DE69020055D1 - Verfahren zur Oxidation aliphatischer Kohlenwasserstoffe in Gegenwart eines festen heterogenen Katalysators und Katalysator. - Google Patents

Verfahren zur Oxidation aliphatischer Kohlenwasserstoffe in Gegenwart eines festen heterogenen Katalysators und Katalysator.

Info

Publication number
DE69020055D1
DE69020055D1 DE69020055T DE69020055T DE69020055D1 DE 69020055 D1 DE69020055 D1 DE 69020055D1 DE 69020055 T DE69020055 T DE 69020055T DE 69020055 T DE69020055 T DE 69020055T DE 69020055 D1 DE69020055 D1 DE 69020055D1
Authority
DE
Germany
Prior art keywords
catalyst
oxidation
aliphatic hydrocarbons
aliphatic hydrocarbon
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69020055T
Other languages
English (en)
Other versions
DE69020055T2 (de
Inventor
Bijan Khazai
Edwin G Vrieland
Graig B Murchison
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69020055D1 publication Critical patent/DE69020055D1/de
Application granted granted Critical
Publication of DE69020055T2 publication Critical patent/DE69020055T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2214/00—Nature of the non-vitreous component
    • C03C2214/04—Particles; Flakes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
DE69020055T 1989-07-20 1990-07-19 Verfahren zur Oxidation aliphatischer Kohlenwasserstoffe in Gegenwart eines festen heterogenen Katalysators und Katalysator. Expired - Fee Related DE69020055T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/383,107 US4973791A (en) 1989-07-20 1989-07-20 Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
US07/505,751 US5146031A (en) 1989-07-20 1990-04-06 Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition

Publications (2)

Publication Number Publication Date
DE69020055D1 true DE69020055D1 (de) 1995-07-20
DE69020055T2 DE69020055T2 (de) 1995-09-21

Family

ID=27010048

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69020055T Expired - Fee Related DE69020055T2 (de) 1989-07-20 1990-07-19 Verfahren zur Oxidation aliphatischer Kohlenwasserstoffe in Gegenwart eines festen heterogenen Katalysators und Katalysator.

Country Status (11)

Country Link
US (2) US4973791A (de)
EP (1) EP0409355B1 (de)
JP (1) JPH0374335A (de)
KR (1) KR0178978B1 (de)
CN (2) CN1026099C (de)
AT (1) ATE123748T1 (de)
AU (1) AU633942B2 (de)
BR (1) BR9003542A (de)
CA (1) CA2021573C (de)
DE (1) DE69020055T2 (de)
MX (1) MX172821B (de)

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US4814545A (en) * 1988-09-19 1989-03-21 Eastman Kodak Company Process for removing impurities from an aromatic stream
US5302773A (en) * 1989-07-20 1994-04-12 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst encapsulated in a hard, glassy silica matrix
US5258347A (en) * 1989-07-20 1993-11-02 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing a molybdate catalyst composition
US4973791A (en) * 1989-07-20 1990-11-27 The Dow Chemical Company Process of oxidizing aliphatic hydrocarbons employing an alkali-promoted molybdate catalyst
US5258348A (en) * 1989-10-31 1993-11-02 The Dow Chemical Company Supported catalyst for the dehydrogenation of hydrocarbons and method for the preparation of the catalyst
US5276257A (en) * 1992-07-09 1994-01-04 The Dow Chemical Company Process for converting butadiene to styrene or ethylbenzene or both using catalysts containing molybdenum
US5733836A (en) * 1996-03-22 1998-03-31 Phillips Petroleum Company Compositions comprising inorganic oxide and process for producing mercaptans
US6521808B1 (en) * 2000-02-17 2003-02-18 The Ohio State University Preparation and use of a catalyst for the oxidative dehydrogenation of lower alkanes
CN101081362B (zh) * 2006-05-31 2010-09-08 中国石油化工股份有限公司 一种含镁铝复合物的载体及其制备方法
KR101419995B1 (ko) * 2012-01-20 2014-07-15 삼성토탈 주식회사 노르말-부탄의 산화적 탈수소화 반응 촉매용 마그네시아-지르코니아 복합담체의 제조방법, 그에 의해 제조된 마그네시아-지르코니아 복합담체에 담지된 마그네슘 오르소바나데이트 촉매의 제조방법 및 상기 촉매를 이용한 노르말-부텐과 1,3-부타디엔의 제조방법
JP2014177408A (ja) * 2013-03-13 2014-09-25 Mitsubishi Chemicals Corp 共役ジエンの製造方法
KR102497673B1 (ko) * 2015-03-18 2023-02-09 디아이씨 가부시끼가이샤 스피넬 입자 및 그 제조 방법 그리고 상기 스피넬 입자를 포함하는 조성물 및 성형물
JP6061173B1 (ja) * 2016-06-23 2017-01-18 Dic株式会社 スピネル粒子およびその製造方法、並びに前記スピネル粒子を含む組成物および成形物
CN113209965B (zh) * 2021-03-24 2022-08-09 西南化工研究设计院有限公司 一种轻烷烃脱氢制烯烃的催化剂及其制备方法和用途

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Also Published As

Publication number Publication date
US4973791A (en) 1990-11-27
AU633942B2 (en) 1993-02-11
CN1048843A (zh) 1991-01-30
ATE123748T1 (de) 1995-06-15
AU5971690A (en) 1991-01-24
KR0178978B1 (ko) 1999-05-15
CA2021573A1 (en) 1991-01-21
CN1052172C (zh) 2000-05-10
MX172821B (es) 1994-01-14
US5146031A (en) 1992-09-08
EP0409355A1 (de) 1991-01-23
EP0409355B1 (de) 1995-06-14
CN1093948A (zh) 1994-10-26
CN1026099C (zh) 1994-10-05
KR910002743A (ko) 1991-02-26
CA2021573C (en) 2000-11-07
BR9003542A (pt) 1991-11-12
DE69020055T2 (de) 1995-09-21
JPH0374335A (ja) 1991-03-28

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