CN102372440A - Insulating ultraviolet-proof baste of window glass - Google Patents
Insulating ultraviolet-proof baste of window glass Download PDFInfo
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- CN102372440A CN102372440A CN2010102607970A CN201010260797A CN102372440A CN 102372440 A CN102372440 A CN 102372440A CN 2010102607970 A CN2010102607970 A CN 2010102607970A CN 201010260797 A CN201010260797 A CN 201010260797A CN 102372440 A CN102372440 A CN 102372440A
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- baste
- ultraviolet
- heat insulation
- tungsten oxide
- resin
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Abstract
The invention discloses an insulating ultraviolet-proof baste of the window glass. The baste comprises the following components by weight percent: 14%-18% of mixed slurry of 5-10nm of nanometer tungstic oxide and indium antimony oxide, 1%-3% of resin and 79%-85% of thinner. The insulating ultraviolet-proof baste of the window glass is characterized by good heat insulation property, high transparency, good ultraviolet-proof effect, convenient construction, high cost performance and the like, and can be widely used in the windows of means of transport such as automobiles, trains and planes.
Description
Technical field
The present invention relates to a kind of heat insulation anti-ultraviolet baste of sight glass; This kind baste has characteristics such as thermal insulation is good, high, the anti-ultraviolet of the transparency is effective, easy construction, cost performance height, can be widely used in the form of the vehicles such as automobile, train, aircraft.
Background technology
Along with the development of society and the progress of science and technology, automobile, train, aircraft etc. all become the vehicles, the especially automobile of people's life, work and tourism gradually, and at present, the annual only Absatzvolumen of car in the whole world reaches 80,000,000.For safety traffic, flight and daylighting etc.; Automobile, train still are that aircraft all is equipped with the polylith form; Form provides the guarantee of safety traffic, flight to the driver, still, and when The sun is shining fiercely; Same form makes the driver enjoy again and decocts: the solar infrared that sees through form rises sharply the driving room temp, makes the extremely hot difficult retaining of driver; The ultraviolet ray that sees through makes the long spot of the irradiated skin of driver, and is serious, becomes skin carcinoma, and driver's health receives serious threat.Also have and drive seat and jewelry in the ultraviolet easy ageing car.Certainly, the wheel house temperature rises, and can turn on the aircondition, and whole heat is all turned on the aircondition, and how much energy that must consume, moreover annual so much automobile, obviously runs counter to the energy-saving and emission-reduction of whole world promotion.Most critical is the health that how to ensure the driver.
In the prior art, the heat insulation and anti-ultraviolet of vehicle glass adopts usually installs metal coating glass or pastes thermal isolation film or the method solution of coating thermal insulating coating, but there is deficiency separately in they, are not suitable for extensive popularization.At first, metal coating glass is installed, has been played heat insulation and anti-ultraviolet effect, still, the deficiency that metal coating glass exists: cost is high; Inconvenient installation is sharp; High-reflectivity to visible light causes " light pollution ", and the driver who is come in the opposite is dazzled, and causes traffic hazard easily.Secondly, on the form of automobile, paste thermal isolation film, when playing heat-blocking action; Basically visible light transmissivity is lower; Generally below 50%, if visible light transmissivity surpasses 50%, heat-proof quality is just poor; Can't resolve existing high transmission rate has high heat insulation rate again, simultaneously positive factory valuable product.Moreover, on the form of automobile, applying thermal insulating coating, site operation is difficulty very; Require workmen's technology consummate especially; Otherwise occur bad phenomenon such as spot, striped, orange peel line easily, for the form of the vehicles, such phenomenon is unacceptable; Phenomenons such as orange peel line are easy to make driver's eye strain, cause traffic hazard easily.
Summary of the invention
Technical problem to be solved by this invention is in order to overcome the deficiency that above-mentioned technology exists, and has proposed that a kind of thermal insulation is good, high, the anti-ultraviolet of the transparency is effective, the heat insulation anti-ultraviolet baste of easy construction, form that cost performance is high.
For solving the problems of the technologies described above; The present invention adopts following technical scheme: a kind of heat insulation anti-ultraviolet baste of form; By particle diameter is that nanometer tungsten oxide and Indium sesquioxide antimony mixed slurry, resin and the thinner of 5～10nm formed, and wherein: the weight percent of nanometer tungsten oxide and Indium sesquioxide antimony mixed slurry, resin and thinner is respectively 14%～18%, 1%～3% and 79%～85%; Wherein: be fit to nanometer tungsten oxide (WO of the present invention
3) be the alcohol solution or the aqueous solution of solid content 30%, nano indium oxide antimony (ITO) is the aqueous solution or the alcohol solution of solid content 30%, this alcohols is propyl carbinol or ethanol; Be fit to resin of the present invention and be selected from silicone resin, modified organic silicone resin and vinyl resin; Be fit to thinner of the present invention and be selected from alcohols and water, this alcohols is propyl carbinol or ethanol.
Preferably; In the above-mentioned baste of the present invention; The ratio of nanometer tungsten oxide alcohols (water) solution and nano indium oxide antimony water (alcohols) solution is (1 ± 0.2) in nanometer tungsten oxide and the Indium sesquioxide antimony mixed slurry: (1 ± 0.2); Nanometer tungsten oxide alcohols (water) solution and nano indium oxide antimony water (alcohols) solution are produced by Shanghai Huzheng Nano-Tech Co., Ltd.; Production process does not have special feature; Comprise the steps: with particle diameter to be that 300～500nm, weight part are 5～30 parts of nanometer tungsten oxides or nano indium oxide antimony powder body, weight part is 40～70 parts of propyl carbinols or ethanol, and weight part is that 1～2 part of polymer-type ion dispersion agent mixes with other auxiliary agents; On high speed dispersor, ball mill, disperse certain hour, can obtain particle diameter is that 5～10nm, solid content are 30% nanometer tungsten oxide alcohols (water) solution or nano indium oxide antimony water (alcohols) solution.
Preferably, in the above-mentioned baste of the present invention, the solid content of modified organic silicone resin is 16%, is commercially available article.
Preferably, in the above-mentioned baste of the present invention, alcohols is propyl carbinol or ethanol in the thinner, and wherein, the ratio of alcohols and water is (40% ± 5%): (60% ± 5%), alcohols are commercially available article, and water is vaal water.
The preparation process of the above-mentioned baste of the present invention does not have special feature, take by weighing nanometer tungsten oxide and Indium sesquioxide antimony mixed slurry, resin and thinner by weight percentage after, adopt ordinary skill in the art means mixed dissolution to get final product.
The heat insulation anti-ultraviolet baste of form provided by the invention; When construction; Only need dip in wet this baste with sponge, paper, chemical fiber fabric etc., smear arbitrarily in the form inboard of the vehicles such as automobile, train, aircraft then to get final product, and bad phenomenon such as spot, striped, orange peel line can not occur.
Embodiment subsequently will prove that the heat insulation anti-ultraviolet baste of form of the present invention has characteristics such as thermal insulation is good, high, the anti-ultraviolet of the transparency is effective, easy construction, cost performance height, can be widely used in the form of the vehicles such as automobile, train, aircraft.After smearing form, obtain following result through test: visible light transmissivity is greater than 88%, and heat insulation rate is 50%～60%, and the ultraviolet isolating rate is greater than 97%.
Embodiment
Below in conjunction with embodiment the present invention is described further, these embodiment are interpreted as only being used to the present invention is described and are not used in restriction protection scope of the present invention.After the content of having read the present invention's record, those skilled in the art can do various changes or modification to the present invention, and these equivalences change and modification falls into scope thereof of the present invention equally.
Embodiment 1
Take by weighing nanometer WO respectively
3Ethanolic soln 78g, nano-ITO aqueous solution 82g, modified organic silicone resin 18g, propyl carbinol: 328g, deionized water: 494g joins in the container, and stirring gets final product.
Embodiment 2
Take by weighing nanometer WO respectively
3Aqueous solution 85g, nano-ITO butanol solution 72g, modified organic silicone resin 21g, propyl carbinol: 369g, deionized water: 453g joins in the container, and stirring gets final product.
Embodiment 3
Take by weighing nanometer WO respectively
3Butanol solution 85g, nano-ITO aqueous solution 85g, modified organic silicone resin 25g, ethanol: 322g, deionized water: 473g joins in the container, and stirring gets final product.
Embodiment 4
Take by weighing nanometer WO respectively
3Aqueous solution 82g, nano-ITO ethanolic soln 75g, modified organic silicone resin 15g, propyl carbinol: 331g, deionized water: 497g joins in the container, and stirring gets final product.
The heat insulation anti-ultraviolet baste of the form for preparing the foregoing description 1 to 4 respectively is applied on the form of automobile, according to this area usual method the form after smearing is carried out optical performance test then, obtains the result and sees the following form 1.
Table 1. is smeared the optical property of the form behind this baste
Can find out that from table 1 the heat insulation anti-ultraviolet baste of the form for preparing through the inventive method is applied in the form, have characteristics such as thermal insulation is good, high, the anti-ultraviolet of the transparency is effective.
Claims (5)
1. the heat insulation anti-ultraviolet baste of a sight glass; It is characterized in that; By particle diameter is that nanometer tungsten oxide and Indium sesquioxide antimony mixed slurry, resin and the thinner of 5～10nm formed; The weight percent of nanometer tungsten oxide and Indium sesquioxide antimony mixed slurry, resin and thinner is respectively 14%～18%, 1%～3% and 79%～85%, and wherein: nanometer tungsten oxide is the alcohol solution or the aqueous solution of solid content 30%, and nanometer tungsten oxide is the aqueous solution or the alcohol solution of solid content 30%; Resin is selected from silicone resin, modified organic silicone resin and vinyl resin; Thinner is selected from alcohols and water.
2. the heat insulation anti-ultraviolet baste of sight glass according to claim 1 is characterized in that, the alcohols in nanometer tungsten oxide and the Indium sesquioxide antimony alcohol solution is propyl carbinol or ethanol.
3. the heat insulation anti-ultraviolet baste of sight glass according to claim 1 is characterized in that, the weight ratio of nanometer tungsten oxide and nano indium oxide antimony is (1 ± 0.2) in nanometer tungsten oxide and the Indium sesquioxide antimony mixed slurry: (1 ± 0.2).
4. the heat insulation anti-ultraviolet baste of sight glass according to claim 1 is characterized in that, the solid content of modified organic silicone resin is 16%.
5. the heat insulation anti-ultraviolet baste of sight glass according to claim 1 is characterized in that, alcohols is propyl carbinol or ethanol in the thinner, and the weight ratio of alcohols and water is (40% ± 5%): (60% ± 5%).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010260797 CN102372440B (en) | 2010-08-24 | 2010-08-24 | Insulating ultraviolet-proof baste of window glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010260797 CN102372440B (en) | 2010-08-24 | 2010-08-24 | Insulating ultraviolet-proof baste of window glass |
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| Publication Number | Publication Date |
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| CN102372440A true CN102372440A (en) | 2012-03-14 |
| CN102372440B CN102372440B (en) | 2013-09-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010260797 Active CN102372440B (en) | 2010-08-24 | 2010-08-24 | Insulating ultraviolet-proof baste of window glass |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708875A (en) * | 2013-12-13 | 2015-06-17 | 精磁科技股份有限公司 | Antifog heat insulating film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416818B1 (en) * | 1998-08-17 | 2002-07-09 | Nanophase Technologies Corporation | Compositions for forming transparent conductive nanoparticle coatings and process of preparation therefor |
| CN101306834A (en) * | 2007-05-29 | 2008-11-19 | 长沙美丰纳米科技有限公司 | High heat insulation nano composite material and method for preparing heat insulation products |
| CN101558336A (en) * | 2006-12-14 | 2009-10-14 | 贝卡尔特股份有限公司 | A solar control film |
-
2010
- 2010-08-24 CN CN 201010260797 patent/CN102372440B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416818B1 (en) * | 1998-08-17 | 2002-07-09 | Nanophase Technologies Corporation | Compositions for forming transparent conductive nanoparticle coatings and process of preparation therefor |
| CN101558336A (en) * | 2006-12-14 | 2009-10-14 | 贝卡尔特股份有限公司 | A solar control film |
| CN101306834A (en) * | 2007-05-29 | 2008-11-19 | 长沙美丰纳米科技有限公司 | High heat insulation nano composite material and method for preparing heat insulation products |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708875A (en) * | 2013-12-13 | 2015-06-17 | 精磁科技股份有限公司 | Antifog heat insulating film |
| CN104708875B (en) * | 2013-12-13 | 2017-06-30 | 精磁科技股份有限公司 | Antifog heat insulating film |
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| Publication number | Publication date |
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| CN102372440B (en) | 2013-09-11 |
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Effective date of registration: 20191211 Address after: 201404 Shanghai, Fengxian District layered Road, No. 5, building 585 Patentee after: Shanghai Shanghai Industrial Co., Ltd. Address before: 201204 Shanghai city Pudong New Area Lianxi Road No. 1151 Patentee before: Shanghai Huzheng Nano-Tech Co., Ltd. |