US20100159273A1 - Method and Apparatus for Forming a Layered Metal Structure with an Anodized Surface - Google Patents

Method and Apparatus for Forming a Layered Metal Structure with an Anodized Surface Download PDF

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Publication number
US20100159273A1
US20100159273A1 US12/358,647 US35864709A US2010159273A1 US 20100159273 A1 US20100159273 A1 US 20100159273A1 US 35864709 A US35864709 A US 35864709A US 2010159273 A1 US2010159273 A1 US 2010159273A1
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United States
Prior art keywords
layer
stainless steel
aluminum
anodized
laminant
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Abandoned
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US12/358,647
Inventor
John Benjamin Filson
Kenneth J. Silverman
Masashige Tatebe
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Apple Inc
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Apple Inc
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Publication date
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Priority to US12/358,647 priority Critical patent/US20100159273A1/en
Assigned to APPLE INC. reassignment APPLE INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TATEBE, MASASHIGE, FILSON, JOHN BENJAMIN, SILVERMAN, KENNETH J.
Publication of US20100159273A1 publication Critical patent/US20100159273A1/en
Priority to US13/723,077 priority patent/US8667661B2/en
Priority to US14/157,183 priority patent/US9347146B2/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/022Anodisation on selected surface areas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/012Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/26Anodisation of refractory metals or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02Electroplating of selected surface areas
    • C25D5/022Electroplating of selected surface areas using masking means
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/04Tubes; Rings; Hollow bodies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/30Foil or other thin sheet-metal making or treating
    • Y10T29/301Method
    • Y10T29/302Clad or other composite foil or thin metal making
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49826Assembling or joining
    • Y10T29/49888Subsequently coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736Al-base component
    • Y10T428/1275Next to Group VIII or IB metal-base component
    • Y10T428/12757Fe

Definitions

  • the present invention relates to the formation of housings for use in electronic devices and, more particularly, to forming cosmetic surfaces on stainless steel housing parts.
  • Many devices e.g., portable electronic devices such as cell phones and media players, include housing walls formed from structurally strong and stiff materials such as stainless steel.
  • the strength provided by materials such a stainless steel enables housing walls to protect internal components of portable electronic devices, and enhances the durability of such devices.
  • stainless steel provides desirable strength characteristics for housing walls
  • the stainless steel may not provide acceptable cosmetic characteristics.
  • a stainless steel surface is often relatively easy to scratch, and a scratched stainless steel surface may be unappealing.
  • anodizing processes may be used on some metals in order to effectively provide a scratch-resistant surface
  • stainless steel may not be anodized, as rust forms on stainless steel due to oxidation.
  • the use of stainless steel may be undesirable.
  • Metals such as aluminum may be anodized to prevent scratching. That is, the surface of some metals, such as aluminum, may be anodized such that the surface becomes substantially scratch-resistant.
  • aluminum is relatively weak structurally. Hence, while an aluminum surface may be anodized to protect the surface from being scratched, the use of aluminum as a housing may be undesirable due to the lack of structural strength associated with aluminum.
  • the present invention pertains to creating a housing structure, such as a housing wall, that includes a stainless steel core and one or more anodized, cosmetic outer surfaces.
  • the present invention may be implemented in numerous ways, including, but not limited to, as a method, system, device, or apparatus. Example embodiments of the present invention are discussed below.
  • a housing arrangement can include a stainless steel layer and at least a first layer.
  • the first layer can have a first bonding surface and a first exterior surface.
  • the first bonding surface can be substantially bonded in direct contact with the stainless steel layer, and the first exterior surface can be an exterior of the housing arrangement.
  • the first exterior surface can be an anodized surface.
  • the first layer is formed from an anodizable material such as aluminum, titanium, niobium, or tantalum.
  • a method for forming a housing arrangement can include directly bonding at least a first laminant layer to a stainless steel layer, and masking at least one surface of the stainless steel layer that is not directly bonded to the first laminant layer.
  • Masking the surface of the stainless steel layer includes applying a mask to the surface of the stainless steel layer.
  • the method can also include anodizing the first laminant layer such that the surface of the stainless steel that is masked is not anodized. Anodizing the first laminant layer causes a surface of the first laminant layer to be anodized.
  • the mask is removed from the surface of the stainless steel layer after the first laminant layer is anodized.
  • directly bonding the first laminant layer to the stainless steel layer includes cladding the first laminant layer to the stainless steel layer.
  • a housing wall that is suitable for use in a portable electronic device can include a first aluminum layer, a second aluminum layer, and a stainless steel layer.
  • the first aluminum layer can include a first cladding surface and a first outer surface
  • the second aluminum layer can include a second cladding surface and a second outer surface.
  • the stainless steel layer is disposed between the first aluminum layer and the second aluminum layer.
  • the first aluminum surface and the second aluminum layer are clad to the stainless steel layer such that the first cladding surface and the second cladding surface are in contact with the stainless steel layer.
  • the first outer surface and the second outer surface are at least partially anodized.
  • FIG. 1 is a block diagram representation of a structure which includes a stainless steel layer on which layers of anodized material are provided in accordance with an embodiment of the present invention.
  • FIG. 2 is a diagrammatic representation of a general process of forming a structure which includes a plurality of anodized layers in accordance with an embodiment of the present invention.
  • FIG. 3 is a process flow diagram which illustrates a method of forming an overall housing that includes a stainless steel layer and at least one anodized layer in accordance with an embodiment of the present invention.
  • FIG. 4 is a block diagram representation of relative thicknesses associated with a three layer housing in accordance with an embodiment of the present invention.
  • FIG. 5 is a block diagram representation of relative thicknesses associated with a two layer housing in accordance with an embodiment of the present invention.
  • FIG. 6A is a diagrammatic representation of a housing prior to a mask being placed over an exposed stainless steel surface in accordance with an embodiment of the present invention.
  • FIG. 6B is a diagrammatic representation of a housing on which a mask has been placed over an exposed stainless steel surface in accordance with an embodiment of the present invention.
  • FIG. 7A is a diagrammatic cross-sectional representation of a section of a masked housing in accordance with an embodiment of the present invention.
  • FIG. 7B is a diagrammatic cross-sectional representation of a section of a masked housing after an anodizing process in accordance with an embodiment of the present invention.
  • FIG. 8 is a diagrammatic top view representation of a structure that includes an etched anodized layer with an underlying stainless steel layer in accordance with an embodiment of the present invention.
  • FIG. 9 is a block diagram representation of a layered structure that includes a stainless steel layer and an aluminum layer which includes an anodized aluminum portion in accordance with an embodiment of the present invention.
  • the strength associated with stainless steel is generally desirable in the formation of housing walls for portable electronic devices including, but not limited to including, mobile phones (e.g., cell phones), portable digital assistants and digital media players.
  • the stiffness associated with stainless steel is also desirable.
  • an anodizable material may be clad to at least one surface of the stainless steel layer and then anodized.
  • a housing may include a stainless steel core that is substantially sandwiched between two layers of anodized material, e.g., anodized aluminum, which have a relatively high bond strength. The layers of anodized material effectively form cosmetic surfaces for the housing, while the stainless steel core provides structural strength, as well as stiffness, for the housing.
  • the structure 100 which includes a stainless steel layer that is sandwiched between layers of anodized material will be described in accordance with an embodiment of the present invention.
  • the structure 100 which may be a wall that is a part of a housing for a portable electronic device, includes a layer of stainless steel 104 .
  • Layer of stainless steel 104 which is effectively a core, has layers of anodized material 108 a, 108 b laminated thereon.
  • layer of stainless steel 104 and layers of anodized material 108 a, 108 b are bonded such that structure 100 is effectively a three-layer metal sandwiched arrangement.
  • FIG. 2 is a diagrammatic representation of a general process of forming a structure which includes a plurality of anodized layers in accordance with an embodiment of the present invention.
  • a stainless steel layer 204 is subjected to a laminating process which allows layers of material 208 a, 208 b to be laminated onto stainless steel layer 204 .
  • the laminating process typically bonds material 208 a, 208 b substantially directly to stainless steel layer 204 .
  • Layers of material 208 a, 208 b are generally formed from anodizable metals, i.e., metals which may be anodized.
  • layers of material 208 a, 208 b may be aluminum, titanium, niobium, or tantalum layers.
  • a laminating process may be substantially any process which allows layers of material 208 a, 208 b to be bonded to stainless steel layer 204 without the use of an intermediate bonding agent. That is, a laminating process may be arranged to allow layers of material 208 a, 208 b to be bonded directly to stainless steel layer 204 .
  • a laminating process may, for example, be a cladding process. As will be understood by those skilled in the art, a cladding is the bonding of metals substantially without an intermediate bonding agent and substantially without remelting the metals.
  • Cladding may take a variety of different forms including, but not limited to including, standard cladding in which layers of material 208 a, 208 b and stainless steel layer 204 are pressed together with roller under high pressure, or fine cladding in which layers of material 208 a, 208 b and stainless steel layer 204 are placed in a vacuum and rolled together after a chemical process is performed.
  • a masking process is used, after layers of material 208 a, 208 b are laminated onto stainless steel layer 204 , to apply masks 212 to cover substantially all exposed areas of stainless steel layer 204 .
  • the exposed areas are generally areas of stainless steel 204 which are not in contact with layers of material 208 a, 208 b.
  • Masks 212 serves to prevent areas of stainless steel layer 204 from oxidizing during an anodizing process arranged to anodize layers of material 208 a, 208 b to form layers of anodized material 208 a ′, 208 b ′.
  • masks 212 may be removed using a de-masking process.
  • a process 301 of forming an overall housing begins at step 305 in which stainless steel which is to be used to from a housing shell is obtained.
  • the stainless steel may be in the form of a stainless steel sheet.
  • a laminant material is clad or otherwise substantially directly bonded to at least one surface of the stainless steel in step 309 .
  • a laminant material such as aluminum may be clad to at least one side of the stainless steel sheet.
  • aluminum such as Al 1100 or Al 5052 may be clad to both sides of a stainless steel sheet to form a sandwich structure or a 3-layer metal arrangement.
  • a sandwich structure will be described as being formed when a laminant material is clad or substantially directly bonded to the stainless steel.
  • the sandwich structure is cut and/or shaped as appropriate in step 313 to form a housing shell.
  • a draw-forming process may be used with respect to the sandwich structure such that the housing shell is formed.
  • a portion of the laminant material may optionally be chemically treated and/or subjected to an overmolding process in step 317 to create a bonding surface.
  • a surface of the housing shell which is intended to form an interior surface of an electronic device may be treated and/or overmolded to provide a bonding surface that allows structures (e.g., internal structures) to be attached.
  • the structures may be plastic structures.
  • the bonding surface may be either a location onto which plastic may be molded, or an attachment point onto which components may be attached, e.g., screwed or otherwise fastened. If a bonding surface is created, then structures may be attached to the bonding surface in optional step 321 . It should be appreciated that the molded structures which are attached in optional step 321 are typically able to withstand an anodizing process.
  • step 325 the surfaces of stainless steel which are exposed, e.g., not in substantially direct contact with the laminant material, are masked in step 325 .
  • a mask is arranged to essentially create a water-tight seal which covers surfaces of the stainless steel, and may generally either be reusable or disposable.
  • a disposable mask is arranged to be used approximately one time.
  • a reusable mask may be formed from a masking material such as silicone rubber or ethylene propylene diene M-class (EPDM) rubber, and may be arranged to be slipped over the exposed surfaces of stainless steel.
  • a disposable mask may be formed from a masking material such as polyvinyl chloride (PVC) or polypropelene (PP), and/or may be arranged to be substantially painted onto or molded onto the exposed surfaces of stainless steel. It should be appreciated that in masking the exposed surface of stainless steel, part of the laminant material may be party covered by or overlapped by a mask.
  • PVC polyvinyl chloride
  • PP polypropelene
  • step 329 in which the laminant material is anodized.
  • Any suitable anodizing process may generally be used to anodize the laminant material.
  • the sandwich structure may be placed in an electrolyte bath as a part of an anodizing process.
  • the anodizing process creates anodized surfaces on the laminant material.
  • the anodized surfaces are created on the laminant material, e.g., aluminum, in the presence of the stainless steel layer. It should be understood, however, that because stainless steel layer is either bonded to the laminant material or masked, substantially only surfaces of laminant material are exposed during an anodizing process.
  • steps 333 and 337 may be substantially combined into the same step.
  • Methods which may be used to remove the areas of laminant material include, but are not limited to including, shearing methods and cutting methods.
  • the cutting methods can, for example, include water jet cutting methods and laser cutting methods.
  • the process of forming an overall housing may be completed after any laminant material which remains unanodized is removed.
  • FIG. 4 is a block diagram representation of relative thicknesses associated with a three-layer metal structure, e.g., a housing, in accordance with an embodiment of the present invention.
  • a structure 400 includes a core stainless steel layer 404 sandwiched between layers of anodized material 408 a, 408 b.
  • Stainless steel layer 404 has a thickness D, while layer of anodized material 408 a has a thickness H 1 and layer of anodized material 408 b has a thickness H 2 .
  • the sum of thickness H 1 and thickness H 2 is less than or approximately equal to half of thickness D.
  • thickness D may be approximately 0.35 millimeters (mm)
  • thickness H 1 may be approximately 0.05 mm
  • thickness H 2 may be approximately 0.10 mm.
  • the sum of thickness H 1 and thickness H 2 is not limited to being less than or approximately equal to half of thickness D.
  • thickness H 1 and thickness H 2 may each be in the range of between approximately 8 microns and approximately 100 microns.
  • thickness H 1 and thickness H 2 are generally greater than approximately 30 microns if anodized material 408 a, 408 b is anodized aluminum.
  • the absolute value of the thicknesses may vary greatly depending on the properties desired in structure 400 .
  • the overall thickness of structure 400 may be between approximately 0.30 mm and approximately 2.0 mm, although the overall thickness may generally vary widely. That is, the sum of thickness H 1 , thickness H 2 , and thickness D may be between approximately 0.30 mm and approximately 2.0 mm.
  • a housing 500 includes a core stainless steel layer 504 and a layer of anodized material 508 .
  • Stainless steel layer 504 has a thickness D
  • layer of anodized material 508 has a thickness H 3 .
  • Thickness H 3 is typically less than or approximately equal to half of D. It should be appreciated, however, that thickness H 3 is not limited to being less than or approximately equal to half of D.
  • a three-layer or two-layer metal structure may included areas of exposed stainless steel, or areas in which stainless steel is not substantially covered by a laminant material. Such areas are generally masked prior to an anodizing process to protect the areas of exposed stainless steel from oxidizing or rusting.
  • an edge of a housing formed from a three-layer metal assembly may be masked with a masking material such that substantially only laminant material, as for example aluminum, is exposed.
  • FIG. 6A is a diagrammatic representation of a housing on which a mask is to be placed
  • FIG. 6B is a diagrammatic representation of the same housing after a mask has been placed over an exposed stainless steel surface in accordance with an embodiment of the present invention.
  • a housing 620 may be a housing that is to be a part of an overall assembly, as for example a bottom of a cell phone assembly. As shown in FIG. 6B , a mask 624 is applied to a top edge of housing 620 .
  • FIG. 7A is a diagrammatic cross-sectional representation of a section of a masked housing in which a mask partially overlaps areas of laminant material accordance with an embodiment of the present invention.
  • a housing 720 includes a stainless steel core 704 that is sandwiched between layers of laminant material 708 a, 708 b. It should be appreciated that layers of laminant material 708 a, 708 b are generally layers of anodizable material, e.g., aluminum.
  • a mask 724 is arranged over a surface 726 of stainless steel core 704 which is not in contact with layers of laminant material 708 a, 708 b.
  • Mask 724 is typically formed from a complaint material which does not react to acid solutions used in an anodizing process, and protects surface 726 from oxidizing during the anodizing process.
  • FIG. 7B is a diagrammatic cross-sectional representation of housing 720 after an anodizing process in accordance with an embodiment of the present invention. After an anodizing process, layers of laminant material 708 a, 708 b are effectively anodized, with the exception of areas 728 which remain substantially unanodized. Areas 728 are unanodized due to mask 724 overlying areas 728 .
  • Mask 724 effectively prevents solutions, as for example acid solutions, used in an anodizing process from coming into contact with areas 728 .
  • areas 728 may be removed from housing 720 using a shearing or cutting process.
  • Mask 724 may also be removed from housing 720 using the same shearing or cutting process used to remove areas 728 .
  • a layer of anodized metal may be etched such that the underlying stainless steel layer is at least partially exposed.
  • the layer of anodized metal may be machined or etched to expose the stainless steel layer for welding purposes, e.g., when features are to be welded to the stainless steel layer.
  • FIG. 8 is a diagrammatic top view representation of a structure that includes an etched anodized layer with an underlying stainless steel layer in accordance with an embodiment of the present invention.
  • a structure 800 includes a layer of anodized material 808 , which may be a layer of anodized aluminum. Areas of layer of anodized material 808 may be etched or otherwise removed such that underlying portions of a stainless steel layer 804 are exposed.
  • FIG. 9 is a block diagram representation of a layered structure that includes a stainless steel layer and an aluminum layer which includes an anodized aluminum portion in accordance with an embodiment of the present invention.
  • a structure 900 includes a stainless steel layer 904 and at least one anodized material layer 908 .
  • anodized material layer 908 is composed of aluminum. After an anodizing process, anodized material layer 908 is such that it includes anodized aluminum 910 a and unanodized aluminum 910 b.
  • anodized aluminum 910 a forms a top surface of anodized material layer 908
  • unanodized aluminum 910 b is bonded to stainless steel layer 904 .
  • laminant layers have been described as being clad to a stainless steel layer, laminant layers are not limited to being clad to a stainless steel layer.
  • a housing wall is not limited to including a stainless steel layer that provides strength.
  • a three-layer metal sandwiched arrangement may include substantially any core to which a laminant layer may be clad or otherwise bonded prior to an anodizing process.
  • an anodized layer may be etched to expose an underlying stainless steel layer.
  • an anodized aluminum layer may be etched to expose the stainless to which the anodized aluminum layer is clad. It should be appreciated that an anodized aluminum layer may also be etched to expose an unanodized aluminum which underlies the anodized aluminum layer.
  • a mask used to prevent stainless steel from oxidizing during an anodizing process is a disposable mask
  • the steps of removing a mask and removing areas of laminant material which were not anodized due to being covered by the mask may be combined into a singled step.
  • a shearing or cutting process used to remove areas of laminant material which were not anodized may also remove a mask that effectively prevented the areas of laminant material from being anodized.
  • plastic may effectively be overmolded on a bonding face after that face has been anodized. That is, molded structures may be attached to an anodized bonding surface in some instances. Anodizing may be removed in selected areas, e.g., using laser etching, to form a surface onto which a molded structure may be attached using a process such as a nano molding process.

Abstract

Methods and apparatus for forming a multi-layered metal structure that includes an anodized surface are disclosed. According to one aspect, a housing arrangement can include a stainless steel layer and at least a first layer. The first layer can have a first bonding surface and a first exterior surface. The first bonding surface can be substantially bonded in direct contact with the stainless steel layer, and the first exterior surface can be an exterior of the housing arrangement. The first exterior surface is an anodized surface. In one embodiment, the first layer can be formed from an anodizable material such as aluminum, titanium, niobium, or tantalum.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application claims priority to U.S. Provisional Patent Application No. 61/140,827, filed Dec. 24, 2008, and entitled “Compact Device Housing and Assembly Techniques Therefor,” which is hereby incorporated herein by reference.
  • BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to the formation of housings for use in electronic devices and, more particularly, to forming cosmetic surfaces on stainless steel housing parts.
  • 2. Description of the Related Art
  • Many devices, e.g., portable electronic devices such as cell phones and media players, include housing walls formed from structurally strong and stiff materials such as stainless steel. The strength provided by materials such a stainless steel enables housing walls to protect internal components of portable electronic devices, and enhances the durability of such devices.
  • In some applications, while stainless steel provides desirable strength characteristics for housing walls, the stainless steel may not provide acceptable cosmetic characteristics. For example, a stainless steel surface is often relatively easy to scratch, and a scratched stainless steel surface may be unappealing. Although anodizing processes may be used on some metals in order to effectively provide a scratch-resistant surface, stainless steel may not be anodized, as rust forms on stainless steel due to oxidation. Hence, for applications in which cosmetic appeal is a relatively important feature, the use of stainless steel may be undesirable.
  • Metals such as aluminum may be anodized to prevent scratching. That is, the surface of some metals, such as aluminum, may be anodized such that the surface becomes substantially scratch-resistant. However, aluminum is relatively weak structurally. Hence, while an aluminum surface may be anodized to protect the surface from being scratched, the use of aluminum as a housing may be undesirable due to the lack of structural strength associated with aluminum.
  • Therefore, what is needed is a method and an apparatus which enables a relatively strong, cosmetically-appealing housing wall to be created.
  • SUMMARY OF THE INVENTION
  • The present invention pertains to creating a housing structure, such as a housing wall, that includes a stainless steel core and one or more anodized, cosmetic outer surfaces. The present invention may be implemented in numerous ways, including, but not limited to, as a method, system, device, or apparatus. Example embodiments of the present invention are discussed below.
  • According to one embodiment of the present invention, a housing arrangement can include a stainless steel layer and at least a first layer. The first layer can have a first bonding surface and a first exterior surface. The first bonding surface can be substantially bonded in direct contact with the stainless steel layer, and the first exterior surface can be an exterior of the housing arrangement. The first exterior surface can be an anodized surface. In one embodiment, the first layer is formed from an anodizable material such as aluminum, titanium, niobium, or tantalum.
  • According to another embodiment of the present invention, a method for forming a housing arrangement can include directly bonding at least a first laminant layer to a stainless steel layer, and masking at least one surface of the stainless steel layer that is not directly bonded to the first laminant layer. Masking the surface of the stainless steel layer includes applying a mask to the surface of the stainless steel layer. The method can also include anodizing the first laminant layer such that the surface of the stainless steel that is masked is not anodized. Anodizing the first laminant layer causes a surface of the first laminant layer to be anodized. The mask is removed from the surface of the stainless steel layer after the first laminant layer is anodized. In one embodiment, directly bonding the first laminant layer to the stainless steel layer includes cladding the first laminant layer to the stainless steel layer.
  • In accordance with still another embodiment of the present invention, a housing wall that is suitable for use in a portable electronic device can include a first aluminum layer, a second aluminum layer, and a stainless steel layer. The first aluminum layer can include a first cladding surface and a first outer surface, and the second aluminum layer can include a second cladding surface and a second outer surface. The stainless steel layer is disposed between the first aluminum layer and the second aluminum layer. The first aluminum surface and the second aluminum layer are clad to the stainless steel layer such that the first cladding surface and the second cladding surface are in contact with the stainless steel layer. The first outer surface and the second outer surface are at least partially anodized.
  • Other aspects and advantages of the invention will become apparent from the following detailed description taken in conjunction with the accompanying drawings which illustrate, by way of example, the principles of the invention.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The invention will be readily understood by the following detailed description in conjunction with the accompanying drawings, in which:
  • FIG. 1 is a block diagram representation of a structure which includes a stainless steel layer on which layers of anodized material are provided in accordance with an embodiment of the present invention.
  • FIG. 2 is a diagrammatic representation of a general process of forming a structure which includes a plurality of anodized layers in accordance with an embodiment of the present invention.
  • FIG. 3 is a process flow diagram which illustrates a method of forming an overall housing that includes a stainless steel layer and at least one anodized layer in accordance with an embodiment of the present invention.
  • FIG. 4 is a block diagram representation of relative thicknesses associated with a three layer housing in accordance with an embodiment of the present invention.
  • FIG. 5 is a block diagram representation of relative thicknesses associated with a two layer housing in accordance with an embodiment of the present invention.
  • FIG. 6A is a diagrammatic representation of a housing prior to a mask being placed over an exposed stainless steel surface in accordance with an embodiment of the present invention.
  • FIG. 6B is a diagrammatic representation of a housing on which a mask has been placed over an exposed stainless steel surface in accordance with an embodiment of the present invention.
  • FIG. 7A is a diagrammatic cross-sectional representation of a section of a masked housing in accordance with an embodiment of the present invention.
  • FIG. 7B is a diagrammatic cross-sectional representation of a section of a masked housing after an anodizing process in accordance with an embodiment of the present invention.
  • FIG. 8 is a diagrammatic top view representation of a structure that includes an etched anodized layer with an underlying stainless steel layer in accordance with an embodiment of the present invention.
  • FIG. 9 is a block diagram representation of a layered structure that includes a stainless steel layer and an aluminum layer which includes an anodized aluminum portion in accordance with an embodiment of the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Example embodiments of the present invention are discussed below with reference to the various figures. However, those skilled in the art will readily appreciate that the detailed description given herein with respect to these figures is for explanatory purposes, as the invention extends beyond these embodiments.
  • The strength associated with stainless steel is generally desirable in the formation of housing walls for portable electronic devices including, but not limited to including, mobile phones (e.g., cell phones), portable digital assistants and digital media players. The stiffness associated with stainless steel is also desirable. However, the cosmetic properties of stainless steel are often lacking. To provide a cosmetic surface for a housing that effectively derives its strength from a stainless steel layer, an anodizable material may be clad to at least one surface of the stainless steel layer and then anodized. In one embodiment, a housing may include a stainless steel core that is substantially sandwiched between two layers of anodized material, e.g., anodized aluminum, which have a relatively high bond strength. The layers of anodized material effectively form cosmetic surfaces for the housing, while the stainless steel core provides structural strength, as well as stiffness, for the housing.
  • Referring initially to FIG. 1, a structure 100 which includes a stainless steel layer that is sandwiched between layers of anodized material will be described in accordance with an embodiment of the present invention. The structure 100, which may be a wall that is a part of a housing for a portable electronic device, includes a layer of stainless steel 104. Layer of stainless steel 104, which is effectively a core, has layers of anodized material 108 a, 108 b laminated thereon. In general, layer of stainless steel 104 and layers of anodized material 108 a, 108 b are bonded such that structure 100 is effectively a three-layer metal sandwiched arrangement.
  • A structure such as structure 100 which includes a stainless steel layer and at least one anodized metal layer may be formed such that an anodizing process occurs after the stainless steel layer is bonded to an anodizable, but still substantially unanodized, metal layer. FIG. 2 is a diagrammatic representation of a general process of forming a structure which includes a plurality of anodized layers in accordance with an embodiment of the present invention. A stainless steel layer 204 is subjected to a laminating process which allows layers of material 208 a, 208 b to be laminated onto stainless steel layer 204. The laminating process typically bonds material 208 a, 208 b substantially directly to stainless steel layer 204.
  • Layers of material 208 a, 208 b are generally formed from anodizable metals, i.e., metals which may be anodized. In one embodiment, layers of material 208 a, 208 b may be aluminum, titanium, niobium, or tantalum layers.
  • A laminating process may be substantially any process which allows layers of material 208 a, 208 b to be bonded to stainless steel layer 204 without the use of an intermediate bonding agent. That is, a laminating process may be arranged to allow layers of material 208 a, 208 b to be bonded directly to stainless steel layer 204. A laminating process may, for example, be a cladding process. As will be understood by those skilled in the art, a cladding is the bonding of metals substantially without an intermediate bonding agent and substantially without remelting the metals. Cladding may take a variety of different forms including, but not limited to including, standard cladding in which layers of material 208 a, 208 b and stainless steel layer 204 are pressed together with roller under high pressure, or fine cladding in which layers of material 208 a, 208 b and stainless steel layer 204 are placed in a vacuum and rolled together after a chemical process is performed.
  • A masking process is used, after layers of material 208 a, 208 b are laminated onto stainless steel layer 204, to apply masks 212 to cover substantially all exposed areas of stainless steel layer 204. The exposed areas are generally areas of stainless steel 204 which are not in contact with layers of material 208 a, 208 b. Masks 212 serves to prevent areas of stainless steel layer 204 from oxidizing during an anodizing process arranged to anodize layers of material 208 a, 208 b to form layers of anodized material 208 a′, 208 b′. After an anodizing process is completed and layers of anodized material 208 a′, 208 b′ are formed, masks 212 may be removed using a de-masking process.
  • With reference to FIG. 3, a process 301 of forming an overall housing that includes a stainless steel layer and at least one anodized layer will be described in accordance with an embodiment of the present invention. A process 301 of forming an overall housing begins at step 305 in which stainless steel which is to be used to from a housing shell is obtained. The stainless steel may be in the form of a stainless steel sheet.
  • After the stainless steel is obtained, a laminant material is clad or otherwise substantially directly bonded to at least one surface of the stainless steel in step 309. By way of example, if the stainless steel is in the form of a stainless steel sheet, a laminant material such as aluminum may be clad to at least one side of the stainless steel sheet. In one embodiment, aluminum such as Al 1100 or Al 5052 may be clad to both sides of a stainless steel sheet to form a sandwich structure or a 3-layer metal arrangement. For ease of discussion, a sandwich structure will be described as being formed when a laminant material is clad or substantially directly bonded to the stainless steel.
  • Once the sandwich structure is formed, the sandwich structure is cut and/or shaped as appropriate in step 313 to form a housing shell. A draw-forming process may be used with respect to the sandwich structure such that the housing shell is formed. Once a housing shell is formed, a portion of the laminant material may optionally be chemically treated and/or subjected to an overmolding process in step 317 to create a bonding surface. By way of example, a surface of the housing shell which is intended to form an interior surface of an electronic device may be treated and/or overmolded to provide a bonding surface that allows structures (e.g., internal structures) to be attached. The structures may be plastic structures. In one embodiment, the bonding surface may be either a location onto which plastic may be molded, or an attachment point onto which components may be attached, e.g., screwed or otherwise fastened. If a bonding surface is created, then structures may be attached to the bonding surface in optional step 321. It should be appreciated that the molded structures which are attached in optional step 321 are typically able to withstand an anodizing process.
  • In step 325, the surfaces of stainless steel which are exposed, e.g., not in substantially direct contact with the laminant material, are masked in step 325. A mask is arranged to essentially create a water-tight seal which covers surfaces of the stainless steel, and may generally either be reusable or disposable. A disposable mask is arranged to be used approximately one time. A reusable mask may be formed from a masking material such as silicone rubber or ethylene propylene diene M-class (EPDM) rubber, and may be arranged to be slipped over the exposed surfaces of stainless steel. A disposable mask may be formed from a masking material such as polyvinyl chloride (PVC) or polypropelene (PP), and/or may be arranged to be substantially painted onto or molded onto the exposed surfaces of stainless steel. It should be appreciated that in masking the exposed surface of stainless steel, part of the laminant material may be party covered by or overlapped by a mask.
  • From step 325, process flow moves to step 329 in which the laminant material is anodized. Any suitable anodizing process may generally be used to anodize the laminant material. For instance, the sandwich structure may be placed in an electrolyte bath as a part of an anodizing process. The anodizing process creates anodized surfaces on the laminant material. The anodized surfaces are created on the laminant material, e.g., aluminum, in the presence of the stainless steel layer. It should be understood, however, that because stainless steel layer is either bonded to the laminant material or masked, substantially only surfaces of laminant material are exposed during an anodizing process.
  • Once the laminant material is anodized, masks previously positioned over exposed surfaces of stainless steel are removed in step 333. Then, in step 337, any areas of the laminant material which remain unanodized, e.g., because the areas were substantially covered by the mask, are removed. In one embodiment, steps 333 and 337 may be substantially combined into the same step. Methods which may be used to remove the areas of laminant material include, but are not limited to including, shearing methods and cutting methods. The cutting methods can, for example, include water jet cutting methods and laser cutting methods. The process of forming an overall housing may be completed after any laminant material which remains unanodized is removed.
  • When a sandwich structure is formed, the thickness of the anodized layers are generally a function of the thickness of a core, e.g., stainless steel, layer. FIG. 4 is a block diagram representation of relative thicknesses associated with a three-layer metal structure, e.g., a housing, in accordance with an embodiment of the present invention. A structure 400 includes a core stainless steel layer 404 sandwiched between layers of anodized material 408 a, 408 b. Stainless steel layer 404 has a thickness D, while layer of anodized material 408 a has a thickness H1 and layer of anodized material 408 b has a thickness H2. In the described embodiment, the sum of thickness H1 and thickness H2 is less than or approximately equal to half of thickness D. By way of example, thickness D may be approximately 0.35 millimeters (mm), thickness H1 may be approximately 0.05 mm, and thickness H2 may be approximately 0.10 mm. It should be appreciated, however, that the sum of thickness H1 and thickness H2 is not limited to being less than or approximately equal to half of thickness D. For instance, thickness H1 and thickness H2 may each be in the range of between approximately 8 microns and approximately 100 microns. In one embodiment, thickness H1 and thickness H2 are generally greater than approximately 30 microns if anodized material 408 a, 408 b is anodized aluminum.
  • In general, the absolute value of the thicknesses may vary greatly depending on the properties desired in structure 400. The overall thickness of structure 400 may be between approximately 0.30 mm and approximately 2.0 mm, although the overall thickness may generally vary widely. That is, the sum of thickness H1, thickness H2, and thickness D may be between approximately 0.30 mm and approximately 2.0 mm.
  • Referring next to FIG. 5, the relative thicknesses of layers included in a two-layer metal structure, e.g., a housing in which only one surface of stainless steel is covered by a laminant material such as aluminum, will be described in accordance with an embodiment of the present invention. A housing 500 includes a core stainless steel layer 504 and a layer of anodized material 508. Stainless steel layer 504 has a thickness D, and layer of anodized material 508 has a thickness H3. Thickness H3 is typically less than or approximately equal to half of D. It should be appreciated, however, that thickness H3 is not limited to being less than or approximately equal to half of D.
  • As described above, a three-layer or two-layer metal structure may included areas of exposed stainless steel, or areas in which stainless steel is not substantially covered by a laminant material. Such areas are generally masked prior to an anodizing process to protect the areas of exposed stainless steel from oxidizing or rusting. In one embodiment, an edge of a housing formed from a three-layer metal assembly may be masked with a masking material such that substantially only laminant material, as for example aluminum, is exposed. FIG. 6A is a diagrammatic representation of a housing on which a mask is to be placed, and FIG. 6B is a diagrammatic representation of the same housing after a mask has been placed over an exposed stainless steel surface in accordance with an embodiment of the present invention. A housing 620 may be a housing that is to be a part of an overall assembly, as for example a bottom of a cell phone assembly. As shown in FIG. 6B, a mask 624 is applied to a top edge of housing 620.
  • A mask, such as mask 624, may partially overlap or cover areas of laminant material. FIG. 7A is a diagrammatic cross-sectional representation of a section of a masked housing in which a mask partially overlaps areas of laminant material accordance with an embodiment of the present invention. A housing 720 includes a stainless steel core 704 that is sandwiched between layers of laminant material 708 a, 708 b. It should be appreciated that layers of laminant material 708 a, 708 b are generally layers of anodizable material, e.g., aluminum.
  • A mask 724 is arranged over a surface 726 of stainless steel core 704 which is not in contact with layers of laminant material 708 a, 708 b. Mask 724 is typically formed from a complaint material which does not react to acid solutions used in an anodizing process, and protects surface 726 from oxidizing during the anodizing process.
  • Often, the application of mask 724 is such that layers of laminant material 708 a, 708 b are partly covered by mask 724. As such, the parts of layers of laminant material 708 a, 708 b which are party covered by mask 724 may be prevented from being anodized during an anodizing process. FIG. 7B is a diagrammatic cross-sectional representation of housing 720 after an anodizing process in accordance with an embodiment of the present invention. After an anodizing process, layers of laminant material 708 a, 708 b are effectively anodized, with the exception of areas 728 which remain substantially unanodized. Areas 728 are unanodized due to mask 724 overlying areas 728. Mask 724 effectively prevents solutions, as for example acid solutions, used in an anodizing process from coming into contact with areas 728.
  • In one embodiment, areas 728 may be removed from housing 720 using a shearing or cutting process. Mask 724 may also be removed from housing 720 using the same shearing or cutting process used to remove areas 728.
  • In one embodiment, a layer of anodized metal may be etched such that the underlying stainless steel layer is at least partially exposed. The layer of anodized metal may be machined or etched to expose the stainless steel layer for welding purposes, e.g., when features are to be welded to the stainless steel layer. FIG. 8 is a diagrammatic top view representation of a structure that includes an etched anodized layer with an underlying stainless steel layer in accordance with an embodiment of the present invention. A structure 800 includes a layer of anodized material 808, which may be a layer of anodized aluminum. Areas of layer of anodized material 808 may be etched or otherwise removed such that underlying portions of a stainless steel layer 804 are exposed.
  • After an anodizing process is performed on an anodizable material which is bonded, e.g., clad, to stainless steel, portions of the anodizable material may remain unanodized. In other words, a top surface of the anodizable material may be anodized, while other parts of the anodizable material are not anodized. If the anodizable material is aluminum, after an anodizing process, a top surface may be anodized aluminum while underlying areas are unanodized aluminum. FIG. 9 is a block diagram representation of a layered structure that includes a stainless steel layer and an aluminum layer which includes an anodized aluminum portion in accordance with an embodiment of the present invention. A structure 900 includes a stainless steel layer 904 and at least one anodized material layer 908. In the described embodiment, anodized material layer 908 is composed of aluminum. After an anodizing process, anodized material layer 908 is such that it includes anodized aluminum 910 a and unanodized aluminum 910 b. Typically, anodized aluminum 910 a forms a top surface of anodized material layer 908, while unanodized aluminum 910 b is bonded to stainless steel layer 904.
  • Although only a few embodiments of the present invention have been described, it should be understood that the present invention may be embodied in many other specific forms without departing from the spirit or the scope of the present invention. By way of example, while a structure which includes a stainless steel layer and at least one anodized layer has been described as being used for a housing wall, such a structure is not limited to being used as a housing wall. A structure which includes a stainless steel layer and one or more anodized layers bonded therethrough may generally be used in substantially any application in which the strength associated with stainless steel and the cosmetic appeal of an anodized layer are desired.
  • While laminant layers have been described as being clad to a stainless steel layer, laminant layers are not limited to being clad to a stainless steel layer. In other words, a housing wall is not limited to including a stainless steel layer that provides strength. Instead of including a stainless steel core, for instance, a three-layer metal sandwiched arrangement may include substantially any core to which a laminant layer may be clad or otherwise bonded prior to an anodizing process.
  • As shown in FIG. 8, an anodized layer may be etched to expose an underlying stainless steel layer. For instance, an anodized aluminum layer may be etched to expose the stainless to which the anodized aluminum layer is clad. It should be appreciated that an anodized aluminum layer may also be etched to expose an unanodized aluminum which underlies the anodized aluminum layer.
  • The operations associated with the various methods of the present invention may vary widely. Steps may be added, removed, altered, combined, and reordered without departing from the spirit or the scope of the present invention. By way of example, if a mask used to prevent stainless steel from oxidizing during an anodizing process is a disposable mask, the steps of removing a mask and removing areas of laminant material which were not anodized due to being covered by the mask may be combined into a singled step. In other words, a shearing or cutting process used to remove areas of laminant material which were not anodized may also remove a mask that effectively prevented the areas of laminant material from being anodized.
  • In one embodiment, plastic may effectively be overmolded on a bonding face after that face has been anodized. That is, molded structures may be attached to an anodized bonding surface in some instances. Anodizing may be removed in selected areas, e.g., using laser etching, to form a surface onto which a molded structure may be attached using a process such as a nano molding process.
  • The many features and advantages of the present invention are apparent from the written description. Further, since numerous modifications and changes will readily occur to those skilled in the art, the invention should not be limited to the exact construction and operation as illustrated and described. Hence, all suitable modifications and equivalents may be resorted to as falling within the scope of the invention.

Claims (21)

1. A housing arrangement comprising:
a stainless steel layer; and
at least a first layer, the first layer having a first bonding surface and a first exterior surface, the first bonding surface being bonded in direct contact with the stainless steel layer, the first exterior surface being an exterior of the housing arrangement, wherein the first exterior surface is anodized.
2. The housing arrangement of claim 1 wherein the first layer is formed from one selected from the group including aluminum, titanium, niobium, and tantalum.
3. The housing arrangement of claim 1 wherein the first bonding surface is clad to the stainless steel layer.
4. The housing arrangement of claim 1 wherein the first layer is a first aluminum layer, and the first exterior surface is a first anodized aluminum surface.
5. The housing arrangement of claim 4 wherein the first anodized aluminum surface has a thickness of between approximately 8 microns and approximately 50 microns.
6. The housing arrangement of claim 4 further including:
a second aluminum layer, the second aluminum layer having a second bonding surface and an attachment surface, the second bonding surface being bonded in direct contact with the stainless steel layer such that the stainless steel layer is sandwiched between the first aluminum layer and the second aluminum layer, the attachment surface being arranged to allow structures to be attached thereon.
7. The housing arrangement of claim 6 wherein the structures are plastic structures and the attachment surface provides a bonding surface for the plastic structures.
8. The housing arrangement of claim 6 wherein the attachment surface is at least partially anodized.
9. The housing arrangement of claim 8 wherein the attachment surface includes aluminum and anodized aluminum.
10. The housing arrangement of claim 1 wherein the stainless steel layer has a first thickness and the at least first layer has a thickness that is less than or approximately equal to one half of the first thickness.
11. A method for forming a housing arrangement comprising:
directly bonding at least a first laminant layer to a stainless steel layer;
masking at least one surface of the stainless steel layer that is not directly bonded to the at least first laminant layer, wherein masking the at least one surface of the stainless steel layer includes applying a mask to the at least one surface of the stainless steel layer;
anodizing the at least first laminant layer, wherein the at least one surface of the stainless steel that is masked is not anodized, wherein anodizing the at least first laminant layer causes a surface of the at least first laminant layer to be anodized; and
subsequently removing the mask from the at least one surface of the stainless steel layer.
12. The method of claim 11 wherein directly bonding the at least first laminant layer to the stainless steel layer includes cladding the at least first laminant layer to the stainless steel layer.
13. The method of claim 11 further comprising:
removing an area that masking the at least one surface of the stainless steel layer prevented the area from being anodized.
14. The method of claim 11 further comprising:
directly bonding a second laminant layer to the stainless steel layer, wherein the stainless steel layer is disposed between the first laminant layer and the second laminant layer.
15. The method of claim 11 wherein the at least first laminant layer is formed from at least one selected from a group including aluminum, titanium, niobium, and tantalum.
16. The method of claim 11 further comprising:
chemically treating at least a portion of the at least first laminant layer to create an attachment surface; and
attaching at least one structure to the attachment surface.
17. The method of claim 16 wherein the at least one structure is a molded structure.
18. A housing wall suitable for use in a portable electronic device, the housing wall comprising:
a first aluminum layer, the first aluminum layer including a first cladding surface and a first outer surface;
a second aluminum layer, the second aluminum layer including a second cladding surface and a second outer surface; and
a stainless steel layer, the stainless steel layer being disposed between the first aluminum layer and the second aluminum layer, the first aluminum surface and the second aluminum layer being clad to the stainless steel layer such that the first cladding surface and the second cladding surface are in contact with the stainless steel layer, wherein the first outer surface and the second outer surface are at least partially anodized.
19. The housing wall of claim 18 wherein the second outer surface having attached thereto at least one part that is to be contained by the housing wall.
20. The housing wall of claim 18 wherein the first outer surface has a thickness of between approximately 8 microns and approximately 50 microns and the second outer surface has a thickness of between approximately 8 microns and approximately 50 microns.
21. The housing wall of claim 18 wherein the stainless steel layer has a first thickness, and wherein the first aluminum layer and the second aluminum layer have a combined thickness that is less than or approximately equal to one half of the first thickness.
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