DE69706654T2 - Kostengünstiges stabiles luftelektrodematerial für hochtemperatur-festoxid elektrochemische zellen - Google Patents

Kostengünstiges stabiles luftelektrodematerial für hochtemperatur-festoxid elektrochemische zellen

Info

Publication number
DE69706654T2
DE69706654T2 DE69706654T DE69706654T DE69706654T2 DE 69706654 T2 DE69706654 T2 DE 69706654T2 DE 69706654 T DE69706654 T DE 69706654T DE 69706654 T DE69706654 T DE 69706654T DE 69706654 T2 DE69706654 T2 DE 69706654T2
Authority
DE
Germany
Prior art keywords
electrodematerial
effective
cost
high temperature
solid oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69706654T
Other languages
English (en)
Other versions
DE69706654D1 (de
Inventor
J Kuo
Prabhakar Singh
J Ruka
R Vasilow
J Bratton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Energy Inc
Original Assignee
Siemens Westinghouse Power Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Westinghouse Power Corp filed Critical Siemens Westinghouse Power Corp
Application granted granted Critical
Publication of DE69706654D1 publication Critical patent/DE69706654D1/de
Publication of DE69706654T2 publication Critical patent/DE69706654T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/016—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on manganites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • H01M2300/0074—Ion conductive at high temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
DE69706654T 1996-02-29 1997-02-27 Kostengünstiges stabiles luftelektrodematerial für hochtemperatur-festoxid elektrochemische zellen Expired - Lifetime DE69706654T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/608,889 US5686198A (en) 1996-02-29 1996-02-29 Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells
PCT/US1997/003019 WO1997032349A1 (en) 1996-02-29 1997-02-27 Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

Publications (2)

Publication Number Publication Date
DE69706654D1 DE69706654D1 (de) 2001-10-18
DE69706654T2 true DE69706654T2 (de) 2002-04-18

Family

ID=24438490

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69706654T Expired - Lifetime DE69706654T2 (de) 1996-02-29 1997-02-27 Kostengünstiges stabiles luftelektrodematerial für hochtemperatur-festoxid elektrochemische zellen

Country Status (12)

Country Link
US (1) US5686198A (de)
EP (1) EP0885466B1 (de)
JP (1) JP2000505593A (de)
KR (1) KR100439394B1 (de)
CN (1) CN1212788A (de)
AU (1) AU717465B2 (de)
CA (1) CA2247471A1 (de)
CZ (1) CZ275498A3 (de)
DE (1) DE69706654T2 (de)
NO (1) NO983842L (de)
TW (1) TW355850B (de)
WO (1) WO1997032349A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014209758A1 (de) * 2014-05-22 2015-11-26 Robert Bosch Gmbh Brennstoffzellenvorrichtung
DE112007000434B4 (de) * 2006-02-23 2018-02-22 National Institute Of Advanced Industrial Science And Technology Stapel aus elektrochemischen Zellen und elektrochemisches Reaktionssystem mit porösem Träger zur Integration von elektrochemischen Zellen mit hoher Dichte

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US5977017A (en) * 1996-04-10 1999-11-02 Catalytic Solutions, Inc. Perovskite-type metal oxide compounds
US5916700A (en) * 1998-01-23 1999-06-29 Siemens Westinghouse Power Corporation Lanthanum manganite-based air electrode for solid oxide fuel cells
US6217822B1 (en) * 1998-02-09 2001-04-17 Siemens Westinghouse Power Corporation Method of making straight fuel cell tubes
DE19908213B4 (de) * 1998-07-27 2005-03-10 Mitsubishi Heavy Ind Ltd Basisrohr für eine Brennstoffzelle
US6379832B1 (en) * 1999-07-19 2002-04-30 Mitsubishi Heavy Industries, Ltd. Base tube for fuel cell and material for base tube
US6605316B1 (en) 1999-07-31 2003-08-12 The Regents Of The University Of California Structures and fabrication techniques for solid state electrochemical devices
US6492051B1 (en) 2000-09-01 2002-12-10 Siemens Westinghouse Power Corporation High power density solid oxide fuel cells having improved electrode-electrolyte interface modifications
FR2817860B1 (fr) * 2000-12-07 2003-09-12 Air Liquide Procede de preparation d'un materiau ceramique de faible epaisseur a gradient de porosite superficielle controle, materiau ceramique obtenu, cellule electrochimique et membrane ceramique le comprenant
US6632554B2 (en) * 2001-04-10 2003-10-14 Hybrid Power Generation Systems, Llc High performance cathodes for solid oxide fuel cells
GB2386126B (en) * 2002-03-06 2006-03-08 Ceres Power Ltd Forming an impermeable sintered ceramic electrolyte layer on a metallic foil substrate for solid oxide fuel cell
US7022429B2 (en) * 2002-04-25 2006-04-04 General Electric Company Fluid passages for power generation equipment
AU2003228791A1 (en) 2002-05-03 2003-11-17 Battelle Memorial Institute Cerium-modified doped strontium titanate composition for solid oxide fuel cell anodes and electrodes for other electrochemical devices
GB0217794D0 (en) * 2002-08-01 2002-09-11 Univ St Andrews Fuel cell electrodes
CN1294670C (zh) * 2004-03-03 2007-01-10 哈尔滨工业大学 一种镓酸镧基固体氧化物燃料电池用正极材料的制备方法
US7468218B2 (en) * 2004-05-07 2008-12-23 Battelle Memorial Institute Composite solid oxide fuel cell anode based on ceria and strontium titanate
US7433023B2 (en) * 2004-09-20 2008-10-07 Applied Kinetics, Inc. Apparatuses and methods for measuring head suspensions and head suspension assemblies
JP2008522370A (ja) 2004-11-30 2008-06-26 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア 電気化学装置用封止ジョイント構造
GB2424878B (en) * 2005-04-08 2010-09-15 Ceres Power Ltd High performance SOFC Cathode material in the 450 C 650 C range
CN100336251C (zh) * 2005-11-09 2007-09-05 合肥学院 一种500～800℃中温固体氧化物燃料电池的阳极材料及使用其的阳极制备方法
AT9543U1 (de) * 2006-07-07 2007-11-15 Plansee Se Verfahren zur herstellung einer elektrisch leitfähigen schicht
JP2009544502A (ja) 2006-07-28 2009-12-17 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア 接合された同心管
US20080254335A1 (en) * 2007-04-16 2008-10-16 Worldwide Energy, Inc. Porous bi-tubular solid state electrochemical device
US20080292918A1 (en) * 2007-05-25 2008-11-27 Caine Finnerty Electrochemical system having multiple independent circuits
FR2925486B1 (fr) * 2007-12-21 2011-07-01 Saint Gobain Ct Recherches Procede de fabrication d'un produit fondu a base de lanthane et de manganese
US20090194223A1 (en) * 2008-02-06 2009-08-06 Battelle Memorial Institute Low-temperature sintering of lanthanum strontium manganite-based contact pastes for sofcs
US8343684B2 (en) * 2008-03-07 2013-01-01 Alan Devoe Fuel cell device and system
AU2008354733B2 (en) * 2008-04-18 2013-10-03 The Regents Of The University Of California Integrated seal for high-temperature electrochemical device
US8952295B2 (en) * 2008-06-18 2015-02-10 Lincoln Global, Inc. Welding wire with perovskite coating
US8901455B2 (en) * 2008-06-18 2014-12-02 Lincoln Global, Inc. Welding wire for submerged arc welding
US20100183929A1 (en) * 2009-01-20 2010-07-22 Adaptive Materials, Inc. Solid oxide fuel cell system including a water based fuel reformer
US8409760B2 (en) * 2009-01-20 2013-04-02 Adaptive Materials, Inc. Method for controlling a water based fuel reformer
US8936888B2 (en) * 2009-01-30 2015-01-20 Adaptive Materials, Inc. Fuel cell system with flame protection member
US20110189578A1 (en) * 2010-02-01 2011-08-04 Adaptive Materials, Inc. Fuel cell system including a resilient manifold interconnecting member
US8796888B2 (en) 2010-07-07 2014-08-05 Adaptive Materials, Inc. Wearable power management system
JP5854368B2 (ja) * 2011-06-21 2016-02-09 Toto株式会社 電極材料の製造方法
US10906017B2 (en) * 2013-06-11 2021-02-02 University Of Florida Research Foundation, Inc. Solar thermochemical reactor and methods of manufacture and use thereof
US10458027B2 (en) * 2015-10-08 2019-10-29 Low Emission Resources Corporation Electrode-supported tubular solid-oxide electrochemical cell
CN105839138B (zh) * 2016-05-10 2017-11-07 东北林业大学 一种固体氧化物电解池高温熔融碳酸盐空气电极的制备方法
CN111902987B (zh) * 2018-04-17 2023-08-25 三井金属矿业株式会社 固体电解质接合体
EP4027136B1 (de) * 2018-07-13 2023-10-04 Fuji Electric Co., Ltd. Kohlendioxidgassensor
CN113402271B (zh) * 2021-06-04 2022-04-29 哈尔滨工业大学 一种提高钽掺杂石榴石型固态电解质致密度及电导率的方法

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112007000434B4 (de) * 2006-02-23 2018-02-22 National Institute Of Advanced Industrial Science And Technology Stapel aus elektrochemischen Zellen und elektrochemisches Reaktionssystem mit porösem Träger zur Integration von elektrochemischen Zellen mit hoher Dichte
DE102014209758A1 (de) * 2014-05-22 2015-11-26 Robert Bosch Gmbh Brennstoffzellenvorrichtung

Also Published As

Publication number Publication date
NO983842D0 (no) 1998-08-21
EP0885466A1 (de) 1998-12-23
EP0885466B1 (de) 2001-09-12
JP2000505593A (ja) 2000-05-09
KR19990087383A (ko) 1999-12-27
AU717465B2 (en) 2000-03-30
WO1997032349A1 (en) 1997-09-04
DE69706654D1 (de) 2001-10-18
NO983842L (no) 1998-10-28
CA2247471A1 (en) 1997-09-04
CZ275498A3 (cs) 1999-12-15
US5686198A (en) 1997-11-11
CN1212788A (zh) 1999-03-31
TW355850B (en) 1999-04-11
AU2058097A (en) 1997-09-16
KR100439394B1 (ko) 2004-09-18

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