CA2472660C - Biodegradable bag - Google Patents
Biodegradable bag Download PDFInfo
- Publication number
- CA2472660C CA2472660C CA 2472660 CA2472660A CA2472660C CA 2472660 C CA2472660 C CA 2472660C CA 2472660 CA2472660 CA 2472660 CA 2472660 A CA2472660 A CA 2472660A CA 2472660 C CA2472660 C CA 2472660C
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- CA
- Canada
- Prior art keywords
- biodegradable
- bag
- films
- less
- polylactic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
- B65D65/466—Bio- or photodegradable packaging materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Abstract
A biodegradable film formable into biodegradable bags includes the blended product of polylactic acid and a suitable biodegradable polymeric resin. The blended product includes from about 5% to about 50% by weight polylactic acid.
Description
TITLE OF THE INVENTION
BIODEGRADABLE BAG
FIELD OF THE INVENTION
This invention relates to biodegradable materials generally, and more particularly to biodegradable resin blends used to create fully biodegradable films that have enhanced strength properties for utilization as the structural walls for various bag containers.
BACKGROUND OF THE INVENTION
Biodegradable materials have long been studied for their applicability in commonly-used products. Recently, increased emphasis has been placed on developing products made from biodegradable materials as replacements for existing, non-biodegradable products. In fact, some governmental regulations call for the phasing out of certain non-biodegradable products in lieu of biodegradable counterparts.
The changeover to the utilization of biodegradable materials in such products, however, has been met with both implementation challenges, as well decreased performance issues. Furthermore, products fabricated from biodegradable materials have typically been more expensive than conventional non-biodegradable products. Such issues have limited the extent to which products fabricated from biodegradable materials have been widely accepted in residential or industrial applications alike.
A particular example of a product that is well suited for the use of biodegradable material is a bag, such as those commonly used and/or sold at grocery stores, or temporary refuse containers, and the like. Recently, certain municipalities have required the use of biodegradable bags. To qualify as "biodegradable", materials forming the biodegradable product must have at least a 90% conversion rate of starting material to C02 and water within six months of disposal thereof. Bags and other containers fabricated from biodegradable materials that have been utilized to date, however, do not perform as well strengthwise as conventional products, and are typically more expensive than such conventional products.
A specific drawback to currently available containers, more particularly bags, fabricated from biodegradable materials is the low strength characteristics associated with such materials. Accordingly, currently available biodegradable containers are undesirably weak, in that such products are substantially stretchable under relatively low forces.
To date, efforts in creating viable and economical fully biodegradable materials have focused primarily on blending known biodegradable polymeric resins such as polyesters with starch to reduce the cost. A popular blend is a resin mixture called Mater-Bi produced and sold by Novamont. Bags made from the Mater-Bi material are widely available, but have substantial physical drawbacks such as low elongation resistance, low puncture resistance, and poor moisture resistance.
Two primary problems to be overcome in order to increase acceptance and use of biodegradable products are strength and price. Polyethylene, one of the most commonly used polymeric resins base for non-biodegradable films used in the manufacture of, for example, bags, is a low cost resin that is versatile enough to handle the physical requirements of any disposal bags. Polyethylene bags are also typically less expensive than their biodegradable counterparts. Such characteristics of polyethylene represent a marketing barrier to the acceptance of similar biodegradable products.
We have surprisingly found that commonly-utilized biodegradable polymeric resins can be blended with a polylactic acid to produce substantially stronger fully biodegradable films than those presently available. A
particular characteristic of the resulting films is reduced elongation under load. Thus, the blends of the present invention enable the production of substantially more durable bags. In addition, the fully biodegradable films of the present invention are typically less costly to produce than currently manufactured biodegradable films. Such factors are important in increasing acceptance of biodegradable containers in environmental programs worldwide.
Lactic acid polymers have been extensively investigated for many years. Primarily, attention has been focused on the biodegradable aspects of such lactic acid polymers. A
great deal of work in the last twenty years centered on the medical use of these polymers, upon which many patents have issued. A patent related to uses for polylactic acid is U.S. Patent No. 6,323, 307, issued to Cargill Dow Polymers on November 27, 2001.
Other patents relating to the use of polylactic acid include U.S. Patent Nos. 5,216,050 and 5,444,113. Such patents generally describe polylactic acid polymers that can be blended or plasticized with internal or external plasticizers.
BIODEGRADABLE BAG
FIELD OF THE INVENTION
This invention relates to biodegradable materials generally, and more particularly to biodegradable resin blends used to create fully biodegradable films that have enhanced strength properties for utilization as the structural walls for various bag containers.
BACKGROUND OF THE INVENTION
Biodegradable materials have long been studied for their applicability in commonly-used products. Recently, increased emphasis has been placed on developing products made from biodegradable materials as replacements for existing, non-biodegradable products. In fact, some governmental regulations call for the phasing out of certain non-biodegradable products in lieu of biodegradable counterparts.
The changeover to the utilization of biodegradable materials in such products, however, has been met with both implementation challenges, as well decreased performance issues. Furthermore, products fabricated from biodegradable materials have typically been more expensive than conventional non-biodegradable products. Such issues have limited the extent to which products fabricated from biodegradable materials have been widely accepted in residential or industrial applications alike.
A particular example of a product that is well suited for the use of biodegradable material is a bag, such as those commonly used and/or sold at grocery stores, or temporary refuse containers, and the like. Recently, certain municipalities have required the use of biodegradable bags. To qualify as "biodegradable", materials forming the biodegradable product must have at least a 90% conversion rate of starting material to C02 and water within six months of disposal thereof. Bags and other containers fabricated from biodegradable materials that have been utilized to date, however, do not perform as well strengthwise as conventional products, and are typically more expensive than such conventional products.
A specific drawback to currently available containers, more particularly bags, fabricated from biodegradable materials is the low strength characteristics associated with such materials. Accordingly, currently available biodegradable containers are undesirably weak, in that such products are substantially stretchable under relatively low forces.
To date, efforts in creating viable and economical fully biodegradable materials have focused primarily on blending known biodegradable polymeric resins such as polyesters with starch to reduce the cost. A popular blend is a resin mixture called Mater-Bi produced and sold by Novamont. Bags made from the Mater-Bi material are widely available, but have substantial physical drawbacks such as low elongation resistance, low puncture resistance, and poor moisture resistance.
Two primary problems to be overcome in order to increase acceptance and use of biodegradable products are strength and price. Polyethylene, one of the most commonly used polymeric resins base for non-biodegradable films used in the manufacture of, for example, bags, is a low cost resin that is versatile enough to handle the physical requirements of any disposal bags. Polyethylene bags are also typically less expensive than their biodegradable counterparts. Such characteristics of polyethylene represent a marketing barrier to the acceptance of similar biodegradable products.
We have surprisingly found that commonly-utilized biodegradable polymeric resins can be blended with a polylactic acid to produce substantially stronger fully biodegradable films than those presently available. A
particular characteristic of the resulting films is reduced elongation under load. Thus, the blends of the present invention enable the production of substantially more durable bags. In addition, the fully biodegradable films of the present invention are typically less costly to produce than currently manufactured biodegradable films. Such factors are important in increasing acceptance of biodegradable containers in environmental programs worldwide.
Lactic acid polymers have been extensively investigated for many years. Primarily, attention has been focused on the biodegradable aspects of such lactic acid polymers. A
great deal of work in the last twenty years centered on the medical use of these polymers, upon which many patents have issued. A patent related to uses for polylactic acid is U.S. Patent No. 6,323, 307, issued to Cargill Dow Polymers on November 27, 2001.
Other patents relating to the use of polylactic acid include U.S. Patent Nos. 5,216,050 and 5,444,113. Such patents generally describe polylactic acid polymers that can be blended or plasticized with internal or external plasticizers.
The invention of the present application describes a simple straightforward method of using PLA to produce a useful product for a rapidly growing environmental problem.
The bags of the present application are unexpectedly tougher, stronger, can handle much heavier loads, and use less resin than conventional biodegradable bags currently available.
It is therefore a primary object of the present invention to provide fully biodegradable materials in film form having strength characteristics similar to that of polyethylene film.
It is a further object of the present invention to provide biodegradable bags formed from one or more fully biodegradable films having strength and durability characteristics similar to that of conventional polyethylene films.
It is another object of the present invention to provide economical fully biodegradable films having enhanced strength and durability characteristics.
It is a still further object of the present invention to provide fully biodegradable films comprising a blended product of polylactic acid and a suitable biodegradable polymeric resin, such as a polyester.
It is a yet further object of the present invention to provide fully biodegradable films comprising a blended product of about 30% by weight polylactic acid and about 70%
by weight of a suitable biodegradable polymeric resin.
It is another object of the present invention to provide a biodegradable bag being formed from one or more fully biodegradable blown films, which films are a blended product of polylactic acid and a suitable biodegradable polymeric resin.
It is another object of the present invention to provide a fully biodegradable bag formed from one or more biodegradable films having a caliper thickness of about 2 5 mils or less.
SUMMARY OF THE INVENTION
By means of the present invention, fully biodegradable films are provided having enhanced physical strengths and durability properties over existing biodegradable films. In addition, the fully biodegradable films of the present invention are considerably less expensive than presently available biodegradable films.
The biodegradable films of the present invention are preferably a blended product of polylactic acid and a suitable biodegradable polymeric resin, with the blended products being from about 5% to about 50% by weight polylactic acid.
In preferred embodiments of the present invention, the polylactic acid-containing biodegradable films may be formed into a bag. In some embodiments, the biodegradable bag may be in the form of a drawstring bag or a die cut bag having a caliper thickness of less than 2 mils.
Preferably, the biodegradable films of the present invention are formed through a blown film process.
The invention thus relates according to an aspect, to a biodegradable bag having a caliper thickness of about 2 mils or less, and being formed from one or more biodegradable films, the biodegradable films consisting essentially of a blended product of equal to or less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester resin having a melt flow rate of less than about Sg/10 min.
5a According to another aspect, the invention relates to a biodegradable film consisting essentially of less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester having a melt flow rate of less than about 5g/10 min and having a caliper thickness of about 2 mils or less.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The objects and advantages enumerated above together with other objects, features, and advances represented by the present invention will now be presented in terms of detailed embodiments. Other embodiments and aspects of the invention are recognized as being within the grasp of those having ordinary skill in the art.
The bags of the present application are unexpectedly tougher, stronger, can handle much heavier loads, and use less resin than conventional biodegradable bags currently available.
It is therefore a primary object of the present invention to provide fully biodegradable materials in film form having strength characteristics similar to that of polyethylene film.
It is a further object of the present invention to provide biodegradable bags formed from one or more fully biodegradable films having strength and durability characteristics similar to that of conventional polyethylene films.
It is another object of the present invention to provide economical fully biodegradable films having enhanced strength and durability characteristics.
It is a still further object of the present invention to provide fully biodegradable films comprising a blended product of polylactic acid and a suitable biodegradable polymeric resin, such as a polyester.
It is a yet further object of the present invention to provide fully biodegradable films comprising a blended product of about 30% by weight polylactic acid and about 70%
by weight of a suitable biodegradable polymeric resin.
It is another object of the present invention to provide a biodegradable bag being formed from one or more fully biodegradable blown films, which films are a blended product of polylactic acid and a suitable biodegradable polymeric resin.
It is another object of the present invention to provide a fully biodegradable bag formed from one or more biodegradable films having a caliper thickness of about 2 5 mils or less.
SUMMARY OF THE INVENTION
By means of the present invention, fully biodegradable films are provided having enhanced physical strengths and durability properties over existing biodegradable films. In addition, the fully biodegradable films of the present invention are considerably less expensive than presently available biodegradable films.
The biodegradable films of the present invention are preferably a blended product of polylactic acid and a suitable biodegradable polymeric resin, with the blended products being from about 5% to about 50% by weight polylactic acid.
In preferred embodiments of the present invention, the polylactic acid-containing biodegradable films may be formed into a bag. In some embodiments, the biodegradable bag may be in the form of a drawstring bag or a die cut bag having a caliper thickness of less than 2 mils.
Preferably, the biodegradable films of the present invention are formed through a blown film process.
The invention thus relates according to an aspect, to a biodegradable bag having a caliper thickness of about 2 mils or less, and being formed from one or more biodegradable films, the biodegradable films consisting essentially of a blended product of equal to or less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester resin having a melt flow rate of less than about Sg/10 min.
5a According to another aspect, the invention relates to a biodegradable film consisting essentially of less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester having a melt flow rate of less than about 5g/10 min and having a caliper thickness of about 2 mils or less.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The objects and advantages enumerated above together with other objects, features, and advances represented by the present invention will now be presented in terms of detailed embodiments. Other embodiments and aspects of the invention are recognized as being within the grasp of those having ordinary skill in the art.
Polylactic acid (PLA), which is marketed by Cargill-Dow under the trade name Cargill-Dow 4042, is typically used for producing biodegradable utensils. Films that are prepared from PLA are stiff, have little elongation and poor tear strength, but are finding some use as food wrappers, lid tops and other applications in which strength and elongation characteristics are not critical.
The present invention has revealed that PLA, when blended with a biodegradable resin such as polyester, forms a starting material mixture that can be processed into relatively thin films having desired physical properties not previously achieved in fully biodegradable materials. A
variety of materials may be selected for use with the PLA in obtaining a suitable resin blend. Preferably, such materials provide added resiliency characteristics to the blended product. In addition, such materials are preferably biodegradable, whereby the blended product is fully degradable, with the PLA component and the other resin components each being biodegradable. In some embodiments of the present invention, each of the biodegradable components in the blended product biodegrade at similar rates throughout the biodegradation process.
A particular example of a biodegradable resin material that is useful in blends of the present invention with PLA
is polyester, which is well known as a biodegradable polymeric material, and is utilized in a variety of applications. Other biodegradable resins, however, may be utilized in blended products of the present invention, so long as a portion of the blend comprises PLA. A polyester resin material particularly useful in compositions of the present invention is sold by BASF under the trade name "Ecoflex FBX 7011".
The present invention has revealed that PLA, when blended with a biodegradable resin such as polyester, forms a starting material mixture that can be processed into relatively thin films having desired physical properties not previously achieved in fully biodegradable materials. A
variety of materials may be selected for use with the PLA in obtaining a suitable resin blend. Preferably, such materials provide added resiliency characteristics to the blended product. In addition, such materials are preferably biodegradable, whereby the blended product is fully degradable, with the PLA component and the other resin components each being biodegradable. In some embodiments of the present invention, each of the biodegradable components in the blended product biodegrade at similar rates throughout the biodegradation process.
A particular example of a biodegradable resin material that is useful in blends of the present invention with PLA
is polyester, which is well known as a biodegradable polymeric material, and is utilized in a variety of applications. Other biodegradable resins, however, may be utilized in blended products of the present invention, so long as a portion of the blend comprises PLA. A polyester resin material particularly useful in compositions of the present invention is sold by BASF under the trade name "Ecoflex FBX 7011".
As a measure of comparison between films having a caliper thickness of about 2 mils or less of the present invention and similar thickness films formed from polyester alone, films produced with 20% of PLA 4042 blended with the polyester resin exhibits a reduced elongation under a given load from 400% to 125%, and the tensile strength is almost doubled with respect to the conventional films. This unexpected improvement enables the production of stronger and, particularly, thinner caliper products having strength characteristics suitable for use in a variety of containers.
An additional advantage introduced through the use of PLA is in the fact that PLA is derived from a renewable resource, as opposed to the typically utilized biodegradable polymeric resins derived from oil-based chemicals. The enhanced strength characteristics of the present blended products allow for relatively thinner films used in containers, thereby reducing the amount of material needed for each product.
A particular application for biodegradable films today is in the manufacture of bags used in packaging and storing compostable material. Presently available biodegradable flexible films suitable for packaging compostable material are available from Eastman, Union Carbide, DuPont, Showa Denko, BASF and Cargill-Dow. All of the films are capable of preparing such bags, though their respective costs and physical properties as compared to conventional polyethylene bags have limited their success in the marketplace.
Bionelle 3001, a biodegradable resin developed by Showa Denko (Japan) and FBX-7011 produced by BASF (Germany) are two example biodegradable resins currently utilized in making bags being sold into the composting industry. Such biodegradable resins may be used in the blends of the present invention along with PLA to create fully biodegrad-able materials exhibiting strength and cost characteristics resembling conventional non-biodegradable materials.
A standard 30 gallon size biodegradable bag in the industry is made with about 1.5 mil FBX-7011. A FBX-7011 bag manufactured to an average caliper of 1.5 mils stretched 460% in one direction and 625% in another under a specific test load before breaking. Tensile (psi) at break averaged 2500 psi in one direction and 2800 psi in the other. Such results illustrate the restrictive weight limitations of conventional biodegradable bags in the composting industry and preclude the use for anything but relatively lightweight applications.
By comparison, a film of the present invention prepared with the inclusion of 20% PLA 4042 in the resin mix produced a thinner film with better physical strength properties.
The average caliper of this new film was 1 mil; the tensile at break was 4600 psi in one direction and 3700 psi in the other, and elongation at break was 126% in one direction and 522% in the other. Measurements on other film blends with an average caliper of 0.75 mils are noted in Examples 2 and 3.
In addition to the enhanced physical properties exhibited by films of the present invention, a major aspect of this new blend is the reduction in caliper of up to 50%, which reduces the cost of the finished product significantly. The caliper thickness of up to about 2 mils, and preferably about 0.175 to about 1.25 mils, is utilized for maintaining flexibility and shape adaptability for the bags of the present invention. Such aspects are extremely important in obtaining wider acceptance in composting programs and other applications.
Example 1 A mixture of biodegradable resin pellets and PLA
pellets was prepared from 95 parts BASF resin FBX-7011 and 5 parts of Cargill Dow (PLA) 4042. After thorough blending, a film was produced from a circular die maintained at a temperature of about 165 C in a conventional blown film machine. The film was produced at a thickness of one mil and the properties compared to a film 50% thicker prepared with no PLA.
Average 6 100% PBX-7011 (1.5 95-5 (7011-PLA) measurements mil) 1 mil Tensile Strength at 2582 psi 6545 psi Break MD
Tensile Strength at 2805 psi 4974 psi Break CD
Elongation at Break 460 % 190%
MD
Elongation at Break 625% 593%
CD
The 5% of PLA blended with the FBX-7011 resin substantially increased the tensile strength and decreased the elongation of the film. These gains in physicals are substantial and were produced with a film of 1 mil thickness as compared to 1.5 mil of the 100% FBX-7011 resin.
Example 2 A blend of PLA pellets with BASF FBX-7011 pellets in a ratio of 70 parts FBX-7011 to 30 parts PLA were used to produce films with an average caliper of 1 mil and 0.75 mil.
Average 6 1 mil 0.75 mil measurements Tensile Strength at 4900 psi 6479 psi Break MD
Tensile Strength at 7900 psi 4631 psi Break CD
Elongation at Break 434% 66%
MD
Elongation at Break 144% 360%
CD
Example 3 A blend of 40 parts PLA pellets with a 60 parts FBX-7011 pellets were used to make a 1 mil and a 0.75 mil films 5 with the following properties:
Average 6 1 mil 0.75 mil measurements Tensile Strength at 5390 psi 6990 psi Break MD
Tensile Strength at 9184 psi 4226 psi Break CD
Elongation at Break 277% 77%
MD
Elongation at Break 168% 162%
CD
Example 4 Seventy parts of Bionolle 3001 from Showa Denko (Japan) was mixed with 30 parts of PLA 4042 and extruded as a blown 10 film with a thickness of 2-mil. The elongation was reduced and the tensile strength increased.
Biodegradable Bags with Draw Strings Initial attempts to prepare a draw strap for biodegradable bags focused on trying straps prepared from the same standard biodegradable resins as is done with conventional polyethylene household bags. These attempts were unsuccessful, as the straps prepared from the standard biodegradable resins exhibited excessive elongation under load, and performed poorly in closing the bag. Trials utilizing thicker films were also unsuccessful. The new PLA
blends of the present invention at about a 70-30 ratio (Examples 2 and 4) produced a strap with substantially less elongation, greater stiffness, and overall good performance closing the new bags particularly in the low frictional resistance between the bag and the strap. In addition, the packaging materials for the present invention are completely biodegradable.
Die Cut Bags Die Cut bags are very common in carrying bag applications. The handles are die cut and are used to carry the bag. Bags made from 100% standard biodegradable resins are limited in scope as the die cut handle stretches too much under load. This precludes their use in any but lightweight load situations. Many specialty stores that sell organic foods use biodegradable bags when the load is light such that the handle will not significantly stretch.
The current films having, for example, 30% by weight PLA, perform well as die cut bags with a handle that is strong enough to function with much heavier loads in the bag as compared to the loads placed on the conventional biodegradable bags. The bags using films of the present invention are less expensive to produce, have superior physical characteristics, and will increase customer satisfaction and acceptance.
The invention has been described herein in considerable detail in order to comply with the patent statutes, and to provide those skilled in the art with the information needed to apply the novel principles and to construct and use embodiments of the invention as required. However, it is to be understood that the invention can be carried out by specifically different devices and that various modifications can be accomplished without departing from the scope of the invention itself.
An additional advantage introduced through the use of PLA is in the fact that PLA is derived from a renewable resource, as opposed to the typically utilized biodegradable polymeric resins derived from oil-based chemicals. The enhanced strength characteristics of the present blended products allow for relatively thinner films used in containers, thereby reducing the amount of material needed for each product.
A particular application for biodegradable films today is in the manufacture of bags used in packaging and storing compostable material. Presently available biodegradable flexible films suitable for packaging compostable material are available from Eastman, Union Carbide, DuPont, Showa Denko, BASF and Cargill-Dow. All of the films are capable of preparing such bags, though their respective costs and physical properties as compared to conventional polyethylene bags have limited their success in the marketplace.
Bionelle 3001, a biodegradable resin developed by Showa Denko (Japan) and FBX-7011 produced by BASF (Germany) are two example biodegradable resins currently utilized in making bags being sold into the composting industry. Such biodegradable resins may be used in the blends of the present invention along with PLA to create fully biodegrad-able materials exhibiting strength and cost characteristics resembling conventional non-biodegradable materials.
A standard 30 gallon size biodegradable bag in the industry is made with about 1.5 mil FBX-7011. A FBX-7011 bag manufactured to an average caliper of 1.5 mils stretched 460% in one direction and 625% in another under a specific test load before breaking. Tensile (psi) at break averaged 2500 psi in one direction and 2800 psi in the other. Such results illustrate the restrictive weight limitations of conventional biodegradable bags in the composting industry and preclude the use for anything but relatively lightweight applications.
By comparison, a film of the present invention prepared with the inclusion of 20% PLA 4042 in the resin mix produced a thinner film with better physical strength properties.
The average caliper of this new film was 1 mil; the tensile at break was 4600 psi in one direction and 3700 psi in the other, and elongation at break was 126% in one direction and 522% in the other. Measurements on other film blends with an average caliper of 0.75 mils are noted in Examples 2 and 3.
In addition to the enhanced physical properties exhibited by films of the present invention, a major aspect of this new blend is the reduction in caliper of up to 50%, which reduces the cost of the finished product significantly. The caliper thickness of up to about 2 mils, and preferably about 0.175 to about 1.25 mils, is utilized for maintaining flexibility and shape adaptability for the bags of the present invention. Such aspects are extremely important in obtaining wider acceptance in composting programs and other applications.
Example 1 A mixture of biodegradable resin pellets and PLA
pellets was prepared from 95 parts BASF resin FBX-7011 and 5 parts of Cargill Dow (PLA) 4042. After thorough blending, a film was produced from a circular die maintained at a temperature of about 165 C in a conventional blown film machine. The film was produced at a thickness of one mil and the properties compared to a film 50% thicker prepared with no PLA.
Average 6 100% PBX-7011 (1.5 95-5 (7011-PLA) measurements mil) 1 mil Tensile Strength at 2582 psi 6545 psi Break MD
Tensile Strength at 2805 psi 4974 psi Break CD
Elongation at Break 460 % 190%
MD
Elongation at Break 625% 593%
CD
The 5% of PLA blended with the FBX-7011 resin substantially increased the tensile strength and decreased the elongation of the film. These gains in physicals are substantial and were produced with a film of 1 mil thickness as compared to 1.5 mil of the 100% FBX-7011 resin.
Example 2 A blend of PLA pellets with BASF FBX-7011 pellets in a ratio of 70 parts FBX-7011 to 30 parts PLA were used to produce films with an average caliper of 1 mil and 0.75 mil.
Average 6 1 mil 0.75 mil measurements Tensile Strength at 4900 psi 6479 psi Break MD
Tensile Strength at 7900 psi 4631 psi Break CD
Elongation at Break 434% 66%
MD
Elongation at Break 144% 360%
CD
Example 3 A blend of 40 parts PLA pellets with a 60 parts FBX-7011 pellets were used to make a 1 mil and a 0.75 mil films 5 with the following properties:
Average 6 1 mil 0.75 mil measurements Tensile Strength at 5390 psi 6990 psi Break MD
Tensile Strength at 9184 psi 4226 psi Break CD
Elongation at Break 277% 77%
MD
Elongation at Break 168% 162%
CD
Example 4 Seventy parts of Bionolle 3001 from Showa Denko (Japan) was mixed with 30 parts of PLA 4042 and extruded as a blown 10 film with a thickness of 2-mil. The elongation was reduced and the tensile strength increased.
Biodegradable Bags with Draw Strings Initial attempts to prepare a draw strap for biodegradable bags focused on trying straps prepared from the same standard biodegradable resins as is done with conventional polyethylene household bags. These attempts were unsuccessful, as the straps prepared from the standard biodegradable resins exhibited excessive elongation under load, and performed poorly in closing the bag. Trials utilizing thicker films were also unsuccessful. The new PLA
blends of the present invention at about a 70-30 ratio (Examples 2 and 4) produced a strap with substantially less elongation, greater stiffness, and overall good performance closing the new bags particularly in the low frictional resistance between the bag and the strap. In addition, the packaging materials for the present invention are completely biodegradable.
Die Cut Bags Die Cut bags are very common in carrying bag applications. The handles are die cut and are used to carry the bag. Bags made from 100% standard biodegradable resins are limited in scope as the die cut handle stretches too much under load. This precludes their use in any but lightweight load situations. Many specialty stores that sell organic foods use biodegradable bags when the load is light such that the handle will not significantly stretch.
The current films having, for example, 30% by weight PLA, perform well as die cut bags with a handle that is strong enough to function with much heavier loads in the bag as compared to the loads placed on the conventional biodegradable bags. The bags using films of the present invention are less expensive to produce, have superior physical characteristics, and will increase customer satisfaction and acceptance.
The invention has been described herein in considerable detail in order to comply with the patent statutes, and to provide those skilled in the art with the information needed to apply the novel principles and to construct and use embodiments of the invention as required. However, it is to be understood that the invention can be carried out by specifically different devices and that various modifications can be accomplished without departing from the scope of the invention itself.
Claims (9)
1. A biodegradable bag having a caliper thickness of about 2 mils or less, and being formed from one or more biodegradable films, said biodegradable films consisting essentially of a blended product of equal to or less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester resin having a melt flow rate of less than about 5g/10 min.
2. A biodegradable bag as in Claim 1 wherein said blended product includes from about 5% to about 30% by weight polylactic acid.
3. A biodegradable bag as in Claim 1 wherein said blended product is film formed from a blown film extrusion process.
4. A biodegradable bag as in Claim 1 wherein said caliper thickness is about 1 mil.
5. A biodegradable bag as in Claim 4 in the form of a drawstring bag.
6. A biodegradable bag as in Claim 4 in the form of a die cut bag.
7. A biodegradable film consisting essentially of less than about 30% by weight polylactic acid and balance aliphatic aromatic copolyester having a melt flow rate of less than about 5g/10 min and having a caliper thickness of about 2 mils or less.
8. A biodegradable film as in Claim 7 having between about 5% and about 30% by weight polylactic acid.
9. A biodegradable film as in Claim 7 being formed through a blown film extrusion process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA 2472660 CA2472660C (en) | 2003-06-02 | 2004-06-28 | Biodegradable bag |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/452,535 US6984426B2 (en) | 2003-06-02 | 2003-06-02 | Biodegradable bag |
| CA 2472660 CA2472660C (en) | 2003-06-02 | 2004-06-28 | Biodegradable bag |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2472660A1 CA2472660A1 (en) | 2005-12-28 |
| CA2472660C true CA2472660C (en) | 2007-08-21 |
Family
ID=32682506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2472660 Expired - Fee Related CA2472660C (en) | 2003-06-02 | 2004-06-28 | Biodegradable bag |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US6984426B2 (en) |
| CA (1) | CA2472660C (en) |
| GB (1) | GB2402393A (en) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7492326B1 (en) | 2003-06-02 | 2009-02-17 | Cortec Corporation | Biodegradable radio frequency identification cards |
| TW200632018A (en) * | 2005-01-11 | 2006-09-16 | Asahi Kasei Life & Living Corp | Matt film or sheet |
| CA2518715A1 (en) * | 2005-09-09 | 2007-03-09 | Spencer Clark Stevens | Biodegradable lawnmower bag |
| BRPI0621962B1 (en) * | 2006-08-31 | 2018-05-29 | Kimberly-Clark Worldwide, Inc. | RESPIRABLE FILM HAVING A BASE LAYER, RESPIRABLE LAMINATE, ABSORBENT ARTICLE AND METHOD FOR FORMATION OF A RESPIRABLE FILM |
| US20090095830A1 (en) * | 2007-10-15 | 2009-04-16 | Simon Huang | Shredder waste management system |
| US20090095829A1 (en) * | 2007-10-15 | 2009-04-16 | Simon Huang | Shredder waste management system |
| US8227658B2 (en) | 2007-12-14 | 2012-07-24 | Kimberly-Clark Worldwide, Inc | Film formed from a blend of biodegradable aliphatic-aromatic copolyesters |
| US7998888B2 (en) * | 2008-03-28 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Thermoplastic starch for use in melt-extruded substrates |
| WO2009137058A1 (en) | 2008-05-06 | 2009-11-12 | Metabolix, Inc. | Biodegradable polyester blends |
| US8147965B2 (en) | 2008-05-14 | 2012-04-03 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing thermoplastic polyurethane |
| US8338508B2 (en) * | 2008-05-14 | 2012-12-25 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing an olefinic elastomer |
| US8759279B2 (en) * | 2008-06-30 | 2014-06-24 | Kimberly-Clark Worldwide, Inc. | Fragranced biodegradable film |
| US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
| US8927617B2 (en) * | 2008-06-30 | 2015-01-06 | Kimberly-Clark Worldwide, Inc. | Fragranced water-sensitive film |
| US8329601B2 (en) | 2008-12-18 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable and renewable film |
| US8283006B2 (en) * | 2008-12-18 | 2012-10-09 | Kimberly-Clark Worldwide, Inc. | Injection molding material containing starch and plant protein |
| ITFI20110190A1 (en) * | 2011-08-31 | 2013-03-01 | Giuseppe Giuliani | "PLASTIC BAG" |
| CN104428209B (en) * | 2012-07-13 | 2016-12-07 | 巴斯夫农业公司阿纳姆(荷兰)苏黎世分公司 | For the net through insecticide impregnation process can aerofluxus package |
| US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
| US10669417B2 (en) | 2013-05-30 | 2020-06-02 | Cj Cheiljedang Corporation | Recyclate blends |
| US10611903B2 (en) | 2014-03-27 | 2020-04-07 | Cj Cheiljedang Corporation | Highly filled polymer systems |
| AU2015344435B2 (en) * | 2014-11-03 | 2018-02-01 | Ashok Chaturvedi | An improved flexible package for packing fresh produce made from a biodegradable flexible film |
| DE102014017015A1 (en) * | 2014-11-19 | 2016-05-19 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable multilayer film |
| US9463924B1 (en) | 2015-03-25 | 2016-10-11 | Dee Volin | Unique biodegradable eight-stacked-reinforced-handle bag, having eight stacked-reinforced handles, multiple triple-locking latches, multiple triple-locking braces, multiple quadruple-locking walls, and multiple double-locking doors |
| US20210277228A1 (en) * | 2018-08-07 | 2021-09-09 | Northern Technologies International Corporation | Biobased polyester blends with enhanced performance properties |
| CN109627703B (en) * | 2018-11-01 | 2020-12-01 | 江苏云之尚节能科技有限公司 | Preparation method of biodegradable self-sealing strip |
| WO2021003146A1 (en) | 2019-07-03 | 2021-01-07 | Northern Technologies International Corporation | Biodegradable vci packaging compositions |
| IT202000013291A1 (en) * | 2020-06-04 | 2021-12-04 | Basiliotti S R L | CLOTHING |
| US20220031531A1 (en) * | 2020-07-30 | 2022-02-03 | The Procter & Gamble Company | Absorbent Article Package Material With Natural Fibers |
| GB2613091A (en) | 2020-07-30 | 2023-05-24 | Procter & Gamble | Absorbent article package material with natural fibres |
| US11718076B1 (en) | 2021-01-27 | 2023-08-08 | Cortec Corporation | Biodegradable tensioning film and fabrication processes for making same |
| CN115216126B (en) * | 2022-08-19 | 2023-11-07 | 山东道恩降解材料有限公司 | Full-degradable self-sealing bag with high repeated use rate |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6323307B1 (en) | 1988-08-08 | 2001-11-27 | Cargill Dow Polymers, Llc | Degradation control of environmentally degradable disposable materials |
| US5502158A (en) * | 1988-08-08 | 1996-03-26 | Ecopol, Llc | Degradable polymer composition |
| US5444113A (en) | 1988-08-08 | 1995-08-22 | Ecopol, Llc | End use applications of biodegradable polymers |
| US5216050A (en) | 1988-08-08 | 1993-06-01 | Biopak Technology, Ltd. | Blends of polyactic acid |
| GB8910095D0 (en) * | 1989-05-03 | 1989-06-21 | Smith Ernest | Bags |
| US6028160A (en) * | 1998-10-01 | 2000-02-22 | Cortec Corporation | Biodegradable vapor corrosion inhibitor products |
| BE1012800A3 (en) * | 1999-07-27 | 2001-03-06 | Solvay | Aliphatic thermoplastic polyester compositions, method of preparation and use thereof. |
| JP2001239634A (en) | 2000-03-01 | 2001-09-04 | Mitsubishi Plastics Ind Ltd | Biodegradable conductive composite sheet, and molded object and carrier tape using the same |
| EP1309661A2 (en) * | 2000-08-11 | 2003-05-14 | bio-tec Biologische Naturverpackungen GmbH & Co. KG | Biodegradable polymeric blend |
| ITTO20010062A1 (en) | 2001-01-25 | 2002-07-25 | Novamont Spa | BINARY MIXTURES OF BIODEGRADABLE ALIPHATIC POLYESTERS AND PRODUCTS OBTAINED FROM THESE. |
| ITTO20010061A1 (en) | 2001-01-25 | 2002-07-25 | Novamont Spa | BINARY MIXTURES OF BIODEGRADABLE ALIPHATIC POLYESTERS AND PRODUCTS OBTAINED FROM THESE. |
| ITTO20010060A1 (en) | 2001-01-25 | 2002-07-25 | Novamont Spa | TERNARTIE MIXTURES OF BIODEGRADABLE ALIPHATIC POLYESTERS AND PRODUCTS OBTAINED FROM THESE. |
| ITTO20010057A1 (en) * | 2001-01-25 | 2002-07-25 | Novamont Spa | BIODEGRADABLE POLYESTER TERNARY MIXTURES AND PRODUCTS OBTAINED FROM THESE. |
| ITTO20010058A1 (en) | 2001-01-25 | 2002-07-25 | Novamont Spa | BIODEGRADABLE POLYESTER TERNARY MIXTURES AND PRODUCTS OBTAINED FROM THESE. |
| US7241832B2 (en) * | 2002-03-01 | 2007-07-10 | bio-tec Biologische Naturverpackungen GmbH & Co., KG | Biodegradable polymer blends for use in making films, sheets and other articles of manufacture |
| JP2002293961A (en) | 2001-03-30 | 2002-10-09 | Unitika Ltd | Bag for clothes |
| JP3510218B2 (en) | 2001-05-02 | 2004-03-22 | ユニチカ株式会社 | Polylactic acid based film and method for producing the same |
| JP2002348445A (en) | 2001-05-28 | 2002-12-04 | Dan Sangyo Kk | Biodegradable plastic packaging band and method for producing the same |
| JP2003064245A (en) | 2001-08-29 | 2003-03-05 | Unitika Ltd | Biodegradable film or sheet, and molding product using the same |
| JP2003082212A (en) | 2001-09-13 | 2003-03-19 | Unitika Ltd | Biodegradable resin film |
-
2003
- 2003-06-02 US US10/452,535 patent/US6984426B2/en not_active Expired - Lifetime
-
2004
- 2004-05-28 GB GB0411964A patent/GB2402393A/en not_active Withdrawn
- 2004-06-28 CA CA 2472660 patent/CA2472660C/en not_active Expired - Fee Related
-
2006
- 2006-01-09 US US11/328,270 patent/US20060121220A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| GB0411964D0 (en) | 2004-06-30 |
| CA2472660A1 (en) | 2005-12-28 |
| US6984426B2 (en) | 2006-01-10 |
| US20040241359A1 (en) | 2004-12-02 |
| GB2402393A (en) | 2004-12-08 |
| US20060121220A1 (en) | 2006-06-08 |
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