US3176844A - Control apparatus - Google Patents

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US3176844A
US3176844A US95569A US9556961A US3176844A US 3176844 A US3176844 A US 3176844A US 95569 A US95569 A US 95569A US 9556961 A US9556961 A US 9556961A US 3176844 A US3176844 A US 3176844A
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water
impedance
ion exchange
exchange material
temperature
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US95569A
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David E Nelson
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Honeywell Inc
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Honeywell Inc
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    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D27/00Simultaneous control of variables covered by two or more of main groups G05D1/00 - G05D25/00
    • G05D27/02Simultaneous control of variables covered by two or more of main groups G05D1/00 - G05D25/00 characterised by the use of electric means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/80Automatic regeneration
    • B01J49/85Controlling or regulating devices therefor

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  • the present invention is concerned with an improvement in control apparatus for use with a water-softening system; in particular, the invention relates to the use of a device which senses the change in impedance of the ion exchange ⁇ material used in the water softener wherein the eiects of a change in impedance of the water due to temperature or ion concentration have no eifect upon an output resulting from the change in impedance of the ion exchange material.
  • the ion exchange material In the water-softening apparatus in which hard water is passed through a tank containing an ion exchange material for removing the hard ions from the water, the ion exchange material eventually needs to be recharged or regenerated.
  • salt or sodium soft ions are introduced into thevion exchange material passing salt water through the ion exchange material.
  • One of these means makes use of the change in impedance of the ion exchange material, and since the impedance of the water can change due to variations in the ion concentration or temperature, these parameters must be compensated for, to prevent a regeneration or recharging cycle when regeneration of the ion exchange material is not necessary.
  • the impedance of the ion exchange material surrounded by Water is sensed by a pair of electrodes inserted into the water softener tank. Since the impedance of the water changes with variations in ion concentration or temperature, a second set of electrodes forming a water cell, which is associated with the water but separated from the ion exchange material, is used to offset the eifect of the change in impedance of the Water on the ion exchange material cell.
  • the output of the water cell In order to have the water cell completely compensate for the effects of the change in impedance of the water on the output of the io-n exchange material cell, the output of the water cell must be made to correspond with the output of the ion exchange material cell as afected by the parameters other than the impedance of the ion exchange material. Since the eifect of the change in impedance of the water due to temperature is different than the change in impedance of the Water due to changes in ion concentration, the network cannot be made to fully compensate for the eifect of the water on the ion ex-v change material cell by the use of a single vwater cell.
  • the present invention is concerned with the use of at least one temperature responsive impedance means which responds to a temperature indicative of the temperature of the water.
  • the output of the responsive means is used to modify the effect of temperature on the compensation for the changes in impedance of the water on the ion exchange material cell.
  • a bridge network has an ion exchange material cell in one branch of the circuit so that the impedance of the branch changes as the impedance of the ion exchange material changes or the impedance of the water changes due to variations in either ion concentration or temperature.
  • a second branch of the bridge network has a Water cell which responds to the impedance of the water as it changes due to changes in ion concentration or temperature.
  • the second branch has its output modified by the impedance change of a network having a temperature responsive impedance element which senses the water temperature.
  • An object of the present invention is to provide an improved control apparatus for controlling the regeneration of a water softener wherein the regeneration cycle is controlled by the impedance of the ion exchange material and the impedance changes of the water due to variations in ion concentration or temperature are made ineffective.
  • Another object of the present invention is to provide an improved control apparatus for controlling theregeneration cycle of a water softener wherein a rst sensor responds to the impedance of the ion exchange material and the water in a water softening tank, a second sensor responds to the impedance of the water as it changes due to a change in ion concentration or temperature, and a third sensor responds to the temperature of the water; so that, when the outputs of the three sensors are combined, no effect by any change in impedance of the water is obtained in controlling associated regeneration apparatus.
  • FIGURE l is a schematic drawing of a typical water softening system wherein a tank contains an ion exchange material and a sensor that responds to the effectiveness' of the ion exchange material to initiate a regeneration cycle.
  • FIGURE 2 is a schematic showing of a second embodiment of a sensor.
  • a tank 10 contains a Water softening resin or ion exchange material l1.
  • the material is commonly available and has the characteristic of replacing certain hard elements or ions in the water, such as calcium, magnesium and other elements, by soft elements or ions, such as sodium which tends to reduce the hardness of the water.
  • soft elements or ions such as sodium which tends to reduce the hardness of the water.
  • organic and inorganic ion exchange materials or resins which exhibit a change in impedance as the soft ions are replaced by hard ions from the Water.
  • One common inorganic ion exchange material is commercially known as Zeolite; however, organic ion exchange materials are numerous and as well known.
  • a regeneration scheduler 12 is a typical valving apparatus for controlling the flow of Water in the system in a predetermined manner.
  • One typical scheduler is shown in the W. I. Hughes Patent 2,012,194 wherein a motor drives a plurality of cams for opening and closing various valves in the water softening system to provide a predetermined sequence of water ow in a time controlled manner.
  • a motor drives a plurality of cams for opening and closing various valves in the water softening system to provide a predetermined sequence of water ow in a time controlled manner.
  • a salt brine tank 21 Connected to the scheduler is a salt brine tank 21 for providing a flow of salt water when water flows through a pipe'22 into tank. 21 to force the saltwater out of the tank through a pipe 23.
  • An exhaustion or ion exchange material sensor 30 is shown inserted in tank 10.
  • the base carries a rst electrode 32 which ⁇ is mounted in the center of the base and projects from ⁇ the ⁇ base to be in contact with the ion exchange material and water in tank 1.0.
  • the second electrode 33 comprises a perforated cylindrical covering for a portion of the base..
  • Electrode 3,3 is in contact with the ion exchange material in water in tank 1d.
  • a third electrode 34 comprises a cylindrical ⁇ covering for a ⁇ portion i exchange material and water.
  • a pair of temperature responsive impedance elements or thermistors 4i) and 41 are mounted in base 31.
  • the thermistors are subjected to the temperature of the base whichl is substantially the temperature of the water in tank 1i).
  • the thermistors or some other suitable temperature responsive elements could be located in some other place to respond to the temperature of the water; however, the temperature of the water as close to the other electrodes 32, 33, and 34 should be measured for proper operation of sensor 30.
  • a bridge network circuit 42 is shown with a source of power 43 connected across terminals 44 and 45.
  • Source of power 43 is a conventional step down transformer.
  • Connected between terminals 44 and 45 are two branch circuits.
  • a rst branch circuit comprises the ion exchange material cell and is traced from terminal 44 through a conductor 50, electrode 33, the ion exchange material 11, electrode 32, a conductor 51, a terminal 52,
  • a second branch is traced as follows: from terminal 44, a resistor 54,
  • VAn output is available from network circuit 42 between terminals 52 and 63.
  • the output is connected to an amplifier relay 70 by conductors 71 and 72.
  • the ampliiier-relay 76 is of a conventional type such as disclosed in :the Wilson Patent 2,420,578.
  • the Ioutput is amplifiedto control the operation of a relay for closing a circuit between conductor '73 and conductor 74 connected to scheduling device 12.
  • the scheduling device is started to run the regeneration operation through a complete cycle to regenerate the ion exchange material 11 in the tank 19.
  • resistors 53 and 64 may be replaced by the coils of a balance type relay.
  • FIGURE 2 a second embodiment of an exhaustion sensor 130 is shown.
  • the sensor has a body 131 for supporting an electrode 132 which is in contact with the water and ion exchange material when the sensor Yis inserted in a water softener tank.
  • An electrode 133 Y which is made up of a perforated cylindrical member surrounding body 131 is also in contact with the ion Electrodes 132 and 133 are adapted to be connected to make up an ion exchange material cell.
  • Electrode 134 which comprises a cylindrical member mounted in chamber 135 is in contact with the water only as fthe water is able to ilow through the perforations of electrode 133.
  • a pair of temperature responsive elements or thermistors 140 and 141 are shown mounted in base 131 to respond to the temperature of the base and thus to the temperature of the water to which electrodes 132, 133, and 134 are exposed.
  • the recharging or regeneration operation of a water softener is quite conventional. After the hard water owing from supply 13 through pipe 14 into tank 19 has delivered a certain amount of soft water from pipe 15 to the soft water supply pipe 20, the impedance of the ion exchange material 11 in tank 1t) will change. When the impedance of the ion exchange material reaches a predetermined value, the effectiveness of the ion exchange material is depleted and a regeneration operation is needed.
  • the scheduling device 12 is initiated to provide a valving sequence to recharge the ion exchange material in the following manner over a predetermined period of time. Once device 12 is energized, a complete regeneration cycle is made before sensor 36 is again placed in control of scheduler 12.
  • Hard water from supply 13 is passed back through tank 1? by way of pipe 15 and pipe 14Y to a drain to flush out the foreign deposits in the tank.
  • the hard water supply 13 is connected to pipe 22 to deliver salt water from pipe 23 into the tank through pipe 14.
  • the salt water passes through tank 1i) and out of drain 83.
  • the scheduling device provides for the rinsing of all the salt out of tank 10 by supplying hard Water from pipe 13 through pipe 14 so the excess salt water is passed out of the drain Si).
  • the -output of circuit 42 is etiective to commence the regeneration operation whenever the impedance of the material reaches some predeterminedl value. Since the impedance between 'the electrodes 32 and 33 is also affected by the impedanceof the water as well as other parameters, the impedance of the water must be taken intoaccount. A water cell made up of electrodes 34 and 33 is connected into network circuit 42 ⁇ to oppose the impedance of the ion exchange material.
  • the eifccts of a change in temperature on Vthe impedance of water is not completely compensated.
  • thermistors 40 and 41 the characteristics of the water cell made up of electrodes 33 and 34 are modified to have an output which canbe used to compensate for the effects of the change in impedance of the water due to either ion concentration or temperature on the resin cell.
  • An increase in temperature of the water and ion exchange material results in an increase in the resistance of both the watery and the ion exchange material.
  • the relative resistance or impedance of the water and ion exchange material has quite a spread as the water resistance Iis quite high and the ion exchange material or resin has a very low resistance. While the change in resistance for a given temperature change may be the same percentage for both the water and resin, when the two resistances are connected in parallel, the efiect of the change in temperature upon the combined resistance is not linear.
  • the resistance between electrodes 32 and 33 -due to the ion to the water is high.
  • the resistance of both the ion exchange material and the water may drop but ⁇ the combined resistance between electrodes 32 and 33 is not proportional to the change in resistance of the water alone as would be measured by the resistance between electrodes 33 and 34 for the same temperature change.
  • the relative size of electrode 32 of the resin cell and electrode 34 of .the water cell has been ⁇ selected to more eiectively match the cells to have a similar change in resistance as temperature changes, 'but the best match is not obtained with the water ...ses 1l arrasar cell alone.
  • the resistance change between conductor 61 and terminal 44 has a characteristic similiar to the resistance change of .the water and resin between electrodes 32 and 33 as eiected by a change ⁇ in temperature whereby the output of sensor 30 is only a measure of the change in resistance of the ion exchange material 11 due -to a change in its ion content.
  • a regeneration control device must be made to control the regeneration process whenever the ⁇ impedance of the ion exchange material reaches some predetermined value.
  • the regeneration process may be started too soon or too late which can have detrimental effects upon the ion exchange material as Well as the 'bringing about of unnecessary regeneration operation.
  • the softener can be placed in any locality which might have a water which changes in ion concentration and in temperature throughout the seasons. As the temperature and ion concentration of the water changes, the impedance change due to these parameters would have no effect upon the -measurements of the impedance of the ⁇ ion exchange material.
  • the operation of the system with exhaustion sensor 1130 as shown in FIGURE 2, when connected in the network of FIGURE 1, is the same as exhaustion Sensor 30.
  • the sensor 130 is adapted to be screwed into the side of a water softening tank, and electrodes 132, 133, and 134 would be connected to the network support 42 in the same manner as electrodes 32, 33, and 34 of sensor 30.
  • Thermistors 140 and 141 are also adapted to be connected into a support suc-h as support 42 in FIGURE 1 in the same manne-r as thermistors 4t] and 41 of exhaustion sensor 30.
  • an electrical network circuit having two lbranches. and an output circuit which has an output signal depending upon the relation of the impedance of said branches, first and second electrodes mounted in the ion exchange material and water of the water softener to be respon-sive to the impedance of the ion exchange material and the Water in the softener, means connecting said first and second electrodes in said first branch, a third electrode mounted in a chamber connected to contain only water trom the softener, said second and third electrodes being responsive to the impedance of the water in the softener, said first electrode having a smaller area than said thi-rd electrode, a temperature responsive means having an impedance which varies with temperature, said temperature responsive means being mounted to respond to the temperature of the water and ion exchange material in the softener, means connecting said second and third electrodes and said responsive
  • an electrical network circuit having two branches and an output circuit which has an output signal depending upon the relation of the impedance of said branches, first impedance responsive means responsive to the impedance of the ion exchange material and the IWater in the softener, means connecting said first means in said first branch, second impedance responsive means responsive to the impedance of the water in the softener, first and -second temperature responsive means having an impedance Which varies inversely with temperature, said first and second responsive means Ibeing mounted to respond to the temperature of the water in said softener, means connecting said first temperature responsive means in series with said second impedance responsive means in said second branch, means connecting said second temperature responsive means :in parallel with said second impedance responsive means whereby the effects of changes of the impedance of the water due Ito changes ot molalities and temperature on said first impedance responsive means can
  • a control system for controlling the regeneration of a water softener having a bed of ion exchange material through which water fiows, ⁇ first electrode means mounted in said bed and responsive to the impedance of the ion exchange material and the water in said sof-tener, second electrode means mounted in said bed and responsive to the impedance of only the water in said softener, third means responsive to the temperature of the water and i-on exchange material in said softener, a regeneration apparatus for said water softener, control means adapted to control a regeneration operation of said apparatus of said softener, and electrical circuit means connect-ing said first, second, and third means to said control means and adapted to compensate for the effects of a change in temperature and ion content of the water and the effect of ⁇ temperature on the ion exchange material whereby said regeneration apparatus is placed in operation when the ion exchange material reaches a predetermined impedance indicative of the depletion of its water softening capabilities.

Description

April 6, 1965 D. E. NELSON 3,176,844
CONTROL APPARATUS Filed March 14. 1961 INVENTOR.
24T/1D E'. NELSON 2 BWMM ATTOENE'Y UnitedStates Patent O 3,176,844 CNTRGL APPARATUS David E. Nelson, Bloomington, Minn., assigner to Honeywell Inc., a corporation of Delaware Filed Mar. 14, 1961, Ser. No. 95,569 3 Claims. (Cl. 21o- 96) The present invention is concerned with an improvement in control apparatus for use with a water-softening system; in particular, the invention relates to the use of a device which senses the change in impedance of the ion exchange `material used in the water softener wherein the eiects of a change in impedance of the water due to temperature or ion concentration have no eifect upon an output resulting from the change in impedance of the ion exchange material.
In the water-softening apparatus in which hard water is passed through a tank containing an ion exchange material for removing the hard ions from the water, the ion exchange material eventually needs to be recharged or regenerated. To recharge or regenerate the ion exchange material, salt or sodium soft ions are introduced into thevion exchange material passing salt water through the ion exchange material. There are various means of initiating the regeneration operation of a lwater softener. One of these means makes use of the change in impedance of the ion exchange material, and since the impedance of the water can change due to variations in the ion concentration or temperature, these parameters must be compensated for, to prevent a regeneration or recharging cycle when regeneration of the ion exchange material is not necessary.
In such control systems, the impedance of the ion exchange material surrounded by Water is sensed by a pair of electrodes inserted into the water softener tank. Since the impedance of the water changes with variations in ion concentration or temperature, a second set of electrodes forming a water cell, which is associated with the water but separated from the ion exchange material, is used to offset the eifect of the change in impedance of the Water on the ion exchange material cell.
In order to have the water cell completely compensate for the effects of the change in impedance of the water on the output of the io-n exchange material cell, the output of the water cell must be made to correspond with the output of the ion exchange material cell as afected by the parameters other than the impedance of the ion exchange material. Since the eifect of the change in impedance of the water due to temperature is different than the change in impedance of the Water due to changes in ion concentration, the network cannot be made to fully compensate for the eifect of the water on the ion ex-v change material cell by the use of a single vwater cell.
The present invention is concerned with the use of at least one temperature responsive impedance means which responds to a temperature indicative of the temperature of the water. The output of the responsive means is used to modify the effect of temperature on the compensation for the changes in impedance of the water on the ion exchange material cell. Specilically, a bridge network has an ion exchange material cell in one branch of the circuit so that the impedance of the branch changes as the impedance of the ion exchange material changes or the impedance of the water changes due to variations in either ion concentration or temperature. A second branch of the bridge network has a Water cell which responds to the impedance of the water as it changes due to changes in ion concentration or temperature. The second branch has its output modified by the impedance change of a network having a temperature responsive impedance element which senses the water temperature.
ICC
An object of the present invention is to provide an improved control apparatus for controlling the regeneration of a water softener wherein the regeneration cycle is controlled by the impedance of the ion exchange material and the impedance changes of the water due to variations in ion concentration or temperature are made ineffective.
Another object of the present invention is to provide an improved control apparatus for controlling theregeneration cycle of a water softener wherein a rst sensor responds to the impedance of the ion exchange material and the water in a water softening tank, a second sensor responds to the impedance of the water as it changes due to a change in ion concentration or temperature, and a third sensor responds to the temperature of the water; so that, when the outputs of the three sensors are combined, no effect by any change in impedance of the water is obtained in controlling associated regeneration apparatus.
These and other objects of the present invention will become apparent upon the study of the specification and drawing, of which:
FIGURE l is a schematic drawing of a typical water softening system wherein a tank contains an ion exchange material and a sensor that responds to the effectiveness' of the ion exchange material to initiate a regeneration cycle.
FIGURE 2 is a schematic showing of a second embodiment of a sensor.
Referring to FIGURE 1, a typical water softener system is shown. A tank 10 contains a Water softening resin or ion exchange material l1. The material is commonly available and has the characteristic of replacing certain hard elements or ions in the water, such as calcium, magnesium and other elements, by soft elements or ions, such as sodium which tends to reduce the hardness of the water. There are various organic and inorganic ion exchange materials or resins which exhibit a change in impedance as the soft ions are replaced by hard ions from the Water. One common inorganic ion exchange material is commercially known as Zeolite; however, organic ion exchange materials are numerous and as well known.
A regeneration scheduler 12 is a typical valving apparatus for controlling the flow of Water in the system in a predetermined manner. One typical scheduler is shown in the W. I. Hughes Patent 2,012,194 wherein a motor drives a plurality of cams for opening and closing various valves in the water softening system to provide a predetermined sequence of water ow in a time controlled manner. For example, during normal operation, hard water Hows from the hard water supply through a pipe 13, scheduler 12, a `pipe 14, tank 10, a pipe 15, and back to t a pipe 20 to supply soft water for domestic purposes or for Whatever the soft Water is used.` Connected to the scheduler is a salt brine tank 21 for providing a flow of salt water when water flows through a pipe'22 into tank. 21 to force the saltwater out of the tank through a pipe 23. t
An exhaustion or ion exchange material sensor 30 is shown inserted in tank 10. Sensor Sllcomprises a base 31 which isscrewed into tank 10. The base carries a rst electrode 32 which `is mounted in the center of the base and projects from `the` base to be in contact with the ion exchange material and water in tank 1.0. The second electrode 33 comprises a perforated cylindrical covering for a portion of the base.. Electrode 3,3 is in contact with the ion exchange material in water in tank 1d. When electrodes 32 and 33 are electrically connected, an ion exchange material or `resin `cell is formed `which measures the impedance of the ion exchange material, the water, and any other parameters which aifect the impedance between electrodes 32 and 33. A third electrode 34 comprises a cylindrical` covering for a` portion i exchange material and water.
arras/ia `When electrode 34 and electrode 33 are connected, a
water cell isV formed which provides an output as a measure of the impedance of the water due to ion concentration and other parameters.
A pair of temperature responsive impedance elements or thermistors 4i) and 41 are mounted in base 31. The thermistors are subjected to the temperature of the base whichl is substantially the temperature of the water in tank 1i). Obviously, the thermistors or some other suitable temperature responsive elements could be located in some other place to respond to the temperature of the water; however, the temperature of the water as close to the other electrodes 32, 33, and 34 should be measured for proper operation of sensor 30.
A bridge network circuit 42 is shown with a source of power 43 connected across terminals 44 and 45. Source of power 43 is a conventional step down transformer. Connected between terminals 44 and 45 are two branch circuits. A rst branch circuit comprises the ion exchange material cell and is traced from terminal 44 through a conductor 50, electrode 33, the ion exchange material 11, electrode 32, a conductor 51, a terminal 52,
. a resistor 53, and back to terminal 45. A second branch is traced as follows: from terminal 44, a resistor 54,
conductor 55, thermistor 40, a conductor 60, thermistor 41, a conductor 61, a resistor 62, a terminal 63, a resistor 64, and back to terminal 45. Connected in parallel with resistor 54 and thermistor 4u is the Water cell as traced Yfrom conductor 61B, conductor 70, electrode 34, electrode 33, and back to terminal 44.
VAn output is available from network circuit 42 between terminals 52 and 63. The output is connected to an amplifier relay 70 by conductors 71 and 72. The ampliiier-relay 76 is of a conventional type such as disclosed in :the Wilson Patent 2,420,578. When the output of the network circuit 42 reaches a predetermined value, the Ioutput is amplifiedto control the operation of a relay for closing a circuit between conductor '73 and conductor 74 connected to scheduling device 12. When the circuit is closed, the scheduling device is started to run the regeneration operation through a complete cycle to regenerate the ion exchange material 11 in the tank 19. While .the network circuit 42 is shown as a conventional circuit, there are other types lof circuits which would be equally applicable for comparing electrical signals and providing an operation of a circuit closing means when a predetermined unbalance of the signal exists. For example, resistors 53 and 64 may be replaced by the coils of a balance type relay.
Referring to FIGURE 2, a second embodiment of an exhaustion sensor 130 is shown. The sensor has a body 131 for supporting an electrode 132 which is in contact with the water and ion exchange material when the sensor Yis inserted in a water softener tank. An electrode 133 Y which is made up of a perforated cylindrical member surrounding body 131 is also in contact with the ion Electrodes 132 and 133 are adapted to be connected to make up an ion exchange material cell. Electrode 134 which comprises a cylindrical member mounted in chamber 135 is in contact with the water only as fthe water is able to ilow through the perforations of electrode 133. When electrodes 133 and 134 are connected, a Water cell is formed. A pair of temperature responsive elements or thermistors 140 and 141 are shown mounted in base 131 to respond to the temperature of the base and thus to the temperature of the water to which electrodes 132, 133, and 134 are exposed.
Operation The recharging or regeneration operation of a water softener is quite conventional. After the hard water owing from supply 13 through pipe 14 into tank 19 has delivered a certain amount of soft water from pipe 15 to the soft water supply pipe 20, the impedance of the ion exchange material 11 in tank 1t) will change. When the impedance of the ion exchange material reaches a predetermined value, the effectiveness of the ion exchange material is depleted and a regeneration operation is needed. Upon the energization of relay 70, the scheduling device 12 is initiated to provide a valving sequence to recharge the ion exchange material in the following manner over a predetermined period of time. Once device 12 is energized, a complete regeneration cycle is made before sensor 36 is again placed in control of scheduler 12. Hard water from supply 13 is passed back through tank 1? by way of pipe 15 and pipe 14Y to a drain to flush out the foreign deposits in the tank. After a predetermined backwash operation, the hard water supply 13 is connected to pipe 22 to deliver salt water from pipe 23 into the tank through pipe 14. The salt water passes through tank 1i) and out of drain 83. When the salt water is in contact with ion exchange material 11, the hard ions collected in the ion exchange material are replaced by soft ions so the ion kexchange material is recharged. A further operation ofthe scheduling device provides for the rinsing of all the salt out of tank 10 by supplying hard Water from pipe 13 through pipe 14 so the excess salt water is passed out of the drain Si).
Since the impedance of the ion exchange material is measured by the impedance between electrodes 32 and 33, the -output of circuit 42 is etiective to commence the regeneration operation whenever the impedance of the material reaches some predeterminedl value. Since the impedance between 'the electrodes 32 and 33 is also affected by the impedanceof the water as well as other parameters, the impedance of the water must be taken intoaccount. A water cell made up of electrodes 34 and 33 is connected into network circuit 42 `to oppose the impedance of the ion exchange material. Since the water cell impedance which is determined by the impedance of the water itself must be made to exactly compensate for the effect of the water impedance, the eifccts of a change in temperature on Vthe impedance of water is not completely compensated. By means of thermistors 40 and 41, the characteristics of the water cell made up of electrodes 33 and 34 are modified to have an output which canbe used to compensate for the effects of the change in impedance of the water due to either ion concentration or temperature on the resin cell.
An increase in temperature of the water and ion exchange material results in an increase in the resistance of both the watery and the ion exchange material. The relative resistance or impedance of the water and ion exchange material has quite a spread as the water resistance Iis quite high and the ion exchange material or resin has a very low resistance. While the change in resistance for a given temperature change may be the same percentage for both the water and resin, when the two resistances are connected in parallel, the efiect of the change in temperature upon the combined resistance is not linear. The resistance between electrodes 32 and 33 -due to the ion to the water is high. When the temperature of the water and thus the temperature of the ion exchange material increases, the resistance of both the ion exchange material and the water may drop but `the combined resistance between electrodes 32 and 33 is not proportional to the change in resistance of the water alone as would be measured by the resistance between electrodes 33 and 34 for the same temperature change. The relative size of electrode 32 of the resin cell and electrode 34 of .the water cell has been `selected to more eiectively match the cells to have a similar change in resistance as temperature changes, 'but the best match is not obtained with the water ...ses 1l arrasar cell alone. By placing the thermistors 40 and 41 which have a negative temperature coefiicient of resistance in the circuit with the electrodes 33 and 34, the resistance change between conductor 61 and terminal 44 has a characteristic similiar to the resistance change of .the water and resin between electrodes 32 and 33 as eiected by a change `in temperature whereby the output of sensor 30 is only a measure of the change in resistance of the ion exchange material 11 due -to a change in its ion content. rThe importance of the applicants contribution to the water softening control system is quite significant since a regeneration control device must be made to control the regeneration process whenever the `impedance of the ion exchange material reaches some predetermined value. If some other parameter affects the impedance measurement, the regeneration process may be started too soon or too late which can have detrimental effects upon the ion exchange material as Well as the 'bringing about of unnecessary regeneration operation. When a control apparatus having the sensor 30 is used, the softener can be placed in any locality which might have a water which changes in ion concentration and in temperature throughout the seasons. As the temperature and ion concentration of the water changes, the impedance change due to these parameters would have no effect upon the -measurements of the impedance of the `ion exchange material.
The operation of the system with exhaustion sensor 1130 as shown in FIGURE 2, when connected in the network of FIGURE 1, is the same as exhaustion Sensor 30. The sensor 130 is adapted to be screwed into the side of a water softening tank, and electrodes 132, 133, and 134 would be connected to the network support 42 in the same manner as electrodes 32, 33, and 34 of sensor 30. Thermistors 140 and 141 are also adapted to be connected into a support suc-h as support 42 in FIGURE 1 in the same manne-r as thermistors 4t] and 41 of exhaustion sensor 30.
While the invention Ihas been described in one particular manner, the :intention is to limit the scope of the invention only by the appended claims of which I claim:
1. In a control system -for controlling the regeneration operation of a water softener wherein an ion exchange material which changes in impedance is used to soften water as Water passes therethrough, an electrical network circuit having two lbranches. and an output circuit which has an output signal depending upon the relation of the impedance of said branches, first and second electrodes mounted in the ion exchange material and water of the water softener to be respon-sive to the impedance of the ion exchange material and the Water in the softener, means connecting said first and second electrodes in said first branch, a third electrode mounted in a chamber connected to contain only water trom the softener, said second and third electrodes being responsive to the impedance of the water in the softener, said first electrode having a smaller area than said thi-rd electrode, a temperature responsive means having an impedance which varies with temperature, said temperature responsive means being mounted to respond to the temperature of the water and ion exchange material in the softener, means connecting said second and third electrodes and said responsive means in said second branch whereby the effects of changes of the impedance of the water ldue to changes in ion concentration or temperature and of the impedance of the ion exchange material due to changes in tempera- "ture can be compensated and said output is determined only by the impedance change of the -ion exchange material due to a change in ion content, control means adapted to control the regeneration cycle of the water softener, and means connecting said output circuit to said control means to start the regeneration operation when the impedance of the ion exchange material reaches a predetermined value.
2. in a control system for controlling the regeneration operation of a water softener wherein an ion exchange material which changes in impedance is used to soften water as water passes therethrough, an electrical network circuit having two branches and an output circuit which has an output signal depending upon the relation of the impedance of said branches, first impedance responsive means responsive to the impedance of the ion exchange material and the IWater in the softener, means connecting said first means in said first branch, second impedance responsive means responsive to the impedance of the water in the softener, first and -second temperature responsive means having an impedance Which varies inversely with temperature, said first and second responsive means Ibeing mounted to respond to the temperature of the water in said softener, means connecting said first temperature responsive means in series with said second impedance responsive means in said second branch, means connecting said second temperature responsive means :in parallel with said second impedance responsive means whereby the effects of changes of the impedance of the water due Ito changes ot molalities and temperature on said first impedance responsive means can be compensated and said output is determined 'only by the impedance change of the ion exchange material due -to a change in ion content, and -control means adapted to control the regeneration cycle of the water softener, and means connecting said output circuit to said control means to start the regeneration operation when said output reaches a predetermined value.
3. In a control system for controlling the regeneration of a water softener having a bed of ion exchange material through which water fiows, `first electrode means mounted in said bed and responsive to the impedance of the ion exchange material and the water in said sof-tener, second electrode means mounted in said bed and responsive to the impedance of only the water in said softener, third means responsive to the temperature of the water and i-on exchange material in said softener, a regeneration apparatus for said water softener, control means adapted to control a regeneration operation of said apparatus of said softener, and electrical circuit means connect-ing said first, second, and third means to said control means and adapted to compensate for the effects of a change in temperature and ion content of the water and the effect of `temperature on the ion exchange material whereby said regeneration apparatus is placed in operation when the ion exchange material reaches a predetermined impedance indicative of the depletion of its water softening capabilities.
References Cited by the Examiner UNITED STATES PATENTS 2,083,074 6/37 Maass 324--30 2,450,459 10/48 Thomson 324--30 2,560,209 7/51 Borell et al 324-30 2,586,169 2/52 Kline 137-93 2,627,503 2/53 Anderson 210--190 2,628,194 2/53 Gilwood 210-98 2,834,937 5/58 Raynor 324--30 2,851,654 9/58 Haddad 324-30 FOREIGN PATENTS 714,642 9/ 54 Great Britain.
REUBEN FRIEDMAN, Primary Examiner.
HARRY B. THORNTON, HERBERT L. MARTIN,
Examiners.

Claims (1)

1. IN A CONTROL SYSTEM FOR CONTROLLING THE REGENERATION OPERATION OF A WATER SOFTNER WHEREIN AN ION EXCHANGE MATERIAL WHICH CHANGES IN IMPEDANCE IS USED TO SOFTEN WATER AS WATER PASSES THERETHROUGH, AN ELECTRICAL NETWORK CIRCUIT HAVING TWO BRANCHES AND AN OUTPUT CIRCUIT WHICH HAS AN OUTPUT SIGNAL DEPENDING UPON THE RELATION OF THE IMPEDANCE OF SAID BRANCHES, FIRST AND SECOND ELECTRODES MOUNTED IN THE ION EXCHANGE MATERIAL AND WATER OF THE WATER SOFTENER TO BE RESPONSIVE TO THE IMPEDANCE OF THE ION EXCHANGE MATERIAL AND THE WATER IN THE SOFTENER, MEANS CONNECTING SAID FIRST AND SECOND ELECTRODES IN SAID FIRST BRANCH, A THIRD ELECTRODE MOUNTED IN A CHAMBER CONNECTED TO CONTAIN ONLY WATER FROM THE SOFTENER, SAID SECOND AND THIRD ELECTRODES BEING RESPONSIVE TO THE IMPEDANCE OF THE WATER IN THE SOFTENER, SAID FIRST ELECTRODE HAVING A SMALLER AREA THAN SAID THIRD ELECTRODE, A TEMPERATURE RESPONSIVE MEANS HAVING AN IMPEDANCE WHICH VARIES WITH TEMPERATURE, SAID TEMPERATURE RESPONSIVE MEANS BEING MOUNTED TO RESPOND TO THE TEMPERATURE OF THE WATER AND
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Cited By (12)

* Cited by examiner, † Cited by third party
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US3355018A (en) * 1964-12-18 1967-11-28 Barnstead Still And Sterilizer Demineralization of water
US3477576A (en) * 1966-10-03 1969-11-11 Honeywell Inc Water softener control
US3618769A (en) * 1968-09-19 1971-11-09 Manuel Adroer Iglesias Apparatus for ion exchange process control
US3768649A (en) * 1971-07-15 1973-10-30 Fleckenstein A J Regeneration sensing system
US4385357A (en) * 1978-04-14 1983-05-24 Water Refining Company, Inc. Water treatment system and control therefor
DE3337169A1 (en) * 1982-10-16 1984-04-19 Yamato Scientific Co., Ltd., Tokyo DEMINERALIZER
US4568465A (en) * 1978-04-14 1986-02-04 Water Refining Company, Inc. Water treatment system and control therefor
US5058032A (en) * 1989-10-23 1991-10-15 Autotrol Corporation Apparatus and method for monitoring a water treatment system
US20060266710A1 (en) * 2005-05-26 2006-11-30 Culligan International Company Service initiation and regeneration control using impedance ratios
EP3114086A4 (en) * 2014-03-06 2017-10-11 The Board of Regents of The University of Texas System Methods and devices for measuring conductivity of fluids
JP2019098317A (en) * 2017-12-07 2019-06-24 水ing株式会社 Pure water manufacturing apparatus and pure water manufacturing method
JP2019155297A (en) * 2018-03-14 2019-09-19 水ing株式会社 Conductivity measuring structure, pure water production apparatus and pure water production method

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US2450459A (en) * 1944-01-13 1948-10-05 Photoswitch Inc Electrode system
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US2083074A (en) * 1935-10-01 1937-06-08 Maass Otto Method and apparatus for determining the consistency of pulp suspensions
US2450459A (en) * 1944-01-13 1948-10-05 Photoswitch Inc Electrode system
US2586169A (en) * 1947-08-04 1952-02-19 Patent Man Inc Apparatus for controlling and measuring the concentration of solutions
US2627503A (en) * 1948-02-24 1953-02-03 Antone D Elmer Water softener
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3355018A (en) * 1964-12-18 1967-11-28 Barnstead Still And Sterilizer Demineralization of water
US3477576A (en) * 1966-10-03 1969-11-11 Honeywell Inc Water softener control
US3618769A (en) * 1968-09-19 1971-11-09 Manuel Adroer Iglesias Apparatus for ion exchange process control
US3768649A (en) * 1971-07-15 1973-10-30 Fleckenstein A J Regeneration sensing system
US4385357A (en) * 1978-04-14 1983-05-24 Water Refining Company, Inc. Water treatment system and control therefor
US4568465A (en) * 1978-04-14 1986-02-04 Water Refining Company, Inc. Water treatment system and control therefor
DE3337169A1 (en) * 1982-10-16 1984-04-19 Yamato Scientific Co., Ltd., Tokyo DEMINERALIZER
US4563272A (en) * 1982-10-16 1986-01-07 Yamato Scientific Co., Ltd. Demineralizer
US5058032A (en) * 1989-10-23 1991-10-15 Autotrol Corporation Apparatus and method for monitoring a water treatment system
US20060266710A1 (en) * 2005-05-26 2006-11-30 Culligan International Company Service initiation and regeneration control using impedance ratios
US7556738B2 (en) 2005-05-26 2009-07-07 Culligan International Company Method for determining the duration of a brine/slow rinse cycle for a water conditioner
EP3114086A4 (en) * 2014-03-06 2017-10-11 The Board of Regents of The University of Texas System Methods and devices for measuring conductivity of fluids
AU2015226950B2 (en) * 2014-03-06 2019-10-31 Thomas A. Davis Methods and devices for measuring conductivity of fluids
AU2020200670B2 (en) * 2014-03-06 2021-06-24 Thomas A. Davis Methods and devices for measuring conductivity of fluids
JP2019098317A (en) * 2017-12-07 2019-06-24 水ing株式会社 Pure water manufacturing apparatus and pure water manufacturing method
JP2019155297A (en) * 2018-03-14 2019-09-19 水ing株式会社 Conductivity measuring structure, pure water production apparatus and pure water production method

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