US3653598A - Vibrating spray apparatus and method of spraying - Google Patents
Vibrating spray apparatus and method of spraying Download PDFInfo
- Publication number
- US3653598A US3653598A US41484A US3653598DA US3653598A US 3653598 A US3653598 A US 3653598A US 41484 A US41484 A US 41484A US 3653598D A US3653598D A US 3653598DA US 3653598 A US3653598 A US 3653598A
- Authority
- US
- United States
- Prior art keywords
- tube
- spray
- liquid
- outlet
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B3/00—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
- B05B3/02—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
- B05B3/028—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements the rotation being orbital
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B3/00—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
- B05B3/02—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S239/00—Fluid sprinkling, spraying, and diffusing
- Y10S239/01—Pattern sprinkler
Definitions
- ABSTRACT A vibrating spray apparatus and method of spraying which produces a spray pattern of substantial uniform density, the sprayapparatus including a spray tube that is free at one of its ends, means to supply liquid to the spray tube from the other end thereof, a motion transmitting device associated with the spray tube to impart vibrations of sufficient magnitude to the spray tube to cause the free end of the tube to move in an orbital path.
- the method of the present invention involves the movement of a stream of liquid in an orbital path wherein the liquid is discharged while moving in the orbital path to produce a pattern of uniform density.
- VIBRATING SPRAY APPARATUS AND METHOD OF SPRAYING This invention relates to a vibrating spray apparatus and method of spraying and has as its objective the provision of a new and improved device of this general class as well as a significant method to achieve remarkably uniform spraying in agricultural and other fields.
- Another advantage inherent in spraying concentrated liquids is that a very small volume will almost necessarily produce a lower total amount of fine droplets (less than 400 microns in diameter), and this will minimize drift of spray droplets that is caused by drafts and wind whereas in high volume spraying a large number of fine droplets is usually produced. Also, where a droplet is produced having a size greater than 2,000 microns in diameter, it normally will subdivide into a primary droplet and a satellite droplet, with the latter usually being a fine droplet.
- liquid spray device which is relatively simple and inexpensive to manufacture in view of its small number of moving parts.
- Still another object of this invention is to provide a spray device that produces stable droplets (between 400 and 2,000 microns in diameter).
- Another object of the present invention is to provide a liquid spray device including an elongated spray tube fixedly mounted at one end and free at the other wherein a restricted outlet is provided, said tube being associated with motion transmitting means capable of imposing vibrations on the free end of the tube of a magnitude and in a direction sufficient to cause the free end of the tube to move in an orbital path whereby liquid supplied to and passing through said tube is broken into discrete particles as it is emitted therefrom through the restricted outlet and is thrown outwardly thereof in a generally uniform, curvilinear pattern by the movement of said tube.
- Another object of the invention is to provide means for orbitting the tube that is positioned remote therefrom whereby the tube is subjected to little or no wear.
- Another object is to dispose the spray tube in a generally vertical position with respect to its major axis whereby the spray emitted therefrom is directed downwardly in an expanding pattern of great uniformity and under close control whereby spraying operations may be generally improved.
- a still further object of the invention is to provide a method for producing a curvilinear spray pattern wherein an elongated spray tube is provided which is fixedly mounted atone end and free at the other end; the tube being caused to gyrate by means acting adjacent the fixed end thereof whereby the free end describes an orbital path. Liquid supplied to the tube and passing outwardly from the free end thereof is broken into substantially uniform particles that are thrown outwardly in an expanding curvilinear pattern, the shape, size and direction of which is controlled, within limits, by the rate of vibrations imparted to said tube and the design of the free end of said tube.
- FIG. 1 is a perspective view of a spray apparatus embodying the present invention, with certain portions cut away and certain other portions shown in section in order to reveal internal portions of the device;
- FIG. 2 is a sectional view taken along the lines 22 of FIG.
- FIG. 3 is an enlarged sectional view taken along the lines 3-3 of FIG. 1;
- FIG. 4 is a greatly enlarged sectional view of the free end of the spray tube shown in FIG. 1 in actual rotation in an orbital path, and showing a second position of the end of the spray tube;
- FIG. 5 is a view taken along the lines 5-5 of FIG. 4.
- an improved spray device 20 is shown.
- This device may be formed from any suitable material that is resistant to the liquid to be sprayed and which has sufficient strength to be useful over extended periods of time, this material is a matter of choice and forms no part of this invention.
- the entire device, except for some moving parts, is molded from a polycarbonate plastic.
- the device 20 includes a liquid reservoir 22 at the upper end thereof which is cylindrical in cross section and which is closed at its upper end by cover 24.
- the cover 24 carries an inlet 26 and an overflow and air vent 28 therein.
- the inlet 26 is connected to any suitable source of liquid by means of conduit 30.
- the inlet 26 is preferably formed from a tubular metal insert 32 pressed into the cover 24.
- a float 40 which is a hollow cylindrical member that is dimensioned so as to control the amount of liquid admitted to said reservoir 22.
- the float moves upwardly to cause a valve (not shown) to close and prevent further liquid to enter.
- the valve opens.
- a protuberance 42 is provided at the bottom of the reservoir 22 to prevent the float 40 closing off an outlet passage 44 from the reservoir.
- This outlet 44 connects with an elongated standpipe 46 that carries a flexible, liquid spray device 48 at its lower extremity.
- This device 48 includes several important details and controls that will be described in detail hereinafter.
- a pair of supports, 50 and 52 may be molded on or attached to the standpipe 46 and these carry the remainder of the mechanism of the device 20.
- Support 50 extends outwardly and normal to the standpipe 46 and supports a small motor 54.
- This motor 54 is a commercially available device (see U.S. Pat. No. 2,842,692) and forms no part of my invention.
- the motor 54 is fixedly positioned on the support bracket 50 which is bifurcated so that the motor may be easily inserted and removed.
- the lower bracket 52 is also bifurcated but in the opposite direction whereby two arms 56 and 58 are formed, their functions will be described later.
- the motor 54 is connected to a shaft 60 through a shock absorbing connection 62. This consists merely of a rubber-like sleeve that embraces the motor shaft at one end and the drive shaft 60 at the other.
- the lower end of shaft 60 connects through a second shock absorbing member 64 with a shaft 66.
- This shaft 66 passes through the arm 56 and is joumalled thereby and is also journalled in the arm 58.
- a weight 68 Between the arms 56 and 58 and fixedly positioned on the shaft 66 is a weight 68.
- This weight 68 is mounted off-center with respect to the shaft 66 whereby during rotation of the shaft 66, the weight 68 causes vibration of the device. This vibration is controlled with respect to the motor 54 and its bearings (not shown) by means of the two shock absorbing connections 62 and 64 and suffers little transmission of the vibration caused by the off-center weight 68, certainly not enough to cause any harm.
- the off-center weight 68 is the means for imparting vibrations to the standpipe 46 which carries the spray device 48 at its lower extremity. It will be noted that the upper end of the device 48 is fixedly mounted to the standpipe 46 but that the lower end thereof is free and unsupported. When the motor 54 causes the off-center weight 68 to rotate, vibrations are set up in the standpipe 46, particularly in the lower end thereof. These vibrations, because of the way they are induced, create an orbital movement that is imperceptible within the standpipe 46 but which is amplified as it reaches the free end of the spray tube 48 causing it to gyrate in an orbit of curvilinear extent.
- the motor 44 operating free at from 10,000 to 12,000 RPM and using a polyethylene spray tube 48 having a free and unsupported length of 1% inches, an outer diameter of three-sixteenths of an inch and a bore of oneeighth of an inch, that the motor speed was reduced to 1,200 to 1,500 RPM when a aqueous vehicle was being sprayed through a terminal nozzle on the tube 48 having four orifices each of 0.017 inches in diameter.
- the vibrations were caused by a brass weight one-half inch long, threeeighths of an inch in diameter and positioned with its axis oneeighth inch off center.
- FIGS. 3 and 4 are offered to show various details of the spray tube 48.
- a check valve 70 is used which prevent leakage when the device is inactive.
- the valve 70 includes an elastomeric seat 72 consisting of an O ring seated in the base of a tubular extension 74 which is closed by gravity by a ball bearing 76 when the device is inactive.
- tubular extension 74 ends in a nipple 73A that is slipped within upstream end 73B of tube 48.
- the downstream end 81A of tube 48 receives plug 81.
- the ball 76 rises and opens the valve 70 whereby liquid may flow downwardly to the end of the tube 48.
- the tube 48 includes a plug 81 with several identical restricted orifices or passages 80 at the free end thereof. It will be noted that these are each bent outwardly a small amount and this acts to increase the extent of the spray pattern. It is apparent that many such deviations in design may be used to alter the type, extent and shape of pattern. It will be discovered that desired results may best be accomplished through trial with limited experimentation for any specific application of the device.
- FIG. 4 shows in dotted lines the positions assumed by the tube 48 when the device is in operation. Another limit is depicted in dotted lines at 82.
- FIG. 5 is offered to show that the orbit 84 of the tube 48 is of generally circular extent although it is apparent that it may also be elliptical, if desired. It is also possible to oscillate the tube 48 through suitable modification. However, more energy is absorbed in this instance due to the cyclic changes in direction of the tube 48. Such an energy loss does not occur when using orbital movement since the direction of movement is always the same.
- an outer cover (not shown) may be used.
- the cover may be provided with bayonet slots which cooperate with protuberances on the lower portion of the reservoir 22. In the instant case, these protuberances are formed by collars that project and protect the power lines for the motor 54. The cover in this form is easily attached or detached as desired.
- the device of this invention may be formed by die-casting, machining or built up from a plurality of parts made from metal, plastic or a combination thereof.
- the invention is in no way limited to specific materials or constructions but is broadly directed to a novel and inexpensive way to obtain an orbital movement of a spray tube which in turn affects a controlled atomization and distribution of liquid particles.
- a dust boot or cover (not shown) which may be slipped over the collar 71.
- a dust boot or cover (not shown) which may be slipped over the collar 71.
- Such a shield if resilient, will in no way affect the gyrations of the tube 48 but will prevent dust from affecting the moving parts of the exciting mechanism.
- a flexible spray tube 48 (as shown) has many advantages in agricultural applications.
- the spray device is positioned rather close to the ground, the flexible tube may flex when clearance is insufficient to pass vegetation, for example. Such flexing does not affect operation nor does it harm the tube or nozzles.
- the use of replaceable nozzles or orifices is highly useful since the quantity and type of spray pattern may be modified by simply changing said nozzles.
- the tube 48 has been disclosed as being formed from a flexible plastic material. On the other hand, it may be fabricated from a relatively non-flexible plastic or from metal, if desired. In this instance, the orbital movement of the free end of the tube will not be as great when exposed to the same exciting force. However, lengthening of the tube and or increasing the exciting force (by greater vibration or increased frequency or both) will improve the extent of the orbital path and it is believed that the exercise of these changes is clearly within the purview of persons skilled in the art.
- the device as disclosed is limited to a generally vertical application due to gravity flow of the liquid to be sprayed, it is apparent that the same may be positioned in any desired manner, due to disposition or desire, and if the gravity feed is not practical, that a pressure feed may be used while still enjoying themany advantages of the device.
- the spray tube is caused to rotate about an axis by a vibrating source of energy, rather than a turning force.
- small quantities of concentrated liquid such as 1 pint per acre, can be precisely and evenly applied to a target area.
- the apparatus of the present invention can handle liquids other than solutions, such as suspensions, and can handle liquids having a wide range of viscosities.
- the present invention is relatively compact and inexpensive. Furthermore, with the present invention the pattern can be made to be dense in the center or dense on the outside or uniform throughout.
- a liquid spray device adapted to produce a spray of substantially uniform density having a generally curvilinear pattern, comprising in combination: an elongated flexible spray tube fixedly mounted at one end and free at the other end and having a restricted outlet at said free end thereof; liquid supply means connected to said tube adjacent said fixed end and adapted to supply liquid thereto to be sprayed from said outlet; and a motion transmitting device associated with said tube and adapted to impart vibrations thereto at a resonant frequency in a direction and of sufficient magnitude to cause the outlet end of said tube to describe an orbital path about a fixed stationary axis through the fixed end of said spray tube whereby liquid being emitted from said outlet is thrown outwardly in the form of discrete particles to produce a predetermined curvilinear spray pattern.
- a liquid spray device adapted to produce a spray having a substantially uniform density and of a generally circular pattern, comprising in combination: a generally perpendicularly disposed, elongated, flexible spray tube fixedly mounted at the inlet end thereof and free at the outlet end; liquid supply means connected to said tube adjacent the fixed end thereof and adapted to supply liquid thereto to be sprayed from said outlet; and a motion producing device associated with said tube and adapted to impart vibrations thereto at a resonant frequency in a direction and with sufficient magnitude to cause the outlet end of said tube to move in a generally circular orbital path about a fixed stationary axis through the fixed end of the spray tube whereby liquid being emitted from said outlet is thrown therefrom in the form of discrete particles to produce a predetermined circular spray pattern.
- said restricted outlet consists of four separate small diameter tubes each bent slightly adjacent the ends thereof so as to be non-parallel with the major axis of the device.
- the device claimed in claim 4 including a motor and offcenter weight which are positioned in misalignment with the axis of said tube.
- a liquid spray device adapted to produce a spray having a substantially uniform density and of a generally circular pattern, comprising in combination: a generally perpendicularly disposed, elongated flexible spray tube fixedly mounted at the inlet end thereof and free at the outlet end; liquid supply means connected to said tube adjacent the fixed end thereof and adapted to supply liquid thereto to be sprayed from said outlet; and a motion producing device associated with said tube and adapted to impart vibrations thereto at a resonant frequency in a direction and with sufficient magnitude to cause the outlet end of said tube to move in a generally circular orbital path about a fixed stationary axis through the fixed end of the spray tube whereby liquid being emitted from said outlet is thrown therefrom in the form of discrete particles to produce a predetermined circular spray pattern, valve means being provided adjacent the device wherein valve means are provided adjacent the fixedly mounted end of the spray tube, said valve means being sensitive to said vibrations to remain open for permitting liquid flow therethrough and closing only when said vibrations cease to prevent such flow.
Abstract
Description
Claims (9)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4148470A | 1970-05-28 | 1970-05-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3653598A true US3653598A (en) | 1972-04-04 |
Family
ID=21916760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US41484A Expired - Lifetime US3653598A (en) | 1970-05-28 | 1970-05-28 | Vibrating spray apparatus and method of spraying |
Country Status (1)
Country | Link |
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US (1) | US3653598A (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4209132A (en) * | 1977-03-18 | 1980-06-24 | Well Men Industrial Company Limited | Shower spray heads |
US4369850A (en) * | 1980-07-28 | 1983-01-25 | The Curators Of The University Of Missouri | High pressure fluid jet cutting and drilling apparatus |
EP0130235A2 (en) * | 1983-07-01 | 1985-01-09 | Wakatsuki Kikai Kabushiki Kaisha | Apparatus for producing ultrahigh pressure water jet |
US4984743A (en) * | 1984-03-26 | 1991-01-15 | The Dow Chemical Company | Pesticide spray nozzle |
WO1996013333A1 (en) * | 1994-10-31 | 1996-05-09 | Jet Blast Products Corp. | Nozzle system |
EP0852160A3 (en) * | 1996-12-02 | 1999-03-31 | Graco Inc. | Pattern controllable dispensing apparatus |
WO1999046126A1 (en) | 1998-03-09 | 1999-09-16 | Hegedus Gyoergy | Liquid dispensing apparatus |
EP1163186A1 (en) * | 1998-11-05 | 2001-12-19 | Graco Inc. | Rotary vibrating applicator for viscous materials |
WO2002062490A2 (en) * | 2001-01-12 | 2002-08-15 | Graco Minnesota Inc. | Swirl applicator tip |
GB2380148A (en) * | 2001-08-07 | 2003-04-02 | Nordson Corp | Orbiting spray nozzle |
US6629649B2 (en) * | 2000-05-05 | 2003-10-07 | Sealant Equipment & Engineering, Inc. | Orbital applicator tool with static mixer tip seal valve |
DE102007006600A1 (en) | 2007-02-09 | 2008-08-14 | Nordson Corp., Westlake | Fluid e.g. sealing material, application device, has application head coupled with drive device e.g. hydraulic actuator, for achieving periodic translation movement, where application head is mounted on linear guide in form of linear rail |
US8833675B1 (en) * | 2010-11-08 | 2014-09-16 | Richard Meigs | Orbital cleaning assembly and method |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1796942A (en) * | 1928-05-31 | 1931-03-17 | Jr Francis M Pottenger | Sprinkler |
US3030031A (en) * | 1959-12-01 | 1962-04-17 | Robert L Barker | Water dispensing device |
US3399638A (en) * | 1967-06-23 | 1968-09-03 | Amchem Prod | Agricultural spray device |
US3488001A (en) * | 1966-10-20 | 1970-01-06 | Donald Alexander Sawers | Garden or field watering devices |
-
1970
- 1970-05-28 US US41484A patent/US3653598A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1796942A (en) * | 1928-05-31 | 1931-03-17 | Jr Francis M Pottenger | Sprinkler |
US3030031A (en) * | 1959-12-01 | 1962-04-17 | Robert L Barker | Water dispensing device |
US3488001A (en) * | 1966-10-20 | 1970-01-06 | Donald Alexander Sawers | Garden or field watering devices |
US3399638A (en) * | 1967-06-23 | 1968-09-03 | Amchem Prod | Agricultural spray device |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4209132A (en) * | 1977-03-18 | 1980-06-24 | Well Men Industrial Company Limited | Shower spray heads |
US4369850A (en) * | 1980-07-28 | 1983-01-25 | The Curators Of The University Of Missouri | High pressure fluid jet cutting and drilling apparatus |
EP0130235A2 (en) * | 1983-07-01 | 1985-01-09 | Wakatsuki Kikai Kabushiki Kaisha | Apparatus for producing ultrahigh pressure water jet |
EP0130235A3 (en) * | 1983-07-01 | 1987-07-01 | Wakatsuki Kikai Kabushiki Kaisha | Apparatus for producing ultrahigh pressure water jet |
US4984743A (en) * | 1984-03-26 | 1991-01-15 | The Dow Chemical Company | Pesticide spray nozzle |
WO1996013333A1 (en) * | 1994-10-31 | 1996-05-09 | Jet Blast Products Corp. | Nozzle system |
US5533673A (en) * | 1994-10-31 | 1996-07-09 | Jet Blast Products Corp. | Nozzle system imparting compound motion |
GB2308556A (en) * | 1994-10-31 | 1997-07-02 | Jet Blast Prod Corp | Nozzle system |
GB2308556B (en) * | 1994-10-31 | 1998-11-04 | Jet Blast Prod Corp | Nozzle system |
EP0852160A3 (en) * | 1996-12-02 | 1999-03-31 | Graco Inc. | Pattern controllable dispensing apparatus |
WO1999046126A1 (en) | 1998-03-09 | 1999-09-16 | Hegedus Gyoergy | Liquid dispensing apparatus |
US6460980B1 (en) | 1998-03-09 | 2002-10-08 | Hegedus Gyoergy | Liquid dispensing apparatus |
EP1163186A1 (en) * | 1998-11-05 | 2001-12-19 | Graco Inc. | Rotary vibrating applicator for viscous materials |
EP1163186A4 (en) * | 1998-11-05 | 2004-09-15 | Graco Inc | Rotary vibrating applicator for viscous materials |
US6629649B2 (en) * | 2000-05-05 | 2003-10-07 | Sealant Equipment & Engineering, Inc. | Orbital applicator tool with static mixer tip seal valve |
WO2002062490A2 (en) * | 2001-01-12 | 2002-08-15 | Graco Minnesota Inc. | Swirl applicator tip |
WO2002062490A3 (en) * | 2001-01-12 | 2003-02-13 | Graco Minnesota Inc | Swirl applicator tip |
GB2380148A (en) * | 2001-08-07 | 2003-04-02 | Nordson Corp | Orbiting spray nozzle |
US6758418B2 (en) | 2001-08-07 | 2004-07-06 | Nordson Corporation | Swirl gun |
DE102007006600A1 (en) | 2007-02-09 | 2008-08-14 | Nordson Corp., Westlake | Fluid e.g. sealing material, application device, has application head coupled with drive device e.g. hydraulic actuator, for achieving periodic translation movement, where application head is mounted on linear guide in form of linear rail |
US8833675B1 (en) * | 2010-11-08 | 2014-09-16 | Richard Meigs | Orbital cleaning assembly and method |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: UNION CARBIDE CORPORATION Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC.;REEL/FRAME:003903/0689 Effective date: 19810608 Owner name: UNION CARBIDE CORPORATION A CORP. OF N.Y. Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC.;REEL/FRAME:003903/0689 Effective date: 19810608 |
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Owner name: MORGAN GUARANTY TRUST COMPANY OF NEW YORK, AND MOR Free format text: MORTGAGE;ASSIGNORS:UNION CARBIDE CORPORATION, A CORP.,;STP CORPORATION, A CORP. OF DE.,;UNION CARBIDE AGRICULTURAL PRODUCTS CO., INC., A CORP. OF PA.,;AND OTHERS;REEL/FRAME:004547/0001 Effective date: 19860106 |
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Owner name: UNION CARBIDE CORPORATION, Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:MORGAN BANK (DELAWARE) AS COLLATERAL AGENT;REEL/FRAME:004665/0131 Effective date: 19860925 |
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Owner name: UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC., Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE CORPORATION A CORP. OF NY;REEL/FRAME:004748/0190 Effective date: 19860930 |
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Owner name: UNION CARBIDE CORPORATION,CONNECTICUT Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC., A CORP. OF PA;REEL/FRAME:004761/0647 Effective date: 19861218 Owner name: UNION CARBIDE CORPORATION, 39 OLD RIDGEBURY RD., D Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC., A CORP. OF PA;REEL/FRAME:004761/0647 Effective date: 19861218 |
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Owner name: RHONE POULENC NEDERLANDS B.V., DRAAISTROOM 1, POST Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE CORPORATION;REEL/FRAME:004751/0394 Effective date: 19861219 |