US3916043A - Method of coating a spliced web - Google Patents

Method of coating a spliced web Download PDF

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US3916043A
US3916043A US198810A US19881071A US3916043A US 3916043 A US3916043 A US 3916043A US 198810 A US198810 A US 198810A US 19881071 A US19881071 A US 19881071A US 3916043 A US3916043 A US 3916043A
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coating
web
pressure
bead
splice
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US198810A
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William F Fowble
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Eastman Kodak Co
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Eastman Kodak Co
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Priority to US198810A priority Critical patent/US3916043A/en
Priority to CA153,543A priority patent/CA978810A/en
Priority to GB5244172A priority patent/GB1385043A/en
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/74Applying photosensitive compositions to the base; Drying processes therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C5/00Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
    • B05C5/007Slide-hopper coaters, i.e. apparatus in which the liquid or other fluent material flows freely on an inclined surface before contacting the work
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/06Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying two different liquids or other fluent materials, or the same liquid or other fluent material twice, to the same side of the work
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/136Coating process making radiation sensitive element

Definitions

  • US. Pat. Nos. 2,681,294 and 2,761,791 disclose methods of coating which include flowing a stream or layer of liquid coating composition from a coating device toward the surface of a web to be coated to maintain a ribbon or bead of coating solution in bridging relation between the coating device and the web surface during the coating operation.
  • a greater pneumatic or other gaseous pressure is maintained on that side of the ribbon or bead of coating solution from which the coated web moves away than on that side toward which the web to be coated approaches.
  • this differential gaseous pressure on the opposite sides of the ribbon or bead of coating composition overcomes many disadvantages of earlier methods of coating, as well as permitting the coating speed to be greatly increased.
  • the increase in speed presents certain difficulties in the coating of spliced webs which results in a considerable loss of coated material as the result of a splice passing through the ribbon or bead of coating composition.
  • One of the primary advantages claimed for this method of coating 30 is that the coating device can be spaced from the web to be coated by an amount sufficient to permit a splice in the web to pass the coating station without having to move the coating device away from the surface being coated.
  • the primary object of the present invention is, therefore, to provide a method of coating over splices in a web material to be coated which is less wasteful of ma- 60 suffering a blow-up" as it is known in the art.
  • FIG. 1 is a diagrammatic side elevation, partly in section, of a form of apparatus by which the improved method can be carried out;
  • FIG. 2 is an exaggerated fragmentary sectional view showing how the spliced ends of two webs form a hump as they move onto the surface of the coating roll by reason of their inherent curl.
  • the web material 10 such as film or paper
  • the web material 10 is drawn from a source of supply, not shown, and partially wrapped around the roll 11 for movement past the coating station 12, the roll 11 being keyed to shaft 13 which is continuously rotated at a desired rate (feet per minute) in accordance with the liquid coating composition to be applied to the web.
  • a desired rate foreet per minute
  • the coating device 15 can be of the type disclosed in US. Pat. Nos. 2,761,419 and 2,681,294 in which a fluid composition 16 is continuously pumped by a constant discharge pump 17 into a cavity 18 at a given rate, the composition being forced through a layer distributing slot 19 in the form of a ribbon and out onto a downwardly inclined slide surface 20.
  • the ribbon flows by gravity in the form of a layer 21 to a point where it forms a coating bead or ribbon 22 between the lip 23 of surface and the surface of the moving web 10.
  • a second fluid composition 25 is pumped into cavity 26 by another constant discharge pump 27 and is forced through the distributing slot 28 in the form of a ribbon and out onto the downwardly inclined slide surface 29.
  • As the layer 30 reaches layer 21 it flows onto the top thereof and the two layers 30 and 21 flow down slide surface 20 and into the coating bead 22.
  • the coating device 15 extends axially with respect to the roll 11 and is mounted on a plate 32 which, in turn, is pivotally mounted on cross shaft 33.
  • the coating device 15 can be moved toward and away from the surface of the web 10 on the roll 11 to vary the depth of the coating bead (determined by the spacing between the coating device and the web surface which the bead must bridge) and/or to permit threading up of the coating apparatus.
  • a vacuum pump 43 is connected to chamber 42 by a pipe 44 which is provided with a regulating valve 45.
  • the pressure within the chamber can be indicated by means of a manometer 46 which is connected to chamber 42 by means of line 47.
  • the coating device 15 When starting a coating operation the coating device 15 is moved or tilted away from the coating roll 11 to permit threading of the web 10 about roll 11. Then after the pumps 17 and 27 are started to form the layers 21 and 30 flowing toward the lip 23 of the coating device, the coating device is moved toward the roll 11 until the layers 21 and 30 contact the surface of the web to form the coating bead 22. After the bead 22 has been formed transversely of web 10, and the layers 21 and 30 are being applied uniformly to the surface of the web, the coating device is moved away from the web into the coat position.
  • the differential pressure on the coating bead is increased just before a splice in the web reaches the coating bead and this increased differential pressure is maintained until the splice has passed through the coating bead, and is then reduced to the normal coating differential pressure, then the splice oriented coating defects and/or the defects caused by bead blow-up are greatly reduced or eliminated. Debead blow-up are greatly reduced or eliminated.
  • the differential pressure may have to be increased from 0.2 inch of water up to 1.2 inches of water above the differential pressure used during normal coating.
  • the splice in a web to be coated generally consists in joining the butted relation, the end of an expiring web and the end of a new web by a strip of adhesive tape placed over the butted ends of the webs and extending transversely of the surface to be coated, see S in FIG. 1. While a splicing tape generally used which is as thin as the required strength allows, the thickness of the tape adds significantly to the overall thickness of the web, particularly as concerns the spacing between the coating device and the web surface being coated, or the depth of the coating bead.
  • splice humping Another condition which can upset the coating bead when a splice in the web passes therethrough is known as splice humping". This occurs primarily in webs of plastic, e.g. acetate, polyester, etc, used as photographic film support as will now be explained. These supports usually have a thickness in the order of 4 to l l mils and are usually stored in rolls for some time before they are coated. As a result, the ends of the supports which are spliced just before coating have an inherent curl which is generally sharper than the arcuate surface of the coating roll 11.
  • the ends of the spliced webs are generally separated by as much as l/32 inch, either because the operator has not made the cut off accurately on the splice board, or if the splice is automatically made by a machine, to insure that the web ends wont overlap.
  • the thin splicing tape T is not strong enough, or the tension in the web going onto the coating roll 11 is not great enough, to straighten the inherent curl out of the spliced ends of the web to make them conform to the circumference of the coating roll.
  • this splice is made on the backside of the film, (the surface not coated) as it sometimes is, or in the instance where both sides are to be coated alternately, then the coating bead will drop down into the space between the separated ends of the spliced webs and have its stability upset as the splice passes through the coating bead.
  • the differential pressure required will vary with the coating composition, the rate of coating and the wetting characteristics of the web surface being coated. However, the pressure differential used must not be so great that it will itself cause rupture of the bead, particularly under normal coating conditions, e.g. those encountered before and after the splice enters, or has passed through, the coating bead.
  • coating bead instability results not only from the sudden change in thickness of the web at a splice, but, in addition, due to the volume of air moved into the bead by the leading edge of the splicing tape. While in this instance the coating bead is not ruptured it is believed that the volume of air moved into the bead by the leading edge of the splicing tape forms a cushion of air which lifts or stretches the coating bead, or shifts the wetting line thereof, longitudinally of the web.
  • the wetting characteristics of the splicing tape T are usually different than those of the web to be coated. If the surface of the tape has a different wetting characteristic for the coating composition than the web itself, this will tend to cause a shift in the wetting line of the coating bead as the splice passes therethrough, and a sudden shift in the wetting line will produce an instability in the bead.
  • Example 1 An aqueous solution of gelatin and silver halide having a viscosity of approximately 4.5 centipoise at F was applied to a web with a wet lay down thickness of approximately 3 mils. This coating composition was coated on a dry 5 mil or 8 mil acetate support. The normal coating suction was 0.5 inch of water and the high vacuum used at splices was 1.0 inch of water. The coating speed was 1 10 feet per minute.
  • Example 2 An aqueous solution of gelatin and silver halide having a viscosity of 8.5 centipoise at 95F was coated at 300 feet per minute with a wet lay down thickness of approximately 2 mils. This material was coated on a polyethylene terephthalate support. The normal coating suction was 0.6 inch of water and the high vacuum at splices was 1.0 inch of water.
  • Example 3 The same materials as used in Example 2 were coated at 400 feet per minute with a normal coating suction of 0.2 inch of water and a high vacuum at splices of 0.7 inch of water.
  • Example 4 An aqueous solution of gelatin, silver halide and latex polymer having a viscosity of 9 centipoise at 95F was coated on a 4 mil polyethylene terephthalate support with a wet lay down thickness of approximately 3 mils.
  • the normal coating suction was 0.6 inch of water and the high vacuum at splices was 0.9 inch of water.
  • the coating speed used was 300 fpm.
  • the coating and high suction were applied to the face of a splice, that is, that side of the support on which the splicing tape is applied.
  • the coating was applied to the back of the support, and the high suction was used on the back of the splice to prevent bead disturbance resulting from the gap between the two butted ends of the support.
  • valve 45 can be manually adjusted to obtain, the desired air pressure differential at the proper time, it is preferred to perform this task automatically and with precision.
  • the valve 45 could be a two position valve, one of its positions producing the desired initial or normal pressure differential for coating, and the other position producing the desired increased pressure differential for the passage of a splice in the web. In order to obtain a quick and automatic response this valve could be operated by an electrical solenoid. Then an electrical signal from a splice detector could shift the valve to its other position as a splice approached the coatingstation and an electrical timer or footage indicator, could automatically shift it to its first position a given time after the splice has passed the coating position for the normal coating condition.
  • valves in the suction line instead of one, one to produce the desired initial pressure differential for coating and the other to produce the increased pressure differential for the passage of splices, and make each of these valves adjustable for different coating conditions.
  • These two valves could be connected in the suction line in parallel and the selective use of one or the other could be controlled by a splice detector and a timer as mentioned above.
  • the present method of coating has been shown in connection with a coating device adapted to apply two coatings to a web simulta neously, it will be appreciated that the coating method could just as well be used in applying a single layer of coating composition, or three or more layers simultaneously of the same or different coating composition, to a moving web.
  • a method of coating 21 spliced strip material from a coating device which comprises moving the strip material adjacent and relative to the coating device; discharging a ribbon of liquid coating composition from the coating device toward said strip of material to form and maintain a bead of liquid composition transversely of an area of the moving strip across which the web moves and picks up a layer of said liquid composition; subjecting the bead of liquid coating composition to an initial differential air pressure to hold the bead of coating composition from movement in the direction of travel of the strip material, the pressures being selected to retain the bead of coating composition in a coating position and to maintain a uniform coating on the strip material, the lesser air pressure being on the side of the bead toward which the web approaches; increasing the initial differential air pressure just before a splice in the strip material reaches said bead;
  • a method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice comprising:
  • a method of coating a moving web of substantially nonporous flexible material containing at least one splice whose thickness is substantially greater than the thickness of the web of material with a liquid coating composition having viscosities of between 3 and 35 centipoises comprising flowing a thin layer of said composition from a coating device to the web of nonporous material to form a bead of composition therebetween extending transversely of the web, said bead having a depth several times the thickness of said web while passing from the coating device to the web and while the web moves toward the coating device and away from the coating device, maintaining the bead of coating composition in a coating condition by applying an initial predetermined differential in gaseous pressures on the two sides of the bead of coating composition, the pressure on that side of the bead from which the web approaches the coating device being less than the pressure on that side of the bead from which the web moves away from the coating device, the improvement which comprises,
  • a method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice comprising:
  • a method of coating a thin layer ofliquid coating material from a coating device onto a web having at least one transverse splice comprising:

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

In coating by discharging a ribbon of coating material onto a moving web to form a coating bead while applying suction to the side of the bead or ribbon which the web approaches, defects caused by a web splice are reduced by momentarily increasing the suction.

Description

United States Patent 1191 111]], 3,916,043 Fowble 5] Oct. 28, 1975 [54] METHOD OF COATING A SPLICED WEB 2,761,418 9/1956 Russell 118/410 2,761,791 9/1956 Russell.... 118/410 [75] Inventor. William F. Fowble, Rochester, NY. 2,952,559 9/1960 Nadeaum 7/34 [73] Assignee; Eastman Kodak Company, 3,206,323 9/1965 Miller 117/34 Rochester NY 3,227,136 l/l966 Bartlett... 118/63 3,348,964 10/1967 Good 1. 118/50 [22] Filed: NOV. 15, 1971 3,502,494 3/1970 Ishiwata 1 118/50 3,503,370 3/1970 Ishiwata 1 117/34 [21] APPl- 198,810 3,518,141 6/1970 Boarns et 61.... 117/34 [44] Published under the Trial Voluntary Protest 364O752 2/1972 Ishiwata 17/34 3,645,773 2/1972 Herzhoff et 211.... 117/34 g rgg g 8 January 1975 as document 3,663,292 5/1972 Herzhoff et a1 117/34 Primary E.raminerWilliam R. Trenor [52] US. Cl 427/294; 96/85; 96/87 R;
96/94 118/50; Attorney, Agent, or F1rmA. P. Lorenzo 427/350 51 Int. C1. BOSC 3/12; BOSD l/26; 603C 1/74 [57] ABSTRACT [58] Field of Search 1 17/34, 47 A, 61, 1 19; In coating by discharging a ribbon of coating material 118/63, 50, 410; 427/294, 296, 350 onto a moving web to form a coating bead While applying suction to the side of the bead or ribbon which [56] References Cited the web approaches, defects caused by a web splice UNITED STATES PATENTS are reduced by momentarily increasing the suction. 2,681,294 6/1954 Beguin 117/34 12 Claims, 2 Drawing Figures 'I 20 iifiat, 72 4 0 1"' 1 r-- f 5 22 CTI E iIIIL 23 5 1 1 I I l7 /0 E 9:552:1 34 I u i 33 |u1ul|||||| 36 VACUUM l SOURCE METHOD OF COATING A SPLICED WEB This invention relates to improvements in the method of applying a layer of liquid coating composition to the surface of a moving web of material, and particularly to a spliced web.
US. Pat. Nos. 2,681,294 and 2,761,791 disclose methods of coating which include flowing a stream or layer of liquid coating composition from a coating device toward the surface of a web to be coated to maintain a ribbon or bead of coating solution in bridging relation between the coating device and the web surface during the coating operation. In order to stabilize the ribbon or bead of coating, and/or prevent it from longitudinally stretching in the direction of the web movement, a greater pneumatic or other gaseous pressure is maintained on that side of the ribbon or bead of coating solution from which the coated web moves away than on that side toward which the web to be coated approaches. The use of this differential gaseous pressure on the opposite sides of the ribbon or bead of coating composition overcomes many disadvantages of earlier methods of coating, as well as permitting the coating speed to be greatly increased. However, the increase in speed presents certain difficulties in the coating of spliced webs which results in a considerable loss of coated material as the result of a splice passing through the ribbon or bead of coating composition. One of the primary advantages claimed for this method of coating 30 is that the coating device can be spaced from the web to be coated by an amount sufficient to permit a splice in the web to pass the coating station without having to move the coating device away from the surface being coated. It has been found, however, that as a splice in the web moves across the coating station longitudinal streaks may develop in the coating, and persist for some time, at all coating speeds, and that blow-up or rupture of the ribbon or bead occurs at high coating speeds, which results in a defective coating until the 40 bead is reformed and becomes stabilized again. It will be appreciated that these imperfections in the coating resulting from the passage of a splice past the coating station, even though they might only persist for a short time, will result in the waste of a considerable length of 45 web, particularly when the coating operation is being carried out at high speeds, e.g. greater than 200 feet per minute.
It has been discovered that if the differential pressure on the opposite sides of the ribbon or bead of coating 50 composition is increased just before a splice in a web enters the coating station and is maintained during the time the splice is passing the coating station and for a short time thereafter, before it is reduced to the level used for normal coating, then these coating problems 55 caused by the passage of a splice past the coating station can be greatly decreased or completely eliminated.
The primary object of the present invention is, therefore, to provide a method of coating over splices in a web material to be coated which is less wasteful of ma- 60 suffering a blow-up" as it is known in the art.
The novel features that I consider characteristic of my invention are set forth with particularity in the appended claims. The invention itself, however, both as to its organization and its methods of operation, together with additional objects and advantages thereof, will best be understood from the following description when read in connection with the accompanying drawings in which:
FIG. 1 is a diagrammatic side elevation, partly in section, of a form of apparatus by which the improved method can be carried out; and
FIG. 2 is an exaggerated fragmentary sectional view showing how the spliced ends of two webs form a hump as they move onto the surface of the coating roll by reason of their inherent curl.
With reference to FIG. 1, the web material 10, such as film or paper, is drawn from a source of supply, not shown, and partially wrapped around the roll 11 for movement past the coating station 12, the roll 11 being keyed to shaft 13 which is continuously rotated at a desired rate (feet per minute) in accordance with the liquid coating composition to be applied to the web. Thus, as the uncoated web is moved into the coating station, the liquid coating composition is applied to the surface thereof and then passes away from the roll for the necessary drying operations.
The coating device 15 can be of the type disclosed in US. Pat. Nos. 2,761,419 and 2,681,294 in which a fluid composition 16 is continuously pumped by a constant discharge pump 17 into a cavity 18 at a given rate, the composition being forced through a layer distributing slot 19 in the form of a ribbon and out onto a downwardly inclined slide surface 20. The ribbon flows by gravity in the form of a layer 21 to a point where it forms a coating bead or ribbon 22 between the lip 23 of surface and the surface of the moving web 10. A second fluid composition 25 is pumped into cavity 26 by another constant discharge pump 27 and is forced through the distributing slot 28 in the form of a ribbon and out onto the downwardly inclined slide surface 29. As the layer 30 reaches layer 21 it flows onto the top thereof and the two layers 30 and 21 flow down slide surface 20 and into the coating bead 22.
The coating device 15 extends axially with respect to the roll 11 and is mounted on a plate 32 which, in turn, is pivotally mounted on cross shaft 33. By means of hand wheel 34 and lead screw 35, which is pivotally connected to extension 36 on plate 32, the coating device 15 can be moved toward and away from the surface of the web 10 on the roll 11 to vary the depth of the coating bead (determined by the spacing between the coating device and the web surface which the bead must bridge) and/or to permit threading up of the coating apparatus.
A casting 40 having end walls 41 together with coating device 15 and a portion of roll 11 form a chamber 42. A vacuum pump 43 is connected to chamber 42 by a pipe 44 which is provided with a regulating valve 45. The pressure within the chamber can be indicated by means of a manometer 46 which is connected to chamber 42 by means of line 47.
When starting a coating operation the coating device 15 is moved or tilted away from the coating roll 11 to permit threading of the web 10 about roll 11. Then after the pumps 17 and 27 are started to form the layers 21 and 30 flowing toward the lip 23 of the coating device, the coating device is moved toward the roll 11 until the layers 21 and 30 contact the surface of the web to form the coating bead 22. After the bead 22 has been formed transversely of web 10, and the layers 21 and 30 are being applied uniformly to the surface of the web, the coating device is moved away from the web into the coat position. The position of lip 23 relative to the web for forming the desired coating bead and for maintaining a uniform coating application will be de pendent upon the fluid composition, the material of the web to be coated and the rate of movement of the web across the bead. In accordance with the method of coating taught by US. Pat. No. 2,681,294, during coating the pressure within chamber 42 is reduced so that it is subatmospheric with a pressure differential of the order of 0.1 inch to 5.0 inch of water depending upon the fluid composition, the material to be coated and the rate of coating. This differential pressure is selected to retain the ribbon or bead of coating in coating position and to maintain a uniform coating on the web material, and as noted will vary with the coating composition, the surface characteristics of the web being coated and the rate of coating.
While this differential pressure maintained on opposite sides of the coating bead tends to stabilize the bead and permit the lip of the coating device to be spaced far enough from the web to be coated to allow the passage of a splice S in the web without having to back off the coating device from the coating roll, it has been found that the passage of a splice in the web through the coating bead produces coating defects which result in considerable waste of product. These coating defects which are most prevalent occur at high speeds of coating, e.g. greater than 200 feet per minute, and result from bead blow-up which is a complete or partial rupture of a coating head 22. When this occurs. the coating is interrupted and does not again become uniform and satisfactory until the bead reforms itself and becomes restabilized. Even if this ruptured bead reforms itself without intervention by the operator it will be appreciated that considerable material is wasted before a uniform coating is reestablished.
Even at the slower coating speeds the passage of a splice through the coating bead has been found to produce coating defects in the form of longitudinal lines, generally referred to as splice oriented defects, which persist for varying lengths of time after a splice has passed through the coating bead. In the latter instance it has been determined that these coating lines have been caused by the stability of the coating bead being upset by the passage ofa splice and/or by bubbles of air which are trapped in the coating bead as a result of the splice passing through.
I have found that if the differential pressure on the coating bead is increased just before a splice in the web reaches the coating bead and this increased differential pressure is maintained until the splice has passed through the coating bead, and is then reduced to the normal coating differential pressure, then the splice oriented coating defects and/or the defects caused by bead blow-up are greatly reduced or eliminated. Debead blow-up are greatly reduced or eliminated. Depending upon the coating composition, the speed of coating and the surface characteristics of the web being coated, as well as the surface characteristics of the splice material used, the differential pressure may have to be increased from 0.2 inch of water up to 1.2 inches of water above the differential pressure used during normal coating.
The reason for bead blow-up or rupture when a splice passes the coating station, particularly at high speeds, is quite understandable. The splice in a web to be coated generally consists in joining the butted relation, the end of an expiring web and the end of a new web by a strip of adhesive tape placed over the butted ends of the webs and extending transversely of the surface to be coated, see S in FIG. 1. While a splicing tape generally used which is as thin as the required strength allows, the thickness of the tape adds significantly to the overall thickness of the web, particularly as concerns the spacing between the coating device and the web surface being coated, or the depth of the coating bead. Also, it is not uncommon when splices are made to have bubbles of air formed under the splice material which form humps in the splice which increases the thickness of the web at the splice to an even greater value. The passage of the splice through the coating bead can readily rupture the bead or upset its stability to the extent that the uniformity of the applied coating is destroyed until the bead is reformed and/or restabilized. Since the leading edge of the splicing tape is generally perpendicular to the web surface it subjects the coating bead to a sudden change in depth which, by itself, is sometimes sufficient to rupture the bead. In addition, at high speed the trailing edge of the splice tape disturbs the boundary layer of air surrounding the web. At high coating speeds, all of this turbulent air following the trailing edge of the splice does not have a chance to exhaust at the edges of the web but must exhaust through the bead. As a result, there is a build up of compressed air behind the splice which aids in the rupture or blow-up" of the coating bead as the splice passes through the same. Feathering of the edges of the splicing tape to lessen this turbulence has been tried but is not the complete answer to the problem of splice oriented coating defects.
Another condition which can upset the coating bead when a splice in the web passes therethrough is known as splice humping". This occurs primarily in webs of plastic, e.g. acetate, polyester, etc, used as photographic film support as will now be explained. These supports usually have a thickness in the order of 4 to l l mils and are usually stored in rolls for some time before they are coated. As a result, the ends of the supports which are spliced just before coating have an inherent curl which is generally sharper than the arcuate surface of the coating roll 11. Although the webs are said-to be butt spliced, actually the ends of the spliced webs are generally separated by as much as l/32 inch, either because the operator has not made the cut off accurately on the splice board, or if the splice is automatically made by a machine, to insure that the web ends wont overlap. As shown in FIG. 2 on an exaggerated scale, theresult of this is that the thin splicing tape T is not strong enough, or the tension in the web going onto the coating roll 11 is not great enough, to straighten the inherent curl out of the spliced ends of the web to make them conform to the circumference of the coating roll. Consequently, a hump in the web appears at the splice, and the effective thickness of this hump may approach the width of the space between the web and the coating device so that as it passes the coating position it can readily upset the stability of, or rupture, depending upon the speed the web is moving at, the coating bead. Likewise, if this splice is made on the backside of the film, (the surface not coated) as it sometimes is, or in the instance where both sides are to be coated alternately, then the coating bead will drop down into the space between the separated ends of the spliced webs and have its stability upset as the splice passes through the coating bead.
Increasing the differential pressure on the opposite sides of the coating bead before the splice reaches the bead, and maintaining this increased differential pressure until the splice passes through the coating bead has been found to prevent the bead from rupturing and quickly overcomes any instability the bead might suffer by reason of the passage of the splice. It will be appreciated that the differential pressure required will vary with the coating composition, the rate of coating and the wetting characteristics of the web surface being coated. However, the pressure differential used must not be so great that it will itself cause rupture of the bead, particularly under normal coating conditions, e.g. those encountered before and after the splice enters, or has passed through, the coating bead.
The coating defects encountered at slow coating speeds, or when no bead blow-up occurs, are not quite so obvious. In this case it is believed that coating bead instability results not only from the sudden change in thickness of the web at a splice, but, in addition, due to the volume of air moved into the bead by the leading edge of the splicing tape. While in this instance the coating bead is not ruptured it is believed that the volume of air moved into the bead by the leading edge of the splicing tape forms a cushion of air which lifts or stretches the coating bead, or shifts the wetting line thereof, longitudinally of the web. As a result, instead of the coating composition being deposited on the web surface right up to the leading edge of the splicing tape T, it is lifted by the cushion of air at the leading edge of the splice and is in fact momentarily unsupported except for this cushion of air. The same effect occurs at the trailing edge of the splice so that the layer(s) of coating instead of flowing sharply down the rear edge of the splicing tape, leave the tape on an incline.
Another factor which might enter into the instability of the coating bead is that the wetting characteristics of the splicing tape T are usually different than those of the web to be coated. If the surface of the tape has a different wetting characteristic for the coating composition than the web itself, this will tend to cause a shift in the wetting line of the coating bead as the splice passes therethrough, and a sudden shift in the wetting line will produce an instability in the bead. Increasing the differential pressure during the time a splice is passing through the coating bead in accordance with the present invention is believed to hold the head down so that it squeezes air out from under the coating and holds the wetting line of the bead constant, rather than the increase in vacuum on the underside of the bead acting to pull air out from under the bead.
In order to more clearly illustrate the applicability of the invention with respect to particular coating applications, several specific examples are described hereinafter. It is to be understood, of course, that the invention is not limited to the materials nor the various features set forth in these examples.
Example 1 An aqueous solution of gelatin and silver halide having a viscosity of approximately 4.5 centipoise at F was applied to a web with a wet lay down thickness of approximately 3 mils. This coating composition was coated on a dry 5 mil or 8 mil acetate support. The normal coating suction was 0.5 inch of water and the high vacuum used at splices was 1.0 inch of water. The coating speed was 1 10 feet per minute.
Example 2 An aqueous solution of gelatin and silver halide having a viscosity of 8.5 centipoise at 95F was coated at 300 feet per minute with a wet lay down thickness of approximately 2 mils. This material was coated on a polyethylene terephthalate support. The normal coating suction was 0.6 inch of water and the high vacuum at splices was 1.0 inch of water.
Example 3 The same materials as used in Example 2 were coated at 400 feet per minute with a normal coating suction of 0.2 inch of water and a high vacuum at splices of 0.7 inch of water.
Example 4 An aqueous solution of gelatin, silver halide and latex polymer having a viscosity of 9 centipoise at 95F was coated on a 4 mil polyethylene terephthalate support with a wet lay down thickness of approximately 3 mils. The normal coating suction was 0.6 inch of water and the high vacuum at splices was 0.9 inch of water. The coating speed used was 300 fpm.
In the first three examples the coating and high suction were applied to the face of a splice, that is, that side of the support on which the splicing tape is applied. In the last example the coating was applied to the back of the support, and the high suction was used on the back of the splice to prevent bead disturbance resulting from the gap between the two butted ends of the support.
In addition to the above examples, reference can also be had to the examples set forth in U.S. Pat. No. 2,681,294 wherein various initial air pressure differentials are disclosed for coating other materials with different fluid compositions. The increased air pressure differential to be used in these examples will again be dependent upon the web material, the fluid coating composition used and the rate of coating.
While the valve 45 can be manually adjusted to obtain, the desired air pressure differential at the proper time, it is preferred to perform this task automatically and with precision. To this end, the valve 45 could be a two position valve, one of its positions producing the desired initial or normal pressure differential for coating, and the other position producing the desired increased pressure differential for the passage of a splice in the web. In order to obtain a quick and automatic response this valve could be operated by an electrical solenoid. Then an electrical signal from a splice detector could shift the valve to its other position as a splice approached the coatingstation and an electrical timer or footage indicator, could automatically shift it to its first position a given time after the splice has passed the coating position for the normal coating condition. It has been found preferable in the coating examples noted above to apply the increased pressure differential at the time a splice is two feet ahead of the coating bead and to maintain this increased pressure differential until the splice is two feet beyond the coating bead. It will be appreciated that the time that this increased pressure differential is applied and the length of time it is maintained may vary with the speed of coating, the type of coating composition used, the material of the web to be coated, and/or the type of splice used to join the web ends. In order to make the differential pressure control system more versatile, so far as its applicability to different coating compositions is concerned, it might be desirable to use two valves in the suction line instead of one, one to produce the desired initial pressure differential for coating and the other to produce the increased pressure differential for the passage of splices, and make each of these valves adjustable for different coating conditions. These two valves could be connected in the suction line in parallel and the selective use of one or the other could be controlled by a splice detector and a timer as mentioned above.
While for purposes of disclosure the present method of coating has been shown in connection with a coating device adapted to apply two coatings to a web simulta neously, it will be appreciated that the coating method could just as well be used in applying a single layer of coating composition, or three or more layers simultaneously of the same or different coating composition, to a moving web.
The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.
I claim:
1. A method of coating 21 spliced strip material from a coating device which comprises moving the strip material adjacent and relative to the coating device; discharging a ribbon of liquid coating composition from the coating device toward said strip of material to form and maintain a bead of liquid composition transversely of an area of the moving strip across which the web moves and picks up a layer of said liquid composition; subjecting the bead of liquid coating composition to an initial differential air pressure to hold the bead of coating composition from movement in the direction of travel of the strip material, the pressures being selected to retain the bead of coating composition in a coating position and to maintain a uniform coating on the strip material, the lesser air pressure being on the side of the bead toward which the web approaches; increasing the initial differential air pressure just before a splice in the strip material reaches said bead;
maintaining the increased differential air pressure until the splice in the strip material has passed through said bead; and
decreasing the differential air pressure to the initial differential air pressure after the splice in the strip material has passed through said bead.
2. The method of coating a strip of spliced strip material as defined in claim 1, wherein the increase in the initial differential takes place a predetermined interval before a splice in the strip material reaches said bead, and the decrease in the differential pressure to the initial differential air pressure takes place a predetermined interval after the splice has passed through said bead of liquid composition.
3. The method of coating a strip of spliced strip material as defined in claim 1, wherein the initial differential air pressure is in the order of 0.1 inch to 5.00 inch of water.
4. The method of coating a strip of spliced strip material as defined in claim 1, wherein the increased differential air pressure is 2 to 12 times that of the initial differential air pressure.
5. A method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice, comprising:
moving the web adjacent and relative to the coating device;
discharging a ribbon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web;
subjecting the surface of the ribbon advancing into contact with the web to an initial predetermined subatmospheric gaseous pressure while maintaining atmospheric pressure on the opposite surface of the ribbon;
reducing said subatmospheric pressure by a predetermined increment a predetermined interval before the splice in the web reaches the ribbon of coating material; maintaining the reduced subatmospheric pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and
increasing said subatmospheric pressure to said initial predetermined subatmospheric pressure after said second interval.
6. The method of coating a strip of spliced strip material as defined in claim 5, wherein the initial subatmospheric pressure is 0.5 inch to 0.7 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.9 inch to 1.0 inch of water less than atmospheric pressure.
7. The method of coating a strip of spliced material as defined in claim 5, wherein the strip of material is butt spliced by a strip of splicing tape extending transversely of and overlying the butted ends of the strip and the splicing tape is on the surface of the web to be coated, the initial subatmospheric pressure is 0.2 inch to 0.7 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.7 inch to 1.0 inch of water less than atmospheric pressure.
8. A method of coating a strip of spliced material as defined in claim 5, wherein the splicing tape is on the uncoated side of the strip of material and the initial subatmospheric pressure is 0.6 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.9 inch of water less than atmospheric pressure.
9. In a method of coating a moving web of substantially nonporous flexible material containing at least one splice whose thickness is substantially greater than the thickness of the web of material with a liquid coating composition having viscosities of between 3 and 35 centipoises, comprising flowing a thin layer of said composition from a coating device to the web of nonporous material to form a bead of composition therebetween extending transversely of the web, said bead having a depth several times the thickness of said web while passing from the coating device to the web and while the web moves toward the coating device and away from the coating device, maintaining the bead of coating composition in a coating condition by applying an initial predetermined differential in gaseous pressures on the two sides of the bead of coating composition, the pressure on that side of the bead from which the web approaches the coating device being less than the pressure on that side of the bead from which the web moves away from the coating device, the improvement which comprises,
increasing the initial pressure differential a predetermined increment a predetermined time interval before a splice in the web reaches the bead of coating composition;
maintaining the increased pressure differential until the splice in the web has passed through said bead of coating composition; and
decreasing the pressure differential to the initial pressure differential after the splice in the web has passed through said bead of coating composition.
10. A method of coating a strip of spliced material as defined in claim 9, wherein the increased pressure differential is applied when the splice is approximately 2 feet ahead of the coating bead and is decreased to the initial differential pressure after the splice is approximately 2 feet beyond the coating bead.
11. A method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice, comprising:
moving the web adjacent and relative to the coating device;
discharging a ribbon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web;
establishiing an initial predetermined gaseous pressure differential across the opposite surfaces of the ribbon, such that the pressure on the surface of the ribbon advancing into contact with the web is lower than the pressure on the opposite surface of the ribbon;
increasing the differential pressure by a predetermined increment a predetermined interval before the splice in the web reaches the ribbon of coating material;
maintaining the increased differential pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and
decreasing the differential pressure to the initial predetermined pressure after said second interval.
12. A method of coating a thin layer ofliquid coating material from a coating device onto a web having at least one transverse splice, comprising:
moving the web adjacent and relative to the coating device;
discharging a ribbon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web;
subjecting the surface of the ribbon advancing into contact with the web to an initial predetermined subatmospheric gaseous pressure in the range of 0.2 to 0.6 inches of water less than atmospheric pressure, while maintaining atmospheric pressure on the opposite surface of the ribbon;
reducing said subatmospheric pressure by a predetermined increment to a pressure in the range of 0.7 to 1.0 inches of water less than atmospheric pressure a predetermined interval before the splice in the web reaches the ribbon of coating material;
maintaining the reduced subatmospheric pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and
increasing said subatmospheric pressure to said initial predetermined subatmospheric pressure after said second interval.

Claims (12)

1. A METHOD OF COATING A SPLICED STRIP MATERIAL FROM A COATING DEVICE WHICH COMPRISES MOVING THE STRIP MATERIAL ADJACENT AND RELATIVE TO THE COATING DEVICE, DISCHARGING A RIBBON OF LIQUID COATING COMPOSITION FROM THE COATING DEVICE TOWARD SAID STRIP OF MATERIAL TO FORM AND MAINTAIN A BEAD OD LIQUID COMPOSITION TRANSVERELY OF AN AREA OF THE MOVING STRIP ACROSS WHICH THE WEB MOVES AND PICKS UP A LAYER OF SAID LIQUID COMPOSITION, SUBJECTING THE BEAD OF LIQID COATING COMPOSITION TO A INITIAL DIFFERENTIAL AIR PRESSURE TO HOLD THE BEAD OF COATING COMPOSITION FROM MOVEMENT IN THE DIRECTION OF TRAVEL OF THE STRIP MATERIAL, THE PRESSURES BEING SELECTED TO RETAIN THE BEAD OF COATING COMPOSITION IN A COATING POSITION AND TO MAINTAIN A UNIFORM COATING ON THE STRIP MATERIAL, THE LESSER AIR PRESSURE BEING ON THE SIDE OF THE BEAD TOWARD WHICH THE WEB APPROACHES, INCREADING THE INITIAL DIFFERENTIAL AIR PRESSURE JUST BEFORE A SPLICE IN THE STRIP MATERIAL REACHES SAID BEAD, MAINTAINING THE INCREASED DIFFERENTIAL AIR PRESSURE UNTIL THE SPLICE IN THE STRIP MATERIAL HAS PASSED THROUGH SAID BEAD, AND DECREASING THE DIFFERENTIAL AIR PRESSURE TO THE INITIAL DIFFERENTIAL AIR PRESSURE AFTER THE SPLICE IN THE STRIP MATERIAL HAS PASSED THROUGH SAID BEAD.
2. The method of coating a strip of spliced strip material as defined in claim 1, wherein the increase in the initial differential takes place a predetermined interval before a splice in the strip material reaches said bead, and the decrease in the differential pressure to the initial differential air pressure takes place a predetermined interval after the splice has passed through said bead of liquid composition.
3. The method of coating a strip of spliced strip material as defined in claim 1, wherein the initial differential air pressure is in the order of 0.1 inch to 5.00 inch of water.
4. The method of coating a strip of spliced strip material as defined in claim 1, wherein the increased differential air pressure is 2 to 12 times that of the initial differential air pressure.
5. A method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice, comprising: moving the web adjacent and relative to the coating device; discharging a ribbon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web; subjecting the surface of the ribbon advancing into contact with the web to an initial predetermined subatmospheric gaseous pressure while maintaining atmospheric pressure on the opposite surface of the ribbon; reducing said subatmospheric pressure by a predetermined increment a predetermined interval before the splice in the web reaches the ribbon of coating material; maintaining the reduced subatmospheric pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and increasing said subatmospheric pressure to said initial predetermined subatmospheric pressure after said second interval.
6. The method of coating a strip of spliced strip material as defined in claim 5, wherein the initial subatmospheric pressure is 0.5 inch to 0.7 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.9 inch to 1.0 inch of water less than atmospheric pressure.
7. The method of coating a strip of spliced mAterial as defined in claim 5, wherein the strip of material is butt spliced by a strip of splicing tape extending transversely of and overlying the butted ends of the strip and the splicing tape is on the surface of the web to be coated, the initial subatmospheric pressure is 0.2 inch to 0.7 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.7 inch to 1.0 inch of water less than atmospheric pressure.
8. A method of coating a strip of spliced material as defined in claim 5, wherein the splicing tape is on the uncoated side of the strip of material and the initial subatmospheric pressure is 0.6 inch of water less than atmospheric pressure and the reduced subatmospheric pressure is 0.9 inch of water less than atmospheric pressure.
9. IN A METHOD OF COATNG A MOVING WEB OF SUBSTANTIALLY NONPOROUS FLIXIBLE MATERIAL CONTAINING AT LEAST ONE SPLICE WHOSE THICKNESS IS SUBSTANTIALLY GREATER THAN THE THICKNESS OF THE WEB OF MATERIAL WITH A LIQUID COATNG COMPOLSITION HAVING VISCOSITIES OF BETWEEN 3 AND 35 CENTIPOISES, COMPRISING FLOWING A THIN LAYER OF SAID COMPOSITION FROM A COATING DEVICE TO THE WEB OF NONPOROUS MATERIAL TO FORM A BEAD OF COMPOSITION THEREBETWEEN EXTENDING TRANSVERSELY OF THE WEB, SAID BEAD HAVING A DEPTH SEVERAL TIMES THE THICKNESS OF SAID WEB WHILE PSSING FROM THE COATING DEVICE TO THE WEB AND WHILE THE WEB MOVES TOWARD THE COATING DEVICE AND AWAY FROM THE CATING DEVICE, MAINTAINING THE BEAD OF COATING COMPOSITION IN A COATING CONDITION BY APPLYING AN INITIAL PREDETERMINED DIFFERENTIAL IN GASEOUS PRESSURES ON THE TWO SIDES OF THE BEAD OF COATING COMPOSITION, THE PRESSURE ON THAT SIDE OF THE BEAD FROM WHICH THE WEB APPROACHES THE COATING DEVICE BEING LESS THAN THE PRESSURE ON THAT SIDE OF THE BEAD FROM WHICH THE WEB MOVES AWAY FROM THE COATING DEVICE, THE IMPROVEMENT WHICH COMPRISES, INCREASING THE INITIAL PRESSURE DIFFERENTIAL A PREDETERMINED INCREMENT A PREDETERMINED TIME INTERVAL BEFORE A SPLICE IN THE WEB REACHES THE BEAD OF COATING COMPOSITION, MAINTAINING THE INCREASED PRESSURE DIFFERENTIAL UNTIL THE SPLICE IN THE WEB HAD PASSED HROUGH SAI BEAD OF COATING COMPOSITION, AND DECREASING THE PRESSURE DIFFERENTIAL TO THE INITIAL PRESSURE DIFFERENTIAL AFTER THE SPLICE IN THE WEB HAS PASSED THROUGH SAID BEAD OF COATING COMPOSITION.
10. A method of coating a strip of spliced material as defined in claim 9, wherein the increased pressure differential is applied when the splice is approximately 2 feet ahead of the coating bead and is decreased to the initial differential pressure after the splice is approximately 2 feet beyond the coating bead.
11. A method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice, comprising: moving the web adjacent and relative to the coating device; discharging a ribbon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web; establishiing an initial predetermined gaseous pressure differential across the opposite surfaces of the ribbon, such that the pressure on the surface of the ribbon advancing into contact with the web is lower than the pressure on the opposite surface of the ribbon; increasing the differential pressure by a predetermined increment a predetermined interval before the splice in the web reaches the ribbon of coating material; maintaining the increased differential pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and decreasing the differential pressure to the initial predetermined pressure after said second interval.
12. A method of coating a thin layer of liquid coating material from a coating device onto a web having at least one transverse splice, comprising: moving the web adjacent and relative to the coating device; discharging a ribBon of the liquid coating material from the coating device onto said moving web in bridging relation between the coating device and the moving web; subjecting the surface of the ribbon advancing into contact with the web to an initial predetermined subatmospheric gaseous pressure in the range of 0.2 to 0.6 inches of water less than atmospheric pressure, while maintaining atmospheric pressure on the opposite surface of the ribbon; reducing said subatmospheric pressure by a predetermined increment to a pressure in the range of 0.7 to 1.0 inches of water less than atmospheric pressure a predetermined interval before the splice in the web reaches the ribbon of coating material; maintaining the reduced subatmospheric pressure for a predetermined interval after the splice in the web reaches the ribbon coating material; and increasing said subatmospheric pressure to said initial predetermined subatmospheric pressure after said second interval.
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US3996885A (en) * 1973-01-26 1976-12-14 Eastman Kodak Company Apparatus for coating a multiple number of layers onto a substrate
US4113903A (en) * 1977-05-27 1978-09-12 Polaroid Corporation Method of multilayer coating
DE2812946A1 (en) * 1977-03-26 1978-09-28 Konishiroku Photo Ind COATING DEVICE
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US4612875A (en) * 1985-03-25 1986-09-23 Qmi Corporation Film coater
US4722297A (en) * 1985-03-25 1988-02-02 The First National Bank Film coater
US4973500A (en) * 1988-10-19 1990-11-27 Nkk Corporation Method of plating metal sheets by passing the sheet upwards in close proximity to an upwardly directed nozzle
US5154951A (en) * 1990-03-26 1992-10-13 Eastman Kodak Company Method and apparatus for use in bead coating a web with liquid composition
US5443638A (en) * 1992-08-22 1995-08-22 Hoechst Aktiengesellschaft Device for generating a subatmospheric pressure
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US3996885A (en) * 1973-01-26 1976-12-14 Eastman Kodak Company Apparatus for coating a multiple number of layers onto a substrate
DE2812946A1 (en) * 1977-03-26 1978-09-28 Konishiroku Photo Ind COATING DEVICE
US4113903A (en) * 1977-05-27 1978-09-12 Polaroid Corporation Method of multilayer coating
US4172001A (en) * 1978-07-07 1979-10-23 Eastman Kodak Company Spliced web adapted for coating with liquid coating compositions
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US5962075A (en) * 1995-06-07 1999-10-05 Avery Dennison Method of multilayer die coating using viscosity adjustment techniques
US6824828B2 (en) 1995-06-07 2004-11-30 Avery Dennison Corporation Method for forming multilayer release liners
US20050074549A1 (en) * 1995-06-07 2005-04-07 Avery Dennison Corporation Method for forming multilayer release liners and liners formed thereby
US20050100677A1 (en) * 1995-06-07 2005-05-12 Avery Dennison Corporation Method for forming multilayer release liners and liners formed thereby
US6576296B1 (en) 1998-03-10 2003-06-10 3M Innovative Properties Company Web coating method and apparatus for continuous coating over splices
US6465165B2 (en) * 1999-05-14 2002-10-15 Eastman Kodak Company Scratch resistant-water resistant overcoat for photographic systems
US20100243157A1 (en) * 2005-12-29 2010-09-30 Hae Joon Son Sealant Forming Apparatus, Sealant Forming Method, And Method Of Manufacturing Liquid Crystal Display Device Using The Same
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