||Blaine E. Myers||System and method for heat energy conservation via corner reflectors|
|US8394485||28 Feb 2011||12 Mar 2013||3M Innovative Properties Company||Compound mold and structured surface articles containing geometric structures with compound faces and method of making same|
|US8456649 *||3 Sep 2009||4 Jun 2013||Brainlab Ag||Retro-reflector for image-guided operation systems|
|US8485672||26 Mar 2010||16 Jul 2013||3M Innovative Properties Company|
|US8511839||8 Dec 2009||20 Aug 2013||Nippon Carbide Industries Co., Inc.||Retroreflective article|
|US8511840||10 May 2010||20 Aug 2013||Nippon Carbide Industries Co., Inc.||Hexagonal cube corner retroreflective article|
|US8534849||15 Apr 2010||17 Sep 2013||3M Innovative Properties Company||Retroreflecting optical construction|
|US8591076 *||2 Mar 2012||26 Nov 2013||Osram Sylvania Inc.||Phosphor sheet having tunable color temperature|
|US8654061||23 Dec 2008||18 Feb 2014||Qualcomm Mems Technologies, Inc.||Integrated front light solution|
|US8670171||18 Oct 2010||11 Mar 2014||Qualcomm Mems Technologies, Inc.||Display having an embedded microlens array|
|US8728610||25 Feb 2000||20 May 2014||3M Innovative Properties Company||Compound mold and structured surface articles containing geometric structures with compound faces and method of making same|
|US8798425||22 Nov 2011||5 Aug 2014||Qualcomm Mems Technologies, Inc.||Decoupled holographic film and diffuser|
|US8848294||22 Oct 2010||30 Sep 2014||Qualcomm Mems Technologies, Inc.||Method and structure capable of changing color saturation|
|US8852722||7 Feb 2013||7 Oct 2014||3M Innovative Properties Company||Compound mold and structured surface articles containing geometric structures with compound faces and method of making same|
|US8872085||26 Sep 2007||28 Oct 2014||Qualcomm Mems Technologies, Inc.||Display device having front illuminator with turning features|
|US8891038||14 Apr 2010||18 Nov 2014||3M Innovative Properties Company||Lightguide with optical film containing voids and blacklight for display system|
|US8902484||15 Dec 2010||2 Dec 2014||Qualcomm Mems Technologies, Inc.||Holographic brightness enhancement film|
|US8928967||4 Oct 2010||6 Jan 2015||Qualcomm Mems Technologies, Inc.||Method and device for modulating light|
|US8964146||14 Apr 2010||24 Feb 2015||3M Innovative Properties Company||Optical film for preventing optical coupling|
|US8971675||28 Mar 2011||3 Mar 2015||Qualcomm Mems Technologies, Inc.||Interconnect structure for MEMS device|
|US8979349||27 May 2010||17 Mar 2015||Qualcomm Mems Technologies, Inc.||Illumination devices and methods of fabrication thereof|
|US9019183||24 Sep 2007||28 Apr 2015||Qualcomm Mems Technologies, Inc.||Optical loss structure integrated in an illumination apparatus|
|US9019590||27 Dec 2011||28 Apr 2015||Qualcomm Mems Technologies, Inc.||Spatial light modulator with integrated optical compensation structure|
|US9025235||1 Feb 2008||5 May 2015||Qualcomm Mems Technologies, Inc.||Optical interference type of color display having optical diffusion layer between substrate and electrode|
|US9110289||13 Jan 2011||18 Aug 2015||Qualcomm Mems Technologies, Inc.||Device for modulating light with multiple electrodes|
|US9121979||27 May 2010||1 Sep 2015||Qualcomm Mems Technologies, Inc.||Illumination devices and methods of fabrication thereof|
|US9200775||23 Apr 2010||1 Dec 2015||3M Innovative Properties Company||Light assembly|
|US9291752||19 Aug 2013||22 Mar 2016||3M Innovative Properties Company||Retroreflecting optical construction|
|US20020196542 *||19 Aug 2002||26 Dec 2002||Reflexite Corporation||Multi-orientation retroreflective structure|
|US20030235674 *||26 Jun 2003||25 Dec 2003||3M Innovative Properties Company||Segmented sheeting and methods of making and using same|
|US20040013856 *||17 Apr 2003||22 Jan 2004||Yoshinori Araki||Reflective articles and method of making|
|US20040051948 *||10 Sep 2003||18 Mar 2004||David Reed||Systems, methods, and apparatus for patterned sheeting|
|US20060011287 *||13 Sep 2005||19 Jan 2006||3M Innovative Properties Company||Segmented sheeting and methods of making and using same|
|US20060056031 *||10 Sep 2004||16 Mar 2006||Capaldo Kevin P||Brightness enhancement film, and methods of making and using the same|
|US20060067572 *||14 Sep 2005||30 Mar 2006||Tattile, L.L.C.||Object imaging system|
|US20060071362 *||10 Sep 2004||6 Apr 2006||Chunghei Yeung||Light management film and its preparation and use|
|US20060114569 *||4 Jan 2006||1 Jun 2006||Capaldo Kevin P||Brightness enhancement film, and methods of making and using the same|
|US20070014011 *||20 Sep 2006||18 Jan 2007||3M Innovative Properties Company||Flexible cube-corner retroreflective sheeting|
|US20070177268 *||26 Mar 2007||2 Aug 2007||3M Innovative Properties Company|
|US20090185265 *||23 Jan 2009||23 Jul 2009||Myers Blaine E||System and Method for Heat Energy Conservation Via Corner Reflectors|
|US20090320193 *||31 Dec 2009||3M Innovative Properties Company||Vapor permeable retroreflective garment|
|US20100053639 *||4 Mar 2010||Christian Maier||Retro-reflector for image-guided operation systems|
|US20100182695 *||26 Mar 2010||22 Jul 2010||3M Innovative Properties Company|
|US20110149395 *||23 Jun 2011||3M Innovative Properties Company|
|US20130229784 *||2 Mar 2012||5 Sep 2013||Osram Sylvania Inc.||Phosphor Sheet Having Tunable Color Temperature|
|USD665584 *||21 Aug 2012||Orafol Europe Gmbh||Retro-reflective sheeting with a corner cube surface pattern having angular corner cube circular regions|
|USD666837 *||11 Sep 2012||Columbia Sportswear North America, Inc.||Patterned bodywear lining material|
|USD670435||6 Nov 2012||Columbia Sportswear North America, Inc.||Heat reflective material with pattern|
|USD670917 *||20 Nov 2012||Columbia Sportswear North America, Inc.||Heat reflective lining material|
|USD707974||11 May 2012||1 Jul 2014||Columbia Sportswear North America, Inc.||Patterned prismatic bodywear lining material|
|USD754978 *||25 Feb 2014||3 May 2016||Under Armour, Inc.||Fabric with surface ornamentation|
|CN101960203B||23 Jan 2009||7 Aug 2013||布莱恩·E·迈克尔||System and method for heat energy conservation via corner reflectors|
|EP0142250A2 *||19 Sep 1984||22 May 1985||Amerace Corporation||Retroreflective sheeting and methods for making same|
|EP0175031A1 *||30 Nov 1984||26 Mar 1986||Amerace Corporation||Retroreflective sheeting|
|EP0342958A2||17 May 1989||23 Nov 1989||Minnesota Mining And Manufacturing Company||High efficiency cube-corner retroreflective material|
|EP0349323A2 *||29 Jun 1989||3 Jan 1990||Minnesota Mining And Manufacturing Company||Retroreflective pavement marker|
|EP0724734A1 *||20 Oct 1994||7 Aug 1996||Minnesota Mining And Manufacturing Company||Conformable cube corner retroreflective sheeting|
|EP0951383A1 *||22 May 1997||27 Oct 1999||Stimsonite Corporation||Retroreflective articles having microcubes, and tools and methods for forming microcubes|
|WO2008045363A2 *||5 Oct 2007||17 Apr 2008||Qualcomm Mems Technologies, Inc.||Light bar with reflector|
|WO2008045363A3 *||5 Oct 2007||24 Jul 2008||Ion Bita||Light bar with reflector|
|WO2010067583A1||8 Dec 2009||17 Jun 2010||Nippon Carbide Industries Co., Inc.||Retroreflective article|
|WO2010131630A1||10 May 2010||18 Nov 2010||Nippon Carbide Industries Co., Inc.||Hexagonal corner cube retroreflective article|
|WO2012057295A1||27 Oct 2011||3 May 2012||Nippon Carbide Industries Co., Inc.||Cube-cornered retroreflective sheet|
|U.S. Classification||359/514, 404/9, 359/532, 40/612, 428/30|
|International Classification||G09F13/16, G09F13/04, G02B5/12, G02B5/124|
|Cooperative Classification||G09F13/16, G02B5/124, G09F2013/0472|
|European Classification||G09F13/16, G02B5/124|
|6 Aug 1990||AS||Assignment|
Owner name: MANUFACTURERS HANOVER TRUST COMPANY, NEW YORK
Free format text: SECURITY INTEREST;ASSIGNOR:AMERACE CORPORATION;REEL/FRAME:005465/0013
Effective date: 19900731