CN1129649C - 热塑性弹性体和聚烯烃的增容共混物 - Google Patents
热塑性弹性体和聚烯烃的增容共混物 Download PDFInfo
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- CN1129649C CN1129649C CN98810171A CN98810171A CN1129649C CN 1129649 C CN1129649 C CN 1129649C CN 98810171 A CN98810171 A CN 98810171A CN 98810171 A CN98810171 A CN 98810171A CN 1129649 C CN1129649 C CN 1129649C
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- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/69—Polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/04—Polyamides derived from alpha-amino carboxylic acids
Abstract
Description
标号 | 供应商 | 描述 |
Kraton LiquidL2203 | Shell | 羟基封端的聚丁二烯,被氢化。近似微结构:55%1,2;45%1,4。 |
Polytail H | Mitsubishi | 羟基封端的聚丁二烯,被氢化。近似微结构:21%1,2;79%1,4。 |
Polytail HA | Mitsubishi | 羟基封端的聚丁二烯,被氢化。近似微结构:83%1,2;17%1,4。 |
Krasol LBH | Kaucuk AG | 羟基封端的聚丁二烯,被氢化。近似微结构:65%1,2;35%1,4。 |
Liquiflex H | Petroflex | 羟基封端的聚丁二烯,被氢化。近似微结构:22%1,2;78%1,4。 |
实施例25 | 实施例26 | 实施例27 | 实施例28 | 实施例29 | 实施例30 | 实施例31 | 实施例32 | 实施例33 | 实施例34 | 实施例35 | 实施例36 | |
聚酯TPU(1) | 60 | 57 | 57 | 57 | 57 | - | - | 57 | 57 | 57 | 57 | 57 |
聚酯TPU(2) | - | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(3) | - | - | - | - | - | 60 | 57 | - | - | - | - | - |
聚醚TPU(4) | - | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(5) | - | - | - | - | - | - | - | - | - | - | - | - |
Profax 6523(6) | 40 | 38 | 38 | 38 | 38 | 40 | 38 | 38 | 38 | 38 | 38 | 38 |
Rexene 41E2(7) | - | - | - | - | - | - | - | - | - | - | - | - |
Exxelor PO-1015(8) | - | - | - | - | - | - | - | - | - | - | - | - |
Bayon YM312(9) | - | - | - | - | - | - | - | - | - | - | - | - |
Hytrel 5544(10) | - | - | - | - | - | - | - | - | - | - | - | - |
Pebax MV 1074(11) | - | - | - | - | - | - | - | - | - | - | - | - |
实施例1 | - | - | 5 | - | - | - | - | - | - | - | - | - |
实施例2 | - | - | - | 5 | - | - | - | - | - | - | - | - |
实施例3 | - | - | - | - | 5 | - | - | - | - | - | - | - |
实施例4 | - | - | - | - | - | - | 5 | - | - | - | - | - |
实施例5 | - | - | - | - | - | - | - | 5 | - | - | - | - |
实施例6 | - | - | - | - | - | - | - | - | 5 | - | - | - |
实施例7 | - | - | - | - | - | - | - | - | - | 5 | - | - |
实施例8 | - | - | - | - | - | - | - | - | - | - | 5 | - |
实施例25 | 实施例26 | 实施例27 | 实施例28 | 实施例29 | 实施例30 | 实施例31 | 实施例32 | 实施例33 | 实施例34 | 实施例35 | 实施例36 | |
实施例9 | - | - | - | - | - | - | - | - | - | - | - | 5 |
实施例10 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例11 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例12 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例13 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例14 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例15 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例16 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例17 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例18 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例19 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例20 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例21 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例22 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例23 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例24 | - | - | - | - | - | - | - | - | - | - | - | - |
对比例1 | - | - | - | - | - | - | - | - | - | - | - | - |
Kraton Liquid L-2203 | - | - | - | - | - | - | - | - | - | - | - | - |
性能 | 实施例25 | 实施例26 | 实施例27 | 实施例28 | 实施例29 | 实施例30 | 实施例31 | 实施例32 | 实施例33 | 实施例34 | 实施例35 | 实施例36 |
悬臂梁式抗冲性,ft-lbs/inch | 5.4 | 8 | 9.1 | 13.5 | 22 | 2.3 | 8.5 | 19.6 | 20.3 | 20.2 | 17.8 | 16.9 |
弯曲模量psi | - | 95K | 77K | 65K | 61K | 53K | 45K | 64K | 62K | 67K | 65K | 64K |
拉伸强度psi | - | - | - | - | - | - | - | - | - | - | - | - |
伸长率% | - | - | - | - | - | - | - | 254 | 251 | 269 | 271 | 263 |
抗撕性,ft-lbs/inch | - | - | - | - | - | - | - | - | - | - | - | - |
泰伯磨耗,g损失 | - | - | - | - | - | - | - | - | - | - | - | - |
静态衰变+5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | - | - |
静态衰变-5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | - | - |
表面电阻率,ohms | - | - | - | - | - | - | - | - | - | - | - | - |
表面(12) | - | del | del | sl del | v sl del | del | del | - | sl del | sl del | sl del | sl del |
实施例37 | 实施例38 | 实施例39 | 实施例40 | 实施例41 | 实施例42 | 实施例43 | 实施例44 | 实施例45 | 实施例46 | 实施例47 | 实施例48 | |
聚酯TPU(1) | 57 | 57 | 57 | 57 | 57 | 57 | 57 | 57 | 57 | - | - | - |
聚酯TPU(2) | - | - | - | - | - | - | - | - | - | 60 | 57 | 57 |
聚醚TPU(3) | - | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(4) | - | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(5) | 38 | 38 | 38 | 38 | 38 | 38 | 38 | 38 | 38 | - | - | - |
Profax 6523(6) | - | - | - | - | - | - | - | - | - | - | - | - |
Rexene 41E2(7) | - | - | - | - | - | - | - | - | - | 40 | 38 | 38 |
Exxelor PO-1015(8) | - | - | - | - | - | - | - | - | - | - | - | - |
Bayon YM312(9) | - | - | - | - | - | - | - | - | - | - | - | - |
Hytrel 5544(10) | - | - | - | - | - | - | - | - | - | - | - | - |
Pebax MV 1074(11) | - | - | - | - | - | - | - | - | - | - | - | - |
实施例1 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例2 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例3 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例4 | - | - | - | - | - | - | - | - | - | - | - | 5 |
实施例5 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例6 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例7 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例8 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例37 | 实施例38 | 实施例39 | 实施例40 | 实施例41 | 实施例42 | 实施例43 | 实施例44 | 实施例45 | 实施例46 | 实施例47 | 实施例48 | |
实施例9 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例10 | 5 | - | - | - | - | - | - | - | - | - | - | - |
实施例11 | - | 5 | - | - | - | - | - | - | - | - | - | - |
实施例12 | - | - | 5 | - | - | - | - | - | - | - | - | - |
实施例13 | - | - | - | 5 | - | - | - | - | - | - | - | - |
实施例14 | - | - | - | - | 5 | - | - | - | - | - | - | - |
实施例15 | - | - | - | - | - | 5 | - | - | - | - | - | - |
实施例16 | - | - | - | - | - | - | 5 | - | - | - | - | - |
实施例17 | - | - | - | - | - | - | - | 5 | - | - | - | - |
实施例18 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例19 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例20 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例21 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例22 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例23 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例24 | - | - | - | - | - | - | - | - | 5 | - | 5 | - |
对比例1 | - | - | - | - | - | - | - | - | - | - | - | - |
Kraton Liquid L-2203 | - | - | - | - | - | - | - | - | - | - | - | - |
性能 | 实施例37 | 实施例38 | 实施例39 | 实施例40 | 实施例41 | 实施例42 | 实施例43 | 实施例44 | 实施例45 | 实施例46 | 实施例47 | 实施例48 |
悬臂梁式抗冲性,ft-lbs/inch | 19.8 | 10.2 | 14.1 | 11 | 10.6 | 10 | 9.2 | 17.1 | 17.9 | - | - | - |
弯曲模量psi | 61K | 67K | 70K | 61K | 92K | 63K | 83K | 73K | 67K | - | - | - |
拉伸强度psi | - | - | - | - | 4090 | 4720 | 4920 | 4790 | - | 4472 | 4829 | 6012 |
伸长率% | 263 | 266 | 263 | 264 | 258 | 270 | 277 | 266 | 249 | 404 | 439 | 501 |
抗撕性,ft-lbs/inch | - | - | - | - | - | - | - | - | - | 597 | 545 | 717 |
泰伯磨耗,g损失 | - | - | - | - | - | - | - | - | - | 0.61 | 0.26 | 0.14 |
静态衰变+5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | - | - |
静态衰变-5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | - | - |
表面电阻率,ohms | - | - | - | - | - | - | - | - | - | - | - | - |
表面(12) | v sl del | v sl del | v sl del | v sl del | - | - | - | - | sev del | - | - | - |
实施例49 | 实施例50 | 实施例51 | 实施例52 | 实施例53 | 实施例54 | 实施例55 | 实施例56 | 实施例57 | 实施例58 | 实施例59 | 实施例60 | |
聚酯TPU(1) | - | - | - | - | - | - | - | - | - | - | - | - |
聚酯TPU(2) | - | - | - | 60 | 57 | 57 | - | - | - | - | - | - |
聚酯TPU(3) | - | - | - | - | - | - | - | - | - | - | - | - |
聚酯TPU(4) | 60 | 57 | 57 | - | - | - | 60 | 57 | 57 | - | - | - |
聚酯TPU(5) | - | - | - | - | - | - | - | - | - | - | 25 | 25 |
Profax 6523(6) | - | - | - | - | - | - | - | - | - | - | - | - |
Rexene 41E2(7) | 40 | 38 | 38 | 40 | 38 | 38 | 40 | 38 | 38 | 100 | 75 | 69 |
Exxelor PO-1015(8) | - | - | - | - | - | - | - | - | - | - | - | - |
Bayon YM312(9) | - | - | - | - | - | - | - | - | - | - | - | 5 |
Hytrel 5544(10) | - | - | - | - | - | - | - | - | - | - | - | - |
Pebax MV 1074(11) | - | - | - | - | - | - | - | - | - | - | - | - |
实施例1 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例2 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例3 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例4 | - | - | 5 | - | 5 | - | - | 5 | - | - | - | - |
实施例5 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例6 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例7 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例8 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例49 | 实施例50 | 实施例51 | 实施例52 | 实施例53 | 实施例54 | 实施例55 | 实施例56 | 实施例57 | 实施例58 | 实施例59 | 实施例60 | |
实施例9 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例10 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例11 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例12 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例13 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例14 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例15 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例16 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例17 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例18 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例19 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例20 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例21 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例22 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例23 | - | - | - | - | - | - | - | - | - | - | - | - |
实施例24 | - | 5 | - | - | - | - | - | - | - | - | - | - |
对比例1 | - | - | - | - | - | - | - | - | - | - | - | - |
Kraton Liquid L-2203 | - | - | - | - | - | 5 | - | - | 5 | - | - | - |
性能 | 实施例49 | 实施例50 | 实施例51 | 实施例52 | 实施例53 | 实施例54 | 实施例55 | 实施例56 | 实施例57 | 实施例58 | 实施例59 | 实施例60 |
悬臂梁式抗冲性,ft-lbs/inch | - | - | - | - | - | - | - | - | - | O.94 | 1.51 | 2.1 |
弯曲模量psi | - | - | - | - | - | - | - | - | - | - | - | - |
拉伸强度psi | 2855 | 2891 | 3733 | 1267 | 3121 | 1830 | 1528 | 1757 | 1097 | 5400 | 3150 | 3640 |
伸长率% | 471 | 508 | 525 | 29 | 289 | 13 | 14 | 147 | 7 | 16 | 11 | 81 |
抗撕性,ft-lbs/inch | 436 | 338 | 549 | 731 | 821 | 366 | 545 | 742 | 428 | - | - | 927 |
泰伯磨耗,g损失 | 0.54 | 0.53 | 0.44 | - | - | - | - | - | - | - | - | - |
静态衰变+5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | 0.4 | 0.11 |
静态衰变-5,000volts.sec. | - | - | - | - | - | - | - | - | - | - | 0.41 | 0.13 |
表面电阻率,ohms | - | - | - | - | - | - | - | - | - | 3.4E+12 | 3.0E+11 | 1.2E+11 |
表面(12) | - | - | - | - | - | - | - | - | - | - | - | - |
实施例61 | 实施例62 | 实施例63 | 实施例64 | 实施例65 | 实施例66 | 实施例67 | 实施例68 | 实施例69 | 实施例70 | 实施例71 | |
聚酯TPU(1) | - | - | - | - | - | - | - | - | - | - | - |
聚酯TPU(2) | - | - | - | - | - | - | - | - | - | - | - |
聚TPU(3) | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(4) | - | - | - | - | - | - | - | - | - | - | - |
聚醚TPU(5) | 25 | 25 | 25 | 25 | 25 | 25 | - | - | - | - | - |
Profax 6523(6) | - | - | - | - | - | - | - | - | - | - | - |
Rexene 41E2(7) | 69 | 69 | 69 | 69 | 69 | 69 | - | - | - | - | - |
Exxelor PO-1015(8) | - | - | - | - | - | - | - | - | - | - | - |
Bayon YM312(9) | 5 | 5 | 5 | 5 | 5 | 5 | - | - | - | - | - |
Hytrel 5544(10) | - | - | - | - | - | - | - | 25 | 25 | - | - |
Pebax MV 1074(11) | - | - | - | - | - | - | - | - | - | 25 | 25 |
实施例1 | - | - | - | - | - | - | - | - | - | - | - |
实施例2 | - | - | - | - | - | - | - | - | - | - | - |
实施例3 | - | - | - | - | - | - | - | - | - | - | - |
实施例4 | - | - | - | - | - | - | - | - | - | - | - |
实施例5 | - | - | - | - | - | - | - | - | - | - | - |
实施例6 | - | - | - | - | - | - | - | - | - | - | - |
实施例7 | - | - | - | - | - | - | - | - | - | - | - |
实施例8 | - | - | - | - | - | - | - | - | - | - | - |
实施例61 | 实施例62 | 实施例63 | 实施例64 | 实施例65 | 实施例66 | 实施例67 | 实施例68 | 实施例69 | 实施例70 | 实施例71 | |
实施例9 | - | - | - | - | - | - | - | - | - | - | - |
实施例10 | - | - | - | - | - | - | - | - | - | - | - |
实施例11 | - | - | - | - | - | - | - | - | - | - | - |
实施例12 | - | - | - | - | - | - | - | - | - | - | - |
实施例13 | - | - | - | - | - | - | - | - | - | - | - |
实施例14 | - | - | - | - | - | - | - | - | - | - | - |
实施例15 | - | - | - | - | - | - | - | - | - | - | - |
实施例16 | - | - | - | - | - | - | - | - | - | - | - |
实施例17 | - | - | - | - | - | - | - | - | - | - | - |
实施例18 | 1 | - | - | - | - | - | - | - | - | - | - |
实施例19 | - | 1 | - | - | - | - | - | - | - | - | - |
实施例20 | - | - | 1 | - | - | - | - | - | - | - | - |
实施例21 | - | - | - | 1 | - | - | - | - | - | - | - |
实施例22 | - | - | - | - | 1 | - | - | - | - | - | - |
实施例23 | - | - | - | - | - | 1 | - | - | - | - | - |
实施例24 | - | - | - | - | - | - | 1 | - | 1 | - | - |
对比例1 | - | - | - | - | - | - | - | - | - | - | 1 |
Kraton Liquid L-2203 | - | - | - | - | - | - | - | - | - | - | - |
实施例61 | 实施例62 | 实施例63 | 实施例64 | 实施例65 | 实施例66 | 实施例67 | 实施例68 | 实施例69 | 实施例70 | 实施例71 | |
性能 | - | - | - | - | - | - | - | - | - | - | - |
悬臂梁式抗冲性,ft-lbs/inch | 12.3 | 12.9 | 7.7 | 6.28 | 7.09 | 6.45 | - | - | - | - | - |
弯曲模量psi | - | - | - | - | - | - | - | - | - | - | - |
拉伸强度psi | 3620 | 3680 | 3730 | 3880 | 3790 | 3830 | 3720 | 4200 | 4220 | 4260 | 4290 |
伸长率% | 200 | 233 | 295 | 227 | 189 | 238 | 325 | 94 | 146 | 111 | 155 |
抗撕性,ft-lbs/inch | 1118 | 1102 | 1008 | 1119 | 1106 | 1059 | - | - | - | - | - |
泰伯磨耗,g损失 | - | - | - | - | - | - | - | - | - | - | - |
静态衰变+5,000volts.sec. | 0.15 | 0.17 | 0.13 | 0.13 | 0.13 | 0.13 | - | - | - | - | - |
静态衰变-5,000volts.sec. | 0.18 | 0.18 | 0.14 | 0.14 | 0.15 | 0.14 | - | - | - | - | - |
表面电阻率,ohms | 1.6E+11 | 1.9E+11 | 7.8E+10 | 2.3E+11 | 2.2E+11 | 1.9E+11 | - | - | - | - | - |
表面(12) | - | - | - | - | - | - | - | - | - | - | - |
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/951,013 US6054533A (en) | 1997-10-15 | 1997-10-15 | Compatibilized blends of a thermoplastic elastomer and a polyolefin |
US08/951,013 | 1997-10-15 |
Publications (2)
Publication Number | Publication Date |
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CN1275998A CN1275998A (zh) | 2000-12-06 |
CN1129649C true CN1129649C (zh) | 2003-12-03 |
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Application Number | Title | Priority Date | Filing Date |
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CN98810171A Expired - Fee Related CN1129649C (zh) | 1997-10-15 | 1998-06-03 | 热塑性弹性体和聚烯烃的增容共混物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US6054533A (zh) |
EP (1) | EP1023396B1 (zh) |
JP (1) | JP4175775B2 (zh) |
KR (1) | KR100551506B1 (zh) |
CN (1) | CN1129649C (zh) |
AT (1) | ATE231899T1 (zh) |
AU (1) | AU7810998A (zh) |
BR (1) | BR9812915A (zh) |
CA (1) | CA2305744A1 (zh) |
DE (1) | DE69811104T2 (zh) |
ES (1) | ES2191940T3 (zh) |
HK (1) | HK1030006A1 (zh) |
WO (1) | WO1999019406A1 (zh) |
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EP1057864A1 (en) * | 1999-06-04 | 2000-12-06 | Johnson Controls Automotive S.r.l. | A functionalized thermoplastic polymer composition and a process for its preparation |
EP1551919A2 (en) * | 2002-10-07 | 2005-07-13 | PolyOne Corporation | Compatibilized thermoplastic vulcanizate blends and their morphology as determined by atomic force microscopy |
US7279174B2 (en) * | 2003-05-08 | 2007-10-09 | Advanced Cardiovascular Systems, Inc. | Stent coatings comprising hydrophilic additives |
JP2005027781A (ja) * | 2003-07-09 | 2005-02-03 | Sumitomo Rubber Ind Ltd | ゴルフボール |
US20050070665A1 (en) * | 2003-09-26 | 2005-03-31 | Ludlow James M. | Transparent thermoplastic blend of a cycloolefin copolymer and a thermoplastic polyurethane |
JP2008531213A (ja) * | 2005-03-02 | 2008-08-14 | クック インコーポレイテッド | 挿入器シース |
BRPI0617036A2 (pt) * | 2005-09-12 | 2010-07-06 | Dow Global Technologies Inc | composição de etileno/alfa-olefina, artigo, pelìcula, método para preparar uma pelìcula, método para preparar um artigo e componente de calçado |
KR20090077010A (ko) * | 2006-11-01 | 2009-07-13 | 다우 글로벌 테크놀로지스 인크. | 폴리우레탄 조성물 및 그로부터 제조된 물품, 및 그의 제조 방법 |
CN101657476B (zh) * | 2006-12-21 | 2013-02-20 | 陶氏环球技术有限责任公司 | 官能化烯烃聚合物,组合物和由其制备的制品,及其制备方法 |
US20100266799A1 (en) * | 2007-07-12 | 2010-10-21 | Dow Global Technologies Inc. | Prepolymers and polymers for elastomers |
WO2009013559A1 (en) * | 2007-07-23 | 2009-01-29 | Cellectis | Meganuclease variants cleaving a dna target sequence from the human hemoglobin beta gene and uses thereof |
WO2009017868A1 (en) * | 2007-07-27 | 2009-02-05 | Dow Global Technologies Inc. | Compositions of thermoplastic polyurethane (tpu), polybutadiene and polydiene-based tpu |
CN102216389A (zh) * | 2007-08-10 | 2011-10-12 | 拜尔材料科学有限公司 | 热塑性聚氨酯共聚物模塑组合物 |
US8802770B2 (en) * | 2008-01-24 | 2014-08-12 | Lubrizol Advanced Materials, Inc. | Hydrophobic thermoplastic polyurethane |
SG163232A1 (en) * | 2008-01-24 | 2010-08-30 | Lubrizol Advanced Mat Inc | Soft thermoplastic elastomer composition |
BRPI0905902B1 (pt) | 2008-02-08 | 2019-01-29 | Union Carbide Chem Plastic | composição de poliofelina/poliuretano termoplástico retardadora de chama, cabo e artigo extrudado |
EP2294102B1 (en) * | 2008-06-30 | 2013-08-21 | Dow Global Technologies LLC | Polyolefin compositions and articles prepared therefrom and methods of making the same |
BRPI1009579B1 (pt) | 2009-03-18 | 2020-09-15 | Lubrizol Advanced Materials, Inc | Poliuretano termoplástico, processo para fabricar um artigo extrudado, película transparente ou tubo transparente, e, sapato tendo uma gáspea e uma sola |
US9334395B2 (en) | 2009-12-11 | 2016-05-10 | Dow Global Technologies Llc | Thermoplastic polymer blends comprising dynamically crosslinked polyurethane in an olefin polymer matrix |
EP2544775B1 (en) * | 2010-03-10 | 2014-12-24 | NIKE Innovate C.V. | Golf balls using hydrophobic thermoplastic polyurethane as a compatibilizer for polymer blends |
US20110224018A1 (en) | 2010-03-10 | 2011-09-15 | Nike, Inc. | Golf Ball Having Moisture Resistant Layer |
US8822001B2 (en) * | 2010-04-27 | 2014-09-02 | Graham Packaging Company, L.P. | Delamination resistant multilayer containers |
CN102174249B (zh) * | 2010-12-21 | 2012-12-05 | 东华大学 | 一种具有低玻璃化转变温度和高断裂伸长率共混热塑性弹性体及其制备方法 |
CN102796364B (zh) * | 2012-08-24 | 2014-04-02 | 奥斯汀新材料(张家港)有限公司 | 一种sbs共混改性热塑性聚氨酯弹性体及其制备方法 |
CN102964808B (zh) * | 2012-12-04 | 2014-07-09 | 福建思嘉环保材料科技有限公司 | 一种环保tpu薄膜及其制备方法 |
CN103788440A (zh) * | 2014-02-11 | 2014-05-14 | 太仓市晨洲塑业有限公司 | 一种改良性tpr配方 |
BR112017003310A2 (pt) * | 2014-08-18 | 2018-01-23 | Basf Se | polibutadienóis modificados por poliéster para produção de elastômeros de poliuretano e poliuretanos termoplásticos |
EP3545040B1 (en) * | 2016-09-23 | 2023-03-15 | The University of Massachusetts | Polyurethane, method of preparation, and article comprising the polyurethane |
CN110506065B (zh) * | 2017-04-12 | 2023-01-24 | 巴斯夫欧洲公司 | 热塑性聚氨酯和复合制品 |
EP4141077A1 (en) * | 2018-12-20 | 2023-03-01 | ACTEGA DS GmbH | Thermoplastic elastomer composition |
US20220289971A1 (en) * | 2019-09-10 | 2022-09-15 | Lubrizol Advanced Materials, Inc. | Thermoplastic polyurethane composition |
CN112759895A (zh) * | 2021-01-20 | 2021-05-07 | 昶力管业(常州)有限公司 | 一种聚酰胺弹性体改性的热缩护套管及其制备方法 |
CN113582821B (zh) * | 2021-09-07 | 2024-02-27 | 泛亚(武汉)食品科技有限公司 | 一种8-甲基癸醛的制备方法 |
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US4567236A (en) * | 1983-07-18 | 1986-01-28 | The Upjohn Co. | Novel polymer blends |
US5242977A (en) * | 1986-07-08 | 1993-09-07 | Bayer Aktiengesellschaft | Poly-α-olefin/polyurethane block copolymers, processes for their production and their use |
JPH0425566A (ja) * | 1990-05-21 | 1992-01-29 | Sanyo Chem Ind Ltd | 樹脂組成物 |
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US5358981A (en) * | 1992-12-07 | 1994-10-25 | Shell Oil Company | Solvent-free water-based emulsions of anionically polymerized polymers |
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EP0641828A1 (en) * | 1993-09-08 | 1995-03-08 | Bayer Corporation | A thermoplastic composition containing polyurethane and polypropylene |
EP0657502A1 (en) * | 1993-12-13 | 1995-06-14 | Du Pont De Nemours International S.A. | Thermoplastic composition containing compatibilizer |
US5486570A (en) * | 1994-09-29 | 1996-01-23 | Shell Oil Company | Polyurethane sealants and adhesives containing saturated hydrocarbon polyols |
US5576388A (en) * | 1994-10-11 | 1996-11-19 | Shell Oil Company | Telechelic polymers and heterotelechelic polydiene block polymers with dual cure systems |
CA2168938C (en) * | 1995-03-13 | 2010-06-01 | Wolfgang Kaufhold | A thermoplastic polyurethane resin |
US5925724A (en) * | 1995-06-23 | 1999-07-20 | Shell Oil Company | Use of polydiene diols in thermoplastic polyurethanes |
-
1997
- 1997-10-15 US US08/951,013 patent/US6054533A/en not_active Expired - Lifetime
-
1998
- 1998-06-03 WO PCT/US1998/011368 patent/WO1999019406A1/en active IP Right Grant
- 1998-06-03 ES ES98926222T patent/ES2191940T3/es not_active Expired - Lifetime
- 1998-06-03 AU AU78109/98A patent/AU7810998A/en not_active Abandoned
- 1998-06-03 KR KR1020007003997A patent/KR100551506B1/ko not_active IP Right Cessation
- 1998-06-03 BR BR9812915-5A patent/BR9812915A/pt not_active Application Discontinuation
- 1998-06-03 CA CA002305744A patent/CA2305744A1/en not_active Abandoned
- 1998-06-03 JP JP2000515968A patent/JP4175775B2/ja not_active Expired - Fee Related
- 1998-06-03 DE DE69811104T patent/DE69811104T2/de not_active Expired - Lifetime
- 1998-06-03 CN CN98810171A patent/CN1129649C/zh not_active Expired - Fee Related
- 1998-06-03 EP EP98926222A patent/EP1023396B1/en not_active Expired - Lifetime
- 1998-06-03 AT AT98926222T patent/ATE231899T1/de not_active IP Right Cessation
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2001
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Also Published As
Publication number | Publication date |
---|---|
JP2001520251A (ja) | 2001-10-30 |
US6054533A (en) | 2000-04-25 |
BR9812915A (pt) | 2000-08-08 |
CN1275998A (zh) | 2000-12-06 |
KR20010024501A (ko) | 2001-03-26 |
KR100551506B1 (ko) | 2006-02-13 |
ATE231899T1 (de) | 2003-02-15 |
DE69811104D1 (de) | 2003-03-06 |
CA2305744A1 (en) | 1999-04-22 |
JP4175775B2 (ja) | 2008-11-05 |
EP1023396A1 (en) | 2000-08-02 |
HK1030006A1 (en) | 2001-04-20 |
EP1023396B1 (en) | 2003-01-29 |
WO1999019406A1 (en) | 1999-04-22 |
ES2191940T3 (es) | 2003-09-16 |
DE69811104T2 (de) | 2003-10-09 |
AU7810998A (en) | 1999-05-03 |
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