CN105950802A - Anti-oil, anti-static and dustproof leather care agent as well as preparation method and application thereof - Google Patents
Anti-oil, anti-static and dustproof leather care agent as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN105950802A CN105950802A CN201610539181.4A CN201610539181A CN105950802A CN 105950802 A CN105950802 A CN 105950802A CN 201610539181 A CN201610539181 A CN 201610539181A CN 105950802 A CN105950802 A CN 105950802A
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- Prior art keywords
- leather
- care products
- leather care
- stirring
- care agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Abstract
The invention discloses an anti-oil, anti-static and dustproof leather care agent as well as a preparation method and an application thereof. The leather care agent is prepared from bis(2-hydroxyethyl)benzyl-N-dodecylammonium chloride, dimethicone, amino silicon oil, high-molecular polymers, organic acid, a nonionic surfactant, essence and water. According to the formula, the solubility of dimethicone and amino silicon oil in raw materials such as the high-molecular polymers, bis(2-hydroxyethyl)benzyl-N-dodecylammonium chloride and the like is good, and the good synergistic effect is realized. The prepared leather care agent can form a protective film on the surface of a leather product, keep out ultraviolet rays, delay fracturing of the leather product caused by illumination and prolong the service life of leather. The care agent can endow the leather product with the excellent hand feeling and impression, and the leather treated with the care agent has the very good oil repellent and water repellent effects.
Description
Technical field
The invention belongs to field of fine chemical, be specifically related to the leather nursing of a kind of oil rub resistance anti-static dust-proof
Agent and preparation method and application.
Background technology
Along with socioeconomic development, people's lifting to material pursuits, increasing leathercraft obtains
Use widely.High-grade leathercraft is always linked together with fashion fleshpots.Along with society
Urbanization, the development of technicalization, leather industry has obtained vigorous growth, and increasing consumer selects
Selecting leatherware and show oneself makings, the thing followed is the increase of leather care products usage amount and leather protects
It is easily generated electrostatic after reason, is easily stained with showing of the problems such as ash, non-oil resistant.
And the leather care products of a oil rub resistance anti-static dust-proof, protective separation film can be formed on leather,
Guaranteeing not viscous ash, oil rub resistance on leather, this is non-the normally off key.
Existing leather nursing glazing agent, mainly uses and adds softening agent, antifungus agent or wax in resin
Emulsion etc., but this can not meet current requirement, does not play the effect of oil rub resistance anti-static dust-proof, and
Polishing effect is inconspicuous, Shortcomings.
Summary of the invention
In order to overcome existing leather care products be easily stained with dirt, not antistatic, be weak to greasy dirt, gloss is dark, make
By defects such as rear easy generation be full of cracks, the primary and foremost purpose of the present invention is to provide a kind of oil rub resistance antistatic to prevent
The leather care products of dirt.
Another object of the present invention is to provide the preparation method of above-mentioned leather care products.
It is still another object of the present invention to provide the purposes of above-mentioned leather care products.
The purpose of the present invention is achieved through the following technical solutions:
A kind of leather care products, is to be prepared by the raw material of following mass percent:
Preferably, described leather care products, is to be prepared by the raw material of following mass percent:
Double (2-hydroxyethyl) benzyl ammonium chloride of N-dodecyl-N.N-in formula is Qing Te company of the U.S.
The antistatic additive produced, it is compounding with other compositions in formula, and preferably antistatic effect is superior, performance
Go out antistatic, characteristic that non-sticky ash is dust-proof.
Preferably, dimethyl-silicon oil viscosity is 500,000, and the ammonia value of amido silicon oil is 0.27；The two becomes
Demultiplexing after formula, the leather care products glazing good film-forming property of gained, there is oil rub resistance characteristic.
Described high molecular polymer optimization polypropylene amide, polyacrylic acid or polyurethane；
Described polyacrylamide preferred cationic polyacrylamide or non-ionic polyacrylamide, preferably 20
Ten thousand monomers aggregate into；
The preferred glacial acetic acid of described organic acid or citric acid；
Described nonionic surfactant preferred isomery C13 alcohol ether-5EO and/or isomery C13 alcohol ether
-7EO, is BASF AG and produces；
The preferred deionized water of described water.
The preparation method of above-mentioned leather care products comprises the following steps:
(1) dimethicone, amido silicon oil, nonionic surfactant, organic acid and water are mixed,
Stirring is allowed to be uniformly dispersed, and makes latex A；
(2) by double for N-dodecyl-N.N-(2-hydroxyethyl) benzyl ammonium chloride, high molecular polymer and
Essence mixes, and stirring is allowed to be uniformly dispersed, and makes emulsion B；
(3) latex A and emulsion B are mixed, after stirring, prepare leather care products；
20-40min is stirred under the preferred 800-1200rpm of stirring described in step (1)；
4-8min is stirred under the preferred 500-800rpm of stirring described in step (2) and (3).
The leather care products of the present invention can be applicable to animal's leather or dermatine is made shoes, clothing,
On suitcase and sofa；
During use, after being cleaned up by leatherware, at distance 20-25cm, spray the leather of the present invention
Nursing agent 1-2 time, then with dry towel wiping uniformly.
The present invention has such advantages as relative to prior art and effect:
1, the dimethicone in inventive formulation, amido silicon oil and high molecular polymer, N-dodecyl
The intermiscibility of the raw materials such as double (2-hydroxyethyl) benzyl ammonium chloride of-N.N-is good, has good collaborative work
With.
2, the leather care products of the present invention can form protecting film on leatherware surface, plays obstruct ultraviolet,
Delay leatherware to produce be full of cracks because of illumination, extend leather and use the time.
3, the nursing agent of the present invention can give the superior feel of leatherware and perception, processes with this nursing agent
The leather crossed has well refuses oil water repellent effect.
4, the electrostatic potential of on leather 2500 volts can be reduced to 0 by the nursing agent of the present invention, forms protective separation
Film, makes the non-sticky ash of leather, and its consumption is few, effective.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention do not limit
In this.
Embodiment 1
A kind of leather care products, is to be prepared by the raw material of following mass percent:
Preparation method comprises the following steps:
(1) by dimethicone, amido silicon oil, nonionic surfactant, organic acid and deionized water
Add in reactor, stir 20-40min under 800-1200rpm and be allowed to be uniformly dispersed, make latex A；
(2) by double for N-dodecyl-N.N-(2-hydroxyethyl) benzyl ammonium chloride, high molecular polymer and
Essence adds in reactor, stirs 4-8min and is allowed to be uniformly dispersed, make emulsion B under 500-800rpm；
(3) latex A and emulsion B are mixed, prepare leather after stirring 4-8min under 500-800rpm and protect
Reason agent.
Embodiment 2
A kind of leather care products, is to be prepared by the raw material of following mass percent:
Preparation method is with embodiment 1.
Embodiment 3
A kind of leather care products, is to be prepared by the raw material of following mass percent:
Preparation method is with embodiment 1.
Embodiment 4
A kind of leather care products, is to be prepared by the raw material of following mass percent:
Preparation method is with embodiment 1.
The leather care products that the embodiment of the present invention prepares is milky, has Flos Osmanthi Fragrantis taste, and viscosity is about 2000.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not by above-mentioned reality
Execute the restriction of example, the change made under other any spirit without departing from the present invention and principle, modification,
Substitute, combine, simplify, all should be the substitute mode of equivalence, within being included in protection scope of the present invention.
Claims (10)
1. a leather care products, it is characterised in that be to be prepared by the raw material of following mass percent:
Leather care products the most according to claim 1, it is characterised in that by following mass percent
Raw material prepares:
Leather care products the most according to claim 1 and 2, it is characterised in that: described dimethicone
Viscosity be 500,000, the ammonia value of amido silicon oil is 0.27.
Leather care products the most according to claim 1 and 2, it is characterised in that: described polyphosphazene polymer
Compound is polyacrylamide, polyacrylic acid or polyurethane.
Leather care products the most according to claim 1 and 2, it is characterised in that: described organic acid is
Glacial acetic acid or citric acid.
Leather care products the most according to claim 1 and 2, it is characterised in that: described nonionic table
Face activating agent is isomery C13 alcohol ether-5EO and/or isomery C13 alcohol ether-7EO.
7. the preparation method of the leather care products described in any one of claim 1-6, it is characterised in that include with
Lower step:
(1) dimethicone, amido silicon oil, nonionic surfactant, organic acid and water are mixed, stir
Mix and be allowed to be uniformly dispersed, make latex A；
(2) by double for N-dodecyl-N.N-(2-hydroxyethyl) benzyl ammonium chloride, high molecular polymer and perfume (or spice)
Essence mixing, stirring is allowed to be uniformly dispersed, and makes emulsion B；
(3) latex A and emulsion B are mixed, after stirring, prepare leather care products.
The preparation method of leather care products the most according to claim 7, it is characterised in that:
Stirring described in step (1) is stirring 20-40min under 800-1200rpm；
Stirring described in step (2) and (3) is stirring 4-8min under 500-800rpm.
9. the leather care products described in any one of claim 1-6 is at animal's leather goods or dermatine goods
Application in nursing.
Leather care products the most according to claim 9 protects at animal's leather goods or dermatine goods
Application in reason, it is characterised in that: during use, after leatherware is cleaned up, in distance 20-25cm
Place's sprinkling leather care products described in any one of claim 1-6 1-2 time, then with dry towel wiping be uniformly
Can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610539181.4A CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610539181.4A CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105950802A true CN105950802A (en) | 2016-09-21 |
| CN105950802B CN105950802B (en) | 2018-06-19 |
Family
ID=56901245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610539181.4A Active CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
Country Status (1)
| Country | Link |
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| CN (1) | CN105950802B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6354477A (en) * | 1986-08-22 | 1988-03-08 | Yuji Kato | Lustering agent composition |
| US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
| CN101284972A (en) * | 2008-06-13 | 2008-10-15 | 魏永红 | Multifunctional care agent and method for making same |
| CN102634285A (en) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | Fur brightener composition and preparation method and application thereof |
-
2016
- 2016-07-08 CN CN201610539181.4A patent/CN105950802B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6354477A (en) * | 1986-08-22 | 1988-03-08 | Yuji Kato | Lustering agent composition |
| US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
| CN101284972A (en) * | 2008-06-13 | 2008-10-15 | 魏永红 | Multifunctional care agent and method for making same |
| CN102634285A (en) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | Fur brightener composition and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN105950802B (en) | 2018-06-19 |
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