CN105940151A - Method for treating laundry - Google Patents
Method for treating laundry Download PDFInfo
- Publication number
- CN105940151A CN105940151A CN201580005544.XA CN201580005544A CN105940151A CN 105940151 A CN105940151 A CN 105940151A CN 201580005544 A CN201580005544 A CN 201580005544A CN 105940151 A CN105940151 A CN 105940151A
- Authority
- CN
- China
- Prior art keywords
- light source
- treatment compositions
- light
- washing machine
- utensil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical group N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- BBNQQADTFFCFGB-UHFFFAOYSA-N purpurin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC(O)=C3C(=O)C2=C1 BBNQQADTFFCFGB-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- KYMBYSLLVAOCFI-UHFFFAOYSA-N thiamine Chemical compound CC1=C(CCO)SCN1CC1=CN=C(C)N=C1N KYMBYSLLVAOCFI-UHFFFAOYSA-N 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- 235000019157 thiamine Nutrition 0.000 description 1
- 239000011721 thiamine Substances 0.000 description 1
- YXVCLPJQTZXJLH-UHFFFAOYSA-N thiamine(1+) diphosphate chloride Chemical compound [Cl-].CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N YXVCLPJQTZXJLH-UHFFFAOYSA-N 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C11D2111/46—
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
Abstract
Method and apparatus for treating laundry.
Description
Technical field
For the method and apparatus processing washing medicated clothing.
Background technology
Even if over the past two decades for the institute in terms of washing dish and the dish of medicated clothing and laundry detergent formulations
Having an improvement, cleaning has the dish stained of particular type spot and medicated clothing is still that inconvenient.Clean reusable
Plastic dishware can be the most challenging.The Plastic Drum with lid is commonly used for depositing leftover meal.Any at these type of plastics
The people depositing food in container lives through the situation that plastics are dirty.This is because numerous food product comprises natural and artificial dye
Material.Food such as Fructus Pruni pseudocerasi and blue berry have red to blue anthocyanin dye.Orange-red carotenoid such as Fructus Lycopersici esculenti is red
It is present in Fructus Lycopersici esculenti or Radix Dauci Sativae with beta-carotene.The turmetic dyes of yellow is present in curry and Caulis et Folium Brassicae junceae.Certainly, above food
Also can splash down by accident on clothes product, cause the spot being difficult to remove.
Conventional dish laundry detergent composition comprises bleach such as SODIUM PERCARBONATE and uses cobalt salt to urge as bleaching
Agent.Some dish and laundry detergent formulations use sodium hypochlorite as bleach.Use the automatic dish of this type of bleach
Washing machine composition of detergent preparation and laundry detergent formulations have effectiveness in various degree, and this effectiveness is not always able to
Meet the expectation of consumer.Depending on the specific inventory dish washing machine cleanser compositions used, plastic-food is deposited
It is common that bucket the most still has spot.Similarly, sometimes when washing in inventory dish washing machine, the dirt on medicated clothing
Stain is removed and is difficult to reach gratifying degree.
Other beneficial activity composition is used for inventory dishwashing wash in machine detergent and laundry detergent composition and be probably
Desired.For example, it may be desirable to comprise useful active component, such as household cleanser, antibacterial and be used for removing dish, cooking a meal
Endosporic active component on tool and medicated clothing.
It is contemplated that many beneficial activity compositions will be had to be included in dish and laundry detergent composition.Certainly, by this type of
Beneficial activity composition is incorporated in commercially available feasible dish washing machine composition of detergent there is many technological challenges.Many useful work
Property composition is not likely to be chemically stable in powder, liquid or gel preparation.Have some beneficial activity composition dish and
Laundry detergent composition is not likely to be physically stable.Some beneficial activity compositions are not likely to be ambient stable.Such as, temperature
Compositions may be had adverse effect by the change of degree and humidity.Additionally, some beneficial activity compositions may be with dish washing machine
Other composition in composition of detergent is incompatible.
The alternative that can be included in dish washing machine composition of detergent by some beneficial activity composition is to use
The chemical substance of photoactivation.Such as, the micronized titanium dioxide in water can be activated to by light become bleach system.Light is lived
Agent, such as phthalocyanines and naphthalene phthalocyanines, including sulfonation phthalocyanine phthalocyanine zinc, can be effectively as optical white and antimicrobial.Similar
Ground, this type of beneficial activity composition can provide in compositions separate with the dish prepared completely or laundry detergent compositions.
The obstruction that photosensitizing chemical material is applied in dish and laundry detergent compositions be need in cyclic process
Dish washing machine or washing machine for clothes internal radiation Cleasing compositions.Dish washing machine and washing machine for clothes can be provided with during fabrication
Interior lamp.But, if effective detergent that kit is containing photosensitizing chemical material, the most of existing utensil in man of consumer is not
There is this type of interior lighting.Consumer will not buy new utensil to utilize the detergent using photosensitizing chemical material.
Even if in consideration of it, the research staff of detergent develops the excellent breakthrough compositions using photochemistry material, the most only having
Some consumers is it can be seen that benefit.To finite part may be ready buy have backlighted utensil consumer supply
The amount of required dish washing machine composition of detergent is not likely to be rational business and advocates.Wait that perhaps several years certain time is straight
The family of consumer is entered for being likely to not inhale from the point of view of an enterprise to the novel backlighted dish washing machine that has
Gravitation.
Limit in view of these, it is still desirable to providing the consumer with can be in dish washing with utilize during clothes washing photosensitive
The method and apparatus of chemical substance new expensive has the backlighted utensil of integrated form without buying, and these needs are not yet
Have been resolved.
Summary of the invention
One embodiment of the invention is the method for processing dish, and the method comprises the following steps: provides and comprises
The treatment compositions of photosensitive component；Described treatment compositions is made to contact with described dish within the appliance；And use radiation of visible light
Described treatment compositions；Wherein by the step for the treatment of compositions described in radiation of visible light by inserting in the case of without instrument
Enter described utensil and can implement from the light source that described utensil removes.
Another embodiment of the present invention is the method for processing medicated clothing, and the method comprises the following steps: provides and comprises
The treatment compositions of photosensitive component；Make described treatment compositions and described contact with clothing within the appliance；And use radiation of visible light
Described treatment compositions；Wherein passing through by the step for the treatment of compositions described in radiation of visible light can be attached in the case of without instrument
It is connected to described utensil and can implement from the light source of the inside of described utensil dismounting.
Another embodiment of the present invention is luminous allotter, and this luminescence allotter includes: lamp housing, described lamp housing bag
Include power source and be electrically connected to the light source of described power source；And it is operably connected to the process combination of described lamp housing
Thing reservoir, described reservoir includes distribution outlet；The size of wherein said luminous allotter and size are set to can be adaptive
Inside at scrubber.
Another embodiment of the present invention is the external member for processing substrate, and this external member includes: lamp housing, described lamp housing
Including light source；And accommodate the container of the photocatalytic treatment compositions containing light activating agent；Wherein said lamp housing and described
Container is packaged together each other.
Accompanying drawing explanation
Fig. 1 is the allotter with light source and reservoir, and this allotter can be put in utensil by consumer.
Fig. 2 is the support for allotter.
Fig. 3 is distributor, it magnet including being operatively attached to distributor.
Fig. 4 is the distributor with locking component, its tooth bar that can be attached in the case of without instrument in utensil
Or other movable part and can from its dismantle.
Fig. 5 is inventory dish washing machine.
Fig. 6 is automatic clothes washing machine.
Fig. 7 is lamp housing, and it includes power source and is electrically connected to the light source of power source.
Fig. 8 is to include lamp housing and the external member of the treatment compositions containing light activating agent, and described lamp housing includes power source
Electrically it is connected to the light source of power source.
Fig. 9 is the external member of the lamp housing including being bonded to container, and wherein applicator is prominent from container and connects with vessel liquid
Logical.
Detailed description of the invention
Photosensitive component can provide in different forms in dish and laundry detergent formulations or with described dish and medicated clothing
Detergent formulations provides together.Such as, photosensitizing chemical material can be in the powder prepared completely, liquid, gel or unit dose
Soluble sachet provides.Photosensitizing chemical material can also be in compositions separate with the dish prepared completely or laundry detergent compositions
Middle offer.If provided as separate compositions, this compositions with photosensitizing chemical material can be in the washing prepared completely
Agent has been in the suds before, during or after being delivered and has delivered.
In order to utilize the laundry detergent composition and composition of detergent comprising photosensitive component, expect to provide light source.Light
Source integrally can provide with dish washing machine or washing machine for clothes.Additionally, light source can be washed by dish washing machine or medicated clothing
Wash machine bulk supply.Light source produces electromagnetic radiation.
Utensil can be provided with one or more watertight light fitting, and this light fixture is shining in rack, and this rack accommodates the most cleaned
Substrate.This light fixture can be recessed in cabinet walls, top board or base plate, and guides in light entrance rack.Situation at dish washing machine
In, light can irradiate wash liquid and any photosensitive component within it provided, and this time just travels to through various distribution arrays
On cleaned dish.
Similarly, for washing machine for clothes, in watertight light fitting can be shining into the rack accommodating washing rotating cylinder or in rotating cylinder itself.
Such as, in vertical type washing machine, the lamp of depression may be provided in drum wall, and photoconduction is guided into rotating cylinder central authorities.Lamp can be towards
Rotating cylinder bottom so that when rotating cylinder is filled up completely with or is partially filled with the wash liquid comprising photosensitive component, light irradiation washs
Liquid is to activate photosensitive component.Certainly, lamp is attachable to the top doors on vertical type washing machine for clothes, or is positioned in top doors,
And light is guided in downwards on wash liquid or exit, water is assigned to rotating cylinder from this outlet.There is the clothing of perforated cylinder
In thing washing machine, this type of rotating cylinder accommodates in the housing, and this housing is the parts accommodating wash liquid.It is advantageous to lamp and be shining into this
Any photosensitive component provided in wash liquid with activation in housing.This layout can make the technical elements providing light simpler
It is single, because lamp need not come in contact with the goods being washed.
Also when wash liquid is stored in the reservoir of utensil, or pump, conduit or other liquid biography can be moved through
During defeated element, or time movable within, light source is made to be radiated on wash liquid.This method is desired so that be just cleaned by
Goods do not block light and irradiate the photosensitive component in wash liquid.
The photolytic activity of various photosensitive components can be change.Such as, some photosensitive components can be by ultraviolet light and/or can
See that light activates.If UV-activated photosensitive component, actual is to make light source be positioned in utensil so that consumer is not
Can visual touch light source.The optimal presentation mode of this layout be when wash liquid during circulating by conduit time make light irradiate
On wash liquid.Can be done relatively easily and build the utensil being constructed so as to.But, if light depth of origin is embedded in utensil, then
In the case of light source burns out or breaks down, change light source be for consumers likely to be of challenge.
If light source is in the rotating cylinder of utensil or in the top board or base plate of utensil, burn out at lamp the most for consumers
Or in the case of breaking down, can relatively easily change light source.Light source is so placed some challenges of existence.First, if made
With ultraviolet light, it may be necessary to use within the appliance and sufficiently control to guarantee that ultraviolet light will not be opened when the door of utensil is opened
Dynamic.Second, waterproof sealing mechanism must be the most strong so that seepage and skill will not occur after consumer changes light source
Enough simply so that ordinary consumer can change light source in art.
Light source can be one or more light emitting diode, incandescent osram lamp, Hg (Ar) uviol lamp, fluorescent lamp, compact
Type fluorescent lamp, cold cathode fluorescence lamp, high intensity discharge or other this type of light source.Light source needs to have to be coordinated with photosensitive component
Wavelength or wave-length coverage spectrum coordinate some spectrum.
Another optional method is to make light source away from washing point, and passes light through optical fiber cable or other transmission means
It is sent at the goods that wash liquid contact is just being cleaned by from light source.
In view of above complexity, it will therefore be apparent that the utensil being constructed without inner lighting system is repacked into and includes by device
The illuminator of tool power supply itself is infeasible on cost and cheap property.The option overcoming this challenge is to provide consumption
Person can put into the portable light source in utensil.
Luminous allotter
Fig. 1 shows that consumer can put into the allotter 10 with light source 20 and reservoir 70 in utensil.Allotter 10
Can be size and size is set to the portable set that can fit in the inside of scrubber, and not disturb and insert point
Any mobile parts of the machine of orchestration 10 or its any content.Inside is understood to be the rotating cylinder of such as washing machine for clothes.
For dishwashing appliance, inside is understood to be the space when dish washing machine runs residing for support and dish.
Typical domestic dishwashing appliance and washing machine for clothes have less than about 1m3, or it is even less than about 0.7m3, or very
To less than about 0.5m3Scrubbing space.Allotter 10 can have less than about 6000cm3Volume.Allotter 10 can have less than about
3000cm3Volume.Allotter 10 can have less than about 1500cm3Volume.Allotter 10 can have less than about 750cm3Body
Long-pending.Allotter 10 can have less than about 325cm3Volume.Allotter 10 can have less than about 150cm3Volume.
Allotter 10 can be slim.Slim for representing that allotter 10 is generally thin.Such as, allotter 10 can have
As sent the less than about 5cm that the direction of light is surveyed from light source 20, or it is even less than about 2cm, or is even less than the thickness of about 0.5cm
Degree.
Allotter 10 can be designed, such that the part of device accommodates the parts for providing light, and other parts can be
Liquid delivery system.For providing the parts of light can include power source 40.Power source can be battery.Battery can be conventional
AA, C, D or other Standard size batteries.Battery can be nickel-chrome battery, lithium ion battery or other type of battery.Power
Source 40 can be the electromotor built in allotter, and the mobile driving electromotor of allotter is powered to light source 20 to produce
Electric current.
It is connected to light source 20 to the electrically conductive property of power source 40.What is called electrically connects and refers to that power can be from power source 40
Be transferred to light source 20, such as by direct-connected circuit, sensing or any technical method known to other for by energy from power source
40 are transferred to light source 20.Power source 40 can be connected by electric wire 50 in the circuit including light source 20.Certainly, it is anticipated that more multiple
Miscellaneous circuit, such as on/off switch, intervalometer or programmable logic controller (PLC), this controller can control start and close,
Brightness, spectrum or other attribute of light sent from light source 20.
Allotter 10 can have lamp housing 60.Lamp housing 60 can include power source 40 and electrically be connected to power source 40
Light source 20.Allotter 10 can farther include to be operably connected to the treatment compositions reservoir 70 of lamp housing 60.Namely
Saying, reservoir 70 and lamp housing 60 can be engaged with each other, such as by reservoir 70 and lamp housing 60, its by integral with one another or that
This material engaged is constituted.For example, it is contemplated that to an embodiment, wherein allotter 10 by one or more occlusions together or
The injection parts engaged the most together are constituted to form allotter 10.
Reservoir 70 can include distributing outlet 80.Distribution outlet 80 can be taphole 90.Reservoir 70 can include multiple
Taphole 90.The size of taphole 90 and big I are set to distribute treatment compositions 100 lentamente.Taphole 90 can be
Circular and that there is 2mm or less diameter.The quantity of taphole 90 and size can be according to the hydrodynamics for the treatment of compositions 100
Depending on characteristic.It is contemplated that the flow velocity of distribution outlet 80 is controlled.Such as, taphole 90 can have scalable thromboembolism, its limit
Make the fluid from taphole 90, the thromboembolism of the open cross section of such as cover plate or Partial Blocking taphole 90.
Lamp housing 60 and reservoir 70 can be arranged in a side-by-side relationship.Alternatively, lamp housing 60 can be arranged so that and makes
In with, reservoir 70 is above lamp housing 60 so that when treatment compositions 100 is distributed from reservoir 70, and it passes through light source 20.
This design can be actual so that the treatment compositions 100 that can comprise photosensitizing chemical material is distributed from reservoir 70 at it
Time be activated.
Light source 20 can be that light emitting diode, electric filament lamp, incandescent osram lamp, Hg (Ar) UV lamp, fluorescent lamp, compact are glimmering
Light modulation, cold cathode fluorescence lamp, high intensity discharge or other this type of light source.Power source 40 needs to provide enough power with to light
Source 20 power supply is to desirable degree.Power source 40 can be the power source being intended for single use, and maybe can be used for multiple times and supply to light source 20
Electricity.
Reservoir 70 can have arrival end 110.Arrival end 110 can be provided with opening, treatment compositions 100 in reservoir 70
Can be delivered in reservoir 70 by this opening.Arrival end 110 can be stopper, lug and key plug, vice etc., makes
Obtain treatment compositions 100 can be placed to easily in reservoir 70.
As shown in the view of Fig. 1, the section of reservoir 70 is shown as removing thus illustrates and reside in reservoir 70
Treatment compositions 100.Treatment compositions 100 can be instantaneously driven across distribution outlet 80 because of gravity flowing.It is contemplated that for from
Reservoir 70 distributes other method for the treatment of compositions 100, and including by pump, this pump is driven by electromechanics or by consumer mechanically
Drive, be provided with the pump of spring-loaded trigger-actuated.
Allotter 10 may also include locking component 120, and it is operably connected to lamp housing 60 and treatment compositions reservoir
One or both of 70.The possible locking component 120 that locking component 120 shown in Fig. 1 simply can be used together with allotter 10
An example.Locking component 120 can include main body 130, and it has one or more wing portion 140 extended from main body 130.Main
Body 130 can be along allotter 10 longitudinal extension.Main body 130 is vertically aligned with allotter 10.
Locking component 120 can be attached to support 140 in the case of without instrument and can dismantle from it, this support 140
As shown in Figure 2.What is called can be attached in the case of without instrument and can refer to that consumer can be attached and dismantle from its dismounting
Dependency structure and the instrument of any offer mechanical advantage is not provided.But, consumer only need to manipulate only the most controllable with its finger
Object.Consumer need not utilize screwdriver, pliers, hammer or other instrument, and this instrument can provide to by consumer's hand
Power provide mechanical advantage.
Such as, consumer can be attached and dismantle locking component 120 from support 140, is thus attached and dismantles allotter 10, and
Do not use any instrument.It is to say, available hands from support 140 be attached and dismantle locking component 120 and not by any offer
The instrument of mechanical advantage.
Locking component 120 can engage with support 140 in a sliding manner.Such as, locking component 120 can have T-shaped, and
And support 140 can have a pair slit 145, its size and size are set to receive the wing portion 140 of T-shaped locking component 120.?
In using, locking component 120 can be slipped in the support 140 of complementation by consumer.In the embodiment shown in Fig. 1 and Fig. 2, T
The arm of shape locking component 120 can slip in the complementary channel 155 of support 140.
Support 140 can include binding agent 150, and this binding agent is attached to support 140 side relative with locking component 120.
In use, binding agent 150 support 140 can be connected to dish washing machine inside (such as wall, base plate, top board, door, support,
Mandrel) or the inside (such as rotating cylinder, cover plate, the rear wall of side entering type washing machine for clothes and antetheca) of washing machine for clothes.Binding agent 150
Need sufficiently tight so that allotter 10 is fixed to wash mill.Binding agent 150 needs the most compatible with wash liquid so that
Binding agent 150 does not discharge support 140 in washing process.
Distributor 10 can include the magnet 160 being operatively attached to distributor 10, as shown in Figure 3.As it is shown on figure 3,
Magnet 160 can be attached to allotter 10 or integral, and be positioned at allotter 10 with light source 20 and distribution outlet 80
That contrary side.In use, magnet 160 can play the inside that distributor 10 is attached to scrubber metal surface or
The effect of parts.
Allotter 10 can be made up of plastics or metal.
Distribution utensil 10 can include one or more locking component 120, and this locking component can be in the case of without instrument
It is attached to the mobile parts in support 170 or other utensil and can dismantle from it, as shown in Figure 4.Locking component 120 can be
Hook 180.Locking component 120 or component 120 can be the arbitrary structures of the part that can be fixed to support 170.Support 170 can
To be visible general type in the dish washing machine designed for using at home.Generally, support 170 has open web
Shape structure, it allows wash liquid to be sprayed by it.Support 170 can have post 172 or the beam of one or more mutual connection
174.The size of one or more hooks 180 and big I are set to be suspended on support 170.Alternatively, locking component 120 can
Being that clip, the wedge of extension laminating or any other can be fixed to the structure of support 170.
Light source 20 can produce the irradiation luminous flux between about 1mW to about 500W.For in inventory dish washing machine
Application for, light source 20 can produce between about 1mW to about 500W, or between about 1W and about 250W, or between about
Irradiation luminous flux between 2W to about 100W.For the application in automatic clothes washing machine, light source 20 can produce between
About 250mW is to about 500W, or about 500mW to 250W, or the irradiation luminous flux between about 1W to about 100W.The radiant light of light source 20
Flux is to launch at by the wavelength of photosensitive component absorption maximum at it to measure.Light source 20 can send wavelength between about 380nm and
Light between about 800nm.
Treatment compositions
Optical white
Treatment compositions 100 can comprise photosensitive component, i.e. photosensitive bleaching agent.Such as, suitable photosensitive bleaching agent can be
Titanium dioxide.The irradiation in visible spectrum between about 380nm and about 800nm can activate two for the purpose of photobleaching
Titanium oxide.When by about wavelength illumination between 10nm and about 1200nm, titanium dioxide also can play the work of optical white
With.Due to potential mankind's exposure problems, the irradiation in ultraviolet spectra is with less captivation.
Treatment compositions 100 can comprise based on the weight for the treatment of compositions 100 in about 0.0000001% to about 25% scope
The titanium dioxide of interior content.Treatment compositions 100 can comprise content in the range of about 0.005% to about 5% by weight
Titanium dioxide.Treatment compositions 100 can comprise other component, its include but not limited to surfactant, spice, stabilizer,
Builder, bleach, antibacterial, enzyme, greying inhibitor, brightening agent etc..
Titanium dioxide can have between about 2nm and about 600nm, or even between about 100nm and about 400nm,
Or even between the granularity between about 2nm and about 80nm.Titanium dioxide can have between about 50m2/ g to about 400m2Between/g
Specific surface area.The bulk density of titanium dioxide can be between about 100g/l to about 800g/l.Titanium dioxide can be that carbon is modified
Titanium dioxide, it has the carbon content between about 0.01 weight % to about 5 weight %.
Treatment compositions 100 can provide with liquid, gel, powder, tablet, emulsion suspension, aerosol or other form.
Light activating agent
Treatment compositions 100 can comprise photosensitive component, i.e. light activating agent.Light activating agent can comprise photosensitive part and hydrophilic portion
Point.Light activating agent can comprise the photosensitive part of less than about 35 weight %.Light activating agent can have between about 350nm and about 750nm
Between, preferably in the range of about the absorption band between 350nm and about 420nm.
Light activating agent can have a following formula:
Wherein,
X is selected from C, O, NH, C=O, CH2, CHR ", CR " R " ', S, SO and SO2；
Y is selected from C, O, NH, C=O, CH2, CHR ", CR " R " ', S, SO and SO2；
R ', R " and R " ' can be-H or the substituent group selected from the part comprised selected from oxygen, nitrogen, sulfur, halogen and hydrocarbon；
R ', R " and R " ' at least one also comprise hydrophilic parts R；
R is selected from water-soluble oligomer, water-soluble polymer and water solubility copolymer；
M is the integer of 0-8；And
Substituent R ', R " and R " ' combination molecule amount more than 400 atomic mass units (AMU).
The light activating agent of the present invention can comprise photosensitive part and hydrophilic segment.For purposes of the present invention, term " hydrophilic
Part " refer to be attracted by water and be dissolved in water to be formed the part of uniform solution.In one embodiment, hydrophilic
Part is selected from water-soluble oligomer, water-soluble polymer and water solubility copolymer.In one embodiment, hydrophilic parts can
Selected from oxyalkylene oligomer, oxyalkylene polymer, oxyalkylene copolymers, ethylene glycol, vinyl alcohol, vinyl pyrrolidone, propylene
Acid, methacrylic acid, acrylamide, cellulose, carboxymethyl cellulose, chitosan, glucosan, polysaccharide, 2-ethyl-2-
Oxazoline, hydroxyethyl methylacrylate, vinylpyridine-N-oxide, diallyldimethylammonium chloride, maleic acid, bad ammonia
Acid, N-isopropylacrylamide, styrene sulfonic acid, vinyl methyl ether, vinyl phosphonate, aziridine and their mixing
Thing.In one embodiment, hydrophilic parts is selected from oxyalkylene oligomer polymer, oxyalkylene oligomer copolymer, second
Enol, vinyl pyrrolidone, acrylic acid, acrylamide, cellulose and their mixture.
For purposes of the present invention, term " photosensitive part " refers to light absorbing photon and is consequently formed excited state
The organic conjugate part of (singlet state or triplet).Should be appreciated that " photosensitive part does not refer to charge transfer excited state to term.Also
Should be understood that as described herein, photosensitive part can comprise single part or two, three, four or the portion of other quantity any
Point, as known in the art.Photosensitive part be selected from xanthone, ton, thiaxanthone, thioxanthene, phenothiazine, fluorescein, two
Benzophenone, alloxazine, isoalloxazine, flavin and their mixture.
It is the U.S. of entitled " PHOTOACTIVATORS " (attorney 13058P) submitted on January 24th, 2014
Suitable light activating agent is described in detail by state's patent application serial numbers 61/930,999.
Photocatalytic compositions
Described treatment compositions can comprise photocatalytic compositions, and this photocatalytic compositions comprises foregoing light and lives
Agent and beneficial activity precursor.Beneficial activity precursor can replace photosensitive bleaching agent as above (such as titanium dioxide), or
Use on the basis of photosensitive bleaching agent.Treatment compositions can be aqueous solution.
Beneficial activity precursor is selected from oxygen-containing halogen, such as chlorite, chlorate, bromite, bromate, iodous acid
Salt, iodate or their mixture.In one embodiment, beneficial activity precursor can be chlorite.Beneficial activity
Precursor can be sodium chlorite (NaClO2).In this embodiment, by the photocatalyst by electron transmission to photoactivation
The chloritic activation produced results in useful activation chlorine dioxide (ClO2).Chlorine dioxide is effective biocide
And bleach.Chlorine dioxide kills microorganism by destroying across cell wall transmission nutrient substance.In addition to the salt, herein also
It is susceptible to other precursor forms various.
Photocatalytic compositions can comprise electron acceptor.For purposes of the present invention, term " electron donor " is defined as
" accept compound or the portion of the electronics from light activating agent when light activating agent is in photoexcited state and/or electron reduction state
Point." this electron transfer process is typically a most quick and reversible process.
At Turro, N.J., V.Ramamurthy, and J.C.Scaiano, Principles of Molecular
Photochemistry:An Introduction, the 7th chapter, page 41 (University Science Books 2009,
Paperback edition) in generally describe electron acceptor and accept to come the ability of electronics of self-exited light activating agent.
Should be appreciated that when Gibbs free energy (Δ G) less than 0 time reactant between reaction be favourable.
The electron acceptor of the present invention can be to accept when light activating agent is in photoexcited state and/or reduction-state to live from light
Any material of the electronics of agent.The concentration of given described light activating agent and the longevity of the photochemistry material excited state of light activating agent
Life, electron acceptor must be present in enough concentration can be can enter with light activating agent in the consumer product compositions of photoactivation
Row Blang collides.
Suitably electron acceptor is selected from: purpurine, 2,2' bipyridyl, 1,4-benzoquinone, 2,3-bis-chloro-5,6-dicyano-right
Benzoquinone, tetrahydroxy-1,4-quinone hydrate, DBH 2,5 di tert butylhydroquinone, tertiary butylated hydroquinone, anthraquinone, diamino-anthraquinone, anthraquinone-2-
Sulfonic acid, anthracene, dicyanobenzenes, five ammonia cobaltous chloride dichloride, silver nitrate, iron sulfate, titanium dioxide, zinc oxide, cadmium selenide, hydrochloric acid
Thiamine, diphosphothiamine, Ammonium persulfate., sodium peroxydisulfate, potassium peroxydisulfate, (2,2,6,6-tetramethyl piperidine-1-base) epoxide,
Dimethyl sulfourea, tetranitromethane, acetoacetic acid lithium, oxaloacetic acid, sodium ascorbate, 2,6-chlorophenesic acid indophenols, 4-methoxy
Base phenol, 4-methyhnorpholine-N-oxide, 4-tert-butyl catechol, allopurinol, 2-methyl-3-hydroxy-4-formyl-5-hydroxymethylpyridine. 5'-phosphate, 2-methyl-3-hydroxy-4-formyl-5-hydroxymethylpyridine. hydrochloric acid
Salt, sodium benzoate, sodium nitrate, sodium nitrite, diatomic oxygen and their mixture.
Suitably photocatalytic compositions, including suitable beneficial activity precursor and suitable electron acceptor, describes in detail
In being filed on January 24th, 2014, the U.S. Patent Application Serial of entitled " CONSUMER PRODUCT COMPOSITIONS "
In number 61/930,993 (attorney 13057P).
For laundry treatment compositions, actual can provide and comprise by weight about 1% to about 25%, or about 1% to about
20%, or the light activating agent of about 3% to about 10% and by weight about 1% to about 50%, or about 3% to about 40%, or about 5%
Preparation to the beneficial activity precursor of about 30%.This type of preparation is applicable to the top being designed for using about 65L wash liquid
Laundry treatment compositions in loaded type washing machine.
For using the washing machine of the laundry liquid of smaller size smaller, such as efficiently anterior loaded type washing machine, can actual carry
For comprising by weight about 0.1% to about 20%, or about 0.5 to about 15% to about 20%, or the photoactivation of about 1% to about 10%
Agent and by weight about 0.5% to about 50%, or about 1% to about 40%, or the system of the beneficial activity precursor of about 3% to about 30%
Agent.
For dish treatment compositions, actual can provide and comprise by weight about 0.1% to about 25%, or about 0.1% to
About 20%, or the light activating agent of about 0.5% to about 10% and by weight 0.01% to about 50%, or about 0.01% to about
25%, or the preparation of the beneficial activity precursor of about 0.1% to about 10%.
Packaging
Treatment compositions 100 can be packaged in opaque packaging.Packaging can by include but not limited to polyethylene, poly-third
Alkene, the material of metal or other material are made.Wave-length coverage is between about 2nm and about 1200nm, or even between about 380nm
Electromagnetic radiation between about 800nm cannot transmission packaging.What is called is opaque refers to that, relative to complete radiation transmission, transmission reduces
Greater than about 80%, or greater than about 90%, or greater than about 95%, or greater than about 99%.
Clean method
Photosensitive component can be used for cleaning and/or processing substrate.Described substrate can be dish or medicated clothing or other material.With
Can comprise the following steps that in the method processing substrate and the treatment compositions 100 comprising photosensitive component is provided；Make process within the appliance
Compositions and substrate contact；And irradiate described treatment compositions with visible ray.Photosensitive component can be light activating agent.
The step carrying out treatment with irradiation compositions 100 with visible ray is usable in without being inserted in utensil in the case of instrument
Portion also can implement from its light source removed.What is called can in the case of without instrument, insertion device be internal and can remove from it and is
Refer to that consumer can not use any offer mechanical advantage by dependency structure insertion device and being removed from utensil by dependency structure
Instrument.But, consumer only need to manipulate only the most controllable with its finger object.Consumer need not utilize screwdriver, pincers
Son, hammer or other instrument, this instrument can provide mechanical advantage to the power provided by consumer's hand.
As non-limiting example, light source can be that the self-sustaining Waterproof battery having and opening and closing switch is for electric light.
Utensil can be domestic dish washing machine, and described method can the domestic dish of dish in the rack including dish washing machine
Dish washing machine is implemented.Dish washing machine can be the dish washing machine being sized to business/industrial use.
In the application relating to dish washing machine, light source can be placed on the base plate of the scrubbing space of dish washing machine by user
On, light source is placed in a part for support, lamp is placed in compartment, be i.e. the part of support or be connected to the portion of support
Divide or light source is placed on other position in dish washing machine.
Coming that the step for the treatment of with irradiation compositions can use with visible ray can be in the case of without instrument in insertion device
Portion also can perform from its light source dismantled.In the application relating to dish washing machine, as non-limiting example, light source is permissible
It is suspended in a part for support or is attached to the inwall of inside, base plate or the top board of dish washing machine.
In the application relating to washing machine for clothes, as non-limiting example, light source can be attached in the case of without instrument
It is connected to the inside of washing machine for clothes and can dismantle from it.Such as, light source can be attached to medicated clothing in the case of without instrument and washes
Wash the revolving drum of the door of machine, washing machine for clothes, or the agitator (if present) of washing machine for clothes can tearing open from it
Unload.The revolving drum of washing machine for clothes may be housed in the inside of washing machine for clothes.The allotter 10 described before can be used to hold
The described method of row.Make treatment compositions can perform in the revolving drum of utensil with the step of contact with clothing within the appliance.
Without being bound by theory think the application for relating to washing machine for clothes, light source can be made valuably to be attached to a certain
Parts, because at least some of relative to rotating cylinder motion cycle of the fabric that accommodated in guiding it of most of washing machine for clothes.
When light source moves in whole washing and perhaps if light source is not attached to certain parts, light source will need the most solid so that
When even clashing into some part of washing machine for clothes, light source can bear the shock of the parts of washing machine for clothes.This solid
Design is likely more costliness compared with more acarpous design.
Schematically showing utensil 300 in Fig. 5, wherein light activating agent or photosensitive component can be used for processing dish.Such as Fig. 5
Shown in, utensil 300 can be inventory dish washing machine 310.Inventory dish washing machine 310 can have door 320, its can open with
The path of internally 330 is provided.Internal 330 can support pending dish 350, such as by cleaning and/or sterilizing or other
Process.The inside 330 of dish washing machine 310 can be defined by rack 340.Rack 340 can have base plate 360 and relative top board
370, the wall 380 of described base plate and the top board rack 340 by extending in-between is connected to each other.One or more supports 170
Can be accommodated in rack 340.One or more mobile parts 390 can be accommodated in rack 340.Mobile parts 390 are permissible
Being mandrel, spray arm extends from described mandrel, and spray arm can distribute wash liquid to rack 340.As it is shown in figure 5, have
The luminous allotter 10 of light source 20 can be attached to the inside 330 of inventory dish washing machine 310 in the case of without instrument, such as
The wall 380 formed by the inner surface of door 320, and can dismantle from it.
Utensil 300 can be automatic clothes washing machine 400, as shown in Figure 6.Automatic clothes washing machine 400 can have door
320, it can open to provide the path of internally 330.Internal 330 can support pending medicated clothing 410, such as by cleaning
And/or sterilize or other process.The inside of automatic clothes washing machine 400 can be defined by rack 340.Revolving drum 420 can be held
It is contained in rack 340.Mobile parts 390, such as agitator, can project upwards and stretch in rotating cylinder 420.As shown in Figure 6, there is light
(such as, the luminous allotter 10 in source 20 can be attached to the inside 330 of automatic clothes washing machine 400 in the case of without instrument
The inner surface of door 320) and can dismantle from it.Alternatively, luminous allotter 10 can freely be attached to the inner surface of rotating cylinder 420
And can dismantle from it.
Mobile parts w390 that light source 20 can be attached in utensil 300 in the case of without instrument also can tear open from it
Unload.Such as, in washing machine for clothes 400, light source can be attached to the agitator of rotating cylinder 420 or wall also in the case of without instrument
Can dismantle from it.In dish washing machine 310, light source 20 can be attached to rotary-jet mandrel also in the case of without instrument
Can dismantle from it.
Static component that light source 20 can be attached in utensil in the case of without instrument also can be dismantled from it.Such as,
In washing machine for clothes 400, light source 20 can be attached to the door 320 of automatic clothes washing machine 400 also in the case of without instrument
Can dismantle from it.In dish washing machine 310, light source 20 can be attached to dish washing machine 310 in the case of without instrument
Base plate 360, top board 370, wall 380 or door 320, and can from its dismantle.
It is contemplated that consumer can use photosensitive component following in the method for clean substrate.Consumer is to utensil 300
Load substrate to be cleaned.Substrate can be dish 350 or medicated clothing 410.Utensil 300 can be dish washing machine 310 or medicated clothing
Washing machine 400.Consumer is then common with existing commercially available dish washing machine 310 or washing machine for clothes 400 by treatment compositions
Mode put in machine.Such as, in existing commercially available utensil, detergent is directly quantitatively adding the rack of machine by consumer
In, or it is quantitatively adding detergent disperser, compartment, pallet or the pop-up type bin in such as utensil 300.
Photosensitive component can provide as the component of the medicated clothing prepared completely or dish cleaning agent.Alternatively, photosensitive component can
Thering is provided with separate preparation, described preparation is only limitted to photosensitive component, or becomes the photosensitive component of subassembly with other.If it is photosensitive
Component provides as the part of the detergent prepared completely, then the detergent prepared completely can be quantitatively adding by consumer simply
In utensil 300, instruction in the operation instruction according to utensil 300 or carry out as routine.If photosensitive component is with complete
The detergent of preparation is provided separately, then photosensitive component direct quantitative can join in the rack 340 of machine or be quantitatively adding point
In orchestration 10.It is contemplated that photosensitive component is put in same compartment, pallet or the bin being placed with the detergent prepared completely.
Optionally, during photosensitive component can be placed into the allotter 10 with reservoir 70.
Then consumer can take steps so that before cleaning circulation or when some in cleaning cycle are suitable
Between place open light source 20.Consumer can be at the front opening light source 20 of the door of its closedown utensil 300.Optionally, light source 20 can connect
In there is the circuit of intervalometer or programmable logic controller, intervalometer or programmable logic controller is on-demand opens
Lamp.Light source 20 can be attached to the inside 330 of utensil 300, or light source 20 can be attached to the inside 330 of utensil by consumer.
Light source 20 can be attached in the case of without instrument utensil inside 330 and can from its dismantle in terms of make
Consumer obtains the advantage that their existing utensil 300 can be used to be provided cleaning by the treatment compositions with photosensitive component.This
Overcome consumer to have to buy new utensil 300 with the difficult problem benefited.This additionally aids the process combination with photosensitive component
The prospect marketing personnel of thing, because for big to the sufficient market scale produced, determines capital and other source investment
Entering the business selling the treatment compositions with photosensitive component, this has practical significance.Come sharp without the method
The substrate stained with photosensitive component detergent, provides the consumer with and does not forever have actual meaning by the attainable benefit of this chemical substance
Justice.Being attached or dismantling light source 20 or allotter 10 by need not instrument, taking the necessary steps and obtaining by being in the suds
The benefit using photosensitive component to give is convenient and inconspicuous for consumers.
Work as cleaning appliance, such as dish washing machine 350 or washing machine for clothes 400 in use time, wash liquid with just by
The substrate contact of cleaning.Light source 20 treatment with irradiation compositions 100 and/or wash liquid are to activate photosensitive component.Once this chemistry
Material is activated, and chemical substance can realize desired cleaning.Can expect that photosensitive component when cycles of washing starts, or can washed
Wash the certain point in cyclic process, automatically or by consumer open utensil and use treatment compositions 100 and deliver.
Light source 20 can be provided by allotter 10, such as shown in Fig. 1.Fig. 7 shows lamp housing, and it includes power source 40 and leads
It is electrically connected to the light source 20 of power source 40.It is to say, light source 20 need not provide, in Fig. 1 together with reservoir 70
Shown in.
Treatment compositions can be the laundry detergent compositions or dishwashing detergent prepared completely.Treatment compositions can comprise by
Any with the CASCADE dishwashing detergent of liquid, powder or the form of unit dose that Procter&Gamble Co. sells
The component of formula.
Owing to being difficult to reequip existing utensil to implement method disclosed herein, therefore light source 20 has power source 40 and can be
Actual, this power source 40 is independent of the power source of inventory dish washing machine 310.Such as, inventory dish washing machine 310 can be inserted
Enter in supply socket or be directly connected in circuit.Power source 40 for light source 20 can be battery.
The step carrying out treatment with irradiation compositions 100 with visible ray can use allotter 10 to perform, and this allotter 10 includes
The reservoir 70 of light source 20 and releasedly receiving treatment compositions 100.
Light source 20 can be attached to support 170 in the case of without instrument and can dismantle from it.
Described utensil can be vertical type or side entering type washing machine for clothes, and described method can be at washing machine for clothes 400
Middle enforcement.Washing machine for clothes 400 can be type conventional in family, or washing machine for clothes 400 be sized to business/
Industrial use, or there is the size that self-service laundry is common.
Treatment compositions can comprise by Procter&Gamble Co. sell with liquid, powder or the form of unit dose
The component of any formula of TIDE laundry detergent compositions.
External member
Also can be expected to be useful in the external member processing substrate.It can be actual for providing external member 190, and it includes lamp housing 60 and holds
Device 200, described lamp housing 60 includes power source 40 and is electrically connected to the light source 20 of power source 40, and described container 200 holds
Receive photosensitive component, such as, comprise the photocatalytic treatment compositions 100 of light activating agent, as shown in Figure 8.Lamp housing 60 and container
200 can be packaged together, as shown in Figure 8 each other.Magnet 160 may be operably coupled to lamp housing 60.For dish washing machine
310 or washing machine for clothes 400 application in, magnet can be used for being attached to lamp housing 60 inside 330 of utensil 300.Alternatively,
Lamp housing 60 need not be provided with magnet 160 or other structure to be attached in inventory dish washing machine 310 by lamp housing 60
Portion 330.Lamp housing 60 can be placed on the base plate 360 of inventory dish washing machine 310 by consumer, or on support 170, or propping up
On frame 170 in the sack accommodating tableware.
Without being bound by theory think by providing the consumer with light source 20 and treatment compositions with single external member 190
100, consumer more easily can obtain the benefit that can be provided by the treatment compositions 100 with photosensitive component.This set
Part 190 can include operation instruction and the obtainable information about expection benefit.Also identical process combination can be provided independently
Thing 100 so that the recycling light source that she obtains together with the treatment compositions 100 of follow-up purchase 20 of consumer.
As a part for external member 190, treatment compositions 100 can provide in opaque containers 200.Container 200 and tool
The lamp housing 60 having light source 20 can be packaged together by shrink wrapped thing 210.Optionally, container 200 and the lamp with light source 20
Shell 60 can be packaged in carton together.
As non-limiting example, treatment compositions 100 can be dish cleaning composition or laundry cleaning composition.Place
Reason compositions 100 can be to use photosensitive component to provide the compositions of other benefit.As non-limiting example, process combination
Thing 100 can be textile dyeing compositions.
In an embodiment of external member 190, lamp housing 60 and container 200 are engaged with each other.Applicator 500 can be from container
200 highlight and can keep fluid connection with container 200, as shown in Figure 9.This type of external member can be actually used in the dirt processed on medicated clothing
Stain.Such as, by rubbing applicator 500 on clothes product, user can be by the container comprising photosensitive component of certain content
The content of 200 is assigned to the staining in part of clothes product.Once clothes product is wetted, can open light source 20 with by light
510 wetted portions guiding clothes product into.Light can activate photosensitive component to process the spot on clothing.Photosensitive component can be light
The bleach of activation, and the bleach activated can bleach spot being processed.Alternatively, in treatment compositions, photosensitive
Component can be titanium dioxide.
Applicator 500 can be ball, and the content of container 200 is sent to container 200 in container 200 by it
Portion.Applicator 500 can be solid or fiber tip, and its one end extends into container 200.
Dimension disclosed herein and value should not be construed as being limited strictly to described exact numerical.On the contrary, unless additionally said
Bright, each such dimension is intended to refer to cited numerical value and the functionally equivalent scope around this numerical value.Such as, open
Dimension for " 40mm " is intended to indicate that " about 40mm ".
Unless specifically excluded or limited, each document cited herein, including any intersection
Quote or Patents or patent application, be incorporated by reference in its entirety the most accordingly herein.Quoting of any document is not to it
Relative to any disclosed in this invention or claimed prior art herein accreditation, or it not independent to it
Ground or propose, advise or disclose recognizing of this type of invention any with the combination with other list of references any or multiple list of references
Can.It addition, to a certain extent, any implication of the term in the literature or definition with in the document being incorporated by reference
Any implication of same term or definition when conflicting mutually, be as the criterion with the implication or definition giving this term in the literature.
Although having illustrate and described specific embodiments of the present invention, but those skilled in the art are come
Say it is readily apparent that multiple other can be made without departing from the spirit and scope of the present invention to be changed and amendment.Cause
This, it is intended to contain all these within the scope of the invention in the following claims and change and amendment.
Claims (12)
1., for the method processing washing medicated clothing, said method comprising the steps of:
Thering is provided treatment compositions, described treatment compositions comprises photosensitive component；
Make described treatment compositions and described washing contact with clothing within the appliance；And
By treatment compositions described in radiation of visible light；
The step for the treatment of compositions described in wherein said radiation of visible light utilizes can be attached to institute in the case of without instrument
State the inside of utensil and can carry out from the light source of the inside of described utensil dismounting.
Method the most according to claim 1, wherein said photosensitive component is light activating agent.
3. according to method in any one of the preceding claims wherein, treatment compositions described in wherein said radiation of visible light
Step utilizes the light source with the power source independent of described utensil to carry out.
4. according to method in any one of the preceding claims wherein, treatment compositions described in wherein said radiation of visible light
Step utilizes allotter to carry out, and described allotter includes described light source and accommodates the storage of described treatment compositions releasedly
Device.
5. according to method in any one of the preceding claims wherein, treatment compositions described in wherein said radiation of visible light
Step provides the irradiation luminous flux between 500mW and 500W under the wavelength between 350nm and 750nm.
6., according to method in any one of the preceding claims wherein, it is the most clear that wherein said utensil has described washing medicated clothing
Clean rack, wherein said light source can be attached to described rack in the case of without instrument and can dismantle from described rack.
7., according to method in any one of the preceding claims wherein, wherein said treatment compositions is that the medicated clothing prepared completely is washed
Wash agent.
8., according to method in any one of the preceding claims wherein, wherein said treatment compositions comprises 0.5 weight % to 20
The light activating agent of weight %.
9., according to method in any one of the preceding claims wherein, wherein said treatment compositions comprises 1 weight % to 10 weights
The light activating agent of amount %.
10., according to method in any one of the preceding claims wherein, wherein said light source can be attached in the case of without instrument
It is connected to the moving assembly in described utensil and can dismantle from described moving assembly.
11. according to method in any one of the preceding claims wherein, wherein said make within the appliance described treatment compositions with
The step of described washing contact with clothing is carried out in revolving drum.
12. 1 kinds for implementing the automatic clothes washing machine according to method in any one of the preceding claims wherein, Qi Zhongsuo
State automatic clothes washing machine to include:
For accommodating the inside of washing medicated clothing；And
Light source；
Wherein said light source can be attached to described inside in the case of without instrument and can dismantle from described inside.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461931038P | 2014-01-24 | 2014-01-24 | |
| US61/931,038 | 2014-01-24 | ||
| PCT/US2015/012407 WO2015112684A1 (en) | 2014-01-24 | 2015-01-22 | Method for treating laundry |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105940151A true CN105940151A (en) | 2016-09-14 |
| CN105940151B CN105940151B (en) | 2020-02-21 |
Family
ID=52478066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580005544.XA Active CN105940151B (en) | 2014-01-24 | 2015-01-22 | Method for treating laundry |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20150211165A1 (en) |
| EP (1) | EP3097226B1 (en) |
| JP (1) | JP6200099B2 (en) |
| CN (1) | CN105940151B (en) |
| CA (1) | CA2935413A1 (en) |
| MX (1) | MX2016009537A (en) |
| WO (1) | WO2015112684A1 (en) |
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| CN111886372A (en) * | 2018-04-02 | 2020-11-03 | 桑原株式会社 | Clothes bleaching device and bleaching method |
| CN114502710A (en) * | 2019-10-08 | 2022-05-13 | 宝洁公司 | Method for washing fabrics |
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| USD797387S1 (en) | 2014-08-19 | 2017-09-12 | Whirlpool Corporation | Topload washing appliance |
| US11085147B2 (en) | 2018-09-27 | 2021-08-10 | Whirlpool Corporation | Sanitation device |
| USD942715S1 (en) | 2018-10-08 | 2022-02-01 | Whirlpool Corporation | Fabric care appliance |
| USD933910S1 (en) * | 2019-10-15 | 2021-10-19 | Wuxi Little Swan Electric Co., Ltd. | Washing machine |
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| DE102010030046A1 (en) * | 2009-07-17 | 2011-02-03 | BSH Bosch und Siemens Hausgeräte GmbH | Photocatalytic treatment unit for use with laundry dryer to perform photocatalytic treatment of laundry item, has set of illuminants that are freely movable in container, where laundry item and illuminants are accommodated in container |
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- 2015-01-12 US US14/594,195 patent/US20150211165A1/en not_active Abandoned
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- 2015-01-22 JP JP2016548132A patent/JP6200099B2/en not_active Expired - Fee Related
- 2015-01-22 WO PCT/US2015/012407 patent/WO2015112684A1/en active Application Filing
- 2015-01-22 CA CA2935413A patent/CA2935413A1/en not_active Abandoned
- 2015-01-22 CN CN201580005544.XA patent/CN105940151B/en active Active
- 2015-01-22 MX MX2016009537A patent/MX2016009537A/en unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111886372A (en) * | 2018-04-02 | 2020-11-03 | 桑原株式会社 | Clothes bleaching device and bleaching method |
| CN111886372B (en) * | 2018-04-02 | 2024-02-20 | 桑原株式会社 | Bleaching device and bleaching method for clothes |
| CN114502710A (en) * | 2019-10-08 | 2022-05-13 | 宝洁公司 | Method for washing fabrics |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2935413A1 (en) | 2015-07-30 |
| CN105940151B (en) | 2020-02-21 |
| US20150211165A1 (en) | 2015-07-30 |
| JP2017506705A (en) | 2017-03-09 |
| JP6200099B2 (en) | 2017-09-20 |
| WO2015112684A1 (en) | 2015-07-30 |
| MX2016009537A (en) | 2016-10-26 |
| EP3097226B1 (en) | 2020-07-08 |
| EP3097226A1 (en) | 2016-11-30 |
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