CN103314059A - Light source with hybrid coating, device including light source with hybrid coating, and/or methods of making the same - Google Patents

Abstract

Certain example embodiments of this invention relate to techniques for improving the performance of Lambertian and non-Lambertian light sources. In certain example embodiments, this is accomplished by (1) providing an organic- inorganic hybrid material on LEDs (which in certain example embodiments may be a high index of refraction material), (2) enhancing the light scattering ability of the LEDs (e.g., by fractal embossing, patterning, or the like, and/or by providing randomly dispersed elements thereon), and/or (3) improving performance through advanced cooling techniques. In certain example instances, performance enhancements may include, for example, better color production (e.g., in terms of a high CRI), better light production (e.g., in terms of lumens and non-Lambertian lighting), higher internal and/or external efficiency, etc.

Description

Have compo light source, comprise the device of the light source with compo and/or the method for making it

Invention field

Some exemplary embodiment of the present invention relates to light source, comprises the device of light source and the method for making it.More specifically, some exemplary embodiment of the present invention relates to for the technology that improves lambert's type or non-lambert's type light source performance (for example efficient, color and/or light generation etc.).In some exemplary embodiment, this is by with the realization of getting off, namely, (1) provides organic-inorganic hybrid materials (can be high-index material) at LED in some exemplary embodiment, (2) light scattering ability (for example by fractal embossing, patterning etc. and/or by the random dispersion element is provided thereon) of increase LED, and/or (3) improve performance by advanced cooling technology.

The background of invention and the summary of embodiment

There is every year generating greatly (estimating up to 25% according to some) to be used for illumination in the U.S..Therefore, exist the more lasting demand of high energy efficiency illumination is provided.As everyone knows, incandescent-lamp bulb is the unusual low energy light source of imitating.The electric power about 90% that they consume is used as heat release rather than light.Fluorescent lamp bulb remains poor efficiency than incandescent-lamp bulb more efficient (for example about 10 the factor) but compare it with solid-state light emitting element as photodiode.

In addition, compare with the ordinary life of solid-state light emitting element such as photodiode, the life-span of incandescent-lamp bulb is shorter relatively, is generally about 750-1000 hour.Comparatively speaking, photodiode for example, generally has 50000 to 70000 hours life-span.Fluorescent lamp bulb has the longer life-span (as 10000-20000 hour) than incandescent light, but imperfect color reproduction is provided.

Color reproduction uses colour rendering index (CRI Ra) to measure usually, and it is the relative measurement of the surface color displacement of object when being lighted by specific lamp.CRI Ra is when 8 reference colors of illumination, and the color reduction of lighting system is average with the modification what kind of measurement the color reduction of reference radiation body (radiator) compares.If the color coordination (coordinate) of one group of test color of illuminated system illumination is identical with the coordination of the same test color of being shone by the reference radiation body, CRI Ra equals 100 so.Daylight has high CRI (Ra is about 100), and incandescent-lamp bulb is also relatively near (RA is greater than 95), and fluorescent lighting is more inaccurate (general Ra is 70-80).The illumination of some type has low-down CRI Ra.For example mercuryvapour lamp or sodium vapor lamp have and are low to moderate about 40 or lower Ra.Another challenge that new lighting system exploitation faces is how to realize high CRI.

Another difficult problem that conventional lamp faces is to need periodic replacement means of illumination (as bulb etc.).This a difficult problem is especially serious for problem the very high place of the place that is difficult to get at (as domed ceiling, bridge, Highrise buildings, traffic tunnel etc.) and/or replacement cost.Corresponding to the use of at least 44000 hours light generating devices, the general life-span of typical light fixture approximately is 20 years (for example using based on 20 years of 6 hours every days).The life-span of light generating device is wanted much shorter usually, thereby produces the needs of periodically changing.Therefore, further challenge is realizing the long lifetime, thereby reduces the down time amount.

Existing the providing of design of light fixture is provided for conventional LED element encapsulation and other electronicss.In this design, packaged LED is installed on the circuit card that is installed on the radiator element, and radiator element is installed to lamp casing with required drive electronics.In many cases, also need extra optics (secondary packaged unit) to produce uniform illumination.The weakness of optics is that LED shows as the point source of fan-out light.Particularly chip-scale LED essence is lambert's type.

Statement " photodiode " is used to refer to basic semiconductor diode structure (for example chip) sometimes.(for example) " encapsulation " device of being formed by several parts at affirmation commonly used and commercially available " LED " ordinary representation of the sale of electronics shop.The device of these encapsulation generally includes the photodiode of based semiconductor, for example (full content of each is included this paper in it by reference) of description in (but being not limited to) United States Patent (USP) the 4918487th, 5631190 and 5912477, the encapsulation of various electric wires connections and package photodiode.

Replace other light sources such as incandescent-lamp bulb with photodiode, encapsulated LED has been used to traditional light fixture, for example, comprise hollow eyeglass and the light fixture that is attached at the base plate on the eyeglass, wherein said base plate has the conventional Socket casing that has the one or more contact elements that are electrically coupled to power supply.For example, thus comprise circuit card, be installed to a plurality of encapsulation of circuit card photodiode, after be installed on the circuit card and be suitable for being connected to the LED bulb that a plurality of LED of connecting piece of light fixture Socket casing can be thrown light on by power supply, be fabricated.

Fig. 1 is non-staining, the diffusion optical fiber array 102 of molded, the soft silicone rubber that can be used in combination with led light source.The example of Fig. 1 can, for example, use in conjunction with backlight keyboard and telltale window, for example in front in the board component.The light pipe element 104 of different size and/or shape, 106 and 108 also can be arranged in the optical fiber array 102.The LED lamp can be mounted to the base portion of solid light pipe element 104,106 and 108, perhaps can put into the hollow light pipe element.Light pipe array 102 can be placed on the LED lamp PC board component to form back light unit.

Fig. 2 is the simplification view of the panel assembly 200 of LED illumination.Backlighted panel adopts the miniature LED lamp 202 of HLMP-650X not painted, non-diffusion SMT to be surface mounted to two-sided PC plate 204.Both sides all use maximum metalization to realize the low thermal resistance of periphery, and plated through-hole 206 is shown in Fig. 2.LED lamp 202 distributes (comprising glass substrate 208) in whole front panel, to realize required illuminating effect.Light from LED lamp 202 blends together in panel, passes light area on 200 of the panels to produce illumination relatively uniformly.These lighting systems are spread and are scribbled the very thin translucent white coating of one deck.By day, LED lamp 202 is closed, and light area 210 reflect ambient light present white.At night, these zones are by LED lamp 202 interior lightings and present the color identical with LED light.The outside surface of panel 200 scribbles the white reflection lacquer, makes and must be opened by the zone on the face of backlighted panel.The anti-spread coated paint of the cuticula of black adds, and finishes 212 to form the outside.The panel integral thickness is 5.84mm.

Though the exploitation of photodiode has thoroughly changed illuminating industry in many aspects, some in the challenge that some characteristics of photodiode propose do not reach as yet fully.For example, the emmission spectrum of any particular led concentrates on single wavelength (because composition and the structure of photodiode determine) usually, this is desirable for some application, but be worthless for other application, for example, be used for providing emmission spectrum that the illumination of very low CRI Ra is provided.

Therefore, be understandable that, need a kind of improved light source/light fixture in the art, overcome one or more these and/or otherwise difficulties, and/or the method for making it.

In some exemplary embodiment, provide a kind of making to comprise the method for the coated article of the substrate that supports coating.Precursor based on titanium is provided.Inner complex is provided.Make the reaction of described precursor based on titanium and described inner complex, contain material to form the chelating titanium.Organic resin material is provided.Make described chelating titanium containing material and described organic resin material crosslinked, to form the organic and inorganic mixing solutions.Settle the organic and inorganic mixing solutions to form coating at substrate.

In some exemplary embodiment, provide a kind of making to comprise the method for the coated article of the substrate that supports coating.The organic and inorganic mixing solutions is provided, described organic and inorganic mixing solutions is made by following steps: make precursor and inner complex reaction based on titanium and/or zirconium, crosslinked with formation organic and inorganic mixing solutions with organic materials to form the chelating material and to make described chelating material.(a) at the wet organic and inorganic mixing solutions of using of substrate, perhaps (b) squeezes out described organic and inorganic mixing solutions introducing mounting medium to substrate with mounting medium then.In case be arranged on the substrate curing organic-inorganic mixing solutions.

In some exemplary embodiment, provide a kind of method of making electronic installation.Substrate is provided.Settle at least one photodiode (LED) at substrate.The organic and inorganic mixing solutions is provided, described organic and inorganic mixing solutions is made by following steps: make precursor and inner complex reaction based on titanium and/or zirconium, crosslinked with formation organic and inorganic mixing solutions with organic materials to form the chelating material and to make described chelating material.(a) the wet organic and inorganic mixing solutions of using at least one LED on the substrate, perhaps (b) introduces mounting medium with described organic and inorganic mixing solutions and then mounting medium squeezed out to the substrate at least one LED.In case be arranged on the substrate curing organic-inorganic mixing solutions.

In some exemplary embodiment, provide a kind of device.First substrate is provided.Mirror is by first substrate supporting.A plurality of photodiodes (LED)/provide second substrate is provided printed circuit board (PCB).Layered product is faced first major surfaces supporting of second substrate of the printed circuit board (PCB) that supports a plurality of LED.Layered product is formed by the first organic and inorganic mixing solutions, and layered product has and is at least about 1.8 specific refractory power.

In some exemplary embodiment, provide a kind of device.First glass substrate is provided.The film mirror paint is by first substrate supporting.A plurality of photodiodes (LED) flip-chip that soft printed circuit board (PCB) (FPC) supporting is mounted thereto.Second glass substrate is provided.Layered product is faced first major surfaces supporting of second substrate of the printed circuit board (PCB) that supports a plurality of LED, and wherein said layered product is lamination first substrate and second substrate together.

In some exemplary embodiment, provide a kind of device.First glass substrate is provided.The film mirror paint is by first substrate supporting.A plurality of photodiodes (LED) flip-chip that soft printed circuit board (PCB) (FPC) supporting is mounted thereto.Polymkeric substance is that the insulator layer on basis inserts between mirror and the FPC, and described insulator layer is formed by the first organic and inorganic mixing solutions.Second glass substrate is provided.Layered product is faced first major surfaces supporting of second substrate of the printed circuit board (PCB) that supports a plurality of LED, and wherein said layered product is lamination first substrate and second substrate together.

In some exemplary embodiment, provide a kind of method of making LED matrix.Substrate is provided.Form a plurality of LED at substrate.Creating random pattern on the LED and/or in the one or more layers at LED, wherein said random pattern has light scattering effect at the light that LED produces.In some exemplary embodiment, provide a kind of LED matrix.

According to some exemplary embodiment, random pattern can be by following establishment: generate fractal pattern, wherein fractal pattern is fractal pattern at random or has the randomness of introducing to wherein; On one or more layers of the fractal pattern that generates being transferred to LED.

According to some exemplary embodiment, random pattern can be by following establishment: the aqueous solution that nm or um level element are provided; Directly or indirectly solution is mounted in the zone on the LED random dispersion element on LED.

In some exemplary embodiment, provide a kind of device.First glass substrate and second glass substrate are provided, and described first substrate and second substrate are substantially parallel and spaced apart, thereby define cavity betwixt.Settle a plurality of posts between first substrate and second substrate.Edge seal is provided by the periphery around first and/or second substrate.At least one bus bar is positioned on the internal surface of second substrate of first substrate.At least one n leg contacts described at least one bus with at least one p leg.At least one conductor connects described at least one n leg and at least one p leg.At least one LED is by at least one conductor supporting.In some exemplary embodiment, provide the method for making it.

In some exemplary embodiment, provide a kind of device.First glass substrate and second glass substrate are provided, and described first substrate and second substrate are substantially parallel and spaced apart, thereby define cavity betwixt.Settle a plurality of posts between first substrate and second substrate.Edge seal is provided by the periphery around first and/or second substrate.At least one bus bar is positioned on the internal surface of second substrate of first substrate.Described at least one bus of a plurality of thermoelectricity (TE) module contact, each described TE module comprises by conductor n leg and p leg connected to each other.A plurality of ILED are positioned on the conductor of a plurality of TE modules.In some exemplary embodiment, provide the method for making it.

Feature described herein, aspect, advantage and exemplary embodiment can be combined in any suitable combination or the sub-portfolio and realize more embodiment.

The accompanying drawing summary

The following detailed description of reference example illustrative embodiment in conjunction with the drawings, these and other feature and advantage can obtain better, understand more completely, wherein:

Fig. 1 is non-staining, the diffusion optical fiber array of molded, the soft silicone rubber that can be used in combination with led light source;

Fig. 2 is the simplification view of the panel assembly of LED illumination;

Fig. 3 shows by the 0.30um of inorganic-organic polymer matrix system preparation and transmittance per-cent and the wavelength of the thick high refractive index matching layer of 0.23um with chart according to some exemplary embodiment;

Fig. 4 illustrates for the schema of making the example procedure of mixing high refractive index film according to some exemplary embodiment;

Fig. 5 illustrates the related basic recipe of Fig. 4 example procedure, crosslinked, curing schedule;

Fig. 6 shows the luminous efficiency of the AlGaAs diode that uses the enhanced light scattering that causes with the fractal embossing of film of not using some exemplary embodiment with chart;

Fig. 7 a is the schema that exemplary flow is shown according to some exemplary embodiment, and this flow process is used for helping to realize to using fractal pattern to realize non-lambert's molded breadth band scattering that high CRI is useful;

Fig. 7 b is the schema that exemplary flow is shown according to some exemplary embodiment, and this flow process is used for helping to realize to using dispersing element to realize non-lambert's molded breadth band scattering that high CRI is useful;

Fig. 8 is the sectional view according to the flat ILED matrix layered product of some exemplary embodiment;

Fig. 9 is the illustrative ILED structure based on AlGaAs according to some exemplary embodiment;

Figure 10 is the sectional view of showing Active Cooling according to some exemplary embodiment, and this cooling technology is used for using electrothermal module flip-chip mounted LEDs array;

Figure 11 is electrically connected in series orthographic plan with parallel hot linked ILED structure according to some exemplary embodiment;

Figure 12 is the sectional view according to the heat sink wafer of flip-chip of some exemplary embodiment;

Figure 13 is the exemplary VIG in conjunction with LED according to exemplary embodiment.

The detailed description of the exemplary embodiment of invention

The method that some illustrative examples relates to generally flat solid-state illumination and/or makes it, this illumination are based on and embed or be laminated to for the LEDS system two-dimensional array of glass flat and/or crooked manifold.In some illustrative examples, go out the efficient that optical coupling technology is used to improve lighting system.This type of device can move under the low current density threshold value in some examples, thereby has reduced heating problem.Present inorganic LED (LEDS or ILEDS) encapsulates with plastics (sometimes being Resins, epoxy) individually.Therefore, LEDS is point source, and light intensity and distance X cos Ω's square is inversely proportional to thus.It is that this type of LEDS is spread in the various system linearity arrays that a kind of trend is arranged recently, and wherein lamp can be coupled on the glass edge of backlight etc. of LCD TV panel for example.In this type of device, use special scatterer coupling luminous.

As everyone knows, lambert's type source is the light source of deferring to lambert's Method of Cosine, and wherein, the radiation of light source is directly proportional with the cosine value with respect to the angle of greatest irradiation rate direction, and wherein this source is checked from this angle.LED is similar to lambert's type source, because they often have big beam divergence and radiation pattern is similar to spheroid.Some exemplary embodiment can comprise lambert's type and/or non-lambert's type light source.In some exemplary embodiment, lambert's type light source can be by realizing to obtain lambert's type or similar lambert's type effect providing coupling photometry scatterer (for example or comprise acetal, silicon-dioxide etc.) near non-lambert's type light source place to non-lambert's type light source.Though with reference to lambert's type (with non-lambert's type) light source, be basic lambert's type (or non-substantially lambert's type) even should be understood that light source, this light source just can be regarded as lambert's type (or non-lambert's type) herein.

Need high efficiency photodiodes (LED) for many application, for example indicating meter, printer, junction service, photoelectricity computer interconnection, etc.Yet, unfortunately, have the gap between the internal efficiency of LED and the external efficiencies thereof.The internal quantum of the measured double-heterostructure of matter can surpass 99%.On the other hand, common packaged LED has only the efficient of percentum usually.One of reason that this is not enough is that the difficulty that light is escaped from high-index semiconductor is very big, for example, because light escape pyramid is very narrow.Specific refractory power is that the escape pyramid of the interior interior lights of the semi-conductor of n=3.5 has only-16 degree, applies as snell law.

The narrow escape pyramid of this of spontaneous emission is contained the solid angle of Ω ≈ 1/4ns2 X 4 π steradian.Only 2% inside produces light and can escape into freeboard, and other then suffer inner full-reflection and suffer to absorb again.Many systems come the idea of coupling diode semi-conductor bright dipping partly to overcome this problem based on the specific refractory power hemisphere dome that uses coupling.Yet the weakness of this Perfect Matchings is that the escape solid angle is Ω ≈ 1/4ns2 X 4 π steradian.

Use mostly that encapsulation is plastics, its specific refractory power that has much smaller than semi-conductive (nc＜＜ns).Epoxy is through being often used as sealing agent, and its specific refractory power is still much smaller than the GaAs that is generally used for the LED material and GaN.

This prescription is the general upper limit in fact, because it can be derived by statistical mechanics phase space parameter under not with reference to the situation of the geometrical shape of particular optic.Therefore, it is applicable to that contrary Winston concentrates the light system of instrument and other types.Structure for the specific refractory power " eyeglass " of mating can be thick, transparent semiconductor layer, and this may increase cost sometimes.Now national state-of-the-art is-30% external efficiencies among the AlGaAs base LED, and it adopts thick transparent semiconductor upper strata and whole base plate with low especially loss optical design etching.A kind of method that increases escape probability is, give photon repeatedly chance find the escape pyramid.

Some exemplary embodiment relates to naked led array, and it provides from the substrate unsticking or with the flip-chip form.Can relate to from the film LED of substrate unsticking (for example peeling off by extension) with linear and two-dimensional array such as, some exemplary embodiment they are tiled to the glass substrate that scribbles bus bar.Some exemplary embodiment can relate to LED directly is installed on the soft PCB.Such PCB can be bonded to the glass substrate with conductive coating paint and dispel the heat with help.Led array can scribble transparent, high refractive index layer in addition.The easier escape from the LED structure reduced absorption thereby this exemplary arrangement advantageously makes light.In some exemplary embodiment, by using different technology with the veining of film surface nanometer, the light chaos that dynamically becomes, and the phase space of light distributes and become ground " traversal ", allow in addition more light find the escape pyramid.The simulation technique of this example technique is verified, has at least 30% external efficiencies to use these illustrative principles among the GaAs LED.

On these devices, between alive circuit and air or low-refraction encapsulated layer, use transparent high refractive index dope layer and can further improve its performance.For example, from the high refractive index alive circuit to air or the more progressively transition of low-refraction encapsulated layer, can allow light more effectively to be coupled into or to be coupled out device, thereby improve its efficient and/or picture quality.Be accompanied by higher efficient, device can be more powerful, consumes energy still less simultaneously.Because some is to be made up to the semiconductor material of about 2.5-3.5 by specific refractory power in these Optical devices, thus the required specific refractory power of this Clear paint layer in whole visible light section for being at least 1.8, be preferably greater than 1.9.

If specific refractory power is enough high, polymkeric substance will be the good selection of coating material, because it is easy to process and potential low cost.Unfortunately, such polymkeric substance does not exist.The polymkeric substance that specific refractory power is the highest in the world at present is considered to have about 1.76 specific refractory power, is relied (Sadayori) and is dug field (Nitto) exploitation by the fixed of day east electrician (Nitto Denko).

Inorganic materials with high refractive index and high transparent can be used in some exemplary embodiment, as possible transition metal oxide, as titanium dioxide or zirconium dioxide (for example brilliant zirconium white of superlattice nm).

The coating of formulations prepared from solutions for example, is frangible sometimes and may ftractures as the material of containing metal oxide compound such as sol-gel paint and nm particle composite material, and because manufacturing process, storage stability and reliability relative complex makes that their application is limited.This coating generally can not be very suitable for high processing temperature (for example being equal to or higher than about 400 degrees centigrade), and this is shortcomings for most of semiconductor devices.

Sputter is the another kind of technology that is used to generate from these and/or other metal oxide high refractive index film at present.Yet unfortunately, electro-optical device manufacturers can seek other and have more cost-benefit method, because the known sputter method that normally cost is higher relatively and throughput capacity is lower.

Some exemplary embodiment relates to based on the compo system based on the zirconic system of the titanium dioxide of polymerization and/or polymerization.At first use to convert titan-alkoxide to relative inactive hexa-coordinate titanium species with the sequestrant reaction with the four-coordination titanium species with hyperergy, prepare organic and inorganic mixed polymer solution.Other required polymeric constituents can be added in the stable titaniferous solution and mix fully then.Stable result is, mixed polymer solution can at room temperature be stablized nearly 6 months, and color and viscosity change ignores.Mixed polymer solution can be coated on the substrate by spin coating or vertical slot with desired thickness.

The film that titanium dioxide enriches is by being lower than thermolysis compo generation under about 250 ℃ height.The desciccator diaphragm of gained can be made as and be as thin as the thick extremely about 4um or bigger of 0.2um.This film has the good transparency, and has up to or be higher than about 1.90 specific refractory power at whole visible light section when being 300 degrees centigrade or higher temperature when solidification value.Obtain the thickness of single application of paints greater than the flawless film of 300nm.The overbrushing material is applicable to film that acquisition is thicker and looks like can't see tangible interface from the SEM sectional view between two continuous coating.It is mechanically firm when being exposed to heat and ultraviolet radiation, stable to mix high refractive index film, and applicable to various optical application.This material is compatible with semiconductor material

In some exemplary embodiment, the organic and inorganic mixed polymer can be introduced by meeting can roll over thin-medium, as ethene-vinyl acetate (EVA), siloxanes, aromatic poly etc.This will allow to use vacuum bonding or degasification, not use autoclave sometimes.

Selection contains the organic polymer of a plurality of hydroxy functional groups.They are selected, and to allow primary or the insecondary chemical adhesion between polymkeric substance and the titanium dioxide phase, promote consistency and the high degree of dispersion of phase.No matter poly-(dibutyl titanic acid ester) polymkeric substance and organic polymer of chelating is that all proportions in whole or essence is compatible in solution or in cured film, and their high transparent and dispersion of refractive index curve are provable.Generally, up to or to be higher than 1.9 specific refractory power be that the 550nm place of 0.4um obtains at thickness.In the time of on being deposited on any inorganic light-emitting diode, even be as thin as the film of 0.4um, also common incremental range 70% is showing from high-index material and is showing the raising light output coupling that lands.

Fig. 3 shows by the 0.30um of inorganic-organic polymer matrix system preparation and transmittance per-cent and the wavelength of the thick high refractive index matching layer of 0.23um with chart according to some exemplary embodiment.0.30um and the thick high refractive index matching layer of 0.23um is deposited over respectively on sapphire and the quartz base plate.As can be seen from Figure 3, be at least about 80% at whole visible spectrum transmittance.In some exemplary embodiment, higher transmittance can be arranged, for example, at least about 85%, more preferably at least about 90%, sometimes even higher.

Fig. 4 illustrates for the schema of making the example procedure of mixing high refractive index film according to some exemplary embodiment.In step S402, provide the inorganic based precursor.In some exemplary embodiment, the inorganic based precursor can be based on the precursor of titanium such as titan-alkoxide, based on composite phosphate of titanium etc.In some exemplary embodiment, the inorganic based precursor can directly or indirectly be deposited on the LED and/or on glass substrate.For example, in some exemplary embodiment,, can be printed based on the phosphate layer of titanium by ald (ALD) deposition based on the precursor of titan-alkoxide, etc.It will be appreciated, of course, that the replacement titanium, or except titanium, other high refractive index inorganic materials can be used for also in some exemplary embodiment.

In step S404, can form inner complex, and can add organic constituent and optional additive.In some illustrative examples, inner complex can be Whitfield's ointment.In some exemplary embodiment, organic constituent can be resin, siloxanes, polyimide, polymeric amide, and/or analogue.

Optional additive also can be introduced into.For example, other inorganic materials (as replacing based on the precursor of titanium or except the precursor based on titanium) can be introduced into the adjustment specific refractory power.In fact, specific refractory power can be by comprising that optionally zirconium white, silicon-dioxide and/or silicate etc. are adjusted up or down.Light-scattering component and/or heat dissipation element also can be introduced into.A kind of exemplary materials is boron nitride, and it is as light scattering agent and the thermit powder that disappears.Softening agent also can be included in some exemplary embodiment.

In step S406, chelating based on the precursor of titanium and organic constituent crosslinkable to generate the organic and inorganic mixing solutions.In one embodiment, titan-alkoxide can react with sequestrant, four-coordination Ti species are converted to the species of inactive relatively hexa-coordinate, for example, to generate chelating poly-(dibutyl titanic acid ester).Certainly, in different embodiments of the invention, other titanate can be generated and/or use.In some illustrative examples, mixed polymer can be mixed together formation by the organic resin with chelating poly-(dibutyl titanic acid ester) and hydroxyl.In some exemplary embodiment, organic constituent and inorganic component can be provided as the per-cent that equates by weight.In some exemplary embodiment, also can be by weight provide organic constituent and inorganic component with 60/40 ratio.Certainly, in different embodiments of the invention, other ratio and/or per-cent also are possible.

In some exemplary embodiment, mixing solutions may be quite liquid.In some exemplary embodiment, liquid mixing solutions is favourable because it can " float " or " moving about " between LED.In this case, mixing solutions can be applied or otherwise be provided as desirable thickness by wet application, vertical channel.Yet in some exemplary embodiment, it can be desirable that the more viscous mixing layered product (for example inorganic and/or other materials that comprises in organic binder bond such as EVA, the silicone resin aromatic poly etc.) that can be extruded is provided.Application facet can be more favourable in " more cleaning " or " few in disorder " for more viscous mixing layered product.The application of mixed polymer or layered product has been shown in step S408.

In step S410, the mixed polymer of coating or layered product are dried and/or solidify.In some exemplary embodiment, dry and/or curing can help desolventizing and water, stays than the more inorganic materials of organic materials.Drying can occur in first high temperature that is lower than about 250Shi degree, and at second high temperature that solidifies about can occurring in more than or equal to 300 degrees centigrade.Some exemplary embodiment can be included under these and/or any other suitable temperature dry with solidify in one or two.

Fig. 5 illustrates the related basic recipe of Fig. 4 example procedure, crosslinked, curing schedule.In Fig. 5 as can be seen, in step S502, the precursor contact pressure resin tackiness agent based on titanium of chelating.In step S504, the precursor crosslinks based on titanium of described resin glue and chelating.In step S506, boil off solvent by heating process, cured film is adhered to substrate (as film, crust, glass etc.).

Some exemplary embodiment relates to from LED (for example ILED) array enhancing scattering of light, for example uses scattering layer.In some sample instance, scattering layer can improve from the light of ILED array to go out to be coupled, and/or helps to realize helping to obtain non-lambert's molded breadth band scattering of high CRI.Experiment shows, the superficial makings of half yardstick of interior lights wavelength, the inner corners randomization that can produce height (sometimes or even completely or almost completely) light in semiconductor film.It can be realized by natural light lithography or any other suitable technique.

The generation of light scattering layer can comprise, for example directly or indirectly in the fractal embossing processing of light-emitting zone upper film.In certain embodiments, this process steps can film transfer and bonding after carry out.In some exemplary embodiment, has the light-emitting zone that can be positioned at LED for the fractal pattern of scattering of light appropriate porosity (for example in some illustrative examples be 10 to 30% porosity) directly or indirectly.Randomness can be inserted into fractal pattern by any suitable technique.For example, can use self similarity distribution (self-similar distribution) to introduce randomness, for example, by by with solid unit square begin to revise Xie Erbinsiji (Sierpinski) pad make up, remove picked at random square quadrant, remove the square quadrant of the residue of picked at random etc.The another kind of mode that increases randomness to fractal structure relates to statistical self-similarity, and for example, by coming every size of limiting pattern in each iteration with the random quantity of choosing from a class range, rather than the specify precise size limits.Random fractal also can be by operation generation at random, as pedesis (Brownian motion) track, the flight of row dimension (L é vy flight), fractal landform, Blang tree etc.

Use above-mentioned and/or other technology, produce the template with suitable feature.Afterwards can be with this template transfer to the target area.In some exemplary embodiment, itself can finish scattering this template.But in some other exemplary embodiment, this template can be used as mask and its part can etched (for example by photoetching and chemical etc.), thereby generates required light scattering characteristic, and template can be removed alternatively.In some exemplary embodiment, this feature can be applied to photodiode or any suitable interface.In some exemplary embodiment, interface, chip, polymkeric substance, semiconductor layer etc. can be helped realize required light scattering effect by veining.

Scattering of light also can obtain by the polystyrene spheres that use have a 0.2um radius, and it is used for the surface of closely packed array coating LED at random.Porosity similar to the above can be used for this exemplary embodiment.Polystyrene spheres can adhere to by surface tension from the aqueous solution in the dipping operation by spin-coating method and/or similar method.This operation can cause described ball to be positioned at random site.Described ball also can be assisted the etching mask of Xe+ ion beam etching as the Cl-of about 10-300nm, is preferably and gos deep into n+ and/or other AlGaAs layers 10-170nm.Plasma body also can be used to carry out this etching.These etching techniques also can be used for forming the fractal pattern in above-described embodiment.Though described some exemplary embodiment about polystyrene spheres, should be appreciated that other material and/or other shape also can be used for different embodiments of the invention.

Fig. 6 with chart show for the LED total light yield of enhancement type and non-enhancement type AlGaAs diode with inject electric current.Therefore, Fig. 6 can think to show with chart the luminous efficiency of the AlGaAs diode of the scattering of light of using the enhancing that causes with the fractal embossing of film of not using some exemplary embodiment.Calibration can be by along with the photodiode current that the photorectifier quantum yield is carried out little correction obtains the ratio of LED electric current.The angular distribution of light from this LED is lambert's type.Linear fit on Fig. 4 is represented optimum current scope widely, and this scope may be subjected to the non-radiative compound restriction at high-end heating and low side sometimes.The square representative from mutually same wafer with rhombus pulled out and handled to two devices of final deforming step together.

Fig. 7 a is the schema that exemplary flow is shown according to some exemplary embodiment, and this flow process is used for helping to realize to using fractal pattern to realize non-lambert's molded breadth band scattering that high CRI is useful.In step S701, generate template, its have at random fractal pattern or to the fractal pattern of wherein having introduced randomness.In step S703, directly or indirectly with this template transfer to the LED the zone or the zone of LED.For example, in some exemplary embodiment, this zone can be on the outermost layer at LED, the semiconductor layer of LED, the interface in the LED matrix apparatus assembly etc.In step S705, this zone is used this template then and carries out veining, etching or embossing.In veining and/or etching embodiment, this template can be used as lithographic patterning, plasma etching, wet etching and/or etc. mask (if for example it is formed by the sensitization base portion).In some exemplary embodiment, template is removed in step S707.But in different embodiment of the present invention, this template also can be left on the original place.In step S709, finish the manufacturing of LED matrix.

Fig. 7 b is the schema that exemplary flow is shown according to some exemplary embodiment, and this flow process is used for helping to realize to using dispersing element to realize non-lambert's molded breadth band scattering that high CRI is useful.In step S711, formed the aqueous solution of nanometer or micron order element.For example, can use spherical, eye shape, cubes and/or other shaped objects.In some exemplary embodiment, such object can have near about full diameter of 0.01 to 1um or distance.In case the aqueous solution is applied to a zone on the LED directly or indirectly, size of component and quantity can be selected, so as to provide goal porosity (as, along above-mentioned line).In step S713, this solution can be used by wet, as by rotate, roll, dipping, groove pressure and/or other coating technology.This coating technology can help random dispersion element on LED, as disperseing with goal porosity.In step S715, applied solution is by dry selectively.In some exemplary embodiment, in step S717, element can be used as the formula etching mask, so that etching or patternings such as LED quilt as the photoetching of use plasma.In some exemplary embodiment, element can be removed.In step S719, finish the manufacturing of LED matrix.

Some example embodiment also relates to ILED array " initiatively cooling " technology.This Active Cooling can help to increase work efficiency, and prolongs the life-span of product.At present, chip manufacturer attempts to adopt to use and laterally injects and design to reduce powerful parasitic absorption on the electrode according to the LED of current-crowding effect, and this is a known problem at all LED.Diode current pours in two central section between the ohmic contact, but appropriateness is away from any one contact in two contacts.This method of design has reduced the parasitic optics absorption at ohmic contact place, but has also aggravated local temperature very regrettably.

The use of LED (as InGaN, AlGaAs and/or analogue) in solid-state illumination and other high brightness applications will be benefited from much larger than the exploitation of the LED of traditional LED light output.Conventional InGaN LED has 350 microns chips, and it has translucent electric current diffusion p contact, and is encapsulated in usually in the lamp of 5mm.As mentioned above, because the photoabsorption in the translucent contact, so light extraction efficiency is poor.In addition, the high thermal resistance of the lamp of 5mm (150 degree C/W) has limited maximum drive current.Therefore, luminous power and brightness output is quite low.

Upwards dispose differently with the extension of the conventional encapsulation of InGaN LED, the extension that some exemplary embodiment relates to the Flip-Chip Using of LED disposes downwards.This exemplary configuration also can help to reduce the thermal resistance of LED.In some illustrative examples, this exemplary configuration can make LED with higher current drives.Calculation result shows, uses the active thermoelectric-cooled rather than uses the contact of reflection p-type to replace translucent contact, and use flip-chip geometrical shape, being conducive to increases about 160-300% with light extraction efficiency.These results all are better than conventional output.In addition, in the exemplary embodiment of enforcement and described same or analogous Active Cooling, the size of LED and/or the drive current of LED can further increase.This advantageously causes bigger luminous power and brightness output.

Fig. 8 is the sectional view according to the flat ILED matrix layered product of some exemplary embodiment.Fig. 8 assembly comprises first glass substrate 802 and second glass 804.In some exemplary embodiment, first substrate 802 can be considered to a kind of upper strata.High refractive index lamination body 806 is by upper strata first substrate, 802 supportings.In some exemplary embodiment, layered product 806 can be formed by above-mentioned organic and inorganic mixing material, as, be extruded moulding.In some illustrative examples, the internal surface 806a of layered product 806 can be by veining.In some exemplary embodiment, layered product 806 is laminated together with first substrate 802 and second substrate 804.

Low-refraction isolator 808 can be by 804 supportings of second substrate.In some exemplary embodiment, low-refraction isolator 808 can be the low-refraction version of above-mentioned organic and inorganic mixing material, as is extruded moulding.Therefore, in some exemplary embodiment, layered product 806 can be formed by similar organic and inorganic mixing material with low-refraction isolator 808, as long as their specific refractory poweres separately are adjusted to target separately.In some exemplary embodiment, layered product 806 can have high refractive index, as be at least about 1.7, more preferably at least about 1.8, sometimes in addition up to or be higher than 1.9, and isolator 808 can have low refraction, as is lower than about 1.8, more preferably be lower than approximately 1.7, and preferably be low to moderate or be lower than 1.6-1.65.

High refractive index layer 812 can be positioned between the soft PCB of layered product 806 and supporting LED 810.The soft PCB that is suitable for some exemplary embodiment can be made or provided by bright section (Minco).High refractive index layer 812 can be organic layer, as titanium oxide (as TiO2 or other suitable stoichiometry), Zirconium oxide (as titanium dioxide TiO2 or other suitable stoichiometry) etc.In some exemplary embodiment, high refractive index layer 812 can-inorganic materials organic by above-mentioned mixing form.Yet, in some illustrative examples, as in order further to increase specific refractory power, great majority or all organic element can be under liquid state or in case begin to be employed at least the time (as under one or more high temperature by dry and/or curing) be removed.In some exemplary embodiment, described material can by wet with or the groove extrusion cover, contact in order to make liquid material fill the gap between the adjacent LED assembly and form with LED arrangement the good of soft PCB810 thereon arranged.In some exemplary embodiment, the surface of described inorganic layer 812 can be by veining.In some exemplary embodiment, one or more can the formation by the organic and inorganic mixing material in layered product 806, insulator layer 808 and the high refractive index layer 812 (or its a plurality of versions separately), the specific refractory power of each layer is by the additive adjustment in the mixing solutions.

In some exemplary embodiment, mirror 814 can be positioned between isolator 808 and second substrate 804.In some illustrative examples, mirror 814 can comprise a plurality of thin film layers, for example can comprise a plurality of as Sn, Ag (1000 dusts are thick according to appointment) and Cu (about 350 dusts are thick) by the order that moves apart from second substrate 804.Certainly, other materials also can be used for replacing or being additional to listed exemplary materials.In different exemplary embodiments, also can use the mirror of other types.Mirror 814 can help as radiator element, thereby helps to improve the performance of LED in assembly.

One or more optional layers also can be arranged on the upper strata glass 802.In some exemplary embodiment, CRI matching layer 816 also can be arranged on the upper strata glass 802.The CRI matching layer can comprise the Cd sill, as CdTe nanocrystal, quantum dot matrix etc.In some exemplary embodiment, scatterer and/or antireflection (AR) composite layer can be arranged on the upper strata glass 802.This AR layer can be three layers of AR coating in some exemplary embodiment.As referring to No. the 12/923146th, U.S. Patent application sequence, by reference its full content is included at this.

In some exemplary embodiment, phosphorescent substance can be embedded into or be placed on the cover glass 802 the layer in.The ultraviolet radiation of sending from LED can cause phosphor luminescence.

In some illustrative examples, the low iron glass substrate of first thin (thick as 1mm) can be provided.The anode layer that comprises transparent conductive coating (TCC) can be capped and apply on it, as, in some exemplary embodiment, apply by wet the application.In some illustrative examples, use ionic fluid so that the OCLS planarization is favourable.Cover anode layer and can be dissolved proper circuit figure by laser pattern.The output coupling layer heap (OCLS) that is used for refractive index match TCC can be inserted between first glass substrate and the anode layer.In some exemplary embodiment, for example, can use the anode layer of the described patterning of heat conductivity resin layer package of type described herein.As previously mentioned, this can help to solve the inside junction temperature of LED, thereby increases work efficiency, and all solid state (or roughly all solid state) intermediate or finished product is provided.In some exemplary embodiment, second glass substrate can support mirror paint (for example Al or Cu mirror paint).Substrate can be etched to form the hole, and siccative can be inserted in such hole.OLED and/or ILED can be used in this type of exemplary arrangement.In some exemplary embodiment, can be exchanged in the position of anode and negative electrode.

Fig. 9 is the illustrative ILED structure based on AlGaAs according to some exemplary embodiment.ILED structure shown in Figure 9 comprises a plurality of layers.This layer can comprise AlGaAs or comprise p+layer 902 (for example about 0.3um is thick), the GaAs of AlGaAs or comprise p 904 layers of (for example about 0.2um is thick), AlGaAs of GaAs or comprise n layer 906 (for example about 0.04um is thick), the AlGaAs of AlGaAs or comprise the n+ layer 908 (for example about 0.4um is thick) of AlGaAs by the order that moves apart second substrate 804, and/or the n+ layer of GaAs (for example about 0.03um is thick).In some exemplary embodiment, p contact 910 can be provided on the p layer 902 and contact with it, and n contact 912 can and contact as the superiors with it on one or more n+ layers and provides.As implied above, in some exemplary embodiment, one or more n-and/or other layers can be roughened or etching.In addition, as implied above, in some exemplary embodiment, on wafer scale, can carry out structurizing, etching, patterning and/or similar operations.Although the ILED shown in Fig. 9 is the AlGaAs type, should be understood that the AlGaN heterojunction can be used in different embodiments of the invention.

As above-mentioned, the present inventor recognizes, realizes the cooling technology that provides advanced by using thermoelectric cell, can improve the efficient of LED lighting system.Thermoelectric cell depends on thermoelectric effect, and thermoelectric effect refers to that generally temperature contrast is to voltage and opposite conversion.In such system, in atomic scale, the thermograde that applies can cause the charged carriers (for example electronics or electron hole) in the material to be diffused into cold side from hot side.Therefore, every side temperature thermounit formation voltage simultaneously not.Therefore, this effect can be used for generating electricity.Some exemplary embodiment provides uses thermoelectric (TE) module to improve the technology of the performance of LED basic matrix row in conjunction with superinsulation, but optional in conjunction with printing opacity, vacuum insulated glass building (VIG) monotechnics.

In some exemplary embodiment, vacuum insulated glass building (VIG) unit is used as high thermal resistance (R〉12) medium, is housed in to face sunlight side power on series connection and the parallel thermoelectric juncture array of heat.According to some exemplary embodiment, the R value preferably is at least 10, more preferably is at least 12, even can be higher.These high R values can realize in the VIG unit that transferee of the present invention makes at present.These unit generally adopt the column of flame and low radiation paint.Certainly, the R-value that the IG unit that typical argon gas and/or xenon are filled provides is about 4, can be used for using in conjunction with some exemplary embodiment, so long as the TE coefficient of index Z is brought up to proper level, for example discusses in more detail below.Under any circumstance, R value 10 will provide about 400 degrees centigrade Δ T, and about 12 R value provides about 600 degrees centigrade Δ T.

The number at the juncture of preferred per unit area is provided as certain level makes packing factor less than 20%.Known, packing factor refers to the ratio (representing with per-cent) of actual obtainable peak power and theoretical(horse)power.It will be appreciated, of course, that packing factor can with Z value balance, be similar to as mentioned above.Therefore, when above-mentioned Z value more than or equal to about 10 the time, packing factor can be reduced to less than or equal about 10%.

According to some exemplary embodiment, the VIG unit can be used for a plurality of purposes.For example, the VIG unit can be the TE juncture supporting that can be integrated in the VIG is provided.As another example, the VIG unit can provide very large temperature head by comprise the TE device in VIG unit itself between hot joining chalaza and cold joint chalaza.Big Δ T can help significantly to improve TE efficient conversely.As another example, the VIG unit can provide supporting to flip-chip or mounted LEDs.And for example, the VIG unit can help heat to isolate LED matrix and reduce the possibility that LED reaches the temperature that weakens its operation efficiency.

Figure 10 is the sectional view of showing Active Cooling according to some exemplary embodiment, and this cooling technology is used for using electrothermal module flip-chip mounted LEDs array.Be similar to conventional VIG unit, the exemplary embodiment of Figure 10 comprises outer substrate 1002 and interior substrate 1004.In some exemplary embodiment of the present invention, the one or both in outer substrate 1002 and the interior substrate 1004 can be glass substrate.This substrate is the distance that a plurality of posts 1006 of relation substantially parallel, that be spaced apart from each other help between the outer substrate 1002 of maintenance and the interior substrate 1004.In some exemplary embodiment of the present invention, post 1006 can be sapphire rods.Edge seal 1008 arranges peripheral with sealing VIG unit, for example, makes the cavity between outer substrate 1002 and the interior substrate 1004 be evacuated to pressure less than atmosphere, and/or is filled with one or more gas (as argon gas, xenon and/or analogue).In different embodiments of the invention, outer substrate 1002 and interior substrate 1004 can be identical or different sizes.

Each electrothermal module comprises n leg 1010a and p leg 1010b, and can be made by any suitable material.For example, electrothermal module can be that bismuthino (for example Bi2Te3, Bi2Se3 etc.), tin white cobalt material are (for example with (Co, Ni, Fe) oxide compound of (P, Sb, As) 3 form or analogue) (for example (SrTiO3) n (SrO) m or analogue).Thermoelectric material can be doped in some exemplary embodiment.When the TE material is doped, for example, doping can be carried out classification to be made and mixes more highly near the hot joining chalaza.

The n leg 1010a of module can be connected by conductor 1012 with p-leg 1010b, and this conductor is also referred to as the sooting conductor because of wherein used material sometimes, but its light-permeable still.In some exemplary embodiment, conductor 1012 can be copper-based material (Cu, CuO etc.), frit (as carbon black, as DAG or analogue).In some exemplary embodiment of the present invention, electrothermal module can be screen printed.The size of each module can be selected in conjunction with required packing factor.When the packing factor that uses 20%, for example, can use the module size of the about 1'' * 1'' of general square shape, but other sizes and/or shape can be combined also with current and/or other packing factors.In some exemplary embodiment, post 1006 can be placed after silk screen printing TE material.

In some exemplary embodiment, substrate 1004 in the TE module does not directly contact.On the contrary, in some exemplary embodiment, bus 1014 is arranged between the internal surface (surface 3) and thermoelectric material of interior substrate 1004.Therefore this bus can be transparent, can be or comprises any suitable material, for example, can be or comprises the transparent conductive coating of Ag, ITO, AZO, indium-gallium-oxide compound etc.Electrically conducting coating also can be CNT base, graphene-based etc.Its method of the electrically conducting coating of CNT base/install and make, for example in No. the 12/659352nd, U.S. Patent application sequence, description is arranged, include its whole disclosures in this paper by reference at this, its method of the electrically conducting coating of graphene-based base/install and make, for example in No. the 12/654269th, U.S. Patent application sequence, description is arranged, include its whole disclosures in this paper by reference at this.For helping to promote power transfer, silver or other conductive glass material (not shown) can be provided to the edge near the VIG unit, directly or indirectly contact with bus 1014.In some exemplary embodiment, edge seal 1008 can be formed by electro-conductive material itself, thereby can be used as suitable connection.

Flip-chip mounted LEDs 1016 can be positioned on the conductor 1012.The details of more relevant flip-chip mounted LEDs 1016 can provide hereinafter, for example in conjunction with Figure 12.

Figure 11 is electrically connected in series orthographic plan with parallel hot linked ILED structure according to some exemplary embodiment.The TE module is electrically connected in series, thus the n leg in first module be connected with the p leg of second module (perhaps vice versa) etc. terminal up to delegation or row, adjacent afterwards row or row are connected, and repeat this pattern along new row.The TE module is parallel hot linked, because it all is positioned at the cavity inside of VIG unit.Each side of VIG unit all comprises at least one positive terminal and at least one negative terminal.Therefore, silver-colored frit mentioned above spreads all over the whole periphery of VIG unit basically, is positioned at position that terminal will be provided etc.As shown in figure 11, the satisfied predetermined packing factor (under the situation of this example, being about 20%) thereby the TE module can take up space.

Further details about the TE module can for example find in the U.S. Patent Application Serial Number 12/801257, includes its whole disclosures in this paper by reference at this.

Figure 12 is the sectional view according to the heat sink wafer of flip-chip in some exemplary embodiment.Usually, it is a kind of mounting means for semiconductor device that flip-chip is installed, unicircuit (IC) chip for example, and it can reduce the demand to bonding wire.Last wafer procedure of processing with chip bonding pad that relevant external circuit directly links to each other on the deposit solder salient point.The manufacturing procedure of flip-chip is similar to conventional IC manufacturing.In the latter stage near flip-chip making processes, attached pads is metallized in order to it is more suitable in welding.This metallization comprises several processing usually.At the little solder joint of each pad deposition.By convention, chip is cut out from wafer.Usually do not need other additional processing, and generally do not have mechanical carrier at all yet.When flip-chip is attached on the circuit, it is inverted in order to solder joint is taken to downwards on the electronics or the web member on the circuit card of lower floor.Scolder is formed by refuse and is electrically connected afterwards.This makes the circuit of chip and lower floor produce little space between installing.In most of the cases, use the electrical insulating property caking agent more powerful mechanical connection to be provided, heat bridge to be provided and to guarantee that weld can be because of the differential heating pressure-bearing of chip and this system's rest part then.The assembly of finishing is at last compared with the traditional system based on carrier and is much smaller.Chip is positioned on the circuit card and on area and height and all is much smaller than carrier.

Referring again to Figure 12, substrate 1202 is provided, for example cut from wafer.In some exemplary embodiment, substrate 1202 can be made by sapphire, quartz or any other suitable material.In some exemplary example, outside surface 1202a can be by veining, patterning, embossing etc., for example, and with as described above.Substrate 1202 supportable a plurality of thin film layers, this thin film layer comprises for example n type GaN layer 1204.N type GaN layer 1204 can support n contact 1206 conversely, for example in its periphery supporting.In some exemplary arrangement, at the center of n type GaN layer 1204, can provide a plurality of further films and/or other layers.For example, can provide enliven section 1208, p-type GaN layer 1210 contacts 1212 with p-type.In some exemplary embodiment, n contact 1206 contacts 1212 with p and can be connected to heat sink wafer 1218 by solder ball 1214,1216 respectively.In some exemplary embodiment, GaN and/or other layers can be the InGaN layer.

Figure 13 is the exemplary VIG in conjunction with LED according to exemplary embodiment.Figure 13 is similar to shown in Figure 10, in this Figure 13, comprises substantially parallel and isolated first glass substrate 1302 and second glass substrate 1304.It is suitable to, edge seal 1308 sealed cavities 1310 that a plurality of posts 1306 help first substrate 1302 and second substrate 1304 are maintained.In some exemplary embodiment, under any circumstance, a plurality of LED1312 are by 1304 supportings of second substrate.

In some exemplary embodiment, cavity 1310 can be evacuated to pressure less than atmosphere.In some exemplary embodiment, cavity 1310 can be with suitable gas (for example rare gas element, as Ar, Kr, Xe, Ne, He etc.).Found that in conjunction with some exemplary embodiment He is particularly advantageous, because it is good heat conducting material.Therefore for example, the VIG that comprises He can replace the thermopair in some illustrative examples.

Above-mentioned technology can be used in conjunction with the exemplary embodiment of Figure 13.For example, high refractive index layer can be arranged on the photodiode.In some illustrative examples, removing all or almost all in conjunction with the exemplary embodiment of Figure 13 from above-mentioned mixolimnion (for example when solidifying), organic materials is favourable.Also can use embossing, patterning and/or other technologies.Though not shown, LED 1312 also can be provided on the soft PCB (not shown), for example, in some illustrative examples, LED 1312 can be that flip-chip is mounted thereto.In some exemplary embodiment, LED 1312 can be embedded into the layered product (not shown).

Vacuum insulated glass building (VIG) unit is known in the art.For example, referring to United States Patent (USP) the 5664395th, 5657607 and No. 5902652, the U.S. discloses the 2009/0151854th, 2009/0151855,2009/0151853,2009/0155499, No. 2009/0155500, U.S. Patent application sequence the 12/453220th and No. 12/453221 are included its disclosure in this paper by reference at this.Can use edge seal in conjunction with some embodiment of the present invention, pump and/or other these citing documents in technology/configuration.

Technology described herein can advantageously help to provide the colourity of improvement.Should be appreciated that the in enormous quantities wrapped and/or purchase when the LED quilt, colourity may be different.Some example technique described herein can help to reduce (sometimes or even eliminate) this problem.

Some illustrative embodiments is described about illuminating product.Yet technology described herein can be used to for example other application, as display product (for example for the backlight in LCD and/or other slab design), and running gear, decoration element (for example window, door, skylight, the side of a ship etc.) etc.

In some exemplary embodiment, lambert's type or non-lambert's type light source can be disposed on flat, the generally flat or crooked substrate.Therefore, be appreciated that means of illumination can comprise flat, generally flat or crooked substrate.

Term used herein " be positioned at ... on ", " by ... the supporting " and similar word should not be understood that two elements are directly adjacent one another are, unless offer some clarification on.In other words, the first layer can be described as " being positioned at " second layer " on " or " by " second layer " supporting ", even one or more layers are arranged therebetween.

Though invention is considered to the most practical, most preferred embodiment and is described in conjunction with current, should be appreciated that to the invention is not restricted to illustrated embodiment that on the contrary, various modifications and the equivalence that should cover within the spirit and scope in the appending claims are arranged.

Claims (20)

1. a making comprises the method for the coated article of the substrate that supports coating, and described method comprises:

Precursor based on titanium is provided;

Inner complex is provided;

Make the reaction of described precursor based on titanium and described inner complex, contain material to form the chelating titanium;

Organic resin material is provided;

Make described chelating titanium containing material and described organic resin material crosslinked, to form the organic and inorganic mixing solutions; With

Settle the organic and inorganic mixing solutions to form coating at substrate.

2. the method for claim 1, wherein described arrangement step relates to groove pressure organic and inorganic mixing solutions.

3. any one described method in the claim as described above further comprises:

Dry and/or solidify described organic and inorganic mixing solutions in forming coating.

4. any one described method in the claim as described above further comprises:

Be lower than dry described organic and inorganic mixing solutions under about 250 degrees centigrade temperature;

Be at least the described organic and inorganic mixing solutions of curing under about 300 degrees centigrade temperature.

5. any one described method in the claim as described above further comprises:

The introducing of organic and inorganic mixing solutions can be rolled over thin-medium, and the described thin-medium of rolling over is positioned on the substrate during described arrangement step.

6. any one described method in the claim as described above, wherein, described arrangement step can be rolled over thin-medium and carries out by being squeezed out at substrate.

7. any one described method in the claim as described above, wherein, described to roll over thin-medium be EVA or comprise EVA.

8. any one described method in the claim as described above, wherein, the described thin-medium of rolling over comprises siloxanes.

9. any one described method in the claim as described above, wherein, described precursor based on titanium is titan-alkoxide.

10. any one described method in the claim as described above, wherein, described reactions steps converts the four-coordination Ti species in the titan-alkoxide to inactive relatively hexa-coordinate species, generates chelating poly-(dibutyl titanic acid ester).

11. any one described method in the claim as described above, wherein, described inner complex is Whitfield's ointment.

12. any one described method in the claim as described above, wherein, described organic resin is that hydroxyl contains organic resin.

13. any one described method in the claim as described above, wherein, described coating has and is at least 1.8 specific refractory power.

14. any one described method in the claim as described above further comprises:

One or more other inorganic materials are introduced described organic and inorganic mixing solutions, to adjust the specific refractory power of coating.

15. any one described method in the claim as described above further comprises:

The organic and inorganic mixing solutions is introduced in scattering of light and/or heat dissipation element.

16. a making comprises the method for the coated article of the substrate that supports coating, described method comprises:

The organic and inorganic mixing solutions is provided, and described organic and inorganic mixing solutions is made by following steps:

Make based on the precursor of titanium and/or zirconium and inner complex reaction, with form the chelating material and

Make described chelating material and organic materials crosslinked to form the organic and inorganic mixing solutions;

(a) at the wet organic and inorganic mixing solutions of using of substrate, perhaps (b) squeezes out described organic and inorganic mixing solutions introducing mounting medium to substrate with mounting medium then; With

In case be arranged on the substrate curing organic-inorganic mixing solutions.

17. a method of making electronic installation, described method comprises:

Substrate is provided;

Settle at least one LED at substrate;

The organic and inorganic mixing solutions is provided, and described organic and inorganic mixing solutions is made by following steps:

Make based on the precursor of titanium and/or zirconium and inner complex reaction, with form the chelating material and

Make described chelating material and organic materials crosslinked to form the organic and inorganic mixing solutions;

(a) the wet organic and inorganic mixing solutions of using at least one LED on the substrate, perhaps (b) introduces mounting medium with described organic and inorganic mixing solutions and then mounting medium squeezed out to the substrate at least one LED; With

In case be arranged on the substrate curing organic-inorganic mixing solutions.

18. method as claimed in claim 17 further comprises:

In case be arranged on the substrate, be lower than dry organic and inorganic mixing solutions under about 250 degrees centigrade temperature.

19. as claim 17 or 18 described methods, wherein, described mounting medium is EVA, siloxanes or aromatic poly.

20. as claim 17,18 or 19 described methods, wherein, described coating has at least 1.8 specific refractory power.

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