US20060233467A1 - Sets of pre-padded bags and methods of making same - Google Patents

Sets of pre-padded bags and methods of making same Download PDF

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Publication number
US20060233467A1
US20060233467A1 US11/106,754 US10675405A US2006233467A1 US 20060233467 A1 US20060233467 A1 US 20060233467A1 US 10675405 A US10675405 A US 10675405A US 2006233467 A1 US2006233467 A1 US 2006233467A1
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Prior art keywords
film
bag
bags
seal
longitudinal
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US11/106,754
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James Mize
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Cryovac LLC
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Cryovac LLC
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Priority to US11/106,754 priority Critical patent/US20060233467A1/en
Assigned to CRYOVAC, INC. reassignment CRYOVAC, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MIZE, JAMES AKERS, JR.
Priority to BRPI0601149-7A priority patent/BRPI0601149A/en
Priority to ARP060101445A priority patent/AR053215A1/en
Priority to AU2006201552A priority patent/AU2006201552A1/en
Publication of US20060233467A1 publication Critical patent/US20060233467A1/en
Assigned to CRYOVAC, INC. reassignment CRYOVAC, INC. CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNEE STREET NAME SHOULD BE 100 ROGERS BRIDGE ROAD; THE CORRECT APPLICATION NUMBER IS 11/106,754 PREVIOUSLY RECORDED ON REEL 016813 FRAME 0499. ASSIGNOR(S) HEREBY CONFIRMS THE THE CURRENT RECORDATION SHOWS THE STREET NAME AS 100 ROAGERS BRIDGE RAOD; THE APPLICATION NUMBER RECORDED IS 11/106,574. Assignors: MIZE, JR., JAMES AKERS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/264Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing liquids

Definitions

  • the present invention relates to bags formed from polymeric film and containing fluid-absorbent pads for absorbing fluids.
  • Poultry and meat are frequently sold in transparent plastic bags.
  • a problem with this type of packaging is that the poultry or meat contains blood and other fluids that flow out of the meat after it has been packaged.
  • the blood and other fluids accumulate in the package, detracting from its appearance.
  • the blood and fluid sometimes leak from the package while the consumer is transporting it home from the market.
  • food bag manufacturers often insert an absorbent pad into the bag prior to packaging the food product.
  • the pad absorbs the exuded blood and fluid and thereby enhances the appearance of the packaged product.
  • the absorbent pads are manually inserted into the bags. The manual labor associated with placing the absorbent pads in the bags prior to product packaging adds to the cost and time associated with this operation.
  • thermoplastic material is extruded from an annular die in the form of a seamless tubing, with the extrudate (known as a “tape”) being relatively thick and relatively narrow.
  • the annular extrudate is then quenched.
  • the tape can then be irradiated and/or coated with one or more additional layers containing thermoplastic polymer.
  • the tape is then reheated to its softening point by exposure to hot water or steam (or other heating means) and is stretched in its longitudinal and transverse directions while the polymer remains in the solid state, resulting in heat-shrinkable film in the form of a seamless tubing.
  • the heat-shrinkable film tubing is then converted into end-seal bags by placing the tubing into a lay-flat configuration and heat-sealing across the tubing to heat-seal the inside surface of the tubing to itself. The seals across the tubing are made at intervals along the length of the tubing, these intervals corresponding with the desired bag lengths.
  • the resulting sealed tubing is then converted into a plurality of heat-shrinkable bags by cutting across the tubing a short distance downstream of each of the transverse heat-seals, resulting in a plurality of lay-flat bags having an open top, two seamless side edges, a heat seal across the bag near the bottom edge of the bag, and a short section of tubing (commonly referred to as a “skirt”) below the transverse heat seal.
  • each bag When end-seal bags extend across the entire width of the lay-flat tubing, such bags come off the production line one at a time, and each bag generally entails a separate sealing cycle and a separate printing cycle. It would be desirable to reduce the number of sealing cycles, printing cycles, and cutting cycles, to increase throughput of the process, and in some cases to provide bags of reduced width. It would also be desirable to provide such bags with absorbent pads and to do so in an automated fashion.
  • the present invention addresses the above needs and achieves other advantages, by providing a set of pre-padded end-seal bags and a process for making sets of such bags.
  • the invention enables the number of printing cycles, as well as the number of cycles used to make the transverse seals, to be substantially reduced while making the same total number of bags, thereby enabling a substantial increase in the number of bags per extrusion die, as well as per print cycle and per transverse seal cycle.
  • the sets of pre-padded bags in preferred embodiments have a lengthwise free shrink (i.e., shrink in the machine direction) that is less than the transverse free shrink (i.e., shrink across the width of the bags), so that during shrinking the bags have less tendency to distort flat, flexible, elongate products packaged in the bag.
  • each set of bags can be provided with an appropriate number of longitudinal tear lines (i.e., tear lines running the length of the bags, i.e., in the machine direction) for ease in separating the bags from one another.
  • tear lines running the length of the bags, i.e., in the machine direction
  • the connected series of bags can be stretched out across the opening of a vacuum chamber without risk of overlap during sealing.
  • each set of bags is connected to at least one other set of bags in a line of succession, e.g., resulting in a chain of sets of bags, which can be of indeterminate length as it comes off a production line.
  • this chain of sets of bags can be provided with transverse tear lines (i.e., a weakened region between the sets of bags, such as a line of perforations, etc.) so that each set of bags can be easily torn free of the chain of bags, as well as lengthwise (i.e., machine direction) tear lines between the bags of each set, so that the packaged product can be offered as singlets or any subset of the original set of bags.
  • the bag length of each of the bags in the set runs in the machine direction of the tubing or film.
  • the bag width of each of the bags in the set runs in the transverse direction across the tubing or film. A greater free shrink in the transverse direction is desirable for the packaging of a wide variety of products, particularly food products that tend to distort by bending along the length of the bag in which they are packaged.
  • Various meat products such as small beef and pork cuts, for example, beef and pork tenderloin, eye of round, single ribs, beef spare ribs, split beef back ribs, and various lamb cuts, tend to distort (i.e., bend) if packaged in a shrink bag having a higher shrink along the length of the bag than across the width of the bag.
  • distort i.e., bend
  • Such package distortion can be reduced or eliminated in the sets of bags of the invention, if the bags are provided with greater free shrink across the bag than along the length of the bag.
  • Sets of pre-padded bags in accordance with the invention can be made with various processes.
  • a chain of sets of pre-padded bags is made from two continuous polymer film webs that are positioned in overlying relation with each other.
  • Absorbent pads are inserted between the two films and preferably adhered to one of the films.
  • the pads are arranged in sets spaced at bag-length intervals along the films, the pads of each set being spaced transversely across the films.
  • the films are then sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags.
  • the films preferably are perforated longitudinally between the bags of each set to facilitate separating the bags of each set.
  • the opposite longitudinal edges of the films are sealed together, and transverse seals are made across the films at spaced bag-length intervals.
  • the films advantageously are perforated across the films adjacent each transverse seal to facilitate separating one set of bags from another.
  • a chain of sets of pre-padded bags is made from a continuous lay-flat tubing.
  • the lay-flat tubing is slit along at least one of its longitudinal edges to open the tubing, and absorbent pads are inserted between the two film portions of the slit lay-flat tubing, and preferably are adhered to one of the film portions of the slit lay-flat tubing.
  • the pads are arranged in sets spaced at bag-length intervals along the lay-flat tubing, the pads of each set being spaced transversely across the lay-flat tubing.
  • the tubing is then sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags.
  • the tubing preferably is perforated longitudinally between the bags of each set to facilitate separating the bags of each set.
  • the (or each) slit longitudinal edge of the tubing is sealed together, and transverse seals are made across the tubing at spaced bag-length intervals.
  • the tubing advantageously is perforated across the films adjacent each transverse seal to facilitate separating one set of bags from another.
  • a chain of pairs of pre-padded bags is made from a single wide lay-flat film.
  • Absorbent pads are placed onto the film and preferably adhered to the film.
  • the pads are arranged in pairs spaced at bag-length intervals along the film, the pads of each set being spaced transversely on opposite sides of a centerline of the film.
  • the film is then C-folded by bringing the opposite longitudinal edges of the film inwardly toward the centerline such that the pads are disposed between two overlying film portions and respective underlying film portions.
  • the longitudinal edges of the overlying film portions are sealed with longitudinal seals to the underlying film portions to form interior side seals of the bags.
  • the film preferably is perforated down the centerline to facilitate separating the bags of each set. Transverse seals are made across the film at spaced bag-length intervals.
  • the film advantageously is perforated across the film adjacent each transverse seal to facilitate separating one set of bags from another.
  • a chain of sets of pre-padded bags is made from a single wide lay-flat film.
  • Absorbent pads are placed onto the film and preferably adhered to the film.
  • the pads are arranged in sets spaced at bag-length intervals along the film, the pads of each set being spaced transversely across half of the width of the film.
  • the film is then folded down the middle (i.e., center-folded) by bringing one of the opposite longitudinal edges of the film over so as to overlie the other longitudinal edge of the film, such that the pads are disposed between an overlying film portion and an underlying film portion.
  • the longitudinal edges of the film portions are sealed together with a longitudinal seal to form an outer side seal for one of the bags of each set of bags of the chain.
  • the folded film is sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags.
  • the film preferably is perforated longitudinally between the bags of each set to facilitate separating the bags of each set. Transverse seals are made across the film at spaced bag-length intervals.
  • the film advantageously is perforated across the film adjacent each transverse seal to facilitate separating one set of bags from another.
  • a set of pre-padded bags made from a film in accordance with a first aspect of the invention comprises a first lay-flat bag and a second lay-flat bag joined along their respective lengths, with an end seal extending across both the first bag and the second bag.
  • Each of the first and second bags contains an absorbent pad, preferably adhered to the film.
  • the first bag has a first side seal extending the length of the first bag
  • the second bag has a second side seal extending the length of the second bag.
  • the first bag is connected with the second bag in an area between the first side seal and the second side seal.
  • Both the first bag and the second bag having a total free shrink at 185° F. of at least 10 percent, and both the first bag and the second bag have a transverse free shrink at 185° F. which is greater than a longitudinal free shrink at 185° F.
  • the set of bags has a first outer side edge and a second outer side edge, and at least one of the first outer side edge and the second outer side edge is a folded edge.
  • the film has a total free shrink, at 185° F., of at least 15 percent; more preferably, at least 20 percent, more preferably, at least 25 percent; more preferably, at least 30 percent; more preferably, at least 35 percent; more preferably, at least 40 percent; more preferably, at least 45 percent.
  • the film has a total free shrink at 185° F. of from 15 to 150 percent; more preferably, from 20 to 140 percent; more preferably, from 25 to 130 percent; more preferably, from 30 to 120 percent; more preferably, from 35 to 110 percent; more preferably, from 40 to 100 percent; and, more preferably, from 45 to 90 percent.
  • the end seal, the first side seal, and the second side seal are heat seals.
  • the end seal, the first side seal, and the second side seal are each a seal of an inside surface of a seamless tubing to itself.
  • the end seal can be a straight seal or can be curved or have at least one curved region. If curved, preferably the end seal is curved so that the bottom of the lay-flat set of bags is convex.
  • the set of bags further comprises a line of weakness between the first bag and the second bag, the line of weakness being between the first side seal and the second side seal.
  • the line of weakness between the first bag and the second bag comprises perforations.
  • the set of bags can comprise a pair of bags
  • the set of bags can further comprise first, second, and third bags, wherein the second bag is between the first bag and the third bag, the second bag having two side seals and an end seal.
  • the first bag is preferably a mirror image of the second bag.
  • the first bag has a length equal to the length of the second bag.
  • first side seal is parallel to the second side seal.
  • the film from which the set of bags is made is a multilayer film comprising a first outer film layer, a second outer film layer, and an inner O 2 -barrier layer comprising at least one polymer selected from the group consisting of vinylidene chloride/methyl acrylate copolymer, vinylidene chloride/vinyl chloride copolymer, ethylene/vinyl alcohol copolymer, polyamide, and polyethylene carbonate.
  • the multilayer film further comprises a fourth layer which serves as a tie layer between the barrier layer and the first outer film layer, and a fifth layer which serves as a tie layer between the barrier layer and the second outer layer.
  • the first bag and the second bag have printing thereon.
  • the present invention pertains to a plurality of sets of pre-padded bags, with each set being in accordance with the first aspect of the invention (described above).
  • the first set of bags comprises a first bag and a second bag joined along their respective lengths, the first pair of bags having a first end seal extending across both the first bag and the second bag, the first bag having a first side seal extending the length of the first bag, and the second bag having a second side seal extending the length of the second bag, the first bag being connected with the second bag in an area between the first side seal and the second side seal.
  • the second set of bags comprises a third bag and a fourth bag, the second set of bags having a second end seal extending across both the third bag and the fourth bag, the third bag having a third side seal extending the length of the third bag and the fourth bag having a fourth side seal extending the length of the fourth bag.
  • the third bag is connected with the fourth bag in an area between the third side seal and the fourth side seal.
  • the second set of bags is joined to the first set of bags in an area below the first end seal.
  • the third side seal is a continuation of the first side seal
  • the fourth side seal is a continuation of the second side seal.
  • the second set of bags is joined to the first set of bags along a transverse line of weakness.
  • the line of weakness between the first set of bags and the second set of bags comprises perforations.
  • the set of bags further comprises a third set of bags which is joined to the second set of bags below the second end seal, and a fourth set of bags joined to the third set of bags below a third end seal, with the plurality of sets of bags being a portion of a chain of sets of bags, the chain being of indeterminate length.
  • preferred embodiments of the second aspect of the invention correspond with preferred features of the first aspect of the present invention.
  • the present invention pertains to a set of pre-padded bags made from a film.
  • the set of bags comprises a first lay-flat bag and a second lay-flat bag joined along their respective lengths, and an end seal extending across both the first bag and the second bag, with the first bag connecting with the second bag at a heat seal between the first bag and the second bag, the heat seal extending the length of the first bag and the second bag, with both the first bag and the second bag having a total free shrink at 185° F. of at least 10 percent and a transverse free shrink at 185° F. which is greater than a longitudinal free shrink at 185° F.
  • Each bag contains an absorbent pad, which preferably is adhered to the film.
  • pre-padded side-seal bags are provided as a continuous chains of serially connected bags.
  • FIG. 1 illustrates a lay-flat view of a set (in this illustration, a pair) of pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges;
  • FIG. 2 illustrates a lay-flat view of a pair of pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, with the pair of bags being connected to one another along a longitudinal line of weakness (e.g., perforations);
  • a longitudinal line of weakness e.g., perforations
  • FIG. 3 illustrates a portion of a continuous chain of pre-padded bag pairs made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, with a longitudinal line of weakness between the bags of each pair, with each pair of bags being connected to the next successive pair of bags with a transverse line of weakness located a short distance downstream of the transverse seal across the bags;
  • FIG. 4 illustrates a lay-flat view of a set (e.g., a pair) of alternative pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, each of the bags of each set having a curved end seal;
  • a set e.g., a pair
  • alternative pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, each of the bags of each set having a curved end seal
  • FIG. 5 illustrates a lay-flat view of an alternative pair of pre-padded bags made by folding a flat film over on itself and sealing it to form a pair of bags, or by slitting a lay-flat tubing along only one longitudinal edge for pad insertion;
  • FIG. 6 illustrates a lay-flat view of an alternative set of pre-padded bags which is made up of three bags across a seamless lay-flat tubing
  • FIG. 7 illustrates a lay-flat view of a set of pre-padded bags made from a single wide lay-flat film that is C-folded
  • FIG. 8 illustrates a lay-flat view of an alternative pair of pre-padded bags in accordance with the present invention
  • FIG. 9 is a schematic depiction of a preferred process for producing multilayer films for use in the sets of bags of the present invention.
  • FIG. 10 illustrates a lay-flat view of a continuous chain of sets of pre-padded side-seal bags in accordance with the present invention.
  • bag is inclusive of L-seal bags, side-seal bags, backseamed bags, and pouches (i.e., “U-sealed” bags).
  • An L-seal bag has an open top, a bottom seal, one side seal along a first side edge, and a seamless (i.e., folded, unsealed) second side edge.
  • a side-seal bag has an open top and a seamless bottom edge, with each of its two side edges having a seal therealong.
  • seals along the side and/or bottom edges can be at the very edge itself, (i.e., seals of a type commonly referred to as “trim seals”), preferably the seals are spaced inward (preferably about 1 ⁇ 4 to 1 ⁇ 2 inch) from the bag side edges, and preferably are made using an impulse-type heat sealing apparatus, which utilizes a bar that is quickly heated and then quickly cooled.
  • a backseamed bag is a bag having an open top, a seal running the length of the bag in which the bag film is either fin-sealed or lap-sealed, two seamless side edges, and a bottom seal along a bottom edge of the bag.
  • the phrase “set of bags” refers to two or more bags that are connected with one another in a side-by-side relationship, with the bags extending across a tubing (seamed or seamless).
  • the set of bags preferably comprises from 2 to 20 bags across the tubing, more preferably from 2 to 5 bags, more preferably 2 to 3 bags.
  • Each bag preferably has a length of at least twice its width, more preferably three to ten times its width, with bag length and bag width being measured based on inside the bag dimensions while the bag is in a lay-flat position.
  • the phrase “connected with”, as applied to the bags of a single set of bags refers to the side-by-side relationship of the bags to one another, and does not require that the bags be directly adhered to one another. That is, two bags are connected with one another even if another bag is between them or even if a section of waste film is between them. Likewise, two bags are connected with one another if they share a common side seal, as illustrated in FIG. 9 , described below.
  • lay-flat film tubing is extruded through an annular die, with the extrudate being cooled and gathered by converging sets of rollers and wound up in flattened form.
  • a lay-flat bag includes bags of various configurations including but not limited to end seal, side seal, L-seal, etc., which can be made by sealing the inside of a lay-flat film tubing to itself, following by cutting across the tubing to convert the tubing into, for example, an end-seal bag.
  • a side-seal bag requires slitting one side edge of the tubing in addition to cutting across the tubing.
  • Side seal and L-seal lay-flat bags can also be made by folding a flat film and sealing the inside surface of the folded film to itself.
  • a pouch is often made by sealing two separate pieces of flat film to one another, with the seals extending up the sides of the pouch and across the bottom of the pouch, leaving the top of the bag open for the insertion of the product to be packaged.
  • the phrase “line of weakness” refers to any line, whether straight or curved, whether wide or narrow, in which the film has been weakened by any means so that the film can readily be torn apart along the line.
  • the line of weakness can be formed by perforating the film.
  • the line of weakness can comprise one or more slits formed in the film along the line at which the film is desired to preferentially tear, the slits being configured so that one or more parts of said line are not slit (although they may be perforated) and thereby serve to keep the film portions on opposite sides of the line connected to each other until it is desired to separate the film portions.
  • heat-shrinkable film refers to a film that has been oriented while in the solid state (as opposed to a blown film, which is oriented at, above, or near the melting point of the polymer).
  • the tension on a heat-shrinkable film increases upon the application of heat if the film is restrained from shrinking.
  • heat-contracted refers to a heat-shrinkable film, or a portion thereof, which has been exposed to heat such that the film or portion thereof is in a heat-shrunken state, i.e., reduced in size (unrestrained) or under increased tension (restrained).
  • the heat-shrinkable film has a total free shrink (i.e., machine direction plus transverse direction), with the free shrink in each direction (measured in accordance with ASTM D 2732) of at least 5 percent at 185° C., more preferably at least 7 percent, still more preferably at least 10 percent, still more preferably at least 15 percent, and yet still more preferably at least 20 percent.
  • the total free shrink at 185° F. can be from 10 to 150 percent, more preferably from 20 to 120 percent, more preferably from 40 to 100 percent.
  • the phrases “inner layer” and “internal layer” refer to any layer, of a multilayer film, having both of its principal surfaces directly adhered to another layer of the film.
  • outer layer refers to any film layer of film having less than two of its principal surfaces directly adhered to another layer of the film.
  • the phrase is inclusive of monolayer and multilayer films.
  • multilayer films there are two outer layers, each of which has a principal surface adhered to only one other layer of the multilayer film.
  • monolayer films there is only one layer, which, of course, is an outer layer in that neither of its two principal surfaces are adhered to another layer of the film.
  • inside layer refers to the outer layer of a multilayer film packaging a product, which is closest to the product, relative to the other layers of the multilayer film.
  • the phrase “outside layer” refers to the outer layer, of a multilayer film packaging a product, which is farthest from the product relative to the other layers of the multilayer film.
  • the “outside surface” of a bag is the surface away from the product being packaged within the bag.
  • the term “adhered” is inclusive of films that are directly adhered to one another using a heat seal or other means, as well as films that are adhered to one another using an adhesive that is between the two films.
  • the pre-padded bag comprises at least two films laminated together.
  • the pre-padded bag is comprised of films that together comprise a total of from 2 to 20 layers; more preferably, from 2 to 12 layers; and still more preferably, from 4 to 12 layers.
  • the multilayer film(s) used in the present invention can have any total thickness desired, so long as the film provides the desired properties for the particular packaging operation in which the film is used, e.g. abuse-resistance (especially puncture-resistance), modulus, seal strength, optics, etc.
  • FIG. 1 is a lay-flat view of a set 10 of two bags 12 and 14 made by sealing together two separate films 16 and 18 in accordance with one embodiment of the invention.
  • the films 16 and 18 are positioned in overlying relation with each other such that first longitudinal edges 20 of the films are aligned and opposite second longitudinal edges 22 of the films are aligned.
  • Fluid-absorbent pads 24 and 26 are disposed between the two films, and preferably are adhered to one of the films, such as film 16 , so that the pads do not shift position during subsequent bag formation and packaging of products.
  • the pads can comprise DRI-LOC® absorbent pads available from Sealed Air Corporation.
  • the invention is not limited in this respect, and any pads suitable for the particular application can be used in each instance.
  • a food-grade pressure-sensitive adhesive or low-temperature food-grade adhesive can be used for adhering the pads to one or both films 16 , 18 .
  • the set 10 of bags is constructed by forming a first longitudinal seal 28 adjacent the first longitudinal edges 20 of the films, a second longitudinal seal 30 spaced in the transverse or width direction of the films from the first longitudinal seal 28 and located generally centrally of the width of the films, a third longitudinal seal 32 transversely spaced a short distance from the second longitudinal seal 30 in the direction of the second longitudinal edges 22 and located generally centrally of the width of the films, and a fourth longitudinal seal 34 adjacent the second longitudinal edges 22 of the films.
  • a transverse seal 36 is formed across the width of the films to form end seals for the two bags 12 , 14 ; that is, a first portion of the transverse seal 36 forms an end seal for bag 12 and a second portion of the transverse seal 36 , which is a continuation of the first portion, forms an end seal for bag 14 .
  • the second and third longitudinal seals 30 , 32 can comprise a single longitudinal seal rather than two separate, spaced seals.
  • the longitudinal seals 28 and 34 form outer longitudinal seals of the bags 12 , 14 , respectively, and the generally centrally located longitudinal seals 30 , 32 (or single centrally located longitudinal seal, in the alternative) form interior longitudinal seals of the bags 12 , 14 , respectively.
  • the transverse seal 36 can be spaced a short distance from the transverse edges of the films so as to form a skirt 38 at the closed bottom ends of the bags.
  • the opposite ends 42 , 44 of the bags 12 , 14 , respectively, are open for loading products into the bags
  • FIG. 2 is a lay-flat view of a set 10 ′ of bags 12 , 14 having features that correspond with the features of the set of bags illustrated in FIG. 1 , except that bag set 10 ′ additionally has a longitudinal line of weakness 46 running the length of the films between the two longitudinal seals 30 , 32 (or bisecting a single centrally located longitudinal seal, in the alternative).
  • Line of weakness 46 is preferably a line of perforations, but other techniques for weakening the films to allow them to tear in a desired location can be used instead.
  • line of weakness 46 can comprise a longitudinal slit in the film, or two or more slits, that extend(s) for part of the length of the bags 12 , 14 , with other portions of the film along line 46 being free of a slit so as to connect bags 12 , 14 to each other until it is desired to separate them.
  • the portion(s) free of a slit optionally can be perforated, if desired, to facilitate separation.
  • FIG. 3 illustrates continuous string or chain 50 of bag pairs 10 ′ having all of the features as illustrated in FIG. 2 .
  • Line of weakness 52 is preferably a set of perforations aligned along a straight line located far enough below transverse seal 36 to provide skirt 38 with adequate width.
  • line of weakness 52 can comprise a longitudinal slit in the film, or two or more slits, that extend(s) for part of the width of the bag pairs 10 ′, with other portions of the film along line 52 being free of a slit so as to connect the bag pairs to each other until it is desired to separate them.
  • the portion(s) free of a slit optionally can be perforated, if desired, to facilitate separation.
  • FIG. 4 is a lay-flat view of a pre-padded bag pair 10 ′′ having features that largely correspond with the features of the pair of bags illustrated in FIG. 2 , except that transverse seal 36 ′′ has curved sections 36 a and 36 b, which provide end seals across the bottom of first bag 12 ′′ and second bag 14 ′′, respectively. Likewise, matching curved sections are present at open top 42 ′′ and 44 ′′ of first bag 12 ′′ and second bag 14 ′′, respectively
  • FIG. 5 is an illustration of an alternative pair of pre-padded bags 60 comprising first bag 62 and second bag 64 that can be made by center-folding a flat film (or slitting a seamless tubing along one longitudinal edge).
  • First bag 62 and second bag 64 have open tops 72 and 74 , respectively.
  • Pair of bags 60 has transverse seal 76 that forms end seals for first bag 62 and second bag 64 .
  • first bag 62 has outer folded edge 80 and inner longitudinal seal 82 (i.e., first bag 62 comprises an L-seal bag).
  • Second bag 64 has both inner longitudinal seal 84 and outer longitudinal seal 86 (i.e., second bag 64 comprises a U-seal bag).
  • Second bag 64 also has skirt 88 running the length of the bag, between outer longitudinal seal 86 and outer edge 90 .
  • pair of bags 60 share central region between the inner longitudinal seals 82 , 84 , which as illustrated has no weakened line, so that products packaged in first bag 62 and second bag 64 are paired with one another unless cut apart along the length of the central region.
  • a line of weakness can be provided between the bags 62 , 64 to facilitate separating the bags from each other.
  • the bag pair 60 also can include an end skirt 92 by virtue of transverse seal 76 being spaced some distance above the lower end edges of the center-folded film
  • a continuous chain of pre-padded bag pairs 60 can be formed from a continuous center-folded film or a continuous lay-flat seamless tubing that is slit along one longitudinal edge to enable the absorbent pads 24 , 26 to be inserted between the film portions.
  • Transverse lines of weakness can be formed in the continuous chain of bags adjacent each of the transverse seals, generally as previously described in connection with FIG. 3 , to facilitate separating the bag pairs from one another
  • FIG. 6 illustrates a lay-flat view of an alternative set 110 of lay-flat pre-padded bags constructed from two separate films in generally the same manner as described in connection with FIG. 1 , except that set 110 has three bags 112 , 114 , and 116 .
  • First bag 112 has an outer longitudinal seal 128 and an interior longitudinal seal 129 (i.e., first bag 112 comprises a U-seal bag), second bag 114 has a longitudinal seal 130 adjacent the longitudinal seal 129 and an opposite longitudinal seal 131 , and third bag 116 has a longitudinal seal 132 adjacent the longitudinal seal 131 and an opposite longitudinal seal 134 .
  • Each of bags 112 , 114 , and 116 shares transverse end seal 136 .
  • First bag 112 is an L-seal bag utilizing a portion of end seal 136 in combination with longitudinal seal 128 .
  • Third bag 116 is also an L-seal bag, also utilizing a portion of end seal 136 , but in combination with longitudinal seal 134 .
  • Second bag 114 is a U-seal bag utilizing yet another portion of end seal 136 , together with longitudinal seal 130 and longitudinal seal 131 .
  • First bag 112 is joined to second bag 114 along line of weakness 137 (preferably a line of perforations), and second bag 114 is joined to third bag 116 along line of weakness 138 (preferably also a line of perforations).
  • First bag 112 includes an absorbent pad 124
  • second bag 114 includes an absorbent pad 126
  • third bag 116 includes an absorbent pad 127 .
  • the absorbent pads preferably are adhered to one of the films
  • a continuous chain of pre-padded bag sets 110 can be formed from continuous lengths of two films in a manner analogous to that described in connection with FIG. 3 .
  • the continuous chain can include transverse lines of weakness adjacent each of the transverse seals 136 to facilitate separating the bag sets from one another
  • FIG. 7 illustrates a lay-flat view of a pair of bags 110 ′ formed from a single wide lay-flat film that is C-folded and then sealed to form a pair of bags 112 ′ and 114 ′. More particularly, after a pair of absorbent pads 124 and 126 are placed onto the film (and preferably adhered thereto) with the pads spaced transversely apart on opposite sides of a longitudinal centerline of the film, the film is folded along a first longitudinal fold line 128 ′ to bring a first longitudinal edge of the lay-flat film inwardly toward and adjacent to the centerline so that a first portion of the film overlies an underlying portion on which pad 124 is disposed, and the first longitudinal edge of the film is sealed to the underlying portion of the film with a first longitudinal seal 129 .
  • the film is also folded along a second fold line 134 ′ to bring the opposite second longitudinal edge of the lay-flat film inwardly toward and adjacent to the centerline so that a second portion of the film overlies an underlying portion on which pad 126 is disposed, and the second longitudinal edge of the film is sealed to the underlying portion of the film with a second longitudinal seal 130 .
  • the first and second longitudinal seals 129 , 130 can be spaced a short distance apart as illustrated in FIG. 7 , or can be substantially coincident.
  • a transverse seal 136 is formed across the C-folded film to form end seals for the bags 112 ′ and 114 ′.
  • first bag 112 ′ comprises an L-seal bag (the L-seal comprising first longitudinal seal 129 and a first portion of transverse seal 136 ), and second bag 114 ′ also comprises an L-seal bag (the L-seal comprising second longitudinal seal 130 and a second portion of transverse seal 136 )
  • Bag pair 110 ′ can also be formed from a seamless lay-flat tubing that is longitudinally slit along a centerline of one film portion to open the tubing for insertion of the pads 124 , 126 , followed by longitudinal sealing of the resulting two longitudinal edges with longitudinal seals 129 , 130 as described above.
  • a line of weakness 137 can be formed between bags 112 ′ and 114 ′ to facilitate separating the bags from each other
  • a chain of interconnected bag pairs 110 ′ can be formed from a seamless lay-flat tubing in a manner generally similar to that described in U.S. Patent Application Publication No. 2004/0255556 A1 to Boal et al., the entire disclosure of which is incorporated herein by reference.
  • the lay-flat tubing has an upper layer and a lower layer.
  • the method entails feeding the tubing to a perforator at which the upper layer and lower layer are perforated along a series of transverse lines spaced apart along the tubing's longitudinal direction at bag-length intervals. After the perforating step, the tubing is fed to a tube opener at which the upper layer is opened along the perforations to create an opening.
  • a single station can sever the upper layer to create the opening and perforate the lower layer at the same time.
  • a pair of absorbent pads are inserted through each opening in the upper layer, generally in the manner described in the Boal '556 application. Once the pads have been inserted, a transverse seal is formed across the tubing adjacent each line of perforations. Longitudinal seals, and optionally a longitudinal line of weakness between the longitudinal seals, are then formed to complete the construction of the chain of bag pairs
  • FIG. 8 illustrates a lay-flat view of an alternative set of lay-flat pre-padded bags 60 ′ in accordance with the present invention.
  • Bag set 60 ′ is constructed from a single wide lay-flat film that is center-folded and then sealed along one longitudinal edge, or from a seamless lay-flat tubing that is slit along one longitudinal edge for pad insertion and then sealed along that slit edge, generally in the same manner described above in connection with FIG. 5 .
  • Bag set 60 ′ comprises a pair of bags 62 ′ and 64 ′ respectively containing absorbent pads 24 , 26 .
  • a transverse seal 76 ′ forms end seals for first bag 62 ′ and second bag 64 ′.
  • first bag 62 ′ has outer folded edge 80 ′ and inner longitudinal seal 82 ′ (i.e., first bag 62 ′ comprises an L-seal bag).
  • Second bag 64 ′ shares the longitudinal seal 82 ′ with first bag 62 ′, and has outer longitudinal seal 86 ′ (i.e., second bag 64 ′ comprises a U-seal bag).
  • Second bag 64 ′ also has skirt 88 ′ running the length of the bag, between outer longitudinal seal 86 ′ and outer edge 90 ′. As illustrated, there is no line of weakness between bags 62 ′ and 64 ′, so that products packaged in first bag 62 ′ and second bag 64 ′ are paired with each other.
  • the bag pair 60 ′ also can include an end skirt 92 ′ by virtue of transverse seal 76 ′ being spaced some distance above the lower end edges of the film
  • the absorbent pads can be placed into the bags in either a flat unfolded configuration or in a folded configuration, and the positioning of the pad within the bag can vary depending on the particular needs in each instance.
  • the film stock film from which the bags are formed has a total thickness of from about 1.5 to 5 mils; more preferably, 1.5 to 4 mils; more preferably, 2 to 3 mils; more preferably, 2 to 2.5 mils.
  • the stock film from which the bag is formed is a multilayer film having from 1 to 20 layers; more preferably, 3 to 10 layers; more preferably, 4 to 8 layers
  • the bag film present in the form of a seamless tubing, backseamed tubing (lap seal, fin seal, or butt sealed backseamed tubing with butt seal tape) or as a flat film, has a total (i.e., L+T) free shrink at 185° F. of from about 45 to 125 percent, with a free shrink in the longitudinal (i.e., machine) direction of from 20 to 50 percent, and a free shrink in the transverse direction of from 25 to 75 percent, with the transverse free shrink being greater than the longitudinal free shrink. More preferably, the bag film has a total free shrink at 185° F.
  • the bag film has a total free shrink at 185° F. of from about 65 to 95 percent, with a free shrink in the longitudinal direction of from 30 to 40 percent, and a free shrink in the transverse direction of from 35 to 55 percent, again with the transverse free shrink being greater than the longitudinal free shrink.
  • the transverse free shrink at 185° F. is higher than the longitudinal free shrink at 185° F. by an amount of from about 5 to 30 percent, more preferably from 8 to 20 percent higher.
  • the transverse free shrink is from 1.1 times to 1.8 times as high as the longitudinal free shrink, more preferably from 1.2 to 1.7 times as high, more preferably from 1.25 to 1.65 times as high.
  • Table I below, provides a preferred multilayer film structure for making a set of bags in accordance with the present invention, including the composition, thickness, and general function of each of the film layers.
  • This film extruded from an annular die and thereafter extrusion coated, was in the form of a seamless tubing and had a total thickness of approximately 2.4 mils, and exhibited a total free shrink at 185° F. of 20% in the machine direction and 33% in the transverse direction.
  • LLDPE #1 was DOWLEX® 2045 linear low density polyethylene, obtained from the Dow Chemical Company of Midland, Mich.
  • LLDPE #2 was ESCORENE® LL3003.32 linear low density polyethylene, obtained from Exxon Chemical Company of Baytown, Tex.
  • SSPE#1 was AFFINITY® P11280 metallocene-catalyzed ethylene/octene copolymer, having a density of 0.900 g/cc and a melt index of 6 g/10 min, obtained from The Dow Chemical Company, of Midland, Mich.
  • HDPE #1 was Fortiflex® T60-500-119 high density polyethylene, obtained from Solvay Polymers, of Deer Park, Tex. EVA No.
  • EBA No. 1 was SP 1802 ethylene/butyl acrylate copolymer containing 18% butyl acrylate, obtained from Chevron Chemical Company, of Houston, Tex.
  • Table II below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 3 mils and a free shrink at 185° F. of 28 percent in the machine direction and 36 percent in the transverse direction.
  • Table III below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of about 2.2 mils and a free shrink at 185° F. of about 31% in the machine direction and about 44% in the transverse direction.
  • Table IV provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2.3 mils and a free shrink at 185° F. of 25 in the machine direction and 41 in the transverse direction.
  • Layer Thickness Layer Function Layer Chemical Identity (mils) Outside and abuse 100% EVA4 0.6 layer O2-Barrier layer 96% VDC/MA #1; 0.17 2% epoxidized soybean oil; and 2% bu-A/MA/bu-MA terpolymer Substrate Core Layer 100% EVA4 1.28 Seal Layer 100% LDPE 0.26
  • Table V provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2 mils and a free shrink at 185° F. of 31 in the machine direction and 46 in the transverse direction.
  • Layer Thickness Layer Function Layer Chemical Identity (mils) Outside and abuse 85% SSPE2 0.18 layer 15% LLDPE3 Core Layer 100% LLDPE2 0.27 Tie Layer 100% EMA 0.09 O2-Barrier layer 96% VDC/MA #1; 0.18 2% epoxidized soybean oil; and 2% bu-A/MA/bu-MA terpolymer Tie Layer 100% EVA1 0.09 Substrate Core Layer 80% LLDPE2 0.73 20% LLDPE3 Seal Layer 90% SSPE1 0.45 10% MB1
  • Table VI provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2 mils and a free shrink at 185° F. of 26 in the machine direction and 42 in the transverse direction.
  • Layer Thickness Layer Function Layer Chemical Identity (mils) Outside and abuse 85% EVA3 0.27 layer 15% LLDPE3 Core Layer 100% LLDPE2 0.4 Core Layer 100% EVA3 .13 Core Layer 100% EVA3 0.09 Substrate Core Layer 76% LLDPE2 0.8 24% MB2 Seal Layer 100% LLDPE4 0.31
  • Table VII provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2.2 mils and a free shrink at 185° F. of 36 in the machine direction and 51 in the transverse direction.
  • Layer Thickness Layer Function Layer Chemical Identity (mils) Outside and abuse 100% SSPE2 0.19 layer Core Layer 100% SSCPE3 0.29 Tie Layer 100% EVA2 0.10 O2-Barrier layer 96% VDC/MA #1; 0.19 2% epoxidized soybean oil; and 2% bu-A/MA/bu-MA terpolymer Tie Layer 100% EVA1 0.10 Substrate Core Layer 90% SSCPE3 0.86 10% EPD Seal Layer 100% SSPE1 0.48
  • SSPE1 was Dow Affinity® PL 1280 ethylene/octene copolymer, having a density of 0.900 g/cc and a melt index of 6 g/10 min.
  • SSPE2 was Dow Affinity® PL 1850, having a density of 0.902 g/cc and a melt index of 3 g/10 min.
  • SSCPE3 was DPF 1150.01 single site catalyzed ethylene/octene copolymer having a density of 0.901 g/cc and a melt index of 0.9 g/10 min, obtained from Dow.
  • LLDPE1 was Exxon Escorene® LL3003.32 linear low density polyethylene having a density of 0.9175 g/cc and a melt index of 3.2 g/10 min.
  • LLDPE2 was Dow Attane® 4203, having a density of 0.905 g/cc and a melt index of 0.8 g/10 min.
  • LLDPE3 is Dow Dowlex® 2045.03 linear low density polyethylene, having a density of 0.92 g/cc and a melt index of 1.1 g/10 min.
  • LLDPE4 was Exceed® 4518PA ethylene/hexene copolymer having a density of 0.918 and a melt index of 4.5 g/10 min.
  • LDPE was Ruxell® V3401 ethylene/octene copolymer having a density of 0.911 g/cc and a melt index of 5.7 to 7.5 g/10 min, obtained from Huntsman.
  • EVA1 was LD-713.93 ethylene/vinyl acetate copolymer, having a vinyl acetate content of 15 percent, a density of 0.933 g/cc and a melt index of 3.5 g/10 min, and was obtained from Exxon.
  • EVA2 was Escorene® LD 761.36 ethylene/vinyl acetate copolymer having a density of 0.95 g/cc, a melt index of 5.7 g/10 min, and a vinyl acetate content of 28 percent, obtained from ExxonMobil.
  • EVA3 was Escorene® LD 318.92 ethylene/vinyl acetate copolymer having a density of 0.93 g/cc, a melt index of 2 g/10 min, and a vinyl acetate content of 9 percent, obtained from ExxonMobil.
  • EVA4 was Elvax® 3128 ethylene/vinyl acetate copolymer having a density of 0.928 g/cc, a melt index of 2 g/10 min, and a vinyl acetate content of 8.9%, obtained from DuPont.
  • EMA was EMAC SP 1305 ethylene/methyl acrylate copolymer, having a methyl acrylate content of 20 percent, a density of 0.944 g/cc and a melt index of 2 g/10 min, also obtained from Exxon.
  • EPD was Vistalon® 7800 ethylene/propylene/diene terpolymer, having a density of 0.87 g/cc and a melt index of 1.5 g/10 min, obtained from Exxon.
  • VDC/MA was SARAN® MA-134 vinylidene chloride/methyl acrylate copolymer, obtained from the Dow Chemical Company.
  • the epoxidized soybean oil was PLAS-CHEK® 775 epoxidized soybean oil, obtained from the Bedford Chemical Division of Ferro Corporation, of Walton Hills, Ohio.
  • Bu-A/MA/bu-MA terpolymer was METABLEN® L-1000 butyl acrylate/methyl methacrylate/butyl methacrylate terpolymer, obtained from Elf Atochem North America, Inc., of 2000 Market Street, Philadelphia, Pa. 19103.
  • MB1 was FSU 93E polyethylene masterbatch with slip and antiblock, having a density of 0.975 g/cc and a melt index of 7.5 g/10 min, obtained from A. Schulman.
  • MB2 was 180637 light cream masterbatch having a density of 1.25 g/cc, obtained from Ampacet.
  • FIG. 9 illustrates a schematic of a preferred process for producing the multilayer films described in Tables I, II, and III, above.
  • solid polymer beads (not illustrated) are fed to a plurality of extruders 140 (for simplicity, only one extruder is illustrated). Inside extruders 140 , the polymer beads are forwarded, melted, and degassed, following which the resulting bubble-free melt is forwarded into die head 142 , and extruded through an annular die, resulting in tubing 144 which is 10 to 30 mils thick, more preferably 15 to 25 mils thick.
  • tubing 144 After cooling or quenching by water spray from cooling ring 146 , tubing 144 is collapsed by pinch rolls 148 , and is thereafter fed through irradiation vault 150 surrounded by shielding 152 , where tubing 144 is irradiated with high energy electrons (i.e., ionizing radiation) from iron core transformer accelerator 154 . Tubing 144 is guided through irradiation vault 150 on rolls 156 . Preferably, tubing 144 is irradiated to a level of about 4.5 MR.
  • irradiated tubing 158 is directed through nip rolls 160 , following which tubing 158 is slightly inflated, resulting in trapped bubble 162 .
  • the tubing is not significantly drawn longitudinally, as the surface speed of nip rolls 164 are about the same speed as nip rolls 160 .
  • irradiated tubing 158 is inflated only enough to provide a substantially circular tubing without significant transverse orientation, i.e., without stretching.
  • Second tubular film 170 is melt extruded from coating die 168 and coated onto slightly inflated, irradiated tube 158 , to form two-ply tubular film 172 .
  • Second tubular film 170 preferably comprises an O 2 -barrier layer, which does not pass through the ionizing radiation. Further details of the above-described coating step are generally as set forth in U.S. Pat. No. 4,278,738, to Brax et al., which is hereby incorporated by reference thereto, in its entirety.
  • two-ply tubing film 172 is wound up onto windup roll 174 . Thereafter, windup roll 174 is removed and installed as unwind roll 176 , on a second stage in the process of making the tubing film as ultimately desired.
  • Two-ply tubular film 172 from unwind roll 176 , is unwound and passed over guide roll 178 , after which two-ply tubular film 172 passes into hot water bath tank 180 containing hot water 182 .
  • the now collapsed, irradiated, coated tubular film 172 is submersed in hot water 182 (having a temperature of about 210° F.) for a retention time of at least about 5 seconds, i.e., for a time period in order to bring the film up to the desired temperature for biaxial orientation. Thereafter, irradiated tubular film 172 is directed through nip rolls 184 , and bubble 186 is blown, thereby transversely stretching tubular film 172 . Furthermore, while being blown, i.e., transversely stretched, nip rolls 188 draw tubular film 172 in the longitudinal direction, as nip rolls 188 have a surface speed higher than the surface speed of nip rolls 184 .
  • irradiated, coated biaxially-oriented blown tubing film 190 is produced, this blown tubing preferably having been both stretched in a ratio of from about 1:1.5-1:6, and drawn in a ratio of from about 1:1.5-1:6. More preferably, the stretching and drawing are each performed a ratio of from about 1:2-1:4. The result is a biaxial orientation of from about 1:2.25-1:36, more preferably, 1:4-1:16. While bubble 186 is maintained between pinch rolls 184 and 188 , blown tubing film 190 is collapsed by rolls 192 , and thereafter conveyed through nip rolls 188 and across guide roll 194 , and then rolled onto wind-up roll 196 . Idler roll 198 assures a good wind-up.
  • the polymer components used to fabricate multilayer films for use in making the bags of the present invention may also contain appropriate amounts of other additives normally included in such compositions.
  • additives normally included in such compositions.
  • antiblocking agents such as talc
  • slip agents such as fatty acid amides
  • fillers such as fatty acid amides
  • pigments and dyes such as fatty acid amides
  • radiation stabilizers including antioxidants
  • fluorescence additives including a material which fluoresces under ultraviolet radiation
  • antistatic agents such as fluoropolymer processing aids
  • viscosity-modifying substances such as fluoropolymer processing aids
  • the multilayer films used to make the bags of the present invention are preferably irradiated to induce crosslinking, as well as corona treated to roughen the surface of the films which are to be adhered to one another.
  • the film is subjected to an energetic radiation treatment, such as corona discharge, plasma, flame, ultraviolet, X-ray, gamma ray, beta ray, and high energy electron treatment, which induce cross-linking between molecules of the irradiated material.
  • an energetic radiation treatment such as corona discharge, plasma, flame, ultraviolet, X-ray, gamma ray, beta ray, and high energy electron treatment, which induce cross-linking between molecules of the irradiated material.
  • BORNSTEIN, et al. discloses the use of ionizing radiation for crosslinking the polymer present in the film.
  • Radiation dosages are referred to herein in terms of the radiation unit “RAD”, with one million RADS, also known as a megarad, being designated as “MR”, or, in terms of the radiation unit kiloGray (kGy), with 10 kiloGray representing 1 MR, as is known to those of skill in the art.
  • a suitable radiation dosage of high energy electrons is in the range of up to about 16 to 166 kGy, more preferably about 40 to 90 kGy, and still more preferably, 55 to 75 kGy.
  • irradiation is carried out by an electron accelerator and the dosage level is determined by standard dosimetry processes.
  • Other accelerators such as a van der Graaf or resonating transformer may be used.
  • the radiation is not limited to electrons from an accelerator since any ionizing radiation may be used.
  • corona treatment and “corona discharge treatment” refer to subjecting the surfaces of thermoplastic materials, such as polyolefins, to corona discharge, i.e., the ionization of a gas such as air in close proximity to a film surface, the ionization initiated by a high voltage passed through a nearby electrode, and causing oxidation and other changes to the film surface, such as surface roughness.
  • thermoplastic materials such as polyolefins
  • Corona treatment of polymeric materials is disclosed in U.S. Pat. No. 4,120,716, to BONET, issued Oct. 17, 1978, herein incorporated in its entirety by reference thereto, discloses improved adherence characteristics of the surface of polyethylene by corona treatment, to oxidize the polyethylene surface.
  • U.S. Pat. No. 4,879,430, to HOFFMAN also hereby incorporated in its entirety by reference thereto, discloses the use of corona discharge for the treatment of plastic webs for use in meat cook-in packaging, with the corona treatment of the inside surface of the web to increase the adhesion of the meat to the adhesion of the meat to the proteinaceous material.
  • corona treatment is a preferred treatment of the multilayer films used to make the pre-padded bag of the present invention, plasma treatment of the film may also be used.
  • a multilayer film is preferably converted to the bags of the present invention by heat sealing both across the film (i.e., a transverse heat seal) as well as heat sealing in the machine direction along the length of the film (i.e., a machine direction seal).
  • the transverse seal is preferably made using a heat sealing method known as “impulse sealing”, which is carried out by placing a seal bar across the film and thereafter momentarily passing current through a heat seal wire on the seal bar. The seal wire heats up, transferring heat through a first side of the film tubing (or folded film) to the other side, causing the film to be sealed to itself. This sealing method is well known to those of skill in the art.
  • the lengthwise heat sealing (i.e., machine direction heat sealing) can be carried out using a seal bar and impulse sealing, i.e., in the same manner that the transverse seals are made.
  • impulse heat sealing is generally carried out by forwarding the film intermittently in a direction along the length of the film tubing or sheet. If continuous forwarding of the film is desired during lengthwise heat sealing, a continuous band sealer can be used.
  • continuous band heat sealers are described in U.S. Pat. No. 5,858,153, to Mack, entitled “Method for Making Tubular Containers”, as well as U.S. Pat. No. 6,344,258 B1, to Rasmussen, entitled “Heat-Sealing Polymer Films”, and U.S. Pat. No.
  • FIG. 10 depicts a continuous chain of sets 200 of pre-padded side-seal bags.
  • Each bag set 200 comprises a first side-seal bag 202 containing an absorbent pad 206 and a second side-seal bag 204 containing an absorbent pad 208 .
  • the chain of bag sets 200 in the illustrated embodiment is constructed from a center-folded film or from a seamless lay-flat tubing that is slit along one longitudinal edge to open the tubing for insertion of the absorbent pads.
  • a folded edge 210 of the center-folded film or slit tubing forms a bottom end of each bag.
  • First bag 202 of each set has a first side seal formed by a first transverse seal 212 extending across the width of the film, and a second side seal formed by a second transverse seal 214 extending across the width of the film.
  • Second bag 204 of each set has a first side seal formed by a third transverse seal 216 extending across the width of the film, and a second side seal formed by a fourth transverse seal 218 extending across the width of the film.
  • the third transverse seal 216 can be spaced longitudinally (i.e., along the lengthwise or machine direction of the film) a short distance from the second transverse seal 214 .
  • first transverse seal 212 of a subsequent bag set 200 can be longitudinally spaced a short distance from the fourth transverse seal 218 of a preceding bag set 200 .
  • Transverse lines of weakness 220 advantageously are formed in the film between the fourth transverse seal 218 of each bag set and the first transverse seal 212 of the subsequent contiguous bag set to facilitate separating the bag sets from one another. It is also possible to include a transverse line of weakness between the two bags 202 , 204 of each bag set, if desired, to facilitate separating the chain into single bags.
  • a chain of pre-padded side-seal bag sets alternatively can be formed from separate first and second films by disposing absorbent pads on the first film (and preferably adhering the pads to the film) and bringing the second film into overlying relation with the first film, longitudinally sealing one longitudinal edge of the first film to the corresponding longitudinal edge of the second film so as to form end seals for the bags, and then forming transverse seals (and optionally the lines of weakness) across the two films generally as described above in connection with FIG. 10 so as to form side seals for the bags.

Abstract

Pre-padded bags are produced from polymeric film material having a machine direction and a transverse direction, for packaging products such as fresh meats and poultry. A set of pre-padded end-seal bags comprises a first bag and a second bag, each bag comprising a first film portion and an underlying second film portion, the first and second film portions being sealed together with a transversely extending seal to form an end seal of each bag, the first and second film portions being sealed together with a longitudinal seal along the machine direction to form a side seal of each bag, the first bag being connected to the second bag in an area between the side seals of the bags, and each bag containing a fluid-absorbent pad.

Description

    BACKGROUND OF THE INVENTION
  • The present invention relates to bags formed from polymeric film and containing fluid-absorbent pads for absorbing fluids.
  • Poultry and meat are frequently sold in transparent plastic bags. A problem with this type of packaging is that the poultry or meat contains blood and other fluids that flow out of the meat after it has been packaged. The blood and other fluids accumulate in the package, detracting from its appearance. In addition, the blood and fluid sometimes leak from the package while the consumer is transporting it home from the market. To counter this problem, food bag manufacturers often insert an absorbent pad into the bag prior to packaging the food product. The pad absorbs the exuded blood and fluid and thereby enhances the appearance of the packaged product. In many cases, the absorbent pads are manually inserted into the bags. The manual labor associated with placing the absorbent pads in the bags prior to product packaging adds to the cost and time associated with this operation.
  • Meat and poultry are often packaged in heat-shrinkable bags, including “end seal” bags. In the making of heat-shrinkable end-seal bags, thermoplastic material is extruded from an annular die in the form of a seamless tubing, with the extrudate (known as a “tape”) being relatively thick and relatively narrow. The annular extrudate is then quenched. Optionally, the tape can then be irradiated and/or coated with one or more additional layers containing thermoplastic polymer. The tape is then reheated to its softening point by exposure to hot water or steam (or other heating means) and is stretched in its longitudinal and transverse directions while the polymer remains in the solid state, resulting in heat-shrinkable film in the form of a seamless tubing. The heat-shrinkable film tubing is then converted into end-seal bags by placing the tubing into a lay-flat configuration and heat-sealing across the tubing to heat-seal the inside surface of the tubing to itself. The seals across the tubing are made at intervals along the length of the tubing, these intervals corresponding with the desired bag lengths. The resulting sealed tubing is then converted into a plurality of heat-shrinkable bags by cutting across the tubing a short distance downstream of each of the transverse heat-seals, resulting in a plurality of lay-flat bags having an open top, two seamless side edges, a heat seal across the bag near the bottom edge of the bag, and a short section of tubing (commonly referred to as a “skirt”) below the transverse heat seal.
  • When end-seal bags extend across the entire width of the lay-flat tubing, such bags come off the production line one at a time, and each bag generally entails a separate sealing cycle and a separate printing cycle. It would be desirable to reduce the number of sealing cycles, printing cycles, and cutting cycles, to increase throughput of the process, and in some cases to provide bags of reduced width. It would also be desirable to provide such bags with absorbent pads and to do so in an automated fashion.
  • BRIEF SUMMARY OF THE INVENTION
  • The present invention addresses the above needs and achieves other advantages, by providing a set of pre-padded end-seal bags and a process for making sets of such bags. The invention enables the number of printing cycles, as well as the number of cycles used to make the transverse seals, to be substantially reduced while making the same total number of bags, thereby enabling a substantial increase in the number of bags per extrusion die, as well as per print cycle and per transverse seal cycle. In addition, the sets of pre-padded bags in preferred embodiments have a lengthwise free shrink (i.e., shrink in the machine direction) that is less than the transverse free shrink (i.e., shrink across the width of the bags), so that during shrinking the bags have less tendency to distort flat, flexible, elongate products packaged in the bag.
  • The process can be used to produce sets of bags in which the bags of each set are connected with one another across the machine direction of the film being used to make the bags. Optionally, each set of bags can be provided with an appropriate number of longitudinal tear lines (i.e., tear lines running the length of the bags, i.e., in the machine direction) for ease in separating the bags from one another. Moreover, because the bags are connected to one another, the connected series of bags can be stretched out across the opening of a vacuum chamber without risk of overlap during sealing.
  • Additionally, the invention can be carried out so that each set of bags is connected to at least one other set of bags in a line of succession, e.g., resulting in a chain of sets of bags, which can be of indeterminate length as it comes off a production line. Optionally, this chain of sets of bags can be provided with transverse tear lines (i.e., a weakened region between the sets of bags, such as a line of perforations, etc.) so that each set of bags can be easily torn free of the chain of bags, as well as lengthwise (i.e., machine direction) tear lines between the bags of each set, so that the packaged product can be offered as singlets or any subset of the original set of bags.
  • In the sets of bags of the invention, the bag length of each of the bags in the set runs in the machine direction of the tubing or film. Likewise, the bag width of each of the bags in the set runs in the transverse direction across the tubing or film. A greater free shrink in the transverse direction is desirable for the packaging of a wide variety of products, particularly food products that tend to distort by bending along the length of the bag in which they are packaged. Various meat products, such as small beef and pork cuts, for example, beef and pork tenderloin, eye of round, single ribs, beef spare ribs, split beef back ribs, and various lamb cuts, tend to distort (i.e., bend) if packaged in a shrink bag having a higher shrink along the length of the bag than across the width of the bag. Such package distortion can be reduced or eliminated in the sets of bags of the invention, if the bags are provided with greater free shrink across the bag than along the length of the bag.
  • Sets of pre-padded bags in accordance with the invention can be made with various processes. In one embodiment, a chain of sets of pre-padded bags is made from two continuous polymer film webs that are positioned in overlying relation with each other. Absorbent pads are inserted between the two films and preferably adhered to one of the films. The pads are arranged in sets spaced at bag-length intervals along the films, the pads of each set being spaced transversely across the films. The films are then sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags. The films preferably are perforated longitudinally between the bags of each set to facilitate separating the bags of each set. The opposite longitudinal edges of the films are sealed together, and transverse seals are made across the films at spaced bag-length intervals. The films advantageously are perforated across the films adjacent each transverse seal to facilitate separating one set of bags from another.
  • In another embodiment, a chain of sets of pre-padded bags is made from a continuous lay-flat tubing. The lay-flat tubing is slit along at least one of its longitudinal edges to open the tubing, and absorbent pads are inserted between the two film portions of the slit lay-flat tubing, and preferably are adhered to one of the film portions of the slit lay-flat tubing. The pads are arranged in sets spaced at bag-length intervals along the lay-flat tubing, the pads of each set being spaced transversely across the lay-flat tubing. The tubing is then sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags. The tubing preferably is perforated longitudinally between the bags of each set to facilitate separating the bags of each set. The (or each) slit longitudinal edge of the tubing is sealed together, and transverse seals are made across the tubing at spaced bag-length intervals. The tubing advantageously is perforated across the films adjacent each transverse seal to facilitate separating one set of bags from another.
  • In still another embodiment, a chain of pairs of pre-padded bags is made from a single wide lay-flat film. Absorbent pads are placed onto the film and preferably adhered to the film. The pads are arranged in pairs spaced at bag-length intervals along the film, the pads of each set being spaced transversely on opposite sides of a centerline of the film. The film is then C-folded by bringing the opposite longitudinal edges of the film inwardly toward the centerline such that the pads are disposed between two overlying film portions and respective underlying film portions. The longitudinal edges of the overlying film portions are sealed with longitudinal seals to the underlying film portions to form interior side seals of the bags. The film preferably is perforated down the centerline to facilitate separating the bags of each set. Transverse seals are made across the film at spaced bag-length intervals. The film advantageously is perforated across the film adjacent each transverse seal to facilitate separating one set of bags from another.
  • In accordance with a further embodiment of the invention, a chain of sets of pre-padded bags is made from a single wide lay-flat film. Absorbent pads are placed onto the film and preferably adhered to the film. The pads are arranged in sets spaced at bag-length intervals along the film, the pads of each set being spaced transversely across half of the width of the film. The film is then folded down the middle (i.e., center-folded) by bringing one of the opposite longitudinal edges of the film over so as to overlie the other longitudinal edge of the film, such that the pads are disposed between an overlying film portion and an underlying film portion. The longitudinal edges of the film portions are sealed together with a longitudinal seal to form an outer side seal for one of the bags of each set of bags of the chain. The folded film is sealed with one or more longitudinal seals (e.g., one longitudinal seal in the case of sets of two bags, two spaced longitudinal seals in the case of sets of three bags, etc.) to form interior side seals of the bags. The film preferably is perforated longitudinally between the bags of each set to facilitate separating the bags of each set. Transverse seals are made across the film at spaced bag-length intervals. The film advantageously is perforated across the film adjacent each transverse seal to facilitate separating one set of bags from another.
  • A set of pre-padded bags made from a film in accordance with a first aspect of the invention comprises a first lay-flat bag and a second lay-flat bag joined along their respective lengths, with an end seal extending across both the first bag and the second bag. Each of the first and second bags contains an absorbent pad, preferably adhered to the film. The first bag has a first side seal extending the length of the first bag, and the second bag has a second side seal extending the length of the second bag. The first bag is connected with the second bag in an area between the first side seal and the second side seal. Both the first bag and the second bag having a total free shrink at 185° F. of at least 10 percent, and both the first bag and the second bag have a transverse free shrink at 185° F. which is greater than a longitudinal free shrink at 185° F.
  • In one embodiment, the set of bags has a first outer side edge and a second outer side edge, and at least one of the first outer side edge and the second outer side edge is a folded edge.
  • Preferably, the film has a total free shrink, at 185° F., of at least 15 percent; more preferably, at least 20 percent, more preferably, at least 25 percent; more preferably, at least 30 percent; more preferably, at least 35 percent; more preferably, at least 40 percent; more preferably, at least 45 percent. Preferably, the film has a total free shrink at 185° F. of from 15 to 150 percent; more preferably, from 20 to 140 percent; more preferably, from 25 to 130 percent; more preferably, from 30 to 120 percent; more preferably, from 35 to 110 percent; more preferably, from 40 to 100 percent; and, more preferably, from 45 to 90 percent.
  • Preferably, the end seal, the first side seal, and the second side seal are heat seals. In one embodiment of the invention, the end seal, the first side seal, and the second side seal are each a seal of an inside surface of a seamless tubing to itself. The end seal can be a straight seal or can be curved or have at least one curved region. If curved, preferably the end seal is curved so that the bottom of the lay-flat set of bags is convex.
  • Preferably, the set of bags further comprises a line of weakness between the first bag and the second bag, the line of weakness being between the first side seal and the second side seal. Preferably, the line of weakness between the first bag and the second bag comprises perforations.
  • Although the set of bags can comprise a pair of bags, the set of bags can further comprise first, second, and third bags, wherein the second bag is between the first bag and the third bag, the second bag having two side seals and an end seal. If the set of bags is a pair of bags, the first bag is preferably a mirror image of the second bag. Preferably, the first bag has a length equal to the length of the second bag. Preferably, first side seal is parallel to the second side seal.
  • Preferably, the film from which the set of bags is made is a multilayer film comprising a first outer film layer, a second outer film layer, and an inner O2-barrier layer comprising at least one polymer selected from the group consisting of vinylidene chloride/methyl acrylate copolymer, vinylidene chloride/vinyl chloride copolymer, ethylene/vinyl alcohol copolymer, polyamide, and polyethylene carbonate. Preferably, the multilayer film further comprises a fourth layer which serves as a tie layer between the barrier layer and the first outer film layer, and a fifth layer which serves as a tie layer between the barrier layer and the second outer layer.
  • Optionally, the first bag and the second bag have printing thereon.
  • In a second aspect, the present invention pertains to a plurality of sets of pre-padded bags, with each set being in accordance with the first aspect of the invention (described above). The first set of bags comprises a first bag and a second bag joined along their respective lengths, the first pair of bags having a first end seal extending across both the first bag and the second bag, the first bag having a first side seal extending the length of the first bag, and the second bag having a second side seal extending the length of the second bag, the first bag being connected with the second bag in an area between the first side seal and the second side seal. The second set of bags comprises a third bag and a fourth bag, the second set of bags having a second end seal extending across both the third bag and the fourth bag, the third bag having a third side seal extending the length of the third bag and the fourth bag having a fourth side seal extending the length of the fourth bag. The third bag is connected with the fourth bag in an area between the third side seal and the fourth side seal. The second set of bags is joined to the first set of bags in an area below the first end seal. Preferably, the third side seal is a continuation of the first side seal, and the fourth side seal is a continuation of the second side seal. Preferably, the second set of bags is joined to the first set of bags along a transverse line of weakness. Preferably, the line of weakness between the first set of bags and the second set of bags comprises perforations. Optionally, the set of bags further comprises a third set of bags which is joined to the second set of bags below the second end seal, and a fourth set of bags joined to the third set of bags below a third end seal, with the plurality of sets of bags being a portion of a chain of sets of bags, the chain being of indeterminate length. Unless inconsistent therewith, preferred embodiments of the second aspect of the invention correspond with preferred features of the first aspect of the present invention.
  • As a third aspect, the present invention pertains to a set of pre-padded bags made from a film. The set of bags comprises a first lay-flat bag and a second lay-flat bag joined along their respective lengths, and an end seal extending across both the first bag and the second bag, with the first bag connecting with the second bag at a heat seal between the first bag and the second bag, the heat seal extending the length of the first bag and the second bag, with both the first bag and the second bag having a total free shrink at 185° F. of at least 10 percent and a transverse free shrink at 185° F. which is greater than a longitudinal free shrink at 185° F. Each bag contains an absorbent pad, which preferably is adhered to the film.
  • In yet another aspect of the invention, pre-padded side-seal bags are provided as a continuous chains of serially connected bags.
  • BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)
  • Having thus described the invention in general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
  • FIG. 1 illustrates a lay-flat view of a set (in this illustration, a pair) of pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges;
  • FIG. 2 illustrates a lay-flat view of a pair of pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, with the pair of bags being connected to one another along a longitudinal line of weakness (e.g., perforations);
  • FIG. 3 illustrates a portion of a continuous chain of pre-padded bag pairs made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, with a longitudinal line of weakness between the bags of each pair, with each pair of bags being connected to the next successive pair of bags with a transverse line of weakness located a short distance downstream of the transverse seal across the bags;
  • FIG. 4 illustrates a lay-flat view of a set (e.g., a pair) of alternative pre-padded bags made from a pair of films or from a seamless lay-flat tubing slit along both longitudinal edges, each of the bags of each set having a curved end seal;
  • FIG. 5 illustrates a lay-flat view of an alternative pair of pre-padded bags made by folding a flat film over on itself and sealing it to form a pair of bags, or by slitting a lay-flat tubing along only one longitudinal edge for pad insertion;
  • FIG. 6 illustrates a lay-flat view of an alternative set of pre-padded bags which is made up of three bags across a seamless lay-flat tubing;
  • FIG. 7 illustrates a lay-flat view of a set of pre-padded bags made from a single wide lay-flat film that is C-folded;
  • FIG. 8 illustrates a lay-flat view of an alternative pair of pre-padded bags in accordance with the present invention;
  • FIG. 9 is a schematic depiction of a preferred process for producing multilayer films for use in the sets of bags of the present invention; and
  • FIG. 10 illustrates a lay-flat view of a continuous chain of sets of pre-padded side-seal bags in accordance with the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION
  • The present inventions now will be described more fully hereinafter with reference to the accompanying drawings, in which some but not all embodiments of the inventions are shown. Indeed, these inventions may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
  • As used herein, the term “bag” is inclusive of L-seal bags, side-seal bags, backseamed bags, and pouches (i.e., “U-sealed” bags). An L-seal bag has an open top, a bottom seal, one side seal along a first side edge, and a seamless (i.e., folded, unsealed) second side edge. A side-seal bag has an open top and a seamless bottom edge, with each of its two side edges having a seal therealong. Although seals along the side and/or bottom edges can be at the very edge itself, (i.e., seals of a type commonly referred to as “trim seals”), preferably the seals are spaced inward (preferably about ¼ to ½ inch) from the bag side edges, and preferably are made using an impulse-type heat sealing apparatus, which utilizes a bar that is quickly heated and then quickly cooled. A backseamed bag is a bag having an open top, a seal running the length of the bag in which the bag film is either fin-sealed or lap-sealed, two seamless side edges, and a bottom seal along a bottom edge of the bag.
  • As used herein, the phrase “set of bags” refers to two or more bags that are connected with one another in a side-by-side relationship, with the bags extending across a tubing (seamed or seamless). The set of bags preferably comprises from 2 to 20 bags across the tubing, more preferably from 2 to 5 bags, more preferably 2 to 3 bags. Each bag preferably has a length of at least twice its width, more preferably three to ten times its width, with bag length and bag width being measured based on inside the bag dimensions while the bag is in a lay-flat position. The phrase “connected with”, as applied to the bags of a single set of bags, refers to the side-by-side relationship of the bags to one another, and does not require that the bags be directly adhered to one another. That is, two bags are connected with one another even if another bag is between them or even if a section of waste film is between them. Likewise, two bags are connected with one another if they share a common side seal, as illustrated in FIG. 9, described below.
  • The phrases “lay-flat film tubing”, “lay-flat bag”, and “lay-flat width” are known to those of skill in the flexible film art. A lay-flat film tubing is extruded through an annular die, with the extrudate being cooled and gathered by converging sets of rollers and wound up in flattened form. A lay-flat bag includes bags of various configurations including but not limited to end seal, side seal, L-seal, etc., which can be made by sealing the inside of a lay-flat film tubing to itself, following by cutting across the tubing to convert the tubing into, for example, an end-seal bag. A side-seal bag requires slitting one side edge of the tubing in addition to cutting across the tubing. Side seal and L-seal lay-flat bags can also be made by folding a flat film and sealing the inside surface of the folded film to itself. A pouch is often made by sealing two separate pieces of flat film to one another, with the seals extending up the sides of the pouch and across the bottom of the pouch, leaving the top of the bag open for the insertion of the product to be packaged.
  • As used herein, the phrase “line of weakness” refers to any line, whether straight or curved, whether wide or narrow, in which the film has been weakened by any means so that the film can readily be torn apart along the line. As one example, the line of weakness can be formed by perforating the film. Alternatively, the line of weakness can comprise one or more slits formed in the film along the line at which the film is desired to preferentially tear, the slits being configured so that one or more parts of said line are not slit (although they may be perforated) and thereby serve to keep the film portions on opposite sides of the line connected to each other until it is desired to separate the film portions.
  • As used herein, the phrases “heat-shrinkable film,” “heat-shrink film” and the like refer to a film that has been oriented while in the solid state (as opposed to a blown film, which is oriented at, above, or near the melting point of the polymer). The tension on a heat-shrinkable film increases upon the application of heat if the film is restrained from shrinking. As a corollary, the phrase “heat-contracted” refers to a heat-shrinkable film, or a portion thereof, which has been exposed to heat such that the film or portion thereof is in a heat-shrunken state, i.e., reduced in size (unrestrained) or under increased tension (restrained). Preferably, the heat-shrinkable film has a total free shrink (i.e., machine direction plus transverse direction), with the free shrink in each direction (measured in accordance with ASTM D 2732) of at least 5 percent at 185° C., more preferably at least 7 percent, still more preferably at least 10 percent, still more preferably at least 15 percent, and yet still more preferably at least 20 percent. The total free shrink at 185° F. can be from 10 to 150 percent, more preferably from 20 to 120 percent, more preferably from 40 to 100 percent.
  • As used herein, the phrases “inner layer” and “internal layer” refer to any layer, of a multilayer film, having both of its principal surfaces directly adhered to another layer of the film.
  • As used herein, the phrase “outer layer” refers to any film layer of film having less than two of its principal surfaces directly adhered to another layer of the film. The phrase is inclusive of monolayer and multilayer films. In multilayer films, there are two outer layers, each of which has a principal surface adhered to only one other layer of the multilayer film. In monolayer films, there is only one layer, which, of course, is an outer layer in that neither of its two principal surfaces are adhered to another layer of the film.
  • As used herein, the phrase “inside layer” refers to the outer layer of a multilayer film packaging a product, which is closest to the product, relative to the other layers of the multilayer film.
  • As used herein, the phrase “outside layer” refers to the outer layer, of a multilayer film packaging a product, which is farthest from the product relative to the other layers of the multilayer film. Likewise, the “outside surface” of a bag is the surface away from the product being packaged within the bag.
  • As used herein, the term “adhered” is inclusive of films that are directly adhered to one another using a heat seal or other means, as well as films that are adhered to one another using an adhesive that is between the two films.
  • Although the films used in the pre-padded bag according to the present invention can be monolayer films or multilayer films, the pre-padded bag comprises at least two films laminated together. Preferably, the pre-padded bag is comprised of films that together comprise a total of from 2 to 20 layers; more preferably, from 2 to 12 layers; and still more preferably, from 4 to 12 layers. In general, the multilayer film(s) used in the present invention can have any total thickness desired, so long as the film provides the desired properties for the particular packaging operation in which the film is used, e.g. abuse-resistance (especially puncture-resistance), modulus, seal strength, optics, etc.
  • FIG. 1 is a lay-flat view of a set 10 of two bags 12 and 14 made by sealing together two separate films 16 and 18 in accordance with one embodiment of the invention. The films 16 and 18 are positioned in overlying relation with each other such that first longitudinal edges 20 of the films are aligned and opposite second longitudinal edges 22 of the films are aligned. Fluid- absorbent pads 24 and 26 are disposed between the two films, and preferably are adhered to one of the films, such as film 16, so that the pads do not shift position during subsequent bag formation and packaging of products. Various materials and constructions can be used for the fluid-absorbent pads. As one non-limiting example, the pads can comprise DRI-LOC® absorbent pads available from Sealed Air Corporation. However, the invention is not limited in this respect, and any pads suitable for the particular application can be used in each instance. A food-grade pressure-sensitive adhesive or low-temperature food-grade adhesive can be used for adhering the pads to one or both films 16, 18.
  • The set 10 of bags is constructed by forming a first longitudinal seal 28 adjacent the first longitudinal edges 20 of the films, a second longitudinal seal 30 spaced in the transverse or width direction of the films from the first longitudinal seal 28 and located generally centrally of the width of the films, a third longitudinal seal 32 transversely spaced a short distance from the second longitudinal seal 30 in the direction of the second longitudinal edges 22 and located generally centrally of the width of the films, and a fourth longitudinal seal 34 adjacent the second longitudinal edges 22 of the films. A transverse seal 36 is formed across the width of the films to form end seals for the two bags 12, 14; that is, a first portion of the transverse seal 36 forms an end seal for bag 12 and a second portion of the transverse seal 36, which is a continuation of the first portion, forms an end seal for bag 14. The second and third longitudinal seals 30, 32 can comprise a single longitudinal seal rather than two separate, spaced seals. In any event, the longitudinal seals 28 and 34 form outer longitudinal seals of the bags 12, 14, respectively, and the generally centrally located longitudinal seals 30, 32 (or single centrally located longitudinal seal, in the alternative) form interior longitudinal seals of the bags 12, 14, respectively. The transverse seal 36 can be spaced a short distance from the transverse edges of the films so as to form a skirt 38 at the closed bottom ends of the bags. The opposite ends 42, 44 of the bags 12, 14, respectively, are open for loading products into the bags
  • FIG. 2 is a lay-flat view of a set 10′ of bags 12, 14 having features that correspond with the features of the set of bags illustrated in FIG. 1, except that bag set 10′ additionally has a longitudinal line of weakness 46 running the length of the films between the two longitudinal seals 30, 32 (or bisecting a single centrally located longitudinal seal, in the alternative). Line of weakness 46 is preferably a line of perforations, but other techniques for weakening the films to allow them to tear in a desired location can be used instead. For example, line of weakness 46 can comprise a longitudinal slit in the film, or two or more slits, that extend(s) for part of the length of the bags 12, 14, with other portions of the film along line 46 being free of a slit so as to connect bags 12, 14 to each other until it is desired to separate them. The portion(s) free of a slit optionally can be perforated, if desired, to facilitate separation. Using slits and perforations in this manner, it is possible to ensure that bag pairs that are filled and sealed and placed into a shrink tunnel while still connected will become detached from each other during the heat-shrinking operation as a result of the shrinkage of the film, which causes the unslit (and optionally perforated) portions to be torn to separate the bags automatically
  • FIG. 3 illustrates continuous string or chain 50 of bag pairs 10′ having all of the features as illustrated in FIG. 2. However, in continuous string 50, immediately beneath skirt 38 of each bag pair 10′ is a transverse line of weakness 52. Line of weakness 52 is preferably a set of perforations aligned along a straight line located far enough below transverse seal 36 to provide skirt 38 with adequate width. Alternatively, line of weakness 52 can comprise a longitudinal slit in the film, or two or more slits, that extend(s) for part of the width of the bag pairs 10′, with other portions of the film along line 52 being free of a slit so as to connect the bag pairs to each other until it is desired to separate them. The portion(s) free of a slit optionally can be perforated, if desired, to facilitate separation.
  • FIG. 4 is a lay-flat view of a pre-padded bag pair 10″ having features that largely correspond with the features of the pair of bags illustrated in FIG. 2, except that transverse seal 36″ has curved sections 36 a and 36 b, which provide end seals across the bottom of first bag 12″ and second bag 14″, respectively. Likewise, matching curved sections are present at open top 42″ and 44″ of first bag 12″ and second bag 14″, respectively
  • FIG. 5 is an illustration of an alternative pair of pre-padded bags 60 comprising first bag 62 and second bag 64 that can be made by center-folding a flat film (or slitting a seamless tubing along one longitudinal edge). First bag 62 and second bag 64 have open tops 72 and 74, respectively. Pair of bags 60 has transverse seal 76 that forms end seals for first bag 62 and second bag 64. In addition, first bag 62 has outer folded edge 80 and inner longitudinal seal 82 (i.e., first bag 62 comprises an L-seal bag). Second bag 64 has both inner longitudinal seal 84 and outer longitudinal seal 86 (i.e., second bag 64 comprises a U-seal bag). Second bag 64 also has skirt 88 running the length of the bag, between outer longitudinal seal 86 and outer edge 90. As in FIG. 1, pair of bags 60 share central region between the inner longitudinal seals 82, 84, which as illustrated has no weakened line, so that products packaged in first bag 62 and second bag 64 are paired with one another unless cut apart along the length of the central region. Alternatively, a line of weakness can be provided between the bags 62, 64 to facilitate separating the bags from each other. The bag pair 60 also can include an end skirt 92 by virtue of transverse seal 76 being spaced some distance above the lower end edges of the center-folded film
  • It will be appreciated that a continuous chain of pre-padded bag pairs 60 can be formed from a continuous center-folded film or a continuous lay-flat seamless tubing that is slit along one longitudinal edge to enable the absorbent pads 24, 26 to be inserted between the film portions. Transverse lines of weakness can be formed in the continuous chain of bags adjacent each of the transverse seals, generally as previously described in connection with FIG. 3, to facilitate separating the bag pairs from one another
  • FIG. 6 illustrates a lay-flat view of an alternative set 110 of lay-flat pre-padded bags constructed from two separate films in generally the same manner as described in connection with FIG. 1, except that set 110 has three bags 112, 114, and 116. First bag 112 has an outer longitudinal seal 128 and an interior longitudinal seal 129 (i.e., first bag 112 comprises a U-seal bag), second bag 114 has a longitudinal seal 130 adjacent the longitudinal seal 129 and an opposite longitudinal seal 131, and third bag 116 has a longitudinal seal 132 adjacent the longitudinal seal 131 and an opposite longitudinal seal 134. Each of bags 112, 114, and 116 shares transverse end seal 136. First bag 112 is an L-seal bag utilizing a portion of end seal 136 in combination with longitudinal seal 128. Third bag 116 is also an L-seal bag, also utilizing a portion of end seal 136, but in combination with longitudinal seal 134. Second bag 114 is a U-seal bag utilizing yet another portion of end seal 136, together with longitudinal seal 130 and longitudinal seal 131. First bag 112 is joined to second bag 114 along line of weakness 137 (preferably a line of perforations), and second bag 114 is joined to third bag 116 along line of weakness 138 (preferably also a line of perforations). First bag 112 includes an absorbent pad 124, second bag 114 includes an absorbent pad 126, and third bag 116 includes an absorbent pad 127. The absorbent pads preferably are adhered to one of the films
  • A continuous chain of pre-padded bag sets 110 can be formed from continuous lengths of two films in a manner analogous to that described in connection with FIG. 3. The continuous chain can include transverse lines of weakness adjacent each of the transverse seals 136 to facilitate separating the bag sets from one another
  • FIG. 7 illustrates a lay-flat view of a pair of bags 110′ formed from a single wide lay-flat film that is C-folded and then sealed to form a pair of bags 112′ and 114′. More particularly, after a pair of absorbent pads 124 and 126 are placed onto the film (and preferably adhered thereto) with the pads spaced transversely apart on opposite sides of a longitudinal centerline of the film, the film is folded along a first longitudinal fold line 128′ to bring a first longitudinal edge of the lay-flat film inwardly toward and adjacent to the centerline so that a first portion of the film overlies an underlying portion on which pad 124 is disposed, and the first longitudinal edge of the film is sealed to the underlying portion of the film with a first longitudinal seal 129. The film is also folded along a second fold line 134′ to bring the opposite second longitudinal edge of the lay-flat film inwardly toward and adjacent to the centerline so that a second portion of the film overlies an underlying portion on which pad 126 is disposed, and the second longitudinal edge of the film is sealed to the underlying portion of the film with a second longitudinal seal 130. The first and second longitudinal seals 129, 130 can be spaced a short distance apart as illustrated in FIG. 7, or can be substantially coincident. A transverse seal 136 is formed across the C-folded film to form end seals for the bags 112′ and 114′. Thus, first bag 112′ comprises an L-seal bag (the L-seal comprising first longitudinal seal 129 and a first portion of transverse seal 136), and second bag 114′ also comprises an L-seal bag (the L-seal comprising second longitudinal seal 130 and a second portion of transverse seal 136)
  • Bag pair 110′ can also be formed from a seamless lay-flat tubing that is longitudinally slit along a centerline of one film portion to open the tubing for insertion of the pads 124, 126, followed by longitudinal sealing of the resulting two longitudinal edges with longitudinal seals 129, 130 as described above. In any event, a line of weakness 137 can be formed between bags 112′ and 114′ to facilitate separating the bags from each other
  • As yet another alternative, a chain of interconnected bag pairs 110′ can be formed from a seamless lay-flat tubing in a manner generally similar to that described in U.S. Patent Application Publication No. 2004/0255556 A1 to Boal et al., the entire disclosure of which is incorporated herein by reference. The lay-flat tubing has an upper layer and a lower layer. The method entails feeding the tubing to a perforator at which the upper layer and lower layer are perforated along a series of transverse lines spaced apart along the tubing's longitudinal direction at bag-length intervals. After the perforating step, the tubing is fed to a tube opener at which the upper layer is opened along the perforations to create an opening. Alternatively, a single station can sever the upper layer to create the opening and perforate the lower layer at the same time. Next, a pair of absorbent pads are inserted through each opening in the upper layer, generally in the manner described in the Boal '556 application. Once the pads have been inserted, a transverse seal is formed across the tubing adjacent each line of perforations. Longitudinal seals, and optionally a longitudinal line of weakness between the longitudinal seals, are then formed to complete the construction of the chain of bag pairs
  • FIG. 8 illustrates a lay-flat view of an alternative set of lay-flat pre-padded bags 60′ in accordance with the present invention. Bag set 60′ is constructed from a single wide lay-flat film that is center-folded and then sealed along one longitudinal edge, or from a seamless lay-flat tubing that is slit along one longitudinal edge for pad insertion and then sealed along that slit edge, generally in the same manner described above in connection with FIG. 5. Bag set 60′ comprises a pair of bags 62′ and 64′ respectively containing absorbent pads 24, 26. A transverse seal 76′ forms end seals for first bag 62′ and second bag 64′. In addition, first bag 62′ has outer folded edge 80′ and inner longitudinal seal 82′ (i.e., first bag 62′ comprises an L-seal bag). Second bag 64′ shares the longitudinal seal 82′ with first bag 62′, and has outer longitudinal seal 86′ (i.e., second bag 64′ comprises a U-seal bag). Second bag 64′ also has skirt 88′ running the length of the bag, between outer longitudinal seal 86′ and outer edge 90′. As illustrated, there is no line of weakness between bags 62′ and 64′, so that products packaged in first bag 62′ and second bag 64′ are paired with each other. The bag pair 60′ also can include an end skirt 92′ by virtue of transverse seal 76′ being spaced some distance above the lower end edges of the film
  • In the various embodiments of bag sets as described above, the absorbent pads can be placed into the bags in either a flat unfolded configuration or in a folded configuration, and the positioning of the pad within the bag can vary depending on the particular needs in each instance.
  • Preferably, the film stock film from which the bags are formed has a total thickness of from about 1.5 to 5 mils; more preferably, 1.5 to 4 mils; more preferably, 2 to 3 mils; more preferably, 2 to 2.5 mils. Preferably the stock film from which the bag is formed is a multilayer film having from 1 to 20 layers; more preferably, 3 to 10 layers; more preferably, 4 to 8 layers
  • Preferably, the bag film, present in the form of a seamless tubing, backseamed tubing (lap seal, fin seal, or butt sealed backseamed tubing with butt seal tape) or as a flat film, has a total (i.e., L+T) free shrink at 185° F. of from about 45 to 125 percent, with a free shrink in the longitudinal (i.e., machine) direction of from 20 to 50 percent, and a free shrink in the transverse direction of from 25 to 75 percent, with the transverse free shrink being greater than the longitudinal free shrink. More preferably, the bag film has a total free shrink at 185° F. of from about 55 to 110 percent, with a free shrink in the longitudinal direction of from 25 to 45 percent, and a free shrink in the transverse direction of from 30 to 65 percent, again with the transverse free shrink being greater than the longitudinal free shrink. More preferably, the bag film has a total free shrink at 185° F. of from about 65 to 95 percent, with a free shrink in the longitudinal direction of from 30 to 40 percent, and a free shrink in the transverse direction of from 35 to 55 percent, again with the transverse free shrink being greater than the longitudinal free shrink.
  • Preferably, the transverse free shrink at 185° F. is higher than the longitudinal free shrink at 185° F. by an amount of from about 5 to 30 percent, more preferably from 8 to 20 percent higher. Preferably, the transverse free shrink is from 1.1 times to 1.8 times as high as the longitudinal free shrink, more preferably from 1.2 to 1.7 times as high, more preferably from 1.25 to 1.65 times as high.
  • Table I, below, provides a preferred multilayer film structure for making a set of bags in accordance with the present invention, including the composition, thickness, and general function of each of the film layers. This film, extruded from an annular die and thereafter extrusion coated, was in the form of a seamless tubing and had a total thickness of approximately 2.4 mils, and exhibited a total free shrink at 185° F. of 20% in the machine direction and 33% in the transverse direction.
    TABLE I
    Layer Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 90% EVA #1 0.58
    layer 10% HDPE #1
    O2-Barrier layer 96% VDC/MA #1; 0.19
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Puncture-resistant 85% LLDPE #1 & 15% EBA #1 1.15
    Sealant and inside 80% SSPE#1 0.48
    layer 20% LLDPE #2
  • In Table I, LLDPE #1 was DOWLEX® 2045 linear low density polyethylene, obtained from the Dow Chemical Company of Midland, Mich.
  • LLDPE #2 was ESCORENE® LL3003.32 linear low density polyethylene, obtained from Exxon Chemical Company of Baytown, Tex. SSPE#1 was AFFINITY® P11280 metallocene-catalyzed ethylene/octene copolymer, having a density of 0.900 g/cc and a melt index of 6 g/10 min, obtained from The Dow Chemical Company, of Midland, Mich. HDPE #1 was Fortiflex® T60-500-119 high density polyethylene, obtained from Solvay Polymers, of Deer Park, Tex. EVA No. 1 was ESCORENE® LD318.92 ethylene/vinyl acetate copolymer having a melt index of 2.0, a density of 0.930 g/cc, and a vinyl acetate mer content of 9 percent, this resin being obtained from the Exxon Chemical Company. EBA No. 1 was SP 1802 ethylene/butyl acrylate copolymer containing 18% butyl acrylate, obtained from Chevron Chemical Company, of Houston, Tex.
  • Table II, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 3 mils and a free shrink at 185° F. of 28 percent in the machine direction and 36 percent in the transverse direction.
    TABLE II
    Layer
    Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 80% SSPE2 0.21
    layer 20% LLDPE3
    Core Layer 100% LLDPE2 0.32
    Tie Layer 100% EMA 0.11
    O2-Barrier layer 96% VDC/MA #1; 0.21
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Tie Layer 100% EVA1 0.11
    Substrate Core Layer 60% LLDPE2 1.5
    40% LLDPE3
    Seal Layer
    60% SSPE1 0.56
    40% LLDPE 1
  • Table III, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of about 2.2 mils and a free shrink at 185° F. of about 31% in the machine direction and about 44% in the transverse direction.
    TABLE III
    Layer
    Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 85% SSPE2 0.19
    layer 15% LLDPE3
    Core Layer 100% LLDPE2 0.29
    Tie Layer 100% EMA 0.1
    O2-Barrier layer 96% VDC/MA; 0.19
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Tie Layer 100% EVA1 0.1
    Substrate Core Layer 80% LLDPE2 0.86
    20% LLDPE3
    Seal Layer
    80% SSPE1 0.48
    20% LLDPE 1
  • Table IV, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2.3 mils and a free shrink at 185° F. of 25 in the machine direction and 41 in the transverse direction.
    TABLE IV
    Layer
    Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 100% EVA4 0.6
    layer
    O2-Barrier layer 96% VDC/MA #1; 0.17
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Substrate Core Layer 100% EVA4 1.28
    Seal Layer 100% LDPE 0.26
  • Table V, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2 mils and a free shrink at 185° F. of 31 in the machine direction and 46 in the transverse direction.
    TABLE V
    Layer
    Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 85% SSPE2 0.18
    layer 15% LLDPE3
    Core Layer 100% LLDPE2 0.27
    Tie Layer 100% EMA 0.09
    O2-Barrier layer 96% VDC/MA #1; 0.18
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Tie Layer 100% EVA1 0.09
    Substrate Core Layer 80% LLDPE2 0.73
    20% LLDPE3
    Seal Layer
    90% SSPE1 0.45
    10% MB1
  • Table VI, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2 mils and a free shrink at 185° F. of 26 in the machine direction and 42 in the transverse direction.
    TABLE VI
    Layer Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 85% EVA3 0.27
    layer 15% LLDPE3
    Core Layer 100% LLDPE2 0.4
    Core Layer 100% EVA3 .13
    Core Layer 100% EVA3 0.09
    Substrate Core Layer 76% LLDPE2 0.8
    24% MB2
    Seal Layer 100% LLDPE4 0.31
  • Table VII, below, provides another preferred multilayer film structure for making the sets of bags in accordance with the present invention, the film having a total thickness of 2.2 mils and a free shrink at 185° F. of 36 in the machine direction and 51 in the transverse direction.
    TABLE VII
    Layer
    Thickness
    Layer Function Layer Chemical Identity (mils)
    Outside and abuse 100% SSPE2 0.19
    layer
    Core Layer 100% SSCPE3 0.29
    Tie Layer 100% EVA2 0.10
    O2-Barrier layer 96% VDC/MA #1; 0.19
    2% epoxidized soybean oil; and
    2% bu-A/MA/bu-MA terpolymer
    Tie Layer 100% EVA1 0.10
    Substrate Core Layer 90% SSCPE3 0.86
    10% EPD
    Seal Layer 100% SSPE1 0.48
  • In Tables II through VII, SSPE1 was Dow Affinity® PL 1280 ethylene/octene copolymer, having a density of 0.900 g/cc and a melt index of 6 g/10 min. SSPE2 was Dow Affinity® PL 1850, having a density of 0.902 g/cc and a melt index of 3 g/10 min. SSCPE3 was DPF 1150.01 single site catalyzed ethylene/octene copolymer having a density of 0.901 g/cc and a melt index of 0.9 g/10 min, obtained from Dow. LLDPE1 was Exxon Escorene® LL3003.32 linear low density polyethylene having a density of 0.9175 g/cc and a melt index of 3.2 g/10 min. LLDPE2 was Dow Attane® 4203, having a density of 0.905 g/cc and a melt index of 0.8 g/10 min. LLDPE3 is Dow Dowlex® 2045.03 linear low density polyethylene, having a density of 0.92 g/cc and a melt index of 1.1 g/10 min. LLDPE4 was Exceed® 4518PA ethylene/hexene copolymer having a density of 0.918 and a melt index of 4.5 g/10 min. LDPE was Ruxell® V3401 ethylene/octene copolymer having a density of 0.911 g/cc and a melt index of 5.7 to 7.5 g/10 min, obtained from Huntsman. EVA1 was LD-713.93 ethylene/vinyl acetate copolymer, having a vinyl acetate content of 15 percent, a density of 0.933 g/cc and a melt index of 3.5 g/10 min, and was obtained from Exxon. EVA2 was Escorene® LD 761.36 ethylene/vinyl acetate copolymer having a density of 0.95 g/cc, a melt index of 5.7 g/10 min, and a vinyl acetate content of 28 percent, obtained from ExxonMobil. EVA3 was Escorene® LD 318.92 ethylene/vinyl acetate copolymer having a density of 0.93 g/cc, a melt index of 2 g/10 min, and a vinyl acetate content of 9 percent, obtained from ExxonMobil. EVA4 was Elvax® 3128 ethylene/vinyl acetate copolymer having a density of 0.928 g/cc, a melt index of 2 g/10 min, and a vinyl acetate content of 8.9%, obtained from DuPont. EMA was EMAC SP 1305 ethylene/methyl acrylate copolymer, having a methyl acrylate content of 20 percent, a density of 0.944 g/cc and a melt index of 2 g/10 min, also obtained from Exxon. EPD was Vistalon® 7800 ethylene/propylene/diene terpolymer, having a density of 0.87 g/cc and a melt index of 1.5 g/10 min, obtained from Exxon. VDC/MA was SARAN® MA-134 vinylidene chloride/methyl acrylate copolymer, obtained from the Dow Chemical Company. The epoxidized soybean oil was PLAS-CHEK® 775 epoxidized soybean oil, obtained from the Bedford Chemical Division of Ferro Corporation, of Walton Hills, Ohio. Bu-A/MA/bu-MA terpolymer was METABLEN® L-1000 butyl acrylate/methyl methacrylate/butyl methacrylate terpolymer, obtained from Elf Atochem North America, Inc., of 2000 Market Street, Philadelphia, Pa. 19103. MB1 was FSU 93E polyethylene masterbatch with slip and antiblock, having a density of 0.975 g/cc and a melt index of 7.5 g/10 min, obtained from A. Schulman. MB2 was 180637 light cream masterbatch having a density of 1.25 g/cc, obtained from Ampacet.
  • FIG. 9 illustrates a schematic of a preferred process for producing the multilayer films described in Tables I, II, and III, above. In the process illustrated in FIG. 9, solid polymer beads (not illustrated) are fed to a plurality of extruders 140 (for simplicity, only one extruder is illustrated). Inside extruders 140, the polymer beads are forwarded, melted, and degassed, following which the resulting bubble-free melt is forwarded into die head 142, and extruded through an annular die, resulting in tubing 144 which is 10 to 30 mils thick, more preferably 15 to 25 mils thick.
  • After cooling or quenching by water spray from cooling ring 146, tubing 144 is collapsed by pinch rolls 148, and is thereafter fed through irradiation vault 150 surrounded by shielding 152, where tubing 144 is irradiated with high energy electrons (i.e., ionizing radiation) from iron core transformer accelerator 154. Tubing 144 is guided through irradiation vault 150 on rolls 156. Preferably, tubing 144 is irradiated to a level of about 4.5 MR.
  • After irradiation, irradiated tubing 158 is directed through nip rolls 160, following which tubing 158 is slightly inflated, resulting in trapped bubble 162. However, at trapped bubble 162, the tubing is not significantly drawn longitudinally, as the surface speed of nip rolls 164 are about the same speed as nip rolls 160. Furthermore, irradiated tubing 158 is inflated only enough to provide a substantially circular tubing without significant transverse orientation, i.e., without stretching.
  • Slightly inflated, irradiated tubing 158 is passed through vacuum chamber 166, and thereafter forwarded through coating die 168. Second tubular film 170 is melt extruded from coating die 168 and coated onto slightly inflated, irradiated tube 158, to form two-ply tubular film 172. Second tubular film 170 preferably comprises an O2-barrier layer, which does not pass through the ionizing radiation. Further details of the above-described coating step are generally as set forth in U.S. Pat. No. 4,278,738, to Brax et al., which is hereby incorporated by reference thereto, in its entirety.
  • After irradiation and coating, two-ply tubing film 172 is wound up onto windup roll 174. Thereafter, windup roll 174 is removed and installed as unwind roll 176, on a second stage in the process of making the tubing film as ultimately desired. Two-ply tubular film 172, from unwind roll 176, is unwound and passed over guide roll 178, after which two-ply tubular film 172 passes into hot water bath tank 180 containing hot water 182. The now collapsed, irradiated, coated tubular film 172 is submersed in hot water 182 (having a temperature of about 210° F.) for a retention time of at least about 5 seconds, i.e., for a time period in order to bring the film up to the desired temperature for biaxial orientation. Thereafter, irradiated tubular film 172 is directed through nip rolls 184, and bubble 186 is blown, thereby transversely stretching tubular film 172. Furthermore, while being blown, i.e., transversely stretched, nip rolls 188 draw tubular film 172 in the longitudinal direction, as nip rolls 188 have a surface speed higher than the surface speed of nip rolls 184. As a result of the transverse stretching and longitudinal drawing, irradiated, coated biaxially-oriented blown tubing film 190 is produced, this blown tubing preferably having been both stretched in a ratio of from about 1:1.5-1:6, and drawn in a ratio of from about 1:1.5-1:6. More preferably, the stretching and drawing are each performed a ratio of from about 1:2-1:4. The result is a biaxial orientation of from about 1:2.25-1:36, more preferably, 1:4-1:16. While bubble 186 is maintained between pinch rolls 184 and 188, blown tubing film 190 is collapsed by rolls 192, and thereafter conveyed through nip rolls 188 and across guide roll 194, and then rolled onto wind-up roll 196. Idler roll 198 assures a good wind-up.
  • The polymer components used to fabricate multilayer films for use in making the bags of the present invention may also contain appropriate amounts of other additives normally included in such compositions. These include antiblocking agents (such as talc), slip agents (such as fatty acid amides), fillers, pigments and dyes, radiation stabilizers (including antioxidants), fluorescence additives (including a material which fluoresces under ultraviolet radiation), antistatic agents, elastomers, viscosity-modifying substances (such as fluoropolymer processing aids) and the like additives known to those of skill in the art of packaging films.
  • The multilayer films used to make the bags of the present invention are preferably irradiated to induce crosslinking, as well as corona treated to roughen the surface of the films which are to be adhered to one another. In the irradiation process, the film is subjected to an energetic radiation treatment, such as corona discharge, plasma, flame, ultraviolet, X-ray, gamma ray, beta ray, and high energy electron treatment, which induce cross-linking between molecules of the irradiated material. The irradiation of polymeric films is disclosed in U.S. Pat. No. 4,064,296, to BORNSTEIN, et al., which is hereby incorporated in its entirety, by reference thereto. BORNSTEIN, et al. discloses the use of ionizing radiation for crosslinking the polymer present in the film.
  • Radiation dosages are referred to herein in terms of the radiation unit “RAD”, with one million RADS, also known as a megarad, being designated as “MR”, or, in terms of the radiation unit kiloGray (kGy), with 10 kiloGray representing 1 MR, as is known to those of skill in the art. A suitable radiation dosage of high energy electrons is in the range of up to about 16 to 166 kGy, more preferably about 40 to 90 kGy, and still more preferably, 55 to 75 kGy. Preferably, irradiation is carried out by an electron accelerator and the dosage level is determined by standard dosimetry processes. Other accelerators such as a van der Graaf or resonating transformer may be used. The radiation is not limited to electrons from an accelerator since any ionizing radiation may be used.
  • As used herein, the phrases “corona treatment” and “corona discharge treatment” refer to subjecting the surfaces of thermoplastic materials, such as polyolefins, to corona discharge, i.e., the ionization of a gas such as air in close proximity to a film surface, the ionization initiated by a high voltage passed through a nearby electrode, and causing oxidation and other changes to the film surface, such as surface roughness.
  • Corona treatment of polymeric materials is disclosed in U.S. Pat. No. 4,120,716, to BONET, issued Oct. 17, 1978, herein incorporated in its entirety by reference thereto, discloses improved adherence characteristics of the surface of polyethylene by corona treatment, to oxidize the polyethylene surface. U.S. Pat. No. 4,879,430, to HOFFMAN, also hereby incorporated in its entirety by reference thereto, discloses the use of corona discharge for the treatment of plastic webs for use in meat cook-in packaging, with the corona treatment of the inside surface of the web to increase the adhesion of the meat to the adhesion of the meat to the proteinaceous material. Although corona treatment is a preferred treatment of the multilayer films used to make the pre-padded bag of the present invention, plasma treatment of the film may also be used.
  • A multilayer film is preferably converted to the bags of the present invention by heat sealing both across the film (i.e., a transverse heat seal) as well as heat sealing in the machine direction along the length of the film (i.e., a machine direction seal). The transverse seal is preferably made using a heat sealing method known as “impulse sealing”, which is carried out by placing a seal bar across the film and thereafter momentarily passing current through a heat seal wire on the seal bar. The seal wire heats up, transferring heat through a first side of the film tubing (or folded film) to the other side, causing the film to be sealed to itself. This sealing method is well known to those of skill in the art.
  • The lengthwise heat sealing (i.e., machine direction heat sealing) can be carried out using a seal bar and impulse sealing, i.e., in the same manner that the transverse seals are made. However, impulse heat sealing is generally carried out by forwarding the film intermittently in a direction along the length of the film tubing or sheet. If continuous forwarding of the film is desired during lengthwise heat sealing, a continuous band sealer can be used. Such continuous band heat sealers are described in U.S. Pat. No. 5,858,153, to Mack, entitled “Method for Making Tubular Containers”, as well as U.S. Pat. No. 6,344,258 B1, to Rasmussen, entitled “Heat-Sealing Polymer Films”, and U.S. Pat. No. 5,034,088, to Denker, entitled “Band Wheel and Tension Control”, each of which is hereby incorporated, in its entirety, by reference thereto. Continuous band sealers are available from, for example, Lamination Plus, 1142 West Flint Meadow Drive, P.O. Box 121, Kaysville, Utah, 84037, and Pierce Packaging Equipment, Inc., 217 South Claremont Street, San Mateo, Calif., 94401
  • It is also within the scope of the present invention to produce sets of pre-padded side-seal bags. FIG. 10 depicts a continuous chain of sets 200 of pre-padded side-seal bags. Each bag set 200 comprises a first side-seal bag 202 containing an absorbent pad 206 and a second side-seal bag 204 containing an absorbent pad 208. The chain of bag sets 200 in the illustrated embodiment is constructed from a center-folded film or from a seamless lay-flat tubing that is slit along one longitudinal edge to open the tubing for insertion of the absorbent pads. A folded edge 210 of the center-folded film or slit tubing forms a bottom end of each bag. First bag 202 of each set has a first side seal formed by a first transverse seal 212 extending across the width of the film, and a second side seal formed by a second transverse seal 214 extending across the width of the film. Second bag 204 of each set has a first side seal formed by a third transverse seal 216 extending across the width of the film, and a second side seal formed by a fourth transverse seal 218 extending across the width of the film. The third transverse seal 216 can be spaced longitudinally (i.e., along the lengthwise or machine direction of the film) a short distance from the second transverse seal 214. Additionally, the first transverse seal 212 of a subsequent bag set 200 can be longitudinally spaced a short distance from the fourth transverse seal 218 of a preceding bag set 200. Transverse lines of weakness 220 advantageously are formed in the film between the fourth transverse seal 218 of each bag set and the first transverse seal 212 of the subsequent contiguous bag set to facilitate separating the bag sets from one another. It is also possible to include a transverse line of weakness between the two bags 202, 204 of each bag set, if desired, to facilitate separating the chain into single bags.
  • A chain of pre-padded side-seal bag sets alternatively can be formed from separate first and second films by disposing absorbent pads on the first film (and preferably adhering the pads to the film) and bringing the second film into overlying relation with the first film, longitudinally sealing one longitudinal edge of the first film to the corresponding longitudinal edge of the second film so as to form end seals for the bags, and then forming transverse seals (and optionally the lines of weakness) across the two films generally as described above in connection with FIG. 10 so as to form side seals for the bags.
  • Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the inventions are not to be limited to the specific and/or preferred embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

Claims (29)

1. A set of pre-padded bags made from a film having a machine direction and a transverse direction, the set of bags comprising a first bag and a second bag, each bag comprising a first film portion and an underlying second film portion, the first and second film portions being sealed together with a transversely extending seal to form an end seal of each bag, the first and second film portions being sealed together with a longitudinal seal along the machine direction to form a side seal of each bag, the first bag being connected to the second bag in an area between the side seals of the bags, and each bag containing a fluid-absorbent pad.
2. The set of pre-padded bags according to claim 1, wherein the first bag has an outer longitudinal side edge and the second bag has an outer longitudinal side edge, and wherein at least one of the outer longitudinal side edges comprises a folded edge.
3. The set of pre-padded bags according to claim 1, wherein the fluid-absorbent pads are adhered to the film.
4. The set of pre-padded bags according to claim 1, wherein the side seals and end seals comprise heat seals.
5. The set of pre-padded bags according to claim 1, wherein the area between the side seals of the bags comprises a line of weakness for facilitating separation of the first bag from the second bag.
6. The set of pre-padded bags according to claim 5, wherein the line of weakness comprises perforations.
7. The set of pre-padded bags according to claim 1, wherein the film at 185° F. has a total free shrink of at least 10 percent and a transverse free shrink greater than a longitudinal free shrink.
8. The set of pre-padded bags according to claim 1, further comprising a third bag and a fourth bag formed by the first and second film portions sealed together with a transversely extending seal to form an end seal of each bag, the first and second film portions being sealed together with a longitudinal seal along the machine direction to form a side seal of each of the third and fourth bags, the third bag being connected to the fourth bag in an area between the side seals of the bags and each bag containing a fluid-absorbent pad, and the third and fourth bags having end edges connected respectively to the end seals of the first and second bags.
9. The set of pre-padded bags according to claim 8, wherein the end edges of the third and fourth bags are connected to the first and second bags along a transverse line of weakness formed in the film.
10. A chain of pre-padded bags formed from a continuous web of film having a machine direction and a transverse direction, the chain of pre-padded bags comprising:
a plurality of bag sets serially connected along the machine direction, each bag set comprising a first bag and a second bag, each bag set comprising a first film portion and an underlying second film portion, the first and second film portions of each bag set being sealed together with a transversely extending seal to form an end seal of each bag, the first bag of each bag set having the first and second film portions sealed together with a first longitudinal seal along the machine direction to form a side seal of the first bag, the second bag of each bag set having the first and second film portions sealed together with a second longitudinal seal along the machine direction to form a side seal of the second bag, the first bag being connected to the second bag in an area between the first and second longitudinal seals, and each bag containing a fluid-absorbent pad, the end seals of each bag set being joined to a subsequent bag set.
11. The chain of pre-padded bags according to claim 10, wherein a bag of each bag set has an outer longitudinal side edge comprising a folded edge.
12. The chain of pre-padded bags according to claim 10, wherein the side seals and end seals comprise heat seals.
13. The chain of pre-padded bags according to claim 10, wherein the area between the side seals of the bags comprises a line of weakness for facilitating separation of the first bag from the second bag.
14. The chain of pre-padded bags according to claim 10, wherein the fluid-absorbent pads are adhered to the film.
15. The chain of pre-padded bags according to claim 10, wherein the film at 185° F. has a total free shrink of at least 10 percent and a transverse free shrink greater than a longitudinal free shrink.
16. The chain of pre-padded bags of claim 10, wherein each bag set is connected to a subsequent bag set along a transverse line of weakness formed in the film to facilitate separating the sets of bags.
17. A method of forming a chain of sets of pre-padded bags, comprising the steps of:
providing a continuous length of seamless lay-flat tubular film having opposite longitudinal edges;
longitudinally slitting at least one of the longitudinal edges of the lay-flat tubular film to open the film;
inserting into the opened lay-flat tubular film, at each of a plurality of longitudinally spaced locations along the continuous length of the film, a set of fluid-absorbent pads spaced apart from each other across the film;
forming a longitudinal seal along the continuous length of the lay-flat tubular film adjacent the or each slit longitudinal edge to form an outer side seal for at least one bag of each set;
forming a longitudinal seal along the continuous length of the lay-flat tubular film at least at one position intermediate the opposite longitudinal edges of the lay-flat tubular film so as to form interior side seals of the bags, whereby the bags of each set are connected along the respective interior side seals; and
forming longitudinally spaced, transverse seals across the film in between the sets of pads so as to form end seals for each bag set.
18. The method according to claim 17, further comprising the step of forming a longitudinal line of weakness in the lay-flat tubular film between the bags of each set to facilitate separating the bags of each set.
19. The method according to claim 17, further comprising the step of forming a transverse line of weakness in the film adjacent each transverse seal to facilitate separating the sets of bags from one another.
20. A method of forming a chain of sets of pre-padded bags, comprising the steps of:
providing a continuous length of film having opposite longitudinal edges;
disposing on the film, at each of a plurality of longitudinally spaced locations along the continuous length of the film, a pair of fluid-absorbent pads spaced apart from each other on opposite sides of a central area of the film;
folding the film to bring the opposite longitudinal edges inwardly toward the central area of the film and positioning the opposite longitudinal edges on opposite sides of the central area, such that a first portion of the film is in overlying relation with an underlying portion of the film to enclose the pads on one side of the central area and a second portion of the film is in overlying relation with another underlying portion of the film to enclose the pads on the other side of the central area;
sealing the longitudinal edges of the film to the underlying portions of the film so as to form interior side seals of the bags, whereby the central area connects the bags of each pair along the respective interior side seals; and
forming longitudinally spaced, transverse seals across the film in between the pairs of pads so as to form end seals for each pair of bags.
21. The method of claim 20, wherein the step of disposing the pads on the film includes adhering the pads to the film.
22. The method of claim 20, wherein the disposing step is performed prior to the folding step.
23. A method of forming a chain of sets of pre-padded bags, comprising the steps of:
providing continuous first and second films each having opposite longitudinal edges;
disposing on the first film, at each of a plurality of longitudinally spaced locations along the continuous length of the first film, a set of fluid-absorbent pads spaced apart from each other across a width of the first film;
positioning the second film in overlying relation with the first film;
sealing the first and second films together along the longitudinal edges of each film;
forming a longitudinal seal along the continuous lengths of the first and second films at least at one position intermediate the opposite longitudinal edges of the films so as to form interior side seals of the bags, whereby the bags of each set are connected along the respective interior side seals; and
forming longitudinally spaced, transverse seals across the first and second films in between the sets of pads so as to form end seals for each set of bags.
24. The method of claim 23, further comprising forming a transverse line of weakness in the films adjacent each of the transverse seals to facilitate separating the sets of bags from one another.
25. The method of claim 23, further comprising forming a longitudinal line of weakness in the films between the bags of each set to facilitate separating the bags of each set from one another.
26. A chain of pre-padded bags formed from a continuous web of film having a machine direction and a transverse direction and having a first film portion in overlying relation with a second film portion, the chain of pre-padded bags comprising:
a plurality of bags serially connected along the machine direction, each bag having a first side seal comprising a first transverse seal formed across the film sealing the first and second film portions together, and a second side seal comprising a second transverse seal formed across the film sealing the first and second film portions together, the second side seal of each bag being connected to the first side seal of a subsequent bag in the chain, each bag having a closed end along one longitudinal edge of the film and an opposite open end along an opposite longitudinal edge of the film, and each bag containing a fluid-absorbent pad.
27. The chain of pre-padded bags of claim 26, wherein the film comprises a center-folded film such that the closed end of each bag comprises a folded edge of the center-folded film.
28. The chain of pre-padded bags of claim 26, further comprising a line of weakness formed in the film between the second side seals of at least some of the bags and the first side seals of subsequent bags respectively connected to said second side seals to facilitate separating the bags from one another.
29. The chain of pre-padded bags of claim 26, wherein the film comprises a seamless lay-flat tubing.
US11/106,754 2005-04-15 2005-04-15 Sets of pre-padded bags and methods of making same Abandoned US20060233467A1 (en)

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US11/106,754 US20060233467A1 (en) 2005-04-15 2005-04-15 Sets of pre-padded bags and methods of making same
BRPI0601149-7A BRPI0601149A (en) 2005-04-15 2006-04-11 pre-padded bag sets and methods of doing the same
ARP060101445A AR053215A1 (en) 2005-04-15 2006-04-12 BAG GAMES PREVIOUSLY PROVIDED WITH STAMPS AND METHODS OF MANUFACTURING THEM
AU2006201552A AU2006201552A1 (en) 2005-04-15 2006-04-12 Sets of pre-padded bags and methods of making same

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US10793344B2 (en) * 2018-04-06 2020-10-06 Lincoln Global, Inc. Hermetically sealed pouch for elongated objects
USD963862S1 (en) 2021-07-06 2022-09-13 Dr. Howard S. Glazer Consulting Llc Strip of barrier envelopes

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