US3394759A - Short-term multicycle combustion stimulation of oil wells - Google Patents

Short-term multicycle combustion stimulation of oil wells Download PDF

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US3394759A
US3394759A US508375A US50837565A US3394759A US 3394759 A US3394759 A US 3394759A US 508375 A US508375 A US 508375A US 50837565 A US50837565 A US 50837565A US 3394759 A US3394759 A US 3394759A
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well
production
formation
hydrocarbons
short
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US508375A
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Carey Kenneth Brandon
Richard D Goddard
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ExxonMobil Upstream Research Co
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Exxon Production Research Co
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/243Combustion in situ

Definitions

  • the present invention concerns an improved method of well stimulation. More particularly, the present invention relates to improvements in oil well stimulation by underground or in situ combustion.
  • Well stimulation by in situ combustion refers to a wellknown process in which a portion of the underground hydrocarbons in the reservoir or formation, particularly heavy viscous oils, are burned in place to provide high temperatures and heat and thereby cause a reduction in viscosity of the formation hydrocarbon oil which is adjacent the burned-out interval or which enters the burnedout interval.
  • an oxidizing gas such as air or a mixture of air and oxygen or other gases capable of sustaining combustion of the formation hydrocarbons, is introduced into the subsurface formation through the production wellbore.
  • the combustible mixture in the formation is ignited in any desired manner, as by electric borehole heaters or chemical catalysts, such as phosphorous, triethylborane, or linseed oil.
  • the oxidizing gas is continuously supplied to the formation to maintain combustion of the subsurface hydrocarbons.
  • the amount of oxidizing gas injected may range from 60 to 180 million cubic feet over a period of one to three months. When the desired quantity of heat has been generated by such combustion, injection of the oxidizing gas is discontinued and burning ceases.
  • a bottom hole choke Prior to returning the well to production, a bottom hole choke is installed because of the hazardous combustible gas mixture (20 percent oxygen) initially produced from the formation. Thereafter, the well is immediately returned to production of hydrocarbons through the bottom hole choke. After producing for several weeks or months until the reservoir pressure is no longer capable of sustaining production, a pump and rods are run into the well to initiate artificial lift of the oil production. Then, when production diminishes or ceases and it is desired to again stimulate the well, the aforementioned steps are repeated.
  • the principal costs of operation are (1) preparation of the well for air injection; (2) use of a catalytic or other igniter; (3) compressor operation for 30 to 90 days of air injection; (4) bottom hole choke installation prior to fiowback; and (5) running pump and rods into a well several weeks after burning to initiate artificial lift of the oil production.
  • a primary object of the present invention is to improve in situ operating procedure of the individual well cyclic combustion stimulation process in order to attain (1) production stimulation similar in magnitude to that achieved by a conventional in situ procedure, such as described above; and (2) reduction in operating costs such that the overall operation is profitable.
  • the process of the invention operates as follows.
  • a conventional 30- to -day first cycle burn is initially conducted.
  • the rods and pump are pulled, and air (or other oxidizing gas) injection is commenced.
  • An ignition catalyst may be required in this cycle.
  • the shut-in period is known as the soak period.
  • the hot combustion gases and any unburned oxygen occupying the burned zone migrate up-structure and the burned zone is resaturated with formation oil. Following the soak period, the Well is returned to production.
  • ambient reservoir temperature is sufficient to initiate combustion simply upon resumption of air injection, thereby eliminating the need for a supplemental igniting catalyst.
  • Additional benefits realized from the improved process are easier surface handling and treating of the produced oil and an increased gravity of the produced oil which makes it more valuable. These two benefits result from thermal cracking of the crude hydrocarbons during flow-back through the burned zone, which remains considerably hotter for the short, more frequent burns than for longer, less frequent ones.
  • the process of the invention improves over previous in situ combustion techniques in including shorter and more frequent burn cycles to sustain flowing production from the wells.
  • the burn period may be between four and ten days at an air injection rate of two million cubic feet per day.
  • a short shut-in soak period follows the burn period. The length of the soak period is chosen sufficiently long to allow the burned zone to become resaturated by capillarity and down-structure gravity drainage and to allow the combustion gases to migrate up-structure out of the burned zone.
  • Electrical or chemical ignition elements are eliminated (after the second cycle) because of the high reactivity of the native formation crude oil at the elevated temperatures. Ingition is attained spontaneously upon resumption of air injection.
  • An example of the cyclic operation in accordance with the method of the present invention follows.
  • a method of well stimulation comprising the steps of:
  • shut-in and production periods also being selected such that upon resumption of the injection of said oxidizing gas following termination of production, said formation hydrocarbons remaining in said formation spontaneously ignite;
  • a method of well stimulation comprising the steps of:'
  • shut-in and production periods also being selected such that upon resumption of the injection of said oxidizing gas following termination of production, said formation hydrocarbons remaining in said formation spontaneously ignite;
  • a method as recited in claim 4 in which said injection of said oxidizing gas prior to the shutting-in of said well is continued for about seven days at an injection rate of about 2.0 million cubic feet per day.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

United States Patent 3,394,759 SHORT-TERM MULTICYCLE COMBUSTION STIMULATION OF OIL WELLS Kenneth Brandon Carey and Richard D. Goddard, Bakersfield, Califi, assignors to Esso Production Research Company No Drawing. Filed Nov. 17, 1965, Ser. No. 508,375 6 Claims. (Cl. 16639) ABSTRACT OF THE DISCLOSURE A method of stimulating an oil-containing formation surrounding a well by a multicycle in situ combustion technique in which in each cycle a short period of burn is followed by a short shut-in soak period. During the soak period the hot combustion gases and any unburned oxygen occupying the burned zone migrate ups-tructure and the burned zone is resaturated with formation oil. The well is returned to production. Air injection is resumed while the reservoir temperature is sufiiciently high to ignite spontaneously the reservoir oil, and then the cycle is repeated.
The present invention concerns an improved method of well stimulation. More particularly, the present invention relates to improvements in oil well stimulation by underground or in situ combustion.
Well stimulation by in situ combustion refers to a wellknown process in which a portion of the underground hydrocarbons in the reservoir or formation, particularly heavy viscous oils, are burned in place to provide high temperatures and heat and thereby cause a reduction in viscosity of the formation hydrocarbon oil which is adjacent the burned-out interval or which enters the burnedout interval. In such a process an oxidizing gas, such as air or a mixture of air and oxygen or other gases capable of sustaining combustion of the formation hydrocarbons, is introduced into the subsurface formation through the production wellbore. The combustible mixture in the formation is ignited in any desired manner, as by electric borehole heaters or chemical catalysts, such as phosphorous, triethylborane, or linseed oil. The oxidizing gas is continuously supplied to the formation to maintain combustion of the subsurface hydrocarbons. The amount of oxidizing gas injected may range from 60 to 180 million cubic feet over a period of one to three months. When the desired quantity of heat has been generated by such combustion, injection of the oxidizing gas is discontinued and burning ceases.
Prior to returning the well to production, a bottom hole choke is installed because of the hazardous combustible gas mixture (20 percent oxygen) initially produced from the formation. Thereafter, the well is immediately returned to production of hydrocarbons through the bottom hole choke. After producing for several weeks or months until the reservoir pressure is no longer capable of sustaining production, a pump and rods are run into the well to initiate artificial lift of the oil production. Then, when production diminishes or ceases and it is desired to again stimulate the well, the aforementioned steps are repeated.
Although this conventional process successfully stimulates oil production, it has several limitations, the foremost of which is high operating costs. The principal costs of operation are (1) preparation of the well for air injection; (2) use of a catalytic or other igniter; (3) compressor operation for 30 to 90 days of air injection; (4) bottom hole choke installation prior to fiowback; and (5) running pump and rods into a well several weeks after burning to initiate artificial lift of the oil production.
3,394,759 Patented July 30, 1968 "ice A primary object of the present invention is to improve in situ operating procedure of the individual well cyclic combustion stimulation process in order to attain (1) production stimulation similar in magnitude to that achieved by a conventional in situ procedure, such as described above; and (2) reduction in operating costs such that the overall operation is profitable.
The process of the invention operates as follows. A conventional 30- to -day first cycle burn is initially conducted. In preparing the well for a second cycle burn, the rods and pump are pulled, and air (or other oxidizing gas) injection is commenced. An ignition catalyst may be required in this cycle. After injecting about 14 million cubic feet of air into the well (e.g., seven days at 2.0M c.f./d.), the well is shut-in for another seven days. The shut-in period is known as the soak period. During this time, the hot combustion gases and any unburned oxygen occupying the burned zone migrate up-structure and the burned zone is resaturated with formation oil. Following the soak period, the Well is returned to production. It is produced for several Weeks or months until reservoir energy no longer sustains flowing production and while the reservoir temperature is sufficiently high to spontaneously ignite upon resumption of air injection. Then, air injection is resumed and the entire cycle is repeated. Preferably, about eight wells are operated in series, thereby making each complete individual well cycle of two-month duration.
Numerous advantages which result from the improved process include:
(1) Little well preparation is needed for the first short cycle burn and none is required for subsequent cycle burns.
(2) Following the first short cycle burn, ambient reservoir temperature is sufficient to initiate combustion simply upon resumption of air injection, thereby eliminating the need for a supplemental igniting catalyst.
(3) Significantly less air injection is required per cycle to achieve stimulation similar to that which results from the longer cycle conventional operation. The heat and pressure previously dissipated when hot combustion gases and unburned oxygen were produced immediately following termination of air injection are conserved in the reservoir when these gases migrate up-structure during the short (seven-day) soak period which follows air injection. This feature of the process tends to provide greater and more lasting production stimulation of the well.
(4) The producing hazard created by initial production of a combustible gas mixture containing hot hydrocarbons and about 20 percent oxygen, previously counteracted by running and producing through a bottom hole choke, is eliminated. Since in the improved process initial production consists of mostly liquid and since the small amount of gas produced contains less than one percent oxygen, there is no need for the installation of a bottom hole choke during the early phases of fiowback.
(5) Since all production under the improved process is flowing production, the work and expense of running pumps and rods to place a well on artificial lift have been eliminated.
Additional benefits realized from the improved process are easier surface handling and treating of the produced oil and an increased gravity of the produced oil which makes it more valuable. These two benefits result from thermal cracking of the crude hydrocarbons during flow-back through the burned zone, which remains considerably hotter for the short, more frequent burns than for longer, less frequent ones.
Thus, the process of the invention improves over previous in situ combustion techniques in including shorter and more frequent burn cycles to sustain flowing production from the wells. Preferably, the burn period may be between four and ten days at an air injection rate of two million cubic feet per day. A short shut-in soak period follows the burn period. The length of the soak period is chosen sufficiently long to allow the burned zone to become resaturated by capillarity and down-structure gravity drainage and to allow the combustion gases to migrate up-structure out of the burned zone. Electrical or chemical ignition elements are eliminated (after the second cycle) because of the high reactivity of the native formation crude oil at the elevated temperatures. Ingition is attained spontaneously upon resumption of air injection. An example of the cyclic operation in accordance with the method of the present invention follows.
Well A was flowing and production was low. No work had been done on Well A since it had been burned previously. Well A was shut-in, the production line disconnected and the injection line connected. No igniter Was necessary because the producing period since the previous cycle was short enough so that the formation temperature was still sufliciently hot to ignite the formation crude oil spontaneously. Air was injected for seven days at a rate of 2 million cubic feet per day. At the end of this period, air injection was switched to Well B and a soda ash solution was pumped into Well A for corrosion control. Well A was then shut-in for seven days to soak, allowing the combustion gases to migrate up-structure and the burned zone to resaturate with hydrocarbons. Then Well B was shut-in and Well A was opened for production. No bottom hole choke was run and liquid production was obtained within two hours. Oxygen content of the produced gas was below 1 percent in eight hours. Oil gravity was around 30 API, as compared to the normal 18.
Having fully described the method, operation, objectives and advantages of our invention, we claim:
1. A method of well stimulation comprising the steps of:
igniting formation hydrocarbons contained in a subsurface formation surrounding a production well;
injecting an oxidizing gas into said formation through said well and burning a portion of the resident reservoir hydrocarbons to raise the temperature of the reservoir rock remote from the wellbore; halting injection of said oxidizing gas; shutting-in said Well for a period of time sufficiently long to allow the burned zone to become resaturated by capillarity and down-structure gravity drainage and to allow the combustion gases to migrate out of the burned zone; producing said formation hydrocarbons through said production well so long as reservoir energy sustains flowing production essentially in the liquid phase;
the length of said shut-in and production periods also being selected such that upon resumption of the injection of said oxidizing gas following termination of production, said formation hydrocarbons remaining in said formation spontaneously ignite; and
then repeating the above steps of injecting oxidizing gas, shutting-in said well and producing formation hydrocarbons.
2. A method as recited in claim 1 in which said oxidizing gas is injected into said subsurface formation for from about four to ten days at a rate of about 2.0 million cubic feet per day in each cycle.
3. A method of well stimulation as recited in claim 1 in which prior to the first cycle recited therein, the following steps are carried out:
igniting said formation hydrocarbons and injecting oxidizing gas and burning a portion of said resident formation hydrocarbons to raise the temperature of the reservoir rock remote from the wellbore, thereby reducing the viscosity of the remaining reservoir hydrocarbons;
halting injection of said oxidizing gas;
installing a bottom hole choke in said well;
producing said formation hydrocarbons through said production well until reservoir energy no longer sustains flowing production;
running a pump and rods into said well and artificially lifting oil production;
halting artificial lifting of production; and
removing said pump and rods from said well.
4. A method of well stimulation comprising the steps of:'
igniting formation hydrocarbons contained in a subsurface formation surrounding a production well and injecting oxidizing gas into said formation through said well and burning a portion of said resident formation hydrocarbons to raise the temperature of the reservoir rock remote from the wellbore, thereby reducing the viscosity of the remaining hydrocarbons;
halting injection of said oxidizing gas;
installing a bottom hole choke in said well;
producing said formation hydrocarbons through said production well until reservoir energy no longer sustains flowing production;
running a pump and rods into said well and artificially lifting oil product-ion;
halting artificial lifting of production;
removing said pump and rods from said well;
igniting said formation hydrocarbons;
injecting an oxidizing gas into said formation through said well and burning a portion of the resident hydrocarbons to raise the temperature of the reservoir rock remote from the wellbore;
halting injection of said oxidizing gas;
shutting-in said well for a period of time sufficiently long to allow the burned zone to become resaturated by capillarity and down-structure gravity drainage and to allow the combustion gases to migrate out of the burned zone;
producing said formation hydrocarbons through said production well so long as reservoir energy sustains flowing production;
the length of said shut-in and production periods also being selected such that upon resumption of the injection of said oxidizing gas following termination of production, said formation hydrocarbons remaining in said formation spontaneously ignite; and
then repeating the above steps of injecting oxidizing gas, shutting-in said well and producing formation hydrocarbons.
5. A method as recited in claim 4 in which said injection of said oxidizing gas prior to the shutting-in of said well is continued for about seven days at an injection rate of about 2.0 million cubic feet per day.
6. A method as recited in claim 5 in which said formation hydrocarbons produce-d following said shut-in period are produced essentially in the liquid state.
References Cited UNITED STATES PATENTS 3,332,482 7/1967 Trantham 1662 3,333,637 8/1967 Prats 166-2 X 3,129,757 4/1964 Sharp 166-11 3,139,928 7/1964 Broussard 1662 3,172,472 3/1965 Smith 16638 3,179,169 4/1965 Cline et a1. 166-38 3,180,412 4/1965 Bednarski et al. 166--11 3,259,186 7/1966 Dietz 16611 3,266,569 8/1966 Sterrett 166-2 3,285,336 11/1966 Gardner 166-11 STEPHEN J. NOVOSAD, Primary Examiner.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3490531A (en) * 1968-05-27 1970-01-20 Phillips Petroleum Co Thermal oil stimulation process
US3554285A (en) * 1968-10-24 1971-01-12 Phillips Petroleum Co Production and upgrading of heavy viscous oils
US5211230A (en) * 1992-02-21 1993-05-18 Mobil Oil Corporation Method for enhanced oil recovery through a horizontal production well in a subsurface formation by in-situ combustion

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3129757A (en) * 1960-05-13 1964-04-21 Socony Mobil Oil Co Inc Miscible fluid displacement method of producing an oil reservoir
US3139928A (en) * 1960-05-24 1964-07-07 Shell Oil Co Thermal process for in situ decomposition of oil shale
US3172472A (en) * 1960-09-22 1965-03-09 Gulf Research Development Co Ignition of fuels below the surface of the ground
US3179169A (en) * 1960-10-20 1965-04-20 Continental Oil Co Method for initiating in situ combustion with pyrophoric materials
US3180412A (en) * 1962-08-07 1965-04-27 Texaco Inc Initiation of in situ combustion in a secondary recovery operation for petroleum production
US3259186A (en) * 1963-08-05 1966-07-05 Shell Oil Co Secondary recovery process
US3266569A (en) * 1962-09-14 1966-08-16 Marathon Oil Co Recovery of viscous unsaturated crude by intermittent gas injection
US3285336A (en) * 1964-09-15 1966-11-15 Gulf Research Development Co Method of thermal stimulation of oil fields
US3332482A (en) * 1964-11-02 1967-07-25 Phillips Petroleum Co Huff and puff fire flood process
US3333637A (en) * 1964-12-28 1967-08-01 Shell Oil Co Petroleum recovery by gas-cock thermal backflow

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3129757A (en) * 1960-05-13 1964-04-21 Socony Mobil Oil Co Inc Miscible fluid displacement method of producing an oil reservoir
US3139928A (en) * 1960-05-24 1964-07-07 Shell Oil Co Thermal process for in situ decomposition of oil shale
US3172472A (en) * 1960-09-22 1965-03-09 Gulf Research Development Co Ignition of fuels below the surface of the ground
US3179169A (en) * 1960-10-20 1965-04-20 Continental Oil Co Method for initiating in situ combustion with pyrophoric materials
US3180412A (en) * 1962-08-07 1965-04-27 Texaco Inc Initiation of in situ combustion in a secondary recovery operation for petroleum production
US3266569A (en) * 1962-09-14 1966-08-16 Marathon Oil Co Recovery of viscous unsaturated crude by intermittent gas injection
US3259186A (en) * 1963-08-05 1966-07-05 Shell Oil Co Secondary recovery process
US3285336A (en) * 1964-09-15 1966-11-15 Gulf Research Development Co Method of thermal stimulation of oil fields
US3332482A (en) * 1964-11-02 1967-07-25 Phillips Petroleum Co Huff and puff fire flood process
US3333637A (en) * 1964-12-28 1967-08-01 Shell Oil Co Petroleum recovery by gas-cock thermal backflow

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3490531A (en) * 1968-05-27 1970-01-20 Phillips Petroleum Co Thermal oil stimulation process
US3554285A (en) * 1968-10-24 1971-01-12 Phillips Petroleum Co Production and upgrading of heavy viscous oils
US5211230A (en) * 1992-02-21 1993-05-18 Mobil Oil Corporation Method for enhanced oil recovery through a horizontal production well in a subsurface formation by in-situ combustion

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