US3619280A - Treated paper and nonwoven material for wiping surfaces and method therefor - Google Patents
Treated paper and nonwoven material for wiping surfaces and method therefor Download PDFInfo
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- US3619280A US3619280A US843223A US3619280DA US3619280A US 3619280 A US3619280 A US 3619280A US 843223 A US843223 A US 843223A US 3619280D A US3619280D A US 3619280DA US 3619280 A US3619280 A US 3619280A
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- 239000000463 material Substances 0.000 title abstract description 46
- 238000000034 method Methods 0.000 title description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 239000012530 fluid Substances 0.000 claims abstract description 11
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 10
- 229940041616 menthol Drugs 0.000 claims description 10
- 241000196324 Embryophyta Species 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- 239000001993 wax Substances 0.000 abstract description 9
- 239000010409 thin film Substances 0.000 abstract description 5
- 150000002334 glycols Chemical class 0.000 abstract description 3
- 239000010665 pine oil Substances 0.000 abstract description 3
- 235000019645 odor Nutrition 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- 238000005498 polishing Methods 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- 239000003981 vehicle Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 8
- 238000010410 dusting Methods 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- 230000001815 facial effect Effects 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 239000005844 Thymol Substances 0.000 description 4
- 229960000790 thymol Drugs 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 3
- 241000723346 Cinnamomum camphora Species 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229960000846 camphor Drugs 0.000 description 3
- 229930008380 camphor Natural products 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 239000003974 emollient agent Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000009429 distress Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 230000037307 sensitive skin Effects 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 210000000436 anus Anatomy 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- -1 menthol Chemical class 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002687 nonaqueous vehicle Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/005—Preparations for sensitive skin
Definitions
- Tissue-type paper and nonwoven material are uniformly impregnated with a nonaqueous liquid carrier selected from liquid hydrocarbons, glycols and pine oils containing an agent uniformly distributed therein automatically, by applying a predetermined quantity of treating fluid to any portion of the nontreated material.
- the agent is selected from waxes, silicones and materials producing a predetermined odor. The agent does not separate from the carrier until at least the treated material is substantially impregnated, and the carrier and agent remain in the material substantially as when it was impregnated and are deposited in the same proportions as a thin film on a surface wiped by the material.
- This invention relates to a disposable treated tissue and nonwoven material. More particularly, it relates to a treated tissue or nonwoven material, which may be used as is, to wipe a predetermined surface and deposit a thin, invisible film on such surface, and which material is then discarded; and a process for treating the tissue and material.
- the treated tissue and material may be used for a variety of personal and cleaning purposes, such as toilet tissue, facial tissue, and dusting and polishing cloths, and wipers.
- Treated paper is old.'l-lowever, all of the treatments to these materials are directed solely to affecting the paper or material.
- paper has been treated with ingredients that inhibit mold growth, bacteria growth, sticking of candy and the like on or to the treated paper. These treated materials are incapable of transmitting that treatment to another surface, since the treating material is dried or hardened after application.
- the manner of treatment for paper on one hand, and tissue or nonwoven material on the other hand is entirely different.
- paper, cloth or the like was treated with the desired ingredients by coating the surface by rollers or other mechanical means, or the paper or cloth was pulled through the treating liquid. While this method is feasible for strong papers and cloths, it is not practical, or is too expensive, for thin materials or multiple tissue paper.
- an agent such as a water-repellant
- a solvent for certain purposes an agent, such as a water-repellant
- This treatment also was with respect to the cloth itself, i.e., waterproofing it.
- the present invention is directed to treating relatively weak paper materials, such as tissue papers and nonwoven materials. These materials are inexpensive and are intended to be disposable.
- the paper and nonwoven materials are treated not for affecting the properties of the paper and material, but to apply the treating fluid in the same proportions as originally applied to the paper, to another surface that is wiped with the treated paper or material, in a thin layer, in which the agent is uniformly distributed.
- the treated tissue or material acts as an applicator for the treating fluid, even while performing its primary function as a facial tissue or wiper or toilet tissue or cluster.
- the different end uses of the material treated in accordance with the present invention require different agents, all of which are completely dispersed in a nonaqueous carrier.
- the total quantity of treating fluid is applied to any portion of the tissue paper and distributes itself throughout the paper uniformly, in the same proportion of agent to carrier, as originally applied, so that a surface wiped with one portion of the treated paper will have the same quantity of agent remaining on it as another surface wiped with a different portion of the treated paper.
- the treated paper applies a nondrying film in a thin layer, so as to provide a maximum polish and high gloss without leaving any smearing film.
- lt is still a further object of the present invention to provide a treated tissue having an emollient feel and a long shelf life, which can be applied to the nose by sufferers of colds and other respiratory afflictions, which provides a desired characteristic odor to relieve the distress caused by these ailments, as well as applying a soothing film for preventing chapping and irritation of the skin.
- Treated paper and nonwoven material prepared in accordance with the present invention is useful for many purposes, such as cleaning, polishing and dusting various types of surfaces, including furniture, automobiles, glass, mirrors and the like.
- the treated paper besides polishing collects and retains the dust in the air with resulting respiratory dangers, as well as the resettling of the dust on the surfaces cleaned.
- the treated tissue made in accordance with the present invention is emollient and can be used dry on the most delicate and fine wood finishes, and deposits an invisible thin film on the surface wiped without the need of further additional material, liquid, or additional polishing or rubbing.
- the present treated paper is easy to use and provides a high gloss on the wiped surface.
- tissue paper may be treated in accordance with the present invention with a nonaqueous liquid carrier vehicle and a chemical which produces an odor, which alleviates the distress occasioned by nasal, throat or bronchial ailments.
- a chemical which produces an odor, which alleviates the distress occasioned by nasal, throat or bronchial ailments.
- One such chemical is menthol, represented by the formula C l-l OH and its homologues.
- Other chemicals are thymol, represented by the formula CH (C H,)C,,H -,OH and its homologues, and camphor, represented by the formula C l- O and its homologues.
- Menthol and thymol and their homologues have properties in common and may be classified under the broad group of phenols and their corresponding carbocyclic products of varying degrees of saturation.
- the chemical homogenously mixed with the carrier retains its odorforming properties, even for a long period of shelf life, and produces a slow, continuous release of the odor for a relatively long period of time, much longer than if the chemical were applied directly, and the present invention not used.
- the treated tissue In use the treated tissue is used in the conventional manner in wiping the nose.
- the odors of the chemical used provides relief to the user and the pliable treated tissue deposits a thin film of oil and odor-producing chemical on the sensitive skin about the nose and lips of the user, which oil prevents irritation and chapping of the skin, and the odor remains for a relatively long period. After use the tissue is discarded.
- essential oils are volatile oils derived from the selected plants and flowers carrying the characteristic odor or flavor of the plant or flower used.
- toilet tissue may be impregnated with a liquid hydrocarbon and a silicone, in accordance with the present invention, which will sooth the irritated skin by depositing a thin layer ofoil on the skin ofthe user without any greasy feeling.
- the paper being treated will absorb sufficient treating material, such as a polishing agent, menthol or other ingredients, to render the paper useful for the purpose intended, such as polishing and dusting, a toilet tissue or a facial type of tissue, without altering the structure of the paper if the paper is treated with a nonaqueous liquid vehicle, in which the treating material is substantially uniformly distributed.
- the treating liquid is selfspreading throughout the entire sheet and is spread evenly over the entire surface of the paper. No separate drying operation is required, as was necessary previously.
- nonaqueous liquid vehicles are known, which are useful for the purpose of the present invention.
- liquid hydrocarbons e.g., normally light liquid hydrocarbon oils, aliphatic naphthas, Stoddard solvents, kerosenes (refined), paraffinic hydrocarbons, natural mineral oil and white mineral oil.
- normally liquid hydrocarbons e.g., normally light liquid hydrocarbon oils, aliphatic naphthas, Stoddard solvents, kerosenes (refined), paraffinic hydrocarbons, natural mineral oil and white mineral oil.
- the nonaqueous liquid vehicles generally employed are those that are nontoxic or norlirritating when the paper contacts the skin.
- All of the ingredients are preferably completely dispersible in the nonaqueous vehicle, and remain so, so that subsequent agitation is not needed to redisperse the ingredients in the vehicle before use.
- a total all-side surface treatment is assured. This is especially important when tissue paper is being used, which comes in one-, two-, three-, four-ply, or more.
- certain agents should be incorporated in the paper.
- a silicone, wax or menthol, scent, perfume or other agent or combination of these may be added to the liquid vehicle a silicone, wax or menthol, scent, perfume or other agent or combination of these, whichwill be absorbed by the paper when the paper is processed in accordance with this invention.
- waxes, scents, pine alcohols, essential oils and/r silicones can be added to the required degree and the resulting admixture remains clear indefinitely without separation. This will permit the production of the treated paper for the many different purposes intended in the invention.
- waxes which are suitable for use, are carnauba. beeswax, candelilla, paraffin, ceresin, esparto, ouricuri, rezowax and other known waxes.
- a feature of the present invention is the fact that no separation of the essential constituents of the treating composition occurs. This is true of the treating liquid before it is applied to the nonwoven material or tissue, as well as the treating composition disposed on the paper or tissue. Since the treatment of the paper in accordance with the present invention may involve contacting the paper with a treating solution for several days, it is very important that the components of the treating liquid do not separate out during this period. Furthermore, since it may take several days for the treating fluid to reach the deeper plies of paper, it is essential for the proper treatment of these deeper plies that the constituents of the treating fluid do not separate out.
- the ratio of the treating liquid to the weight of treated paper will vary in the range of from about 10 to 70 parts by weight of the treated paper.
- a multiple of paper sheets, size 12 inches X24 inches, requires for end use a 25 percent treatment.
- the weight of the paper unit untreated is 10 grams; therefore, 2.5 grams of the solution is applied to any part of this paper unit, which distributes itself throughout the paper evenly in a relatively short time.
- the range of wax or combination of waxes added can vary from I percent to 40 percent of the impregnating liquid, with about 7 percent to 15 percent being preferred; the silicone added should not be less than one-tenth of a percent and the range of the odor-producing chemical can vary from about fif- 10 teen-hundredth of a percent to about seven-tenths of a percent, all percentages being by weight of the impregnated sheet.
- EXAMPLE 1 The percentages of the materials indicated below in this example, are based on the total weight of the treating liquid made in accordance with the present invention.
- the solution penetrated every part of its corresponding paper to provide a uniform distribution of the treating solution throuh tth dv m t r F m g on e paper an 0 er e en ire sur ace. or e pur pose of this invention, a permanently dispersed and uniform distribution of the vehicle throughout the paper is necessary.
- the sheet is treated in any convenient manner with a predetermined quantity of the nonaqueous treating solution from about 7/2% to about 70% of the weight of the treated paper product applied locally to any spot or part of the surface thereof.
- the entire quantity of treating liquid applied to the paper is absorbed and retained by the paper.
- the treated paper or tissue is packaged in the normal manner, and within a relatively short time, i.e., several hours to a few days, the treating solution spreads by itself to penetrate every part of the paper without any further act being necessary to provide a uniform and homogeneous distribution of the treating solution throughout the paper.
- the treated paper feels dry to the touch.
- An impregnated paper sheet made in accordance with the present invention is soft and clothlike, so that it covers all of the areas or surfaces to be wiped or contacted.
- the treated paper is pliable and soft, so that the most sensitive skin surface or furniture surface rubbed with it will not be irritated, marred or scratched. Dust or loose dirt on the furniture adheres to the surface of the treated sheet when the furniture is wiped by the sheet used as a polishing or dusting cloth. In view of the large surfaces of the sheet, a large amount of dust can be collected. lf smearing or transferring a heavy layer of oil to the surface wiped is to be avoided, care should be taken as to how much treating liquid is applied to the paper. Further, the added agents, especially the odor-producing compounds, such as menthol, are retained on the sheets and on the surface wiped, for long periods of time, with little or insignificant loss of effective power. Thus, the present invention provides long shelf life for the treated paper.
- a medicated tissue for depositing a thin film on the skin of the user which emits a medical odor comprising tissue paper uniformly impregnated with a nonaqueous treating fluid consisting essentially of a liquid hydrocarbon oil containing an agent uniformly distributed therein, said agent being selected from menthol, a homologue of menthol, thymol, a homologue of thymol, camphor, and a homologue of camphor, said agent being not less than 0.1% by weight of the treated tissue and the treating fluid being at least about 7 /2 to 70% of the weight of the impregnated tissue with the proportion of the liquid hydrocarbon oil being greater than that of the agent, there being no separation of the liquid hydrocarbon oil and agent until at least the tissue is substantially impregnated, said liquid hydrocarbon oil and said agent releasably remaining uniformly distributed in said tissue during the normal life of the tissue in the state substantially as when the tissue was impregnated and capable of being deposited as a film on the skin of the user wiped by the tissue
Abstract
Tissue-type paper and nonwoven material are uniformly impregnated with a nonaqueous liquid carrier selected from liquid hydrocarbons, glycols and pine oils containing an agent uniformly distributed therein automatically, by applying a predetermined quantity of treating fluid to any portion of the nontreated material. The agent is selected from waxes, silicones and materials producing a predetermined odor. The agent does not separate from the carrier until at least the treated material is substantially impregnated, and the carrier and agent remain in the material substantially as when it was impregnated and are deposited in the same proportions as a thin film on a surface wiped by the material.
Description
I United States Patent 11113,619,280
[72] Inventor Fred F. Scheuer 2,584,413 2/1952 Baer et al 106/287 X Bronx, N.Y. 2,681,859 6/1954 Wenaas 106/287 X [21] Appl. No. 843,223 2,820,719 1/1958 Trusler et a1.. 117/158 X [22] Filed July 18, 1969 2,933,431 4/1960 Sperouleas 424/28 X Continuation of Ser. No. 475,234 3,071,479 1/1963 Fulenwider.... 106/287 X July 27, 1965, abandoned 3,230,289 1/1966 Eder et a1. .t 1 17/161 X [45] Patented Nov. 9, 1971 [73] Assignee Dustikin Products, Inc. j f immliler wlmam DlMamn Bronx NY. sszstan! .rammer-M.R. Lusignan Attorney-Howard C. Miskin [54] TREATED PAPER AND NON-WOVEN MATERIAL FOR WIPING SURFACES AND METHOD THEREFOR 4 Claims, No Drawings US. Cl 117/154, 15/209, 117/155 R, 117/158, 424/28 Int. Cl D2lh l/40, D21h 5/22 'Field of Search 15/209, 210,506,104.93;106/287C;117/154,158,155 R; 424/28 References Cited UNITED STATES PATENTS 7/1884 Wheeler 117/158 X ABSTRACT: Tissue-type paper and nonwoven material are uniformly impregnated with a nonaqueous liquid carrier selected from liquid hydrocarbons, glycols and pine oils containing an agent uniformly distributed therein automatically, by applying a predetermined quantity of treating fluid to any portion of the nontreated material. The agent is selected from waxes, silicones and materials producing a predetermined odor. The agent does not separate from the carrier until at least the treated material is substantially impregnated, and the carrier and agent remain in the material substantially as when it was impregnated and are deposited in the same proportions as a thin film on a surface wiped by the material.
T A APER AND NQ L-WQVEN. MATERIAL. F WIPING SURFACES AND METHOD THEREFOR This application is a continuation of my copending application for Treated Paper and Tissue, filed July 27, 1965, Ser. No. 475,234, now abandoned.
This invention relates to a disposable treated tissue and nonwoven material. More particularly, it relates to a treated tissue or nonwoven material, which may be used as is, to wipe a predetermined surface and deposit a thin, invisible film on such surface, and which material is then discarded; and a process for treating the tissue and material. The treated tissue and material may be used for a variety of personal and cleaning purposes, such as toilet tissue, facial tissue, and dusting and polishing cloths, and wipers.
Treated paper is old.'l-lowever, all of the treatments to these materials are directed solely to affecting the paper or material. Hence, paper has been treated with ingredients that inhibit mold growth, bacteria growth, sticking of candy and the like on or to the treated paper. These treated materials are incapable of transmitting that treatment to another surface, since the treating material is dried or hardened after application. Further, the manner of treatment for paper on one hand, and tissue or nonwoven material on the other hand, is entirely different. Heretofore, paper, cloth or the like was treated with the desired ingredients by coating the surface by rollers or other mechanical means, or the paper or cloth was pulled through the treating liquid. While this method is feasible for strong papers and cloths, it is not practical, or is too expensive, for thin materials or multiple tissue paper. Similarly, for certain purposes an agent, such as a water-repellant, was distributed over the surface of cloth by dissolving the agent in a solvent, spreading the solution on the surface, and evaporating the solvent, thereby leaving the agent attached to the surface. This treatment also was with respect to the cloth itself, i.e., waterproofing it.
The present invention is directed to treating relatively weak paper materials, such as tissue papers and nonwoven materials. These materials are inexpensive and are intended to be disposable. The paper and nonwoven materials are treated not for affecting the properties of the paper and material, but to apply the treating fluid in the same proportions as originally applied to the paper, to another surface that is wiped with the treated paper or material, in a thin layer, in which the agent is uniformly distributed. In effect, the treated tissue or material acts as an applicator for the treating fluid, even while performing its primary function as a facial tissue or wiper or toilet tissue or cluster.
The different end uses of the material treated in accordance with the present invention require different agents, all of which are completely dispersed in a nonaqueous carrier. The total quantity of treating fluid is applied to any portion of the tissue paper and distributes itself throughout the paper uniformly, in the same proportion of agent to carrier, as originally applied, so that a surface wiped with one portion of the treated paper will have the same quantity of agent remaining on it as another surface wiped with a different portion of the treated paper.
it is an object of the present invention to provide a disposable treated tissue or nonwoven material, which is useful for many purposes, including personal, toilet, and dusting and polishing of furniture and glass surfaces, and which is simple and convenient to use.
It is another object of the present invention to provide a treated paper, which is disposable, economical and effective in polishing delicate surfaces, such as furniture, cars, metal, plastic and glass, when wiped with any part of this treated paper. The treated paper applies a nondrying film in a thin layer, so as to provide a maximum polish and high gloss without leaving any smearing film.
It is a further object of the present invention to provide a treated tissue, which is dry to the touch and having an emollient feel, which is usable as toilet tissue by sufferers of piles and other irritations of the anus.
lt is still a further object of the present invention to provide a treated tissue having an emollient feel and a long shelf life, which can be applied to the nose by sufferers of colds and other respiratory afflictions, which provides a desired characteristic odor to relieve the distress caused by these ailments, as well as applying a soothing film for preventing chapping and irritation of the skin.
It is another object of the present invention to provide a method for preparing such treated paper in a similar manner.
Treated paper and nonwoven material prepared in accordance with the present invention is useful for many purposes, such as cleaning, polishing and dusting various types of surfaces, including furniture, automobiles, glass, mirrors and the like. The treated paper besides polishing collects and retains the dust in the air with resulting respiratory dangers, as well as the resettling of the dust on the surfaces cleaned. The treated tissue made in accordance with the present invention is emollient and can be used dry on the most delicate and fine wood finishes, and deposits an invisible thin film on the surface wiped without the need of further additional material, liquid, or additional polishing or rubbing. The present treated paper is easy to use and provides a high gloss on the wiped surface.
-Additionally, tissue paper may be treated in accordance with the present invention with a nonaqueous liquid carrier vehicle and a chemical which produces an odor, which alleviates the distress occasioned by nasal, throat or bronchial ailments. One such chemical is menthol, represented by the formula C l-l OH and its homologues. Other chemicals are thymol, represented by the formula CH (C H,)C,,H -,OH and its homologues, and camphor, represented by the formula C l- O and its homologues. Menthol and thymol and their homologues have properties in common and may be classified under the broad group of phenols and their corresponding carbocyclic products of varying degrees of saturation. The chemical homogenously mixed with the carrier retains its odorforming properties, even for a long period of shelf life, and produces a slow, continuous release of the odor for a relatively long period of time, much longer than if the chemical were applied directly, and the present invention not used.
In use the treated tissue is used in the conventional manner in wiping the nose. The odors of the chemical used provides relief to the user and the pliable treated tissue deposits a thin film of oil and odor-producing chemical on the sensitive skin about the nose and lips of the user, which oil prevents irritation and chapping of the skin, and the odor remains for a relatively long period. After use the tissue is discarded.
Also, other chemicals can be used to provide desired odors to the impregnated paper, including essential oils" and artificial scents, which produce animal, tree, plant, flower, astringent and medicinal odors, which are well known in the cosmetic and perfumery fleld. Essential oils" are volatile oils derived from the selected plants and flowers carrying the characteristic odor or flavor of the plant or flower used. (See The Condensed Chemical Dictionary"-7th Edition, Reinhold Publishing Corp. 196 l 1966.)
Similarly, toilet tissue may be impregnated with a liquid hydrocarbon and a silicone, in accordance with the present invention, which will sooth the irritated skin by depositing a thin layer ofoil on the skin ofthe user without any greasy feeling.
Heretofore, in the manufacture of treated facial and toilet tissues and polishing and dust cloths made of paper, cotton and the like, it has been customary to impregnate the material with an aqueous solution containing the treating ingredients by spraying, soaking and the like, which ingredients were then air dried on the material. Because of the nature of the structure of the cloth or special types of paper, these could be subjected to treatment with an aqueous solution for long periods of time without deleterious effect. In attempting to apply these aqueous processes to the treatment of conventional paper, such as tissue paper, it was found that the results were not satisfactory. It was found that paper treated with an aqueous solution could not absorb more than one percent of water without altering its structure. The absorption of this small amount of water would not result in the deposition of adequate amounts of the treating material, such as polishing agents on the paper. It was thus necessary to devise a method to deposit an adequate amount of the treating material on the paper without altering the structure of the paper. Also, the dried paper required wetting in some manner from an outside source before using, in order to be effective.
In accordance with the present invention, the paper being treated will absorb sufficient treating material, such as a polishing agent, menthol or other ingredients, to render the paper useful for the purpose intended, such as polishing and dusting, a toilet tissue or a facial type of tissue, without altering the structure of the paper if the paper is treated with a nonaqueous liquid vehicle, in which the treating material is substantially uniformly distributed. The treating liquid is selfspreading throughout the entire sheet and is spread evenly over the entire surface of the paper. No separate drying operation is required, as was necessary previously.
A variety of nonaqueous liquid vehicles are known, which are useful for the purpose of the present invention. Among these may be mentioned liquid hydrocarbons, glycols and pine oils. The preferred liquid vehicles are the normally liquid hydrocarbons, e.g., normally light liquid hydrocarbon oils, aliphatic naphthas, Stoddard solvents, kerosenes (refined), paraffinic hydrocarbons, natural mineral oil and white mineral oil.
Since the products of the present invention generally come in contact with the skin, the nonaqueous liquid vehicles generally employed are those that are nontoxic or norlirritating when the paper contacts the skin.
All of the ingredients are preferably completely dispersible in the nonaqueous vehicle, and remain so, so that subsequent agitation is not needed to redisperse the ingredients in the vehicle before use. By using the proper percentage of liquid vehicle, a total all-side surface treatment is assured. This is especially important when tissue paper is being used, which comes in one-, two-, three-, four-ply, or more.
For some purposes, certain agents should be incorporated in the paper. Thus, for example, there may be added to the liquid vehicle a silicone, wax or menthol, scent, perfume or other agent or combination of these, whichwill be absorbed by the paper when the paper is processed in accordance with this invention.
With the present invention, waxes, scents, pine alcohols, essential oils and/r silicones can be added to the required degree and the resulting admixture remains clear indefinitely without separation. This will permit the production of the treated paper for the many different purposes intended in the invention.
Some waxes, which are suitable for use, are carnauba. beeswax, candelilla, paraffin, ceresin, esparto, ouricuri, rezowax and other known waxes.
A feature of the present invention is the fact that no separation of the essential constituents of the treating composition occurs. This is true of the treating liquid before it is applied to the nonwoven material or tissue, as well as the treating composition disposed on the paper or tissue. Since the treatment of the paper in accordance with the present invention may involve contacting the paper with a treating solution for several days, it is very important that the components of the treating liquid do not separate out during this period. Furthermore, since it may take several days for the treating fluid to reach the deeper plies of paper, it is essential for the proper treatment of these deeper plies that the constituents of the treating fluid do not separate out.
The relative proportions of the ingredients contained in the impregnating liquid may be varied considerably without departing from the spirit of this invention. in the preferred practice of the invention, the ratio of the treating liquid to the weight of treated paper will vary in the range of from about 10 to 70 parts by weight of the treated paper. For example, a multiple of paper sheets, size 12 inches X24 inches, requires for end use a 25 percent treatment. The weight of the paper unit untreated is 10 grams; therefore, 2.5 grams of the solution is applied to any part of this paper unit, which distributes itself throughout the paper evenly in a relatively short time.
5 The range of wax or combination of waxes added can vary from I percent to 40 percent of the impregnating liquid, with about 7 percent to 15 percent being preferred; the silicone added should not be less than one-tenth of a percent and the range of the odor-producing chemical can vary from about fif- 10 teen-hundredth of a percent to about seven-tenths of a percent, all percentages being by weight of the impregnated sheet.
The following examples are further illustrative of the present invention. It is to be understood, however, that this invention is not limited thereto.
EXAMPLE 1 The percentages of the materials indicated below in this example, are based on the total weight of the treating liquid made in accordance with the present invention.
Seven percent of camauba wax and three percent paraffin wax was mixed with a solution containing 87% hydrocarbon distillate" and 3% silicones until fully and uniformly dispersed. Paper treated with this liquid is useful in dusting and polishing.
" A Colorless, light, nonodorous I00 F. 30/35. Silicons- I00 Centistrokes viscosity at I00" F.
petroleum distillate, Saybolt viscosity at Example 2 A solution was prepared by mixing 1% menthol and 1% lavender with 97% of hydrocarbon distillate" and l% cosmetic silicones This solution is used in treating facial tissues. The percentages of materials indicated above in this example, are based on the total weight ofthe treating solution made in accordance with this invention Siliconesnonirritating-20 Centistrokes Viscosity at I00 F The above solutions were affixed onto two test samples of paper. The treating solutions were free-flowing and a predetermined amount was applied locally to one spot or part of the surface of the paper to be treated. Within a few days, the solution penetrated every part of its corresponding paper to provide a uniform distribution of the treating solution throuh tth dv m t r F m g on e paper an 0 er e en ire sur ace. or e pur pose of this invention, a permanently dispersed and uniform distribution of the vehicle throughout the paper is necessary.
In preparing the treated sheet constituting the product of 6 this invention, the sheet is treated in any convenient manner with a predetermined quantity of the nonaqueous treating solution from about 7/2% to about 70% of the weight of the treated paper product applied locally to any spot or part of the surface thereof. The entire quantity of treating liquid applied to the paper is absorbed and retained by the paper. Ad-
vantageously, the treated paper or tissue is packaged in the normal manner, and within a relatively short time, i.e., several hours to a few days, the treating solution spreads by itself to penetrate every part of the paper without any further act being necessary to provide a uniform and homogeneous distribution of the treating solution throughout the paper. The treated paper feels dry to the touch.
An impregnated paper sheet made in accordance with the present invention is soft and clothlike, so that it covers all of the areas or surfaces to be wiped or contacted. The treated paper is pliable and soft, so that the most sensitive skin surface or furniture surface rubbed with it will not be irritated, marred or scratched. Dust or loose dirt on the furniture adheres to the surface of the treated sheet when the furniture is wiped by the sheet used as a polishing or dusting cloth. In view of the large surfaces of the sheet, a large amount of dust can be collected. lf smearing or transferring a heavy layer of oil to the surface wiped is to be avoided, care should be taken as to how much treating liquid is applied to the paper. Further, the added agents, especially the odor-producing compounds, such as menthol, are retained on the sheets and on the surface wiped, for long periods of time, with little or insignificant loss of effective power. Thus, the present invention provides long shelf life for the treated paper.
What I claim is:
l. A medicated tissue for depositing a thin film on the skin of the user which emits a medical odor comprising tissue paper uniformly impregnated with a nonaqueous treating fluid consisting essentially of a liquid hydrocarbon oil containing an agent uniformly distributed therein, said agent being selected from menthol, a homologue of menthol, thymol, a homologue of thymol, camphor, and a homologue of camphor, said agent being not less than 0.1% by weight of the treated tissue and the treating fluid being at least about 7 /2 to 70% of the weight of the impregnated tissue with the proportion of the liquid hydrocarbon oil being greater than that of the agent, there being no separation of the liquid hydrocarbon oil and agent until at least the tissue is substantially impregnated, said liquid hydrocarbon oil and said agent releasably remaining uniformly distributed in said tissue during the normal life of the tissue in the state substantially as when the tissue was impregnated and capable of being deposited as a film on the skin of the user wiped by the tissue wherein the agent and an oil are homogeneously mixed on the skin of the user to provide a slow continuous release of the odor of the agent.
2. A tissue in accordance with claim 1, wherein said agent further has the characteristic odor of a selected animal, plant, flower, tree or medicine, and a silicone, said agent not exceeding 2% of the treated tissue.
3. A tissue according to claim 1, wherein the weight of liquid hydrocarbon and said agent is at least about l0% to 70% by weight of the impregnated paper.
4. A tissue according to claim 2, wherein said agent includes about 1% of menthol, l% oflavender and about 1% to 8% ofa silicone, all percentages being based on total weight of the treating fluid, and said carrier being a white mineral oil.
Claims (3)
- 2. A tissue in accordance with claim 1, wherein said agent further has the characteristic odor of a selected animal, plant, flower, tree or medicine, and a silicone, said agent not exceeding 2% of the treated tissue.
- 3. A tissue according to claim 1, wherein the weight of liquid hydrocarbon and said agent is at least about 10% to 70% by weight of the impregnated paper.
- 4. A tissue according to claim 2, wherein said agent includes about 1% of menthol, 1% of lavender and about 1% to 8% of a silicone, all percentages being based on total weight of the treating fluid, and said carrier being a white mineral oil.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84322369A | 1969-07-18 | 1969-07-18 |
Publications (1)
Publication Number | Publication Date |
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US3619280A true US3619280A (en) | 1971-11-09 |
Family
ID=25289376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US843223A Expired - Lifetime US3619280A (en) | 1969-07-18 | 1969-07-18 | Treated paper and nonwoven material for wiping surfaces and method therefor |
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US (1) | US3619280A (en) |
Cited By (30)
Publication number | Priority date | Publication date | Assignee | Title |
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US3965519A (en) * | 1974-07-08 | 1976-06-29 | S. C. Johnson & Son, Inc. | Disposable floor polishing wipe |
US4123592A (en) * | 1976-04-07 | 1978-10-31 | Philip Morris Incorporated | Process for incorporating flavorant into cellulosic substrates and products produced thereby |
US4233976A (en) * | 1978-07-06 | 1980-11-18 | Minnesota Mining And Manufacturing Company | Styptic device |
US4493124A (en) * | 1981-10-27 | 1985-01-15 | Michael Agapiou | Toilet cleaning tool |
US4562060A (en) * | 1977-12-01 | 1985-12-31 | Astra Lakemedel Aktiebolag | Local anesthetic mixture for topical application, process for its preparation, as well as method for obtaining local anesthesia |
US4564535A (en) * | 1982-01-22 | 1986-01-14 | Henkel Kommanditgesellschaft Auf Aktien | Product and process for scenting packaging materials |
US4627936A (en) * | 1984-10-05 | 1986-12-09 | Gould Paper Corp. | Towel premoistened with antistatic solution for cleaning cathode-ray tubes and the like |
FR2637798A1 (en) * | 1988-10-18 | 1990-04-20 | Chauvin Sa Laboratoire | NEW PALPEBRAL COMPRESSES, THEIR PROCESS OF IMBIBITION AND THE PRODUCTS THUS PRODUCED |
US5473789A (en) * | 1993-10-18 | 1995-12-12 | Oster; Alan L. | Disposable toilet seat cleaning pad |
US5525345A (en) * | 1993-12-13 | 1996-06-11 | The Proctor & Gamble Company | Lotion composition for imparting soft, lubricious feel to tissue paper |
WO1996019204A1 (en) * | 1994-12-19 | 1996-06-27 | The Procter & Gamble Company | Medicated tissue paper product |
US5558873A (en) * | 1994-06-21 | 1996-09-24 | Kimberly-Clark Corporation | Soft tissue containing glycerin and quaternary ammonium compounds |
GB2299101A (en) * | 1995-03-22 | 1996-09-25 | Neil Edward Hobday | A personal hygiene system including menthol |
US5601871A (en) * | 1995-02-06 | 1997-02-11 | Krzysik; Duane G. | Soft treated uncreped throughdried tissue |
US5605749A (en) * | 1994-12-22 | 1997-02-25 | Kimberly-Clark Corporation | Nonwoven pad for applying active agents |
US5624676A (en) * | 1995-08-03 | 1997-04-29 | The Procter & Gamble Company | Lotioned tissue paper containing an emollient and a polyol polyester immobilizing agent |
US5650218A (en) * | 1995-02-06 | 1997-07-22 | Kimberly-Clark Corporation | Soft treated tissue |
US5705164A (en) * | 1995-08-03 | 1998-01-06 | The Procter & Gamble Company | Lotioned tissue paper containing a liquid polyol polyester emollient and an immobilizing agent |
US5716692A (en) * | 1994-06-17 | 1998-02-10 | The Procter & Gamble Co. | Lotioned tissue paper |
AU692855B2 (en) * | 1994-06-21 | 1998-06-18 | Kimberly-Clark Worldwide, Inc. | Soft tissue containing glycerin and quaternary ammonium compounds |
US5871763A (en) * | 1997-04-24 | 1999-02-16 | Fort James Corporation | Substrate treated with lotion |
US5885697A (en) * | 1996-12-17 | 1999-03-23 | Kimberly-Clark Worldwide, Inc. | Soft treated tissue |
US6428794B1 (en) | 1994-06-17 | 2002-08-06 | The Procter & Gamble Company | Lotion composition for treating tissue paper |
US20020146561A1 (en) * | 2001-01-19 | 2002-10-10 | Guido Baumoller | Lotioned fibrous web having a short water absorption time |
US20020148583A1 (en) * | 2001-01-19 | 2002-10-17 | Guido Baumoller | Tissue paper penetrated with softening lotion |
US6485733B1 (en) | 1998-12-31 | 2002-11-26 | Kimberly-Clark Worldwide, Inc. | Absorbent article composition for sequestering skin irritants |
US20040026289A1 (en) * | 2002-08-08 | 2004-02-12 | Halkyard Douglas R. | Mirror wipe assembly |
US20040072488A1 (en) * | 2001-04-12 | 2004-04-15 | The Procter & Gamble Company | Cleaning sheets having long-lasting perfume odor |
US20050115856A1 (en) * | 2002-08-08 | 2005-06-02 | Halkyard Douglas R. | Mirror wipe assembly |
US10092932B2 (en) | 2015-04-30 | 2018-10-09 | Alan Oster | Multilayered disposable cleaning pad |
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US3965519A (en) * | 1974-07-08 | 1976-06-29 | S. C. Johnson & Son, Inc. | Disposable floor polishing wipe |
US4123592A (en) * | 1976-04-07 | 1978-10-31 | Philip Morris Incorporated | Process for incorporating flavorant into cellulosic substrates and products produced thereby |
US4562060A (en) * | 1977-12-01 | 1985-12-31 | Astra Lakemedel Aktiebolag | Local anesthetic mixture for topical application, process for its preparation, as well as method for obtaining local anesthesia |
US4233976A (en) * | 1978-07-06 | 1980-11-18 | Minnesota Mining And Manufacturing Company | Styptic device |
US4493124A (en) * | 1981-10-27 | 1985-01-15 | Michael Agapiou | Toilet cleaning tool |
US4564535A (en) * | 1982-01-22 | 1986-01-14 | Henkel Kommanditgesellschaft Auf Aktien | Product and process for scenting packaging materials |
US4627936A (en) * | 1984-10-05 | 1986-12-09 | Gould Paper Corp. | Towel premoistened with antistatic solution for cleaning cathode-ray tubes and the like |
EP0365427A1 (en) * | 1988-10-18 | 1990-04-25 | Laboratoire Chauvin Sa | Eyelid compresses, process for soaking same and resultant products |
FR2637798A1 (en) * | 1988-10-18 | 1990-04-20 | Chauvin Sa Laboratoire | NEW PALPEBRAL COMPRESSES, THEIR PROCESS OF IMBIBITION AND THE PRODUCTS THUS PRODUCED |
US5473789A (en) * | 1993-10-18 | 1995-12-12 | Oster; Alan L. | Disposable toilet seat cleaning pad |
US5525345A (en) * | 1993-12-13 | 1996-06-11 | The Proctor & Gamble Company | Lotion composition for imparting soft, lubricious feel to tissue paper |
US5716692A (en) * | 1994-06-17 | 1998-02-10 | The Procter & Gamble Co. | Lotioned tissue paper |
US6428794B1 (en) | 1994-06-17 | 2002-08-06 | The Procter & Gamble Company | Lotion composition for treating tissue paper |
US5558873A (en) * | 1994-06-21 | 1996-09-24 | Kimberly-Clark Corporation | Soft tissue containing glycerin and quaternary ammonium compounds |
AU692855C (en) * | 1994-06-21 | 2001-07-19 | Kimberly-Clark Worldwide, Inc. | Soft tissue containing glycerin and quaternary ammonium compounds |
AU692855B2 (en) * | 1994-06-21 | 1998-06-18 | Kimberly-Clark Worldwide, Inc. | Soft tissue containing glycerin and quaternary ammonium compounds |
US5720966A (en) * | 1994-12-19 | 1998-02-24 | The Procter & Gamble Company | Medicated tissue paper product |
KR100373792B1 (en) * | 1994-12-19 | 2003-04-21 | 더 프록터 앤드 갬블 캄파니 | Medicated tissue paper product |
WO1996019204A1 (en) * | 1994-12-19 | 1996-06-27 | The Procter & Gamble Company | Medicated tissue paper product |
US5605749A (en) * | 1994-12-22 | 1997-02-25 | Kimberly-Clark Corporation | Nonwoven pad for applying active agents |
US5650218A (en) * | 1995-02-06 | 1997-07-22 | Kimberly-Clark Corporation | Soft treated tissue |
US5665426A (en) * | 1995-02-06 | 1997-09-09 | Kimberly-Clark Corporation | Soft treated tissue |
US5614293A (en) * | 1995-02-06 | 1997-03-25 | Kimberly-Clark Corporation | Soft treated uncreped throughdried tissue |
US5601871A (en) * | 1995-02-06 | 1997-02-11 | Krzysik; Duane G. | Soft treated uncreped throughdried tissue |
GB2299101A (en) * | 1995-03-22 | 1996-09-25 | Neil Edward Hobday | A personal hygiene system including menthol |
GB2299101B (en) * | 1995-03-22 | 1998-09-09 | Neil Edward Hobday | A personal hygiene system |
US5705164A (en) * | 1995-08-03 | 1998-01-06 | The Procter & Gamble Company | Lotioned tissue paper containing a liquid polyol polyester emollient and an immobilizing agent |
US5624676A (en) * | 1995-08-03 | 1997-04-29 | The Procter & Gamble Company | Lotioned tissue paper containing an emollient and a polyol polyester immobilizing agent |
US5885697A (en) * | 1996-12-17 | 1999-03-23 | Kimberly-Clark Worldwide, Inc. | Soft treated tissue |
US5871763A (en) * | 1997-04-24 | 1999-02-16 | Fort James Corporation | Substrate treated with lotion |
US6485733B1 (en) | 1998-12-31 | 2002-11-26 | Kimberly-Clark Worldwide, Inc. | Absorbent article composition for sequestering skin irritants |
US6551607B1 (en) | 1998-12-31 | 2003-04-22 | Kimberly-Clark Worldwide, Inc. | Method for sequestration of skin irritants with substrate compositions |
US6517848B1 (en) | 1998-12-31 | 2003-02-11 | Kimberly-Clark Worldwide, Inc. | Method for sequestration of skin irritants with absorbent article composition |
US6521241B1 (en) | 1998-12-31 | 2003-02-18 | Kimberly-Clark Worldwide, Inc. | Substrate composition for sequestration of skin irritants |
US6521240B1 (en) | 1998-12-31 | 2003-02-18 | Kimberly-Clark Worldwide, Inc. | Facial tissue composition for sequestration of nasal secretion skin irritants |
US6521242B1 (en) | 1998-12-31 | 2003-02-18 | Kimberly-Clark Worldwide, Inc. | Method for sequestration of nasal secretion skin irritants with facial tissue |
US6905697B2 (en) | 2001-01-19 | 2005-06-14 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
US20020146561A1 (en) * | 2001-01-19 | 2002-10-10 | Guido Baumoller | Lotioned fibrous web having a short water absorption time |
US6860967B2 (en) | 2001-01-19 | 2005-03-01 | Sca Hygiene Products Gmbh | Tissue paper penetrated with softening lotion |
US20050100573A1 (en) * | 2001-01-19 | 2005-05-12 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
US20020148583A1 (en) * | 2001-01-19 | 2002-10-17 | Guido Baumoller | Tissue paper penetrated with softening lotion |
US8545861B2 (en) | 2001-01-19 | 2013-10-01 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
US20040072488A1 (en) * | 2001-04-12 | 2004-04-15 | The Procter & Gamble Company | Cleaning sheets having long-lasting perfume odor |
US20040026289A1 (en) * | 2002-08-08 | 2004-02-12 | Halkyard Douglas R. | Mirror wipe assembly |
US20050115856A1 (en) * | 2002-08-08 | 2005-06-02 | Halkyard Douglas R. | Mirror wipe assembly |
US7325675B2 (en) * | 2002-08-08 | 2008-02-05 | Halkyard Douglas R | Adhesively-securable mirror wipe assembly |
US10092932B2 (en) | 2015-04-30 | 2018-10-09 | Alan Oster | Multilayered disposable cleaning pad |
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