CA2384964C - Method for linking two plastic work pieces without using foreign matter - Google Patents
Method for linking two plastic work pieces without using foreign matter Download PDFInfo
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- CA2384964C CA2384964C CA002384964A CA2384964A CA2384964C CA 2384964 C CA2384964 C CA 2384964C CA 002384964 A CA002384964 A CA 002384964A CA 2384964 A CA2384964 A CA 2384964A CA 2384964 C CA2384964 C CA 2384964C
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- work pieces
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Links
- 238000000034 method Methods 0.000 title claims abstract description 51
- 239000004033 plastic Substances 0.000 title claims abstract description 12
- 229920003023 plastic Polymers 0.000 title claims abstract description 12
- 230000005855 radiation Effects 0.000 claims abstract description 30
- 230000009477 glass transition Effects 0.000 claims abstract description 24
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000002086 nanomaterial Substances 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000004452 microanalysis Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 13
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 6
- 239000004926 polymethyl methacrylate Substances 0.000 description 6
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- 239000010408 film Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
- B29C66/028—Non-mechanical surface pre-treatments, i.e. by flame treatment, electric discharge treatment, plasma treatment, wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
- B29C66/1122—Single lap to lap joints, i.e. overlap joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/53—Joining single elements to tubular articles, hollow articles or bars
- B29C66/534—Joining single elements to open ends of tubular or hollow articles or to the ends of bars
- B29C66/5346—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
- B29C66/53461—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
- B29C66/712—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined the composition of one of the parts to be joined being different from the composition of the other part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
- B29C66/7311—Thermal properties
- B29C66/73117—Tg, i.e. glass transition temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/04—After-treatment of articles without altering their shape; Apparatus therefor by wave energy or particle radiation, e.g. for curing or vulcanising preformed articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/121—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives by heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
- B29C66/024—Thermal pre-treatments
- B29C66/0242—Heating, or preheating, e.g. drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/756—Microarticles, nanoarticles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24612—Composite web or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24628—Nonplanar uniform thickness material
- Y10T428/24661—Forming, or cooperating to form cells
Abstract
The invention relates to a method for linking two adjacent plastic work pieces (2, 3). The inventive method is characterized in that the intended contact zone (K) of at least one of the two work pieces (2) with which the latter adjoins to the other work piece (3) is at least partially subjected to a high- energy radiation to such an extent that the glass transition temperature is reduced in a marginal zone (R). The two work pieces (2, 3) are brought in the desired position relative to each other. For establishing the connection of the two work pieces (2, 3) at least the marginal zone (R) modified by the previous radiation process is heated at least in its surface area to a temperature that is higher than the glass transition temperature of the marginal zone (R) modified by the radiation process but lower than the glass transition temperature of the zones of the work pieces (2, 3) that have not been modified. The invention also relates to an article (1) produced according to the inventive method that consists of two work pieces (2, 3) that are linked without using foreign matte. The inventive article is characterized in that recesses (V), especially channel-shaped recesses, are introduced in at least one contact zone (K) of the two work pieces (2).
Description
Method for Linking Two Plastic Work Pieces Without Using Foreign Matter The invention relates to a method for linking two adjacent plastic work pieces. The invention also relates to an article formed from at least two non-adhesively bonded work pieces, manufactured according to such method, and a preferred application of such an article.
Such methods are used, for example, in the bonding of microstructured work pieces, and they are also becoming increasingly important in the field of microfluidics for applications in reaction engineering, analytical technology, sampling technology and filtration technology, as well as in hydraulics and pneumatics. For such applications numerous miniaturized systems have been developed recently. The materials used are usually glass and silicon, and also thermoplastics. Regardless of the material used, in the fabrication of closed channels microstructures are first provided in a plane (substrate manufacturing), which in a following processing step are closed with a cover. While the process of anodic bonding is a suitable technology for glass and silicon, intensive worldwide efforts are underway to develop cost-effective methods for the bonding of microstructured plastic work pieces. Conventional bonding or adhesion methods such as the use of adhesives or heat seals, the classical method of thermo-welding, laser welding or ultrasound welding are problematic when plastics are used because of the stringent requirements for structural or dimensional stability in microtechnology. The insertion of thin-film electrodes, for example for generating an ion flow or for detecting a fluid channel which on the one hand should be easy to contact from the outside, but on the other hand should have direct contact with the medium in the closed channels, is particularly problematic because the thin-firm electrodes can become imperceptibly and unintentionally coated during the welding process.
From WO 99/51422, a method is known which is derived from classical thermo-welding, a solute thermoplastic is spun onto one or both polymer work pieces to be bonded. The solvent evaporates, and on the entire component remains a very thin film of the spun thermoplastics which has a lower melting point than the substrate or cover material. The bond is created by compression and heating to temperatures which are below the glass transition temperature of the substrate and cover material, but above that of the spun thermoplastics.
A disadvantage of the method described in the above named patent is that the solvent of the spun polymer can destroy the sensitive microstructures or nanostructures by partially or completely dissolving them. There is also the danger that corrosion cracks can occur in the microstructures.
Furthermore, the microstructures or nanostructures can become plugged in the spinning process. This would make the resulting fluid structure unusable. There is also a danger that the thin-film electrodes may become coated.
Setting out from the discussed prior art, it is therefore the object of the invention to make an above named method available by which two plastic work pieces can be bonded to each other in a cost-effective manner and in a continuous manufacturing process.
Such methods are used, for example, in the bonding of microstructured work pieces, and they are also becoming increasingly important in the field of microfluidics for applications in reaction engineering, analytical technology, sampling technology and filtration technology, as well as in hydraulics and pneumatics. For such applications numerous miniaturized systems have been developed recently. The materials used are usually glass and silicon, and also thermoplastics. Regardless of the material used, in the fabrication of closed channels microstructures are first provided in a plane (substrate manufacturing), which in a following processing step are closed with a cover. While the process of anodic bonding is a suitable technology for glass and silicon, intensive worldwide efforts are underway to develop cost-effective methods for the bonding of microstructured plastic work pieces. Conventional bonding or adhesion methods such as the use of adhesives or heat seals, the classical method of thermo-welding, laser welding or ultrasound welding are problematic when plastics are used because of the stringent requirements for structural or dimensional stability in microtechnology. The insertion of thin-film electrodes, for example for generating an ion flow or for detecting a fluid channel which on the one hand should be easy to contact from the outside, but on the other hand should have direct contact with the medium in the closed channels, is particularly problematic because the thin-firm electrodes can become imperceptibly and unintentionally coated during the welding process.
From WO 99/51422, a method is known which is derived from classical thermo-welding, a solute thermoplastic is spun onto one or both polymer work pieces to be bonded. The solvent evaporates, and on the entire component remains a very thin film of the spun thermoplastics which has a lower melting point than the substrate or cover material. The bond is created by compression and heating to temperatures which are below the glass transition temperature of the substrate and cover material, but above that of the spun thermoplastics.
A disadvantage of the method described in the above named patent is that the solvent of the spun polymer can destroy the sensitive microstructures or nanostructures by partially or completely dissolving them. There is also the danger that corrosion cracks can occur in the microstructures.
Furthermore, the microstructures or nanostructures can become plugged in the spinning process. This would make the resulting fluid structure unusable. There is also a danger that the thin-film electrodes may become coated.
Setting out from the discussed prior art, it is therefore the object of the invention to make an above named method available by which two plastic work pieces can be bonded to each other in a cost-effective manner and in a continuous manufacturing process.
This object is achieved according to the invention in that - the intended contact surface of at least one of the two work pieces, with which it contacts the other work piece, is subjected to radiation of such a high energy level that the glass transition temperature is lowered in the marginal area, - the two work pieces are brought into a mutual position in accordance with the intended use, and - subsequently, to produce the bond of the two work pieces, at least the modified marginal layer in the area of its surface is heated to a temperature which is above the glass transition temperature of the marginal layer modified by radiation, but below that of the unmodified areas of the respective work piece.
With the method according to the invention, a marginal layer of the contact surface of at least one of the two work pieces, by which this work piece will be touching the other work piece in the subsequent bond, is modified in such a way that the glass transition temperature in this marginal layer is lowered in comparison with the other parts of this work piece. This is accomplished by radiating the contact surface with a high-energy radiation, such as a UV, laser, X ray and/or synchrotron radiation.
During this radiation process, the long-chain polymers are destroyed, which causes a reduction in molecular weight and thus a lowering of the glass transition temperature. The intensity and duration of the radiation depend on the plastic to be modified and on the desired strength of the marginal layer to be modified. The thickness or depth of the modified marginal layer may be only a few m or fractions of a m.
In a downstream processing step, the two work pieces are brought into a mutual position in accordance with the intended use. This can be done immediately following the radiation process or at any subsequent time.
With the method according to the invention, a marginal layer of the contact surface of at least one of the two work pieces, by which this work piece will be touching the other work piece in the subsequent bond, is modified in such a way that the glass transition temperature in this marginal layer is lowered in comparison with the other parts of this work piece. This is accomplished by radiating the contact surface with a high-energy radiation, such as a UV, laser, X ray and/or synchrotron radiation.
During this radiation process, the long-chain polymers are destroyed, which causes a reduction in molecular weight and thus a lowering of the glass transition temperature. The intensity and duration of the radiation depend on the plastic to be modified and on the desired strength of the marginal layer to be modified. The thickness or depth of the modified marginal layer may be only a few m or fractions of a m.
In a downstream processing step, the two work pieces are brought into a mutual position in accordance with the intended use. This can be done immediately following the radiation process or at any subsequent time.
Once the two work pieces are brought into a mutual position according to the intended use, the next processing step - the actual bonding step - is to heat at least the surface areas of the modified marginal layer to a temperature above the glass transition temperature of the modified marginal layer, but below the glass transition temperature of the work piece not modified in that manner. Due to the process of heating at least the surface areas of the modified marginal layer above its glass transition temperature, these softened marginal layers bond with the contact surface of the contiguous other work piece. This heating step can be accomplished either by selectively heating the modified marginal layer or appropriate parts thereof, as can be done, for example, by radiating with microwave radiation if the marginal layer is appropriately doped, or by heating the two work pieces together in the mutual position according to the intended use.
The main advantage of this method is that the bond between the two work pieces is accomplished without the use of extraneous materials, in particular without adhesives or solvents. Furthermore, the thickness of the modified marginal layer can be adjusted so that it is considerably smaller than the depth of a microstructure or nanostructure, thus avoiding the danger of a material flowing into and plugging such a structure during the bonding process. Furthermore, the two work pieces brought into a mutual position according to the intended use can be held under pressure in relation to each other during the process of heating the modified marginal layer, since the unmodified areas and those containing the structures are not softened and thus remain dimensionally stable. Furthermore, this method is suitable for the production of continuously manufactured articles consisting of two components, for example, for bonding two films, since the process of radiation and mutual alignment as well as the process of heating can be continuous when films are used.
The microstructure or nanostructure can be inserted into one of the two work pieces in an upstream processing step.
The method can also be used in such a way that the contact surfaces of both work pieces are subjected to the radiation process to develop such a modified marginal zone with a lowered glass transition temperature in both, so that both modified marginal layers are softened during the heating step and fuse together.
The method according to the invention is also particularly suitable for bonding two contiguous plastic work pieces when the contact siirface of one work piece carries an electrode such as a structured thin-film electrode. By limiting the amount of material involved in the bonding process, which can be reduced to a minimum, this method - in contrast to the prior art - also prevents the electrodes from becoming covered by volatile constituents or molten material. Furthermore, when both work pieces be subjected to the radiation process, there is the advantage that the underground under the electrodes is not modified and thus remains dimensionally stable. This means that the electrode is not subjected to much mechanical stress during the bonding process and is therefore not damaged or destroyed by cracking, as may be the case with other thermal bonding processes when the softened underground yields under stress.
Below, the object of the invention is described by means of an embodiment and with reference to the drawings, where Fig. 1 shows a schematic three-dimensional view of a microfluid element consisting of two work pieces;
Fig. 2 shows one of the work pieces from Fig. 1, provided with microstructural recesses, in a first processing step;
Fig. 3 shows the work piece from Fig. 2 after completion of the first processing step, with a modified marginal layer;
Fig. 4 shows the two work pieces from Fig. 1 brought into a mutual position in accordance with the intended use;
Fig. 5 shows the bonded work pieces from Fig. 4, and Fig. 6 shows a schematic cross section of another microfluid element with integrated thin-film electrodes.
A microfluid element 1, a partial view of which is shown in Fig. 1, consists of two work pieces 2, 3, which, when bonded together, form the microfluid element 1. Work pieces 2 and 3 are films made from a thermoplastic such as polymethylmethacrylate (PMMA). However, the thermoplastics may certainly also consist of polycarbonate or a polymethacryl, In general, any plastic can be used whose surface, when subjected to high-energy radiation, can be modified so that the glass transition temperature of the modified layer lies below that of the starting material. The top surface of work piece 2 has channel-like recesses V, resulting in a structured surface of work piece 2. The webs S which separate the recesses from each other and whose top surfaces are all arranged in the same plane, together form individual contact surfaces K, on which, bordering on the finished microfluid element 1, borders the underside U of work piece 3, which serves as the contact surface. Thus, work piece 3 serves as a cover for closing the recesses V of work piece 2, enabling them to form channels.
To connect the two work pieces 2, 3, it is provided in a first step that the contact surfaces of the two work pieces 2, 3 (as shown in Fig. 2 only by means of work piece 2) are radiated by a high-energy radiation -indicated by the arrows - to achieve a lowering of the glass transition temperature in the marginal layer that borders on the top surface.
In the embodiment described here, the PMMA surface is preferably modified by UV radiation in the wavelength range of 250-280 nm.
Practically any mercury vapour lamp whose tube is transparent in the appropriate wavelength range can be used for this purpose. The necessary radiation periods depend on the lamp intensity. The connection between intensity and depth of damage during the radiation of PMMA with a respective UV source is explained in detail in Frank et al (W.F.X. Frank, B. Knodler, A. Schosser, T.K. Strempel, T. Tschudi, F. Linde, D.
Muschert, A. Stelmszyk, H. Strack, A. Brduer, P. Dannberg, R. Goring, "Waveguides in Polymers"; Proceedings SPIE vol. 2290, pages 125-132.
In the example of PMMA, the lowering of the glass transition temperature is approximately 35 C, which means that in the embodiment described, the glass transition temperature was also lowered from 105 C to 70 C.
The UV radiation of PMMA as a work piece material has been studied in detail by A. Schosser, B. Knodler, T. Tschudi, W.F.X. Frank, A.
Stelmaszyk, D. Muschert, D. Ruck, S. Brunner, F. Pozzi, S. Morasca. C.
de Bernardi, "Optical components in polymers", SPIE, vol. 2540, pages 110-117; and radiation with X rays in LIGA-Verfahren [LIGA Method], W. Menz, J. Mohr, "Mikrosystemtechnik fiir Ingenieure" [Microsystems Technology for Engineers], VCH-Verlag, Weinheim, 1997. These indicate that such radiation causes substantially a reduction in the molecular weight of PMNIA.
The marginal layer R of work piece 2, modified by the radiation process, is shown in Fig. 3; the modified marginal layer of work piece 3 is designed accordingly. The drawing explains not only that the contact surfaces K
have a modified marginal layer R on the top surface, but also that the lowest point of recesses V has a corresponding marginal layer. However, the latter is of no consequence for the method of bonding the last work pieces 2, 3 with each other. It also does not affect the usability of the subsequently formed channel. Instead of radiating the entire surface of work piece 2, as shown in Fig. 2, radiation can also be selective, for example by introducing a mask, if only the marginal layers of certain sections, such as contact surfaces K, are to be modified as described.
In a next step, to bond the two work pieces 2, 3 together, work piece 3, which serves as a cover, is placed by its modified marginal layer R onto the contact surfaces K of work piece 2, so that the recesses V are closed and are now representing fluid channels. In this situation, it is practical to fix the two work pieces 2, 3 to each other, as indicated schematically by the two arrows pointing in opposite direction.
Finally, to produce a chemical bond between the two work pieces 2, 3, these are heated to a temperature that is above the glass transition temperature of the modified marginal layers R, R', but below that of the unmodified areas of work pieces 2, 3. In the embodiment shown, work pieces 2, 3 are heated to a temperature of about 90 C. After the modified marginal layers R, R' have exceeded their glass transition temperature (70 C), they soften so that the two modified marginal layers R, R' fuse with each other. If, as also shown in Fig. 4 and 5, the two work pieces 2, 3 exert pressure upon each other, this benefits the bonding process. After cooling down to below the glass transition temperature, work pieces 2, 3 are bonded. The former contact surface between the two work pieces 2, 3 is shaded in Fig. 5.
It should be emphasized that during this heating process, the glass transition temperature of the unmodified work piece sections is not exceeded. They retain their dimensional stability, and there is no danger that the recesses V are pinched or plugged during the bonding process.
In the design of microstructured components, it is practical when the two work pieces 2, 3 are made of the same material - as provided in the embodiment shown -, since the lateral walls of the channels that are formed have the same surface characteristics around the circumference, due to the homogeneous material. Thanks to the non-adhesive bond of the two work pieces 2, 3 and to the fact that they are made of identical material, the bond surface does not represent a potential weak point, as could happen, for example, in case of thermal stress, if different materials with different expansion coefficients are used.
Fig. 6 shows another microfluid element 4 formed by bonding two work pieces 5, 6, also both made of PIVIMA film. Work piece 5 is identical to work piece 2 of the previous embodiment. Work piece 6 is the cover for closing recesses V; in contrast to cover 3, it has electrodes E on the underside. The electrodes E extend to some recesses V o that measurements can be taken in the channels formed by recesses V in microfluid element 4, for example, to measure the conductivity of the fluid carried in such a channel. The two work pieces 5, 6 are bonded in the same manner as described in Fig. 2 to 5, to form microfluid element 4. The description of the bonding method explains that it eliminates the danger of the surfaces of electrodes E, which form a lateral wall in some regions, being damaged or coated.
The bonding method according to the invention can be regarded as a hot-melt adhesion method, in which - as a result of a radiation-induced reduction in molecular weight - the hot-melt adhesion is produced by a marginal layer of the base material of the work pieces to be bonded.
List of references I microfluid element 2 work piece 3 work piece 4 microfluid element 5 work piece 6 work piece E electrode K contact surface R, R' modified marginal layer S web U underside v recess
The main advantage of this method is that the bond between the two work pieces is accomplished without the use of extraneous materials, in particular without adhesives or solvents. Furthermore, the thickness of the modified marginal layer can be adjusted so that it is considerably smaller than the depth of a microstructure or nanostructure, thus avoiding the danger of a material flowing into and plugging such a structure during the bonding process. Furthermore, the two work pieces brought into a mutual position according to the intended use can be held under pressure in relation to each other during the process of heating the modified marginal layer, since the unmodified areas and those containing the structures are not softened and thus remain dimensionally stable. Furthermore, this method is suitable for the production of continuously manufactured articles consisting of two components, for example, for bonding two films, since the process of radiation and mutual alignment as well as the process of heating can be continuous when films are used.
The microstructure or nanostructure can be inserted into one of the two work pieces in an upstream processing step.
The method can also be used in such a way that the contact surfaces of both work pieces are subjected to the radiation process to develop such a modified marginal zone with a lowered glass transition temperature in both, so that both modified marginal layers are softened during the heating step and fuse together.
The method according to the invention is also particularly suitable for bonding two contiguous plastic work pieces when the contact siirface of one work piece carries an electrode such as a structured thin-film electrode. By limiting the amount of material involved in the bonding process, which can be reduced to a minimum, this method - in contrast to the prior art - also prevents the electrodes from becoming covered by volatile constituents or molten material. Furthermore, when both work pieces be subjected to the radiation process, there is the advantage that the underground under the electrodes is not modified and thus remains dimensionally stable. This means that the electrode is not subjected to much mechanical stress during the bonding process and is therefore not damaged or destroyed by cracking, as may be the case with other thermal bonding processes when the softened underground yields under stress.
Below, the object of the invention is described by means of an embodiment and with reference to the drawings, where Fig. 1 shows a schematic three-dimensional view of a microfluid element consisting of two work pieces;
Fig. 2 shows one of the work pieces from Fig. 1, provided with microstructural recesses, in a first processing step;
Fig. 3 shows the work piece from Fig. 2 after completion of the first processing step, with a modified marginal layer;
Fig. 4 shows the two work pieces from Fig. 1 brought into a mutual position in accordance with the intended use;
Fig. 5 shows the bonded work pieces from Fig. 4, and Fig. 6 shows a schematic cross section of another microfluid element with integrated thin-film electrodes.
A microfluid element 1, a partial view of which is shown in Fig. 1, consists of two work pieces 2, 3, which, when bonded together, form the microfluid element 1. Work pieces 2 and 3 are films made from a thermoplastic such as polymethylmethacrylate (PMMA). However, the thermoplastics may certainly also consist of polycarbonate or a polymethacryl, In general, any plastic can be used whose surface, when subjected to high-energy radiation, can be modified so that the glass transition temperature of the modified layer lies below that of the starting material. The top surface of work piece 2 has channel-like recesses V, resulting in a structured surface of work piece 2. The webs S which separate the recesses from each other and whose top surfaces are all arranged in the same plane, together form individual contact surfaces K, on which, bordering on the finished microfluid element 1, borders the underside U of work piece 3, which serves as the contact surface. Thus, work piece 3 serves as a cover for closing the recesses V of work piece 2, enabling them to form channels.
To connect the two work pieces 2, 3, it is provided in a first step that the contact surfaces of the two work pieces 2, 3 (as shown in Fig. 2 only by means of work piece 2) are radiated by a high-energy radiation -indicated by the arrows - to achieve a lowering of the glass transition temperature in the marginal layer that borders on the top surface.
In the embodiment described here, the PMMA surface is preferably modified by UV radiation in the wavelength range of 250-280 nm.
Practically any mercury vapour lamp whose tube is transparent in the appropriate wavelength range can be used for this purpose. The necessary radiation periods depend on the lamp intensity. The connection between intensity and depth of damage during the radiation of PMMA with a respective UV source is explained in detail in Frank et al (W.F.X. Frank, B. Knodler, A. Schosser, T.K. Strempel, T. Tschudi, F. Linde, D.
Muschert, A. Stelmszyk, H. Strack, A. Brduer, P. Dannberg, R. Goring, "Waveguides in Polymers"; Proceedings SPIE vol. 2290, pages 125-132.
In the example of PMMA, the lowering of the glass transition temperature is approximately 35 C, which means that in the embodiment described, the glass transition temperature was also lowered from 105 C to 70 C.
The UV radiation of PMMA as a work piece material has been studied in detail by A. Schosser, B. Knodler, T. Tschudi, W.F.X. Frank, A.
Stelmaszyk, D. Muschert, D. Ruck, S. Brunner, F. Pozzi, S. Morasca. C.
de Bernardi, "Optical components in polymers", SPIE, vol. 2540, pages 110-117; and radiation with X rays in LIGA-Verfahren [LIGA Method], W. Menz, J. Mohr, "Mikrosystemtechnik fiir Ingenieure" [Microsystems Technology for Engineers], VCH-Verlag, Weinheim, 1997. These indicate that such radiation causes substantially a reduction in the molecular weight of PMNIA.
The marginal layer R of work piece 2, modified by the radiation process, is shown in Fig. 3; the modified marginal layer of work piece 3 is designed accordingly. The drawing explains not only that the contact surfaces K
have a modified marginal layer R on the top surface, but also that the lowest point of recesses V has a corresponding marginal layer. However, the latter is of no consequence for the method of bonding the last work pieces 2, 3 with each other. It also does not affect the usability of the subsequently formed channel. Instead of radiating the entire surface of work piece 2, as shown in Fig. 2, radiation can also be selective, for example by introducing a mask, if only the marginal layers of certain sections, such as contact surfaces K, are to be modified as described.
In a next step, to bond the two work pieces 2, 3 together, work piece 3, which serves as a cover, is placed by its modified marginal layer R onto the contact surfaces K of work piece 2, so that the recesses V are closed and are now representing fluid channels. In this situation, it is practical to fix the two work pieces 2, 3 to each other, as indicated schematically by the two arrows pointing in opposite direction.
Finally, to produce a chemical bond between the two work pieces 2, 3, these are heated to a temperature that is above the glass transition temperature of the modified marginal layers R, R', but below that of the unmodified areas of work pieces 2, 3. In the embodiment shown, work pieces 2, 3 are heated to a temperature of about 90 C. After the modified marginal layers R, R' have exceeded their glass transition temperature (70 C), they soften so that the two modified marginal layers R, R' fuse with each other. If, as also shown in Fig. 4 and 5, the two work pieces 2, 3 exert pressure upon each other, this benefits the bonding process. After cooling down to below the glass transition temperature, work pieces 2, 3 are bonded. The former contact surface between the two work pieces 2, 3 is shaded in Fig. 5.
It should be emphasized that during this heating process, the glass transition temperature of the unmodified work piece sections is not exceeded. They retain their dimensional stability, and there is no danger that the recesses V are pinched or plugged during the bonding process.
In the design of microstructured components, it is practical when the two work pieces 2, 3 are made of the same material - as provided in the embodiment shown -, since the lateral walls of the channels that are formed have the same surface characteristics around the circumference, due to the homogeneous material. Thanks to the non-adhesive bond of the two work pieces 2, 3 and to the fact that they are made of identical material, the bond surface does not represent a potential weak point, as could happen, for example, in case of thermal stress, if different materials with different expansion coefficients are used.
Fig. 6 shows another microfluid element 4 formed by bonding two work pieces 5, 6, also both made of PIVIMA film. Work piece 5 is identical to work piece 2 of the previous embodiment. Work piece 6 is the cover for closing recesses V; in contrast to cover 3, it has electrodes E on the underside. The electrodes E extend to some recesses V o that measurements can be taken in the channels formed by recesses V in microfluid element 4, for example, to measure the conductivity of the fluid carried in such a channel. The two work pieces 5, 6 are bonded in the same manner as described in Fig. 2 to 5, to form microfluid element 4. The description of the bonding method explains that it eliminates the danger of the surfaces of electrodes E, which form a lateral wall in some regions, being damaged or coated.
The bonding method according to the invention can be regarded as a hot-melt adhesion method, in which - as a result of a radiation-induced reduction in molecular weight - the hot-melt adhesion is produced by a marginal layer of the base material of the work pieces to be bonded.
List of references I microfluid element 2 work piece 3 work piece 4 microfluid element 5 work piece 6 work piece E electrode K contact surface R, R' modified marginal layer S web U underside v recess
Claims (14)
1. Method for bonding two contiguous plastic work pieces without using foreign matter, wherein each work piece comprises an intended contact surface through which the work pieces are to be connected, and wherein at least one work piece comprises microstructure recesses in the contact surface, characterized by:
subjecting the intended contact surface of at least one of the two work pieces by which it borders on the other work piece at least in some sections to a high-energy radiation which causes the lowering of the glass transition temperature in a marginal layer, bringing the two work pieces into a mutual position according to the intended use, and heating at least the modified marginal layer to a temperature which is above the glass transition temperature of the marginal layer modified by radiation, but below that of the unmodified areas of the respective work piece so that the microstructure recesses maintain their dimensional stability, to produce the bond of the two work pieces.
subjecting the intended contact surface of at least one of the two work pieces by which it borders on the other work piece at least in some sections to a high-energy radiation which causes the lowering of the glass transition temperature in a marginal layer, bringing the two work pieces into a mutual position according to the intended use, and heating at least the modified marginal layer to a temperature which is above the glass transition temperature of the marginal layer modified by radiation, but below that of the unmodified areas of the respective work piece so that the microstructure recesses maintain their dimensional stability, to produce the bond of the two work pieces.
2. Method for bonding two contiguous plastic work pieces without using foreign matter, wherein each work piece comprises an intended contact surface through which the work pieces are to be connected, and wherein at least one work piece comprises nanostructure recesses in the contact surface, characterized by:
subjecting the intended contact surface of at least one of the two work pieces by which it borders on the other work piece at least in some sections to a high-energy radiation which causes the lowering of the glass transition temperature in a marginal layer, bringing the two work pieces into a mutual position according to the intended use, and heating at least the modified marginal layer to a temperature which is above the glass transition temperature of the marginal layer modified by radiation, but below that of the unmodified areas of the respective work piece so that the nanostructure recesses maintain their dimensional stability, to produce the bond of the two work pieces.
subjecting the intended contact surface of at least one of the two work pieces by which it borders on the other work piece at least in some sections to a high-energy radiation which causes the lowering of the glass transition temperature in a marginal layer, bringing the two work pieces into a mutual position according to the intended use, and heating at least the modified marginal layer to a temperature which is above the glass transition temperature of the marginal layer modified by radiation, but below that of the unmodified areas of the respective work piece so that the nanostructure recesses maintain their dimensional stability, to produce the bond of the two work pieces.
3. Method according to one of claims 1 and 2, characterized in that the entire contact surface is subjected to the high-energy radiation process.
4. Method according to one of claims 1 and 3, characterized in that the step of heating is performed while the two work pieces are under pressure in relation to each other.
5. Method according to one of claims 1 to 4, characterized in that the two work pieces brought into a mutual position according to their intended use are heated to accomplish the bond.
6. Method according to one of claims 1 to 5, characterized in that the contact surfaces of the two work pieces are radiated with high-energy radiation for the formation of a modified marginal layer on each.
7. Article formed of two work pieces bonded together without using foreign matter, produced according to one of claims 1 to 6, characterized in that the modified marginal layer in at least one contact surface of the two work pieces is only fractions of a µm.
8. Article according to claim 7, characterized in that at least one of the two work pieces is provided with electrodes on its contact surface.
9. Article according to claim 7, characterized in that at least one of the two work pieces is provided with structured thin-film electrodes on its contact surface.
10. Article according to one of claims 8 and 9, characterized in that the electrodes on the contact surface and the channel-like recesses are assigned to the other work piece, and that the electrodes in at least some sections form a wall of a closed recess after the two work pieces are bonded.
11. Article according to one of claims 8 to 10, characterized in that at least one of the two work pieces is designed as a microstructured filter.
12. Article according to one of claims 8 to 10, characterized in that at least one of the two work pieces is designed as a nanostructured filter.
13. Use of an article according to one of claims 7 to 12, characterized in that at this article is used as a microanalysis unit.
14. Use of an article according to one of claims 7 to 12, characterized in that at this article is used as a microreactor unit.
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DE19945604A DE19945604A1 (en) | 1999-09-23 | 1999-09-23 | Method of joining workpieces made of plastic and its use in microstructure and nanostructure technology |
PCT/EP2000/008584 WO2001021384A1 (en) | 1999-09-23 | 2000-09-02 | Method for linking two plastic work pieces without using foreign matter |
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CA2384964C true CA2384964C (en) | 2008-07-08 |
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CA002384964A Expired - Fee Related CA2384964C (en) | 1999-09-23 | 2000-09-02 | Method for linking two plastic work pieces without using foreign matter |
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US (1) | US6838156B1 (en) |
EP (1) | EP1216141B1 (en) |
JP (1) | JP4751554B2 (en) |
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DE4231810A1 (en) | 1992-09-23 | 1994-03-24 | Basf Magnetics Gmbh | Process for the hot bonding of semi-crystalline polymers with metals |
SE501380C2 (en) * | 1993-06-15 | 1995-01-30 | Pharmacia Lkb Biotech | Ways to manufacture microchannel / microcavity structures |
JPH07299907A (en) * | 1993-08-11 | 1995-11-14 | Fuji Electric Co Ltd | Ink jet recording head and production thereof |
US5589860A (en) | 1993-08-11 | 1996-12-31 | Fuji Electric Co., Ltd. | Ink jet recording head and method of producing the same |
JPH08118661A (en) | 1994-10-21 | 1996-05-14 | Fuji Electric Co Ltd | Method and apparatus for producing ink jet recording head |
SE514491C2 (en) * | 1995-09-20 | 2001-03-05 | Uponor Innovation Ab | Method of sealing a pipe |
WO1999025783A1 (en) | 1997-11-14 | 1999-05-27 | INSTITUT FüR MIKROTECHNIK MAINZ GMBH | Process for joining microstructured plastic parts and component produced by this process |
DE19815632C2 (en) | 1998-04-07 | 2001-02-15 | Max Planck Gesellschaft | Adhesive-free connections of polymer components to create closed micro and nanochannel structures |
-
1999
- 1999-09-23 DE DE19945604A patent/DE19945604A1/en not_active Ceased
-
2000
- 2000-03-29 US US10/088,922 patent/US6838156B1/en not_active Expired - Lifetime
- 2000-09-02 DK DK00967644T patent/DK1216141T3/en active
- 2000-09-02 EP EP00967644A patent/EP1216141B1/en not_active Expired - Lifetime
- 2000-09-02 CA CA002384964A patent/CA2384964C/en not_active Expired - Fee Related
- 2000-09-02 ES ES00967644T patent/ES2257325T3/en not_active Expired - Lifetime
- 2000-09-02 DE DE50012537T patent/DE50012537D1/en not_active Expired - Lifetime
- 2000-09-02 JP JP2001524789A patent/JP4751554B2/en not_active Expired - Fee Related
- 2000-09-02 AT AT00967644T patent/ATE322369T1/en not_active IP Right Cessation
- 2000-09-02 AU AU77744/00A patent/AU7774400A/en not_active Abandoned
- 2000-09-02 WO PCT/EP2000/008584 patent/WO2001021384A1/en active IP Right Grant
Also Published As
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DK1216141T3 (en) | 2006-07-03 |
EP1216141A1 (en) | 2002-06-26 |
JP2003509251A (en) | 2003-03-11 |
ES2257325T3 (en) | 2006-08-01 |
DE19945604A1 (en) | 2003-08-07 |
AU7774400A (en) | 2001-04-24 |
EP1216141B1 (en) | 2006-04-05 |
ATE322369T1 (en) | 2006-04-15 |
DE50012537D1 (en) | 2006-05-18 |
JP4751554B2 (en) | 2011-08-17 |
US6838156B1 (en) | 2005-01-04 |
WO2001021384A1 (en) | 2001-03-29 |
CA2384964A1 (en) | 2001-03-29 |
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