US2999817A - Azeotropic composition - Google Patents
Azeotropic composition Download PDFInfo
- Publication number
- US2999817A US2999817A US49436A US4943660A US2999817A US 2999817 A US2999817 A US 2999817A US 49436 A US49436 A US 49436A US 4943660 A US4943660 A US 4943660A US 2999817 A US2999817 A US 2999817A
- Authority
- US
- United States
- Prior art keywords
- solvent
- azeotropic composition
- azeotropic
- methylene chloride
- trifluoroethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 32
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 33
- 239000002904 solvent Substances 0.000 description 22
- 238000004140 cleaning Methods 0.000 description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 7
- 230000004907 flux Effects 0.000 description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 7
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000000976 ink Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- YACLCMMBHTUQON-UHFFFAOYSA-N 1-chloro-1-fluoroethane Chemical class CC(F)Cl YACLCMMBHTUQON-UHFFFAOYSA-N 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical class FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- -1 Trichloroethylene, tetrachloroethylene Chemical group 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011101 paper laminate Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/006—Cleaning, washing, rinsing or reclaiming of printing formes other than intaglio formes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5059—Mixtures containing (hydro)chlorocarbons
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02809—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing chlorine and fluorine
- C23G5/02812—Perhalogenated hydrocarbons
- C23G5/02816—Ethanes
- C23G5/02819—C2Cl3F3
Definitions
- This invention relates to an azeotropic composition and particularly to the azeotropic mixture of 1,1,2-triohloro- 1,2,2-trifluoroethane and methylene chloride.
- chlorofluorome'thanes and chlorofluoroethanes have attained widespread'use as specialty solvents in recent years, particularly trichlorofluoromethane and trichlorotrifluoroethane. Both of these' compounds are relatively low boiling liquids (CCl F, 23.8 C.; CCI FCCIF 47.6" C.), which are nontoxic and nonfiamrnable, and which have good solvent power for greases, oils, waxes and the like. They have therefore found widespread use for cleaning electricmotors, compressors, oxygen storage tanks, photographic film, lithographic plates, typewriters; instruments gauges, sound tape, and as noncorrosivebrines.
- the chlorofluoromethanes and chlorofluoroethanes have insufficient solvent power alone. This is particularly true in the electronic industry during the manufacture of printed circui L.
- Printed circuits are well known in the electronics art; and consist of a circuit formed from a soft metal on a solid, nonconducting surface such as a reinforced phenolic 1 resin. During manufacture, the solid surface is coated with the metal, the desired portion of metal is coated with an impervious coating, and the excess metal is removed by etching with a suitable acid. After the excess metal has been removed, it is necessary to remove the impervious coating because solder joints must be made to the printed circuit" and these will not form if the coating is present.
- the circuits are coated with a rosin flux to permit the joints to be soldered, which rosin flux must then be removed.
- the chlorofluoromethane and chlorofluoroethane solvents do not have sufiicient solvent power to clean printed circuits; that is, to etfectively remove the rosin flux.
- this invention comprises an azeotropic composition consisting of about 52% by weight of 1,1,2- trichloro-l,2,2atrifluoroethane and about 48% by weight of methylene chloride and boiling at 37 C. at 760 mm. pressure.
- the azeotropic mixture of this invention has the desired properties which render it useful for this pur'p'oseI r i
- the azeotropic mixture of l,l,2-trichloro-l,2,2-trifluoroethane and methylene chloride is of special value for cleaning printed circuits.
- the l, --l,2-trichloro-l,2,2- trifiuoroethane alone is'not an elfective' solvent for cleaning printed circuits, and has no deleteriousfefiect on the boards which form the bases of the printed circuits.
- Methylene chloride alone deleteriously ,aifects such boards, particularly laminated boards impregnated with phenolic resins, causing softening, swelling "and delamination of such boards and dissolving certain marking inks which are used to code various electronic components in the printed circuit assembly.
- the azeotropic mixture of this invention does not have these effects and is an excellent solvent for such purpose.
- the azeotrope of this invention has several advantages over the solvents heretofore employed for cleaning printed circuits.
- Trichloroethylene, tetrachloroethylene, and methyl chloroform are unstable and require stabilizers, whereas the azeotropic composition of this invention does not require a stabilizer, has a more favorable evaporation rate (is lower boiling), and is considerably less toxic than such solvents.
- the azeotropic composition of this invention is more effective as a solvent for such purposes than trichloroethylene and tetrachloroethylene.
- Inhibited methyl chloroform (containing dioxane as a stabilizer) is too strong a solvent and attacks the backing of the printed circuits.
- the azeotropic composition of this invention was established by the fractional distillation of a mixture containing 20% by weight'of l,l,2-trichloro-1,2,2-trifluoroethane and by weight of methylene chloride.
- Printed circuit boards are usually prepared by impregnating glass cloth, nylon, or paper laminates with a phenol-formaldehyde resin or an epoxy resin.
- Printed circuits are prepared by a variety of methods. In a typical procedure, the board consists originally of a phenolic resin impregnated base to which is bonded a sheet of copper, 2 to 4 mils thick, covering one surface of the board. The desired circuitis drawn on the copper with an asphalt based ink, using the silk screen method.
- excess copper is then removed by etching with a ferric chloride-hydrochloric acid bath, sometimes containing ammonium chloride, leaving on the board the copper that is covered by the ink.
- the asphalt ink is removed by cleaning with the azeotropic composition of this invention in an ultrasonic bath (some mechanical scrubbing is often used).
- the entire surface of the board is then coated with a rosin flux and dried.
- the electronic components (resistors, capacitors, etc.) are then added at the proper places for soldering to the circuit.
- the board is then passed over a molten solder bath, contacting the desired joints With the molten metal, whereby the soldering is effected.
- the excess rosin flux remaining on the board must be removed since, if present in the final assembly, it will lead to corrosion, poor electrical resistance and other deleterious properties.
- the board is cleaned by placing it in an ultrasonic bath operating at about 32 kilocycles per second and at about 25 C., where it remains for one minute. If 1,1,2-trichloro-1,2,2-trifluoroethane is used alone as the solvent in the bath, it has no effect on the rosin flux. If trichloroethylene is used as the solvent in the bath, about 5% to about 50% of the flux remains after the treatment. If the same cleaning operation is repeated on another circuit board using the azeotropic mixture of 1,1,2-trichloro- 1,2,2-trifluoroethane and methylene chloride as the solvent, the rosin fiux is completely removed. Neither the 1,1,2 trichloro-1,2,2-trifluoroethane nor the azeotropic mixture has any efiect on the board which constitutes the backing of the printed circuit.
- azeotropic composition of this invention in cleaning printed circuits is given for illustrative purposes solely, that this invention is not restricted to such specific embodiment, and that other techniques may be employed. Also, the azeotropic composition can be used for other purposes as indicated in the general description.
- A11 azetropic composition consisting of about 52% by Weight of 1,1,2-trich1oro-1,2,2-trifluoroethane and about 48% by weight of methylene chloride and boiling at 37 C. and 760 mm. pressure.
Description
United States Patent C "ice j 2,999,817 AZEOTROPIC COMPOSITION corporation of Delaware No Drawing. Filed Aug. 15, 1960, Ser. No. 49,436
1 Claim. '(Cl. 252172) This invention relates to an azeotropic composition and particularly to the azeotropic mixture of 1,1,2-triohloro- 1,2,2-trifluoroethane and methylene chloride.
Several of the chlorofluorome'thanes and chlorofluoroethanes have attained widespread'use as specialty solvents in recent years, particularly trichlorofluoromethane and trichlorotrifluoroethane. Both of these' compounds are relatively low boiling liquids (CCl F, 23.8 C.; CCI FCCIF 47.6" C.), which are nontoxic and nonfiamrnable, and which have good solvent power for greases, oils, waxes and the like. They have therefore found widespread use for cleaning electricmotors, compressors, oxygen storage tanks, photographic film, lithographic plates, typewriters; instruments gauges, sound tape, and as noncorrosivebrines.
For certain solvent purposes however, the chlorofluoromethanes and chlorofluoroethanes have insufficient solvent power alone. This is particularly true in the electronic industry during the manufacture of printed circui L. Printed circuits are well known in the electronics art; and consist of a circuit formed from a soft metal on a solid, nonconducting surface such as a reinforced phenolic 1 resin. During manufacture, the solid surface is coated with the metal, the desired portion of metal is coated with an impervious coating, and the excess metal is removed by etching with a suitable acid. After the excess metal has been removed, it is necessary to remove the impervious coating because solder joints must be made to the printed circuit" and these will not form if the coating is present. After the imprevious coating is removed, the circuits are coated with a rosin flux to permit the joints to be soldered, which rosin flux must then be removed. The chlorofluoromethane and chlorofluoroethane solvents do not have sufiicient solvent power to clean printed circuits; that is, to etfectively remove the rosin flux.
It is an object of this invention to provide a novel azeotropic composition which has new and unusual properties. Another object is to provide an azeotropic composition which is valuable as a solvent, and particularly for cleaning printed circuits. A further object is to provide such a composition which is nonflammable and nontoxic, both in the liquid phase and in the vapor phase. Other objects are to provide new compositions of matter and to advance the art. Still other objects will appear hereinafter.
The above and other objects may be accomplished in accord with this invention which comprises an azeotropic composition consisting of about 52% by weight of 1,1,2- trichloro-l,2,2atrifluoroethane and about 48% by weight of methylene chloride and boiling at 37 C. at 760 mm. pressure.
It has been found that l,1,2-trichloro-l,2,2-trifiuoroethane and methylene chloride (CH Cl when admixed in the above proportions form an azeotrope which distils at constant composition, the liquid phase and the vapor phase in equilibrium therewith having the same composition. Such mixture is nonflammable and nontoxic in both the liquid phase and the vapor phase. It is useful as a heat exchange medium and as a hydraulic fluid. It is particularly useful as a solvent for greases, oils, waxes, and the like, in cleaning electric motors, compressors, photographic film, oxygen storage tanks, lithographic, plates, typewriters, precision instruments, gauges, sound tape, components of engines which use liquid oxygen, and
2,999,817, Patented Sept. 12, 1961 printed circuits. The 1,1,2trichloro-1,2,2-trifluoroethane alone has insufiicient solvent power for many of such purposes, and the methylene chloride alone is objectionable for some of such purposes. It has been found that, in the azeotrope, the components modify the solvent properties of each other so that the azeotropic mixture is an excellent solvent for such purposes without having the disadvantages of either.
In the cleaning of components of engines which use liquid oxygen, it is particularly-important that the solvent remove alloxidizable materials so that they will not contact the liquid oxygen and that the solvent leave no residue which will react with liquid oxygen. The azeotropic mixture of this invention has the desired properties which render it useful for this pur'p'oseI r i The azeotropic mixture of l,l,2-trichloro-l,2,2-trifluoroethane and methylene chloride is of special value for cleaning printed circuits. The l, --l,2-trichloro-l,2,2- trifiuoroethane alone is'not an elfective' solvent for cleaning printed circuits, and has no deleteriousfefiect on the boards which form the bases of the printed circuits. Methylene chloride alone deleteriously ,aifects such boards, particularly laminated boards impregnated with phenolic resins, causing softening, swelling "and delamination of such boards and dissolving certain marking inks which are used to code various electronic components in the printed circuit assembly. The azeotropic mixture of this invention does not have these effects and is an excellent solvent for such purpose.
The azeotrope of this invention has several advantages over the solvents heretofore employed for cleaning printed circuits. Trichloroethylene, tetrachloroethylene, and methyl chloroform, are unstable and require stabilizers, whereas the azeotropic composition of this invention does not require a stabilizer, has a more favorable evaporation rate (is lower boiling), and is considerably less toxic than such solvents. The azeotropic composition of this invention is more effective as a solvent for such purposes than trichloroethylene and tetrachloroethylene. Inhibited methyl chloroform (containing dioxane as a stabilizer) is too strong a solvent and attacks the backing of the printed circuits. -Isopropyl alcohol-toluene blends are flammable and irritating. The azeotropic mixture of 1,l,Z-trichloro-1,2,2-trifluoroethane and methylene chloride does not suifer from any of these defects.
The azeotropic composition of this invention was established by the fractional distillation of a mixture containing 20% by weight'of l,l,2-trichloro-1,2,2-trifluoroethane and by weight of methylene chloride. The first fraction collected, amounting to 40% of the original mixture, was the azeotrope containing 52% by weight of 1,1,Z-trichloro-1,2,2-trifluoroethane and 48% by weight of methylene chloride having a boiling point of 37 C. at 760 mm. pressure, freezing point C. to 92 C., 11 1.3860. Distillation of mixtures of different proportions, eg 60% CCl- FCClF and 40% CH Cl always gave, as the first fraction, the azeotrope boiling at 37 C. The fractions boiling at 37 C. could be redisti-lled, giving material which boiled at 37 C. throughout with no separation into the components of the mixture.
Printed circuit boards are usually prepared by impregnating glass cloth, nylon, or paper laminates with a phenol-formaldehyde resin or an epoxy resin. Printed circuits are prepared by a variety of methods. In a typical procedure, the board consists originally of a phenolic resin impregnated base to which is bonded a sheet of copper, 2 to 4 mils thick, covering one surface of the board. The desired circuitis drawn on the copper with an asphalt based ink, using the silk screen method. The
excess copper is then removed by etching with a ferric chloride-hydrochloric acid bath, sometimes containing ammonium chloride, leaving on the board the copper that is covered by the ink. After washing 01f the etch solution, the asphalt ink is removed by cleaning with the azeotropic composition of this invention in an ultrasonic bath (some mechanical scrubbing is often used). The entire surface of the board is then coated with a rosin flux and dried. The electronic components (resistors, capacitors, etc.) are then added at the proper places for soldering to the circuit. The board is then passed over a molten solder bath, contacting the desired joints With the molten metal, whereby the soldering is effected. After cooling, the excess rosin flux remaining on the board must be removed since, if present in the final assembly, it will lead to corrosion, poor electrical resistance and other deleterious properties.
The board is cleaned by placing it in an ultrasonic bath operating at about 32 kilocycles per second and at about 25 C., where it remains for one minute. If 1,1,2-trichloro-1,2,2-trifluoroethane is used alone as the solvent in the bath, it has no effect on the rosin flux. If trichloroethylene is used as the solvent in the bath, about 5% to about 50% of the flux remains after the treatment. If the same cleaning operation is repeated on another circuit board using the azeotropic mixture of 1,1,2-trichloro- 1,2,2-trifluoroethane and methylene chloride as the solvent, the rosin fiux is completely removed. Neither the 1,1,2 trichloro-1,2,2-trifluoroethane nor the azeotropic mixture has any efiect on the board which constitutes the backing of the printed circuit.
It will be understood that the preceding detailed description of the use of the azeotropic composition of this invention in cleaning printed circuits is given for illustrative purposes solely, that this invention is not restricted to such specific embodiment, and that other techniques may be employed. Also, the azeotropic composition can be used for other purposes as indicated in the general description.
From the preceding description, it will be apparent that this invention provides a novel azeotropic composition which has unusual properties and which is useful for a wide variety of purposes. Accordingly, it will be apparent that invention constitutes a valuable contribution to and advance in the art.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
A11 azetropic composition consisting of about 52% by Weight of 1,1,2-trich1oro-1,2,2-trifluoroethane and about 48% by weight of methylene chloride and boiling at 37 C. and 760 mm. pressure.
References Cited in the file of this patent UNITED STATES PATENTS 2,155,510 Shepperd Apr. 25, 1939 2,547,887 Reed et a1 Apr. 3, 1951 2,911,331 Dennis et a1. Nov. 3, 1959 OTHER REFERENCES Industrial solvents, Mellan, 2nd ed. (1950), pp. 4879, 314-315, 372-373.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US49436A US2999817A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
US49427A US2999816A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US49436A US2999817A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
US49427A US2999816A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
Publications (1)
Publication Number | Publication Date |
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US2999817A true US2999817A (en) | 1961-09-12 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US49436A Expired - Lifetime US2999817A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
US49427A Expired - Lifetime US2999816A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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US49427A Expired - Lifetime US2999816A (en) | 1960-08-15 | 1960-08-15 | Azeotropic composition |
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Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3212998A (en) * | 1962-12-06 | 1965-10-19 | Dow Chemical Co | Azeotropic distillation of bromine |
US3282853A (en) * | 1964-03-24 | 1966-11-01 | Du Pont | Azeotropic composition and process for attenuating magnetic ink characters |
US3330776A (en) * | 1964-12-08 | 1967-07-11 | Du Pont | Trichlorotrifluoroethane hexafluoropropanol composition |
US3332881A (en) * | 1964-12-21 | 1967-07-25 | Du Pont | Azeotropic composition |
US3351560A (en) * | 1965-04-09 | 1967-11-07 | Dow Chemical Co | Solvent composition |
US3400077A (en) * | 1965-12-22 | 1968-09-03 | Allied Chem | Fluorinated hydrocarbon containing compositions |
FR2077227A1 (en) * | 1970-01-20 | 1971-10-22 | Hoechst Ag | |
US3625763A (en) * | 1968-12-04 | 1971-12-07 | Bunker Ramo | Conformal coating stripping method and composition |
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US3915875A (en) * | 1973-03-23 | 1975-10-28 | Mc Donnell Douglas Corp | Low temperature fluid |
US3951843A (en) * | 1973-01-09 | 1976-04-20 | Lfe Corporation | Fluorocarbon composition for use in plasma removal of photoresist material from semiconductor devices |
US4055521A (en) * | 1975-10-08 | 1977-10-25 | Allied Chemical Corporation | Constant boiling ternary compositions and the process for using such compositions in the preparation of polyurethane foam |
DE2835284A1 (en) * | 1978-08-11 | 1980-02-14 | Siemens Ag | SOLVENT USED IN THE FIXING DEVICE OF A PRINT OR COPIER |
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US3275563A (en) * | 1962-08-03 | 1966-09-27 | Dick Co Ab | Offset erasing fluid |
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US3431211A (en) * | 1965-03-05 | 1969-03-04 | Du Pont | Azeotropic compositions |
US3477952A (en) * | 1966-07-01 | 1969-11-11 | Du Pont | Azeotropic composition |
US3530073A (en) * | 1968-09-30 | 1970-09-22 | Union Carbide Corp | Azeotropic composition |
US3539462A (en) * | 1968-10-17 | 1970-11-10 | Union Carbide Corp | Azeotropic composition |
US3663255A (en) * | 1969-12-01 | 1972-05-16 | Dow Chemical Co | Composition containing chlorinated hydrocarbons ketones and glycol ethers, for reflowing organic surfaces |
US3691092A (en) * | 1970-10-29 | 1972-09-12 | Du Pont | 1,1,1,3,3,3-hexafluoro-2-propanol/c1 to c4 alkanol complexes |
GB1399867A (en) * | 1971-09-27 | 1975-07-02 | Ici Ltd | Cleaning process |
US3936387A (en) * | 1972-02-04 | 1976-02-03 | Phillips Petroleum Company | Azeotrope of 1,2-dichloro-1-fluoroethane and methanol |
US3846327A (en) * | 1972-05-30 | 1974-11-05 | Union Carbide Corp | Azeotropic composition |
US3881949A (en) * | 1973-02-27 | 1975-05-06 | Du Pont | Vapor degreaser process employing trichlorotrifluoroethane and ethanol |
US4035258A (en) * | 1973-08-27 | 1977-07-12 | Phillips Petroleum Company | Azeotropic compositions |
US3940342A (en) * | 1973-09-13 | 1976-02-24 | Phillips Petroleum Company | Azeotrope of 1,2-dichloro-1,1,2-trifluoroethane and trichlorofluoromethane |
US4002573A (en) * | 1973-09-13 | 1977-01-11 | Phillips Petroleum Company | Azeotropes of 1,2-dichloro-1,1,2-trifluoroethane |
US3960746A (en) * | 1974-07-25 | 1976-06-01 | E. I. Du Pont De Nemours And Company | Azeotrope-like compositions of methanol, nitromethane and trichlorotrifluoroethane |
US4024086A (en) * | 1975-08-06 | 1977-05-17 | Phillips Petroleum Company | Constant boiling admixtures |
US4062794A (en) * | 1975-12-08 | 1977-12-13 | Allied Chemical Corporation | Azeotrope-like compositions of trichlorotrifluoroethane, methanol, ethanol, isopropanol and nitromethane |
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US4440963A (en) * | 1982-08-09 | 1984-04-03 | Phillips Petroleum Company | Production of MTBE and ETBE |
US4662948A (en) * | 1984-11-28 | 1987-05-05 | Electric Power Research Institute | On-site removal of PCB and dioxins from soils |
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JPH01188599A (en) * | 1988-01-22 | 1989-07-27 | Daikin Ind Ltd | Azeotropic solvent composition |
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US4904407A (en) * | 1988-12-01 | 1990-02-27 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,2-trichloro-1,2,2-trifluoroethane, methanol, nitromethane, 1,2-dichloroethylene and 1-chloropropane |
US4900470A (en) * | 1988-12-01 | 1990-02-13 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,2-trichloro-1,2,2-trifluoroethane, methanol, nitromethane and 1-chloropropane |
US4971085A (en) * | 1988-12-27 | 1990-11-20 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,2-trichloro-1,2,3-trifluoroethane, methanol, nitromethane, 1,2-dichloroethylene, acetone and hexane |
US4973362A (en) * | 1988-12-27 | 1990-11-27 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,2-trichloro-1,2,2-trifluoroethane, methanol, nitromethane, 1,2-dichloroethylene and hexane |
US4936923A (en) * | 1989-03-01 | 1990-06-26 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of 1,1,2-trichlorotrifluoroethane with cis-1,2-dichloroethylene and n-propanol or isopropanol with or without nitromethane |
US4961869A (en) * | 1989-08-03 | 1990-10-09 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of 2,3-dichloro-1,1,1,3,3-pentafluoropropane with trans-1,2-dichloroethylene and methanol |
US5035830A (en) * | 1990-03-21 | 1991-07-30 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of hexafluoropropylene/ethylene cyclic dimer with methanol or ethanol |
US5034149A (en) * | 1990-03-21 | 1991-07-23 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 3-chloro-1,1,1-trifluoropropane with methanol or ethanol, or trans-1,2-dichloroethylene |
US5098595A (en) * | 1990-07-23 | 1992-03-24 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of 1,1,1,2,3,3-hexafluoro-3-methoxypropane and cis-1,2-dichloroethylene with methanol or ethanol or isopropanol or n-propanol |
US5023010A (en) * | 1990-07-23 | 1991-06-11 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1,1,2,3,3-hexafluoro-3-methoxypropane with methanol or isopropanol or N-propanol |
US5026498A (en) * | 1990-10-03 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1,1,2,3,3-hexafluoro-3-methoxypropane with one of trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, 1,1-dichloro-1,2-difluoroethane or 1,2-dichloro-1,1,-difluoroethane |
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Cited By (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3212998A (en) * | 1962-12-06 | 1965-10-19 | Dow Chemical Co | Azeotropic distillation of bromine |
US3282853A (en) * | 1964-03-24 | 1966-11-01 | Du Pont | Azeotropic composition and process for attenuating magnetic ink characters |
US3330776A (en) * | 1964-12-08 | 1967-07-11 | Du Pont | Trichlorotrifluoroethane hexafluoropropanol composition |
US3332881A (en) * | 1964-12-21 | 1967-07-25 | Du Pont | Azeotropic composition |
US3351560A (en) * | 1965-04-09 | 1967-11-07 | Dow Chemical Co | Solvent composition |
US3400077A (en) * | 1965-12-22 | 1968-09-03 | Allied Chem | Fluorinated hydrocarbon containing compositions |
US3625763A (en) * | 1968-12-04 | 1971-12-07 | Bunker Ramo | Conformal coating stripping method and composition |
FR2077227A1 (en) * | 1970-01-20 | 1971-10-22 | Hoechst Ag | |
US3846332A (en) * | 1971-08-02 | 1974-11-05 | Airco Inc | Azeotropes of 1-chloro-2,2,2-trifluoroethyl difluoromethyl ether with acetone, methyl ethylketone and tetrahydrofuran |
US3951843A (en) * | 1973-01-09 | 1976-04-20 | Lfe Corporation | Fluorocarbon composition for use in plasma removal of photoresist material from semiconductor devices |
US3915875A (en) * | 1973-03-23 | 1975-10-28 | Mc Donnell Douglas Corp | Low temperature fluid |
FR2231771A1 (en) * | 1973-05-29 | 1974-12-27 | Cerca | Corrosion protection of uranium radiation shields - by cleaning surface then electrode positing nickel, zinc, cadmium or nickel-tin alloy |
US4055521A (en) * | 1975-10-08 | 1977-10-25 | Allied Chemical Corporation | Constant boiling ternary compositions and the process for using such compositions in the preparation of polyurethane foam |
DE2835284A1 (en) * | 1978-08-11 | 1980-02-14 | Siemens Ag | SOLVENT USED IN THE FIXING DEVICE OF A PRINT OR COPIER |
US4476036A (en) * | 1983-09-12 | 1984-10-09 | Allied Corporation | Quaternary 1,1,2-trichloro-1,2,2-trifluoro azeotropic cleaning composition |
US4873021A (en) * | 1986-12-30 | 1989-10-10 | E. I. Du Pont De Nemours And Company | Azeotrope or azeotrope-like composition of trichlorotrifluoroethane and dichlorodifluoroethane |
US4715900A (en) * | 1987-01-08 | 1987-12-29 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of trichlorotrifluoroethane, dichlorodifluoroethane and methanol/ethanol |
US4808331A (en) * | 1988-05-24 | 1989-02-28 | E. I. Du Pont De Nemours And Company | Azeotrope or azeotrope-like composition of 1,1,2,-trichloro-1,2,2-trifluoroethane, trans-1,2-dichloroethylene and cyclopentane |
US4954289A (en) * | 1989-06-12 | 1990-09-04 | E. I. Du Pont De Nemours And Company | Azeotropes of hydrogen-containing halocarbons with butanes |
US5066417A (en) * | 1989-07-20 | 1991-11-19 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 2,2-dichloro-1,2-difluoroethane with methanol, ethanol, or trans-1,2-dichloroethylene |
US5176757A (en) * | 1990-03-05 | 1993-01-05 | E. I. Du Pont De Nemours And Company | 1,1,2,2,3,3-hexafluorocyclopentane and use thereof in compositions and processes for cleaning |
US5084199A (en) * | 1990-03-05 | 1992-01-28 | E. I. Du Pont De Nemours And Company | 1,1,2,2,3,3-hexafluorocyclopentane and use thereof in compositions and processes for cleaning |
US5240634A (en) * | 1990-03-12 | 1993-08-31 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of 1,1-dichloro-1,2-difluoroethane and cis-1,2-dichloroethylene with methanol or ethanol or n-propanol |
US5026497A (en) * | 1990-03-12 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of perfluoro-1,2-dimethylcyclobutane with methanol and 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane |
US4994202A (en) * | 1990-03-12 | 1991-02-19 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of perfluoro-1,2-dimethylcyclobutane with 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane |
WO1991013946A1 (en) * | 1990-03-12 | 1991-09-19 | E.I. Du Pont De Nemours And Company | Azeotropic compositions of perfluoro-1,2-dimethylcyclobutane with 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane |
US5026499A (en) * | 1990-03-21 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of hexafluoropropylene/ethylene cyclic dimer with trans-1,2-dichloroethylene and methanol |
US4986928A (en) * | 1990-03-21 | 1991-01-22 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1-chloro-1,2,2-trifluorocyclobutane and methanol |
US5221361A (en) * | 1990-08-17 | 1993-06-22 | E. I. Du Pont De Nemours And Company | Compositions of 1,1,1,2,2,5,5,5,-octafluoro-4-trifluoromethylpentane and use thereof for cleaning solid surfaces |
US5073290A (en) * | 1990-08-17 | 1991-12-17 | E. I. Du Pont De Nemours And Company | Compositions of 1,1,1,2,2,5,5,5-octafluoro-4-trifluormethypentane and use thereof for cleaning solid surfaces |
US5073288A (en) * | 1990-08-17 | 1991-12-17 | E. I. Du Pont De Nemours And Company | Compositions of 1,1,1,2,2,3,5,5,5-nonafluoro-4-trifluoromethylpentane and use thereof for cleaning solid surfaces |
US5037573A (en) * | 1990-10-03 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1-dichloro-1-fluoroethane and n-perfluorobutylethylene |
US5023009A (en) * | 1990-10-03 | 1991-06-11 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1,1,2,3,3-hexafluoro-3-methoxypropane and 2,2,3,3,3-pentafluoropropanol-1 |
US5037572A (en) * | 1990-10-03 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of n-perfluorobutylethylene and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
US5039445A (en) * | 1990-10-03 | 1991-08-13 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of N-perfluorobutylethylene and cis-1,2-dichloroethylene with methanol or ethanol or isopropanol |
US5723701A (en) * | 1990-10-11 | 1998-03-03 | E. I. Du Pont De Nemours And Company | Saturated linear polyfluorohydrocarbons, processes for their production, and their use in cleaning compositions |
US5171902A (en) * | 1990-10-11 | 1992-12-15 | E. I. Du Pont De Nemours And Company | Saturated linear polyfluorohydrocarbons, processes for their production, and their use in cleaning compositions |
US5504265A (en) * | 1990-10-11 | 1996-04-02 | E. I. Du Pont De Nemours And Company | Saturated linear polyfluorohydrocarbons, processes for their production, and their use in cleaning compositions |
US5683978A (en) * | 1990-10-11 | 1997-11-04 | E. I. Du Pont De Nemours And Company | Saturated linear polyfluorohydrocarbons in cleaning compositions |
US6506950B1 (en) | 1990-10-11 | 2003-01-14 | E. I. Du Pont De Nemours And Company | Saturated linear polyfluorohydrocarbons, processes for their production, and their use in cleaning compositions |
US5076956A (en) * | 1990-11-29 | 1991-12-31 | E. I. Du Pont De Nemours And Company | Compositions of octafluorotrifluoromethylpentane and nonafluorotrifluoromethylpentane and use thereof for cleaning solid surfaces |
US5250213A (en) * | 1991-05-06 | 1993-10-05 | E. I. Du Pont De Nemours And Company | 1,1,1,2,2,3,3,4,4,5,6-undecafluorohexane and use thereof in compositions and processes for cleaning |
US5268122A (en) * | 1991-08-28 | 1993-12-07 | E. I. Du Pont De Nemours And Company | Gem-dihydropolyfluoroalkanes and monohydropolyfluoroalkenes, processes for their production, and use of gem-dihydropolyfluoroalkanes in cleaning compositions |
US6194619B1 (en) | 1991-08-28 | 2001-02-27 | E. I. Du Pont De Nemours And Company | Gem-dihydropolyfluoroalkanes and monohydropolyfluoroalkenes, processes for their production, and use of gem-dihydropolyfluoroalkanes in cleaning compositions |
US6030934A (en) * | 1997-02-19 | 2000-02-29 | 3M Innovative Properties Company | Azeotropic compositions of methoxy-perfluoropropane and their use |
US6281185B1 (en) | 1997-02-19 | 2001-08-28 | 3M Innovative Properties Company | Azeotropic compositions of methoxy-perfluoropropane and their use |
US5851977A (en) * | 1997-08-26 | 1998-12-22 | Ppg Industries, Inc. | Nonflammable organic solvent compositions |
US8592538B2 (en) | 2011-12-20 | 2013-11-26 | Honeywell International Inc. | Azeotropes of methyl chloride with fluorocarbons |
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