US20070266503A1 - Airlaid Method with an Improved Through-Put Rate - Google Patents
Airlaid Method with an Improved Through-Put Rate Download PDFInfo
- Publication number
- US20070266503A1 US20070266503A1 US10/561,131 US56113104A US2007266503A1 US 20070266503 A1 US20070266503 A1 US 20070266503A1 US 56113104 A US56113104 A US 56113104A US 2007266503 A1 US2007266503 A1 US 2007266503A1
- Authority
- US
- United States
- Prior art keywords
- fibers
- short
- weight
- fibrous nonwoven
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 [2*]N1=CC=N(CNC(=O)O[3*])C1[3*].[4*]S(=O)(=O)O Chemical compound [2*]N1=CC=N(CNC(=O)O[3*])C1[3*].[4*]S(=O)(=O)O 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4266—Natural fibres not provided for in group D04H1/425
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43825—Composite fibres
- D04H1/43828—Composite fibres sheath-core
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
- D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/544—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/55—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/732—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by fluid current, e.g. air-lay
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
- A61F2013/15821—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing
- A61F2013/15934—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing for making non-woven
- A61F2013/15943—Apparatus or processes for manufacturing characterized by the apparatus for manufacturing for making non-woven by air-laid technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
- D10B2201/24—Viscose
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
- D10B2509/02—Bandages, dressings or absorbent pads
- D10B2509/026—Absorbent pads; Tampons; Laundry; Towels
Definitions
- the present invention relates to a method for producing a fibrous nonwoven by applying an aerodynamic process (hereinafter referred to as “airlaid process”), a fibrous nonwoven produced according to this method as well as a short fiber suitable for use in said method.
- airlaid process an aerodynamic process
- cellulose fibers have been used in airlaid processes, which cellulose fibers may have minor amounts of other fibers admixed thereto, such as viscose fibers.
- One problem associated particularly with the use of major amounts of viscose fibers resides in that the throughput or capacity achievable in conventional airlaid machinery is substantially lower than when use is made of cellulose fibers only.
- throughput it is meant the weight of fibers transferred to the conveying air stream within a specific period of time.
- considerable deviations in the target basis weight are encountered and thus the quality of the resulting fibrous nonwovens is poor.
- the applicants of the present invention have surprisingly found that, by providing short viscose fibers with a finish, the throughput in an airlaid process can be considerably increased.
- the improvement achieved is in a magnitude which even exceeds the throughput obtainable with the conventional use of cellulose fibers so that it is believed that the process according to the invention is generally applicable independent of the specific fiber used.
- FIG. 1 is a graph illustrating the dependency of the throughput on the moisture content
- FIG. 2 is a graph illustrating the dependency of the throughput on the amount of finish.
- the present invention thus relates to a method for making a fibrous nonwoven, said method comprising the steps of depositing at least one short fiber-including layer by an airlaid process, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with said finish.
- a fibrous nonwoven is understood to be a layer of fibers comprising short fibers in random array.
- Short fibers are defined herein to mean fibers having a length in the range of from 2 to 12 mm.
- short fibers generally account for more than 50 percent by weight, typically more than 60 percent by weight, of the layer.
- Short fibers plus short binder fibers and/or short suberabsorbent fibers generally account for more than 90 percent by weight, typically more than 95 percent by weight, of the layer.
- At least a fraction of the short fibers is provided with the finish.
- at least 5 percent by weight of the short fibers are provided with the finish, preferably at least 10 percent by weight such as at least 25 percent by weight, for example, at least 50 percent by weight.
- An example for the use of fiber blends is a blend wherein, e.g., preferably more than 25%, particularly more than 50%, for example, the total of the short fibers involving problems as far as the throughput is concerned, such as viscose fibers, are provided with the finish, while the short fibers which are unproblematic to use comprise no finish.
- substantially all short fibers used in the airlaid process can be provided with the finish.
- a binder material may be airlaid in addition to the short fibers.
- binder material is generally understood to be materials which, due to their dissolving or melting capacity, are suitable to bind short fibers.
- the binders may be present in arbitrary form, e.g., as powder etc., to the extent that they are suitable for use in an airlaid process.
- binder materials are preferably also used likewise in the form of short fibers, i.e., short binder fibers.
- fibers which, due to their dissolving capacity, are suitable for use as binder fibers are polyvinyl alcohol fibers (PVA fibers) and alginate fibers.
- Fibers which, due to their melting capacity, are suitable for use as binder fibers generally comprise melt adhesives or fibers including thermoplastic material having a lower melting point than the fibers to be bound.
- Melt binder fibers may be used as full-profile fibers or multi-component fibers.
- a preferred melt binder fiber is a two-component fiber (BICO fiber), for example, a bi-component fiber comprising a fiber sheath made of a polymer having a lower melting point than the polymer of the fiber core.
- BICO fiber two-component fiber
- a bi-component fiber comprising a fiber sheath made of a polymer having a lower melting point than the polymer of the fiber core.
- a two-component fiber comprising a polyester core and a polyethylene sheath.
- short binder fiber relates to fibers having a length in the range of from 2 to 12 mm, preferably 4 to 8 mm.
- the short binder fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex such as 3.0 dtex.
- the binder is used in an amount which is eventually determined by the desired properties of the final product. Therefore, the parameters which influence the amount of binder used are the type of binder and the type of fibers or fiber blend to be bound as well as the strength, softness/stiffness and basis weight etc. of the final product. Generally, the amount of binder used is 1 to 30 percent by weight, based on the total weight of the short fibers to be bound and the binder, particularly 1 to 20 percent by weight such as 3 to 10 percent by weight, for example, 5 to 8 percent by weight.
- the moisture content of the short fibers used in the airlaid process has an influence on the throughput. Accordingly, the short fibers used preferably have a moisture content in the range of from 4 to 16%, particularly of from 6 to 14% such as 8 to 12%. The moisture is measured according to the method described hereinbelow.
- Short fibers which are suitable for use in the process according to the invention comprise substantially all fiber types known in the art, i.e., natural fibers, cellulosic man-made fibers, synthetic fibers and inorganic fibers as well as combinations thereof.
- natural fibers are natural vegetable fibers such as cellulose, cotton, jute, flax, hemp and coconut fibers as well as natural animal fibers such as wool or silk.
- Cellulosic man-made fibers comprise regenerated cellulose fibers such as viscose fibers, cuprous fibers and Lyocell fibers.
- Synthetic fibers comprise, for example, polyolefin fibers, polyester fibers and polyamide fibers.
- Inorganic fibers comprise glass fibers, silicate fibers, carbon fibers, boron fibers and metal fibers.
- Preferred for use in the method according to the invention are natural fibers, particularly natural vegetable fibers and cellulosic man-made fibers, in particular cellulose fibers, cotton fibers, viscose fibers and Lyocell fibers.
- the short fibers thus comprise short viscose fibers, at least a fraction of the short viscose fibers being provided with the finish. Preferably, at least 20%, even more preferably at least 50%, of the short viscose fibers are provided with the finish. For example, all of the short viscose fibers are provided with the finish. It is advantageous for the short viscose fibers to have a multi-limbed cross-section, for example, a three-limbed cross-section. Such fibers are known in the art, for example, from U.S. Pat. No. 5,643,914, the disclosure of which is incorporated herein by reference. Fibers having a three-limbed cross-section are, for example, shown in FIGS. 1 to 5 of said document.
- the viscose fibers are used in an amount of more than 85 percent by weight, based on the total weight of the short fibers, particularly in an amount of more than 90 percent by weight such as more than 95 percent by weight.
- exclusively short viscose fibers i.e., 100 percent by weight, are used as the short fibers.
- short fibers have a length in the range of from 2 to 12 mm, preferably a length in the range of from 4 to 8 mm such as 5 to 6 mm. Generally, the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex, for example, about 3.3 dtex.
- a superabsorbent material may be used in addition.
- Superabsorbents (SAP) are well known in the art and are thus not described herein in further detail. SAPs usually consist of acrylate-based polymers and are characterized in that they are capable of absorbing many times their own weight of aqueous fluid.
- the superabsorbent materials are used in the process according to the invention in any suitable form which is compatible with the airlaid process, such as in the form of granules, preferably in the form of fibers, particularly short fibers having a length in the range of from 2 to 12 mm, particularly 4 to 8 mm. If use is made of superabsorbent materials, the amount used is usually 0.1 to 50 percent by weight, particularly 5 to 10 percent by weight, based on the weight of the short fibers (exclusive the amount of short binder fiber which might be present).
- the finish is present in an amount of more than 0.035 percent by weight, based on the weight of the short fibers provided with the finish.
- the finish amount as used herein, is understood to constitute the amount of finish as indicated by the fiber manufacturer to be actually present on the fiber.
- the amounts indicated in this description thus relate to analysis values of the fiber manufacturer (Acordis), as determined by Soxleth extraction, derivatization (methylation) of the sample, gas-chromatographic separation and detection by means of flame-ionization detector.
- the amount of finish, based on the viscose fibers, is preferably more than 0.05 percent by weight, more preferably 0.10 percent by weight, and most preferably more than 0.15 percent by weight.
- the upper limit of the finish amount is the amount at which a further increase of the throughput does not appear to make any sense anymore, for example, due to other limiting process parameters, at which the throughput is nearly optimal and further costs for more finish do not appear to be justified or at which the high finish content results into or contributes to undesired product properties.
- the maximum finish amount is thus governed by the airlaid machinery used, the short fibers or short fiber blends used as well as by the final product and its desired properties.
- the maximum finish amount is 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight, based on the weight of the short fibers provided with the finish.
- the maximum finish amount is 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight, based on the weight of the short fibers provided with the finish.
- analogous finish amounts are contemplated.
- Suitable as finish is any material which, when being present on the surface of the short fibers in the indicated amount, is suitable to improve the throughput of the airlaid process according to the invention.
- the finish is selected from:
- the imidazolinium ethosulfates and methosulfates have generally a structure according to the following general formula (I) wherein R2 is H or a C1-C6 alkyl moiety, R3 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 6 to 22 carbon atoms, which moiety may contain one or more free hydroxyl groups, R4 is methyl or ethyl, r is 2, 3 or 4, and s is 0 or 1.
- R2 and R3 are defined as in the first preferred embodiment, and s is 0.
- R2 is methyl or ethyl, preferably methyl
- R3 is, in each case independently of each other, a hydrocarbon moiety having 6 to 12 carbon atoms, r is 2, and s is 1.
- R3 is an alkyl moiety.
- Examples of ethylene oxide derivatives are the diesters of lauric acid, palmitic acid, oleic acid and/or stearic acid with polyethylene glycol having an average molecular weight of, for example, 400 or 600.
- Examples of sorbitan ester are the ethoxylated derivatives of sorbitan monoesters, diesters and triesters with lauric acid, palmitic acid, oleic acid and/or stearic acid.
- An example of glyceride derivatives is hydrogenated ethoxylated castor oil, and examples of the imidazolinium derivatives are Rewoquat®W75 and Rewoquat®W90 of Degussa.
- the throughput is preferably improved by at least 20%, more preferably by at least 50% and most preferably by at least 100%, as compared to the same short fibers, but without said finish.
- the method according to the invention may be combined with further steps for forming a fibrous layer, particularly a fibrous nonwoven. Accordingly, the process according to the invention can be performed in that the layer which is formed is deposited on a previously formed fibrous sheet.
- the previously formed fibrous sheet may be, for example, a sheet formed by applying an airlaid process, or a sheet formed by applying another process, for example, a spunbond or meltblown sheet, or a combination of such sheets.
- the method according to the invention may comprise the laying of several layers, for example, the laying of two or three layers, if desired, in combination with one or more other sheets, as explained above.
- said fibrous nonwoven may be subjected to further process steps.
- steps comprise, for example, a heat treatment, particularly if thermoplastic binder fibers are used.
- the heat treatment comprises heating the fibrous nonwoven to a temperature above the softening point of the binder fiber or of the component of the binder fiber having the lowest melting point over a period of time which is sufficient to cause the fiber or component to at least partially melt.
- Further optional process steps comprise compacting, embossing, printing etc.
- the present invention also relates to a fibrous nonwoven produced according to the method of the present invention. Accordingly, the present invention also provides a fibrous nonwoven, comprising at least one short fiber-including layer, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with said finish.
- the layer comprises short fibers in an amount of 70 to 99 percent by weight and binder material in an amount of 1 to 30 percent by weight, based on the total weight of short fibers and binder material.
- the binder material is a binder material as described above in respect of the method according to the invention and preferably comprises short binder fibers, particularly multi-component fibers such as bi-component fibers including a polyester core and a polyethylene sheath.
- short binder fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex.
- the short fibers are short fibers as described above in respect of the method according to the invention and preferably comprise natural fibers, particularly natural vegetable fibers and cellulosic man-made fibers, particularly cellulose fibers, cotton fibers, viscose fibers and Lyocell fibers.
- the layer of the fibrous nonwoven according to the invention comprises short viscose fibers, at least a fraction of which is provided with a finish.
- a finish Preferably, at least 20%, more preferably at least 50%, of the short viscose fibers are provided with the finish.
- all of the short viscose fibers are provided with the finish.
- the short viscose fibers have a multi-limbed cross-section such as a three-limbed cross-section.
- the viscose fibers are present in an amount of more than 85 percent by weight, based on the total weight of the short fibers, particularly in an amount of more than 90 percent by weight such as more than 95 percent by weight.
- exclusively short viscose fibers are present as the short fibers.
- the short fibers have a length in the range of from 2 to 12 mm and preferably a length in the range of from 4 to 8 mm such as 5 to 6 mm.
- the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex such as about 3.3 dtex.
- the layer may comprise a superabsorbent material (SAP), preferably in the form of fibers, particularly short fibers, having a length in the range of from 2 to 12 mm, particularly 4 to 8 mm. If use is made of a superabsorbent material, the amount used is usually 0.1 to 50 percent by weight, particularly 5 to 10 percent by weight, based on the weight of the short fibers.
- SAP superabsorbent material
- the finish is present in an amount of more than 0.035 percent by weight, preferably in an amount of more than 0.05 percent by weight, more preferably in an amount of more than 0.10 percent by weight and most preferably in an amount of more than 0.15 percent by weight, the maximum amount being 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight.
- the indicated amounts relate to the weight of the short fibers provided with the finish.
- the finish is a finish as described above in connection with the method according to the invention.
- the fibrous nonwoven according to the invention may also comprise several layers according to the invention and/or other sheets, as explained above.
- the short fiber-including layer of the fibrous nonwoven has a basis weight of 50 to 350 g/m 2 , typically 75 to 250 g/m 2 , particularly 150 to 220 g/m 2 , such as about 180 g/m 2 .
- the density of the layer is generally 0.02 to 0.5 g/cm 3 , typically 0.03 to 0.2 g/cm 3 , particularly 0.04 to 0.1 g/cm 3 .
- the above values relate to the material web as deposited in the airlaid process before compacting process steps, such as calandering or embossing.
- the density is determined by a standard method under a load of 0.2 kPa.
- the short fiber-including layer of the fibrous nonwoven according to the invention has an absorbent capacity of at least 3 g/g fibrous nonwoven, preferably at least 4 g/g, particularly preferred of at least 4.8 g/g.
- the absorbent capacity is measured according to the generally known Syngina test (“Syngina Absorbancy Test”) and in the absence of superabsorbent materials.
- the present invention furthermore relates to a short fiber which is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight.
- the short fiber is a man-made cellulose fiber or a synthetic fiber.
- the short fiber is a viscose fiber which may have a multi-limbed cross-section, such as a three-limbed cross-section.
- the short fiber has a length in the range of from 2 to 12 mm, preferably in the range of from 4 to 8 mm such as 5 to 6 mm.
- the short fiber has a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex, for example, about 3.3 dtex.
- the finish is present in an amount of more than 0.035 percent by weight, preferably more than 0.05 percent by weight, more preferably in an amount of more than 0.10 percent by weight and most preferably in an amount of more than 0.15 percent by weight, the maximum amount being 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight.
- Suitable finish materials are the finish materials described above in connection with the method according to the invention.
- the present invention relates to the use of a short fiber as described above in an airlaid process.
- the invention moreover, relates to an absorbent article comprising a fibrous nonwoven produced according to the method according to the invention and to a fibrous nonwoven as described above, respectively.
- the absorbent article has an absorbent capacity of at least 3 g/g fibrous nonwoven, preferably of at least 4 g/g, particularly preferred of at least 4.8 g/g, as measured by the Syngina test.
- the absorbent article is, for example, a hygiene article, such as a tampon, a sanitary napkin, a diaper or an incontinence article or a household article, industrial article or medical article.
- a hygiene article such as a tampon, a sanitary napkin, a diaper or an incontinence article or a household article, industrial article or medical article.
- the absorbent article according to the invention is a tampon which comprises a helically winding of a short fiber-including layer according to the invention.
- the layer comprises 60 to 100 percent by weight of three-limbed short viscose fibers and 0 to 40 percent by weight of short cellulose fibers, based on the total weight of the short fibers.
- the short cellulose fibers and the short viscose fibers have a length of 4 to 8 mm, preferably of about 6 mm and a length-to-weight ratio of 3 to 4 dtex.
- the layer comprises 5 to 15 percent by weight of a BICO short binder fiber, based on the weight of short fibers and short binder fibers.
- the tampon has an absorbent capacity of at least 4 g/g under load, a stiffness of at least 20N and an expansion capacity of at least 150%.
- Moisture-proof containers are weighed with an accuracy of ⁇ 0.005 g at room temperature and the temperature at which the fiber samples are weighed after oven drying has been performed.
- the values T RT (tare weight at room temperature) and T H (tare weight hot) are recorded. Care must be taken that the determination of G H is performed with open lid.
- a fiber sample (about 5 g) is introduced into the container.
- the container is closed by the lid in moisture-proof manner and weighed with an accuracy of ⁇ 0.005 g.
- the value G RT (weight at room temperature) is recorded.
- the lid is removed from the containers and the container and lid are introduced into a hot air oven with a temperature of 105 ⁇ 3° C.
- Drying is performed over at least three hours, for example, overnight. During drying the oven must not be opened.
- the short fiber was a three-limbed rayon fiber (Danofil VY), obtained by dry-cutting using a guillotine process, with a length-to-weight ratio of 3.3 dtex and a length of 5 mm.
- the finish employed was polyglycol palmitate stearate ester.
- the fibers were then used for producing airlaid nonwovens using a Danweb airlaid line with 4 forming heads and a forming width of 600 mm.
- the airlaid line is suitable for multi-bonding and for producing latex-bonded and thermally bonded products.
- the bore diameter of the forming heads was 4.5 mm.
- the fibers of the samples 1-5 were used in combination with a binder fiber Trevira T255 (PET/PE) with a length-to-weight ratio of 3.0 dtex and a length of 6 mm with a weight ratio of rayon fibers to binder fibers of 93:7.
- the environmental conditions were 23° C. and 73% relative humidity, the target basis weight was 180 to 220 g/m 2 at a density of 0.04 g/cm 3 .
- the highest amount of fibers passing through the forming heads without blocking the forming heads is determined.
- the basis weight must remain stable at target with a maximum variation of ⁇ 10% from the target value in machine and cross direction.
- the maximum capacity is the maximum amount of fibers fed to the forming heads per unit of time measured at the fiber feed metering unit.
- the test was successively performed on samples 1 to 5, i.e., the moisture and/or finish values were increased from test to test to avoid contamination of the system by fibers with higher moisture or finish amounts.
Abstract
The invention relates to a method for producing a fibrous nonwoven by applying an aerodynamic process providing an improved throughput, a fibrous nonwoven produced according to said process, as well as a short fiber suitable for use in said method.
Description
- The present invention relates to a method for producing a fibrous nonwoven by applying an aerodynamic process (hereinafter referred to as “airlaid process”), a fibrous nonwoven produced according to this method as well as a short fiber suitable for use in said method.
- It is known in the art to form fibrous nonwovens by applying airlaid processes. These processes are dry processes wherein the fibers, after having been subjected to opening, are transferred to an air stream and subsequently airlaid on a screen surface.
- So far, primarily cellulose fibers have been used in airlaid processes, which cellulose fibers may have minor amounts of other fibers admixed thereto, such as viscose fibers. One problem associated particularly with the use of major amounts of viscose fibers resides in that the throughput or capacity achievable in conventional airlaid machinery is substantially lower than when use is made of cellulose fibers only. By throughput it is meant the weight of fibers transferred to the conveying air stream within a specific period of time. Moreover, considerable deviations in the target basis weight are encountered and thus the quality of the resulting fibrous nonwovens is poor.
- The applicants of the present application have conducted tests and found that, when use is made solely of commercial quality short viscose fibers in an airlaid process, merely a throughput is achieved which usually accounts for less than 10% of the throughput achievable with cellulose fibers.
- There is thus a need for airlaid processes which enable an increased throughput with a higher amount of viscose fibers and thus allow to make use of the capacity of the production machinery more efficiently.
- The applicants of the present invention have surprisingly found that, by providing short viscose fibers with a finish, the throughput in an airlaid process can be considerably increased. The improvement achieved is in a magnitude which even exceeds the throughput obtainable with the conventional use of cellulose fibers so that it is believed that the process according to the invention is generally applicable independent of the specific fiber used.
- It is principally known in the art to provide fibers with a finish. Fibers which have been provided with a finish are used, for example, in carding processes. However, this is a process which is principally different and, moreover, uses longer fibers. According to the applicants' todays' knowledge, there has so far been no reason to use fibers with a finish in airlaid processes.
- The invention will be described in detail hereinafter with reference to the attached drawings, wherein:
-
FIG. 1 is a graph illustrating the dependency of the throughput on the moisture content, and -
FIG. 2 is a graph illustrating the dependency of the throughput on the amount of finish. - The present invention thus relates to a method for making a fibrous nonwoven, said method comprising the steps of depositing at least one short fiber-including layer by an airlaid process, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with said finish.
- As used herein, a fibrous nonwoven is understood to be a layer of fibers comprising short fibers in random array. Short fibers are defined herein to mean fibers having a length in the range of from 2 to 12 mm. The term short fibers, as used herein, includes all short fibers used in the process, exclusive short binder fibers and superabsorbent fibers which might be present. A “short fiber-including layer”, as used herein, means a layer wherein the fibers which primarily constitute said layer are short fibers, but additional materials such as binder materials, superabsorbents etc. may be present in the form of longer fibers or in a form other than fibers. If binder materials and/or superabsorbents are present and are not present in the form of short fibers, the short fibers generally account for more than 50 percent by weight, typically more than 60 percent by weight, of the layer. Short fibers plus short binder fibers and/or short suberabsorbent fibers generally account for more than 90 percent by weight, typically more than 95 percent by weight, of the layer.
- According to the invention, at least a fraction of the short fibers is provided with the finish. Generally, at least 5 percent by weight of the short fibers are provided with the finish, preferably at least 10 percent by weight such as at least 25 percent by weight, for example, at least 50 percent by weight. An example for the use of fiber blends is a blend wherein, e.g., preferably more than 25%, particularly more than 50%, for example, the total of the short fibers involving problems as far as the throughput is concerned, such as viscose fibers, are provided with the finish, while the short fibers which are unproblematic to use comprise no finish. Alternatively, substantially all short fibers used in the airlaid process can be provided with the finish.
- According to a special embodiment of the method according to the invention, a binder material may be airlaid in addition to the short fibers. As used herein, binder material is generally understood to be materials which, due to their dissolving or melting capacity, are suitable to bind short fibers. The binders may be present in arbitrary form, e.g., as powder etc., to the extent that they are suitable for use in an airlaid process. However, binder materials are preferably also used likewise in the form of short fibers, i.e., short binder fibers.
- Examples of fibers which, due to their dissolving capacity, are suitable for use as binder fibers are polyvinyl alcohol fibers (PVA fibers) and alginate fibers. Fibers which, due to their melting capacity, are suitable for use as binder fibers generally comprise melt adhesives or fibers including thermoplastic material having a lower melting point than the fibers to be bound. Melt binder fibers may be used as full-profile fibers or multi-component fibers. A preferred melt binder fiber is a two-component fiber (BICO fiber), for example, a bi-component fiber comprising a fiber sheath made of a polymer having a lower melting point than the polymer of the fiber core. One example for such a fiber is a two-component fiber comprising a polyester core and a polyethylene sheath.
- The term “short binder fiber”, as used herein, relates to fibers having a length in the range of from 2 to 12 mm, preferably 4 to 8 mm. Generally, the short binder fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex such as 3.0 dtex.
- The binder is used in an amount which is eventually determined by the desired properties of the final product. Therefore, the parameters which influence the amount of binder used are the type of binder and the type of fibers or fiber blend to be bound as well as the strength, softness/stiffness and basis weight etc. of the final product. Generally, the amount of binder used is 1 to 30 percent by weight, based on the total weight of the short fibers to be bound and the binder, particularly 1 to 20 percent by weight such as 3 to 10 percent by weight, for example, 5 to 8 percent by weight.
- The inventors have also found that the moisture content of the short fibers used in the airlaid process has an influence on the throughput. Accordingly, the short fibers used preferably have a moisture content in the range of from 4 to 16%, particularly of from 6 to 14% such as 8 to 12%. The moisture is measured according to the method described hereinbelow.
- Short fibers which are suitable for use in the process according to the invention comprise substantially all fiber types known in the art, i.e., natural fibers, cellulosic man-made fibers, synthetic fibers and inorganic fibers as well as combinations thereof. Examples of natural fibers are natural vegetable fibers such as cellulose, cotton, jute, flax, hemp and coconut fibers as well as natural animal fibers such as wool or silk. Cellulosic man-made fibers comprise regenerated cellulose fibers such as viscose fibers, cuprous fibers and Lyocell fibers. Synthetic fibers comprise, for example, polyolefin fibers, polyester fibers and polyamide fibers. Inorganic fibers comprise glass fibers, silicate fibers, carbon fibers, boron fibers and metal fibers.
- Preferred for use in the method according to the invention are natural fibers, particularly natural vegetable fibers and cellulosic man-made fibers, in particular cellulose fibers, cotton fibers, viscose fibers and Lyocell fibers.
- As mentioned above, the method according to the present invention was originally developed for use of a high amount of viscose fibers. According to a preferred embodiment of the invention, the short fibers thus comprise short viscose fibers, at least a fraction of the short viscose fibers being provided with the finish. Preferably, at least 20%, even more preferably at least 50%, of the short viscose fibers are provided with the finish. For example, all of the short viscose fibers are provided with the finish. It is advantageous for the short viscose fibers to have a multi-limbed cross-section, for example, a three-limbed cross-section. Such fibers are known in the art, for example, from U.S. Pat. No. 5,643,914, the disclosure of which is incorporated herein by reference. Fibers having a three-limbed cross-section are, for example, shown in FIGS. 1 to 5 of said document.
- According to this embodiment, the viscose fibers are used in an amount of more than 85 percent by weight, based on the total weight of the short fibers, particularly in an amount of more than 90 percent by weight such as more than 95 percent by weight. For example, exclusively short viscose fibers, i.e., 100 percent by weight, are used as the short fibers.
- As defined herein, short fibers have a length in the range of from 2 to 12 mm, preferably a length in the range of from 4 to 8 mm such as 5 to 6 mm. Generally, the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex, for example, about 3.3 dtex. In the process according to the invention a superabsorbent material may be used in addition. Superabsorbents (SAP) are well known in the art and are thus not described herein in further detail. SAPs usually consist of acrylate-based polymers and are characterized in that they are capable of absorbing many times their own weight of aqueous fluid. The superabsorbent materials are used in the process according to the invention in any suitable form which is compatible with the airlaid process, such as in the form of granules, preferably in the form of fibers, particularly short fibers having a length in the range of from 2 to 12 mm, particularly 4 to 8 mm. If use is made of superabsorbent materials, the amount used is usually 0.1 to 50 percent by weight, particularly 5 to 10 percent by weight, based on the weight of the short fibers (exclusive the amount of short binder fiber which might be present).
- The finish is present in an amount of more than 0.035 percent by weight, based on the weight of the short fibers provided with the finish. The finish amount, as used herein, is understood to constitute the amount of finish as indicated by the fiber manufacturer to be actually present on the fiber.
- The amounts indicated in this description thus relate to analysis values of the fiber manufacturer (Acordis), as determined by Soxleth extraction, derivatization (methylation) of the sample, gas-chromatographic separation and detection by means of flame-ionization detector.
- The amount of finish, based on the viscose fibers, is preferably more than 0.05 percent by weight, more preferably 0.10 percent by weight, and most preferably more than 0.15 percent by weight. The upper limit of the finish amount is the amount at which a further increase of the throughput does not appear to make any sense anymore, for example, due to other limiting process parameters, at which the throughput is nearly optimal and further costs for more finish do not appear to be justified or at which the high finish content results into or contributes to undesired product properties. The maximum finish amount is thus governed by the airlaid machinery used, the short fibers or short fiber blends used as well as by the final product and its desired properties.
- As far as viscose fibers are concerned, it is presently contemplated that the maximum finish amount is 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight, based on the weight of the short fibers provided with the finish. For other fiber types analogous finish amounts are contemplated.
- Suitable as finish is any material which, when being present on the surface of the short fibers in the indicated amount, is suitable to improve the throughput of the airlaid process according to the invention. Preferably, the finish is selected from:
- (a) ester derivatives and ether derivatives of polyethylene oxide and polypropylene oxide of the general formula:
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
wherein R1 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 12 to 22 carbon atoms, particularly 14 to 20 carbon atoms, which moiety may contain one or more free hydroxyl groups, o and p are independently of each other 0 or l, m is 0 or 1, and n is 1 to 15, preferably 3 to 11, particularly 4 to 7,
(b) mono-, di- and triesters of sorbitanes with fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(c) mono-, di-, and triglycerides of fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(d) imidazolinium ethosulfates and methosulfates
(e) ethoxylated and propoxylated derivatives of the compounds according to (a), (b), (c) and (d), and
(f) mixtures of compounds according to (a), (b), (c), (d) or/and (e). - The imidazolinium ethosulfates and methosulfates have generally a structure according to the following general formula (I)
wherein R2 is H or a C1-C6 alkyl moiety, R3 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 6 to 22 carbon atoms, which moiety may contain one or more free hydroxyl groups, R4 is methyl or ethyl, r is 2, 3 or 4, and s is 0 or 1. - According to a first embodiment, preferred imidazolinium derivatives according to formula (I) are imidazolinium methosulfates (R4=methyl), wherein R2 is methyl or ethyl, more preferably methyl, R3 is, in each case independently of each other, a hydrocarbon moiety having 14 to 18 carbon atoms, r is 2, and s is 1. According to a second preferred embodiment, R2 and R3 are defined as in the first preferred embodiment, and s is 0. According to a further preferred embodiment, R2 is methyl or ethyl, preferably methyl, R3 is, in each case independently of each other, a hydrocarbon moiety having 6 to 12 carbon atoms, r is 2, and s is 1. According to a still further preferred embodiment, R3 is an alkyl moiety.
- Examples of ethylene oxide derivatives are the diesters of lauric acid, palmitic acid, oleic acid and/or stearic acid with polyethylene glycol having an average molecular weight of, for example, 400 or 600. Examples of sorbitan ester are the ethoxylated derivatives of sorbitan monoesters, diesters and triesters with lauric acid, palmitic acid, oleic acid and/or stearic acid. An example of glyceride derivatives is hydrogenated ethoxylated castor oil, and examples of the imidazolinium derivatives are Rewoquat®W75 and Rewoquat®W90 of Degussa.
- By use of short fibers, at least a fraction of which is provided with a finish, the throughput is preferably improved by at least 20%, more preferably by at least 50% and most preferably by at least 100%, as compared to the same short fibers, but without said finish.
- The method according to the invention may be combined with further steps for forming a fibrous layer, particularly a fibrous nonwoven. Accordingly, the process according to the invention can be performed in that the layer which is formed is deposited on a previously formed fibrous sheet. The previously formed fibrous sheet may be, for example, a sheet formed by applying an airlaid process, or a sheet formed by applying another process, for example, a spunbond or meltblown sheet, or a combination of such sheets.
- Moreover, the method according to the invention may comprise the laying of several layers, for example, the laying of two or three layers, if desired, in combination with one or more other sheets, as explained above. On the (top) layer according to the invention there may be deposited one or more other sheets, as explained above.
- After the fibrous nonwoven has been formed in accordance with the invention, said fibrous nonwoven may be subjected to further process steps. Such steps comprise, for example, a heat treatment, particularly if thermoplastic binder fibers are used. In this case, the heat treatment comprises heating the fibrous nonwoven to a temperature above the softening point of the binder fiber or of the component of the binder fiber having the lowest melting point over a period of time which is sufficient to cause the fiber or component to at least partially melt. Further optional process steps comprise compacting, embossing, printing etc.
- The present invention also relates to a fibrous nonwoven produced according to the method of the present invention. Accordingly, the present invention also provides a fibrous nonwoven, comprising at least one short fiber-including layer, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with said finish.
- According to a special embodiment, the layer comprises short fibers in an amount of 70 to 99 percent by weight and binder material in an amount of 1 to 30 percent by weight, based on the total weight of short fibers and binder material.
- The binder material is a binder material as described above in respect of the method according to the invention and preferably comprises short binder fibers, particularly multi-component fibers such as bi-component fibers including a polyester core and a polyethylene sheath. Generally, short binder fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex.
- The short fibers are short fibers as described above in respect of the method according to the invention and preferably comprise natural fibers, particularly natural vegetable fibers and cellulosic man-made fibers, particularly cellulose fibers, cotton fibers, viscose fibers and Lyocell fibers.
- According to a particular embodiment, the layer of the fibrous nonwoven according to the invention comprises short viscose fibers, at least a fraction of which is provided with a finish. Preferably, at least 20%, more preferably at least 50%, of the short viscose fibers are provided with the finish. For example, all of the short viscose fibers are provided with the finish. Preferably, the short viscose fibers have a multi-limbed cross-section such as a three-limbed cross-section.
- According to this embodiment, the viscose fibers are present in an amount of more than 85 percent by weight, based on the total weight of the short fibers, particularly in an amount of more than 90 percent by weight such as more than 95 percent by weight. For example, exclusively short viscose fibers are present as the short fibers.
- As defined herein, the short fibers have a length in the range of from 2 to 12 mm and preferably a length in the range of from 4 to 8 mm such as 5 to 6 mm. Generally, the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex such as about 3.3 dtex.
- The layer may comprise a superabsorbent material (SAP), preferably in the form of fibers, particularly short fibers, having a length in the range of from 2 to 12 mm, particularly 4 to 8 mm. If use is made of a superabsorbent material, the amount used is usually 0.1 to 50 percent by weight, particularly 5 to 10 percent by weight, based on the weight of the short fibers.
- As described above in respect of the method according to the invention, the finish is present in an amount of more than 0.035 percent by weight, preferably in an amount of more than 0.05 percent by weight, more preferably in an amount of more than 0.10 percent by weight and most preferably in an amount of more than 0.15 percent by weight, the maximum amount being 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight. The indicated amounts relate to the weight of the short fibers provided with the finish.
- The finish is a finish as described above in connection with the method according to the invention.
- The fibrous nonwoven according to the invention may also comprise several layers according to the invention and/or other sheets, as explained above.
- Generally, the short fiber-including layer of the fibrous nonwoven has a basis weight of 50 to 350 g/m2, typically 75 to 250 g/m2, particularly 150 to 220 g/m2, such as about 180 g/m2.
- The density of the layer is generally 0.02 to 0.5 g/cm3, typically 0.03 to 0.2 g/cm3, particularly 0.04 to 0.1 g/cm3. The above values relate to the material web as deposited in the airlaid process before compacting process steps, such as calandering or embossing. The density is determined by a standard method under a load of 0.2 kPa.
- Generally, the short fiber-including layer of the fibrous nonwoven according to the invention has an absorbent capacity of at least 3 g/g fibrous nonwoven, preferably at least 4 g/g, particularly preferred of at least 4.8 g/g. The absorbent capacity is measured according to the generally known Syngina test (“Syngina Absorbancy Test”) and in the absence of superabsorbent materials.
- The present invention furthermore relates to a short fiber which is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight.
- According to one embodiment, the short fiber is a man-made cellulose fiber or a synthetic fiber.
- According to a preferred embodiment, the short fiber is a viscose fiber which may have a multi-limbed cross-section, such as a three-limbed cross-section.
- The short fiber has a length in the range of from 2 to 12 mm, preferably in the range of from 4 to 8 mm such as 5 to 6 mm. Generally, the short fiber has a length-to-weight ratio of 1.0 to 6.0 dtex, preferably 2.0 to 4.0 dtex, for example, about 3.3 dtex.
- The finish is present in an amount of more than 0.035 percent by weight, preferably more than 0.05 percent by weight, more preferably in an amount of more than 0.10 percent by weight and most preferably in an amount of more than 0.15 percent by weight, the maximum amount being 1 percent by weight, particularly 0.75 percent by weight such as 0.50 percent by weight.
- Suitable finish materials are the finish materials described above in connection with the method according to the invention.
- Furthermore, the present invention relates to the use of a short fiber as described above in an airlaid process.
- The invention, moreover, relates to an absorbent article comprising a fibrous nonwoven produced according to the method according to the invention and to a fibrous nonwoven as described above, respectively. The absorbent article has an absorbent capacity of at least 3 g/g fibrous nonwoven, preferably of at least 4 g/g, particularly preferred of at least 4.8 g/g, as measured by the Syngina test.
- The absorbent article is, for example, a hygiene article, such as a tampon, a sanitary napkin, a diaper or an incontinence article or a household article, industrial article or medical article.
- According to a particularly preferred embodiment, the absorbent article according to the invention is a tampon which comprises a helically winding of a short fiber-including layer according to the invention. The layer comprises 60 to 100 percent by weight of three-limbed short viscose fibers and 0 to 40 percent by weight of short cellulose fibers, based on the total weight of the short fibers. The short cellulose fibers and the short viscose fibers have a length of 4 to 8 mm, preferably of about 6 mm and a length-to-weight ratio of 3 to 4 dtex. Furthermore, the layer comprises 5 to 15 percent by weight of a BICO short binder fiber, based on the weight of short fibers and short binder fibers. The tampon has an absorbent capacity of at least 4 g/g under load, a stiffness of at least 20N and an expansion capacity of at least 150%.
- The invention will be described in further detail with reference to the example given below. The example is merely of illustrative nature and should not be interpreted to be limiting in any way.
- Measuring Method
- Determination of the Moisture of the Fibers
- 1. Moisture-proof containers are weighed with an accuracy of ±0.005 g at room temperature and the temperature at which the fiber samples are weighed after oven drying has been performed. The values TRT (tare weight at room temperature) and TH (tare weight hot) are recorded. Care must be taken that the determination of GH is performed with open lid.
- 2. A fiber sample (about 5 g) is introduced into the container. The container is closed by the lid in moisture-proof manner and weighed with an accuracy of ±0.005 g. The value GRT (weight at room temperature) is recorded.
- 3. The lid is removed from the containers and the container and lid are introduced into a hot air oven with a temperature of 105±3° C.
- 4. Drying is performed over at least three hours, for example, overnight. During drying the oven must not be opened.
- 5. While being still in the oven, the containers are closed in moisture-proof manner. The closed container is weighed at the same temperature at which GH was measured. The value is recorded as GH (weight hot).
- 6. Calculation
- After pretests had been conducted in which the influence of a finish present on the fibers was determined as well as a lesser influence of the fibers' moisture content, fibers according to the specification indicated in Table 1 were produced. The short fiber was a three-limbed rayon fiber (Danofil VY), obtained by dry-cutting using a guillotine process, with a length-to-weight ratio of 3.3 dtex and a length of 5 mm. The finish employed was polyglycol palmitate stearate ester.
- The fibers were then used for producing airlaid nonwovens using a Danweb airlaid line with 4 forming heads and a forming width of 600 mm. The airlaid line is suitable for multi-bonding and for producing latex-bonded and thermally bonded products. The bore diameter of the forming heads was 4.5 mm.
- The fibers of the samples 1-5 were used in combination with a binder fiber Trevira T255 (PET/PE) with a length-to-weight ratio of 3.0 dtex and a length of 6 mm with a weight ratio of rayon fibers to binder fibers of 93:7. The environmental conditions were 23° C. and 73% relative humidity, the target basis weight was 180 to 220 g/m2 at a density of 0.04 g/cm3.
- In order to determine the maximum throughput of the airlaid machinery, the highest amount of fibers passing through the forming heads without blocking the forming heads is determined. In addition, the basis weight must remain stable at target with a maximum variation of ±10% from the target value in machine and cross direction. The maximum capacity is the maximum amount of fibers fed to the forming heads per unit of time measured at the fiber feed metering unit.
- The test was successively performed on samples 1 to 5, i.e., the moisture and/or finish values were increased from test to test to avoid contamination of the system by fibers with higher moisture or finish amounts.
- In each test the fiber feed was increased up to the point where a fiber accumulation in the forming heads occurred. The last stable setting up to this point is the maximum throughput in the airlaid machinery. The airlaid machinery used two of four forming heads. The results of the tests are summarized in Table 1.
TABLE 1 Finish Maximum Sample no. Moisture, % amount, % throughput 1 4.1 0.045 120.5 2 8.2 0.031 140.6 3 8.7 0.052 154.0 4 9.1 0.085 170.1 5 9.3 0.16 222.6
Moisture: measured according to the method described herein
Type of finish: polyglycol palmitate stearate ester
Maximum throughput: indicated in kg/h per 2 forming heads
- The results are graphically represented in
FIGS. 1 and 2 . The results show in particular: - 1. An increased finish content as well as an increased moisture content increase the throughput of viscose fibers in the airlaid line.
- 2. Increasing moisture from 4.1 to 8.7%, with a comparable finish content, increases the throughput from 120.5 to 154.0 kg (+28%) (
FIG. 1 ). - 3. Increasing the finish amount from 0.052 to 0.085 and further to 0.16, with a comparable moisture content, increases the throughput from 154.0 to 170.1 kg (+10%) and finally to 222.6 kg (+45%) (
FIG. 2 ). - 4. The highest throughput was achieved with 9.3% moisture and 0.16% finish. The graphical evaluation given in
FIGS. 1 and 2 suggests that, if moisture and/or finish are further increased, a further increase of the throughput may be expected. - 5. The throughputs achieved in these tests exceeded all results obtained so far with synthetic fibers on the airlaid line employed.
- 6. It is presumed that the throughputs achieved in these tests also exceed the maximum throughputs of 100% cellulose. For the heads with 4.5 mm bore diameter secure data are not yet available. With forming heads having 4.00 mm bores, the maximum values for 100% are about 80 kg/h per forming head, i.e., 160 kg/h per two forming heads.
Claims (45)
1. A method for producing a fibrous nonwoven, said method comprising depositing at least one short fiber-including layer by an airlaid process, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with said finish.
2. The method according to claim 1 , wherein the layer comprises short fibers in an amount of 70 to 99 percent by weight and binder material in an amount of 1 to 30 percent by weight, based on the total weight of short fibers and binder material.
3. The method according to claim 2 , wherein the binder material comprises short binder fibers.
4. The method according to claim 3 , wherein the short binder fibers are multi-component fibers.
5. The method according to claim 4 , wherein the short binder fibers are bi-component fibers comprising a polyester core and a polyethylene sheath.
6. The method according to claim 5 , wherein the short binder fibers have a length-to weight ratio of 1.0 to 6.0 dtex.
7. The method according to claim 6 , wherein the short fibers have a moisture in the range of from 4 to 16%.
8. The method according to claim 7 wherein the short fibers comprise short cellulose fibers, short cotton fibers, cellulosic man-made fibers, short synthetic fibers or a combination thereof.
9. The method according to claim 8 , wherein the short fibers comprise short viscose fibers and at least a fraction of the short viscose fibers is provided with the finish.
10. The method according to claim 9 , wherein at least a fraction of the short viscose fibers has a multi-limbed cross-section.
11. The method according to claim 10 , wherein the multi-limbed cross-section is a three-limbed cross-section.
12. The method according to claim 9 , wherein the short fibers comprise the viscose fibers in an amount of more than 85 percent by weight, based on the total weigh of the short fibers.
13. The method according to claim 12 , wherein the short fibers have a length in the range of from 4 to 8 mm.
14. The method according to claim 13 , wherein the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex.
15. The method according to claim 14 , wherein the layer further comprises superabsorbent material.
16. The method according to claim 15 , wherein the finish is selected from
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
(a) ester derivatives and ether derivatives of polyethylene oxide and polypropylene oxide of the general formula:
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
wherein R1 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 12 to 22 carbon atoms, particularly 14 to 20 carbon atoms, which moiety may contain one or more free hydroxyl groups, o and p are independently of each other 0 or l, m is 0 or 1, and n is 1 to 15, preferably 3 to 11, particularly 4 to 7,
(b) mono-, di- and triesters of sorbitanes with fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(c) mono-, di-, and triglycerides of fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(d) imidazolinium ethosulfates and methosulfates
(e) ethoxylated and propoxylated derivatives of the compounds according to (a), (b), (c) and (d), and
(f) mixtures of compounds according to (a), (b), (c), (d) or/and (e).
17. The method according to claim 16 , wherein the at least one short fiber-including layer is deposited on a fibrous sheet.
18. The method according to claim 17 , wherein the fibrous sheet is a short fiber-including layer which has been deposited by an airlaid process.
19. The method according to claim 18 , comprising depositing two or three short fiber-including layers.
20. A fibrous nonwoven comprising at least one short fiber-including layer, wherein at least a fraction of the short fibers is provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight of the short fibers provided with the finish.
21. The fibrous nonwoven according to claim 20 , wherein the layer comprises short fibers in an amount of 70 to 99 percent by weight and binder material in an amount of 1 to 30 percent by weight, based on the total weight of short fibers and binder material.
22. The fibrous nonwoven according to claim 21 , wherein the binder material comprises short binder fibers.
23. The fibrous nonwoven according to claim 22 , wherein the short binder fibers are multi-component fibers.
24. The fibrous nonwoven according to claim 23 , wherein the short binder fibers are two-component fibers comprising a polyester core and a polyethylene sheath.
25. The fibrous nonwoven according to claim 24 , wherein the short binder fibers have a length-to-weight ratio of 1.0 to 6.0 dtex.
26. The fibrous nonwoven according to claim 25 , wherein the short fibers comprise short cellulose fibers, short cotton fibers, cellulosic man-made fibers, short synthetic fibers or a combination thereof.
27. The fibrous nonwoven according to claim 26 , wherein the short fibers comprise short viscose fibers and the viscose fibers are provided with the finish.
28. The fibrous nonwoven according to claim 27 , wherein at least a fraction of the short viscose fibers has a multi-limbed cross-section.
29. The fibrous nonwoven according to claim 28 , wherein the multi-limbed cross-section is a three-limbed cross-section.
30. The fibrous nonwoven according to claim 29 , wherein the short fibers comprise the viscose fibers in an amount of more than 85 percent by weight, based on the total weight of the short fibers.
31. The fibrous nonwoven according to claim 30 , wherein the short fibers have a length in the range of from 4-8 mm.
32. The fibrous nonwoven according to claim 31 , wherein the short fibers have a length-to-weight ratio of 1.0 to 6.0 dtex.
33. The fibrous nonwoven according to claim 32 , wherein the layer further comprises superabsorbent material.
34. The fibrous nonwoven according to claim 33 , wherein the finish is selected from
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
(a) ester derivatives and ether derivatives of polyethylene oxide and polypropylene oxide of the general formula:
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
wherein R1 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 12 to 22 carbon atoms, particularly 14 to 20 carbon atoms, which moiety may contain one or more free hydroxyl groups, o and p are independently of each other 0 or 1, m is 0 or 1, and n is 1 to 15, preferably 3 to 11, particularly 4 to 7,
(b) mono-, di- and triesters of sorbitanes with fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(c) mono-, di-, and triglycerides of fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(d) imidazolinium ethosulfates and methosulfates
(e) ethoxylated and propoxylated derivatives of the compounds according to (a), (b), (c) and (d), and
(f) mixtures of compounds according to (a), (b), (c), (d) or/and (e).
35. A multi-layer fibrous nonwoven, comprising at least one layer of a fibrous nonwoven according to claim 34 .
36. A short fiber provided with a finish in an amount of more than 0.035 percent by weight, based on the fiber weight.
37. The short fiber according to claim 36 , wherein the short fiber is a viscose fiber.
38. The short fiber according to claim 37 , wherein the short fiber has a multi-limbed cross-section.
39. The short fiber according to claim 38 , wherein the length-to weight ratio is 1.0 to 6.0 dtex.
40. The short fiber according to claim 39 , wherein the finish is selected from
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
(a) ester derivatives and ether derivatives of polyethylene oxide and polypropylene oxide of the general formula:
R1-(CO)O—O—[—CH2—(CH2)m—O—]n—(CO)p-R1
wherein R1 is, in each case independently of each other, a saturated or unsaturated hydrocarbon moiety having 12 to 22 carbon atoms, particularly 14 to 20 carbon atoms, which moiety may contain one or more free hydroxyl groups, o and p are independently of each other 0 or 1, m is 0 or 1, and n is 1 to 15, preferably 3 to 11, particularly 4 to 7,
(b) mono-, di- and triesters of sorbitanes with fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(c) mono-, di-, and triglycerides of fatty acids of the formula R1-COOH, wherein R1 is, in each case independently of each other, as defined above,
(d) imidazolinium ethosulfates and methosulfates
(e) ethoxylated and propoxylated derivatives of the compounds according to (a), (b), (c) and (d), and
(f) mixtures of compounds according to (a), (b), (c), (d) or/and (e).
41. Use of a short fiber according to claim 40 in an airlaid process.
42. An absorbent article, comprising a fibrous nonwoven according to claim 41 , having an absorbent capacity of at least 3 g/g fibrous nonwoven.
43. The absorbent article according to claim 42 , wherein the article is a hygienic article.
44. The absorbent article according to claim 43 , wherein the hygienic article is a tampon, a sanitary napkin, a diaper or an incontinence article.
45. The absorbent article according to claim 42 , wherein the article is a household article, an industrial article or a medical article.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10327026A DE10327026B4 (en) | 2003-06-16 | 2003-06-16 | Airlaid method with improved throughput, nonwoven fabric, use of a viscose short fiber and absorbent article |
DE10327026.4 | 2003-06-16 | ||
PCT/EP2004/006441 WO2004113608A2 (en) | 2003-06-16 | 2004-06-15 | Airlaid method with an improved through-put rate |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070266503A1 true US20070266503A1 (en) | 2007-11-22 |
Family
ID=33520610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/561,131 Abandoned US20070266503A1 (en) | 2003-06-16 | 2004-06-15 | Airlaid Method with an Improved Through-Put Rate |
Country Status (12)
Country | Link |
---|---|
US (1) | US20070266503A1 (en) |
EP (1) | EP1633923A2 (en) |
JP (1) | JP4792391B2 (en) |
KR (1) | KR101121362B1 (en) |
AR (1) | AR044784A1 (en) |
AU (1) | AU2004249862B2 (en) |
BR (1) | BRPI0411471A (en) |
CA (1) | CA2528421A1 (en) |
DE (1) | DE10327026B4 (en) |
MX (1) | MXPA05013207A (en) |
WO (1) | WO2004113608A2 (en) |
ZA (1) | ZA200509720B (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060247592A1 (en) * | 2005-04-29 | 2006-11-02 | Schmidt-Forst Alexander | Dual mode absorbent tampon |
US20070018364A1 (en) * | 2005-07-20 | 2007-01-25 | Pierre Riviere | Modification of nonwovens in intelligent nips |
US20070209768A1 (en) * | 2004-02-25 | 2007-09-13 | Concert Gmbh | Method For The Production Of A Fibrous Web From Cellulose Fibers In A Draining Process |
US20070260211A1 (en) * | 2005-12-30 | 2007-11-08 | Schmidt-Forst Alexander M | Absorbent tampon for feminine hygiene |
EP2491174A2 (en) * | 2009-10-21 | 2012-08-29 | 3M Innovative Properties Company | Porous supported articles and methods of making |
US20130115451A1 (en) * | 2011-09-27 | 2013-05-09 | FiberVision Corporation | Bonding fiber for airlaid multi-layer products and process for production of said airlaid multi-layer products |
US8530721B2 (en) | 2011-03-18 | 2013-09-10 | Kimberly-Clark Worldwide, Inc. | Resilient tampon and method for making |
US8882876B2 (en) | 2012-06-20 | 2014-11-11 | Hollingsworth & Vose Company | Fiber webs including synthetic fibers |
US9027765B2 (en) | 2010-12-17 | 2015-05-12 | Hollingsworth & Vose Company | Filter media with fibrillated fibers |
US20150360159A1 (en) * | 2014-06-11 | 2015-12-17 | Fibervisions, L.P. | Blended Fiber Filters |
US9352267B2 (en) | 2012-06-20 | 2016-05-31 | Hollingsworth & Vose Company | Absorbent and/or adsorptive filter media |
US9511330B2 (en) | 2012-06-20 | 2016-12-06 | Hollingsworth & Vose Company | Fibrillated fibers for liquid filtration media |
US10137392B2 (en) | 2012-12-14 | 2018-11-27 | Hollingsworth & Vose Company | Fiber webs coated with fiber-containing resins |
EP3534858B1 (en) | 2016-11-07 | 2021-03-24 | The Procter & Gamble Company | Tampon |
WO2023225547A1 (en) * | 2022-05-17 | 2023-11-23 | Better Made Hemp, LLC | Hemp-based absorbent article |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009055951A1 (en) | 2009-11-27 | 2011-06-01 | Glatfelter Falkenhagen Gmbh | Absorbing structure |
DE102010006228A1 (en) | 2010-01-28 | 2011-08-18 | Glatfelter Falkenhagen GmbH, 16928 | Absorbent structure for use as disposable product, for e.g. for hygiene area, particularly in hygiene product, has sequence of layers, two outer layers and liquid storage layer that is arranged between outer layers |
US20110184365A1 (en) | 2010-01-28 | 2011-07-28 | Glatfelter Falkenhagen Gmbh | Flexible, highly absorbent material |
CA2787887C (en) | 2010-01-28 | 2018-06-12 | Glatfelter Falkenhagen Gmbh | Flexible, strongly absorbing material |
WO2011148136A2 (en) * | 2010-05-25 | 2011-12-01 | Ananas Anam Limited | Natural nonwoven materials |
US9814630B2 (en) | 2010-12-23 | 2017-11-14 | Kimberly-Clark Worldwide, Inc. | Vaginal insert device having a support portion with plurality of foldable areas |
US9022919B2 (en) | 2010-12-23 | 2015-05-05 | Kimberly-Clark Worldwide, Inc. | Vaginal insert device having a support portion with plurality of struts |
US8911344B2 (en) | 2011-12-20 | 2014-12-16 | Kimberly-Clark Worldwide, Inc. | Vaginal insert device having perpendicular segments |
CN106012295A (en) * | 2016-08-03 | 2016-10-12 | 江苏盛纺纳米材料科技股份有限公司 | Nano-fibre hot air hydrophilic non-woven material and preparation method |
KR20180001590U (en) * | 2016-11-18 | 2018-05-29 | 권영원 | Textile material for manufacturing beauty mask pack |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617439A (en) * | 1969-01-02 | 1971-11-02 | Buckeye Cellulose Corp | Process for improving comminution pulp sheets and resulting air-laid absorbent products |
US4432834A (en) * | 1978-10-25 | 1984-02-21 | Nalco Chemical Company | Additive for felted cellulose fibers |
US4540521A (en) * | 1984-01-16 | 1985-09-10 | National Distillers And Chemical Corporation | Liquid quaternary ammonium antistatic compositions |
US4575376A (en) * | 1983-11-07 | 1986-03-11 | International Playtex | Method for increasing the absorbency of cellulosic fibers |
US4619779A (en) * | 1982-06-30 | 1986-10-28 | The Procter & Gamble Company | Detergent additive product |
US5234720A (en) * | 1990-01-18 | 1993-08-10 | Eastman Kodak Company | Process of preparing lubricant-impregnated fibers |
US5308896A (en) * | 1992-08-17 | 1994-05-03 | Weyerhaeuser Company | Particle binders for high bulk fibers |
US20020032421A1 (en) * | 1997-04-24 | 2002-03-14 | John B Scott | Nonwoven, absorbent fibrous web and method of manufacture |
US6378179B1 (en) * | 2001-01-05 | 2002-04-30 | Gary F. Hirsch | System and method for reconstituting fibers from recyclable waste material |
US6436855B1 (en) * | 1999-09-24 | 2002-08-20 | Chisso Corporation | Hydrophilic fiber and non-woven fabric, and processed non-woven products made therefrom |
US6554814B1 (en) * | 1999-05-10 | 2003-04-29 | The Procter & Gamble Company | Protection tampon and method of making |
US6759567B2 (en) * | 2001-06-27 | 2004-07-06 | Kimberly-Clark Worldwide, Inc. | Pulp and synthetic fiber absorbent composites for personal care products |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3093502A (en) * | 1959-12-30 | 1963-06-11 | Johnson & Johnson | Nonwoven fabrics and methods of manufacturing the same |
GB1029651A (en) * | 1961-03-01 | 1966-05-18 | British United Shoe Machinery | Improvements in or relating to fibrous sheet material |
JPS63303184A (en) * | 1987-05-29 | 1988-12-09 | 松本油脂製薬株式会社 | Treatment agent for binder fiber |
JPH0551872A (en) * | 1991-08-09 | 1993-03-02 | Matsumoto Yushi Seiyaku Co Ltd | Treating agent for binder fiber |
JP3278288B2 (en) * | 1994-04-12 | 2002-04-30 | 日本バイリーン株式会社 | Entangled nonwoven fabric and interlining using the same |
US5505719A (en) * | 1994-06-30 | 1996-04-09 | Mcneil-Ppc, Inc. | Multilayered absorbent structures |
CA2256550A1 (en) * | 1996-06-19 | 1997-12-24 | Chisso Corporation | Nonwoven short fibre fabric and absorbent article made by using same |
JP3802073B2 (en) * | 1996-10-24 | 2006-07-26 | ファイバービジョンズ アクティーゼルスカブ | Polyolefin fiber and process for producing the same |
JPH11107164A (en) * | 1997-09-30 | 1999-04-20 | Kawashima:Kk | Disposable sheet for medical application, and its production |
JP4221849B2 (en) * | 1998-11-20 | 2009-02-12 | チッソ株式会社 | Thermal adhesive composite fiber, fiber assembly and non-woven fabric using the same |
US6344109B1 (en) * | 1998-12-18 | 2002-02-05 | Bki Holding Corporation | Softened comminution pulp |
-
2003
- 2003-06-16 DE DE10327026A patent/DE10327026B4/en not_active Expired - Fee Related
-
2004
- 2004-06-15 US US10/561,131 patent/US20070266503A1/en not_active Abandoned
- 2004-06-15 EP EP04739911A patent/EP1633923A2/en not_active Withdrawn
- 2004-06-15 AU AU2004249862A patent/AU2004249862B2/en not_active Ceased
- 2004-06-15 MX MXPA05013207A patent/MXPA05013207A/en unknown
- 2004-06-15 JP JP2006515941A patent/JP4792391B2/en not_active Expired - Fee Related
- 2004-06-15 WO PCT/EP2004/006441 patent/WO2004113608A2/en active Application Filing
- 2004-06-15 ZA ZA200509720A patent/ZA200509720B/en unknown
- 2004-06-15 BR BRPI0411471-0A patent/BRPI0411471A/en not_active IP Right Cessation
- 2004-06-15 CA CA002528421A patent/CA2528421A1/en not_active Abandoned
- 2004-06-16 AR ARP040102092A patent/AR044784A1/en active IP Right Grant
-
2005
- 2005-12-15 KR KR1020057024052A patent/KR101121362B1/en active IP Right Grant
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617439A (en) * | 1969-01-02 | 1971-11-02 | Buckeye Cellulose Corp | Process for improving comminution pulp sheets and resulting air-laid absorbent products |
US4432834A (en) * | 1978-10-25 | 1984-02-21 | Nalco Chemical Company | Additive for felted cellulose fibers |
US4619779A (en) * | 1982-06-30 | 1986-10-28 | The Procter & Gamble Company | Detergent additive product |
US4575376A (en) * | 1983-11-07 | 1986-03-11 | International Playtex | Method for increasing the absorbency of cellulosic fibers |
US4540521A (en) * | 1984-01-16 | 1985-09-10 | National Distillers And Chemical Corporation | Liquid quaternary ammonium antistatic compositions |
US5234720A (en) * | 1990-01-18 | 1993-08-10 | Eastman Kodak Company | Process of preparing lubricant-impregnated fibers |
US5308896A (en) * | 1992-08-17 | 1994-05-03 | Weyerhaeuser Company | Particle binders for high bulk fibers |
US20020032421A1 (en) * | 1997-04-24 | 2002-03-14 | John B Scott | Nonwoven, absorbent fibrous web and method of manufacture |
US6554814B1 (en) * | 1999-05-10 | 2003-04-29 | The Procter & Gamble Company | Protection tampon and method of making |
US6436855B1 (en) * | 1999-09-24 | 2002-08-20 | Chisso Corporation | Hydrophilic fiber and non-woven fabric, and processed non-woven products made therefrom |
US6378179B1 (en) * | 2001-01-05 | 2002-04-30 | Gary F. Hirsch | System and method for reconstituting fibers from recyclable waste material |
US6759567B2 (en) * | 2001-06-27 | 2004-07-06 | Kimberly-Clark Worldwide, Inc. | Pulp and synthetic fiber absorbent composites for personal care products |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070209768A1 (en) * | 2004-02-25 | 2007-09-13 | Concert Gmbh | Method For The Production Of A Fibrous Web From Cellulose Fibers In A Draining Process |
US8470219B2 (en) * | 2004-02-25 | 2013-06-25 | Glatfelter Falkenhagen | Method for the production of a fibrous web from cellulose fibers in an air-laid process |
US8912383B2 (en) | 2005-04-29 | 2014-12-16 | Kimberly-Clark Worldwide, Inc. | Dual mode absorbent tampon |
US8293968B2 (en) | 2005-04-29 | 2012-10-23 | Kimberly-Clark Worldwide, Inc. | Dual mode absorbent tampon |
US20060247592A1 (en) * | 2005-04-29 | 2006-11-02 | Schmidt-Forst Alexander | Dual mode absorbent tampon |
US20070018364A1 (en) * | 2005-07-20 | 2007-01-25 | Pierre Riviere | Modification of nonwovens in intelligent nips |
US8827974B2 (en) | 2005-12-30 | 2014-09-09 | Kimberly-Clark Worldwide, Inc. | Absorbent tampon for feminine hygiene |
US20070260211A1 (en) * | 2005-12-30 | 2007-11-08 | Schmidt-Forst Alexander M | Absorbent tampon for feminine hygiene |
EP2491174A2 (en) * | 2009-10-21 | 2012-08-29 | 3M Innovative Properties Company | Porous supported articles and methods of making |
EP2491174A4 (en) * | 2009-10-21 | 2014-01-08 | 3M Innovative Properties Co | Porous supported articles and methods of making |
US8828162B2 (en) | 2009-10-21 | 2014-09-09 | 3M Innovative Properties Company | Porous supported articles and methods of making |
US9027765B2 (en) | 2010-12-17 | 2015-05-12 | Hollingsworth & Vose Company | Filter media with fibrillated fibers |
US10478758B2 (en) | 2010-12-17 | 2019-11-19 | Hollingsworth & Vose Company | Filter media with fibrillated fibers |
US8530721B2 (en) | 2011-03-18 | 2013-09-10 | Kimberly-Clark Worldwide, Inc. | Resilient tampon and method for making |
US9278154B2 (en) | 2011-03-18 | 2016-03-08 | Kimberly-Clark Worldwide, Inc. | Resilient tampon and method for making |
US20130115451A1 (en) * | 2011-09-27 | 2013-05-09 | FiberVision Corporation | Bonding fiber for airlaid multi-layer products and process for production of said airlaid multi-layer products |
US8882876B2 (en) | 2012-06-20 | 2014-11-11 | Hollingsworth & Vose Company | Fiber webs including synthetic fibers |
US9352267B2 (en) | 2012-06-20 | 2016-05-31 | Hollingsworth & Vose Company | Absorbent and/or adsorptive filter media |
US9511330B2 (en) | 2012-06-20 | 2016-12-06 | Hollingsworth & Vose Company | Fibrillated fibers for liquid filtration media |
US10322380B2 (en) | 2012-06-20 | 2019-06-18 | Hollingsworth & Vose Company | Fibrillated fibers for liquid filtration media |
US11247182B2 (en) | 2012-06-20 | 2022-02-15 | Hollingsworth & Vose Company | Fibrillated fibers for liquid filtration media |
US10137392B2 (en) | 2012-12-14 | 2018-11-27 | Hollingsworth & Vose Company | Fiber webs coated with fiber-containing resins |
US20150360159A1 (en) * | 2014-06-11 | 2015-12-17 | Fibervisions, L.P. | Blended Fiber Filters |
EP3534858B1 (en) | 2016-11-07 | 2021-03-24 | The Procter & Gamble Company | Tampon |
WO2023225547A1 (en) * | 2022-05-17 | 2023-11-23 | Better Made Hemp, LLC | Hemp-based absorbent article |
Also Published As
Publication number | Publication date |
---|---|
BRPI0411471A (en) | 2006-07-11 |
EP1633923A2 (en) | 2006-03-15 |
CA2528421A1 (en) | 2004-12-29 |
AU2004249862B2 (en) | 2010-08-19 |
JP2007526950A (en) | 2007-09-20 |
AR044784A1 (en) | 2005-10-05 |
WO2004113608A3 (en) | 2005-04-21 |
AU2004249862A1 (en) | 2004-12-29 |
DE10327026B4 (en) | 2010-11-04 |
ZA200509720B (en) | 2007-03-28 |
JP4792391B2 (en) | 2011-10-12 |
KR20060025553A (en) | 2006-03-21 |
DE10327026A1 (en) | 2005-01-20 |
MXPA05013207A (en) | 2006-03-09 |
WO2004113608A2 (en) | 2004-12-29 |
KR101121362B1 (en) | 2012-03-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20070266503A1 (en) | Airlaid Method with an Improved Through-Put Rate | |
EP1257703B1 (en) | Biodegradable thermoplastic nonwoven webs for fluid management | |
EP2464776B1 (en) | Fibrous structures | |
US6479415B1 (en) | Absorbent structures having fluid acquisition and distribution layer | |
CA2281802C (en) | Cellulose-binding fibres | |
US5316601A (en) | Fiber blending system | |
EP2819712B1 (en) | Hygiene product | |
NO851027L (en) | ABSORBING SHEET PRODUCT | |
EP2464775B1 (en) | Fibrous structures and method for making same | |
IE45041B1 (en) | Absorbent fibrous pads | |
US20020032421A1 (en) | Nonwoven, absorbent fibrous web and method of manufacture | |
DE69915673T2 (en) | MATERIAL STRUCTURE FOR USE IN ABSORBENT ARTICLES AND ABSORBENT ARTICLES CONTAINING SUCH MATERIAL STRUCTURE | |
AU2005201872A1 (en) | Polysaccharide treated cellulose fibers | |
DE102006000781A1 (en) | Cover and transfer layer structure for sanitary article, has non-woven cover layer whereby non-woven cover layer contains super absorbing fibers and multi-component fibers that are produced by calendaring | |
WO2005051439A1 (en) | Absorbent sanitary product | |
KR20020071009A (en) | Biodegradable nonwoven webs for fluid management | |
US20040103970A1 (en) | Air-laid web with hollow synthetic fibers | |
TR2021011107A2 (en) | A NEW COMPOSITE OF NONWOVEN FABRIC ABSORBENT MATERIAL AND ITS MANUFACTURING METHOD | |
JPH10212650A (en) | Filament nonwoven cloth and absorbing material made thereof | |
MXPA99008903A (en) | Cellulose-binding fibres | |
MXPA01005909A (en) | An absorbent structure including a thin, calendered airlaid composite and a process for making the composite |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: HAKLE-KIMBERLY DEUTSCHLAND GMBH, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SCHMIDT-FORST, ALEXANDER;ASCHENBRENNER, FRANZ;REEL/FRAME:017707/0920;SIGNING DATES FROM 20060501 TO 20060504 |
|
AS | Assignment |
Owner name: KIMBERLY-CLARK WORLDWIDE, INC., WISCONSIN Free format text: NAME CHANGE;ASSIGNOR:KIMBERLY-CLARK WORLDWIDE, INC.;REEL/FRAME:034880/0634 Effective date: 20150101 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |