US2116289A - Fabric, paper, leather, or the like - Google Patents

Fabric, paper, leather, or the like Download PDF

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Publication number
US2116289A
US2116289A US1375635A US2116289A US 2116289 A US2116289 A US 2116289A US 1375635 A US1375635 A US 1375635A US 2116289 A US2116289 A US 2116289A
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fabric
printing
grooves
solution
network
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Shepherd Thomas Lewis
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31826Of natural rubber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31826Of natural rubber
    • Y10T428/31841Next to cellulosic

Definitions

  • This invention relates to fabrics, paper, leather or the like and the manufacture thereof, such fabrics being of the known type in which an extensible fabrichas imprinted thereon a line or 5 other open pattern of rubber, preferably an aqueous dispersion of latex. This pattern is then dried and vulcanized and it will be found, when the fabric is stretched in any direction, that it will always return to normal shape and size. The same result will be obtained when a multilayer fabric is made. work pattern is imprinted on one'layer of fabric, a second layer is pressed on to the still tacky pattern, thus forming a two layer fabric.
  • a further modified form of multifabric may beformed by placing between two sheets of fabric each bearing an open work pattern, an intermediate solidified open work layer of coagulated material formed from an aqueous dispersion of latex, con- 20 verted rubber or the like.
  • Figure 1 is a perspective view of a known form of multifabric, i. e. in which an open solidified network is arranged between two fabric layers each being imprinted on their adjacent faces with an open work pattern.
  • Figure 2 is a side elevation of an engraved printing roller used in preparing the multifabric 40 in Figure 1.
  • Figure 3 is a plan view of a network forming a part of the fabric in Figure 1.
  • Figure 4 is a perspective view of an improved 45 form of two-ply fabric made accordingtothe invention. i
  • Figures 5 and 6 are perspective views of two kinds of printing rollers that may be used
  • Figure 7 is a diagrammatic view of an appa- 50 ratus whereby the invention may be carried into effect;
  • Figure 8 is a transverse section of Figure 6 showing a portion of the roller drawn to an enlarged scale
  • Figure 9 is a view similar to Figure 8 but in In that case after the open which the recesses in the roller are modified in shape.
  • Figure 10 is plan view of a modified form of fabric with one of the layers turned back.
  • a network I as shown is prepared from coagulable material and for this purpose a suitable solution such as an aqueous dispersion of latex, converted rubber or the like is fed to an engraved 10 printing roller b shown in Figure 2.
  • the roller b is formed wltha series of crossgrooves or recesses 0 extending both longitudinally and circumferentially, helically or otherwise so as to form a network.
  • a printing roller b arranged as shown in Figure 7 it is fed by means of a transfer roller d which dips into a bath e containing the latex.
  • Latex 180 Sulphur 2.25 Zinc oxide 3.0 Accelerator 0.75 Anti-oxidant 0.5 Casein solution 10% 5.0
  • Such a fluid possessesan advantage over the comparatively thick paste or cream that is often used, because it will not result in the presence of air bubbles during the printing operation owing to its low viscosity value and again the lines or patterns printed on the fabric will be uniform and possess sharply defined edges.
  • a machine may be used similar to that already described and shown in Figure 'l in which a represents a travelling blanket or a length of fabric to be printed.
  • the grooves are shown as V shape, the depth of which is substantially equal to the width at the mouth so that when the printing roller b is in contact with the sheet of material a, capillary attraction will have an influence so as to regulate the amount of solution which will be taken out of the grooves during the printing contact. Whilst any suitable dimensions of depth and width may be used, it has been found in practice that a groove having a depth and width both 1/25th of an inch has given good results.
  • the groove q shown in Figure 8 is intended to illustrate it being full of solution before the printing operation whilst the groove r shows the condition'of the same groove after printing has occurred and it willbe noticed that in the latter groove 1' about one third of the quantity or charge of solution is left remaining in the groove after the printing operation; that is to say, by the printing contact only a .predetermined quantity of solution is transmitted to the fabric whereby only just enough will be supplied for the purpose and there will be no excess which would result in the lines printed upon the fabric being somewhat uneven and non-uniform.
  • Figure 9 is shown a modified form of groove in the printing cylinder and in this case the grooves are somewhat rectangular in shape and have a width about three times greater than the depth of 1/25th of an inch.
  • the bottom of the groove is serrated as shown at t,
  • an extensible fabric of the kind referred to may be obtained by the means described and illustrated, such fabric being permeable both to m0is ture and air so that adequate ventilation is en sured.
  • Such a fabric may be also improved by replacing the solidified network It by a flexible and elastic or non-elastic fabric consisting of a woven, knitted, braided or lace network of rubber or contractile threads and with or without ordinary textile threads such as cotton, silk, artificial silk or linen combined therewith, such textile threads being suitably treated (as by twisting) to allow for the stretching movements.
  • a compound fabric of this kind maybe easily made by applying upon an extensible or non-extensible fabricl a layer formed of solidified network It. Upon this network there is laid atextile fabric 0 already interwoven with elastic threads p, the adjacent surfaces of the layers having applied thereon a pattern n of adhesive solution.
  • a reservoir for liquid coagulable material a feed roll printing roll contacting said feed roll, a pressure roll rotatably mounted adjacent said printing roll 'so as to. permit a fabric sheet to pass therebepartly immersed therein, a
  • said printing, roll having grooves in the peripheral surface thereof, said grooves havinli rounded conical cross-sections whereby the grooves holda portion 01' a liquid material by capillary attraction-within the grooves when the exposed surface or the liquid is contacted by the fabric sheet.

Description

'r. SHEPHERD FABRIC; PAPER, LEATHER, OR THE LIKE May 3, 1933-.
2 She ets-Sheet 1- Filed March 29, 1955 ig/a Maia? fr. SHEPHERD FABRIC, PAPER, LEATHER, OR THE LIKE Filed March 29, 1935 t 2 Sheets-Sheet 2 Patented May 3, 1938 UNITED STATES PATENT OFFICE,
rAnamrnrr-m, 23221:. on v I Application March 29, 1935, Serial No. 13,756
. In Great Britain June 11, 1934 3 Claims. (01. 1-50) This invention relates to fabrics, paper, leather or the like and the manufacture thereof, such fabrics being of the known type in which an extensible fabrichas imprinted thereon a line or 5 other open pattern of rubber, preferably an aqueous dispersion of latex. This pattern is then dried and vulcanized and it will be found, when the fabric is stretched in any direction, that it will always return to normal shape and size. The same result will be obtained when a multilayer fabric is made. work pattern is imprinted on one'layer of fabric, a second layer is pressed on to the still tacky pattern, thus forming a two layer fabric. A further modified form of multifabric may beformed by placing between two sheets of fabric each bearing an open work pattern, an intermediate solidified open work layer of coagulated material formed from an aqueous dispersion of latex, con- 20 verted rubber or the like.
Whilst such fabrics are quite successful in practice, there is a tendency that when theopen work pattern is being printed, the lines of the pattern may be blurred and uneven this being 25 due partly to an excess of rubber solution being used and partly to the different absorbent qualities of the sheets of fabric.
The object of the invention to be hereinafter described is to overcome these disadvantages.
30 To this end the invention will now be described with reference to the accompanying drawings in which:-
Figure 1 is a perspective view of a known form of multifabric, i. e. in which an open solidified network is arranged between two fabric layers each being imprinted on their adjacent faces with an open work pattern.
Figure 2 is a side elevation of an engraved printing roller used in preparing the multifabric 40 in Figure 1.
Figure 3 is a plan view of a network forming a part of the fabric in Figure 1.
Figure 4 is a perspective view of an improved 45 form of two-ply fabric made accordingtothe invention; i
Figures 5 and 6 are perspective views of two kinds of printing rollers that may be used;
Figure 7 is a diagrammatic view of an appa- 50 ratus whereby the invention may be carried into effect; v
Figure 8 is a transverse section of Figure 6 showing a portion of the roller drawn to an enlarged scale; and
55 Figure 9 is a view similar to Figure 8 but in In that case after the open which the recesses in the roller are modified in shape.
Figure 10 is plan view of a modified form of fabric with one of the layers turned back.
In the manufacture of a fabric shown in Fig- 5 ure 1, and referring also to Figures 2v and 3, a network I: as shown is prepared from coagulable material and for this purpose a suitable solution such as an aqueous dispersion of latex, converted rubber or the like is fed to an engraved 10 printing roller b shown in Figure 2. The roller b is formed wltha series of crossgrooves or recesses 0 extending both longitudinally and circumferentially, helically or otherwise so as to form a network. With a printing roller b arranged as shown in Figure 7, it is fed by means of a transfer roller d which dips into a bath e containing the latex. After the rollerb has picked up the solution a doctor blade I wipes over the surface of the printing roller b and leaves the solution in the grooves c. A moving blanket 9 passes round the roller h, and the printing roller rotatesin contact with the moving blanket and prints thereon the network lines of solution contained-in the grooves. The blanket passes on and means are provided whereby the printed network k (Figure 3) is subsequently dried and vulcanized in any usual way. After this the finished network is separated from the blanket and it is now inserted as shown in Figure 1 between .30 two layers of extensible fabric 1, m, for instance stockinette which have. each been previously treatedby a printing process by a printing roller similar to b, Figure 2, but in which the grooves are obliquely arranged, by which a pattern 11. as shown by the dotted diagonal crossing lines, of adhesive solution is applied to the adjacent surfaces of the two layers Z, m of stockinette. A sort of sandwich construction is thus obtained comprising two layers of stockinette for example and the interposed solid network It. The whole is then subjected to pressure by means of rollers, a press or the like so as to cause the three layers to adhere to each other very intimately and tightly by means of the adhesive solution pat- 5 tern n. The resultant fabric is then suitably dried and/or cured or vulcanized with the result that astro'ng composite fabric is obtained which, I after being extended orstretched, will always contract back to normal size.
It has been found in practice, with such a known fabric, that in regard to the printing process described both for the solidified network It as well as adhesive solution pattern n Fig. 1 that in order to prevent air bubbles being formed and to. obtain a smooth and uniform line, regard must be had to the viscosity of the aqueous dispersion of latex or similar solution as well as the dimensions of the grooves or recesses c of the engraved printing roller 21. For this purpose the latex or rubber solution which is used is much more liquid in character than is usual with solutions of this kind, 1. e., it possesses a fluidity approaching that of milk and the following is a typical example of a suitable mix which will yield good results:-
a v rts by weight Latex 180 Sulphur 2.25 Zinc oxide 3.0 Accelerator 0.75 Anti-oxidant 0.5 Casein solution 10% 5.0
Such a fluid possessesan advantage over the comparatively thick paste or cream that is often used, because it will not result in the presence of air bubbles during the printing operation owing to its low viscosity value and again the lines or patterns printed on the fabric will be uniform and possess sharply defined edges.
To obtain such an improved printing result, a machine may be used similar to that already described and shown in Figure 'l in which a represents a travelling blanket or a length of fabric to be printed.
In the enlarged sectional view in Figure 8. two groovesv are shown in the surface of the printing roller 2), such grooves being noted by q and r respectively.
It is to be noted that the grooves are shown as V shape, the depth of which is substantially equal to the width at the mouth so that when the printing roller b is in contact with the sheet of material a, capillary attraction will have an influence so as to regulate the amount of solution which will be taken out of the grooves during the printing contact. Whilst any suitable dimensions of depth and width may be used, it has been found in practice that a groove having a depth and width both 1/25th of an inch has given good results. The groove q shown in Figure 8 is intended to illustrate it being full of solution before the printing operation whilst the groove r shows the condition'of the same groove after printing has occurred and it willbe noticed that in the latter groove 1' about one third of the quantity or charge of solution is left remaining in the groove after the printing operation; that is to say, by the printing contact only a .predetermined quantity of solution is transmitted to the fabric whereby only just enough will be supplied for the purpose and there will be no excess which would result in the lines printed upon the fabric being somewhat uneven and non-uniform.
I By therefore carefully determining the size of the grooves beforehand in relation to the degree of viscosity of the solution, the exact amount of mixture is transferred to the fabric during the printing operation and no more. Thus, there'will be no excess transferred and in order to still further control the printing operation it is preferred to soak the fabric before the printing with a very weak acid solution to prevent the rubber print from too much penetration and to cause it to lie upon the surface rather than soak into it. A suitable solution for this purpose may be one half to two per cent. of acetic acid and the cloth or fabric so'soaked is semi-dried and then printed. In the two-ply fabric illustrated in Figure 4 such acid solution is, indicated by the hatched lines s.
In Figure 9 is shown a modified form of groove in the printing cylinder and in this case the grooves are somewhat rectangular in shape and have a width about three times greater than the depth of 1/25th of an inch. In this case the bottom of the groove is serrated as shown at t,
whereby the same feature of retaining a part of the solution in the groove will be maintained as the serrations will form extended surface contact by which capillary attraction is increased to keep back-the desired amount of. solution. .Such serrations are useful in the case illustrated where the grooves aresubstantially rectangular in shape. It is to be noted however that the above dimensions are given by way of example only.
Although in Figures 5 and 6 two examples are shown of printing rollers, one in which the grooves are circumferential and the other in Figure 6 where the grdbves are longitudinal, it is to be understood that any other shape of groove or arrangement or design may be used, the cross section of the grooves shown in such rollers being of the character shown in Figure 8 or 9 or such other section as will produce the result desired of keeping back a certain part of the solution.
It is also to be understood that for printing the solidified network It grooves will be used of a capacity relatively greater than those employed to print the adhesive line pattern 11..
From the foregoing it will be understood that an extensible fabric of the kind referred to may be obtained by the means described and illustrated, such fabric being permeable both to m0is ture and air so that adequate ventilation is en sured. Such a fabric may be also improved by replacing the solidified network It by a flexible and elastic or non-elastic fabric consisting of a woven, knitted, braided or lace network of rubber or contractile threads and with or without ordinary textile threads such as cotton, silk, artificial silk or linen combined therewith, such textile threads being suitably treated (as by twisting) to allow for the stretching movements.
. A compound fabric of this kind (see Figure 10) maybe easily made by applying upon an extensible or non-extensible fabricl a layer formed of solidified network It. Upon this network there is laid atextile fabric 0 already interwoven with elastic threads p, the adjacent surfaces of the layers having applied thereon a pattern n of adhesive solution.
Having now described my invention. what I claim as new and desire to secure by Letters Patent is 1. In apparatus for use in manufacturing elastic fabric, a reservoir for liquid coagulable material, a feed, roll partly immersed therein, a printing roll contacting said feed roll, a pressure roll mounted adjacent said printing roll in such a manner as to permit a fabric sheet to pass therebetween, said printing roll having grooves in the periphery thereof, said grooves being substantially V-shaped and the depth of each being substantially equal to the width thereof at the mouth whereby said grooves hold approximately onethird of the liquid material therein by capillary attraction when the exposed surface of the liquid within the grooves engages the fabric sheet.
2. Apparatus as claimed in claim 1 wherein the depth of the grooves and the width thereof at the mouth are approximately 1/25th of an inch.
3. In apparatus for use in manufacturing elastic fabric, a reservoir for liquid coagulable material, a feed roll printing roll contacting said feed roll, a pressure roll rotatably mounted adjacent said printing roll 'so as to. permit a fabric sheet to pass therebepartly immersed therein, a
tween, said printing, roll having grooves in the peripheral surface thereof, said grooves havinli rounded conical cross-sections whereby the grooves holda portion 01' a liquid material by capillary attraction-within the grooves when the exposed surface or the liquid is contacted by the fabric sheet. 'm oms LEWIS smnnnn. p
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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531036A (en) * 1946-07-26 1950-11-21 Samuel M Langston Co Apparatus for applying pattern forming material
US2940868A (en) * 1955-05-26 1960-06-14 Smith & Nephew Adhesive medical and surgical dressings
US3044442A (en) * 1958-03-03 1962-07-17 Pott Cyrus Dennis Apparatus for applying coatings to surfaces of articles
US3056707A (en) * 1957-10-28 1962-10-02 Pittsburgh Plate Glass Co Sound deadener and absorber
US3206353A (en) * 1961-12-29 1965-09-14 Pid Corp Ribbed cover plate for coating application cylinder
US3464876A (en) * 1964-11-16 1969-09-02 Staflex Intern Ltd Method of forming a fusible interlining material
US3485705A (en) * 1966-11-08 1969-12-23 Johnson & Johnson Nonwoven fabric and method of manufacturing the same
US3625795A (en) * 1969-12-29 1971-12-07 Goodrich Co B F Spray process for depositing adhesive and bonding laminates
US4173199A (en) * 1974-12-02 1979-11-06 Codama Holding S.A. Apparatus for reinforcing a fabric by applying a fluid reinforcing material thereto
US4194030A (en) * 1974-12-02 1980-03-18 Codama Holding S.A. Method for reinforcing fabric by applying a fluid reinforcing material thereto
US4261288A (en) * 1978-09-25 1981-04-14 Herbert Kannegiesser Gmbh & Co. Apparatus for reinforcing textile fabrics by coating them with plastic
US4344379A (en) * 1981-02-02 1982-08-17 Molins Machine Company, Inc. Bonding machine and gravure applicator roll
US5194299A (en) * 1984-10-19 1993-03-16 Minnesota Mining And Manufacturing Company Repositionable pressure-sensitive adhesive sheet material
US5983970A (en) * 1991-10-17 1999-11-16 Trygg; Lars Erik Apparatus for applying labels to objects having a helically grooved gluine roller
US20060046597A1 (en) * 2004-08-24 2006-03-02 San Fang Chemical Industry Co., Ltd. Permeable artificial leather with realistic feeling and method for making the same
US20060263601A1 (en) * 2005-05-17 2006-11-23 San Fang Chemical Industry Co., Ltd. Substrate of artificial leather including ultrafine fibers and methods for making the same
US20070207687A1 (en) * 2004-05-03 2007-09-06 San Fang Chemical Industry Co., Ltd. Method for producing artificial leather
US20080020142A1 (en) * 2004-09-16 2008-01-24 Chung-Chih Feng Elastic Artificial Leather
US20080149264A1 (en) * 2004-11-09 2008-06-26 Chung-Chih Feng Method for Making Flameproof Environmentally Friendly Artificial Leather
US20080187715A1 (en) * 2005-08-08 2008-08-07 Ko-Feng Wang Elastic Laminate and Method for Making The Same
US20080220701A1 (en) * 2005-12-30 2008-09-11 Chung-Ching Feng Polishing Pad and Method for Making the Same
US20080227375A1 (en) * 2005-05-27 2008-09-18 Chung-Chih Feng Ultra Fine Fiber Polishing Pad
US7794796B2 (en) 2006-12-13 2010-09-14 San Fang Chemical Industry Co., Ltd. Extensible artificial leather and method for making the same

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531036A (en) * 1946-07-26 1950-11-21 Samuel M Langston Co Apparatus for applying pattern forming material
US2940868A (en) * 1955-05-26 1960-06-14 Smith & Nephew Adhesive medical and surgical dressings
US3056707A (en) * 1957-10-28 1962-10-02 Pittsburgh Plate Glass Co Sound deadener and absorber
US3044442A (en) * 1958-03-03 1962-07-17 Pott Cyrus Dennis Apparatus for applying coatings to surfaces of articles
US3206353A (en) * 1961-12-29 1965-09-14 Pid Corp Ribbed cover plate for coating application cylinder
US3464876A (en) * 1964-11-16 1969-09-02 Staflex Intern Ltd Method of forming a fusible interlining material
US3485705A (en) * 1966-11-08 1969-12-23 Johnson & Johnson Nonwoven fabric and method of manufacturing the same
US3625795A (en) * 1969-12-29 1971-12-07 Goodrich Co B F Spray process for depositing adhesive and bonding laminates
US4173199A (en) * 1974-12-02 1979-11-06 Codama Holding S.A. Apparatus for reinforcing a fabric by applying a fluid reinforcing material thereto
US4194030A (en) * 1974-12-02 1980-03-18 Codama Holding S.A. Method for reinforcing fabric by applying a fluid reinforcing material thereto
US4261288A (en) * 1978-09-25 1981-04-14 Herbert Kannegiesser Gmbh & Co. Apparatus for reinforcing textile fabrics by coating them with plastic
US4344379A (en) * 1981-02-02 1982-08-17 Molins Machine Company, Inc. Bonding machine and gravure applicator roll
US5194299A (en) * 1984-10-19 1993-03-16 Minnesota Mining And Manufacturing Company Repositionable pressure-sensitive adhesive sheet material
US5983970A (en) * 1991-10-17 1999-11-16 Trygg; Lars Erik Apparatus for applying labels to objects having a helically grooved gluine roller
US20070207687A1 (en) * 2004-05-03 2007-09-06 San Fang Chemical Industry Co., Ltd. Method for producing artificial leather
US20060046597A1 (en) * 2004-08-24 2006-03-02 San Fang Chemical Industry Co., Ltd. Permeable artificial leather with realistic feeling and method for making the same
US20080020142A1 (en) * 2004-09-16 2008-01-24 Chung-Chih Feng Elastic Artificial Leather
US20080149264A1 (en) * 2004-11-09 2008-06-26 Chung-Chih Feng Method for Making Flameproof Environmentally Friendly Artificial Leather
US7494697B2 (en) 2005-05-17 2009-02-24 San Fang Chemical Industry Co., Ltd. Substrate of artificial leather including ultrafine fibers and methods for making the same
US20060263601A1 (en) * 2005-05-17 2006-11-23 San Fang Chemical Industry Co., Ltd. Substrate of artificial leather including ultrafine fibers and methods for making the same
US20090098785A1 (en) * 2005-05-17 2009-04-16 Lung-Chuan Wang Substrate of Artificial Leather Including Ultrafine Fibers
US20080227375A1 (en) * 2005-05-27 2008-09-18 Chung-Chih Feng Ultra Fine Fiber Polishing Pad
US7762873B2 (en) 2005-05-27 2010-07-27 San Fang Chemical Industry Co., Ltd. Ultra fine fiber polishing pad
US20080187715A1 (en) * 2005-08-08 2008-08-07 Ko-Feng Wang Elastic Laminate and Method for Making The Same
US20080220701A1 (en) * 2005-12-30 2008-09-11 Chung-Ching Feng Polishing Pad and Method for Making the Same
US7794796B2 (en) 2006-12-13 2010-09-14 San Fang Chemical Industry Co., Ltd. Extensible artificial leather and method for making the same

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