EP0431458A1 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- EP0431458A1 EP0431458A1 EP90122748A EP90122748A EP0431458A1 EP 0431458 A1 EP0431458 A1 EP 0431458A1 EP 90122748 A EP90122748 A EP 90122748A EP 90122748 A EP90122748 A EP 90122748A EP 0431458 A1 EP0431458 A1 EP 0431458A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning composition
- cleaning
- composition according
- hcf2
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02803—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/264—Aldehydes; Ketones; Acetals or ketals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/28—Organic compounds containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
Abstract
Description
- The present invention relates to a cleaning composition and more particularly to a cleaning composition which is suitable for removal of fluxes, fats and oils, dust, etc. deposited on IC components, components of precision instruments or the like.
- In the manufacture of IC components, components of precision instruments, etc., cleaning has been heretofore conducted usually using an organic solvent to remove the fluxes, dust and the like which deposited on components during assembling. For such cleaning, 1,1,2-trichloro-1,2,2-trifluoroethane (R-113) has been widely used as the organic solvent. R-113 is nonflammable, low in toxicity and excellent in stability. Further, R-113, which has a proper solvency, can selectively dissolve only dirts and is unlikely to corrode metals, plastics, elastomers and the like. Printed boards to be cleaned for removal of fluxes are mostly composite products composed of metals, plastics, elastomers and the like. Also from this viewpoint, R-113 is beneficial.
- However, use of R-113 is being restricted because R-113 would be likely to destroy the ozone layer in the stratosphere and may become the cause of cutaneous cancer.
- It is an object of the present invention to provide a cleaning composition which is utterly unlikely to destroy the ozone layer and which is capable of accomplishing effective cleaning for removal of fluxes, oils and the like.
- It is another object of the invention to provide a cleaning composition which has such a suitable solvency that it can selectively dissolve only dirts and it will not corrode metals, plastics, elastomers, etc.
- We conducted extensive research to achieve the foregoing objects, and found the following. Specific aliphatic fluorohydrocarbons are (1) entirely free from the possibility of destroying the ozone layer because of the absence of chlorine in the molecule; (2) outstanding in the ability to remove fluxes, fats and oils, dust, etc.; and (3) capable of selectively dissolving only dirts without corroding composite products composed of metals, plastics, elastomers, etc. because of their proper solvency like that of R-113 heretofore used. The present invention has been accomplished based on these novel findings.
- According to the present invention, there is provided a cleaning composition containing as an active component an aliphatic fluorohydrocarbon represented by the formula
CnFmH2n+2-m
wherein 4≦n≦6 and 6≦m≦12.
The cleaning composition according to the invention contains as an active component an aliphatic fluorohydrocarbon represented by the formula
CnFmH2n+2-m
wherein 4≦n≦6 and 6≦m≦12. Such compound has never been used as a cleaning agent for removing fluxes, fats and oils, etc. - Examples of aliphatic fluorohydrocarbons present in the cleaning composition of the invention are compounds represented by the formulas C₄F₆H₄, C₄F₈H₂, C₅F₇H₅, C₅F₈H₄, C₅F₉H₃, C₅F₁₀H₂, C₆F₉H₅ and C₆F₁₂H₂, respectively. Preferred examples of aliphatic fluorohydrocarbons are 1, 1,2,3,4,4-
hexafluorobutane (HCF₂CFHCFHCF₂H), 1,1,1,2,2,3,3,4-
octafluorobutane (CF₃CF₂CF₂CH₂F), 1,1,2,2,3,3,4-
heptafluoropentane (HCF₂(CF₂)₂CFHCH₃, 1,1,2,3,3,4,5,5-
octafluoropentane (HCF₂CFHCf₂CFHCF₂H), 1,1,2,2,3,3,4,4,5,-
nonafluoropentane (HCF₂(CF₂)₃CH₂F), 1,1,1,2,3,3,4,4,5,5,-
decafluoropentane (CF₃CF(CHF₂)CF₂CF₂H), 1,1,1,2,2,3,3,4,4,-
nonafluorohexane (CF₃(CF₂)₃CH₂CH₃), 1,1,2,2,3,3,4,4,5,5,6,6-
dodecafluorohexane (HCF₂(CF₂)₄CF₂H), 2-trifluoromethyl-
1,1,1,3,4,4,5,5,5-nonafluoropentane ((CF₃)₂CHCFHCF₂CF₃), etc. The above-exemplified alipahtic fluorohydrocarbons can be used singly or at least two of them are usable in mixture. The amount of the aliphatic fluorohydrocarbon to be contained in the cleaning composition of the invention is not specifically limited, usually about 7O% by weight or more, preferably about 8O% by weight or more. - The composition of the invention may contain at least one organic solvent selected from the group consisting of hydrocarbons, alcohols, esters and ketones in order to increase the solvency for dissolving fluxes. The amount of the organic solvent used is not specifically limited, usually about 30% by weight or less, preferably about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, based on the whole amount of the cleaning composition of the invention. If the mixture of the aliphatic fluorohydrocarbon and the organic solvent can be an azeotropic composition, it is preferred to use the mixture as the azeotropic composition.
- Useful hydrocarbons are not specifically limited. Preferred hydrocarbons are hexane, heptane, isoheptane, octane, isooctane, methylcyclopentane, cyclohexane, methylcyclohexane, toluene, etc.
- Useful alcohols are not specifically limited. Preferred alcohols are chain saturated alcohols having about 1 to about 5 carbon atoms, such as methanol, ethanol, n-propanol, isopropanol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, pentyl alcohol, sec-amyl alcohol, 1-ethyl-1-propanol, 2-methyl-1-butanol, isopentyl alcohol, tert-pentyl alcohol, 3-methyl-2-butanol, neopentyl alcohol, 2-ethyl-1-butanol, etc. Among them, methanol, ethanol, isopropanol, n-propanol, etc. are desirable.
- Useful esters are not specifically limited. Preferred esters are esters of fatty acids having about 1 to about 5 carbon atoms with lower alcohols having about 1 to about 6 carbon atoms, such as methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, methyl propionate, ethyl propionate, propyl propionate, isopropyl propionate, methyl butyrate, ethyl butyrate, methyl valerate, etc. Among them, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, etc. are preferred.
- Useful ketones are not specifically limited. Preferred ketones are those represented by the formula R-CO-R' wherein R and R' each represent a saturated hydrocarbon group having about 1 to about 4 carbon atoms. Examples of such ketones are acetone, 2-butanone, 2-pentanone, 3-pentanone, 4-methyl-2-pentanone, etc. Among them, acetone, 2-butanone, 4-methyl-2-pentanone, etc. are preferred.
- The composition of the invention may further contain ingredients heretofore used for this kind of cleaning compositions according to a particular application. Useful ingredients are surfactants and like auxiliary agents for cleaning compositions, stabilizers, hydrogen-containing chlorofluorohydrocarbons which would be less likely to destroy the ozone layer, hydrogen-containing fluorohydrocarbons and other hydrocarbons which are entirely free from the possibility of destroying the ozone layer, and so on. In removal of fluxes, fats and oils, dust, etc. using the cleaning composition of the invention, a conventional cleaning method can be employed. Such cleaning methods include, for example, manually wiping methods, immersion methods, spraying methods, oscillating methods, ultrasonic cleaning methods, steam cleaning methods, etc.
- The cleaning composition of the invention is not prone at all to destroy the ozone layer and is capable of accomplishing effective cleaning for removal of fluxes. Having a proper solvency like that of R-113 heretofore used, the cleaning composition of the invention can selectively dissolve and remove only dirts (including fluxes, fats and oils, dust, etc.) without corroding composite products composed of metals, plastics, elastomers, etc.
- The present invention will be described below in more detail with reference to the following examples.
- A test for ability to remove fluxes was carried out using the cleaning compositions Nos. 1 to 27 of the present invention listed below in Table 1 and containing as an active component 1,1,2,2,3,3,4-heptafluoropentane (7F pentane), 1,1,2,3,3,4,5,5-octafluoropentane (8F pentane) or 2-trifluoromethyl-1,1,3,4,4,5,5,5-nonafluoropentane (6FDH2).
- A flux (trade name: Tamura F-Al-4, product of Tamura Seisakusho) was applied on the entire surface of a printed board (copper clad laminate). The coated board was preheated at 110°C for 20 seconds and soldering was conducted at 250°C for 5 seconds. After the soldering, the printed board was immersed in the cleaning composition of the invention, followed by one minute of ultrasonic cleaning. The degree of the removal of the flux was evaluated according to the following criteria. Table 1 shows the results.
- A:
- Flux was removed satisfactorily
- B:
- A slight quantity of flux remained unremoved
- C:
- A considerable quantity of flux remained unremoved
- In order to check the influence on the plastics materials exerted by the cleaning compositions Nos. 1 to 18 used in Example 1, various plastics materials listed below in Table 2 were immersed in each composition at 50°C for 1 hour. On withdrawal, the variation (expressed in percentage) of the weight of each plastics material was measured and the degree of the influence was evaluated according to the following criteria. Table 2 shows the results.
- 0:
- Little or no influence was found (Variation of the weight: 0 to 1%)
- 1
- : The plastics material was slightly swelled, but substantially no problem was caused (Variation of the weight: 1 to 5%)
- 2:
- The plastics material was swelled and eroded (Variation of weight: 5 to 10%)
- The results shown in Tables 1 and 2 reveal that the composition of the present invention is excellent in ability to effectively remove fluxes and does not erode the plastics materials.
- A flux (trade name: F-AL-4, product of Tamura Seisakusho) was applied on a printed board (10 cm x 10 cm) and the coated board was preheated at 110°C. Soldering was conducted at 250°C for 5 seconds. A test for ability to remove fluxes was conducted using the cleaning compositions of the invention as listed below in Table 3 by subjecting the printed board treated above to ultrasonic cleaning for 60 seconds and to vapor cleaning for 60 seconds.
- After the cleaning, the degree of removal of the flux was evaluated by observing the printed board with the unaided eye and according to the following criteria. On the other hand, the amount of ionic residue was measured using an Omega meter 500 (trade name of a product of KENKO) and utilized for evaluation according to the following criterion. Table 3 shows the results.
- Criteria for evaluation of the degree of removal of flux with the unaided eye:
- A:
- The flux was removed satisfactorily
- B:
- A slight degree of flux remained unremoved
- C:
- A considerable degree of flux remained unremoved
-
- A 100 mesh-cylindrical wire net (25ø x 15H mm) on which spindle oil was deposited was immersed in the cleaning composition of the invention heated to 60°C, followed by 60 seconds of ultrasonic cleaning. The wire net was further immersed in a solvent heated to 40 to 60°C and subjected to shaking with hands or to ultrasonic cleaning for 60 seconds. Thereafter, vapor cleaning was conducted for 60 seconds, whereby the cleaning composition was tested for degreasing ability. After the test, the quantity of oil remaining on the wire net was measured by an oil content meter (product of Horiba, Ltd.) and the degree of removal of oils was expressed in cleaning degree (%).
-
- As described above, the cleaning compositions of the present invention are excellent in degreasing ability.
Claims (6)
- A cleaning composition containing as an active component an aliphatic fluorohydrocarbon represented by the formula
CnFmH2n+2-m
wherein 4≦n≦6 and 6≦m≦12. - A cleaning composition according to claim 1 wherein the aliphatic fluorohydrocarbon is at least one compound selected from the group consisting of compounds represented by the formulas C₄F₆H₄, C₄F₈H₂, C₅F₇H₅, C₅F₈H₄, C₅F₉H₃, C₅F₁₀H₂, C₆F₉H₅ and C₆F₁₂H₂, respectively.
- A cleaning composition according to claim 1 wherein the aliphatic fluorohydrocarbon is at least one compound selected from the group consisting of 1,1,2,3,4,4-hexafluorobutane (HCF₂CFHCFHCF₂H), 1,1,1,2,2,3,3,4-octafluorobutane (CF₃CF₂CF₂CH₂F), 1, 1, 2,2,3,3,4-heptafluoropentane (HCF₂(CF₂)₂CFHCH₃, 1,1,2,3,3,4,5,5--octafluoropentane (HCF₂CFHCF₂CFHCF₂H), 1,1,2,2,3,3,4,4,5,-nonafluoropentane (HCF₂(CF₂)₃CH₂F), 1,1,1,2,3,3,4,4,5,5,-decafluoropentane (CF₃CF(CHF₂)CF₂CF₂H), 1,1,1,2,2,3,3,4,4,-nonafluorohexane (CF₃(CF₂)₃CH₂CH₃), 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorohexane (HCF₂(CF₂)₄CF₂H), and 2-trifluoromethyl-1,1,1,,3,4,4,5,5,5-nonafluoropentane ((CF₃)₂CHCFHCF₂CF₃).
- A cleaning composition according to claim 1 which contains at least one organic solvent selected from hydrocarbons, alcohols, esters and ketones.
- A cleaning composition according to claim 1 which contains at least 70% by weight of the aliphatic fluorohydrocarbon.
- A cleaning composition according to claim 4 which contains about 30% by weight or less of the organic solvent.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31864389 | 1989-12-07 | ||
JP31864489 | 1989-12-07 | ||
JP318643/89 | 1989-12-07 | ||
JP31864289 | 1989-12-07 | ||
JP318644/89 | 1989-12-07 | ||
JP318642/89 | 1989-12-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0431458A1 true EP0431458A1 (en) | 1991-06-12 |
Family
ID=27339673
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90122748A Withdrawn EP0431458A1 (en) | 1989-12-07 | 1990-11-28 | Cleaning composition |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0431458A1 (en) |
JP (1) | JP2850533B2 (en) |
KR (1) | KR910012220A (en) |
AU (1) | AU635362B2 (en) |
BR (1) | BR9006196A (en) |
CA (1) | CA2031421A1 (en) |
CS (1) | CS611190A2 (en) |
PL (1) | PL288145A1 (en) |
RU (1) | RU2010847C1 (en) |
Cited By (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5100572A (en) * | 1990-10-03 | 1992-03-31 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of polyfluoropentanes and methanol |
WO1992019706A2 (en) * | 1991-05-06 | 1992-11-12 | E.I. Du Pont De Nemours And Company | 1,1,1,2,2,3,3,4,4,5,6-undecafluorohexane and use thereof in compositions and processes for cleaning |
EP0516029A1 (en) * | 1991-05-28 | 1992-12-02 | Daikin Industries, Limited | A method of desiccating articles |
EP0519432A2 (en) * | 1991-06-21 | 1992-12-23 | Hoechst Aktiengesellschaft | Azeotrope-like mixture of 2-propanol and 1H-perfluorohexane |
EP0519431A2 (en) * | 1991-06-21 | 1992-12-23 | Hoechst Aktiengesellschaft | Azeotrope-like mixture of methanol and 1H-perfluorohexane |
US5194170A (en) * | 1992-04-02 | 1993-03-16 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1,2,2,3,3,4,4-octafluorobutane and either tran-1,2-dichloroethylene, cis 1,2-dichloroethylene, or 1-1 dichloroethane |
WO1993005002A2 (en) * | 1991-08-28 | 1993-03-18 | E.I. Du Pont De Nemours And Company | Gem-dihydropolyfluoroalkanes and monohydropolyfluoroalkenes, processes for their production, and use of gem-dihydropolyfluoroalkanes in cleaning compositions |
US5196137A (en) * | 1991-10-01 | 1993-03-23 | E. I. Du Pont De Nemours And Company | Azeotropic composition of 1,1,1,2,3,4,4,5,5,5-decafluoropentane and trans-1,2-dichloroethylene, cis-1,2-dichloroethylene or 1,1-dichlorethane |
WO1993008240A1 (en) * | 1991-10-18 | 1993-04-29 | E.I. Du Pont De Nemours And Company | Azeotropic compositions of 1,1,2,2,3,3,4,4-octafluorobutane and alcohols or ketones |
WO1993010203A1 (en) * | 1991-11-19 | 1993-05-27 | Daikin Industries, Ltd. | Refrigerant comprising octafluorobutane |
WO1993011280A1 (en) * | 1991-12-02 | 1993-06-10 | Allied-Signal, Inc. | Multiple solvent cleaning system |
US5219489A (en) * | 1991-08-15 | 1993-06-15 | Allied-Signal Inc. | Azeotrope-like compositions of 2-trifluoromethyl-1,1,1,2-tetrafluorobutane and methanol |
US5219488A (en) * | 1992-03-16 | 1993-06-15 | Allied-Signal Inc. | Azeotrope-like compositions of 2-trifluoromethyl-1,1,1,2-tetrafluorobutane and ethanol or isopropanol |
US5219490A (en) * | 1992-04-27 | 1993-06-15 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1,2,3,3-pentafluoropropane |
US5221361A (en) * | 1990-08-17 | 1993-06-22 | E. I. Du Pont De Nemours And Company | Compositions of 1,1,1,2,2,5,5,5,-octafluoro-4-trifluoromethylpentane and use thereof for cleaning solid surfaces |
US5225099A (en) * | 1992-03-16 | 1993-07-06 | Allied-Signal Inc. | Azeotrope-like compositions of 4-trifluoromethyl-1,1,1,2,2,3,3,5,5,5-decafluoropentane |
EP0552225A1 (en) * | 1990-10-11 | 1993-07-28 | Du Pont | Binary azeotropic compositions of (cf 3?chfchfcf 2?cf 3?) with methanol or ethanol or isopropanol. |
EP0552286A1 (en) * | 1990-10-11 | 1993-07-28 | Du Pont | Ternary azeotropic compositions of 43-10mee (cf 3?chfchfcf 2?cf 3?) and trans 1,2-dichloroethylene with methanol or ethanol. |
US5250208A (en) * | 1992-04-02 | 1993-10-05 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions |
US5259983A (en) * | 1992-04-27 | 1993-11-09 | Allied Signal Inc. | Azeotrope-like compositions of 1-H-perfluorohexane and trifluoroethanol or n-propanol |
US5268120A (en) * | 1991-05-02 | 1993-12-07 | Elf Atochem, S.A. | Composition based on 1,1-dichloro-1-fluoroethane, 1,1,1,3,3-pentafluorobutane and methanol, for cleaning and/or drying solid surfaces |
US5268121A (en) * | 1991-05-02 | 1993-12-07 | Elf Atochem, S.A. | Compositions based on 1,1,1,3,3-pentafluorobutane and methanol for the cleaning and/or drying of solid surfaces |
US5288422A (en) * | 1993-03-15 | 1994-02-22 | Alliedsignal Inc. | Azeotrope-like compositions of 1,1,1,3,3,5,5,5-octafluoropentane, chlorinated ethylenes, and optionally nitromethane |
US5290473A (en) * | 1993-03-15 | 1994-03-01 | Alliedsignal Inc. | Azeotrope-like compositons of 1,1,1,3,3,5,5,5-octafluoropentane, C1-C5 alkanol and optionally nitromethane |
EP0607969A1 (en) * | 1993-01-22 | 1994-07-27 | Canon Kabushiki Kaisha | Mixed solvent composition, and cleaning method and cleaning apparatus making use of the same |
EP0610507A1 (en) * | 1991-10-31 | 1994-08-17 | Daikin Industries, Ltd. | Cleaning solvent composition and cleaning method |
US5352375A (en) * | 1993-08-17 | 1994-10-04 | Alliedsignal Inc. | Azeotrope-like compositions of 1,1,1,2,2,3,3,-heptafluoropentane, C1 -C3 alkanol and optionally nitromethane |
WO1994028196A1 (en) * | 1993-06-01 | 1994-12-08 | Alliedsignal Inc. | Multiple solvent cleaning system |
US5395997A (en) * | 1993-07-29 | 1995-03-07 | Alliedsignal Inc. | Process for the preparation of hydrofluorocarbons having 3 to 7 carbon atoms |
US5424002A (en) * | 1991-08-26 | 1995-06-13 | Daikin Industries, Ltd. | Solvent composition comprising mixture of polyfluoroalkane and lower alcohol |
US5445757A (en) * | 1993-03-31 | 1995-08-29 | Solvay (Societe Anonyme) | Compositions comprising pentafluorobutane and use of these compositions |
US5444986A (en) * | 1992-07-16 | 1995-08-29 | Kajima Corporation | Method of producing ice by using fluorinated pentane |
WO1996010061A1 (en) * | 1994-09-29 | 1996-04-04 | E.I. Du Pont De Nemours And Company | Oftafluorobutane compositions |
US5531916A (en) * | 1990-10-03 | 1996-07-02 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon cleaning compositions |
EP0731162A1 (en) * | 1995-03-09 | 1996-09-11 | Elf Atochem S.A. | Use of hydrofluoroalkenes as cleaning agents and compositions containing them |
US5562853A (en) * | 1994-09-29 | 1996-10-08 | E. I. Du Pont De Nemours And Company | 1,1,2,2,3,3,4,4,-octafluorobutane compositions |
US5578137A (en) * | 1993-08-31 | 1996-11-26 | E. I. Du Pont De Nemours And Company | Azeotropic or azeotrope-like compositions including 1,1,1,2,3,4,4,5,5,5-decafluoropentane |
US5648325A (en) * | 1993-10-18 | 1997-07-15 | Ag Technology Co., Ltd. | Mixed solvent composition with 1-H-perfluorohexane, methanol or ethanol, and optionally a hydrocarbon |
US5696307A (en) * | 1994-01-21 | 1997-12-09 | Alliedsignal Inc. | Hydrofluoroalkanes as cleaning and degreasing solvents |
US5705471A (en) * | 1994-09-29 | 1998-01-06 | E. I. Du Pont De Nemours And Company | 1,1,2,2,3,3,4,4-octaflourobutane compositions |
US5824826A (en) * | 1997-06-27 | 1998-10-20 | Alliedsignal Inc. | Process for the preparation of 1,1,2,3,3,4-hexafluorobutane |
EP0885952A1 (en) * | 1997-06-20 | 1998-12-23 | Elf Atochem S.A. | Cleaning and degreasing composition without flash point |
US6162304A (en) * | 1997-07-25 | 2000-12-19 | Alliedsignal Inc. | Cleaning vapor compression systems |
US6355113B1 (en) | 1991-12-02 | 2002-03-12 | 3M Innovative Properties Company | Multiple solvent cleaning system |
US6688118B1 (en) | 1996-03-01 | 2004-02-10 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of cyclopentane |
WO2007016121A2 (en) * | 2005-07-27 | 2007-02-08 | Honeywell International Inc. | Hydrofluorocarbon refrigerant compositions |
USRE39819E1 (en) | 1998-07-24 | 2007-09-04 | Atofina | Cleaning or drying compositions based on 1,1,1,2,3,4,4,5,5,5-decafluoropentane |
US7531495B2 (en) | 2000-06-01 | 2009-05-12 | Asahi Kasei Kabushiki Kaisha | Cleaning agent, cleaning method and cleaning apparatus |
US8021490B2 (en) | 2007-01-04 | 2011-09-20 | Eastman Chemical Company | Substrate cleaning processes through the use of solvents and systems |
CN101463300B (en) * | 2008-11-28 | 2011-09-28 | 江苏海迅实业集团股份有限公司 | Cleaning agent for magnetic head |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0585966A (en) * | 1991-09-25 | 1993-04-06 | Daikin Ind Ltd | Refrigerant |
JP3274878B2 (en) * | 1992-02-03 | 2002-04-15 | タイホー工業株式会社 | Cleaning agent for carbon |
CN1119456A (en) * | 1993-03-12 | 1996-03-27 | 大金工业株式会社 | Process for producing clean article |
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- 1990-11-26 AU AU66916/90A patent/AU635362B2/en not_active Ceased
- 1990-11-28 EP EP90122748A patent/EP0431458A1/en not_active Withdrawn
- 1990-11-28 JP JP2331976A patent/JP2850533B2/en not_active Expired - Lifetime
- 1990-12-04 CA CA002031421A patent/CA2031421A1/en not_active Abandoned
- 1990-12-06 BR BR909006196A patent/BR9006196A/en not_active Application Discontinuation
- 1990-12-06 RU SU904894031A patent/RU2010847C1/en active
- 1990-12-07 KR KR1019900020128A patent/KR910012220A/en not_active Application Discontinuation
- 1990-12-07 CS CS906111A patent/CS611190A2/en unknown
- 1990-12-07 PL PL28814590A patent/PL288145A1/en unknown
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US5346645A (en) * | 1991-05-28 | 1994-09-13 | Daikin Industries, Ltd. | Desiccant composition and a method of desiccating articles |
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US5266232A (en) * | 1991-06-21 | 1993-11-30 | Hoechst Aktiengesellschaft | Azeotrope-like mixture of methanol and 1H-perfluorohexane |
US5266231A (en) * | 1991-06-21 | 1993-11-30 | Hoechst Aktiengesellschaft | Azeotrope-like mixture of 2-propanol and 1H-perfluorohexane |
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US5219489A (en) * | 1991-08-15 | 1993-06-15 | Allied-Signal Inc. | Azeotrope-like compositions of 2-trifluoromethyl-1,1,1,2-tetrafluorobutane and methanol |
US5424002A (en) * | 1991-08-26 | 1995-06-13 | Daikin Industries, Ltd. | Solvent composition comprising mixture of polyfluoroalkane and lower alcohol |
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US5444986A (en) * | 1992-07-16 | 1995-08-29 | Kajima Corporation | Method of producing ice by using fluorinated pentane |
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Also Published As
Publication number | Publication date |
---|---|
AU635362B2 (en) | 1993-03-18 |
PL288145A1 (en) | 1991-08-26 |
RU2010847C1 (en) | 1994-04-15 |
AU6691690A (en) | 1991-06-13 |
CS611190A2 (en) | 1991-09-15 |
KR910012220A (en) | 1991-08-07 |
BR9006196A (en) | 1991-09-24 |
CA2031421A1 (en) | 1991-06-08 |
JPH0428798A (en) | 1992-01-31 |
JP2850533B2 (en) | 1999-01-27 |
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