DE69913932D1 - Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation - Google Patents
Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisationInfo
- Publication number
- DE69913932D1 DE69913932D1 DE69913932T DE69913932T DE69913932D1 DE 69913932 D1 DE69913932 D1 DE 69913932D1 DE 69913932 T DE69913932 T DE 69913932T DE 69913932 T DE69913932 T DE 69913932T DE 69913932 D1 DE69913932 D1 DE 69913932D1
- Authority
- DE
- Germany
- Prior art keywords
- metallocen
- production
- olefin polymerization
- carrier catalyst
- polymerization carried
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-1998-0044308A KR100430438B1 (ko) | 1998-10-22 | 1998-10-22 | 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법 |
KR9844308 | 1998-10-22 | ||
PCT/KR1999/000635 WO2000023483A1 (en) | 1998-10-22 | 1999-10-22 | Supported metallocene catalyst, its preparation method and olefin polymerization therewith |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69913932D1 true DE69913932D1 (de) | 2004-02-05 |
DE69913932T2 DE69913932T2 (de) | 2004-11-18 |
Family
ID=19554970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1999613932 Expired - Lifetime DE69913932T2 (de) | 1998-10-22 | 1999-10-22 | Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation |
Country Status (5)
Country | Link |
---|---|
US (1) | US6683016B1 (de) |
EP (1) | EP1042375B1 (de) |
KR (1) | KR100430438B1 (de) |
DE (1) | DE69913932T2 (de) |
WO (1) | WO2000023483A1 (de) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100404780B1 (ko) * | 2000-02-18 | 2003-11-07 | 대림산업 주식회사 | 메탈로센 화합물과 이로부터 제조되는 메탈로센 촉매 및이를 이용한 올레핀의 중합 방법 |
EP1201683A1 (de) * | 2000-10-30 | 2002-05-02 | SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) | Verfahren zur Polymerisation von Alpha-Olefinen |
KR100447799B1 (ko) * | 2001-01-03 | 2004-09-08 | 대림산업 주식회사 | 메탈로센 화합물 및 이를 포함하는 촉매 조성물 |
US7294681B2 (en) | 2002-10-15 | 2007-11-13 | Exxonmobil Chemical Patents Inc. | Mutliple catalyst system for olefin polymerization and polymers produced therefrom |
US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US7323526B2 (en) * | 2005-07-29 | 2008-01-29 | Univation Technologies, Llc | Supported metallocene-alkyl catalyst composition |
KR100681302B1 (ko) | 2005-12-16 | 2007-02-09 | 대림산업 주식회사 | 올레핀 중합용 촉매 및 이를 이용한 올레핀의 중합방법 |
ATE542836T1 (de) * | 2006-03-30 | 2012-02-15 | Total Petrochemicals Res Feluy | Verfahren zur herstellung von ethylenpolymeren unter verwendung einer reihe von hintereinander angeordneten reaktoren |
US20070255028A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
KR101339550B1 (ko) * | 2011-11-24 | 2013-12-10 | 삼성토탈 주식회사 | 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법 |
CN111212856B (zh) * | 2017-10-31 | 2023-03-24 | 埃克森美孚化学专利公司 | 来自在脂肪族溶剂中原位形成负载的铝氧烷的无甲苯的二氧化硅负载的单中心茂金属催化剂 |
KR102342780B1 (ko) | 2018-02-08 | 2021-12-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 |
RU2666736C1 (ru) * | 2018-05-30 | 2018-09-12 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ получения синтетических высоковязких полиальфаолефиновых базовых масел |
WO2023285880A1 (en) * | 2021-07-15 | 2023-01-19 | Braskem S.A. | Continuous process for metallocene preliminary polymerization for gas-phase polymerization process |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4551690A (en) * | 1982-03-18 | 1985-11-05 | Branson Ultrasonics Corporation | Automatic tuning circuit for use in an ultrasonic apparatus |
US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4897455A (en) | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4730071A (en) * | 1986-08-15 | 1988-03-08 | Shell Oil Company | Process for preparing aluminoxanes |
US4937217A (en) | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst |
US4937301A (en) | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US4912075A (en) | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
JP2538969B2 (ja) * | 1988-02-16 | 1996-10-02 | 昭和化学工業株式会社 | 珪藻土から高品位化した多孔質珪藻殻の製造方法 |
US5086025A (en) | 1988-03-29 | 1992-02-04 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US5008228A (en) | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US5147949A (en) | 1988-03-29 | 1992-09-15 | Exxon Chemical Patents Inc. | Polymerization process using a silica gel supported metallocene-alumoxane catalyst |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US4935397A (en) | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
JPH04170455A (ja) * | 1990-11-01 | 1992-06-18 | Mitsui Petrochem Ind Ltd | 環状オレフィン系樹脂組成物 |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
DE69219206T2 (de) | 1991-05-31 | 1997-08-28 | Mitsui Petrochemical Ind | Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
US5602067A (en) | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5608019A (en) | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5420220A (en) | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
EP0690878B2 (de) | 1993-03-25 | 2004-12-29 | Exxonmobil Oil Corporation | Verfahren zur herstellung granulären harzes |
US5473020A (en) | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
EP0774954B1 (de) * | 1994-07-05 | 1999-08-04 | LTS LOHMANN Therapie-Systeme GmbH | Hydrogel für die applikation von therapeutischen und/oder kosmetischen wirkstoffen an die haut |
JP3355572B2 (ja) * | 1994-08-23 | 2002-12-09 | 新日本石油株式会社 | オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法 |
FI952098A (fi) * | 1995-05-02 | 1996-11-03 | Borealis As | LLDPE-polymeerien valmistusmenetelmä |
US5587439A (en) * | 1995-05-12 | 1996-12-24 | Quantum Chemical Corporation | Polymer supported catalyst for olefin polymerization |
JPH10120716A (ja) | 1996-08-27 | 1998-05-12 | Mitsui Chem Inc | 予備重合固体状触媒、その調製方法およびオレフィンの不均一系重合方法 |
TR200002753T2 (tr) * | 1998-03-26 | 2000-12-21 | The Dow Chemical Company | İyon ile yer değiştirilmiş alüminyum-magnezyum ya da flüorinlenmiş magnezyum silikat aerojelleri ve bunlardan sağlanan katalizör destekleri |
-
1998
- 1998-10-22 KR KR10-1998-0044308A patent/KR100430438B1/ko not_active IP Right Cessation
-
1999
- 1999-10-22 DE DE1999613932 patent/DE69913932T2/de not_active Expired - Lifetime
- 1999-10-22 WO PCT/KR1999/000635 patent/WO2000023483A1/en active IP Right Grant
- 1999-10-22 EP EP99951232A patent/EP1042375B1/de not_active Expired - Lifetime
- 1999-10-22 US US09/582,187 patent/US6683016B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69913932T2 (de) | 2004-11-18 |
WO2000023483A1 (en) | 2000-04-27 |
EP1042375A1 (de) | 2000-10-11 |
KR100430438B1 (ko) | 2004-07-19 |
US6683016B1 (en) | 2004-01-27 |
KR20000026665A (ko) | 2000-05-15 |
EP1042375B1 (de) | 2004-01-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2184600A (en) | Olefin polymerization catalysts, their production and use | |
ATE233790T1 (de) | Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung | |
DZ2740A1 (fr) | Catalyseurs de polymésation. | |
DZ2737A1 (fr) | Catalyseurs de polymérisation. | |
DZ2738A1 (fr) | Catalyseurs de polymérisation. | |
NO20012785L (no) | Katalysator og fremgangsmåte for olefinpolymerisasjon | |
BR9810289B1 (pt) | processo de preparaÇço de polÍmeros em blocos, e, polÍmero. | |
NO20023403D0 (no) | Substituerte gruppe 4 metallkomplekser, katalysatorer og olefinpolymerisasjonsfremgangsmåte | |
DE19781849T1 (de) | Ringförmige, konzentrische Extruderdüse | |
DE69624917D1 (de) | Katalysator, verfahren und damit hergestellte polymere | |
DE69919425D1 (de) | Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid | |
ID27764A (id) | Katalis-katalis polimerisasi | |
SG91813A1 (en) | Olefin polymerization catalyst and polymerization process | |
DE69913932D1 (de) | Metallocen-trägerkatalysator, seine herstellung sowie damit durchgeführte olefinpolymerisation | |
TR199600425A2 (tr) | Kati titanyum katalizör bileseni, bu bileseni iceren etilen polimerizasyonu katalizörü ve etilen polimerizasyonu islemi. | |
FI964585A (fi) | Käsitelty alusta, jolla on parantuneet irrotusominaisuudet | |
AU9464198A (en) | Supported metallocene catalyst, process for preparing the same, and process for producing olefin polymers | |
DE69905011T2 (de) | Bis(tetrahydro-indenyl) metallocene, und diesen enthaltende olefinpolymerisationskatalysatoren | |
FI970438A0 (fi) | Foerfarande i panna, saerskilt i sodapanna | |
NO20012982D0 (no) | Olefinpolymerisasjonskatalysatorsystem, polymerisasjonsprosess og polymer derfra | |
DE69421752T2 (de) | Sphärischer Ziegler-Katalysator zur Olefinpolymerisation, seine Herstellung und Verwendung | |
NO981631D0 (no) | Katalysator for polymerisasjon av etylen, og fremgangsmÕte for fremstilling av denne | |
DE69937090D1 (de) | Halbleiterträger, seine Herstellung, Aufbau und dessen Herstellung | |
DE3764251D1 (de) | Olefinpolymerisationskatalysator, seine herstellung und anwendung. | |
AU4932999A (en) | Mu-oxobismetallocene complexes, catalyst for olefin polymerization containing the same, and polymerization method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |