CA2558804A1 - Composite materials of nano-dispersed silicon and tin and methods of making the same - Google Patents

Composite materials of nano-dispersed silicon and tin and methods of making the same Download PDF

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Publication number
CA2558804A1
CA2558804A1 CA002558804A CA2558804A CA2558804A1 CA 2558804 A1 CA2558804 A1 CA 2558804A1 CA 002558804 A CA002558804 A CA 002558804A CA 2558804 A CA2558804 A CA 2558804A CA 2558804 A1 CA2558804 A1 CA 2558804A1
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compound
lithium
tin
silicon
li2o
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CA002558804A
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French (fr)
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CA2558804C (en
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Yuan Gao
Daniel Diesburg
John Engel
Marina Yakovleva
Brian Fitch
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Livent USA Corp
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Individual
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/02—Silicon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G19/00—Compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/387—Tin or alloys based on tin
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

Abstract

Composite compounds of tin and lithium, silicon and lithium, or tin, silicon, and lithium having tin and silicon nano-dispersed in a lithium-containing matrix may be used as electrode materials and particularly anode materials for use with rechargeable batteries. Methods of making the composite compounds include the oxidation of alloys, the reaction of stabilized lithium metal powder with tin and silicon oxides, and the reaction of inorganic salts of lithium with tin and silicon containing compounds.

Claims (16)

1. A compound, comprising silicon and/or tin nano-dispersed within a lithium-containing framework.
2. The compound of Claim 1, wherein the compound is single phase or multi-phase.
3. The compound of Claim 1, wherein the compound is selected from the group consisting of Si:Li2O, Si:2Li2O, Si:3Li2O, and SiSn:3Li2O.
4. The compound of Claim 1, wherein the compound comprises a compound represented by the formula Sn1-X Si X:.alpha.Li2O, wherein 0 <= x <= 1 and 1 <= .alpha. <= 3.
5. The compound of Claim 1, wherein the compound comprises a compound represented by the formula Sn1-X Si X:.alpha.Li2O + .gamma.Sn1-y Si y:.beta.Li2O, wherein 0 <= x <= 1,1 <= .alpha. <= 3,0 <= y <=1,1<=.beta.<=3,and 0 < .gamma. < 1.
6. The compound of Claim 1, wherein at least a portion of the lithium-containing framework is formed from a stabilized lithium metal powder.
7. The compound of Claim 1, wherein at least a portion of the lithium-containing framework is formed from a lithium oxide.
8. The compound of Claim 6, wherein the compound is single phase or multi-phase.
9. The compound of Claim 6, wherein the compound is selected from the group consisting of Sn:Li2O, Sn:2Li2O, Sn:3Li2O, and SiSn:3Li2O.
10. The compound of Claim 6, wherein the compound comprises a compound represented by the formula Sn1-X Si X:.alpha.Li2O, wherein 0 <= x <= 1 and 1 <= .alpha. <= 3.
11. The compound of Claim 7, wherein the compound is represented by the formula Sn1-X Si X:.alpha.Li2O + .gamma.Sn1-y Si y:.beta.Li2O, wherein 0 <= x <= 1,1 <= .alpha. <= 3,0 <= y <= 1,1 <=
.beta. <= 3, and 0 < .gamma. <
1.
12. The compound of Claim 1, wherein said lithium-containing framework comprises a matrix selected from the group consisting of lithium oxide, lithium fluoride, lithium carbonate, lithium phosphate, lithium silicate, and lithium sulfate.
13. A method for forming a compound comprising silicon and/or tin nano-dispersed in a lithium-containing structure, comprising reacting an oxide of silicon and/or tin with a lithium-containing compound.
14. The method of Claim 13, wherein the lithium-containing compound is stabilized lithium metal powder.
15. A method for forming a compound comprising silicon or tin nano-dispersed in a lithium oxide fluoride or carbonate structure, comprising exposing an alloy comprising silicon and/or tin and lithium to oxygen, fluoride or carbon to oxidize, fluorinate or carbonate at least a portion of the lithium.
16. A battery, comprising an anode having tin or silicon nanoparticles dispersed in a lithium oxide matrix.
CA2558804A 2004-04-15 2005-04-15 Composite materials of nano-dispersed silicon and tin and methods of making the same Expired - Fee Related CA2558804C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US56267904P 2004-04-15 2004-04-15
US60/562,679 2004-04-15
US11/106,225 2005-04-14
US11/106,225 US8231810B2 (en) 2004-04-15 2005-04-14 Composite materials of nano-dispersed silicon and tin and methods of making the same
PCT/US2005/012848 WO2006078269A2 (en) 2004-04-15 2005-04-15 Composite materials of nano-dispersed silicon and tin and methods of making the same

Publications (2)

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CA2558804A1 true CA2558804A1 (en) 2006-07-27
CA2558804C CA2558804C (en) 2012-10-30

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US (3) US8231810B2 (en)
EP (1) EP1735859B1 (en)
JP (2) JP5508675B2 (en)
KR (1) KR101166900B1 (en)
CA (1) CA2558804C (en)
DE (1) DE112005000762T5 (en)
GB (2) GB2425398B (en)
RU (1) RU2370858C2 (en)
WO (1) WO2006078269A2 (en)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2395059B (en) * 2002-11-05 2005-03-16 Imp College Innovations Ltd Structured silicon anode
KR100595896B1 (en) * 2003-07-29 2006-07-03 주식회사 엘지화학 A negative active material for lithium secondary battery and a method for preparing same
US7968233B2 (en) 2004-02-18 2011-06-28 Solicore, Inc. Lithium inks and electrodes and batteries made therefrom
US8231810B2 (en) * 2004-04-15 2012-07-31 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
FR2873855B1 (en) * 2004-07-30 2006-12-08 Cnes Epic NEGATIVE ELECTRODE COMPOSITE MATERIAL, MANUFACTURING METHOD, NEGATIVE ELECTRODE AND LITHIUM-ION BATTERY
GB0601318D0 (en) 2006-01-23 2006-03-01 Imp Innovations Ltd Method of etching a silicon-based material
GB0601319D0 (en) * 2006-01-23 2006-03-01 Imp Innovations Ltd A method of fabricating pillars composed of silicon-based material
US7776473B2 (en) * 2006-03-27 2010-08-17 Shin-Etsu Chemical Co., Ltd. Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
US8039152B2 (en) * 2007-04-03 2011-10-18 Toyota Motor Engineering & Manufacturing North America, Inc. Tin in an active support matrix
GB0709165D0 (en) 2007-05-11 2007-06-20 Nexeon Ltd A silicon anode for a rechargeable battery
GB0713896D0 (en) * 2007-07-17 2007-08-29 Nexeon Ltd Method
GB0713898D0 (en) * 2007-07-17 2007-08-29 Nexeon Ltd A method of fabricating structured particles composed of silcon or a silicon-based material and their use in lithium rechargeable batteries
GB0713895D0 (en) * 2007-07-17 2007-08-29 Nexeon Ltd Production
US20090191458A1 (en) * 2007-07-23 2009-07-30 Matsushita Electric Industrial Co., Ltd. Porous network negative electrodes for non-aqueous electrolyte secondary battery
US8871024B2 (en) * 2008-06-05 2014-10-28 Soraa, Inc. High pressure apparatus and method for nitride crystal growth
WO2010014966A1 (en) * 2008-08-01 2010-02-04 Seeo, Inc High capacity anodes
US9882241B2 (en) 2008-08-01 2018-01-30 Seeo, Inc. High capacity cathode
GB2464157B (en) 2008-10-10 2010-09-01 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material
GB2464158B (en) 2008-10-10 2011-04-20 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries
WO2010091116A2 (en) * 2009-02-03 2010-08-12 The Florida International University Board Of Trustees Method of forming an anode material for a lithium ion battery
GB2470056B (en) 2009-05-07 2013-09-11 Nexeon Ltd A method of making silicon anode material for rechargeable cells
GB2470190B (en) 2009-05-11 2011-07-13 Nexeon Ltd A binder for lithium ion rechargeable battery cells
US9853292B2 (en) 2009-05-11 2017-12-26 Nexeon Limited Electrode composition for a secondary battery cell
FR2951714B1 (en) * 2009-10-27 2013-05-24 Electricite De France ELECTROCHEMICAL DEVICE WITH SOLID ELECTROLYTE CONDUCTING IONS ALKALI AND AQUEOUS ELECTROLYTE
JP5411780B2 (en) * 2010-04-05 2014-02-12 信越化学工業株式会社 Anode material for non-aqueous electrolyte secondary battery, method for producing anode material for non-aqueous electrolyte secondary battery, and lithium ion secondary battery
GB201005979D0 (en) 2010-04-09 2010-05-26 Nexeon Ltd A method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries
GB201009519D0 (en) 2010-06-07 2010-07-21 Nexeon Ltd An additive for lithium ion rechargeable battery cells
GB201014706D0 (en) 2010-09-03 2010-10-20 Nexeon Ltd Porous electroactive material
GB201014707D0 (en) 2010-09-03 2010-10-20 Nexeon Ltd Electroactive material
FR2965106B1 (en) * 2010-09-17 2015-04-03 Commissariat Energie Atomique ELECTRODE FOR AN ALL SOLID LITHIUM BATTERY AND METHOD FOR PRODUCING SUCH ELECTRODE
US9054373B2 (en) 2010-10-01 2015-06-09 Uchicago Argonne, Llc Anode materials for lithium ion batteries
US20120121976A1 (en) * 2010-11-16 2012-05-17 Panasonic Corporation Porous network negative electrodes for non-aqueous electrolyte secondary battery
DE102011011155A1 (en) * 2011-02-14 2012-08-16 Li-Tec Battery Gmbh Process for the production of electrodes
DE102011011154A1 (en) * 2011-02-14 2012-08-16 Li-Tec Battery Gmbh Process for the production of electrodes
US20130106029A1 (en) * 2011-10-27 2013-05-02 Infinite Power Solutions, Inc. Fabrication of High Energy Density Battery
JP5912493B2 (en) * 2011-12-15 2016-04-27 出光興産株式会社 Composition comprising lithium particles, electrode and battery
JP5440661B2 (en) * 2012-06-27 2014-03-12 株式会社豊田自動織機 Silicon-containing material and active material for secondary battery containing silicon-containing material
US10381640B2 (en) * 2012-08-27 2019-08-13 Nippon Steel Corporation Negative electrode active material
JP6264299B2 (en) * 2012-12-17 2018-01-24 日本電気株式会社 Negative electrode material for lithium ion secondary battery and evaluation method thereof
US10340531B2 (en) * 2013-03-08 2019-07-02 Eaglepicher Technologies Llc Li—Si—Sn alloy, anode material of the alloy, and batteries including same
DE102013014627A1 (en) * 2013-08-30 2015-03-05 Volkswagen Aktiengesellschaft Pre-lithiation of silicon particles
EP3103151B1 (en) * 2014-02-03 2019-09-04 Ramot at Tel-Aviv University Ltd. Electrode compositions and alkali metal batteries comprising same
WO2015114640A1 (en) 2014-02-03 2015-08-06 Ramot At Tel-Aviv University Ltd. Anode compositions and alkali metal batteries comprising same
JP6176511B2 (en) * 2014-05-29 2017-08-09 株式会社豊田自動織機 Silicon material and negative electrode of secondary battery
JP5971279B2 (en) * 2014-05-30 2016-08-17 エス・イー・アイ株式会社 Method for producing electrode material
DE102014214899A1 (en) * 2014-07-30 2016-02-04 Bayerische Motoren Werke Aktiengesellschaft Composite electrode for an electrochemical cell and electrochemical cell
US9966598B2 (en) * 2014-09-30 2018-05-08 The Board Of Trustees Of The Leland Stanford Junior University High capacity prelithiation reagents and lithium-rich anode materials
US9780361B2 (en) * 2014-11-12 2017-10-03 GM Global Technology Operations LLC Methods for forming porous materials
CN107112534B (en) * 2015-01-28 2021-06-25 三洋电机株式会社 Negative electrode active material for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery
TWI692903B (en) * 2015-03-02 2020-05-01 香港商艾鷗電池有限公司 Silicon: silicon oxide: lithium composite material having nano silicon particles embedded in a silicon: silicon lithium silicate composite matrix, and a process for manufacture thereof
WO2016154617A1 (en) 2015-03-26 2016-09-29 David Mitlin Anodes for batteries based on tin-germanium-antimony alloys
US11398627B2 (en) * 2015-06-12 2022-07-26 The Board Of Trustees Of The Leland Stanford Junior University Cathode additives for lithium-ion batteries
US10468668B1 (en) * 2015-08-27 2019-11-05 Binergy Scientific, Inc. Methods and compositions for anode and cathode nanocomposite materials for thermal batteries
CN109923706B (en) * 2016-09-02 2022-01-04 香港商Eo细胞有限公司 Silicon-silicon oxide-lithium composite material with volume change compensation and preparation method thereof
WO2018081224A1 (en) 2016-10-26 2018-05-03 The Regents Of The University Of Michigan Metal infiltrated electrodes for solid state batteries
FI129862B (en) * 2018-10-24 2022-10-14 Broadbit Batteries Oy Improved anode material and anode for a rechargeable battery, a method of production thereof and an electrochemical cell made therefrom
JP7284692B2 (en) 2019-11-26 2023-05-31 住友化学株式会社 Method for producing aromatic alcohol
CN113809285B (en) * 2020-06-12 2023-08-08 比亚迪股份有限公司 Silicon-based composite anode material, preparation method thereof and all-solid-state lithium battery
CN113809309B (en) * 2020-06-12 2023-08-08 比亚迪股份有限公司 Silicon-based composite anode material, preparation method thereof and all-solid-state lithium battery
CN113809330B (en) * 2020-06-12 2023-08-08 比亚迪股份有限公司 Silicon-based composite anode material, preparation method thereof and all-solid-state lithium battery
CN117897832A (en) 2022-08-15 2024-04-16 太克万株式会社 Composite material and method for producing composite material

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3271196A (en) 1961-11-08 1966-09-06 Leesona Corp Fuel cell electrodes
US3508967A (en) 1967-09-22 1970-04-28 Gulton Ind Inc Negative lithium electrode and electrochemical battery containing the same
JPS58199806A (en) 1982-05-17 1983-11-21 Toshiba Corp Production of metallic lithium powder
JPH0789483B2 (en) 1984-05-07 1995-09-27 三洋化成工業株式会社 Secondary battery
DE3680249D1 (en) 1985-05-10 1991-08-22 Asahi Chemical Ind SECONDARY BATTERY.
JPH063745B2 (en) 1986-07-02 1994-01-12 シャープ株式会社 Non-aqueous electrolyte secondary battery
JPS63178449A (en) 1987-01-16 1988-07-22 Hitachi Maxell Ltd Nonaqueous electrolyte secondary battery
US4945014A (en) 1988-02-10 1990-07-31 Mitsubishi Petrochemical Co., Ltd. Secondary battery
US5028500A (en) 1989-05-11 1991-07-02 Moli Energy Limited Carbonaceous electrodes for lithium cells
JPH0439859A (en) 1990-06-04 1992-02-10 Mitsubishi Petrochem Co Ltd Secondary battery electrode
US5153082A (en) 1990-09-04 1992-10-06 Bridgestone Corporation Nonaqueous electrolyte secondary battery
JP3133318B2 (en) 1990-09-18 2001-02-05 三洋電機株式会社 Rechargeable battery
JP3162437B2 (en) 1990-11-02 2001-04-25 セイコーインスツルメンツ株式会社 Non-aqueous electrolyte secondary battery
JP3126030B2 (en) 1990-11-22 2001-01-22 大阪瓦斯株式会社 Lithium secondary battery
US5244757A (en) 1991-01-14 1993-09-14 Kabushiki Kaisha Toshiba Lithium secondary battery
DE4101533A1 (en) 1991-01-19 1992-07-23 Varta Batterie ELECTROCHEMICAL SECONDARY ELEMENT
JP3291750B2 (en) 1992-02-25 2002-06-10 松下電器産業株式会社 Non-aqueous electrolyte secondary battery and method of manufacturing the same
US5340670A (en) 1992-06-01 1994-08-23 Kabushiki Kaisha Toshiba Lithium secondary battery and method of manufacturing carbonaceous material for negative electrode of the battery
DE69325006T2 (en) 1992-12-07 1999-09-23 Honda Motor Co Ltd Alkaline ion absorbing / desorbing carbonaceous material, electrode material for secondary battery using this material and lithium battery using this electrode material
AU6128994A (en) * 1993-02-18 1994-09-14 Fmc Corporation Alkali metal dispersions
US5312623A (en) 1993-06-18 1994-05-17 The United States Of America As Represented By The Secretary Of The Army High temperature, rechargeable, solid electrolyte electrochemical cell
CA2127621C (en) 1994-07-08 1999-12-07 Alfred Macdonald Wilson Carbonaceous insertion compounds and use as anodes in rechargeable batteries
JPH08213052A (en) 1994-08-04 1996-08-20 Seiko Instr Inc Nonaqueous electrolyte secondary battery
US5543021A (en) 1994-09-01 1996-08-06 Le Carbone Lorraine Negative electrode based on pre-lithiated carbonaceous material for a rechargeable electrochemical lithium generator
FR2724490B1 (en) 1994-09-09 1996-10-25 Lorraine Carbone CARBON / POLYMER COMPOSITE ELECTRODE FOR LITHIUM RECHARGEABLE ELECTROCHEMICAL GENERATOR
US5707756A (en) 1994-11-29 1998-01-13 Fuji Photo Film Co., Ltd. Non-aqueous secondary battery
JP3092041B2 (en) * 1994-11-30 2000-09-25 日本原子力研究所 Method for producing Li2O particles
US5595837A (en) 1995-04-12 1997-01-21 Valence Technology, Inc. Process for prelithiation of carbon based anodes for lithium batteries
JP3158981B2 (en) * 1995-08-17 2001-04-23 東ソー株式会社 Manufacturing method of non-aqueous lithium battery
US5753387A (en) 1995-11-24 1998-05-19 Kabushiki Kaisha Toshiba Lithium secondary battery
US5672446A (en) 1996-01-29 1997-09-30 Valence Technology, Inc. Lithium ion electrochemical cell
US5958622A (en) 1996-03-28 1999-09-28 Kabushiki Kaisha Toyota Chuo Kenkyusho Negative electrode material for lithium secondary batteries
JPH10117406A (en) 1996-06-14 1998-05-06 Fuji Photo Film Co Ltd Electric car and its drive power source unit
US6270926B1 (en) 1996-07-16 2001-08-07 Murata Manufacturing Co., Ltd. Lithium secondary battery
EP0948825B1 (en) 1996-12-20 2001-06-27 Danionics A/S Lithium secondary battery with flake graphite negative electrode
JPH10223259A (en) 1997-02-03 1998-08-21 Toyota Central Res & Dev Lab Inc Lithium secondary battery and manufacture thereof
US6387564B1 (en) 1997-02-28 2002-05-14 Asahi Kasei Kabushiki Kaisha Non-aqueous secondary battery having an aggregation layer
US6156457A (en) 1997-03-11 2000-12-05 Kabushiki Kaisha Toshiba Lithium secondary battery and method for manufacturing a negative electrode
JP3200025B2 (en) 1997-03-26 2001-08-20 セイコーインスツルメンツ株式会社 Non-aqueous electrolyte secondary battery
US5807645A (en) 1997-06-18 1998-09-15 Wilson Greatbatch Ltd. Discharge promoter mixture for reducing cell swelling in alkali metal electrochemical cells
JPH1125975A (en) 1997-07-02 1999-01-29 Toyota Central Res & Dev Lab Inc Negative electrode active material
US5948569A (en) 1997-07-21 1999-09-07 Duracell Inc. Lithium ion electrochemical cell
JPH11120993A (en) 1997-10-17 1999-04-30 Japan Storage Battery Co Ltd Nonaqueous electrolyte secondary battery
KR100245808B1 (en) 1997-12-30 2000-03-02 박찬구 Process for manufacturing lithium ion secondary battery electrode compounds
US6168885B1 (en) 1998-08-21 2001-01-02 Sri International Fabrication of electrodes and devices containing electrodes
JP2000067853A (en) 1998-08-18 2000-03-03 Matsushita Battery Industrial Co Ltd Negative electrode for lithium secondary battery
DE19839217C2 (en) 1998-08-28 2001-02-08 Fraunhofer Ges Forschung Pasty masses, layers and layer structures, cells and processes for their production
JP2000123877A (en) * 1998-10-15 2000-04-28 Tosoh Corp Lithium secondary battery
JP2000164210A (en) 1998-11-24 2000-06-16 Fuji Photo Film Co Ltd Non-aqueous secondary battery
DE19858924A1 (en) * 1998-12-19 2000-06-21 Aventis Res & Tech Gmbh & Co Improving the safety of lithium batteries for use in electronic devices by using an electrolyte containing a diol-derived partly-fluorinated compound
KR100326457B1 (en) 1999-03-10 2002-02-28 김순택 A positive active material for a lithium secondary battery and a method of preparing the same
SE516891C2 (en) 1999-06-14 2002-03-19 Ericsson Telefon Ab L M Binder and / or electrolyte material for an electrode in a battery cell, electrode for a battery cell, and process for producing a binder and / or electrolyte material for an electrode
KR100359605B1 (en) 1999-10-13 2002-11-07 사단법인 고등기술연구원 연구조합 Lithium secondary battery cathode composition, lithium secondary battery cathode and lithium secondary battery employing the same, and method for preparing the same
US6541156B1 (en) 1999-11-16 2003-04-01 Mitsubishi Chemical Corporation Negative electrode material for non-aqueous lithium secondary battery, method for manufacturing the same, and non-aqueous lithium secondary battery using the same
JP4274663B2 (en) 2000-02-17 2009-06-10 三菱重工業株式会社 Nonaqueous electrolyte secondary battery
KR20020003742A (en) 2000-07-03 2002-01-15 손헌준 Anode materials of lithium secondary batteries
US6556422B2 (en) * 2000-07-05 2003-04-29 Samsung Electro-Mechanics Co., Ltd. Dielectric ceramic composition, multi-layer ceramic capacitor using the same, and manufacturing method therefor
KR100344357B1 (en) 2000-08-19 2002-07-20 제노에너지(주) Li Power Anode, Li Battery Using Li Power Anode and Method for Making the Same
KR100389655B1 (en) 2000-10-14 2003-06-27 삼성에스디아이 주식회사 Lithium-ion secondary thin-film battery exhibiting good cycling stability and high ion-conductivity
US6706447B2 (en) 2000-12-22 2004-03-16 Fmc Corporation, Lithium Division Lithium metal dispersion in secondary battery anodes
US8980477B2 (en) 2000-12-22 2015-03-17 Fmc Corporation Lithium metal dispersion in secondary battery anodes
US7276314B2 (en) 2000-12-22 2007-10-02 Fmc Corporation Lithium metal dispersion in secondary battery anodes
US6855460B2 (en) * 2001-02-08 2005-02-15 The University Of Chicago Negative electrodes for lithium cells and batteries
JP3785966B2 (en) * 2001-08-23 2006-06-14 株式会社村田製作所 Manufacturing method of multilayer ceramic electronic component and multilayer ceramic electronic component
DK200200615A (en) 2001-12-19 2003-06-20 Fmc Corp Lithium metal dispersion in secondary battery nodes
KR100508945B1 (en) * 2003-04-17 2005-08-17 삼성에스디아이 주식회사 Negative electrode for lithium battery, method of preparing same, and lithium battery comprising same
US20050130043A1 (en) 2003-07-29 2005-06-16 Yuan Gao Lithium metal dispersion in electrodes
JP4126374B2 (en) 2003-10-22 2008-07-30 独立行政法人産業技術総合研究所 Composition for producing biological models such as blood vessel walls and internal organs
US8231810B2 (en) * 2004-04-15 2012-07-31 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
US20090061321A1 (en) * 2007-08-31 2009-03-05 Fmc Corporation, Lithium Division Stabilized lithium metal powder for li-ion application, composition and process
JP5234621B2 (en) 2008-11-05 2013-07-10 日新製鋼株式会社 Drawing method of metal plate

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