US3533821A - Talc treatment and talc containing pigments - Google Patents
Talc treatment and talc containing pigments Download PDFInfo
- Publication number
- US3533821A US3533821A US625633A US3533821DA US3533821A US 3533821 A US3533821 A US 3533821A US 625633 A US625633 A US 625633A US 3533821D A US3533821D A US 3533821DA US 3533821 A US3533821 A US 3533821A
- Authority
- US
- United States
- Prior art keywords
- talc
- brightness
- kaolin
- treatment
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Definitions
- This invention relates to talc treatment and talc containing pigments and particularly to a method of treating talc to improve its brightness and a pigment containing tale of unique properties as a pigment for paint and the like.
- talc a very low brightness e.g. 65 or less and which contain calcium carbonate and organic material. These talcs have little commercial utility because of the presence of calcium carbonate and because of their poor color which is usually a gray of low brightness.
- Calcining is preferably carried out at about 1050 F. for one hour.
- EXAMPLE I A crude Texas talc having a gray color and a brightness of 65 was ground to the size range 200-325 mesh.
- the ground talc was slurried in water to form a slurry of about 25% solids.
- the slurry was then treated with a solution of H SO +alum (50-50) to an equilibrium pH, which is in the range 4-7.
- the treated talc was then filtered, washed and dried and thereafter calcined for one hour at 1050 F.
- the calcined talc was quenched in water, ground to remove agglomerates and screened through a 200 mesh screen, dried and pulverized.
- the final product had a brightness of 94-96% at 457 mp. relative to a smoked magnesium oxide block.
- EXAMPLE II The same Texas talc ground to 200-325 mesh as in Example I was slurried in water to 25% solids and treated with 11 H 80 to an equilibrium pH which is in the range of 4-7. A Georgia kaolin of 0.55 micron average particle size having a brightness of 87-90 was slurried to 25% solids. Kaolin with average particle sizes other than 0.55 micron could also be used with similar reice sults. The two vslurries were blended in the ratio of 20% tale to by weight kaolin on dry basis. The blended slurry was filtered, washed and dried, pulverized and calcined for one hour at 1050 F.
- the calcined product was quenched in water, ground to remove agglomerates, passed through a 200 mesh screen, filtered, dried and pulverized.
- the final product had a brightness of 96 to 98%, which is surprisingly high since the same clay calcined had a brightness of -92% and the treated talc (Example I) had a brightness of 94-96%.
- the average particle size of the blend was 4 microns whereas that of the clay after calcination and pulverization was 0.9-1.8 microns. While I have used a ratio of 20% talc to 80% kaolin in this example, I have used as much as 50% talc to 50% kaolin with similar results.
- Example I The product of Example I was formulated into a paint vehicle and compared with New York State Talc (untreated) and the same New York State Talc (treated by the process of this invention precisely as in Example I).
- Example II The product of Example II was formulated into a paint vehicle and compared with calcined clay and water washed clay, both frequently used as pigments. The results appear in Table H.
- the paint formulations were made up as follows:
- talc containing pigments formed by adding to a slurry of talc an aqueous slurry of kaolin in the Weight proportion of 75-80% kaolin to about 2025% talc on the dry basis are a highly satisfactory bright pigment.
Description
United States Patent Of 3,533,821 TALC TREATMENT AND TALC CONTAININ PIGMENTS John D. Lundquist, Clark, N.J., assignor to Georgia Kaolin Company, a corporation of New Jersey No Drawing. Filed Mar. 24, 1967, Ser. No. 625,633 Int. Cl. C09c 1/02, 1/28 U.S. Cl. 106-306 2 Claims ABSTRACT OF THE DISCLOSURE A method of treating tale to improve its brightness by the steps of grinding, slurrying, treating to acid pH, filtering, washing and calcining either alone or in admixture with kaolin.
This invention relates to talc treatment and talc containing pigments and particularly to a method of treating talc to improve its brightness and a pigment containing tale of unique properties as a pigment for paint and the like.
There are large deposits of talc throughout the world which have a very low brightness e.g. 65 or less and which contain calcium carbonate and organic material. These talcs have little commercial utility because of the presence of calcium carbonate and because of their poor color which is usually a gray of low brightness.
I have found a method of treating such low brightness gray talcs which will eliminate the gray color, the undesirable calcium carbonate and will raise the brightness to a level equal to that of the best natural white talcs.
I have found that if these talcs are ground, slurried, treated with sulfate ion to a constant pH on the acid side, filtered, washed and calcined either alone or in admixture with kaolin I can produce a product having a brightness equal to that of natural white talcs.
Preferably, I slurry the talc after grinding the talc to a size between 200 and 325 mesh and then add either sulfuric acid or a mixture of acid and alum to provide sulfate ion in the slurry. Calcining is preferably carried out at about 1050 F. for one hour.
In the foregoing general description of my invention I have set out certain objects, purposes and advantages. However, other objects, purposes and advantages will become apparent from the following examples.
EXAMPLE I A crude Texas talc having a gray color and a brightness of 65 was ground to the size range 200-325 mesh. The ground talc was slurried in water to form a slurry of about 25% solids. The slurry was then treated with a solution of H SO +alum (50-50) to an equilibrium pH, which is in the range 4-7. The treated talc was then filtered, washed and dried and thereafter calcined for one hour at 1050 F. The calcined talc was quenched in water, ground to remove agglomerates and screened through a 200 mesh screen, dried and pulverized. The final product had a brightness of 94-96% at 457 mp. relative to a smoked magnesium oxide block.
EXAMPLE II The same Texas talc ground to 200-325 mesh as in Example I was slurried in water to 25% solids and treated with 11 H 80 to an equilibrium pH which is in the range of 4-7. A Georgia kaolin of 0.55 micron average particle size having a brightness of 87-90 was slurried to 25% solids. Kaolin with average particle sizes other than 0.55 micron could also be used with similar reice sults. The two vslurries were blended in the ratio of 20% tale to by weight kaolin on dry basis. The blended slurry was filtered, washed and dried, pulverized and calcined for one hour at 1050 F. The calcined product was quenched in water, ground to remove agglomerates, passed through a 200 mesh screen, filtered, dried and pulverized. The final product had a brightness of 96 to 98%, which is surprisingly high since the same clay calcined had a brightness of -92% and the treated talc (Example I) had a brightness of 94-96%. The average particle size of the blend was 4 microns whereas that of the clay after calcination and pulverization was 0.9-1.8 microns. While I have used a ratio of 20% talc to 80% kaolin in this example, I have used as much as 50% talc to 50% kaolin with similar results.
The product of Example I was formulated into a paint vehicle and compared with New York State Talc (untreated) and the same New York State Talc (treated by the process of this invention precisely as in Example I).
The results appear in Table I.
TABLE I New Texas New York York Talc Talc Talc (treated) (untreated) (treated) Percent refleetance 92-93 89-90 90-91 Contrast ratio 0 -0. 98 0. 96 0. 96 Yellowness 0 02-0. 03 0. 02 0. 02 Gloss 1. 2 2. 0 2. 0 Sheen 1 max. 0. 5-1. 0 0. 5 Holdout Viscosity stability- Dry pigment brightness, perce 94-96 89-90 95-96 1 Fair. 9 Excellent. 3 Good. 4 Extremely poor.
From the foregoing table, it can be seen that even a good, naturally bright talc such as New York State can be much improved by my process.
The product of Example II was formulated into a paint vehicle and compared with calcined clay and water washed clay, both frequently used as pigments. The results appear in Table H.
TABLE II Water- Example Calcined wash II Blend clay clay Percent reflectance. 92-93 90-91 87-89 Contrast ratio 0. 98-0. 99 0. 96-0. 97 0. 92-0. 96 Yellowness 0. 01-0. 02 0. 02-0. 03 0. 04-0. 00 1-2 2-3 5-9 1-2 3-5 10-24 1 Fair-good. 2 Poor. 3 Fair. 4 Good.
The paint formulations were made up as follows:
TYPICAL FORMULATION Pounds Gallons Total LON) The same improved results are obtained With other paint formulations.
While the foregoing examples are based on the use of sulfuric acid and mixtures of sulfuric acid and alum, similar improvements in the talc can be obtained by the introduction of chloride or phosphate ion by introduction of HCl or H PO in place of H 50 In the practice of my invention I have found that talc containing pigments formed by adding to a slurry of talc an aqueous slurry of kaolin in the Weight proportion of 75-80% kaolin to about 2025% talc on the dry basis are a highly satisfactory bright pigment.
In the foregoing specification, I have set out certain preferred practices and embodiments of my invention, however, it Will be understood that this invention may be otherwise embodied within the scope of the following claims.
I claim:
1. The method of forming a tale containing pigment comprising the steps of grinding talc to about 200 to 325 mesh, forming an aqueous slurry of said ground talc,
4 treating said slurry with a compound providing in solution a sulfate ion to a constant pH in the range 47, adding to said acidified slurry of talc an aqueous slurry of kaolin in the Weight proportion of 7580% kaolin to References Cited UNITED STATES PATENTS 2,920,974 1/1960 Allen 106306 2,943,971 7/ 1960 Taylor. 3,3 66,501
l/1968 Lamar 106306 JAMES E. POER, Primary Examiner US. Cl. X.R. 106-288, 309
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No 3 ,533, 821 October 13 1970 John D. Lundquist It is certified that error appears in the above identified patent and that said Letters Patent are hereby corrected as shown below:
Column 2 Table I under the heading "Texas Talc (Treated) line 29, "1.2" should read 1-2 Table II, under the heading "Water-wash clay", line 46, "0.92-0.96" should read 0.92-0.94 next line, "0.04-0.00" should read 0.04-0.06 next line, "5-9" should read 5-6 next line "10-24" should read 10-20 Signed and sealed this 6th day of April 1971.
(SEAL) Attest:
EDWARD M.PLETCHER,JR.
Attesting Officer Commissioner of Patents WILLIAM E SCHUYLER, JR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US62563367A | 1967-03-24 | 1967-03-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3533821A true US3533821A (en) | 1970-10-13 |
Family
ID=24506939
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US625633A Expired - Lifetime US3533821A (en) | 1967-03-24 | 1967-03-24 | Talc treatment and talc containing pigments |
Country Status (4)
Country | Link |
---|---|
US (1) | US3533821A (en) |
JP (1) | JPS5240916B1 (en) |
DE (1) | DE1592887A1 (en) |
GB (1) | GB1174460A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3853574A (en) * | 1972-11-15 | 1974-12-10 | T Ferrigno | Processing modified pigmentary compositions |
US3928059A (en) * | 1972-11-15 | 1975-12-23 | Thomas Howard Ferrigno | Hydrous magnesium containing silicate minerals with reduced absorbencies |
US3957527A (en) * | 1974-07-29 | 1976-05-18 | Georgia Kaolin Company | Color developing substrates for manifold copy systems and process for producing the same |
US3965241A (en) * | 1975-06-16 | 1976-06-22 | Cyprus Mines Corporation | Leaching tremolite impurity from talc |
US4075030A (en) * | 1975-06-30 | 1978-02-21 | Yara Engineering Corporation | High bulking clay pigments and methods of making the same |
US4812299A (en) * | 1986-06-17 | 1989-03-14 | J. M. Huber Corporation | Synthetic alkali metal alumino-silicates, methods and uses, compositions and their methods of preparation |
US4978516A (en) * | 1987-10-26 | 1990-12-18 | Asada Mill Co., Ltd. | Process for treating talc |
US5076889A (en) * | 1986-06-17 | 1991-12-31 | J.M. Huber Corporation | Synthetic alkali metal alumino-silicates compositions and their methods of preparation |
US5127995A (en) * | 1986-06-17 | 1992-07-07 | J. M. Huber Corporation | Synthetic alkali metal alumino-silicates and use as fillers in newsprint |
US5219660A (en) * | 1987-06-01 | 1993-06-15 | Wason Satish K | Precipitated encapsulated paper pigments and methods |
US5312485A (en) * | 1988-08-05 | 1994-05-17 | J. M. Huber Corporation | Precipitated encapsulated paper pigments and methods |
US5352287A (en) * | 1988-08-05 | 1994-10-04 | J. M. Huber Corporation | Precipitated encapsulated paper pigments and methods |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0050936A1 (en) * | 1980-10-23 | 1982-05-05 | ENGLISH CLAYS LOVERING POCHIN & COMPANY LIMITED | Improvements in or relating to the preparation of aqueous suspensions of talc |
FR2674515B1 (en) * | 1991-03-29 | 1993-09-03 | Talc Luzenac | TALKY SUBSTANCES HAVING SPECIFIC SURFACE PROPERTIES AND METHODS OF MANUFACTURE. |
CZ2012839A3 (en) * | 2012-11-26 | 2014-07-16 | Vysoké Učení Technické V Brně | Process for preparing and use of delaminated and dehydroxylated talk |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2920974A (en) * | 1957-02-15 | 1960-01-12 | Columbia Southern Chem Corp | Method of preparing a finely-divided alumina-silica pigment |
US2943971A (en) * | 1955-10-31 | 1960-07-05 | Pigmented paper and preparation | |
US3366501A (en) * | 1964-12-10 | 1968-01-30 | Cyprus Mines Corp | Calcined hydrophilic talc pigment |
-
1967
- 1967-03-24 US US625633A patent/US3533821A/en not_active Expired - Lifetime
- 1967-10-24 GB GB48379/67A patent/GB1174460A/en not_active Expired
- 1967-11-10 JP JP42072059A patent/JPS5240916B1/ja active Pending
- 1967-11-15 DE DE19671592887 patent/DE1592887A1/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2943971A (en) * | 1955-10-31 | 1960-07-05 | Pigmented paper and preparation | |
US2920974A (en) * | 1957-02-15 | 1960-01-12 | Columbia Southern Chem Corp | Method of preparing a finely-divided alumina-silica pigment |
US3366501A (en) * | 1964-12-10 | 1968-01-30 | Cyprus Mines Corp | Calcined hydrophilic talc pigment |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3853574A (en) * | 1972-11-15 | 1974-12-10 | T Ferrigno | Processing modified pigmentary compositions |
US3928059A (en) * | 1972-11-15 | 1975-12-23 | Thomas Howard Ferrigno | Hydrous magnesium containing silicate minerals with reduced absorbencies |
US3957527A (en) * | 1974-07-29 | 1976-05-18 | Georgia Kaolin Company | Color developing substrates for manifold copy systems and process for producing the same |
US3965241A (en) * | 1975-06-16 | 1976-06-22 | Cyprus Mines Corporation | Leaching tremolite impurity from talc |
US4075030A (en) * | 1975-06-30 | 1978-02-21 | Yara Engineering Corporation | High bulking clay pigments and methods of making the same |
US4076548A (en) * | 1975-06-30 | 1978-02-28 | Yara Engineering Corporation | High bulking clay pigments and method of making the same |
US4812299A (en) * | 1986-06-17 | 1989-03-14 | J. M. Huber Corporation | Synthetic alkali metal alumino-silicates, methods and uses, compositions and their methods of preparation |
US5076889A (en) * | 1986-06-17 | 1991-12-31 | J.M. Huber Corporation | Synthetic alkali metal alumino-silicates compositions and their methods of preparation |
US5127995A (en) * | 1986-06-17 | 1992-07-07 | J. M. Huber Corporation | Synthetic alkali metal alumino-silicates and use as fillers in newsprint |
US5219660A (en) * | 1987-06-01 | 1993-06-15 | Wason Satish K | Precipitated encapsulated paper pigments and methods |
US4978516A (en) * | 1987-10-26 | 1990-12-18 | Asada Mill Co., Ltd. | Process for treating talc |
US5312485A (en) * | 1988-08-05 | 1994-05-17 | J. M. Huber Corporation | Precipitated encapsulated paper pigments and methods |
US5352287A (en) * | 1988-08-05 | 1994-10-04 | J. M. Huber Corporation | Precipitated encapsulated paper pigments and methods |
Also Published As
Publication number | Publication date |
---|---|
DE1592887A1 (en) | 1971-02-04 |
GB1174460A (en) | 1969-12-17 |
JPS5240916B1 (en) | 1977-10-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3533821A (en) | Talc treatment and talc containing pigments | |
US3702773A (en) | Alkanolamine stabilized high solids titanium dioxide slurry | |
GB1400067A (en) | Tio2 slurries | |
US3556828A (en) | Process for treating titanium dioxide pigments | |
US3446348A (en) | Process for treating clay | |
AU661582B2 (en) | Composite pigmentary material | |
US3876442A (en) | Process of treating titanium dioxide pigment | |
US2357101A (en) | Titanium pigments and process for producing the same | |
US2178383A (en) | Carbon black | |
AU724485B2 (en) | Process of producing zinc sulfide pigments and application thereof | |
US3941603A (en) | TiO2 Pigment for industrial paints based on water reducible systems | |
US2406465A (en) | Titanium oxide pigment production | |
DE666530C (en) | Manufacture of composite pigments | |
US2369246A (en) | Titanium oxide pigment production | |
US2212629A (en) | Method of preparing composite pigments | |
US2266793A (en) | Pigment composition and process of making same | |
US2219129A (en) | Titanium oxide pigment and process for producing same | |
US3459575A (en) | Titanium pigment manufacture | |
US2220952A (en) | Production of improved pigments | |
US3152000A (en) | Method for treating titanium dioxide pigments to obtain high gloss properties | |
US2326157A (en) | Activated anhydrite, process of making the same, and product including it | |
US2361986A (en) | Composite pigments and process of producing same | |
US2226573A (en) | Process of making cadmium red pigment | |
US3656986A (en) | Chrome pigments | |
US2026862A (en) | Preparation of titanium pigments |