DE69426182D1 - Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte - Google Patents

Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte

Info

Publication number
DE69426182D1
DE69426182D1 DE69426182T DE69426182T DE69426182D1 DE 69426182 D1 DE69426182 D1 DE 69426182D1 DE 69426182 T DE69426182 T DE 69426182T DE 69426182 T DE69426182 T DE 69426182T DE 69426182 D1 DE69426182 D1 DE 69426182D1
Authority
DE
Germany
Prior art keywords
ethylene
preparation
products obtained
obtained therefrom
elastomeric copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69426182T
Other languages
English (en)
Other versions
DE69426182T2 (de
Inventor
Maurizio Galimberti
Enrico Albizzati
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of DE69426182D1 publication Critical patent/DE69426182D1/de
Application granted granted Critical
Publication of DE69426182T2 publication Critical patent/DE69426182T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/902—Monomer polymerized in bulk in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers
DE69426182T 1993-09-13 1994-08-29 Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte Expired - Fee Related DE69426182T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI931963A IT1271407B (it) 1993-09-13 1993-09-13 Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti

Publications (2)

Publication Number Publication Date
DE69426182D1 true DE69426182D1 (de) 2000-11-30
DE69426182T2 DE69426182T2 (de) 2001-05-17

Family

ID=11366888

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69426182T Expired - Fee Related DE69426182T2 (de) 1993-09-13 1994-08-29 Verfahren zur Herstellung von elastomeren Copolymeren des Ethylens und daraus erhaltene Produkte

Country Status (17)

Country Link
US (2) US6046287A (de)
EP (1) EP0643079B1 (de)
JP (1) JP3703865B2 (de)
KR (1) KR950008546A (de)
CN (1) CN1055481C (de)
AT (1) ATE197160T1 (de)
AU (1) AU688349B2 (de)
CA (1) CA2131939A1 (de)
DE (1) DE69426182T2 (de)
ES (1) ES2152280T3 (de)
FI (1) FI944192A (de)
GR (1) GR3034812T3 (de)
IL (1) IL110903A (de)
IT (1) IT1271407B (de)
MY (1) MY112105A (de)
RU (1) RU2143441C1 (de)
TW (1) TW396162B (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
TW434291B (en) * 1996-05-28 2001-05-16 Mitsui Chemicals Inc Ethylene random copolymer, process for its preparation and rubber composition
WO1998020045A1 (en) * 1996-11-01 1998-05-14 Union Carbide Chemicals & Plastics Technology Corporation Reduction of fouling in olefin polymerization systems
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US20040192816A1 (en) * 2001-04-13 2004-09-30 Maurizio Galimberti Product in subdivided form for preparing crosslinkable elastomeric compositions
JP2004523644A (ja) * 2001-04-13 2004-08-05 ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ 架橋性エラストマー組成物を調製するための細分割形態の生成物
US20040144466A1 (en) * 2001-04-13 2004-07-29 Maurizio Galimberti Tyre comprising an ethylene copolymer, tread band and elastomeric composition used therein
EP1385708B1 (de) * 2001-04-13 2004-10-13 PIRELLI PNEUMATICI Società per Azioni Reifen mit hoher strassenhaftung, lauffläche und darin benutzte elastomermischung
JP2004535319A (ja) * 2001-07-25 2004-11-25 ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ エラストマー性組成物を連続的に製造するための方法および装置
EP1298148A1 (de) * 2001-09-27 2003-04-02 Atofina Research S.A. Katalysatorbestandteil, der ein Metallocen mit zwei Tetrahydroindenyl-Liganden enthält, zur Herstellung eines Polyolefins
WO2003037655A1 (en) * 2001-10-30 2003-05-08 Pirelli Pneumatici S.P.A. Tyre with low rolling resistance, tread band and elastomeric composition used therein
US7964128B2 (en) 2001-12-19 2011-06-21 Pirelli Pneumatici S.P.A. Process and apparatus for continuously producing an elastomeric composition
CA2482830C (en) * 2002-04-29 2012-12-18 Pirelli & C. S.P.A. Fire resistant cable
RU2290303C2 (ru) * 2002-07-11 2006-12-27 Пирелли Пнеуматичи С.П.А. Способ и устройство для непрерывного получения эластомерной композиции
DE10250025A1 (de) 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe
KR101262305B1 (ko) * 2009-07-01 2013-05-08 주식회사 엘지화학 전이금속 촉매를 이용한 탄성 중합체의 제조방법
EP2543684B1 (de) 2011-07-07 2016-12-21 Borealis AG Verfahren zur Herstellung von isotaktischem Polypropylen
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
KR101391692B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668834B1 (en) * 1985-10-16 1996-05-07 Uniroyal Chem Co Inc Low molecular weight ethylene-alphaolefin copolymer intermediates
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5229478A (en) * 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
JPH0445110A (ja) * 1990-06-12 1992-02-14 Japan Synthetic Rubber Co Ltd エチレン系共重合体の製造方法
BR9106589A (pt) * 1990-06-22 1993-06-01 Exxon Chemical Patents Inc Catalisadores de monociclopentadienil metaloceno isentos de aluminio para a polimerizacao de olefinas
JP3193066B2 (ja) * 1991-05-02 2001-07-30 三菱化学株式会社 プロピレンランダム共重合体の製造法
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
EP0552945B1 (de) * 1992-01-23 1997-05-07 Mitsui Petrochemical Industries, Ltd. Verfahren zur Herstellung eines Polyolefins
IT1254547B (it) * 1992-03-23 1995-09-25 Montecatini Tecnologie Srl Copolimeri elastomerici dell'etilene con alfa-olefine.
AU660808B2 (en) * 1992-06-18 1995-07-06 Montell Technology Company B.V. Catalysts for the polymerization of olefins
JPH08501325A (ja) * 1992-06-18 1996-02-13 スペリレーネ エッセ．アール．エッレ． エチレン系ポリマーの製造法
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
EP0692516A1 (de) * 1994-07-15 1996-01-17 Hans-Joachim Burger Massgenauer thermoplastischer syntaktischer Schaum

Also Published As

Publication number Publication date
ES2152280T3 (es) 2001-02-01
GR3034812T3 (en) 2001-02-28
CN1055481C (zh) 2000-08-16
IL110903A0 (en) 1994-11-28
JP3703865B2 (ja) 2005-10-05
ATE197160T1 (de) 2000-11-15
US6046287A (en) 2000-04-04
CA2131939A1 (en) 1995-03-14
MY112105A (en) 2001-04-30
ITMI931963A1 (it) 1995-03-13
US6262215B1 (en) 2001-07-17
IT1271407B (it) 1997-05-28
KR950008546A (ko) 1995-04-19
FI944192A0 (fi) 1994-09-12
EP0643079B1 (de) 2000-10-25
CN1102415A (zh) 1995-05-10
AU7287094A (en) 1995-03-23
EP0643079A3 (de) 1995-04-26
EP0643079A2 (de) 1995-03-15
AU688349B2 (en) 1998-03-12
ITMI931963A0 (it) 1993-09-13
RU2143441C1 (ru) 1999-12-27
FI944192A (fi) 1995-03-14
IL110903A (en) 2000-06-01
DE69426182T2 (de) 2001-05-17
JPH07149834A (ja) 1995-06-13
TW396162B (en) 2000-07-01
RU94033097A (ru) 1996-07-20

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8328 Change in the person/name/address of the agent

Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8328 Change in the person/name/address of the agent

Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC

8328 Change in the person/name/address of the agent

Representative=s name: DERZEIT KEIN VERTRETER BESTELLT

8339 Ceased/non-payment of the annual fee