US3325242A - Process for dyeing and printing with reactive dyestuffs - Google Patents
Process for dyeing and printing with reactive dyestuffs Download PDFInfo
- Publication number
- US3325242A US3325242A US3325242DA US3325242A US 3325242 A US3325242 A US 3325242A US 3325242D A US3325242D A US 3325242DA US 3325242 A US3325242 A US 3325242A
- Authority
- US
- United States
- Prior art keywords
- parts
- reactive
- dimethylhydrazine
- dyeing
- dyestuff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 62
- 238000004043 dyeing Methods 0.000 title description 114
- 238000007639 printing Methods 0.000 title description 52
- 239000000975 dye Substances 0.000 claims description 120
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 106
- -1 HYDRAZINE COMPOUND Chemical class 0.000 claims description 90
- 239000002657 fibrous material Substances 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 38
- 229910052757 nitrogen Inorganic materials 0.000 claims description 38
- QJGQUHMNIGDVPM-UHFFFAOYSA-N CTK2H8874 Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 32
- 229920002678 cellulose Polymers 0.000 claims description 30
- 239000001913 cellulose Substances 0.000 claims description 30
- 238000002360 preparation method Methods 0.000 claims description 30
- 238000004040 coloring Methods 0.000 claims description 28
- 150000002829 nitrogen Chemical group 0.000 claims 4
- 239000004744 fabric Substances 0.000 description 132
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 132
- 239000000243 solution Substances 0.000 description 120
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 72
- 229920000742 Cotton Polymers 0.000 description 66
- 241000219146 Gossypium Species 0.000 description 66
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 58
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 44
- 125000001309 chloro group Chemical group Cl* 0.000 description 36
- 125000004433 nitrogen atoms Chemical group N* 0.000 description 36
- 229910052801 chlorine Inorganic materials 0.000 description 34
- 125000005843 halogen group Chemical group 0.000 description 30
- 239000011780 sodium chloride Substances 0.000 description 30
- 239000004202 carbamide Substances 0.000 description 22
- 239000000543 intermediate Substances 0.000 description 22
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 22
- 150000002429 hydrazines Chemical class 0.000 description 20
- 238000005406 washing Methods 0.000 description 20
- 238000009835 boiling Methods 0.000 description 18
- 238000001035 drying Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 239000004615 ingredient Substances 0.000 description 16
- 230000001808 coupling Effects 0.000 description 14
- 238000010168 coupling process Methods 0.000 description 14
- 238000005859 coupling reaction Methods 0.000 description 14
- 238000010020 roller printing Methods 0.000 description 14
- RHUYHJGZWVXEHW-UHFFFAOYSA-N 1,1-dimethyhydrazine Chemical compound CN(C)N RHUYHJGZWVXEHW-UHFFFAOYSA-N 0.000 description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 12
- 229920000297 Rayon Polymers 0.000 description 12
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 12
- 239000001488 sodium phosphate Substances 0.000 description 12
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 12
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 12
- 235000019801 trisodium phosphate Nutrition 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 10
- 125000004432 carbon atoms Chemical group C* 0.000 description 10
- 230000003197 catalytic Effects 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000002964 rayon Substances 0.000 description 10
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000001187 sodium carbonate Substances 0.000 description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 125000001424 substituent group Chemical group 0.000 description 10
- 229940005550 Sodium alginate Drugs 0.000 description 8
- JNIGYQOBELCEIZ-MAKDUZDQSA-L barium(2+);5-chloro-4-methyl-2-[(2Z)-2-(2-oxonaphthalen-1-ylidene)hydrazinyl]benzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N\N=C/2C3=CC=CC=C3C=CC\2=O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N\N=C/2C3=CC=CC=C3C=CC\2=O)=C1S([O-])(=O)=O JNIGYQOBELCEIZ-MAKDUZDQSA-L 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- MSXHSNHNTORCAW-UHFFFAOYSA-M sodium 3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].OC1OC(C([O-])=O)C(O)C(O)C1O MSXHSNHNTORCAW-UHFFFAOYSA-M 0.000 description 8
- 239000000661 sodium alginate Substances 0.000 description 8
- 235000010413 sodium alginate Nutrition 0.000 description 8
- 239000010981 turquoise Substances 0.000 description 8
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 150000008049 diazo compounds Chemical class 0.000 description 6
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000001184 potassium carbonate Substances 0.000 description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- RBTKNAXYKSUFRK-UHFFFAOYSA-N Heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N Phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 4
- JVBXVOWTABLYPX-UHFFFAOYSA-L Sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 4
- GRVFOGOEDUUMBP-UHFFFAOYSA-N Sodium sulfide Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L Sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 239000000370 acceptor Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 125000004429 atoms Chemical group 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 229940037395 electrolytes Drugs 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- ZBKFYXZXZJPWNQ-UHFFFAOYSA-N isothiocyanate group Chemical group [N-]=C=S ZBKFYXZXZJPWNQ-UHFFFAOYSA-N 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 150000007522 mineralic acids Chemical class 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229910052979 sodium sulfide Inorganic materials 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- YIFRANFPHCPHBU-UHFFFAOYSA-N 1,3-diamino-9,10-dioxoanthracene-2-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(N)C(S(O)(=O)=O)=C2N YIFRANFPHCPHBU-UHFFFAOYSA-N 0.000 description 2
- FQDIANVAWVHZIR-OWOJBTEDSA-N 1,4-Dichlorobut-2-ene Chemical compound ClC\C=C\CCl FQDIANVAWVHZIR-OWOJBTEDSA-N 0.000 description 2
- SPSSDDOTEZKOOV-UHFFFAOYSA-N 2,3-dichloroquinoxaline Chemical compound C1=CC=C2N=C(Cl)C(Cl)=NC2=C1 SPSSDDOTEZKOOV-UHFFFAOYSA-N 0.000 description 2
- CZPWVGJYEJSRLH-UHFFFAOYSA-N 289-95-2 Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2H-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 2
- GBAOOJAWDCNOGO-UHFFFAOYSA-N 3,4,5-trichloropyridazine Chemical compound ClC1=CN=NC(Cl)=C1Cl GBAOOJAWDCNOGO-UHFFFAOYSA-N 0.000 description 2
- NZEDMAWEJPYWCD-UHFFFAOYSA-N 3-prop-2-enylsulfonylprop-1-ene Chemical compound C=CCS(=O)(=O)CC=C NZEDMAWEJPYWCD-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M Benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N Chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- OBRHSNVZWZEQIU-UHFFFAOYSA-N ClC(CC[NH-])Cl Chemical compound ClC(CC[NH-])Cl OBRHSNVZWZEQIU-UHFFFAOYSA-N 0.000 description 2
- PCUABNXBLPTXDV-UHFFFAOYSA-N ClC=CC(=O)NC(=CS(=O)(=O)C=C(NC(=O)C=CCl)NC(=O)C=C)NC(=O)C=C Chemical group ClC=CC(=O)NC(=CS(=O)(=O)C=C(NC(=O)C=CCl)NC(=O)C=C)NC(=O)C=C PCUABNXBLPTXDV-UHFFFAOYSA-N 0.000 description 2
- UBJVUCKUDDKUJF-UHFFFAOYSA-N Diallyl sulfide Chemical compound C=CCSCC=C UBJVUCKUDDKUJF-UHFFFAOYSA-N 0.000 description 2
- 229940093912 Gynecological Sulfonamides Drugs 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920002456 HOTAIR Polymers 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 2
- LVIYYTJTOKJJOC-UHFFFAOYSA-N Nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N Octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- PBMFSQRYOILNGV-UHFFFAOYSA-N Pyridazine Chemical group C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 2
- 229910006069 SO3H Inorganic materials 0.000 description 2
- 240000004203 Syringa vulgaris Species 0.000 description 2
- 235000004338 Syringa vulgaris Nutrition 0.000 description 2
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 2
- FYOWZTWVYZOZSI-UHFFFAOYSA-N Thiourea dioxide Chemical compound NC(=N)S(O)=O FYOWZTWVYZOZSI-UHFFFAOYSA-N 0.000 description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N Triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N Xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- LONQTZORWVBHMK-UHFFFAOYSA-N [N].NN Chemical group [N].NN LONQTZORWVBHMK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating Effects 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229940008075 allyl sulfide Drugs 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 229940027983 antiseptics and disinfectants Quaternary ammonium compounds Drugs 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000001246 bromo group Chemical group Br* 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- TUCNEACPLKLKNU-UHFFFAOYSA-N ethanone Chemical compound C[C]=O TUCNEACPLKLKNU-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229940079867 intestinal antiinfectives Sulfonamides Drugs 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229940005938 ophthalmologic antiinfectives Sulfonamides Drugs 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- UFUASNAHBMBJIX-UHFFFAOYSA-N propan-1-one Chemical compound CC[C]=O UFUASNAHBMBJIX-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- HCJTYESURSHXNB-UHFFFAOYSA-N propynamide Chemical compound NC(=O)C#C HCJTYESURSHXNB-UHFFFAOYSA-N 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000012048 reactive intermediate Substances 0.000 description 2
- 239000003638 reducing agent Substances 0.000 description 2
- 239000004627 regenerated cellulose Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 229960001663 sulfanilamide Drugs 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 125000000565 sulfonamide group Chemical group 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 229960001367 tartaric acid Drugs 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- 229940026752 topical Sulfonamides Drugs 0.000 description 2
- IVNZBWNBYXERPK-DZGBHZPSSA-K trisodium;(8Z)-7-oxo-8-[(4-sulfonatonaphthalen-1-yl)hydrazinylidene]naphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N\N=C3/C(=O)C=CC=4C=C(C=C(C=43)S([O-])(=O)=O)S(=O)(=O)[O-])=CC=C(S([O-])(=O)=O)C2=C1 IVNZBWNBYXERPK-DZGBHZPSSA-K 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S534/00—Organic compounds -- part of the class 532-570 series
- Y10S534/01—Mixtures of azo compounds
Definitions
- the present invention provides a process for dyeing or printing fibrous materials with the aid of reactive dyestuffs or reactive dyestuif intermediates.
- reactive dyestuifs describes dyestuffs that enter a covalent bond with the material to be dyed in the course of the dyeing or printing process, and as a rule this is accompanied by elimination of the reactive substituent of the dyestuif.
- the speed at which the bond between the dyestutt and the substratum is formed depends, on one hand, on the dyeing conditions-such as temperature, pH value of the dyebath or the printing pasteand, on the other, on the reactivity of the reactive grouping of the dyestuif.
- the present invention provides a process for increasing the reactivity of reactive dyestuff compounds viz. reactive dyestuffs proper or reactive dyestuif intermediates, wherein there is used a hydrazine containing at least one tertiary nitrogen atom or a water-soluble salt thereof.
- one of the two nitrogen atoms of such a hydrazine grouping must be bound to two carbon atoms, while the other nitrogen atom may be substituted or unsubstituted.
- suitable cyclic hydrazine compounds more especially those in which one of the two hydrazine nitrogen atoms, or both, is or are members of one or several rings.
- a hydrazine or hydrazine salt that is soluble in the dyebath or in the printing paste, and it may contain, in addition to one or more than one hydrazine group, substituents that do not react with the reactive dyestuffs, for example halogen atoms, nitro, alkoxy or hydroxyl groups, but preference is given to such hydrazines as contain, in addition to at least one N--N group, only carbon and hydrogen atoms, for example a hydrazine that is substituted exclusively by non-aromatic hydrocarbon radicals and contains at least one tertiary nitrogen atom.
- Such hyd-razines may correspond, for example, to the formula R1 Ra immed States Patent M Patented June 13, 1967 in which m and neach is a whole number not greater than 4, preferably 1, and p is a whole number not greater than 5.
- the aliphatic hydrocarbon radicals in these hydrazine compounds may be branched, but they are preferably unbranched.
- NNHO-SH 3 or the hydrazine salt NNH-i 3SH- ⁇ N--NH1 H3O H3C/ sired may be used for the reaction instead of the free bases-may be derived, for example, from the conven-' tional inorganic or organic acids, for example from sulfuric, hydrochloric, phosphoric, acetic, formic, propionic, chloracetic, oxalic or tartaric acid.
- reactive dyestuffs there are advantageously used in the present process those of the water-soluble variety, for example organic dyestuffs from diazo or coupling components containing carboxyl groups, sulfonic acid groups or aliphatically bound sulfuric acid ester groups.
- epoxide groups ethylene imino groups, isocyanate groups, isothiocyanate groups, carbamic acid aryl ester groups, the propiolic acid amide grouping, monoand dichlorotcrotonylamino, chloroacrylamino, acrylamino, vinylsulfone groups and primarily groupings containing a labile substituent and which are easy to split with entrainment of the bond election pair, for example sulfohalide groups, aliphatically lbound sulfuric acid ester groups and aliphatically bound sulfonyloxy groups and halogen atoms, more especially an aliphatically bound chlorine atom.
- labile substituents are advantageously in position '7 or B of an aliphatic radical which is bound to the dyestuff molecule directly or through an amino, s-ulfone or sulfonamide group; in those relevant dyestuffs in which the labile substituents are halogen atoms, those mobile halogen atoms may also be present in an aliphatic acyl radical, for example in an acetyl radical, or in position B or in positions a and ,8 of a propionyl radical or preferably in a heterocyclic radical, for example in a pyrimidine or pyridazine ring, or above all in a triazine ring.
- the dyestuffs contain with advantage a grouping of the formula G imalogen -XC C- alogen ni r C ilalogen in which X represents a nitrogen bridge and Z a hydrogen atom, a possibly substituted amino group, an etherified hydroxyl or mercapto group or a halogen atom or an alkyl, aryl or aralkyl group, and A stands for a hydrogen atom or a halogen atom.
- the halogen atoms are, for example, bromine atoms or preferably chlorine atoms.
- dyestuffs containing dip'henoxytriazine groupings and those which contain a grouping of the formula NHC C-S-Y il C in in which X stands for and Y stands for a group in which R represents an ortho-arylene radical.
- Suitable reactive groupings are the following radicals: Trichloropyridazine, dichloroquinoxaline, dichlorobutene, halogenated pyridazone, sulfonic acid dichloropropylamide, allylsulfone, allylsulfide, 2-halogenbenzthiazolecarbamide, isothiocyanate and li-sulfatopropionic acid amide radicals.
- the present process may be performed with a wide variety of organic dyestuffs, for example oxazine, triphenylmethane, xanthene, nitro, accridone, azo, anthraquinone and phthalocyanine dyestuffs.
- organic dyestuffs for example oxazine, triphenylmethane, xanthene, nitro, accridone, azo, anthraquinone and phthalocyanine dyestuffs.
- azo dyestuff series there may be mentioned, for example, disazo and trisazo dyestuffs, and more especially monoazo dyestuffs.
- disazo and trisazo dyestuffs and more especially monoazo dyestuffs.
- monoazo dyestuffs A large number of such active azo dyestuffs is already known so that there is no need to deal with them in greater detail here.
- anthraquinone dyestuffs there may be mentioned primarily the l-amino-4-bromanthraquinone-Z-sulfonic acid and the dyestuffs derived from 1:4 diaminoanthraquinone 2 sulfonic acid. These and other anthraquinone dyestuffs are manufactured in known manner.
- a suitable phthalocyanine dyestuffs there may be mentioned above all dyestuffs which are derived from nickel or copper phthalocyanine sulfonamides and contain at least two free sulfonic acid groups per molecule and which contain at least in one sulfonamide radical a group with at least one labile halogen atom.
- the present process may also be performed with vat dyestuffs that are water-soluble or insoluble in the oxidized form and dispersion dyestuffs having the characteristics of reactive dyestuffs.
- the fibrous material is dyed or printed with a preparation manufactured from a reactive dyestuff and a hydrazine containing at least one tertiary nitrogen atom;
- reaction products of reactive dyestuffs with hydrazines containing at least one tertiary nitrogen atom they are accessible, for example, by treating the substituted hydrazine with the reactive dyestuff in an aqueous medium at room temperature or at a slightly higher temperature. If desired, these products may be isolated, for example salted out.
- catalytic ratio describes a ratio which is substantially smaller than the ratio referred to under (a).
- the amount of hydrazine compound referred to the reactive dyestuif may, however, vary Within certain limits and depends on the reactivity of the hydrazine used. Referred to the amount of dyestuff the catalytic amount of hydrazine compound may vary from about 0.1 to and preferably from about 0.2 to 2% by weight.
- the reactive dyestuff and the hydrazine are applied in any desired order of succession to the fibrous material, if desired with the use of intermediate drying.
- the present process is suitable for dyeing or printing a wide variety of fibrous materials such as paper or leather or above all textile materials, for example those made from animal fibers such as silk, and above all those from cellulose fibers, including both native cellulose fibers such as linen or cotton and fibers from regenerated cellulose such as rayon (viscose) or rayon staple.
- dyeing and printing are carried out under the conditions convention-ally used for reactive dyestuffs, more especially also when a catalytic proportion of the hydrazine compound is used.
- concomitantly inorganic acid acceptors such as carbonates, hydroxides, bicarbonates or phosphates of alkali metals, or mixtures thereof.
- bases such as trimethyl benzyl ammonium hydroxide or sodium trichloracetate.
- reactive vat dyestuffs the process may be performed in the presence of a conventional reducing agent such as sodium hydrosulfite, thiourea dioxide, sodium sulfide or sodium sulfoxylate.
- the conventional additives such as elec trolytes, forexample sodium chloride, sodium acetate, or non-electrolytes such as urea or thickeners, such as alginates.
- the conventional additives such as meta-nitrobenzenesulfonic acid.
- the hydrazine is added to the dyebath or to the printing paste. If dyeing is carried out as a two-stage process-the application of the dyestufi and the fixation with the acid acceptor being performed separately--it is possible to add the hydrazine only in the second stage of the process.
- the fibrous materials are dyed or printed under the conditions conventionally used for reactive dyestuffs.
- the present process allows the reaction times and/or the reaction temperature to be reduced and/or dyeings and prints of greater tinctori-al strength to be produced, for example by the cold pad batch method, by the pad-steam or pad-dry method, by the wet-pad steam process and more especially by the exhaustion method and in printing.
- the dyestuffs may 'be fixed at widely dif- Example 1 A solution of 30 parts of the dyestulf of the formula SOaH Cl 5 SOzH SOaH II I if in 800 parts of boiling water is cooled to 20 C.
- a cotton fabric is padded with the above solution to a weight increase of 75%, immediately reeled up and left to itself in this state for 6 to 12 hours at 20 C., after which the untfixed portion of the dyestuff is removed by a thorough rinse in cold and in boiling water and finally soaped in the usual manner.
- the resulting blue dyeing displays good fastness to light and washing and is substantially more intense than a comparable dyeing produced without addition of N :N-dirnethylhydrazine.
- Example 2 A cotton fabric is impregnated at 50 solution which contains per 1000 parts of the dyestuif of the formula C. with a padding of water 25 parts
- the resulting brilliant red dyeing is distinctly of greater tinctorial strength than a comparable dyeing produced without NzN-dimethylhydrazine.
- the results achieved are equally good when instead of 0.05 to 0.2 part 2 parts of dimethylhydrazine are used. It is also possible to quaternate 3 of the 25 parts of dyestulf used with 0.2 part of N:N-dimethylhydrazine and to add this product together with the remaining 22 parts of unquaternated dyestuff to the padding solution. When the 0.05 to 0.2. part of NzN- dimethylhydrazine is then omitted from the dyebath, all remaining conditions being identical, a similar, good dyeing is obtained.
- Example 3 A solution of 1.5 parts of the dyestuff of the formula l SOaH l l Cu 0 HN-C C-I-IN I I N N N HOsS S0311 dimethylhydrazine. Fixing takes 1 /2 hours at 40 C.
- dyed yarn is thoroughly rinsed in cold and in hot water and finally soaped at the boil.
- a brilliant violet dyeing is obtained which possesses good fastness properties and is of considerably greater tinctorial strength than a comparable dyeing produced in the absence of NzN-dimethylhydrazine.
- Example 4 A mixture of 30 parts of the dyestuff mentioned in Example 2 and 50 parts of urea is dissolved in 700 parts of boiling water. This solution is cooled to 40 C., 20 parts of sodium carbonate and 0.2 part of NzN-dimethylhydrazine are added, and the solution is made up with cold water to 1000 parts.
- a cotton fabric is padded with the above solution to a weight increase of 75% and then steamed directly, that is to say Without being intermediately dried, for 1 minute.
- the steamed fabric is rinsed and soapedin the usual manner.
- the resulting brilliant red dyeing has very good fastness to light and washing.
- Example 5 A mixture of 20 parts of the dyestuff of the formula and 40 parts of urea is dissolved in 600 parts of boiling water. The solution is cooled to 40 C., 20 parts of soclium carbonate and 0.2 part of NzN-dimethylhydrazine are added, and the whole is made up with cold water to 1000 parts.
- a cotton fabric is padded with this solution to a weight increase of 70%.
- the fabric is then reeled up and kept for 1 hour in a pad-roll installation at a temperature of C. measured with a wet-bulb thermometer then thoroughly rinsed in cold and in hot water and soaped at the boil.
- the resulting deep orange dyeing has very good fastness to light and washing and greater tinctorial strength than a comparable dyeing produced without addition of N N-dimethylhydrazine.
- Example 6 A solution of 3 parts of the dyestuif of Example 1 in parts of water is used to impregnate a cotton fabric to a weight increase of 70%. After an intermediate drying the fabric is impregnated with a solution of 250 parts of sodium chloride, 6 parts of sodium hydroxide 100% and 1 part of NzN-dimethylhydrazine in 900 parts of water, to achieve a weight increase of 80%. Immediately thereafter the fabric is steamed for 30 seconds with steam heated at 103 to C., then thoroughly rinsed in cold and in hot water, washed for 5 minutes at the boil with addition of soap and then dried.
- the resulting brilliant blue dyeing has very good fastness to light and washing.
- a comparably produced dyeing without addition of NzN-dimethylhydrazine is substantially weaker.
- Example 7 A mixture of 40 parts of the 1:2-chromium complex of the dyestuff of the formula and 200 parts of urea is dissolved in 870 parts of hot water and the solution is cooled to room temperature, and 20 parts of sodium carbonate and 1 part of N:N-dimethylhydrazine are then stirred into the solution. This solution is used to impregnate a mercerized cotton fabric to a weight increase of 70%. The fabric is then dried in a current of hot air to a residual moisture content of 8%, then thoroughly rinsed in cold and in boiling Water, and dried.
- the resulting covered greenish blue dyeing has very good wet fastness properties.
- a cotton fabric is printed withthis printing paste on a roller printing machine, then dried and steamed for 3 minutes at 100 C. in a Mather-Platt ager.
- the fixed print is rinsed in cold and in hot water and dried.
- the .resulting print is of equal tinctorial strength to that obtained by fixing for 8 minutes without addition of N:N- dimethylhydrazine.
- a printing paste is prepared from the following ingredients:
- Example 10 A printing paste is prepared from the following ingredients:
- the resulting turquoise print has substantially greater 10 tinctorial strength than when fixed for 8 minutes without addition of NzN-dimethylhydrazine.
- the dyestuff used in this example corresponds to the formula where Cu-Pc represents the copper phthalocyanine residue.
- Example 11 A cellulose fabric is padded at 20 to 30 C. with a solution containing per 1000 parts of water 10 parts of sodium hydroxide solution of 30% strength, 20 parts of the dyestuff ofthe formula l r ll 0 and 0.1 part of N:N-dimethylhydrazine. The fabric is then reeled up, wrapped in a plastic film, stored for 6 hours, then rinsed, oxidized, soaped at the boil, once more rinsed and dried. The resulting red dyeing is fast to washing at the boil. Similar results are obtained by using 10 parts of sodium sulfide instead of 10 parts of sodium hya droxide solution of 30% strength.
- Example 12 A mercerized cotton fabric is padded to a weight increase of 70% with a solution containing per 1000 parts of water 30 parts of the dyestuif mentioned in Example 1. With or Withoutbeing subjected to intermediate drying the impregnated fabric is then fixed for 2 minutes at C. in a bath containing in 1000 parts of water 15 parts of trisodium phosphate, 200 parts of sodium chloride and 0.5 part of N1N-dimethylhydrazine. The fixed fabric is thoroughly rinsed in cold and in boiling Water and soaped as usual. The resulting deep blue dyeing has good properties of fastness.
- Example 13 i NH- A cotton fabric is padded at room temperature to a weight increase of 70% with a solution containing per 1000 parts of water 0.5 part of NzN-dimethylhydrazine.
- the fabric so pretreated is then impregnated with a dyestufl solution containing per 1000 parts of water 30 parts of the dyestuif used in Example 1, 50 parts of urea and 20 parts of sodium carbonate.
- the resulting brilliant blue dyeing has good fastness to light and washing.
- a cotton fabric is printed with the above paste on a roller printing machine and dried, then fixed for 30 seconds in a rapid ager, and rinsed in cold and in hot Water.
- the resulting colorless prints obtained in this manner are developed for minutes at 25 C. in a bath containing per 1000 parts of water 2 parts of diazotized orthochloraniline, then thoroughly rinsed in cold and in hot water.
- the resulting orange print has good properties of general fastness.
- NzN-dimethylhydrazine is omitted, a weaker print results.
- diazotized ortho-chloraniline produces a red print, diazotized or-th-o-nitraniline a bluish red print and 12 diazotized para-nitro-ortho-anisidine a violet print in good yield.
- Example 15 A printing paste is prepared from the following ingredients:
- Example 16 A cot-ton fabric is printed with the printing paste described in Example 15 and then dried. The dried prints are fixed for 10 seconds with the aid of an infra-red drier and finished off as described in Example 1.
- the resulting red print is as strong as the print of Example 15.
- NzN-dimethylhydrazine is omitted, the resulting print is of inferior tinctorial strength.
- Example 17 A solution of 0.6 part of the dyestuif used in Example 2 in 100 parts of hot water is added to a dyebath containing in 900 parts of water 50 parts of sodium chloride. 20 parts of natural silk are dyed in the resulting dyebath for 30 minutes at 40 C. The dyestufi which has only been absorbed by the fiber is fixed by the addition of 2 parts of sodium carbonate and 0.06 part of N:N-di-methylhydrazine for 90 minutes, likewise at 40 C.; the fabric is then thoroughly rinsed in cold and in hot water and finally soaped at C.
- the resulting brilliant red dyeing is fast to light and washing and of much greater tinctorial strength than a comparable dyeing produced without addition of NzN- dirnethylhydrazine.
- a mercerized cotton fabric is padded with the above solution, reeled up and stored for 3 hours at a constant temperature of 30 C. After this storing the unfixed portion of dyestuif is washed out by thoroughly rinsing the fabric in cold and in hot water.
- the fabric impregnated in this manner is then developed with a freshly prepared solution containing in 31000 partsofwater 2 parts of the .diazo compound of meta-chloraniline. After coupling the fabric is rinsed and soaped at the boil. The resulting brilliant scarlet dyeing has good fastness to washing and rubbing.
- Example 20 A mixture of 6 parts of the coupling component of the formula I /C ⁇ K t 110.5: NH-O C-NH SOaH N and 60 parts of sodium chloride is dissolved in 1000 parts of water at 70 C. This solution is used to dye 50 parts of cotton tricot for 30 minutes at a temperature of 70 C. The fabric is then fixed in the same bath after addition of 15 parts of crystalline trisodium phosphate and 02 part of NzN-dimethylhydrazine for 90 minutes at 70 C. After this exhaustion treatment the unfixed portion of the coupling component is washed out in cold and in hot water.
- the tricot treated in this manner is then coupled in a solution containing per 1000 parts of water 2 parts of the freshlyprepared diazo compound para-nitro-orthoanisidine and finished off as described in Example 1.
- the resulting strong brilliant red dyeing has good properties of fastness.
- a dyeing produced in identical manner but without addition of NzN-dimethylhydrazine was found to be substantially inferior in tinctorial strength.
- Example 21 A mercerized cotton fabric is padded at 40 C. with a solution containing per 1000 parts of water 30 parts of the dyestuff used in Example 1, 200 parts of urea, 20 parts of sodium carbonate and 0.5 part of N:N-dimethylhydrazine. To fix t-he dyeing the impregnated fabric is exposed to the action of a high-frequency electric field; it is then rinsed in cold and in hot water, soaped at the boil, once more rinsed and dried.
- the resulting fast, deep blue dyeing is of greater tinctorial strength than a comparable dyeing produced without addition of NzN-dimethylhydrazine.
- Example 22 A cotton fabric is padded at 40 C. with a solution containing in 1000 parts of water, 30 parts of the dyestuff of the formula A solution of 10 parts of the dyestutf of the formula 01 /(l3 ⁇ N lr' C NHOHZ CHTOH and 10 parts of the dyestutf of the formula S OzCHgCHzOSOiH in 800 parts of warm water is cooled to 25 C. and then mixed with 15 parts of trisodium phosphate, 5 parts by volume of a sodium hydroxide solution of 30% strength and 0.2 part of NzN-dimethylhydrazine. The Whole is then made up with cold water to 1000 parts by volume.
- a cotton fabric is impregnated with the above solution, immediately reeled up and so kept for 4 hours at 25 C. After this storing the unfixed portion of dye stuff is washed out by thoroughly rinsing the fabric in cold and in hot water and the fabric is then soaped at the boil. 7 The resulting violet dyeing is much deeper than when NzN-dimethylhyd-razine is omitted.
- a cotton fabric is padded with this solution to a weight increase of 70%, reeled up and kept for 6 hours at a constant temperature of 25 C.
- the stored material is thoroughly rinsed in cold and in hot water and finally soaped at the boil.
- Example 25 When the dyestuffs shown in Example 24 are replaced by a combination of 30 parts of the dyestuff of Example 10 and 20 parts of the dyestuff of the formula 01 E OCH:
- Example 26 A printing paste is prepared from the following ingredients:
- a cotton fabric is printed with this paste on a roller printing machine, dried and then fixed for 30 seconds in a rapid ager. The fabric is then finished off as described in Example 1.
- the resulting turquoise print has good properties of fastness and is substantially stronger than when NzN- dimethylhydrazine is omitted.
- Example 27 A printing paste is prepared from the following ingredients:
- Example 28 A printing paste is prepared from the following ingredients:
- the resulting turquoise print is of considerably greater tinctorial strength than when NzN-dimethylhydrazine is omitted.
- Example 29 A printing paste is prepared from the following ingredients:
- a spun rayon fabric is printed with this paste, then dried and padded with a solution containing in 1000 parts of water 150 parts of sodium chloride, 100 parts of potassium carbonate and 30 parts by volume of a sodium hydroxide solution of 30% strength, squeezed on a padder to a residual liquor content of 70% and then, without intermediate drying, fixed in a rapid ager for 30 seconds.
- the fabric is then finished off as described in Example 1.
- Example 30 A printing paste is prepared from the following ingredients:
- the resulting yellowish brown print is of considerably greater tinctorial strength than when N:N-dimethylhydrazine is omitted and has good properties of fastness.
- Example 31 A solution of 4 parts of the dyestuff used in Example 1 in 100 parts of water is used to pad a cotton fabric to a weight increase of 70%.
- the fabric After an intermediate drying the fabric is conveyed through a solution of 250 parts of sodium chloride, 6 parts of sodium hydroxide of 100% strength and 1 part of NzN-dimethylhydrazine in 900 parts of water.
- This bath is located over one leg of a molten metal bath shaped in the form of a U.
- the chemical solution and the metal bath have a temperature of 90 C.
- the fabric is first conveyed through the chemical bath and immediately thereafter through the metal bath.
- the time of residence of the fabric in the metal bath is 7 to 10 seconds. After it has left the metal bath the fabric is thoroughly rinsed in cold water and then for about 10 minutes in boiling water, and dried.
- Example 32 the formula in 500 parts of water is mixed with a solution of 20 parts of the dyestuif of the formula shown in Example 1 in 449.8 parts of water, 30 parts by volume of a sodium hydroxide solution of 30% strength, 20 parts of crystalline sodium sulfate and 0.2 part of NzN-dimethylhydrazine.
- a cotton fabric is padded with this solution, then reeled up and stored for 3 hours at a constant temperature of 30 C. After this storing the unfixed dyestulf is washed out by rinsing the fabric thoroughly in cold and in hot Water.
- the impregnated fabric is then coupled with a freshly prepared solution containing in 1000 parts of water 2 parts of the diazo compound of meta-chloraniline.
- the resulting deep claret dyeing has good fastness to washing and rubbing.
- Example 33 parts of a cotton fabric are immersed at 25 C. in a bath which contains in 3000 parts of water 1 part of the dyestuff of the formula shown in Example 2.
- a bath which contains in 3000 parts of water 1 part of the dyestuff of the formula shown in Example 2.
- 150 parts of sodium chloride then 25 parts of anhydrous sodium carbonate and after another 5 minutes 10 parts of N2N-dimethylhydrazine are added.
- the fabric remains for 1 hour in the dyebath and is then rinsed and soaped in the usual manner. A red dyeing is obtained.
- Example 34 100 parts of a cotton fabric are padded with a solution which contains in 1000 parts of water 20 parts of the dyestulf of the composition shown in Example 2 and 50 parts of sodium chloride, and then expressed to a weight increase of 100%.
- the fabric is then immersed for 10 seconds in a solution containing in 1000 parts of Water 10 parts of NzN-dimethylhydrazine and 50 parts of sodium chloride, and finally rinsed and soaped in the usual manner.
- a strong red dyeing is obtained which is much stronger than a comparably produced dyeing in the absence of NzN-dimethylhydrazine.
- Example 35 70 parts of the dyestulf of the formula shown in Ex ample 2 are dissolved in 2000 parts of water, mixed with 8 parts of NzN-dimethylhydrazine and stirred for 3 hours at 20 to 25 C. 600 parts of sodium chloride are then added and the whole is stirred for 2 hours longer at 20 to 25 C. The precipitate formed is filtered off and washed with saturated sodium chloride solution and then dried at about 30 C. under reduced pressure.
- Example 36 1.5 parts of the dyestuff of the formula shown in Example 2 are dissolved in 25 parts of boiling water. A dyebath is prepared from this solution in admixture with a solution of 60 parts of sodium chloride in 750 parts of waterand 50 parts of cotton yarn are dyed in it for 30 minutes at 40 C. The dyestuff deposited on the fiber is then fixed with addition of 0.04 part of one of the hydrazine compounds of the formulae and of 15 parts of tris'odium phosphate, in the same bath for 1 /2 hours at 40 C. The yarn is then thoroughly rinsed in cold and in hot water and finally soaped at the boil. A strong red dyeing is obtained.
- Example 3 7 A cotton fabric is impregnated at room temperature with a padding solution which contains in 1000 parts of water Parts Dyestufi mentioned in Example 1 30 Urea 50 Sodium bicarbonate and 20 N:N-dimethylhydrazine 1.5
- the fabric Without undergoing an intermediate drying the fabric is then steamed for 20 seconds at 120 C. in a high-temperature ager and then finished off in known manner. A blue dyeing is obtained which is fast to washing at the boil and is distinctly stronger than a dyeing produced without adding NzN-dimethylhydrazine.
- Process for coloring cellulose fibrous and nitrogenous materials with reactive dyestuff compounds which comprises applying to the fibrous material an aqueous preparation containing a member selected from the group consisting of (a) a non-quaternized reactive dyestuff compound and a hydrazine compound containing at least one tertiary nitrogen atom, said hydrazine compound being present in an amount of from about 0.1% to about 10% by weight on the weight of the dyestuif.
- Process for coloring cellulose fibrous and nitrogenous materials with reactive dyestuff compounds which comprises applying to the fibrous material an aqueous preparation containing a member selected from the group consisting of (a) a non-quaternized reactive dyestutf compound and a hydrazine compound containing at least one tertiary nitrogen atom, said hydrazine compound being present in an amount of from about 0.1% to about 10% by weight on the weight of the dyestuif.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive halogen atom and from about 0.2% to 2% by weight based on the weight of the dyestutf of a hydrazine compound containing at least one tertiary nitrogen atom.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive halogen atom quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom which comprises applying to the fibrous material an aqueous preparation containing a nonquaternized dyestulf with at least one reactive halogen atom and a dyestufi with at least one reactive halogen atom quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by weight based on the weight of the dyestufi of a hydrazine compound of the formula R2 wherein R and R are members selected from the group consisting of alkyl radicals with at most 4 carbon atoms and alkylene members of the same saturated nitrogen-containing, at most siX-membered, heterocyclic ring, and R is a member selected from the group consisting of hydrogen and alkyl radicals with at most 4 carbon atoms.
- Process for coloring cellulose fibrous and nitroge lawn materials with dyestuffs containing at least one reac tive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by weight based on the weight of the dyestuff of a hydrazine compound of the formula (CmH2m+1) pr 2p1) N-N (C H2n'H) ⁇ H- wherein m and n are whole numbers of at most 4 and p is a whole number of at most 5.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by Weight based on the weight of the dyestuif of N:N-dimethylhydrazine.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom which comprises applying to the librous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and a hydrazine compound of the formula z). wherein r and s each stands for the whole numbers 3 and 4.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing the dyestuif and from about 0.2% to 2% by weight based on the weight of the dyestuff of 1:5-diaza-bicyclo-(0:3:3)- octane.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestufis containing at least one reactive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing the dyestuif and from about 0.2% to 2% by Weight based on the weight of the dyestuif of N-amino-N:N-diaza-bicyclo- (2:222) -octane sulfate.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reac' tive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing a nonquaternized dyestuif with at least one reactive chlorine atom and a dyestuif with at least one reactive chlorine atom quaternized with a hydrazine compound of the formula NNH-Rl R2 wherein R and R are members selected from the group consisting of alkyl radicals with at most 4 carbon atoms wherein m and n are whole numbers of at most 4 and p is a whole number of at most 5.
- Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom which comprises applying to the fibrous material an aqueous preparation containing nonquaternized dyestuff with at least one reactive chlorine atom and dyestuff with at least one reactive chlorine atom quaternized with NzN-dimethylhydrazine.
Description
The present invention provides a process for dyeing or printing fibrous materials with the aid of reactive dyestuffs or reactive dyestuif intermediates. As is known the term reactive dyestuifs describes dyestuffs that enter a covalent bond with the material to be dyed in the course of the dyeing or printing process, and as a rule this is accompanied by elimination of the reactive substituent of the dyestuif. The speed at which the bond between the dyestutt and the substratum is formed depends, on one hand, on the dyeing conditions-such as temperature, pH value of the dyebath or the printing pasteand, on the other, on the reactivity of the reactive grouping of the dyestuif. It is known that in this respect considerable differences exist between individual reactive dyestuffs. The present invention provides a process for increasing the reactivity of reactive dyestuff compounds viz. reactive dyestuffs proper or reactive dyestuif intermediates, wherein there is used a hydrazine containing at least one tertiary nitrogen atom or a water-soluble salt thereof.
Being a tertiary nitrogen atom, one of the two nitrogen atoms of such a hydrazine grouping must be bound to two carbon atoms, while the other nitrogen atom may be substituted or unsubstituted. There are also suitable cyclic hydrazine compounds, more especially those in which one of the two hydrazine nitrogen atoms, or both, is or are members of one or several rings.
In general, it is of advantage to use a hydrazine or hydrazine salt that is soluble in the dyebath or in the printing paste, and it may contain, in addition to one or more than one hydrazine group, substituents that do not react with the reactive dyestuffs, for example halogen atoms, nitro, alkoxy or hydroxyl groups, but preference is given to such hydrazines as contain, in addition to at least one N--N group, only carbon and hydrogen atoms, for example a hydrazine that is substituted exclusively by non-aromatic hydrocarbon radicals and contains at least one tertiary nitrogen atom.
Such hyd-razines may correspond, for example, to the formula R1 Ra immed States Patent M Patented June 13, 1967 in which m and neach is a whole number not greater than 4, preferably 1, and p is a whole number not greater than 5. The aliphatic hydrocarbon radicals in these hydrazine compounds may be branched, but they are preferably unbranched.
Finally, there may be mentioned especially also those hydrazine compounds whose vicinal nitrogen atoms are at the same time members of two condensed rings, for example those of the formula (4) CHr-CH:
C N-NHr CHr-C 2 1:5-diaza-bicyclo-(0z3:3)-octane of the formula (5) CH: /CH:
05 f an,
cgc ficfh $111 (1H2 $11 I S04E- NH,
(7) alkyl H alkyl SOaH or more especially (8) H3O H N-N 30 SOaH alkyl NNH( i-SH alkyl such as HaC\ fi,
NNHO-SH 3 or the hydrazine salt NNH-i 3SH- \N--NH1 H3O H3C/ sired may be used for the reaction instead of the free bases-may be derived, for example, from the conven-' tional inorganic or organic acids, for example from sulfuric, hydrochloric, phosphoric, acetic, formic, propionic, chloracetic, oxalic or tartaric acid.
As reactive dyestuffs there are advantageously used in the present process those of the water-soluble variety, for example organic dyestuffs from diazo or coupling components containing carboxyl groups, sulfonic acid groups or aliphatically bound sulfuric acid ester groups. As relevant reactive groupings there may be mentioned the epoxide groups, ethylene imino groups, isocyanate groups, isothiocyanate groups, carbamic acid aryl ester groups, the propiolic acid amide grouping, monoand dichlorotcrotonylamino, chloroacrylamino, acrylamino, vinylsulfone groups and primarily groupings containing a labile substituent and which are easy to split with entrainment of the bond election pair, for example sulfohalide groups, aliphatically lbound sulfuric acid ester groups and aliphatically bound sulfonyloxy groups and halogen atoms, more especially an aliphatically bound chlorine atom. These labile substituents are advantageously in position '7 or B of an aliphatic radical which is bound to the dyestuff molecule directly or through an amino, s-ulfone or sulfonamide group; in those relevant dyestuffs in which the labile substituents are halogen atoms, those mobile halogen atoms may also be present in an aliphatic acyl radical, for example in an acetyl radical, or in position B or in positions a and ,8 of a propionyl radical or preferably in a heterocyclic radical, for example in a pyrimidine or pyridazine ring, or above all in a triazine ring. The dyestuffs contain with advantage a grouping of the formula G imalogen -XC C- alogen ni r C ilalogen in which X represents a nitrogen bridge and Z a hydrogen atom, a possibly substituted amino group, an etherified hydroxyl or mercapto group or a halogen atom or an alkyl, aryl or aralkyl group, and A stands for a hydrogen atom or a halogen atom. The halogen atoms are, for example, bromine atoms or preferably chlorine atoms.
It is of special value to use dyestuffs that contain the grouping of the formula in which n is a Whole number not greater than 4 and Z has the above meaning.
Further suitable are dyestuffs containing dip'henoxytriazine groupings and those which contain a grouping of the formula NHC C-S-Y il C in in which X stands for and Y stands for a group in which R represents an ortho-arylene radical.
Further suitable reactive groupings are the following radicals: Trichloropyridazine, dichloroquinoxaline, dichlorobutene, halogenated pyridazone, sulfonic acid dichloropropylamide, allylsulfone, allylsulfide, 2-halogenbenzthiazolecarbamide, isothiocyanate and li-sulfatopropionic acid amide radicals.
The present process may be performed with a wide variety of organic dyestuffs, for example oxazine, triphenylmethane, xanthene, nitro, accridone, azo, anthraquinone and phthalocyanine dyestuffs.
From the azo dyestuff series there may be mentioned, for example, disazo and trisazo dyestuffs, and more especially monoazo dyestuffs. A large number of such active azo dyestuffs is already known so that there is no need to deal with them in greater detail here.
From the series of the anthraquinone dyestuffs there may be mentioned primarily the l-amino-4-bromanthraquinone-Z-sulfonic acid and the dyestuffs derived from 1:4 diaminoanthraquinone 2 sulfonic acid. These and other anthraquinone dyestuffs are manufactured in known manner. A suitable phthalocyanine dyestuffs there may be mentioned above all dyestuffs which are derived from nickel or copper phthalocyanine sulfonamides and contain at least two free sulfonic acid groups per molecule and which contain at least in one sulfonamide radical a group with at least one labile halogen atom.
The present process may also be performed with vat dyestuffs that are water-soluble or insoluble in the oxidized form and dispersion dyestuffs having the characteristics of reactive dyestuffs.
There are several favorable variants available for the performance of the present process. Inter alia, there may be used different proportions, for example for every reactive group of one molecular proportion of a dyestuff at least 1 molecular proportion of the hydrazine compound, or for the same amount of dyestuff less than 1 molecular proportion of hydrazine compound may be used. It is also possible to quaternate the dyestuff with the hydrazine compound, in which case the ratio quaternated dyestuff: dyebath is so that the amount of hydrazine compound present in the quaternated dyestuff corresponds to that amount of hydrazine compound which would have to be added in the unquaternated state to the dyebath or to the printing paste. In connection with both ratiosand more especially in the case of the ratio named first (which is hereinafter referred to as the stoichiometric ratio)there may be distinguished three methods, namely:
(a) For dyeing or printing the fibrous material use is made of reaction products of reactive dyestuffs and a hydrazine containing at least one tertiary nitrogen atom;
(b) The fibrous material is dyed or printed with a preparation manufactured from a reactive dyestuff and a hydrazine containing at least one tertiary nitrogen atom;
(c) The reactive d-yestuff and the hydrazine containing at least one tertiary nitrogen atom are applied separately to the fibrous material.
For the method described under (a) it is necessary to prepare reaction products of reactive dyestuffs with hydrazines containing at least one tertiary nitrogen atom; they are accessible, for example, by treating the substituted hydrazine with the reactive dyestuff in an aqueous medium at room temperature or at a slightly higher temperature. If desired, these products may be isolated, for example salted out.
reactive group of a mol of dyestuif less than one mol of hydrazine compound is used; it is especially suitable for a catalytic ratio. As is usual catalytic ratio describes a ratio which is substantially smaller than the ratio referred to under (a). The amount of hydrazine compound referred to the reactive dyestuif may, however, vary Within certain limits and depends on the reactivity of the hydrazine used. Referred to the amount of dyestuff the catalytic amount of hydrazine compound may vary from about 0.1 to and preferably from about 0.2 to 2% by weight.
In variant (c), in which the hydrazine compound may be used in a stoichiometric or a catalytic ratio, the reactive dyestuff and the hydrazine are applied in any desired order of succession to the fibrous material, if desired with the use of intermediate drying.
In other respects it is immaterial whether and to what extent the reaction of the reactive dyestuif with the hydrazine compound by any one of the dilferent variants and in the different ratios gives rise to other reactions, such as formation of quaternary ammonium compounds.
What has been said above with regard to the reactive dyestuffs applies in appropriate manner also to the reactive intermediates, for example reactive coupling components.
The present process is suitable for dyeing or printing a wide variety of fibrous materials such as paper or leather or above all textile materials, for example those made from animal fibers such as silk, and above all those from cellulose fibers, including both native cellulose fibers such as linen or cotton and fibers from regenerated cellulose such as rayon (viscose) or rayon staple. In other respects dyeing and printing are carried out under the conditions convention-ally used for reactive dyestuffs, more especially also when a catalytic proportion of the hydrazine compound is used. For dyeing and printing cellul-osic textile materials it is of special advantage to use concomitantly inorganic acid acceptors, such as carbonates, hydroxides, bicarbonates or phosphates of alkali metals, or mixtures thereof. Also bases such as trimethyl benzyl ammonium hydroxide or sodium trichloracetate. When reactive vat dyestuffs are used, the process may be performed in the presence of a conventional reducing agent such as sodium hydrosulfite, thiourea dioxide, sodium sulfide or sodium sulfoxylate. It is also possible to incorporate with the dyebaths and printing pastes the conventional additives, such as elec trolytes, forexample sodium chloride, sodium acetate, or non-electrolytes such as urea or thickeners, such as alginates. To prevent undesirable reduction phenomena, more especially in the dyestuffs, use may be made of one of the conventional additives, such as meta-nitrobenzenesulfonic acid. As a rule the hydrazine is added to the dyebath or to the printing paste. If dyeing is carried out as a two-stage process-the application of the dyestufi and the fixation with the acid acceptor being performed separately--it is possible to add the hydrazine only in the second stage of the process. When dyeing or printing is carried out in a neutral to acidic medium, for example in the case of nitrogenous textile fibers or leather, it is of advantage to use a water-soluble hydrazine salt, and the same applies to the case where at the same time a finishing operation with a curable aminoplast, for example a condensation product of formaldehyde with melamine or urea, is carried out.
As mentioned above, the fibrous materials are dyed or printed under the conditions conventionally used for reactive dyestuffs. The present process allows the reaction times and/or the reaction temperature to be reduced and/or dyeings and prints of greater tinctori-al strength to be produced, for example by the cold pad batch method, by the pad-steam or pad-dry method, by the wet-pad steam process and more especially by the exhaustion method and in printing. Depending on the method used, the dyestuffs may 'be fixed at widely dif- Example 1 A solution of 30 parts of the dyestulf of the formula SOaH Cl 5 SOzH SOaH II I if in 800 parts of boiling water is cooled to 20 C. and mixed with 10 parts by volume of a sodium hydroxide solution of 30% strength, 20 parts of crystalline sodium sulfate and 0.05 to 0.2 part of N:N-dimethyl hydrazine of the formula whereupon the resulting solution is made up with cold water to 1000 parts.
A cotton fabric is padded with the above solution to a weight increase of 75%, immediately reeled up and left to itself in this state for 6 to 12 hours at 20 C., after which the untfixed portion of the dyestuff is removed by a thorough rinse in cold and in boiling water and finally soaped in the usual manner.
The resulting blue dyeing displays good fastness to light and washing and is substantially more intense than a comparable dyeing produced without addition of N :N-dirnethylhydrazine.
When 15 parts of trisodium phosphate are used instead of 10 parts by volume of sodium hydroxide solution, good results are likewise obtained.
With equal results there may be used 2 parts of dimethylhydrazine instead of 0.05 to 0.2 part thereof.
Similar good results are obtained by using 1:5-diazabicyclo (0:3:3) octane instead of N:N dimethylhydrazine.
By using for every 1000 parts of dyebath 4 parts of a solution containing in 99 parts of a 5% aqueous dimethylhydrazine solution, 1 part of sodium sulfite, and 20 parts of sodium carbonateinstead of 0.05 to 0.2 part of dimethylhydrazine and -10 parts by volume of 30% sodium hydroxide solution, similar good results are obtained.
Example 2 A cotton fabric is impregnated at 50 solution which contains per 1000 parts of the dyestuif of the formula C. with a padding of water 25 parts The resulting brilliant red dyeing is distinctly of greater tinctorial strength than a comparable dyeing produced without NzN-dimethylhydrazine. The results achieved are equally good when instead of 0.05 to 0.2 part 2 parts of dimethylhydrazine are used. It is also possible to quaternate 3 of the 25 parts of dyestulf used with 0.2 part of N:N-dimethylhydrazine and to add this product together with the remaining 22 parts of unquaternated dyestuff to the padding solution. When the 0.05 to 0.2. part of NzN- dimethylhydrazine is then omitted from the dyebath, all remaining conditions being identical, a similar, good dyeing is obtained.
Example 3 A solution of 1.5 parts of the dyestuff of the formula l SOaH l l Cu 0 HN-C C-I-IN I I N N N HOsS S0311 dimethylhydrazine. Fixing takes 1 /2 hours at 40 C. The
dyed yarn is thoroughly rinsed in cold and in hot water and finally soaped at the boil.
A brilliant violet dyeing is obtained which possesses good fastness properties and is of considerably greater tinctorial strength than a comparable dyeing produced in the absence of NzN-dimethylhydrazine.
When the dyestuff used above is replaced by an equivalent amount of the dyestuff of the formula good results are likewise obtained.
Similar, good results are obtained by using N:N:N- trimethylhydrazine instead of NzN-dimethylhydrazine.
Example 4 A mixture of 30 parts of the dyestuff mentioned in Example 2 and 50 parts of urea is dissolved in 700 parts of boiling water. This solution is cooled to 40 C., 20 parts of sodium carbonate and 0.2 part of NzN-dimethylhydrazine are added, and the solution is made up with cold water to 1000 parts.
A cotton fabric is padded with the above solution to a weight increase of 75% and then steamed directly, that is to say Without being intermediately dried, for 1 minute. The steamed fabric is rinsed and soapedin the usual manner.
The resulting brilliant red dyeing has very good fastness to light and washing. The same procedure, except that NzN-dirnethylhydrazine is omitted, gives a considerably weaker dyeing.
3 Example 5 A mixture of 20 parts of the dyestuff of the formula and 40 parts of urea is dissolved in 600 parts of boiling water. The solution is cooled to 40 C., 20 parts of soclium carbonate and 0.2 part of NzN-dimethylhydrazine are added, and the whole is made up with cold water to 1000 parts.
A cotton fabric is padded with this solution to a weight increase of 70%. The fabric is then reeled up and kept for 1 hour in a pad-roll installation at a temperature of C. measured with a wet-bulb thermometer then thoroughly rinsed in cold and in hot water and soaped at the boil.
The resulting deep orange dyeing has very good fastness to light and washing and greater tinctorial strength than a comparable dyeing produced without addition of N N-dimethylhydrazine.
Example 6 A solution of 3 parts of the dyestuif of Example 1 in parts of water is used to impregnate a cotton fabric to a weight increase of 70%. After an intermediate drying the fabric is impregnated with a solution of 250 parts of sodium chloride, 6 parts of sodium hydroxide 100% and 1 part of NzN-dimethylhydrazine in 900 parts of water, to achieve a weight increase of 80%. Immediately thereafter the fabric is steamed for 30 seconds with steam heated at 103 to C., then thoroughly rinsed in cold and in hot water, washed for 5 minutes at the boil with addition of soap and then dried.
The resulting brilliant blue dyeing has very good fastness to light and washing. A comparably produced dyeing without addition of NzN-dimethylhydrazine is substantially weaker.
Example 7 A mixture of 40 parts of the 1:2-chromium complex of the dyestuff of the formula and 200 parts of urea is dissolved in 870 parts of hot water and the solution is cooled to room temperature, and 20 parts of sodium carbonate and 1 part of N:N-dimethylhydrazine are then stirred into the solution. This solution is used to impregnate a mercerized cotton fabric to a weight increase of 70%. The fabric is then dried in a current of hot air to a residual moisture content of 8%, then thoroughly rinsed in cold and in boiling Water, and dried.
The resulting covered greenish blue dyeing has very good wet fastness properties.
The same method, but without addition of NzN-dimethylhydrazine, yields a substantially lighter tint.
A cotton fabric is printed withthis printing paste on a roller printing machine, then dried and steamed for 3 minutes at 100 C. in a Mather-Platt ager. The fixed print is rinsed in cold and in hot water and dried. The .resulting print is of equal tinctorial strength to that obtained by fixing for 8 minutes without addition of N:N- dimethylhydrazine.
A similar result is obtained on a spun rayon fabric.
l. o %C\ HOsS g i HzN-C O-lEINGN i Example 9 A printing paste is prepared from the following ingredients:
Parts Dyestuff mentioned in Example 1 50 Urea 200 Water 378 Sodium alginate thickening 5021000 350 Sodium bicarbonate 10 N:N-dimethylhydrazine 2. Sodium meta-nitrobenzenesulfonate -i 10 Example 10 A printing paste is prepared from the following ingredients:
, Parts Dyestulf of the formula shown below O Urea 200 Water 328 Sodium alginate thickening 50:1000 350 Aqueous potassium carbonate solution of 50% strength 60 N: N-dimethylhydrazine 2 Sodium meta-nitrobenzenesulfonate A cotton fabric is printed with the above printing paste on a roller printing machine, dried and then steamed for seconds in a rapid agar. The fabric is then finished off as described in Example8.
The resulting turquoise print has substantially greater 10 tinctorial strength than when fixed for 8 minutes without addition of NzN-dimethylhydrazine.
The dyestuff used in this example corresponds to the formula where Cu-Pc represents the copper phthalocyanine residue.
Example 11 A cellulose fabric is padded at 20 to 30 C. with a solution containing per 1000 parts of water 10 parts of sodium hydroxide solution of 30% strength, 20 parts of the dyestuff ofthe formula l r ll 0 and 0.1 part of N:N-dimethylhydrazine. The fabric is then reeled up, wrapped in a plastic film, stored for 6 hours, then rinsed, oxidized, soaped at the boil, once more rinsed and dried. The resulting red dyeing is fast to washing at the boil. Similar results are obtained by using 10 parts of sodium sulfide instead of 10 parts of sodium hya droxide solution of 30% strength.
Example 12 A mercerized cotton fabric is padded to a weight increase of 70% with a solution containing per 1000 parts of water 30 parts of the dyestuif mentioned in Example 1. With or Withoutbeing subjected to intermediate drying the impregnated fabric is then fixed for 2 minutes at C. in a bath containing in 1000 parts of water 15 parts of trisodium phosphate, 200 parts of sodium chloride and 0.5 part of N1N-dimethylhydrazine. The fixed fabric is thoroughly rinsed in cold and in boiling Water and soaped as usual. The resulting deep blue dyeing has good properties of fastness.
A comparable dyeing produced without addition of NzN-dimethylhydrazine displayed a much weaker tint.
When thedyestuif used above is replaced by the dyestuff of the formula (N) NE;
SO3H
Example 13 i NH- A cotton fabric is padded at room temperature to a weight increase of 70% with a solution containing per 1000 parts of water 0.5 part of NzN-dimethylhydrazine.
The fabric so pretreated is then impregnated with a dyestufl solution containing per 1000 parts of water 30 parts of the dyestuif used in Example 1, 50 parts of urea and 20 parts of sodium carbonate.
Without intermediate drying the fabric is then steamed for one minute. Rinsing and soaping is performed as in Example 12.
The resulting brilliant blue dyeing has good fastness to light and washing.
A cotton fabric is printed with the above paste on a roller printing machine and dried, then fixed for 30 seconds in a rapid ager, and rinsed in cold and in hot Water. The resulting colorless prints obtained in this manner are developed for minutes at 25 C. in a bath containing per 1000 parts of water 2 parts of diazotized orthochloraniline, then thoroughly rinsed in cold and in hot water.
The resulting orange print has good properties of general fastness. When NzN-dimethylhydrazine is omitted, a weaker print results.
When ortho-chloraniline is replaced by 2 parts of diazotized ortho-nitr-aniline, an orange print is obtained which has identical properties.
When ortho-chloraniline is replaced by 2 parts of paranitro-ortho-anisidine, a red print is obtained which has identical properties.
When the printing paste is prepared with the coupling component of the formula and in other respects the procedure described above is adopted, diazotized ortho-chloraniline produces a red print, diazotized or-th-o-nitraniline a bluish red print and 12 diazotized para-nitro-ortho-anisidine a violet print in good yield.
When NzN-dimethylhydrazine is omitted, the resulting prints are weaker.
Example 15 A printing paste is prepared from the following ingredients:
Parts Dyestuff used in Example 2 50 Urea 200 Water 378 Sodium alginate thickening 5021000 350 Sodium bicarbonate 10 NzN-dimethylhydrazine 2 Sodium meta-nitrobenzenesulfonate 10 A cotton fabric is printed with this paste with the aid of a roller printing machine and then, without intermediate drying, fixed for 2 minutes in dry heat at 150 C. The fabric is finished off as described in Example 1.
A red print is obtained. When NzN-dimethylhydrazine is omitted, the resulting print is much weaker.
Example 16 A cot-ton fabric is printed with the printing paste described in Example 15 and then dried. The dried prints are fixed for 10 seconds with the aid of an infra-red drier and finished off as described in Example 1.
The resulting red print is as strong as the print of Example 15. When NzN-dimethylhydrazine is omitted, the resulting print is of inferior tinctorial strength.
Example 17 Example 18 A solution of 0.6 part of the dyestuif used in Example 2 in 100 parts of hot water is added to a dyebath containing in 900 parts of water 50 parts of sodium chloride. 20 parts of natural silk are dyed in the resulting dyebath for 30 minutes at 40 C. The dyestufi which has only been absorbed by the fiber is fixed by the addition of 2 parts of sodium carbonate and 0.06 part of N:N-di-methylhydrazine for 90 minutes, likewise at 40 C.; the fabric is then thoroughly rinsed in cold and in hot water and finally soaped at C.
The resulting brilliant red dyeing is fast to light and washing and of much greater tinctorial strength than a comparable dyeing produced without addition of NzN- dirnethylhydrazine.
When the dyestufi used above is replaced by an equivalent amount of the disazo-dyestufi of the formula a yellowish brown dyeing is obtained.
13 Example 19 A solution of 40 parts of the coupling component of the formula HOsS SOaH
in 929.8 parts of water is mixed with parts of a sodium hydroxide solution of 30% line sodium sulfate and 0.2 part of NzN-dimethylhydrazine.
A mercerized cotton fabric is padded with the above solution, reeled up and stored for 3 hours at a constant temperature of 30 C. After this storing the unfixed portion of dyestuif is washed out by thoroughly rinsing the fabric in cold and in hot water.
The fabric impregnated in this manner is then developed with a freshly prepared solution containing in 31000 partsofwater 2 parts of the .diazo compound of meta-chloraniline. After coupling the fabric is rinsed and soaped at the boil. The resulting brilliant scarlet dyeing has good fastness to washing and rubbing.
I A comparable dyeing produced without addition of NzN-dimethylhydrazine is considerably weaker.
When the development is carried out with 2 parts (per 1000 parts of water) of diazotized para-nitro-ortho-anisidine instead of with meta-chloraniline, a deep claret dyeing is obtained which has good properties of general fastness and is likewise substantially stronger than a comparable dyeing produced without addition of N:N-dimethylhydrazine.
Example 20 A mixture of 6 parts of the coupling component of the formula I /C\ K t 110.5: NH-O C-NH SOaH N and 60 parts of sodium chloride is dissolved in 1000 parts of water at 70 C. This solution is used to dye 50 parts of cotton tricot for 30 minutes at a temperature of 70 C. The fabric is then fixed in the same bath after addition of 15 parts of crystalline trisodium phosphate and 02 part of NzN-dimethylhydrazine for 90 minutes at 70 C. After this exhaustion treatment the unfixed portion of the coupling component is washed out in cold and in hot water.
The tricot treated in this manner is then coupled in a solution containing per 1000 parts of water 2 parts of the freshlyprepared diazo compound para-nitro-orthoanisidine and finished off as described in Example 1.
The resulting strong brilliant red dyeing has good properties of fastness.
A dyeing produced in identical manner but without addition of NzN-dimethylhydrazine was found to be substantially inferior in tinctorial strength.
HOaS- strength, parts of crystal- 1 4 Example 21 A mercerized cotton fabric is padded at 40 C. with a solution containing per 1000 parts of water 30 parts of the dyestuff used in Example 1, 200 parts of urea, 20 parts of sodium carbonate and 0.5 part of N:N-dimethylhydrazine. To fix t-he dyeing the impregnated fabric is exposed to the action of a high-frequency electric field; it is then rinsed in cold and in hot water, soaped at the boil, once more rinsed and dried.
The resulting fast, deep blue dyeing is of greater tinctorial strength than a comparable dyeing produced without addition of NzN-dimethylhydrazine.
Example 22 A cotton fabric is padded at 40 C. with a solution containing in 1000 parts of water, 30 parts of the dyestuff of the formula A solution of 10 parts of the dyestutf of the formula 01 /(l3\ N lr' C NHOHZ CHTOH and 10 parts of the dyestutf of the formula S OzCHgCHzOSOiH in 800 parts of warm water is cooled to 25 C. and then mixed with 15 parts of trisodium phosphate, 5 parts by volume of a sodium hydroxide solution of 30% strength and 0.2 part of NzN-dimethylhydrazine. The Whole is then made up with cold water to 1000 parts by volume.
A cotton fabric is impregnated with the above solution, immediately reeled up and so kept for 4 hours at 25 C. After this storing the unfixed portion of dye stuff is washed out by thoroughly rinsing the fabric in cold and in hot water and the fabric is then soaped at the boil. 7 The resulting violet dyeing is much deeper than when NzN-dimethylhyd-razine is omitted.
When the above dyestufl mixture is replaced by 20 parts of the 1:2-chromium complex in which 2 molecules of the dyestuff of the formula are bound to one atom of chromium, a deep black dyeing is obtained which has good properties of fastness.
'(where Cu-Pc represents the copper phthalocyanine residue) and 20 parts of the dyestuff of the formula is dissolved in 800 parts of boiling water; the solution is cooled to 25 C. and mixed with 16 parts of trisodium phosphate, 8 parts by volume of sodium hydroxide solution of 30% strength and 0.2 part of N:N-dimethylhydrazine. The whole is then made up with cold water to 1000 parts by volume.
A cotton fabric is padded with this solution to a weight increase of 70%, reeled up and kept for 6 hours at a constant temperature of 25 C. The stored material is thoroughly rinsed in cold and in hot water and finally soaped at the boil.
' A brilliant yellowish green dyeing is obtained. A comparable combination dyeing produced without addition of NzN-dimethylhydrazine displays Weaker tints.
Example 25 When the dyestuffs shown in Example 24 are replaced by a combination of 30 parts of the dyestuff of Example 10 and 20 parts of the dyestuff of the formula 01 E OCH:
and dyeing is performed in identical manner, similar good results are obtained.
Example 26 A printing paste is prepared from the following ingredients:
A cotton fabric is printed with this paste on a roller printing machine, dried and then fixed for 30 seconds in a rapid ager. The fabric is then finished off as described in Example 1.
to The resulting turquoise print has good properties of fastness and is substantially stronger than when NzN- dimethylhydrazine is omitted.
Example 27 A printing paste is prepared from the following ingredients:
50 parts of the dyestufi of the formula (obtained by condensing the basic aminoazo dyestutf with 2 2 4 6-trichloropyrimidine) A cotton fabric is printed with this paste on a roller printing machine or by the screen printing method. The fabric is dried and then fixed for 30 seconds in a rapid ager and finished off as described in Example 1. The resulting yellow print is of much greater tinctorial strength than when N:N-dimethylhydrazine is omitted.
Example 28 A printing paste is prepared from the following ingredients:
Parts Dyestuff of the formula shown in Example 22 30 Water ".4 420 Sodium alginate thickening 5011000 550 A cotton fabric is printed with this paste and then dried. The dried fabric is padded with a solution containing in 1000 parts of water 150 parts of sodium chloride, parts of potassium carbonate, 30 parts by volume of a sodium hydroxide solution of 30% strength and 2 parts of NtN-dimethylhydrazine and squeezed to a residual liquor content of 70%, then without intermediate drying fixed for 30 seconds in a rapid ager and finished off as described in Example 1.
The resulting turquoise print is of considerably greater tinctorial strength than when NzN-dimethylhydrazine is omitted.
A similar, good result is obtained on a spun rayon fabric.
Example 29 A printing paste is prepared from the following ingredients:
r A spun rayon fabric is printed with this paste, then dried and padded with a solution containing in 1000 parts of water 150 parts of sodium chloride, 100 parts of potassium carbonate and 30 parts by volume of a sodium hydroxide solution of 30% strength, squeezed on a padder to a residual liquor content of 70% and then, without intermediate drying, fixed in a rapid ager for 30 seconds. The fabric is then finished off as described in Example 1.
The resulting turquoise print is of good tinctorial strength. When the same procedure is followed but without addition of NzN-dimethylhydrazine, a considerably weaker print results.
An equally good result is obtained on a cotton fabric.
Example 30 A printing paste is prepared from the following ingredients:
20 parts of the 1:2-cobalt complex of the dyestufi of the formula A cotton fabric is printed with this paste on a roller printing machine and dried, then fixed for 30 seconds in a rapid ager and finished off as described in Example 1.
The resulting yellowish brown print is of considerably greater tinctorial strength than when N:N-dimethylhydrazine is omitted and has good properties of fastness.
Example 31 A solution of 4 parts of the dyestuff used in Example 1 in 100 parts of water is used to pad a cotton fabric to a weight increase of 70%.
After an intermediate drying the fabric is conveyed through a solution of 250 parts of sodium chloride, 6 parts of sodium hydroxide of 100% strength and 1 part of NzN-dimethylhydrazine in 900 parts of water. This bath is located over one leg of a molten metal bath shaped in the form of a U. The chemical solution and the metal bath have a temperature of 90 C. The fabric is first conveyed through the chemical bath and immediately thereafter through the metal bath. The time of residence of the fabric in the metal bath is 7 to 10 seconds. After it has left the metal bath the fabric is thoroughly rinsed in cold water and then for about 10 minutes in boiling water, and dried.
The resulting strong, of fastness.
When the same procedure is adopted but the N:N-dimethylhydrazine is omitted from the chemical bath, a pale lilac dyeing results.
blue dyeing has good properties 18 Example 32 the formula in 500 parts of water is mixed with a solution of 20 parts of the dyestuif of the formula shown in Example 1 in 449.8 parts of water, 30 parts by volume of a sodium hydroxide solution of 30% strength, 20 parts of crystalline sodium sulfate and 0.2 part of NzN-dimethylhydrazine.
A cotton fabric is padded with this solution, then reeled up and stored for 3 hours at a constant temperature of 30 C. After this storing the unfixed dyestulf is washed out by rinsing the fabric thoroughly in cold and in hot Water.
The impregnated fabric is then coupled with a freshly prepared solution containing in 1000 parts of water 2 parts of the diazo compound of meta-chloraniline.
The resulting deep claret dyeing has good fastness to washing and rubbing.
A comparable dyeing produced without addition of NzN-dimethylhydrazine was of much weaker tinctorial strength.
Example 33 parts of a cotton fabric are immersed at 25 C. in a bath which contains in 3000 parts of water 1 part of the dyestuff of the formula shown in Example 2. In the course of 30 minutes 150 parts of sodium chloride, then 25 parts of anhydrous sodium carbonate and after another 5 minutes 10 parts of N2N-dimethylhydrazine are added. The fabric remains for 1 hour in the dyebath and is then rinsed and soaped in the usual manner. A red dyeing is obtained.
Without adding NcN-dimethylhydrazine a substantially weaker dyeing results.
Example 34 100 parts of a cotton fabric are padded with a solution which contains in 1000 parts of water 20 parts of the dyestulf of the composition shown in Example 2 and 50 parts of sodium chloride, and then expressed to a weight increase of 100%. The fabric is then immersed for 10 seconds in a solution containing in 1000 parts of Water 10 parts of NzN-dimethylhydrazine and 50 parts of sodium chloride, and finally rinsed and soaped in the usual manner. A strong red dyeing is obtained which is much stronger than a comparably produced dyeing in the absence of NzN-dimethylhydrazine.
Example 35 70 parts of the dyestulf of the formula shown in Ex ample 2 are dissolved in 2000 parts of water, mixed with 8 parts of NzN-dimethylhydrazine and stirred for 3 hours at 20 to 25 C. 600 parts of sodium chloride are then added and the whole is stirred for 2 hours longer at 20 to 25 C. The precipitate formed is filtered off and washed with saturated sodium chloride solution and then dried at about 30 C. under reduced pressure.
100 parts of cotton are dyed for 45 minutes at 40 C. in a bath which contains in 2000 parts of water 3 parts of the resulting product and parts of sodium chloride. 30 parts of trisodium phosphate are added and the temperature is kept for another 45 minutes at 40 C. The
cotton is then thoroughly rinsed in cold and in hot water and soaped for 15 minutes at the boil, to yield a deep red dyeing which has good properties of fastness.
Example 36 1.5 parts of the dyestuff of the formula shown in Example 2 are dissolved in 25 parts of boiling water. A dyebath is prepared from this solution in admixture with a solution of 60 parts of sodium chloride in 750 parts of waterand 50 parts of cotton yarn are dyed in it for 30 minutes at 40 C. The dyestuff deposited on the fiber is then fixed with addition of 0.04 part of one of the hydrazine compounds of the formulae and of 15 parts of tris'odium phosphate, in the same bath for 1 /2 hours at 40 C. The yarn is then thoroughly rinsed in cold and in hot water and finally soaped at the boil. A strong red dyeing is obtained.
Example 3 7 A cotton fabric is impregnated at room temperature with a padding solution which contains in 1000 parts of water Parts Dyestufi mentioned in Example 1 30 Urea 50 Sodium bicarbonate and 20 N:N-dimethylhydrazine 1.5
Without undergoing an intermediate drying the fabric is then steamed for 20 seconds at 120 C. in a high-temperature ager and then finished off in known manner. A blue dyeing is obtained which is fast to washing at the boil and is distinctly stronger than a dyeing produced without adding NzN-dimethylhydrazine.
When the padded fabric is dried before being subjected to the high-temperature steam treatment and N2N-dimethylhydrazine is used, a similar, good result is achieved.
What is claimed is:
1. Process for coloring cellulose fibrous and nitrogenous materials with reactive dyestuff compounds which comprises applying to the fibrous material an aqueous preparation containing a member selected from the group consisting of (a) a non-quaternized reactive dyestuff compound and a hydrazine compound containing at least one tertiary nitrogen atom, said hydrazine compound being present in an amount of from about 0.1% to about 10% by weight on the weight of the dyestuif.
(b) a reactive dyestuff compound quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
(c) a non-quaternized reactive dyestufi compound and a reactive dyestufi compound quaternized with a bynitrogen atom.
2. Process for coloring cellulose fibrous and nitrogenous materials with reactive dyestuff compounds which comprises applying to the fibrous material an aqueous preparation containing a member selected from the group consisting of (a) a non-quaternized reactive dyestutf compound and a hydrazine compound containing at least one tertiary nitrogen atom, said hydrazine compound being present in an amount of from about 0.1% to about 10% by weight on the weight of the dyestuif.
(b) a reactive dyestufi compound quaternized with a hydrazine compound containing at least one tertiary nitrogen atom and (c) a non-quaternized reactive dyestuff compound and a reactive dyestuff compound quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
3. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom, which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive halogen atom and from about 0.2% to 2% by weight based on the weight of the dyestutf of a hydrazine compound containing at least one tertiary nitrogen atom.
4. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom, which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive halogen atom quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
5. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive halogen atom, which comprises applying to the fibrous material an aqueous preparation containing a nonquaternized dyestulf with at least one reactive halogen atom and a dyestufi with at least one reactive halogen atom quaternized with a hydrazine compound containing at least one tertiary nitrogen atom.
6. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by weight based on the weight of the dyestufi of a hydrazine compound of the formula R2 wherein R and R are members selected from the group consisting of alkyl radicals with at most 4 carbon atoms and alkylene members of the same saturated nitrogen-containing, at most siX-membered, heterocyclic ring, and R is a member selected from the group consisting of hydrogen and alkyl radicals with at most 4 carbon atoms.
7. Process for coloring cellulose fibrous and nitroge nous materials with dyestuffs containing at least one reac tive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by weight based on the weight of the dyestuff of a hydrazine compound of the formula (CmH2m+1) pr 2p1) N-N (C H2n'H) \H- wherein m and n are whole numbers of at most 4 and p is a whole number of at most 5.
8. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and from about 0.2% to 2% by Weight based on the weight of the dyestuif of N:N-dimethylhydrazine.
9. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom, which comprises applying to the librous material an aqueous preparation containing a dyestuff with at least one reactive chlorine atom and a hydrazine compound of the formula z). wherein r and s each stands for the whole numbers 3 and 4.
10. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing the dyestuif and from about 0.2% to 2% by weight based on the weight of the dyestuff of 1:5-diaza-bicyclo-(0:3:3)- octane.
11. Process for coloring cellulose fibrous and nitrogenous materials with dyestufis containing at least one reactive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing the dyestuif and from about 0.2% to 2% by Weight based on the weight of the dyestuif of N-amino-N:N-diaza-bicyclo- (2:222) -octane sulfate.
12. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reac' tive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing a nonquaternized dyestuif with at least one reactive chlorine atom and a dyestuif with at least one reactive chlorine atom quaternized with a hydrazine compound of the formula NNH-Rl R2 wherein R and R are members selected from the group consisting of alkyl radicals with at most 4 carbon atoms wherein m and n are whole numbers of at most 4 and p is a whole number of at most 5.
14. Process for coloring cellulose fibrous and nitrogenous materials with dyestuffs containing at least one reactive chlorine atom, which comprises applying to the fibrous material an aqueous preparation containing nonquaternized dyestuff with at least one reactive chlorine atom and dyestuff with at least one reactive chlorine atom quaternized with NzN-dimethylhydrazine.
References Cited UNITED STATES PATENTS 2,190,848 2/ 1940 Petersen et al. 260249.5 2,192,127 2/ 1940 Ebel et -al. 260--249.6 2,235,480 3/1941 Graenacher et a1. 260-2496 2,873,269 2/1959 Fasciati et al 8-l.2 3,004,002 10/1961 Stephen 81.2 3,116,103 12/1963 Gamlen et al. 8-54.2 X
FOREIGN PATENTS 174,377 3/1953 Austria.
NORMAN G. TORCHIN, Primary Examiner. A. H. WINKELSTEIN, Examiner. I. HERBERT, Assistant Examiner.
Claims (1)
1. PROCESS FOR COLORING CELLULOSE FIBROUS AND NITROGENOUS MATERIALS WITH REACTIVE DYESTUFF COMPOUNDS WHICH COMPRISES APPLYING TO THE FIBROUS MATERIAL AN AQUEOUS PREPARATION CONTAINING A MEMBER SELECTED FROM THE GROUP CONSISTING OF (A) A NON-QUATERNIZED REACTIVE DYESTUFF COMPOUND AND A HYDRAZINE COMPOUND CONTAINING AT LEAST ONE TERTIARY NITROGEN ATOMS, SAID HYDRAZINE COMPOUND BEING PRESENT IN AN AMOUNT OF FROM ABOUT 0.1% TO ABOUT 10% BY WEIGHT ON THE WEIGHT OF THE DYESTUFF. (B) A REACTIVE DYESTUFF COMPOUND QUATERNIZED WITH A HYDRAZINE COMPOUND CONTAINING AT LEAST ONE TERTIARY NITROGEN ATOM. (C) A NON-QUATERNIZED REACTIVE DYESTUFF COMPOUND AND A REACTIVE DYESTUFF COMPOUND QUATERNIZED WITH A HYDRAZINE COMPOUND CONTAINING AT LEAST ONE TERTIARY NITROGEN ATOM.
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US3325242A true US3325242A (en) | 1967-06-13 |
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US3325242D Expired - Lifetime US3325242A (en) | Process for dyeing and printing with reactive dyestuffs |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US3413077A (en) * | 1963-10-03 | 1968-11-26 | Acna | Process of dyeing cellulose and polyamide fabrics with reactive dyestuffs |
US3765835A (en) * | 1968-04-25 | 1973-10-16 | Du Pont | Anionic dispersion of a salt of a cationic dye and a selected arylsulfonate |
US5559215A (en) * | 1994-05-02 | 1996-09-24 | Hoechst Aktiengesellschaft | Black mixture of fibre-reactive azo dyes containing essentially a navy-blue disazo dye and an orange monoazo dye, as well as novel fibre-reactive phenylazonaphthol dyes containing A 2-(2'-sufophenylamino)-4-fluoro-1,3,5-triazin-6-ylamino group |
US20080003176A1 (en) * | 1997-09-02 | 2008-01-03 | Takayoshi Sasaki | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
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US2190848A (en) * | 1936-05-31 | 1940-02-20 | Gen Aniline & Film Corp | Dyeings |
US2192127A (en) * | 1936-11-25 | 1940-02-27 | Gen Aniline & Film Corp | Process of producing fast dyeings |
US2235480A (en) * | 1934-11-13 | 1941-03-18 | Soc Of Chemical Ind | Amidelike derivatives and process of making the same |
AT174377B (en) * | 1951-09-10 | 1953-03-25 | Chemie Linz Ag | Process for the preparation of new heterocyclic compounds substituted by quaternary ammonium groups |
US2873269A (en) * | 1956-09-14 | 1959-02-10 | Ciba Ltd | Monoazo-dyestuffs |
US3004002A (en) * | 1958-05-26 | 1961-10-10 | American Cyanamid Co | Homopolymers of 1,3 bis-(hydroxymethyl) 2-imidazolidones or imidazolithiones |
US3116103A (en) * | 1959-09-24 | 1963-12-31 | Ici Ltd | Textile colouration process |
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US2235480A (en) * | 1934-11-13 | 1941-03-18 | Soc Of Chemical Ind | Amidelike derivatives and process of making the same |
US2190848A (en) * | 1936-05-31 | 1940-02-20 | Gen Aniline & Film Corp | Dyeings |
US2192127A (en) * | 1936-11-25 | 1940-02-27 | Gen Aniline & Film Corp | Process of producing fast dyeings |
AT174377B (en) * | 1951-09-10 | 1953-03-25 | Chemie Linz Ag | Process for the preparation of new heterocyclic compounds substituted by quaternary ammonium groups |
US2873269A (en) * | 1956-09-14 | 1959-02-10 | Ciba Ltd | Monoazo-dyestuffs |
US3004002A (en) * | 1958-05-26 | 1961-10-10 | American Cyanamid Co | Homopolymers of 1,3 bis-(hydroxymethyl) 2-imidazolidones or imidazolithiones |
US3116103A (en) * | 1959-09-24 | 1963-12-31 | Ici Ltd | Textile colouration process |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US3413077A (en) * | 1963-10-03 | 1968-11-26 | Acna | Process of dyeing cellulose and polyamide fabrics with reactive dyestuffs |
US3765835A (en) * | 1968-04-25 | 1973-10-16 | Du Pont | Anionic dispersion of a salt of a cationic dye and a selected arylsulfonate |
US5559215A (en) * | 1994-05-02 | 1996-09-24 | Hoechst Aktiengesellschaft | Black mixture of fibre-reactive azo dyes containing essentially a navy-blue disazo dye and an orange monoazo dye, as well as novel fibre-reactive phenylazonaphthol dyes containing A 2-(2'-sufophenylamino)-4-fluoro-1,3,5-triazin-6-ylamino group |
US20080003176A1 (en) * | 1997-09-02 | 2008-01-03 | Takayoshi Sasaki | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US20080008645A1 (en) * | 1997-09-02 | 2008-01-10 | Takayoshi Sasaki | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US20080031807A1 (en) * | 1997-09-02 | 2008-02-07 | Takayoshi Sasaki | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US7531160B2 (en) | 1997-09-02 | 2009-05-12 | Ishihara Sangyo Kaisha, Ltd. | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US7943114B2 (en) | 1997-09-02 | 2011-05-17 | Ishihara Sangyo Kaisha, Ltd. | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US7947249B2 (en) | 1997-09-02 | 2011-05-24 | Ishihara Sangyo Kaisha, Ltd. | Fine hollow powder, thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
US8163386B1 (en) | 1997-09-02 | 2012-04-24 | Ishihara Sangyo Kaisha, Ltd. | Fine hollow powder thin flaky titanium oxide powder obtained by pulverization of the fine hollow powder and processes for producing the same |
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