EP0629631A3 - Novel transition metal compound, and polymerization catalyst containing it. - Google Patents
Novel transition metal compound, and polymerization catalyst containing it. Download PDFInfo
- Publication number
- EP0629631A3 EP0629631A3 EP94304053A EP94304053A EP0629631A3 EP 0629631 A3 EP0629631 A3 EP 0629631A3 EP 94304053 A EP94304053 A EP 94304053A EP 94304053 A EP94304053 A EP 94304053A EP 0629631 A3 EP0629631 A3 EP 0629631A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- transition metal
- metal compound
- polymerization catalyst
- catalyst containing
- novel transition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02004078A EP1209165B1 (en) | 1993-06-07 | 1994-06-06 | Propylene elastomer |
Applications Claiming Priority (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13625593 | 1993-06-07 | ||
JP13625593 | 1993-06-07 | ||
JP136255/93 | 1993-06-07 | ||
JP15736793 | 1993-06-28 | ||
JP15736793 | 1993-06-28 | ||
JP157367/93 | 1993-06-28 | ||
JP23856293 | 1993-09-24 | ||
JP23856293 | 1993-09-24 | ||
JP238562/93 | 1993-09-24 | ||
JP250743/93 | 1993-10-06 | ||
JP25074393 | 1993-10-06 | ||
JP25074393 | 1993-10-06 | ||
JP29207193 | 1993-11-22 | ||
JP292071/93 | 1993-11-22 | ||
JP29207193A JP3401306B2 (en) | 1993-11-22 | 1993-11-22 | Propylene polymer |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02004078A Division EP1209165B1 (en) | 1993-06-07 | 1994-06-06 | Propylene elastomer |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0629631A2 EP0629631A2 (en) | 1994-12-21 |
EP0629631A3 true EP0629631A3 (en) | 1995-03-01 |
EP0629631B1 EP0629631B1 (en) | 2002-08-28 |
Family
ID=27527451
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02004078A Revoked EP1209165B1 (en) | 1993-06-07 | 1994-06-06 | Propylene elastomer |
EP94304053A Expired - Lifetime EP0629631B1 (en) | 1993-06-07 | 1994-06-06 | Novel transition metal compound, and polymerization catalyst containing it |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02004078A Revoked EP1209165B1 (en) | 1993-06-07 | 1994-06-06 | Propylene elastomer |
Country Status (6)
Country | Link |
---|---|
US (4) | US5504172A (en) |
EP (2) | EP1209165B1 (en) |
KR (1) | KR100293971B1 (en) |
CN (2) | CN1049896C (en) |
CA (1) | CA2125246C (en) |
DE (2) | DE69431222T2 (en) |
Families Citing this family (366)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5466766A (en) * | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
EP0638593A1 (en) * | 1993-08-02 | 1995-02-15 | Shell Internationale Researchmaatschappij B.V. | Catalyst compositions |
CN1052734C (en) * | 1993-11-29 | 2000-05-24 | 三井化学株式会社 | Propylene elastomer |
DE69518094T2 (en) * | 1994-04-11 | 2001-03-22 | Mitsui Chemicals Inc | Process for the preparation of a propylene polymer composition and propylene polymer composition |
TW383313B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers |
IT1272923B (en) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | METALLOCENIC COMPOUNDS, PROCEDURE FOR THEIR PREPARATION, AND THEIR USE IN CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
DE19506286A1 (en) * | 1995-02-23 | 1996-08-29 | Basf Ag | Statistical copolymers of propylene for foams |
CN1076282C (en) * | 1995-03-02 | 2001-12-19 | 三井化学株式会社 | Polypropylene composite film |
AT403376B (en) * | 1995-07-03 | 1998-01-26 | Danubia Petrochem Polymere | METALLOCENES WITH SILYL-SUBSTITUTED BRIDGES AND THEIR USE FOR OLEFIN POLYMERIZATION |
DE69620760T2 (en) * | 1995-07-06 | 2002-12-05 | Exxonmobil Chem Patents Inc | METHOD FOR PRODUCING POLYMERIZED SUPPORTED METALLOCENE CATALYST SYSTEMS |
TW401445B (en) * | 1995-07-13 | 2000-08-11 | Mitsui Petrochemical Ind | Polyamide resin composition |
DE19527047A1 (en) * | 1995-07-25 | 1997-01-30 | Danubia Petrochem Deutschland | Metallocene catalysts esp. used for prepn. of high mol. mass polypropylene@ - comprise silyl substd., di:yl bridged cpds., and at least one cyclopentadienyl gp. capable of forming sandwich structure |
US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
DE19544828A1 (en) * | 1995-12-01 | 1997-06-05 | Hoechst Ag | High molecular copolymers |
DE19606167A1 (en) * | 1996-02-20 | 1997-08-21 | Basf Ag | Supported catalyst systems |
DE19606165A1 (en) * | 1996-02-20 | 1997-08-21 | Basf Ag | Process for the preparation of polymers of alkenes by gas phase polymerization |
DE19608814A1 (en) * | 1996-03-07 | 1997-10-02 | Hoechst Ag | Process for the production of indene |
US5897941A (en) * | 1996-04-12 | 1999-04-27 | Cryovac, Inc. | High modulus film |
JP3181920B2 (en) * | 1996-04-22 | 2001-07-03 | 日本ポリオレフィン株式会社 | Catalyst for producing polyolefin and method for producing polyolefin |
IT1283630B1 (en) * | 1996-05-09 | 1998-04-23 | Enichem Spa | PROCESS FOR THE PREPARATION OF EP (D) M ELASTOMERIC COPOLYMERS |
US7919561B2 (en) * | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
EP0856506A1 (en) * | 1997-02-04 | 1998-08-05 | Akzo Nobel N.V. | Process of preparing 2-alkyl-2,3-dihydro-1H-benz(e)indene-1-one derivatives |
US6525157B2 (en) * | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
US6635715B1 (en) * | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
US7026404B2 (en) * | 1997-08-12 | 2006-04-11 | Exxonmobil Chemical Patents Inc. | Articles made from blends made from propylene ethylene polymers |
US6921794B2 (en) * | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
TW482770B (en) * | 1997-08-15 | 2002-04-11 | Chisso Corp | Propylene/ethylene random copolymer, molding material, and molded article |
US6319998B1 (en) | 1998-03-04 | 2001-11-20 | Exxon Mobil Chemical Patents Inc. | Method for making polymer blends by using series reactors |
JP4275857B2 (en) | 1998-03-04 | 2009-06-10 | エクソンモービル・ケミカル・パテンツ・インク | Method for enhancing diene conversion in EPDM type polymerization |
JP4418107B2 (en) | 1998-03-04 | 2010-02-17 | エクソンモービル・ケミカル・パテンツ・インク | Products and methods for producing polyolefin polymer dispersions |
WO2000001766A1 (en) * | 1998-07-01 | 2000-01-13 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
WO2000001745A1 (en) * | 1998-07-02 | 2000-01-13 | Exxon Chemical Patents Inc. | Propylene olefin copolymers |
GB9816940D0 (en) | 1998-08-05 | 1998-09-30 | Bp Chem Int Ltd | Polymerisation catalysts |
BR0012197A (en) | 1999-06-24 | 2002-03-12 | Dow Chemical Co | Polyolefin composition with improved impact properties and article made of it |
US6194527B1 (en) * | 1999-09-22 | 2001-02-27 | Equistar Chemicals, L.P. | Process for making polyolefins |
US7250211B1 (en) * | 1999-10-26 | 2007-07-31 | Idemitsu Kosan Co., Ltd. | Polypropylene films and multilayered laminate |
IT1314261B1 (en) * | 1999-12-03 | 2002-12-06 | Enichem Spa | METALLOCENIC COMPOUNDS BRIDGE, PROCESS FOR THEIR PREPARATION AND THEIR USE AS CATALYSTS FOR THE POLYMERIZATION OF OLEFINS. |
US6919036B2 (en) | 2000-01-21 | 2005-07-19 | U.S. Borax Inc. | Nonaborate compositions and their preparation |
DE60102917T2 (en) | 2000-01-24 | 2005-04-07 | Dow Global Technologies, Inc., Midland | COMPOSITION AND FOILS FROM THIS |
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- 1994-06-06 DE DE69434709T patent/DE69434709T2/en not_active Expired - Lifetime
- 1994-06-06 CA CA002125246A patent/CA2125246C/en not_active Expired - Lifetime
- 1994-06-06 EP EP94304053A patent/EP0629631B1/en not_active Expired - Lifetime
- 1994-06-07 US US08/255,713 patent/US5504172A/en not_active Expired - Lifetime
- 1994-06-07 CN CN94107136A patent/CN1049896C/en not_active Expired - Lifetime
- 1994-06-07 KR KR1019940012756A patent/KR100293971B1/en not_active IP Right Cessation
- 1994-06-07 CN CNB99105007XA patent/CN1169847C/en not_active Expired - Lifetime
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1995
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1996
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1997
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Also Published As
Publication number | Publication date |
---|---|
DE69431222D1 (en) | 2002-10-02 |
EP1209165A2 (en) | 2002-05-29 |
US5739366A (en) | 1998-04-14 |
DE69434709D1 (en) | 2006-05-24 |
CN1169847C (en) | 2004-10-06 |
DE69431222T2 (en) | 2003-04-17 |
EP0629631A2 (en) | 1994-12-21 |
US5504172A (en) | 1996-04-02 |
CN1103067A (en) | 1995-05-31 |
CA2125246C (en) | 2001-07-03 |
EP1209165B1 (en) | 2006-04-19 |
US5767033A (en) | 1998-06-16 |
CN1233619A (en) | 1999-11-03 |
KR950000715A (en) | 1995-01-03 |
CN1049896C (en) | 2000-03-01 |
US5959046A (en) | 1999-09-28 |
KR100293971B1 (en) | 2001-09-17 |
EP1209165A3 (en) | 2004-08-04 |
CA2125246A1 (en) | 1994-12-08 |
DE69434709T2 (en) | 2006-10-19 |
EP0629631B1 (en) | 2002-08-28 |
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