DE69426182T2 - Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte - Google Patents
Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene ProdukteInfo
- Publication number
- DE69426182T2 DE69426182T2 DE69426182T DE69426182T DE69426182T2 DE 69426182 T2 DE69426182 T2 DE 69426182T2 DE 69426182 T DE69426182 T DE 69426182T DE 69426182 T DE69426182 T DE 69426182T DE 69426182 T2 DE69426182 T2 DE 69426182T2
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- preparation
- products obtained
- obtained therefrom
- elastomeric copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/902—Monomer polymerized in bulk in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI931963A IT1271407B (it) | 1993-09-13 | 1993-09-13 | Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69426182D1 DE69426182D1 (de) | 2000-11-30 |
DE69426182T2 true DE69426182T2 (de) | 2001-05-17 |
Family
ID=11366888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69426182T Expired - Fee Related DE69426182T2 (de) | 1993-09-13 | 1994-08-29 | Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte |
Country Status (17)
Country | Link |
---|---|
US (2) | US6046287A (de) |
EP (1) | EP0643079B1 (de) |
JP (1) | JP3703865B2 (de) |
KR (1) | KR950008546A (de) |
CN (1) | CN1055481C (de) |
AT (1) | ATE197160T1 (de) |
AU (1) | AU688349B2 (de) |
CA (1) | CA2131939A1 (de) |
DE (1) | DE69426182T2 (de) |
ES (1) | ES2152280T3 (de) |
FI (1) | FI944192A (de) |
GR (1) | GR3034812T3 (de) |
IL (1) | IL110903A (de) |
IT (1) | IT1271407B (de) |
MY (1) | MY112105A (de) |
RU (1) | RU2143441C1 (de) |
TW (1) | TW396162B (de) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1273660B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propilene |
IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
TW434291B (en) * | 1996-05-28 | 2001-05-16 | Mitsui Chemicals Inc | Ethylene random copolymer, process for its preparation and rubber composition |
WO1998020045A1 (en) * | 1996-11-01 | 1998-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Reduction of fouling in olefin polymerization systems |
US6225427B1 (en) | 1998-10-15 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst |
US20040192816A1 (en) * | 2001-04-13 | 2004-09-30 | Maurizio Galimberti | Product in subdivided form for preparing crosslinkable elastomeric compositions |
WO2002083432A1 (en) * | 2001-04-13 | 2002-10-24 | Pirelli Pneumatici S.P.A. | Tyre with high roadholding, tread band and elastomeric composition used therein |
DE60201086T2 (de) * | 2001-04-13 | 2005-09-22 | Pirelli Pneumatici S.P.A. | Reifen,der ein ethylen-copolymer enthält, lauffläche und darin benutzte elastomermischung |
JP2004523644A (ja) * | 2001-04-13 | 2004-08-05 | ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ | 架橋性エラストマー組成物を調製するための細分割形態の生成物 |
KR20040023813A (ko) * | 2001-07-25 | 2004-03-19 | 피렐리 뉴아티씨 소시에떼 퍼 아찌오니 | 엘라스토머 혼합물의 연속제조 공정 및 장치 |
EP1298148A1 (de) * | 2001-09-27 | 2003-04-02 | Atofina Research S.A. | Katalysatorbestandteil, der ein Metallocen mit zwei Tetrahydroindenyl-Liganden enthält, zur Herstellung eines Polyolefins |
BR0116626A (pt) * | 2001-10-30 | 2003-12-23 | Pirelli | Pneumático para rodas de veìculo, composição elastomérica, banda de rodagem para pneumáticos de roda de veìculo, e, artigo fabricado elastomérico reticulado |
US7964128B2 (en) | 2001-12-19 | 2011-06-21 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
CA2482830C (en) * | 2002-04-29 | 2012-12-18 | Pirelli & C. S.P.A. | Fire resistant cable |
KR100958128B1 (ko) * | 2002-07-11 | 2010-05-18 | 피렐리 타이어 소시에떼 퍼 아찌오니 | 연속적으로 엘라스토머 조성물을 생산하는 생산방법 및 장치 |
DE10250025A1 (de) | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe |
KR101262305B1 (ko) * | 2009-07-01 | 2013-05-08 | 주식회사 엘지화학 | 전이금속 촉매를 이용한 탄성 중합체의 제조방법 |
EP2543684B1 (de) * | 2011-07-07 | 2016-12-21 | Borealis AG | Verfahren zur Herstellung von isotaktischem Polypropylen |
RU2510646C2 (ru) * | 2012-06-26 | 2014-04-10 | Дэлим Индастриал Ко, Лтд. | Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина |
KR101391692B1 (ko) | 2012-11-14 | 2014-05-07 | 주식회사 엘지화학 | 3원계 탄성 공중합체 및 이의 제조 방법 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4668834B1 (en) * | 1985-10-16 | 1996-05-07 | Uniroyal Chem Co Inc | Low molecular weight ethylene-alphaolefin copolymer intermediates |
IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5229478A (en) * | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
US5001205A (en) * | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
CA1327673C (en) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
JPH0445110A (ja) * | 1990-06-12 | 1992-02-14 | Japan Synthetic Rubber Co Ltd | エチレン系共重合体の製造方法 |
ATE147761T1 (de) * | 1990-06-22 | 1997-02-15 | Exxon Chemical Patents Inc | Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation |
JP3193066B2 (ja) * | 1991-05-02 | 2001-07-30 | 三菱化学株式会社 | プロピレンランダム共重合体の製造法 |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
DE69310390T2 (de) * | 1992-01-23 | 1997-10-23 | Mitsui Petrochemical Ind | Verfahren zur Herstellung eines Polyolefins |
IT1254547B (it) * | 1992-03-23 | 1995-09-25 | Montecatini Tecnologie Srl | Copolimeri elastomerici dell'etilene con alfa-olefine. |
ATE195326T1 (de) * | 1992-06-18 | 2000-08-15 | Montell Technology Company Bv | Katalysator zur olefinpolymerisation |
KR100280253B1 (ko) * | 1992-06-18 | 2001-02-01 | 간디 지오프레이 에이치. | 에틸렌 중합체의 제조방법 |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
EP0692516A1 (de) * | 1994-07-15 | 1996-01-17 | Hans-Joachim Burger | Massgenauer thermoplastischer syntaktischer Schaum |
-
1993
- 1993-09-13 IT ITMI931963A patent/IT1271407B/it active IP Right Grant
-
1994
- 1994-08-29 AT AT94113512T patent/ATE197160T1/de not_active IP Right Cessation
- 1994-08-29 EP EP94113512A patent/EP0643079B1/de not_active Expired - Lifetime
- 1994-08-29 ES ES94113512T patent/ES2152280T3/es not_active Expired - Lifetime
- 1994-08-29 DE DE69426182T patent/DE69426182T2/de not_active Expired - Fee Related
- 1994-09-06 TW TW083108202A patent/TW396162B/zh not_active IP Right Cessation
- 1994-09-09 AU AU72870/94A patent/AU688349B2/en not_active Ceased
- 1994-09-09 IL IL11090394A patent/IL110903A/xx not_active IP Right Cessation
- 1994-09-09 MY MYPI94002379A patent/MY112105A/en unknown
- 1994-09-12 FI FI944192A patent/FI944192A/fi unknown
- 1994-09-12 RU RU94033097A patent/RU2143441C1/ru active
- 1994-09-13 JP JP21928494A patent/JP3703865B2/ja not_active Expired - Fee Related
- 1994-09-13 CN CN94115881A patent/CN1055481C/zh not_active Expired - Fee Related
- 1994-09-13 KR KR1019940023099A patent/KR950008546A/ko not_active Application Discontinuation
- 1994-09-13 CA CA002131939A patent/CA2131939A1/en not_active Abandoned
-
1997
- 1997-04-03 US US08/825,660 patent/US6046287A/en not_active Expired - Fee Related
-
2000
- 2000-02-07 US US09/499,481 patent/US6262215B1/en not_active Expired - Fee Related
- 2000-11-10 GR GR20000402499T patent/GR3034812T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
IL110903A (en) | 2000-06-01 |
US6262215B1 (en) | 2001-07-17 |
FI944192A0 (fi) | 1994-09-12 |
IT1271407B (it) | 1997-05-28 |
EP0643079A2 (de) | 1995-03-15 |
GR3034812T3 (en) | 2001-02-28 |
RU2143441C1 (ru) | 1999-12-27 |
US6046287A (en) | 2000-04-04 |
JP3703865B2 (ja) | 2005-10-05 |
ATE197160T1 (de) | 2000-11-15 |
RU94033097A (ru) | 1996-07-20 |
JPH07149834A (ja) | 1995-06-13 |
EP0643079B1 (de) | 2000-10-25 |
AU688349B2 (en) | 1998-03-12 |
TW396162B (en) | 2000-07-01 |
FI944192A (fi) | 1995-03-14 |
KR950008546A (ko) | 1995-04-19 |
ITMI931963A1 (it) | 1995-03-13 |
EP0643079A3 (de) | 1995-04-26 |
ES2152280T3 (es) | 2001-02-01 |
CN1055481C (zh) | 2000-08-16 |
CA2131939A1 (en) | 1995-03-14 |
IL110903A0 (en) | 1994-11-28 |
DE69426182D1 (de) | 2000-11-30 |
ITMI931963A0 (it) | 1993-09-13 |
CN1102415A (zh) | 1995-05-10 |
AU7287094A (en) | 1995-03-23 |
MY112105A (en) | 2001-04-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8328 | Change in the person/name/address of the agent |
Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN |
|
8328 | Change in the person/name/address of the agent |
Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC |
|
8328 | Change in the person/name/address of the agent |
Representative=s name: DERZEIT KEIN VERTRETER BESTELLT |
|
8339 | Ceased/non-payment of the annual fee |