DE69613378T2 - Organoboran-polyamin-komplex initiator systeme sowie damit hergestellte polymerisierbare zusammensetzungen - Google Patents

Organoboran-polyamin-komplex initiator systeme sowie damit hergestellte polymerisierbare zusammensetzungen

Info

Publication number
DE69613378T2
DE69613378T2 DE69613378T DE69613378T DE69613378T2 DE 69613378 T2 DE69613378 T2 DE 69613378T2 DE 69613378 T DE69613378 T DE 69613378T DE 69613378 T DE69613378 T DE 69613378T DE 69613378 T2 DE69613378 T2 DE 69613378T2
Authority
DE
Germany
Prior art keywords
organoboran
compositions produced
polymerizable compositions
initiator systems
produced therewith
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69613378T
Other languages
English (en)
Other versions
DE69613378D1 (de
Inventor
V Pocius
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of DE69613378D1 publication Critical patent/DE69613378D1/de
Application granted granted Critical
Publication of DE69613378T2 publication Critical patent/DE69613378T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3253—Polyamines being in latent form
    • C08G18/3268—Salt complexes of polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/637—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the in situ polymerisation of the compounds having carbon-to-carbon double bonds in a reaction mixture of saturated polymers and isocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6648—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6651—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
DE69613378T 1995-08-11 1996-07-01 Organoboran-polyamin-komplex initiator systeme sowie damit hergestellte polymerisierbare zusammensetzungen Expired - Lifetime DE69613378T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/514,190 US5686544A (en) 1995-08-11 1995-08-11 Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
PCT/US1996/011190 WO1997007151A1 (en) 1995-08-11 1996-07-01 Organoborane polyamine complex initiator systems and polymerizable compositions made therewith

Publications (2)

Publication Number Publication Date
DE69613378D1 DE69613378D1 (de) 2001-07-19
DE69613378T2 true DE69613378T2 (de) 2002-05-02

Family

ID=24046159

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69613378T Expired - Lifetime DE69613378T2 (de) 1995-08-11 1996-07-01 Organoboran-polyamin-komplex initiator systeme sowie damit hergestellte polymerisierbare zusammensetzungen

Country Status (9)

Country Link
US (4) US5686544A (de)
EP (1) EP0843695B1 (de)
JP (1) JP4134302B2 (de)
CN (1) CN1100806C (de)
AU (1) AU6482296A (de)
BR (1) BR9609933A (de)
CA (1) CA2229166A1 (de)
DE (1) DE69613378T2 (de)
WO (1) WO1997007151A1 (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5691065A (en) * 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5686544A (en) * 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
EP0859801B1 (de) * 1995-11-07 2001-06-13 Minnesota Mining And Manufacturing Company Initiator system und klebstoff zusammensetzung diesen enthaltend
US5935711A (en) * 1996-10-23 1999-08-10 3M Innovative Properties Company Organoborane amine complex initiator systems and polymerizable compositions made therewith
US6812308B2 (en) 2000-11-21 2004-11-02 3M Innovative Properties Company Initiator systems and adhesive compositions made therewith
US6383655B1 (en) 1998-06-12 2002-05-07 3M Innovative Properties Company Low odor polymerizable compositions useful for bonding low surface energy substrates
AU1929100A (en) 1998-12-03 2000-06-19 Dexter Corporation, The Adhesive compositions with retarding additive
US6799966B1 (en) 1999-03-04 2004-10-05 3M Innovative Properties Company Fluoropolymeric orthodontic article
US6252023B1 (en) 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6878440B1 (en) 1999-07-02 2005-04-12 3M Innovative Properties Company Pressure sensitive adhesive sheet and production method thereof
JP3816697B2 (ja) * 1999-07-07 2006-08-30 大日精化工業株式会社 重合体が結合した機能剤、その製造方法、それらの使用方法及びそれらを使用した物品
US6410667B1 (en) 1999-11-04 2002-06-25 3M Innovative Properties Company Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith
US6486090B1 (en) 1999-11-04 2002-11-26 3M Innovative Properties Company Initiator/hydroxide and initiator/alkoxide complexes, systems comprising the complexes, and polymerized compositions made therewith
US6806330B1 (en) 1999-12-17 2004-10-19 Dow Global Technologies Inc. Amine organoborane complex polymerization initiators and polymerizable compositions
US6479602B1 (en) * 2000-03-15 2002-11-12 3M Innovative Properties Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
US20040091713A1 (en) * 2000-06-09 2004-05-13 Toshihiro Suwa Adherable fluorine-containing material sheet, adhesive fluorine-containing material sheet, and adhering method and adhesion structure of fluorine-containing material sheet
EP1201722A1 (de) * 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisationsinitiatoren, polymerisierbare Zusammensetzungen und deren Verwendungen
JP2002294101A (ja) * 2001-03-28 2002-10-09 Nippon Paint Co Ltd 樹脂組成物、ボロン含有重合体の製造方法及び防汚塗料
GB0114684D0 (en) 2001-06-15 2001-08-08 Dow Chemical Co Automobile assembly
BR0212192A (pt) * 2001-08-15 2004-10-05 Dow Global Technologies Inc Conjunto para interior veicular
US20030044553A1 (en) * 2001-08-23 2003-03-06 Ravi Ramanathan Fuel tanks
US20030047268A1 (en) * 2001-08-23 2003-03-13 Korchnak Gregory J. Method for repairing fuel tanks
US6740716B2 (en) * 2001-10-30 2004-05-25 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
WO2003089536A2 (en) * 2002-04-19 2003-10-30 Loctite (R & D) Limited Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US6867271B1 (en) 2002-06-24 2005-03-15 Henkel Corporation Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
US20040001945A1 (en) * 2002-06-27 2004-01-01 Cate Peter J. Composite foam structure having an isotropic strength region and anisotropic strength region
US7098279B2 (en) * 2002-10-22 2006-08-29 Loctite (R&D) Limited Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
MXPA05008586A (es) * 2003-02-13 2005-11-04 Dow Global Technologies Inc Ensamble reforzado de panel de instrumentos y metodo para elaborarlo.
CN100427336C (zh) * 2003-02-13 2008-10-22 陶氏环球技术公司 座椅系统及其制作方法
US7250091B2 (en) * 2003-02-13 2007-07-31 Dow Global Technologies Inc Method of forming a seating system
US6777512B1 (en) * 2003-02-28 2004-08-17 Dow Global Technologies Inc. Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
US20040238114A1 (en) * 2003-06-02 2004-12-02 Dow Global Technologies Inc. Air bag system and method of forming the same
RU2358992C2 (ru) * 2003-06-09 2009-06-20 Дау Глобал Текнолоджиз Инк. Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции
WO2005000980A2 (en) * 2003-06-18 2005-01-06 Dow Global Technologies Inc. Paint formulation for a low surface energy substrate
US7360519B2 (en) 2003-07-10 2008-04-22 Dow Global Technologies, Inc. Engine intake manifold assembly
CN1835993A (zh) * 2003-08-13 2006-09-20 陶氏环球技术公司 将管道系统和管道连接到装备、固定物、设备、结构和器具的方法
US7638007B2 (en) * 2003-08-13 2009-12-29 Dow Global Technologies, Inc Method for joining substrates and objects
GB0326286D0 (en) 2003-11-11 2003-12-17 Vantico Gmbh Initiator systems for polymerisable compositions
WO2005063480A1 (en) * 2003-12-22 2005-07-14 Dow Global Technologies Inc. Accelerated organoborane amine complex initiated polymerizable compositions
US8501886B2 (en) * 2003-12-22 2013-08-06 Dow Global Technologies Llc Accelerated organoborane amine complex initiated polymerizable compositions
US20070172989A1 (en) * 2004-02-27 2007-07-26 Akzo Nobel N.V. Polymerization initiator systems containing aluminum compounds as curing inhibitors and polymerizable compositions made therewith
US7360552B2 (en) * 2004-04-23 2008-04-22 Dow Global Technologies Inc. Injectable structural adhesive
US7368171B2 (en) * 2004-09-03 2008-05-06 H.B. Fuller Licensing & Financing, Inc. Laminating adhesive, laminate including the same, and method of making a laminate
US8202932B2 (en) * 2004-12-03 2012-06-19 Loctite (R&D) Limited Adhesive bonding systems having adherence to low energy surfaces
JP5242168B2 (ja) * 2005-01-04 2013-07-24 ダウ・コーニング・コーポレイション 有機硅素官能性硼素アミン触媒錯体およびこれから調製された硬化性組成物
EP1833864B1 (de) * 2005-01-04 2013-06-12 Dow Corning Corporation Durch organoboran-amin-komplexe gehärtete siloxane und silane
EP1913040B1 (de) 2005-02-16 2021-03-31 Dow Silicones Corporation Polymerteilchen und verkapselte zusammensetzungen unter verwendung von organoboran-amin-komplexen
US7408012B1 (en) 2005-04-18 2008-08-05 Loctite (R&D) Limited Adhesive bonding systems having adherence to low energy surfaces
WO2007064374A2 (en) * 2005-08-12 2007-06-07 Sugarcrm, Inc. Customer relationship management system and method
WO2007040794A1 (en) * 2005-09-21 2007-04-12 Dow Corning Corporation Ambient lithographic method using organoborane amine complexes
EP1934296A1 (de) 2005-10-07 2008-06-25 Dow Gloval Technologies Inc. Amido-organoborat-initiatorsysteme
US7682663B2 (en) * 2006-02-23 2010-03-23 Bowling Green State University Remote curing of polymer coating by gaseous, vaporous or aerosol initiating agent
US20070236049A1 (en) * 2006-03-31 2007-10-11 Dow Global Technologies Inc. Modular assembly for a vehicle
CN101506308B (zh) * 2006-06-20 2011-09-14 道康宁公司 可固化有机硅组合物
US7887668B2 (en) * 2006-08-30 2011-02-15 Dow Global Technologies Inc. Amine organoborane polymerizable compostion and uses therefor
US7524907B2 (en) 2006-10-12 2009-04-28 Dow Global Technologies, Inc. Accelerated organoborane initiated polymerizable compositions
US20080103274A1 (en) * 2006-10-12 2008-05-01 Jialanella Gary L Accelerated organoborane initiated polymerizable compositions
US20080299317A1 (en) * 2007-05-29 2008-12-04 Hable Christopher T Acrylate adhesive material and method of use therefor
CN101925664B (zh) * 2007-12-27 2013-05-29 3M创新有限公司 脲基压敏粘合剂
US8742050B2 (en) * 2008-03-28 2014-06-03 Henkel US IP LLC Two part hybrid adhesive
KR101665534B1 (ko) 2008-07-28 2016-10-13 다우 코닝 코포레이션 복합 물품
US20110104508A1 (en) * 2008-08-29 2011-05-05 Dow Global Technologies Inc. Adhesive for bonding to flexible polymer surfaces
CN102197039A (zh) 2008-10-23 2011-09-21 陶氏环球技术有限责任公司 用于有机硼烷化合物的封闭剂
KR101747980B1 (ko) 2009-05-15 2017-06-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 우레탄계 감압 접착제
US8080594B2 (en) * 2010-04-16 2011-12-20 Thomas R. Haddix Time-release dental adhesive
SG187933A1 (en) * 2010-08-26 2013-03-28 3M Innovative Properties Co Double-sided multi-layer adhesive
EP2635625B1 (de) 2010-11-01 2016-11-30 Dow Brasil S.A. Polyolefine mit einer oder mehreren modifizierten oberflächen zur besseren anhaftung von funktionellen polyisocyanat-haftstoffen
CN103180402B (zh) * 2010-11-05 2015-09-23 3M创新有限公司 具有防滑性质的有机硅改性粘合剂
GB2491170B (en) 2011-05-26 2013-11-06 Henkel Ireland Ltd Two-part polymerisable compositions
KR20140024467A (ko) * 2011-06-23 2014-02-28 쓰리엠 이노베이티브 프로퍼티즈 컴파니 도로 표지 조성물 시스템
EP2935468B1 (de) 2012-12-20 2020-02-26 3M Innovative Properties Company Triorganoboran-amino-funktionalisierte nanopartikel, zusammensetzungen und verfahren
EP3013868B1 (de) 2013-06-28 2017-10-18 3M Innovative Properties Company Säuremodifizierte nanopartikel, polymerisierbare zwei-komponenten-zusammensetzungen und verfahren
BR112016013079B1 (pt) 2013-12-11 2022-05-10 Sika Technology Ag Método para o tratamento de substratos, estrutura composta, uso de uma composição compreendendo um alquilborano, método para emenda de correias elásticas, e correia elástica
US9757898B2 (en) 2014-08-18 2017-09-12 Lord Corporation Method for low temperature bonding of elastomers
EP3103847A1 (de) 2015-06-10 2016-12-14 Sika Technology AG Verbindung von fugenbändern
EP3464495A4 (de) 2016-05-27 2020-03-04 IPS Corporation Klebstoffzusammensetzungen mit polyharnstoff-poly(meth)acrylat-interpenetrierendem polymernetz und verfahren zur verwendung davon
JP6851380B2 (ja) * 2016-08-09 2021-03-31 株式会社イーテック ２液混合型接着剤
CN114797328A (zh) 2017-08-31 2022-07-29 唐纳森公司 过滤器滤芯；空气滤清器组件；外壳；特征；部件；以及方法
CA3074424C (en) * 2017-08-31 2022-03-22 Hercules Llc Urethane acrylate hybrid structure adhesives
KR20210095872A (ko) * 2018-11-27 2021-08-03 가부시끼가이샤 이테크 2액 혼합형 접착제
GB2580162B (en) 2018-12-21 2022-07-13 Henkel IP & Holding GmbH One-part photocurable (meth) acrylate compositions
FR3098818B1 (fr) 2019-07-18 2021-06-25 Bostik Sa Composition adhésive bi-composante comprenant un complexe organoborane-amine
FR3109383B1 (fr) 2020-04-16 2022-05-06 Bostik Sa Composition bi-composante et utilisations
CN113861376A (zh) 2020-06-30 2021-12-31 科思创德国股份有限公司 用于制备复合材料的聚氨酯组合物
CN113736424A (zh) * 2021-09-30 2021-12-03 烟台德邦科技股份有限公司 一种单组分热固性聚氨酯结构胶及其制备方法

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2985633A (en) * 1958-10-30 1961-05-23 Union Carbide Corp Polymerization of ethylene with organoboron compounds treated with oxygen
BE599646A (de) * 1960-02-02
US3340193A (en) * 1960-12-30 1967-09-05 Monsanto Co Mineral oil containing alkyl polymethacrylate antifoamant
US3275611A (en) * 1960-12-30 1966-09-27 Monsanto Co Process for polymerizing unsaturated monomers with a catalyst comprising an organoboron compound, a peroxygen compound and an amine
US3141862A (en) * 1961-03-01 1964-07-21 Exxon Research Engineering Co Graft copolymerization using boron alkyls in the presence of oxygen as catalysts
US3257360A (en) * 1961-07-27 1966-06-21 Monsanto Co Terpolymers and processes for making same
GB1113723A (en) * 1964-05-21 1968-05-15 Minnesota Mining & Mfg Dental filling material
BE674405A (de) * 1965-01-06 1966-06-28
US3425988A (en) * 1965-01-27 1969-02-04 Loctite Corp Polyurethane polyacrylate sealant compositions
BE524840A (de) * 1965-12-17
US3418260A (en) * 1966-01-20 1968-12-24 Du Pont Imidazole-borane polymers
US3527737A (en) * 1967-09-15 1970-09-08 G C Kagaku Kogyo Kk Adhesive compositions
JPS4616888Y1 (de) * 1968-02-15 1971-06-12
JPS4818928B1 (de) * 1969-12-13 1973-06-09
JPS5137092B2 (de) * 1972-04-28 1976-10-13
US4043982A (en) * 1972-05-29 1977-08-23 Loctite (Ireland) Limited Peroxide initiated polymerizable acrylate-isocyanate monomer compositions
US3853818A (en) * 1973-01-22 1974-12-10 Air Prod & Chem Aminoborate esters as polyurethane catalysts
DE2557858A1 (de) * 1975-12-22 1977-06-30 Ver Foerderung Inst Kunststoff Verfahren zum herstellen von polyurethan-harzen, insbesondere von polyurethan-schaeumen
JPS53102394A (en) * 1977-02-18 1978-09-06 Hitachi Ltd Two-pack type resin composition
US4167616A (en) * 1977-08-22 1979-09-11 Rohm And Haas Company Polymerization with diborane adducts or oligomers of boron-containing monomers
DE3207263A1 (de) * 1982-03-01 1983-09-08 Henkel KGaA, 4000 Düsseldorf Organo-borverbindungen enthaltende stoffgemische, verfahren zu ihrer herstellung und ihre verwendung
DE3201780A1 (de) * 1982-01-21 1983-08-25 Henkel KGaA, 4000 Düsseldorf Neue polymere organo-borverbindungen und ihre verwendung
DE3201731A1 (de) * 1982-01-21 1983-07-28 Henkel KGaA, 4000 Düsseldorf "aerob haertende kunststoffmassen"
DE3207264A1 (de) * 1982-03-01 1983-09-08 Henkel KGaA, 4000 Düsseldorf Neue boralkylverbindungen, verfahren zu ihrer herstellung und ihre verwendung
US4731416A (en) * 1984-10-01 1988-03-15 The Dow Chemical Company Polyurethane-type adhesives containing nonaqueous solutions of acrylate polymers
DE3518965A1 (de) * 1985-05-25 1986-11-27 Henkel KGaA, 40589 Düsseldorf Schmelzbare und dabei aerob aushaertende kunststoffmassen und verfahren zu ihrer herstellung
US4656229A (en) * 1985-12-02 1987-04-07 National Starch And Chemical Corporation Anaerobic adhesive compositions
US4684538A (en) * 1986-02-21 1987-08-04 Loctite Corporation Polysiloxane urethane compounds and adhesive compositions, and method of making and using the same
US5021507A (en) * 1986-05-05 1991-06-04 National Starch And Chemical Investment Holding Corporation Arcylic modified reactive urethane hot melt adhesive compositions
JP2528098B2 (ja) * 1986-06-06 1996-08-28 三井石油化学工業株式会社 セラミックス用接着剤
CA1292591C (en) * 1986-10-30 1991-11-26 Takeshi Sakashita Curable composition
US4721751A (en) * 1987-03-26 1988-01-26 Ppg Industries, Inc. Polyurea-polyurethane acrylate dispersions
JPH075680B2 (ja) * 1987-07-03 1995-01-25 三井石油化学工業株式会社 硬化性組成物
JP2811839B2 (ja) * 1989-12-06 1998-10-15 三井化学株式会社 歯科用チタンまたはその合金用硬化性接着剤組成物
JP2812527B2 (ja) * 1990-03-15 1998-10-22 三井化学株式会社 歯科接着剤用触媒ペースト状組成物
CA2048232A1 (en) * 1990-09-05 1992-03-06 Jerry W. Williams Energy curable pressure-sensitive compositions
US5143884A (en) * 1991-04-29 1992-09-01 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5106928A (en) * 1991-04-29 1992-04-21 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
JPH05235089A (ja) * 1992-02-26 1993-09-10 Fujitsu Ltd フェイスダウン実装用半導体チップ
US5286821A (en) * 1992-03-17 1994-02-15 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5401805A (en) * 1992-04-06 1995-03-28 The Penn State Research Foundation Olefin graft copolymers prepared using borane-containing olefin backbone polymers
US5310835A (en) * 1993-09-30 1994-05-10 National Starch And Chemical Investment Holding Corporation Transparent two-part acrylic adhesive composition and the method of use thereof
BR9408536A (pt) * 1994-02-22 1997-08-05 Minnesota Mining & Mfg Composição acrílica polimerizável compósito ligado processo para ligar entre si adesivamente dois substratos e para melhorar a adesão de um adesivo subsequentemente aplicado em um substrato de fluoroplástico
US5621143A (en) * 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5616796A (en) * 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5686544A (en) * 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith

Also Published As

Publication number Publication date
DE69613378D1 (de) 2001-07-19
CN1100806C (zh) 2003-02-05
CA2229166A1 (en) 1997-02-27
EP0843695A1 (de) 1998-05-27
US6008308A (en) 1999-12-28
MX9800917A (es) 1998-05-31
JP4134302B2 (ja) 2008-08-20
CN1192756A (zh) 1998-09-09
WO1997007151A1 (en) 1997-02-27
BR9609933A (pt) 1999-06-08
JPH11510845A (ja) 1999-09-21
AU6482296A (en) 1997-03-12
EP0843695B1 (de) 2001-06-13
US5994484A (en) 1999-11-30
US5686544A (en) 1997-11-11
US6093778A (en) 2000-07-25

Similar Documents

Publication Publication Date Title
DE69613378D1 (de) Organoboran-polyamin-komplex initiator systeme sowie damit hergestellte polymerisierbare zusammensetzungen
DE69716630T2 (de) Organoboran-aminkomplex initiatorsysteme und daraus hergestellte polymerisierbare zusammensetzungen
DE69514693D1 (de) Polymer-polyol sowie vorgeformte stabilisierungssysteme
DE69419947D1 (de) Pfropfpolymerisation
AU5617796A (en) Concrete accelerators
DE69633924D1 (de) Statistische toleranzberechnung
DE59610442D1 (de) Schalldämpfungsvorrichtung
DE69823562T2 (de) Initiatorsystem sowie damit hergestellte polymerisierbare zusammensetzungen
DE59610024D1 (de) Trennmaschine
ATA8095A (de) Laminatbauteil
DE69636966D1 (de) Radiofrequenz-Teilchenbeschleuniger
DE69604968D1 (de) Wagenblockierkeil
BR9610193A (pt) 4-Tiocarbamoil-1-(2-Pirazolil)-pirazóis
DE29617394U1 (de) Bauelement, insbesondere Baustein
DE59306740D1 (de) Feuerwerkskörper, insbesondere Bühnenfeuerwerk
DE29502314U1 (de) Regalsystem
DE29502279U1 (de) Absperrhahn
KR970027081U (ko) 안전 귀마개
DE59607139D1 (de) Küchengerät
KR970000107U (ko) 유압 냉면기
ES1029711Y (es) Trueno pirotecnico.
DE29508468U1 (de) Abwehr-Einrichtung
KR960030005U (ko) 인삼밭 덧발
DE29503539U1 (de) Wantenspanner
KR970047684U (ko) 가변 감쇄기

Legal Events

Date Code Title Description
8364 No opposition during term of opposition