CA2239950A1 - Syntactic rigid pur/pir foam boardstock - Google Patents
Syntactic rigid pur/pir foam boardstockInfo
- Publication number
- CA2239950A1 CA2239950A1 CA002239950A CA2239950A CA2239950A1 CA 2239950 A1 CA2239950 A1 CA 2239950A1 CA 002239950 A CA002239950 A CA 002239950A CA 2239950 A CA2239950 A CA 2239950A CA 2239950 A1 CA2239950 A1 CA 2239950A1
- Authority
- CA
- Canada
- Prior art keywords
- microspheres
- pir foam
- rigid pur
- syntactic
- microns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to the use of hollow microspheres filled with a hydrocarbon, to introduce uniform cell geometries in syntactic foams having a bimodal cell structure. The rigid foam product includes from 40 to 60 percent by weight of the hollow microspheres, the microspheres having average diameters ranging from 80 to 140 microns. The microspheres are encapsulated from 60 to 40 percent by weight of a closed cell polyurethane foam, the cells of the foam having average diameters from 0.01 to 40 microns.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90944797A | 1997-08-11 | 1997-08-11 | |
US08/909,447 | 1997-08-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2239950A1 true CA2239950A1 (en) | 1999-02-11 |
CA2239950C CA2239950C (en) | 2007-09-18 |
Family
ID=25427242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002239950A Expired - Fee Related CA2239950C (en) | 1997-08-11 | 1998-06-09 | Syntactic rigid pur/pir foam boardstock |
Country Status (11)
Country | Link |
---|---|
US (1) | US6166109A (en) |
EP (1) | EP0896976B1 (en) |
JP (1) | JPH11140219A (en) |
CN (1) | CN1088005C (en) |
AT (1) | ATE300579T1 (en) |
CA (1) | CA2239950C (en) |
DE (1) | DE69830955T2 (en) |
DK (1) | DK0896976T3 (en) |
ES (1) | ES2245798T3 (en) |
HK (1) | HK1021519A1 (en) |
TW (1) | TW408151B (en) |
Families Citing this family (63)
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---|---|---|---|---|
ATE221906T1 (en) * | 1999-01-26 | 2002-08-15 | Huntsman Int Llc | FOAMED THERMOPLASTIC POLYURETHANES |
DE60025949T2 (en) * | 1999-12-24 | 2006-08-17 | Huntsman International Llc, Salt Lake City | By gas-assisted injection molding |
US20030060110A1 (en) * | 1999-12-24 | 2003-03-27 | Desai Dilipkumar R. | Expanded extruded polymeric textile |
DE50008414D1 (en) * | 2000-04-11 | 2004-12-02 | Siempelkamp Handling Sys Gmbh | Production of foam-filled sandwich elements with foam application in cassettes |
US6682555B2 (en) * | 2000-11-13 | 2004-01-27 | Wit Ip Corporation | Methods for treating the prostate and inhibiting obstruction of the prostatic urethra using biodegradable stents |
KR20030064853A (en) | 2000-12-21 | 2003-08-02 | 다우 글로벌 테크놀로지스 인크. | Blowing agents compositions containing hydrofluorocarbons, a low-boiling alcohol and/or low-boiling carbonyl compound |
RU2276164C2 (en) | 2000-12-21 | 2006-05-10 | Дау Глобал Текнолоджиз Инк. | Foaming agent composition and polymeric foam comprising fluorohydrocarbon liquid under normal condition and carbon dioxide |
WO2002083757A1 (en) * | 2001-04-09 | 2002-10-24 | Toyo Boseki Kabushiki Kaisha | Polyurethane composition and polishing pad |
EP1401639A4 (en) * | 2001-05-25 | 2007-01-03 | Ip Rights Llc | Expandable microspheres for foam insulation and methods |
DE10129232A1 (en) | 2001-06-19 | 2003-01-02 | Basf Ag | Process for the production of syntactic polyurethane |
CN100348663C (en) * | 2001-11-02 | 2007-11-14 | 日本皇冠塞株式会社 | Sealing element with excellent safety and environmentally friendly action for cover, and metal cover |
US7199168B2 (en) * | 2002-02-13 | 2007-04-03 | Bayer Materialscience Llc | Process for making cellular composites using polymeric isocyanates as binders for hollow filler particles |
JP2003292889A (en) * | 2002-04-08 | 2003-10-15 | Fujikura Kasei Co Ltd | Foamable coating composition, coated article having foamed coating film and method for forming foamed coating film |
US20040171339A1 (en) * | 2002-10-28 | 2004-09-02 | Cabot Microelectronics Corporation | Microporous polishing pads |
US6913517B2 (en) * | 2002-05-23 | 2005-07-05 | Cabot Microelectronics Corporation | Microporous polishing pads |
US6706776B2 (en) | 2002-06-18 | 2004-03-16 | Bayer Corporation | Syntactic foams with improved water resistance, long pot life and short demolding times |
DE10358368A1 (en) | 2003-12-11 | 2005-07-07 | Basf Ag | Syntactic polyurethanes and their use for off-shore insulation |
DE10358371A1 (en) | 2003-12-11 | 2005-07-28 | Basf Ag | Syntactic polyurethane containing oil, preferably castor oil |
DE102004010809A1 (en) * | 2004-03-05 | 2005-09-22 | Bayer Materialscience Ag | Flexible moldings made of foamed polyurethane and their use |
ATE376031T1 (en) * | 2004-05-28 | 2007-11-15 | Albemarle Corp | FLAME-RESISTANT POLYURETHANES AND ADDITIVES THEREOF |
JP2006022139A (en) * | 2004-07-06 | 2006-01-26 | Takao Kawai | Foamed polyurethane having microcavities and its manufacturing method |
ITRM20050125A1 (en) * | 2005-03-18 | 2006-09-19 | Aviointeriors S P A | POLYURETHANE FOAM WITH IMPROVED PROPERTY AND PADDED STRUCTURE MADE WITH SUCH A FOAM. |
ITVA20050025A1 (en) * | 2005-04-15 | 2006-10-16 | Whirlpool Co | PROCEDURE FOR THE PRODUCTION OF EXPANDED POLYMERIC MATERIALS AND EXPANDED POLYMERIC MATERIAL OBTAINED BY THIS PROCEDURE |
US20070021518A1 (en) * | 2005-07-21 | 2007-01-25 | Lear Corporation | Additives to spray urethane |
CN100381500C (en) * | 2006-03-02 | 2008-04-16 | 海洋化工研究院 | Buoyancy material with micro bubble and cell composite structure |
BRPI0708829A2 (en) | 2006-03-24 | 2012-03-13 | Century-Board Usa, Llc | methods of forming composite polymeric material in an extruder |
CN100378166C (en) * | 2006-04-08 | 2008-04-02 | 海洋化工研究院 | Workable solid buoyancy material for deep sea and method for preparing same |
ATE424995T1 (en) * | 2006-08-01 | 2009-03-15 | Epurex Films Gmbh & Co Kg | METHOD FOR PRODUCING MULTI-LAYER FILMS FROM THERMOPLASTIC POLYURETHANES |
ES2738525T3 (en) | 2007-03-21 | 2020-01-23 | Ash Tech Ind L L C | General purpose materials that incorporate a matrix of microparticles |
US8445101B2 (en) | 2007-03-21 | 2013-05-21 | Ashtech Industries, Llc | Sound attenuation building material and system |
US20090239429A1 (en) | 2007-03-21 | 2009-09-24 | Kipp Michael D | Sound Attenuation Building Material And System |
DE102007015660A1 (en) * | 2007-03-31 | 2008-10-02 | Brugg Rohr Ag, Holding | Flexible heat-insulated conduit |
US20110092607A1 (en) * | 2008-05-27 | 2011-04-21 | Koninklijke Philips Electronics N.V. | Method of preparing a rigid foam material and method of preparing a resin material with reduced viscosity |
US20100028650A1 (en) * | 2008-07-31 | 2010-02-04 | Nhk Spring Co., Ltd. | Closed-cell urethane sheet, manufacturing method thereof and waterproof sealing materials |
WO2010022895A1 (en) * | 2008-08-27 | 2010-03-04 | Bayer Materialscience Ag | Viscoelastic rigid polyurethane and polyisocyanurate foams |
US8591677B2 (en) | 2008-11-04 | 2013-11-26 | Ashtech Industries, Llc | Utility materials incorporating a microparticle matrix formed with a setting agent |
CN102639620B (en) | 2009-11-20 | 2014-01-22 | 巴斯夫欧洲公司 | Resin foams containing microballoons |
KR101231023B1 (en) * | 2009-11-26 | 2013-02-07 | 제일모직주식회사 | Rigid polyurethane foam having an excellent insulating ability and method for preparing the same |
JP5566851B2 (en) * | 2010-03-04 | 2014-08-06 | 日東電工株式会社 | Thermally foamable resin composition, thermally foamable resin sheet, thermally foamable laminate, foam and production method thereof |
KR101332433B1 (en) | 2010-08-24 | 2013-11-22 | 제일모직주식회사 | Rigid polyurethane foam having good insulation property and method for preparing the same |
US8937106B2 (en) | 2010-12-07 | 2015-01-20 | Basf Se | Melamine resin foams with nanoporous fillers |
EP2734561A4 (en) * | 2011-07-19 | 2015-05-06 | Johnson Controls Tech Co | Foam reinforced structural member |
DE102011083017A1 (en) | 2011-09-20 | 2013-03-21 | Evonik Industries Ag | Composite materials comprising an open-cell polymer matrix and granules embedded therein |
DE102011083011A1 (en) * | 2011-09-20 | 2013-03-21 | Evonik Goldschmidt Gmbh | Composite materials comprising a polymer matrix and granules embedded therein |
US9745224B2 (en) | 2011-10-07 | 2017-08-29 | Boral Ip Holdings (Australia) Pty Limited | Inorganic polymer/organic polymer composites and methods of making same |
EP2657280A1 (en) * | 2012-04-23 | 2013-10-30 | Basf Se | Polyurethane composite material containing mineral particles |
US8883869B2 (en) | 2012-08-08 | 2014-11-11 | Provee Technologies, Llc | Impact absorbing foam |
CN103240884B (en) * | 2013-05-07 | 2015-07-15 | 西北工业大学 | Preparation method of polycarbonate microporous material with bimodal distribution |
WO2016022103A1 (en) | 2014-08-05 | 2016-02-11 | Amitabha Kumar | Filled polymeric composites including short length fibers |
GB201420055D0 (en) * | 2014-11-11 | 2014-12-24 | Technion Res & Dev Foundation | Low density micropsheres |
JP5828950B1 (en) * | 2014-11-21 | 2015-12-09 | サンユレック株式会社 | Polyurethane resin composition, sealing material and electric / electronic component |
US9988512B2 (en) | 2015-01-22 | 2018-06-05 | Boral Ip Holdings (Australia) Pty Limited | Highly filled polyurethane composites |
WO2016195717A1 (en) | 2015-06-05 | 2016-12-08 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with lightweight fillers |
AU2016274974B9 (en) * | 2015-06-12 | 2019-07-11 | 3M Innovative Properties Company | Buoyancy module |
US20170267585A1 (en) | 2015-11-12 | 2017-09-21 | Amitabha Kumar | Filled polyurethane composites with size-graded fillers |
CN108701894B (en) | 2016-03-25 | 2021-05-18 | 康普技术有限责任公司 | Antenna with lens formed of lightweight dielectric material and associated dielectric material |
US11431100B2 (en) * | 2016-03-25 | 2022-08-30 | Commscope Technologies Llc | Antennas having lenses formed of lightweight dielectric materials and related dielectric materials |
AT518807B1 (en) * | 2016-06-21 | 2018-07-15 | Rainer Kurbos Dr | disco foam |
DE102017206542A1 (en) * | 2017-04-19 | 2018-10-25 | Bayerische Motoren Werke Aktiengesellschaft | Manufacturing method for a fiber composite component |
CN111095674B (en) | 2017-09-15 | 2022-02-18 | 康普技术有限责任公司 | Method for preparing composite dielectric material |
DE102017216409B4 (en) * | 2017-09-15 | 2022-01-05 | Weberit Werke Dräbing Gmbh | PLASTIC COMPONENT, COMPRESSION SPRING GUIDE ELEMENT AND TWO-MASS FLYWHEEL |
EP3587465A1 (en) * | 2018-06-27 | 2020-01-01 | Solvay Sa | Process for the preparation of a polyurethane foam |
CN113061284B (en) * | 2021-03-24 | 2023-03-14 | 中国科学院深圳先进技术研究院 | Light organic composite material and preparation method thereof |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1694653C3 (en) * | 1966-12-01 | 1973-10-25 | Minnesota Mining And Manufacturing Co., Saint Paul, Minn. (V.St.A.) | Process for the production of a filler-containing polyurethane |
US3510392A (en) * | 1968-09-16 | 1970-05-05 | Pittsburgh Corning Corp | Glass nodules in cellular polyurethane |
US4038238A (en) * | 1973-08-29 | 1977-07-26 | The Dow Chemical Company | Low density rapid-setting polyurethanes |
US4082702A (en) * | 1975-09-18 | 1978-04-04 | Dow Corning Corporation | Flame retardant rigid polyurethane syntactic foam |
US4303729A (en) * | 1979-07-20 | 1981-12-01 | Torobin Leonard B | Hollow plastic microspheres |
US4303736A (en) * | 1979-07-20 | 1981-12-01 | Leonard Torobin | Hollow plastic microspheres |
US4722943A (en) * | 1987-03-19 | 1988-02-02 | Pierce & Stevens Corporation | Composition and process for drying and expanding microspheres |
US4843104A (en) * | 1987-03-19 | 1989-06-27 | Pierce & Stevens | Syntactic polymer foam compositions containing microsphere fillers |
US4902722A (en) * | 1987-11-19 | 1990-02-20 | Pierce & Stevens Corp. | Expandable graphic art printing media using a syntactic foam based on mixture of unexpanded and expanded hollow polymeric microspheres |
US4916173A (en) * | 1988-05-06 | 1990-04-10 | Ciba-Geigy Corporation | Polyurethane syntactic foam modeling stock |
US4959395A (en) * | 1988-06-28 | 1990-09-25 | The B. F. Goodrich Company | Bulk polymerized molded products containing cycloolefin monoments with microencapsulated blowing agents |
JPH04257429A (en) * | 1991-02-08 | 1992-09-11 | Oji Paper Co Ltd | Preparation of foamed sheet |
-
1998
- 1998-06-09 CA CA002239950A patent/CA2239950C/en not_active Expired - Fee Related
- 1998-07-20 TW TW087111759A patent/TW408151B/en not_active IP Right Cessation
- 1998-07-29 AT AT98114186T patent/ATE300579T1/en not_active IP Right Cessation
- 1998-07-29 DK DK98114186T patent/DK0896976T3/en active
- 1998-07-29 EP EP98114186A patent/EP0896976B1/en not_active Expired - Lifetime
- 1998-07-29 ES ES98114186T patent/ES2245798T3/en not_active Expired - Lifetime
- 1998-07-29 DE DE69830955T patent/DE69830955T2/en not_active Expired - Fee Related
- 1998-08-07 CN CN98116227A patent/CN1088005C/en not_active Expired - Fee Related
- 1998-08-10 JP JP10236604A patent/JPH11140219A/en active Pending
- 1998-09-23 US US09/159,014 patent/US6166109A/en not_active Expired - Lifetime
-
2000
- 2000-01-28 HK HK00100550A patent/HK1021519A1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2239950C (en) | 2007-09-18 |
DE69830955T2 (en) | 2006-04-20 |
ATE300579T1 (en) | 2005-08-15 |
EP0896976A1 (en) | 1999-02-17 |
HK1021519A1 (en) | 2000-06-16 |
CN1088005C (en) | 2002-07-24 |
JPH11140219A (en) | 1999-05-25 |
EP0896976B1 (en) | 2005-07-27 |
TW408151B (en) | 2000-10-11 |
US6166109A (en) | 2000-12-26 |
DK0896976T3 (en) | 2005-10-10 |
CN1223927A (en) | 1999-07-28 |
DE69830955D1 (en) | 2005-09-01 |
ES2245798T3 (en) | 2006-01-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20140610 |