EP0391392A3 - Low-foam, cold-stable aqueous detergents containing nonionic, anionic and cationic surface active agents and their utilization - Google Patents

Low-foam, cold-stable aqueous detergents containing nonionic, anionic and cationic surface active agents and their utilization Download PDF

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Publication number
EP0391392A3
EP0391392A3 EP19900106442 EP90106442A EP0391392A3 EP 0391392 A3 EP0391392 A3 EP 0391392A3 EP 19900106442 EP19900106442 EP 19900106442 EP 90106442 A EP90106442 A EP 90106442A EP 0391392 A3 EP0391392 A3 EP 0391392A3
Authority
EP
European Patent Office
Prior art keywords
low
anionic
foam
utilization
cold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19900106442
Other languages
German (de)
French (fr)
Other versions
EP0391392B1 (en
EP0391392A2 (en
Inventor
Wolfgang Klinger
Eckhard Milewski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of EP0391392A2 publication Critical patent/EP0391392A2/en
Publication of EP0391392A3 publication Critical patent/EP0391392A3/en
Application granted granted Critical
Publication of EP0391392B1 publication Critical patent/EP0391392B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86Mixtures of anionic, cationic, and non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/18Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
    • C11D1/20Fatty acid condensates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/42Amino alcohols or amino ethers
    • C11D1/44Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/722Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/74Carboxylates or sulfonates esters of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Cosmetics (AREA)
  • Paper (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)

Abstract

The surfactant compositions are obtained by mixing 1 part by weight of at least one non-ionic surfactant and 0.3 to 9 parts by weight of a specific mixture of water and at least one anionic surfactant and at least one cationic surfactant. They are concentrated, and generally clear, liquids which are distinguished, in particular by favourable foaming and wetting characteristics, low surface tension and low pour point and, by reason of these special properties, can be used for many purposes.
EP90106442A 1989-04-06 1990-04-04 Low-foam, cold-stable aqueous detergents containing nonionic, anionic and cationic surface active agents and their utilization Expired - Lifetime EP0391392B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3911098A DE3911098A1 (en) 1989-04-06 1989-04-06 LOW-foaming and cold-stable liquid surfactant compositions from water and nonionic, anionic and cationic surfactants and their use
DE3911098 1989-04-06

Publications (3)

Publication Number Publication Date
EP0391392A2 EP0391392A2 (en) 1990-10-10
EP0391392A3 true EP0391392A3 (en) 1991-01-16
EP0391392B1 EP0391392B1 (en) 1995-07-26

Family

ID=6377968

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90106442A Expired - Lifetime EP0391392B1 (en) 1989-04-06 1990-04-04 Low-foam, cold-stable aqueous detergents containing nonionic, anionic and cationic surface active agents and their utilization

Country Status (8)

Country Link
US (1) US5298193A (en)
EP (1) EP0391392B1 (en)
JP (1) JPH02284639A (en)
AT (1) ATE125564T1 (en)
BR (1) BR9001527A (en)
CA (1) CA2013920A1 (en)
DE (2) DE3911098A1 (en)
ES (1) ES2076984T3 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT103U1 (en) * 1992-04-16 1995-02-27 Purator Umwelttechnik Gmbh METHODS FOR WASHING AND DRYING AND, WHEREAS, GROWING IN MOTOR VEHICLE WASHING SYSTEMS
US6180740B1 (en) 1998-02-27 2001-01-30 E. I. Du Pont De Nemours And Company Stabilization of fluorochemical copolymer emulsions
US6617303B1 (en) 1999-01-11 2003-09-09 Huntsman Petrochemical Corporation Surfactant compositions containing alkoxylated amines
BR0015923A (en) * 1999-11-22 2003-06-24 Huntsman Spec Chem Corp Surfactant Adjuvants Useful in Herbicide Compositions
DE10203225A1 (en) 2002-01-28 2003-07-31 Weigert Chem Fab Cleaning surgical instruments
DE10316001A1 (en) * 2003-04-07 2004-10-21 Goldschmidt Ag Aqueous formulations containing combinations of anionic and cationic surfactants to create a yield point
DE102004039727A1 (en) * 2004-08-16 2006-02-23 Bode Chemie Gmbh & Co. Kg Detergents and disinfectants for medical instruments with improved efficacy against hepatitis B viruses
EP2123350B1 (en) * 2008-05-20 2012-02-29 Cognis IP Management GmbH Aqueous tenside compounds with low pour point
EP2455156B1 (en) * 2010-11-18 2013-06-05 Cognis IP Management GmbH Low viscosity aqueous compounds
FR3095558B1 (en) 2019-04-24 2021-04-30 Niedax France COVER FIXING ELEMENT FOR CABLE TRACK

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3684736A (en) * 1970-09-10 1972-08-15 William L Groves Jr Low-foaming surface active compositions and method of preparing such compositions
US4321165A (en) * 1977-06-29 1982-03-23 The Procter & Gamble Company Detergent compositions comprising cationic, anionic and nonionic surfactants
EP0151678A1 (en) * 1983-08-12 1985-08-21 THE PROCTER & GAMBLE COMPANY Stable liquid detergent compositions
GB2195653A (en) * 1986-10-06 1988-04-13 Colgate Palmolive Co Cationic/anionic surfactant complex antistatic and fabric softening emulsion for wash cycle laundry applications

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2398295A (en) * 1943-03-13 1946-04-09 Emulsol Corp Emulsions
US2779741A (en) * 1950-12-26 1957-01-29 Gen Aniline & Film Corp Water-soluble compositions containing water-insoluble organic amines
US3658717A (en) * 1969-07-07 1972-04-25 Atlas Chem Ind Surfactants for solvent/water systems and textile treating compositions
US3668136A (en) * 1969-07-07 1972-06-06 Witco Chemical Corp Compatible anionic-catonic surfactant compositions
JPS54159416A (en) * 1978-06-07 1979-12-17 Lion Corp Liquid detergent composition
US4392965A (en) * 1981-11-12 1983-07-12 Woodward Fred E Laundry softener antistatic composition
US4913828A (en) * 1987-06-10 1990-04-03 The Procter & Gamble Company Conditioning agents and compositions containing same
US4751009A (en) * 1987-08-05 1988-06-14 Akzo America Inc. Fabric softeners comprising stable single phase clear solutions of anionic and cationic surfactants
US4810409A (en) * 1987-12-16 1989-03-07 Sterling Drug Inc. Stable, isotropic liquid laundry detergents
DE3908008A1 (en) * 1988-10-11 1990-04-12 Hoechst Ag CONCENTRATED AND LIQUID WATER-BASED SURFACTANT COMPOSITION, METHOD FOR THE PRODUCTION AND USE THEREOF
US4919839A (en) * 1989-02-21 1990-04-24 Colgate Palmolive Co. Light duty microemulsion liquid detergent composition containing an aniocic/cationic complex

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3684736A (en) * 1970-09-10 1972-08-15 William L Groves Jr Low-foaming surface active compositions and method of preparing such compositions
US4321165A (en) * 1977-06-29 1982-03-23 The Procter & Gamble Company Detergent compositions comprising cationic, anionic and nonionic surfactants
EP0151678A1 (en) * 1983-08-12 1985-08-21 THE PROCTER & GAMBLE COMPANY Stable liquid detergent compositions
GB2195653A (en) * 1986-10-06 1988-04-13 Colgate Palmolive Co Cationic/anionic surfactant complex antistatic and fabric softening emulsion for wash cycle laundry applications

Also Published As

Publication number Publication date
US5298193A (en) 1994-03-29
EP0391392B1 (en) 1995-07-26
ATE125564T1 (en) 1995-08-15
DE59009425D1 (en) 1995-08-31
CA2013920A1 (en) 1990-10-06
EP0391392A2 (en) 1990-10-10
BR9001527A (en) 1991-04-23
ES2076984T3 (en) 1995-11-16
JPH02284639A (en) 1990-11-22
DE3911098A1 (en) 1990-10-11

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